Andy needs to determine the freezing point depression of 30.0 mL of 0.50 m AlCl3 aqueous solution. When dissolved, AlCl3 dissociates into Al3 and Cl-. Andy realizes that he may need to reduce the effect of ion-pairing in his 0.50 m AlCl3 aqueous solution. Which of the following would reduce the ion-pairing effect in his AlCl3 solution?A. Add some solid AICIz to his solution.B. Add some water to his solution.C. Use only half of his initial volume.D. Use 45 mL of the 0.50 m AlCl3 solution.

Answer:

Reactions involving the replacement of one atom or group of atoms. - Substitution reaction

Reactions involving removal of two atoms or groups from a molecule - Elimination reaction

Products show increased bond order between two adjacent atoms - Elimination reaction

Reactant requires presence of a π bond - Addition reaction

Product is the structural isomer of the reactant - Rearrangement reaction

Explanation:

When an atom or a group of atoms is replaced by another in a reaction, then such is a substitution reaction. A typical example is the halogenation of alkanes.

A reaction involving the removal of two atoms or groups from a molecule resulting in increased bond order of products is called an elimination reaction. A typical example of such is dehydrohalogenation of alkyl halides.

Any reaction that involves a pi bond is an addition reaction because a molecule is added across the pi bond. A typical example is hydrogenation of alkenes.

Rearrangement reactions yield isomers of a molecule. Rearrangement may involve alkyl or hydride shifts in molecules.

Reactions involving the replacement of one atom or group of atoms is substitution reaction, reactions involving removal of two atoms or groups from a molecule and products show increased bond order between two adjacent atoms is elimination reaction, reactant requires presence of a π bond in addition reaction and product is the structural isomer of the reactant is rearrangement reaction.

Chemical reactions are those reactions in which reactants undergoes through a variety of changes for the formation of new product.

Hence, classification of above points are done according to their characteristics.

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Answer:

Limiting reagent is the potassium carbonate.

Percent yield of calcium carbonate is: 39.3 %

Explanation:

The reaction is:

CaCl₂ + K₂CO₃ → CaCO₃ + 2KCl

Formula for percent yield is:

(Produced yield / Thoeretical yield) . 100

Firstly we determine the moles of each reactant, in order to say what is the limiting reagent: ratio is 1:1.

1 mol of chloride need 1 mol of carbonate.

14.570 g . 1 mol /110.98 g = 0.131 moles of CaCl₂

12.285 g . 1 mol / 138.2g = 0.0889 moles of carbonate.

Limiting reagent is carbonate. For 0.131 moles of CaCl₂ we need the same amount of carbonate and we have less moles.

Ratio is also 1:1, with calcium carbonate.

1 mol of potassium carbonate produces 1 mol of calcium carbonate

then, 0.0889 moles will produce the same amount of CaCO₃

We convert moles to mass: 0.0889 mol . 100.08g /mol = 8.89 g

That's the theoretical yield; to find the percent yield:

(3.494 g / 8.89g) . 100 = 39.3%

Answer:

2 K(s) + Cl₂(g) ⟶ 2 KCl(s)

2 Cu(s) + O₂(g) ⟶ 2 CuO(s)

Explanation:

Both reactions are synthesis reactions (two substances combine to form another).

Reaction: K(s) + Cl₂(g) ⟶

The product is the binary salt KCl. The balanced chemical equation is:

2 K(s) + Cl₂(g) ⟶ 2 KCl(s)

Reaction: Cu(s) + O₂(g) ⟶

The most likely product is the metal oxide CuO. The balanced chemical equation is:

2 Cu(s) + O₂(g) ⟶ 2 CuO(s)

Answer: hello some part of your question is missing below is the missing part

In an experiment to determine the % of ascorbic acid in Vitamin C Tablets by Titration with Potassium Bromate,

answer:

Oxidation half reaction of Vitamin C

Explanation:

The solution will turn cloudy dark purple even after reaching endpoint when allowed to settle with time. because of the Oxidation half reaction of Vitamin C. also during the Titration process few drops of starch solution will be added to help determine the endpoint of the experiment .

Answer:

On heating, the van der Waals dispersion forces existing then will easily break as it has a low boiling point and sublimates into gas. On heating iodine in the test tube, iodine evolves as violet fuming gas.

Explanation:

Chemistry and chemical reactions are not just limited to the laboratories but also the world around you.

Chemistry in Food Production:

Plants produce food for themselves through photosynthesis; which is a complex chemical reaction in itself. The chemical reaction that takes place in photosynthesis is the most common and vital chemical reaction. 

6 CO2 + 6 H2O + light → C 6H12O6 + 6 O2

Chemistry in Hygiene:

Right before you consume your food, you make it a point to wash your hands with soap. Isn’t it? The cleaning action of soap is based on its ability to act as an emulsifying agent. Soaps are fatty acids salts of sodium or potassium; produced by a chemical reaction called saponification. Soaps interact with the grease or oil molecule, which, in turn, results in a cleaner surface.

The Chemistry of an Onion:

Ever wondered why you shed tears while chopping an onion? This also happens because of the underlying chemistry concepts. As soon as you slice an onion, sulfenic acid is formed from amino acid sulfoxides. Sulfenic acid is responsible for the volatile gas, propanethiol S-oxide, that stimulates the production of tears in the eyes.

