A solution is known to contain only one type of cation. Addition of Cl1- ion to the solution had no apparent effect, but addition of (SO4)2- ion resulted in a precipitate. Which cation is present

Answer:

The correct answer is CaO > LiBr > KI.

Explanation:

Lattice energy is directly proportional to the charge and is inversely proportional to the size. The compound LiBr comprises Li+ and Br- ions, KI comprises K+ and I- ions, and CaO comprise Ca²⁺ and O²⁻ ions.  

With the increase in the charge, there will be an increase in lattice energy. In the given case, the lattice energy of CaO will be the highest due to the presence of +2 and -2 ions. K⁺ ions are larger than Li⁺ ion, and I⁻ ions are larger than Br⁻ ion.  

The distance between Li⁺ and Br⁻ ions in LiBr is less in comparison to the distance between K⁺ and I⁻ ions in KI. As a consequence, the lattice energy of LiBr is greater than KI. Therefore, CaO exhibits the largest lattice energy, while KI the smallest.  

Arranging the chemical compounds in order of decreasing magnitude of lattice energy, we have:

c. CaO.

a. LiBr

b. KI

Lattice energy can be defined as a measure of the energy required to dissociate one (1) mole of an ionic compound into its constituent anions and cations, in the gaseous state.

Hence, it is typically used to measure the bond strength of ionic compounds.

Generally, lattice energy is inversely proportional to the size of the ions and directly proportional to their electric charges.

Lithium bromide (LiBr) comprises the following ions:

Potassium iodide (KI) comprises the following ions:

Calcium oxide (CaO) comprises the following ions:

From the above, we can deduce that there is an increase in the charge possessed by the ionic chemical compounds and as such this would result in an increase in the lattice energy.

In order of decreasing magnitude of lattice energy, the chemical compounds are arranged as:

I. CaO.

II. KI.

III. LiBr.

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Answer:

Explanation:

A tertiary alcohol is a compound (an alcohol) in which the carbon atom that has the hydroxyl group (-OH) is also bonded (saturated) to three different carbon atoms.

Based on the question, the only tertiary alcohol that can result from C₆H₁₄O that have a 4-carbon chain is

2-hydroxy-2,3-dimethylbutane

     H  OH   H    H

      |     |       |      |

H - C - C -   C  - C - H

      |     |       |      |

     H  CH₃  CH₃ H

From the above, we can see that the carbon atom having the hydroxyl group is also bonded to three other carbon atoms. And since we aren't considering stereochemistry, this is the only tertiary alcohol we can have with a 4-carbon chain

Answer:

CO2 will diffuse more rapidly.

Explanation:

From Graham's law of diffusion, we understood that the rate of diffusion of a gas is inversely proportional to the square root of its density as shown below:

Rate (R) & 1/√Density (d)

R & 1/√d

But, the density of a gas is directly proportional to the relative molecular mass (M) of the gas.

Thus, we can say that the rate of diffusion of a gas is inversely proportional to the square root of the molar mass of the gas. This can be represented mathematically as:

Rate (R) & 1/√Molar mass (M)

R & 1/√M

From the above illustration, we can say that the lighter the gas, the faster the rate of diffusion and the heavier the gas, the slower the rate of diffusion.

Now, to answer the question given above,let us determine the molar mass of Cl2 and CO2.

This is illustrated below:

Molar mass of Cl2 = 2 x 35.5 = 71 g/mol

Molar mass of CO2 = 12 + (2x16) = 12 + 32 = 44 g/mol

Summary

Gas >>>>>> Molar mass

Cl2 >>>>>> 71 g/mol

CO2 >>>>> 44 g/mol

From the illustration above, we can see that CO2 is lighter than Cl2.

Therefore, CO2 will diffuse more rapidly.

Answer: CO2

Explanation:

Answer: [tex]\Delta G^{0}[/tex] = 168.12 kJ

Explanation: Gibbs Free Energy, at any time, is defined as the enthalpy of the system minus product of temperature and entropy of the reaction, i.e.:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

Enthalpy is defined as internal heat existent in the system. It is calculated as:

[tex]\Delta H^{0} = \Sigma H^{0}_{product} - \Sigma H^{0}_{reagent}[/tex]

Using Enthalpy Formation Table:

[tex]\Delta H^{0} = [3*(-299.9)+(-524.7)] - (-1277)[/tex]

[tex]\Delta H^{0} = 62,6 kJ[/tex]

Entropy is the degree of disorder in the system. It is found by:

[tex]\Delta S^{0} = \Sigma S^{0}_{products} - \Sigma S^{0}_{reagents}[/tex]

Calculating:

[tex]\Delta S^{0} = (-321.7) + 3(-10.8) - 0[/tex]

[tex]\Delta S^{0} = -354.1J[/tex]

And so, Gibbs Free energy will be:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

[tex]\Delta G^{0} = 62600 - [298.(-354.1)][/tex]

[tex]\Delta G^{0} = 168121.8 J[/tex]

Rounding to the nearest kJ:

[tex]\Delta G^{0}[/tex] = 168.12 kJ

Answer:

466 torr

Explanation:

Step 1: Given data

Step 2: Calculate the final pressure

Since we have a gas changing at a constant temperature, we can calculate the final pressure using Boyle's law.

