mechanism and origin of remote stereocontrol in the organocatalytic enantioselective formal c(sp2)-h alkylation using nitroalkanes as alkylating agents

Answer:

Na2S

Explanation:

since the charge of Na is +1 and the charge of S -2

Steam distillation cannot distinguish para hydroxy benzaldehyde from its ortho isomer because it has a higher boiling point and is more soluble in water.

Hydrogen bonds do benzaldehyde have?

We note a relationship between the advent of antiviral characteristics in the compounds and the presence of hydrogen bonds in the benzaldehyde molecules.

The intermolecular hydrogen bonds between the oxygen in the aldehyde and the water molecules as well as the acidic hydrogen from the OH group are present in meta benzaldehyde (B). As a result, the chemical has a higher chance of forming hydrogen bonds with water molecules.

(CH3)2C=O and CCl4 cannot create H-bonds with one another.

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Since the majority of the prey consumed by Bald Eagles in this ecosystem comes from nearby marine communities, we predicted that the recent decline in otter populations would have a negative indirect impact on Bald Eagle diets and demography.

In nutrition, diet is the sum of food consumed by a person or other organism. Despite what we had anticipated, we found no changes in the density of breeding pairs on four islands between 1993-1994 and 2000-2002.

Bald eagles can find fish, their main source of food, nearby rivers, lakes, and marshes where they live. However, as their numbers increase, bald eagles are extending their range and even building nests in cities. Waterfowl, turtles, rabbits, snakes, other small animals, and carrion are among the other things that bald eagles eat.

Bald Eagle diets, however, underwent significant changes between the two time periods, likely as a result of changes in prey availability brought on by the rise and subsequent decline in sea otter populations.

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Option D; Any pair of aldehyde or ketone reactants where one of the reactants has no alfa-hydrogens will lead to a single aldol product.

Aldehydes are carbonyl compounds that are produced both naturally and artificially and are present everywhere in the environment. Aldehydes are reactive species, therefore naturally, they are hazardous to the body. Any member of the family of organic compounds known as an aldehyde contains a carbon atom that also shares a single bond with a hydrogen atom, a double bond with an oxygen atom, and a double bond with another atom or group of atoms (designated R in general chemical formulas and structure diagrams). All aldehydes have what is known as the carbonyl group, a double bond between carbon and oxygen. Many aldehydes have pleasant aromas, and in theory, they are created by dehydrogenating (removing hydrogen) alcohols, which is how the word "aldehyde" originated.

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The products of a rxn in order:

1. Balance the skeleton equation and add state symbols (when applicable) to create a complete balanced equation

2. Write all reactants in ion notation.

3. Bond all the ions, reactants and products, to produce a skeleton equation

4. According to the pattern the reactants predict, move the ions only to the correct arrangement as products.

1. Balance the skeleton equation and add state symbols (when applicable) to create a complete balanced equation.

2. Write all reactants in ion notation.

3. Bond all the ions, reactants and products, to produce a skeleton equation.

4. According to the pattern the reactants predict, move the ions only to the correct arrangement as products.

For example, if the reactants are NH4+ and OH- and the predicted products are NH3 and H2O, the skeleton equation would be NH4+ + OH- --> NH3 + H2O.

The process of moving the ions to the correct positions would then be: NH4+ + OH- --> NH4OH --> NH3 + H2O.

5. Once the ions are in the correct positions, double check that the equation is balanced by counting the number of atoms on both sides of the equation (i.e. the number of nitrogen atoms must be the same on both sides, the number of hydrogen atoms must be the same on both sides, and the number of oxygen atoms must be the same on both sides).

6. Move the ions only to the correct arrangement as products: Move the ions to the correct positions to form the products of the reaction. Make sure that the number of atoms on each side of the equation are equal and the state.

7. If the equation is balanced, you have successfully predicted.

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The correct equation for solving for the temperature at which a reaction becomes spontaneous is AH - AS.

This equation is based on the equation for Gibbs Free Energy, which states that AG = AH - TS. In this equation, AG is the Gibbs Free Energy, AH is the enthalpy, T is temperature, and S is the entropy.