Chemistry in Baking:

Who does not like to eat fluffy freshly baked bread? Baking soda is an efficient leavening agent. The addition of baking soda to food items before cooking leads to the production of carbon dioxide (CO2); which causes the foods to rise. This whole process of rising of baked good is called chemical leavening.

Chemistry in Food Preservatives:

In case you ever read the ingredients on the bottle of ketchup, jams or pickles, you might be surprised to see a never-ending list of chemicals. What are they? These chemicals are called food preservatives; which delay the growth of microorganisms in foods. The chemical food preservatives not only prohibit the growth of bacteria, virus, fungi but also hinder the oxidation of fats, which is responsible for making the foods rancid. The most common chemical food preservatives are sodium benzoate, sorbic acid, potassium sorbate, calcium sorbate, sodium sorbate, propionic acid, and the salts of nitrous acid.

Chemistry in Digestion

The moment you put food in your mouth, a number of different chemical reactions start in your digestive tract. Saliva contains the enzyme amylase, which is responsible for breaking down carbohydrates, the stomach starts producing hydrochloric acid, the liver releases bile and the list of compounds released during digestion goes on. How do they work? All these enzymes undergo chemical reactions so that proper digestion, as well as assimilation of the food, occurs.

The Working of a Sunscreen

Before going out on a sunny day, you make it a point to wear sunscreen. Even the principle, behind the working of a sunscreen, has a chemistry background. The sunscreen uses a combination of organic and inorganic compounds to act as a filter for incoming ultraviolet rays. Sunblocks, on the other hand, scatter away UV light; so that it is unable to penetrate deep into the skin. Sunblocks contain complex chemical compounds like zinc oxide or titanium oxide, which prevent the UV rays to invade deeper into the skin.

Chemistry in Rust Formation

With time, your iron instruments start developing an orange-brown flaky coating called rust. The rusting of iron is a type of oxidation reaction. The atoms in the metal iron undergo oxidation and reduction; causing rusting. The formation of verdigris on copper and the tarnishing of silver are also the other everyday examples of chemical reactions. The chemical equation underlying rusting is:

Fe + O2 + H2O → Fe2O3. XH2O

Hope it helps.

Answer:

(a) The moles of CuSO₄ is 3.125 × 10⁻³ moles.

(b) The moles of Cu is 3.125 × 10⁻³ moles.

(c) The mass of Cu is 0.2 g.

Explanation:

Given:

Mass of CuSO₄ = 0.5 g

Molar mass of CuSO₄ = 160 g/mol

The given balanced chemical equation is:

[tex]2Al+3CuSO_4\rightarrow 3Cu+Al_2(SO_4)_3[/tex]

Part (a):

Calculating the moles of CuSO₄.

[tex]\text{Moles of } CuSO_4=\frac{\text{Mass of }CuSO_4}{\text{Molar mass of }CuSO_4}\\\\\text{Moles of } CuSO_4=\frac{0.5g}{160g/mol}\\\\\text{Moles of } CuSO_4=3.125\times 10^{-3}mol[/tex]

Thus, the moles of CuSO₄ is 3.125 × 10⁻³ moles.

Part (b):

Calculating the moles of Cu.

From the balanced chemical equation, we conclude that:

As, 3 moles of CuSO₄ reacts to give 3 moles of Cu

So, 3.125 × 10⁻³ moles of CuSO₄ reacts to give 3.125 × 10⁻³ moles of Cu

Thus, the moles of Cu is 3.125 × 10⁻³ moles.

Part (c):

Calculating the mass of Cu.

Mass of Cu = Moles of Cu × Molar mass of Cu

Molar mass of Cu = 64 g/mol

Mass of Cu = (3.125 × 10⁻³ mole) × (64 g/mol)

Mass of Cu = 0.2 g

Thus, the mass of Cu is 0.2 g.

Answer:

0.375mL of solution of nalorphine must be injected

Explanation:

A solution of 0.40% (w/v) contains 0.40g of solute (In this case, nalorphine), in 100mL of solution. To obtain 1.5mg of nalorphine = 1.5x10⁻³g of nalorphine are needed:

1.5x10⁻³g * (100mL / 0.40g) =

1 NaCl + 1 HCl ➡️ 1 NaCl + Water (H2O) .

Answer:

Explanation:

[H+] = 0.1x0.03x2 + 0.2x0.03 = 0.012 mol

[OH-] = 0.001x0.05x2 = 0.0001 mol

=> [H+] dư = 0.012 - 0.0001 =0.0119 mol

pH = -log[H+] = 1.92

Answer:

2-ethyl-3-methylbut-2-ene

Explanation:

The whole idea of IUPAC nomenclature is to devise a universally accepted system of writing the name of a compound from its structure.

According to IUPAC nomenclature, the root of the compound is the longest carbon chain. The substituents are named in alphabetical order and in such a way as to give each one the lowest number. The position of the functional group is indicated accordingly.

For the compound in question, its correct IUPAC name is 2-ethyl-3-methylbut-2-ene.