P₁ × V₁ = P₂ × V₂

P₂ = P₁ × V₁ / V₂

P₂ = 626 torr × 5.00 L / 6.72 L

P₂ = 466 torr

Answer:

The anawer of this question is 0.024 m/h

Explanation:

Other explanations of the question are additional.

Answer:

Reaction of Chlorine with Hydrogen Chlorine and Hydrogen mixed together explodes when exposed to sunlight, which produces Hydrogen Chloride. In the dark away from sunlight, no reaction occurs, so light energy is required for a reaction. Cl2 + H2 = 2 HCl Reaction of Chlorine with Non-Metals Chlorine directly combines with most non-metals.

Explanation:

I hope this helps bro

Answer:

3BaO + Al₂(SO₄)₃  →  Al₂O₃+ 3BaSO₄

Explanation:

Yes! A reactiin occurs between barium hydroxide and auminium sulphate.

barium sulfate (BaSO4) and aluminum hydroxide (Al(OH)3) are the products obtained in this reaction.

The reaction is given by the equation below;

3BaO + Al₂(SO₄)₃  →  Al₂O₃+ 3BaSO₄

Answer:

It has 2

Explanation:

The significant figures are 1 and 5!

Hope this helps:)

Answer:

A double bond is formed when two pairs of electrons are shared between the two participating atoms. It is represented by two dashes (=). It is represented by two dashes (=). Double covalent bonds are much stronger than a single bond, but they are less stable

Explanation:

Answer:

Siδ⁺ -- Pδ⁻⁻

Clδ⁻⁻ -- Pδ⁺

Siδ⁺ -- Clδ⁻⁻

Of the mentioned bonds the most polar bond is Si -- Cl

The polarity of the bond primarily relies upon the electronegativity difference between the two atoms that forms the bond. Therefore, if the electronegativity difference between the two atoms that forms the bond is more the bond will be more polar, and if it is less then the bond will be less polar. The electronegativity of the atoms mentioned is Si = 1.8 , P = 2.1 and Cl = 3.00.  

Therefore, the Si - Cl atoms exhibit more electronegativity difference, thus, the Si - Cl bond will be the most polar bond.  

Answer:

Zeros located at the end of significant figures are significant.

Explanation:

Hope it will help :)

Answer:

A process that involves rearrangement

Explanation:

A chemical reaction is the process that involves rearrangement of the molecular or ironic structure of a substance, as a distinct from a change in physical form or a nuclear reaction.

Answer:

Explanation:

Chemistry

The chemical reaction H2(g) + ½ O2(g) → H2O(l) describes the formation of water from its elements.

The reaction between iron and sulfur to form iron(II) sulfide is another chemical reaction, represented by the chemical equation:

8 Fe + S8 → 8 FeS

Explanation:

An atom undergoes alpha decay by losing a helium atom.

So when bismuth undergoes alpha decay, we have;

²¹⁰₈₃Bi --> ⁴₂He + X

Mass number;

210 = 4 + x

x = 206

Atomic number;

83 = 2 + x

x = 81

The element is Thallium. The symbol is Ti.

For the second part;

X --> ⁴₂He + ²³⁴₉₀Th

Mass number;

x = 4 + 234 = 238

Atomic Number;

x = 2 + 90 = 92

The balanced nuclear equation is;

²³⁸₉₂U --> ⁴₂He + ²³⁴₉₀Th

Answer: d=2000 g/L

Explanation:

Density is mass/volume. The units are g/L. Since we are given mass and volume, we can divide them to find density. First, we need to convert kg to g.

[tex]10kg*\frac{1000g}{1kg} =10000 g[/tex]

Now that we have grams, we can divide to get density.

[tex]d=\frac{10000g}{5 L}[/tex]

d=2000g/L

Answer:

4.22

Explanation:

We know from the question, that the pOH of the solution is 9.78. Now the pOH is defined as -log [OH^-].

If the pOH of a solution is given, one may obtain the pH of such solution from the formula;

pH + pOH =14

Hence we can write;

pH = 14-pOH

pH = 14 - 9.78 = 4.22

Hence the pH of the solution is 4.22.

Answer:

A (I_2(g), Br_2 (g), Cl_2 (g), F_2 (B): The ranking can best be explained by the trend entropy decreases as 5. molar mass decreases.

B (H_2O_2 (g), H_2S(g), H_2O(g): The ranking can best be explained by the decreases a trend entropy decreases as 3. molar mass and structure complexity decreases.

C. (C(s, amorphous), C(s, graphite), C(s, diamond): The ranking can best be explained by the trend entropy decreases as 4. structure complexity decreases.

Explanation:

Hello.

In this case, we can understand a higher entropy when more disorder is present and a lower entropy when less disorder is present, thus:

A (I_2(g), Br_2 (g), Cl_2 (g), F_2 (B): The ranking can best be explained by the trend entropy decreases as 5. molar mass decreases since iodine has the greatest molar mass (254 g/mol) and fluorine the least molar mass (38 g/mol).