Therefore, if one knows the enthalpy and the entropy of a reaction, then one can calculate the temperature at which the reaction becomes spontaneous by subtracting the entropy from the enthalpy. This is because, at a given temperature, a reaction is spontaneous if the Gibbs Free Energy is negative.

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The statement that is  true about the elements;

Atom X and Atom Y are in the same row on the periodic table. Option C

We know that the periodic table has to do with an arrangement of the elements in an order that is systematic. As such, when we look at the periodic table, we are looking at a systematization of the elements in a way that it is quite easy for us to be able to identify the elements.

Now we know that the mass number is the sum of the atomic number which in turn is the proton number and the number of the neutrons in the atom.

We know that the atomic number is what would tell us the group to which the element has been found to belong and in this case we can see that element X is just right to element Y in the periodic table.

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a) Carbon tetra chloride in the preparation of alkynes acts a solvent

b) Hydrogen bromide in the preparation of alkynes adds across the multiple bonds of the alkyne

We know that in a chemical reaction, there are certain chemical species that are involved in the reaction because they interact and lead to the final products. In effect, the discussion about a chemical change just have to do with how reactants are able to interact with each other, bonds are broken and new bonds are made.

In each of the cases that have been mentioned in the question, what we have is an addition reaction. We can see that there is a substrate that has some reagents that act on it and then there is the product that we get as the bonds in the substrate are broken and new bonds are made.

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Answer: o solve this problem, we need to use the equation for the rate of a chemical reaction with a single reactant:

rate = k[reactant]

where k is the rate constant, [reactant] is the concentration of the reactant, and rate is the rate of the reaction.

The goal of the problem is to determine how long it takes for the reaction to be 72.6% complete. We can express this as a percentage of the reactant being consumed: 100% - 72.6% = 27.4% of the reactant remains.

We can rearrange the rate equation to solve for time:

time = (1/rate) * (1 - (27.4/100))

Substituting in the given values, we have:

time = (1/0.1161 s-1) * (1 - (27.4/100))

= 8.66 s

Therefore, it takes approximately 8.66 seconds for the reaction to be 72.6% complete.

Note: It is important to make sure to use consistent units when solving this problem. In this case, the rate constant is given in seconds, so the time unit should also be in seconds.

The balanced chemical equation is, Mg(s)+ SnSO4 (aq.) → MgSO4(aq.)+ Sn(s) .

The half cell reactions are, Sn2+(aq.)  + 2e-    ----->   Sn(s) and Mg(s)  ---->  Mg2+(aq.)   +  2e-  

A Half cell reaction is expressed either as an oxidation reaction in which electrons are lost or a reduction reaction where electronic are gained. The reactions occur in an electrochemical cell in which the electrons are lost at the anode through oxidation and consumed at the cathode where the reduction occurs. Half-cell reactions are useful in galvanic and voltaic cells in which the electrons flow from the anode to the cathode through an electrolyte to produce an electromotive force (EMF).

Half cell Reaction at cathode : Reduction 

Sn2+(aq.)  + 2e-    ----->   Sn(s)

Half- cell reaction at anode  : Oxidation 

Mg(s)  ---->  Mg2+(aq.)   +  2e-  

E1  is made of   Mg

E2 is made of  Sn 

Chemical species in solution S1 are  Mg2+  and SO42-  .

Chemical species in solution S2 are   Sn2+  and SO42-  

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This chemical reaction: ca(s) zncl2(aq)zn(s)cacl2(aq) then, balanced half-reactions describing the oxidation and reduction that happen in this reaction is Ca (s) + ZnCl2 (aq) ---> Zn (s) + CaCl2 (aq).

When the substrate's oxidation states change, a chemical reaction known as redox (reduction-oxidation) takes place. Reduction occurs when electrons are obtained or the oxidation state drops; oxidation occurs when electrons are lost or the oxidation state increases. There are two types of redox reactions: During an electron transfer, only one electron (usually) travels from the reducing agent to the oxidant. This type of redox reaction is frequently discussed in terms of redox couples and electrode potentials. When one substrate gives way to another, an atom transfers. When iron rusts, for example, oxygen's oxidation state decreases as it receives electrons released by the iron, while the oxidation state of the iron atoms increases as the iron transforms into an oxide. Despite the fact that oxidation processes are typically related to the generation of oxides, other chemical species can carry out the same function.  To weaken C=C (and other) bonds, hydrogen atoms are exchanged during hydrogenation.

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1. (a) Electrolysis Cause a non- is the process of using ·Spontane electrical energy to cause a non Spontane reaction to occur.

Explanation: direct current is to an electrochemical soupe cell, a reaction that is When normally nonspontaneous can be made to proceed the process is called electrolysis. energy provides electrons for carrying applied externally and The Source of electrical the reaction in a nonspontaneous direction.

1) b) Oxidation always occurs in Anode, in any cell, Whether it would be an electrochemical cell or a galvanic cell. The only difference is the charge, in electrochemical- The cell-cell anode is +vely charged and Cathode is the -ve charged.

so, in an Anode electrolytic cell Oxidation, occurs at the Anode

1) C) reduction always occurs in Cathode for all types of cells. In an electrolytic, all reduction occurs at Cathode

1)(d) Acid releases H+ in Solution, in electro- chemicaly reation, eg, Hcl → H⁺ + c H+ reduce at the cathode to form H₂ gas.

H+ e(⁻) -> 1/2  H2 (g) ↑ 60,

In the electrochemical reaction, studied today, H(+) from Acid Was reduced to hydrogen gas.

1(e) cell potential (E), Δve = - NFE  Δve Gibbs Free energy, For Spontaneous reaction to occur, she has to be negative, There for E has to be positive

So, when the total cell potential is a positive value, this Indicates that the Positive electrochemical reaction is Positive.

1) (f) Faraday, represents the amount of electric charge Carried by one mole of electrons.

F (Faraday) = 96500 e/mol Number of electrons per mole, ie Avogrode number Charge of electron 6.023x1023 6.24 X1018 = 96500 C/mol F

1) g) when Δve of a reaction is positive, then the reaction becomes nonspontaneous, i.e. reaction does not occur spontaneously. Therefore we have to add that amount to the System energy that Can drive that reaction to occur.

So, The Power source supplies the energy necessary For a non-spontaneous reaction to occur.

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The polystyrene sample weighs 57.3 grammes in total. We made the assumption in this case that the heat given off by the hot body is equal to the heat absorbed by the cold body temperature.

We made the assumption in this case that the heat given off by the hot body is equal to the heat absorbed by the cold body temperature.

where, = the polystyrene's specific heat

C = water's specific heat

T = polystyrene mass

M = 100.0 g of water mass

T1 is the system's end temperature, while I is the polystyrene's starting temperature.

F is the water's starting temperature.

The weight of the polystyrene is 59.6 g (mpmp).

Once you've entered all the values into the formula above, you'll obtain

Consequently, the polystyrene sample weighs 57.3 grammes.

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In a closed system, which is one where no matter can enter or leave, the total mass remains constant so mass will NOT change during a chemical reaction in a closed system and the correct option is option B and D.

In a closed system, the total mass remains constant according to the Law of Conservation of Mass, which states that mass cannot be created or destroyed in a chemical reaction. Therefore, during a chemical reaction in a closed system, the mass of the substances involved will not change.

There is no release or absorption of energy whereas the rearrangement of atoms and molecules can result in changes in density. It is important to note that while mass remains constant, the composition and arrangement of the substances can undergo significant transformations.

Thus, the ideal selection is option B and D.

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the direction of electron flow and labelling  anode and the cathode are: At anode is where oxidation takes place, that is Cr(s) Cr3+(aq) +3e- this is the oxidation .

At cathode is where reduction takes place, Fe3+(aq)+3e- Fe(s).This is the reduction Cell reaction is Cr(s) Cr3+(aq)+3e- where E°-0.73V Fe3+(aq)+3e- Fe(s) where E°= -0.036V Cr(s) +Fe3+(aq) Cr3(aq)+Fe(s) E°cell=0.69V Cell reaction for Cr(s) +Fe3+(aq)→ Cr3+(aq) + Fe(s) is E cell is 0.69V. What happens would be that electrons flow from the negative terminal thru the loop and into the gate electrode of the origin. Current flows and particle flow are both employed. An electrode is a strong insulating material that conduct electric current through nonmetals solids, liquids, gases, plasmas, or vacuums. The anode is indeed the electrode into which electrons flow. The cathode is indeed the electrode out of which electricity is given or flows. Typically, the anode is on the positive side. A cathode is a drawback.

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Rank the relative viscosity and vapor pressure of the substances Paraffin, hexadecane, octane, 2,2,4-trimethylpentane,methane.

In addition to being a fuel or fuel component for diesel and tractor engines, paraffin is frequently utilized as a fuel for jet engines and rockets. These are some typical applications for paraffin: Paraffin wax, a white or colorless soft solid that is used as a lubricant, in candles, crayons, electrical insulation, and petroleum jelly, is a complex mixture of hydrocarbons that is especially obtained from distillates of wood, coal, petroleum, or shale oil. It is primarily used in coating and sealing, candles, rubber compounding, pharmaceuticals, and cosmetics. Consuming excessive amounts of paraffin might result in intestinal blockage, which can bring on symptoms including nausea, vomiting, and constipation. An individual with a dye allergy could get tongue swelling if the paraffin contains that dye.

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Answer:

3Ca(OH)2 = 3(40+2(16+1))

= 222

448.2 ÷ 222 = 2.02mol

6NaOH = 6(23+16+1)

= 240

240 × 2.02mol = 484.5 g

According to Dalton's law of partial pressure, the pressure of the oxygen collected is 98.02 kPa.

Pressure is defined as the force applied on an object perpendicular to it's surface per unit area over which it is distributed.Gauge pressure is a pressure which is related with the ambient pressure.

There are various units by which pressure is expressed most of which are derived units which are obtained from unit of force divided by unit of area . The SI unit of pressure is pascal .

In this case,  pressure of the oxygen collected is obtained by Dalton's law of partial pressure, as 101-2.98=98.02 kPa.

Thus, the  pressure of the oxygen collected is 98.02 kPa.

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If chemical signals in the cytoplasm control the progression of a cell to the M phase of the cell cycle, then fusion of a cell in G1 with a cell in early M phase would most likely result in the condensation of chromatin in preparation of nuclear division in both cells.

The cytoplasm is the dispersed phase fluid that surrounds the inside of the cell. It acts as a catalyst for biochemical processes. It serves as a foundation on such what other organs can function inside the cell. Every one of the features for cellular growth, economic expansion and reproduction are decided to carry out in the cytoplasm of a cell. Chromatin is a DNA and protein mixture that forms the chromatids unearthed in the mitochondria of humans as well as other higher organisms. Many proteins, particularly histones, package the huge quantity of DNA in a genetic code into a highly condensed package that can fit inside the cell nucleus.

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Because NH3 molecules in the liquid phase require energy to overcome their intermolecular interactions and transform into free gas molecules, this expression reads NH3(l)— NH3(g). Heat is transferred from the environment to the system during phase shifts.

Ammonia has the chemical formula NH3 and is a colourless gas.Nitrogen and hydrogen make up its composition. Its name in aqueous form is ammonium hydroxide. This inorganic substance smells strongly. It is hazardous and corrosive in its concentrated form. Ammonia has a density of 0.769 kg/m3 at STP, making it lighter than air. It is frequently employed as fertiliser. Additionally, it is employed in the production of explosives like TNT and nitrocelluloseAdditionally, it is employed in the manufacture of soda ash and the Ostwald process to produce nitric acid. A strong alkali, such as sodium hydroxide or calcium hydroxide  2NH4Cl + Ca(OH)2 → CaCl2 + 2H2O + 2NH3(g) is heated with an ammonium salt, such as ammonium chloride NH4Cl, to produce ammonia (g)

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Answer:

When a photon of light hits an electron, the photon transfers some of its energy to the electron. If the photon has enough energy, it can excite the electron, which means that it can raise the electron to a higher energy state. In other words, the photon's energy can be absorbed by the electron, causing the electron to move to a higher energy level within an atom or molecule.

Answer:

Explanation:

As we know that in the photoelectric effect, a low-energy gamma photon that collides with an atom can tranfer all its energy to an inner orbital electron and cause the ejection of the ELECTRON FROM THE ATOM

The amount of energy required to eject the electrons depends upon on the atomic number.

Based on the mass of the mixtures and the masses of the rice grains and the navy beans;

The number of grains of rice in the mixture is 160 grains

The number of navy beans in the mixture is 2282 navy beans

The mass of the navy beans is obtained from the mass of the mixture of the rice and navy beans.

The mass of the navy beans is obtained using the formula below:

Mass of navy beans = mass of mixture - mass of the rice grains

The mass of the mixture of the rice and navy beans = 143.85 g

The mass of the rice grains = 4.65 g

assuming the mass of a single grain of rice is 0.029 grams

The number of grains of rice = 4.65 / 0.029

The number of grains of rice in the mixture  = 160 grains

Assuming the mass of a single navy bean is 0.0601 g

The number of navy beans = (143.85 - 4.65) / 0.061

The number of navy beans  = 2282 navy beans

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The exothermic processes are;

freezing of water into ice

sodium hydroxide dissolving in water producing a hot solution

condensation of water vapor into rain droplets

We know that an exothermic reaction has to do with the kind of reaction that involves the loss of energy. This implies that energy is given out by the system.

In this case we would look for the kind of processes in which the temperature would increase at the end of the process much higher than it was at the beginning of the process.

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The symbol for each isotope in the form Ax (a)⁶⁰₂₇Co and  (b)²²₁₀  Ne and (c)¹³¹₅₃I and (d)²⁴⁴₉₄ Pu

They are atoms that have different numbers of neutrons but the same amount of protons. Despite having nearly equal chemical properties, they have different masses, which impacts their physical qualities.

Every element has an isotope. The number of protons in each atom of a particular element is the same, but the total amount of neutrons and protons in each atom varies. They are virtually equal or identical when that comes to an element's isotopes' chemical characteristics. Different isotopes have almost comparable chemical characteristics.

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Answer: 1 mol .

Explanation:

At STP ;  1 mol of a gas contains a volume of 22.4 L (liters).

Answer:

water and ammonia (nh3)

Explanation:

NH3 + H2O => NH4OH

Answer:

it's not possible for a solid material to transfer heat through convection.

Explanation:

This would require more movement within the material, than a solid is capable of.

This brings us to liquids and gases.

The number of moles of water lost when the sample was heated is 0.1026 mol. the formula of hydrated compound is MgCl₂.6H₂O.

When the sample is heated The total number of moles of water lost is given as :

mass of H₂O loss = 25.825 - 23.997

                            = 1.848 g

moles of H₂O = mass / molar mass

                       = 1.848 / 18

                       = 0.1026 mol

mass of anhydrous MgCl₂ = 23.977 - 22.347

                                            = 1.630 g

moles of MgCl₂ = mass / molar mass

                          = 1.630 / 95.20

                          = 0.0171 mol

moles of H₂O per MgCl₂ = 0.1026 / 0.0171

                                         = 5.99 = 6 mol

the formula of hydrated compound = MgCl₂.6H₂O

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Genetics focus on short tandem repeats in the DNA, that are non-coding regions.

DNA is a genetic material of human beings, plants and animals. It serves an of carrying information for survival, growth, development, immunity, digestion, metabolism and other significant processes. Besides, it is unique among each individual and hence can be utilised for identification.

DNA typing or fingerprinting is known by several other names. At a specific locus, there repeated units of nitrogenous bases. However, the number varies which can be detected to identify the family relationship, parentage, identity and transplantation.

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