B (H_2O_2 (g), H_2S(g), H_2O(g): The ranking can best be explained by the decreases a trend entropy decreases as 3. molar mass and structure complexity decreases since hydrogen peroxide weights 34 g/mol as well as hydrogen sulfide but the peroxide has more bonds (more complex, higher entropy).

C. (C(s, amorphous), C(s, graphite), C(s, diamond): The ranking can best be explained by the trend entropy decreases as 4. structure complexity decreases since diamond has a well-ordered structure and amorphous carbon has a very disordered one.

Best regards.

Answer:

D

Explanation:

Addition of 0.05 M HCl, will react with all of the C2H3O2- from LiAc which will give 0.05 M more HAc. So there will be no Acetate ion left to make the solution buffer. Hence, the correct option for the this question is d, which is adding 0.050 moles of HCl.

The action that destroys the buffer is option c. adding 0.050 moles of HCl.

It is a solution of a weak acid and salt.

Here, The buffer will destroy at the time when either HC2H3O2 or NaC2H3O2 should not be present in the solution.

The addition of equal moles of HCl finishly reacts with equal moles of NaC2H3O2. Due to this,  there will be only acid in the solution.

Since

moles of HC2H3O2 = 1*0.250 = 0.250

moles of NaC2H3O2 = 1*0.050 = 0.050.

moles of HCl is added = 0.050

Now

The reaction between HCl and NaC2H3O2

[tex]HCl + NaC_2H_3O_2 \rightarrow HC_2H_3O_2 + NaCl[/tex]

Now

BCA table is

            NaC2H3O2  HCl       HC2H3O2

Before 0.050 0.050 0.250

Change -0.050 -0.050 +0.050

After 0 0 0.300

Now, the solution contains the acid (HC2H3O2 ) only.

Therefore addition of 0.050 moles of HCl will destroy the buffer.

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Answer:

The binding energy = 8.64972649×10¹⁰ kJ/mole

Explanation:

Given that:

An atom of 108Te has a mass of 107.929550 amu.

In a 108 Te atom, there are 52 protons and 56 neutrons

where;

mass of proton= 1.007825 amu

mass of neutron= 1.008665 amu

Similarly; The atomic number of Te = 52

the mass of 52 protons = 52 ×  1.007825  amu

the mass of 52 protons = 52.4069 amu

the mass of 56 neutrons = 56 ×  1.008665 amu

the mass of 56 neutrons = 56.48524 amu

The total mass can now be = the mass of 52 protons + the mass of 56 neutrons

The total mass = 52.4069 amu +  56.48524 amu

The total mass = 108.89214  amu

Recall  : it is given that An atom of 108Te has a mass of 107.929550 amu.

Therefore, the mass defect will be = 108.89214  amu - 107.929550 amu

the mass defect = 0.96259amu

where 1 amu = 1.66× 10⁻²⁷ kg

Therefore, 0.96259amu = (0.96259  × 1.66× 10⁻²⁷) kg

= 1.5978994 × 10⁻²⁷kg

The binding energy = mass defect × (speed of light)²

where;

speed of light c = 2.99792 × 10⁸ m/s

The binding energy = 1.5978994 × 10⁻²⁷kg  ×  2.99792 × 10⁸ m/s

The binding energy = 1.43611597 × 10⁻¹⁰  J

The binding energy =  1.43611597 × 10⁻¹³ kJ/atom

since 1 mole = 6.023 × 10²³ atom (avogadro's constant)

Then;

The binding energy = ( 1.43611597 × 10⁻¹³ )× (6.023 × 10²³)  kJ/mole

The binding energy = 8.64972649×10¹⁰ kJ/mole

Answer:

B and C

Explanation:

The google definition of precipitate is "a solid formed by a change in a solution, often due to a chemical reaction or change in temperature that decreases solubility of a solid". So in this case, the "solid formed from a frozen liquid" and "a chunky solid form from 2 liquids combining" are both examples of a precipitate.

The correct answer is C, a chunky solid form from 2 liquids combining.

In the laboratory, we usually mix two chemicals. When we mix the chemicals, we expect them to interact in one way or another. The interaction of those chemicals is known as a chemical reaction.

When we mix two liquid chemicals and they interact with each other to yield a solid product, we say that a chemical reaction has occurred and that such chemical reaction has produced a precipitate.

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Answer:

A. The atomic mass is 243 amu, and the atomic number is 95.

Answer:

The oxidation state of silver in [tex]\rm Ag_2O[/tex] is [tex]+1[/tex].

The oxidation state of sulfur in [tex]\rm SO_2[/tex] is [tex]+4[/tex].

Explanation:

The oxidation states of atoms in a compound should add up to zero.

There are two silver [tex]\rm Ag[/tex] atoms and one oxygen [tex]\rm O[/tex] atom in one formula unit of [tex]\rm Ag_2O[/tex]. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of oxygen in most compounds (with the exception of peroxides and fluorides) is [tex]-2[/tex]. Silver oxide [tex]\rm Ag_2O[/tex] isn't an exception. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the (average) oxidation state of [tex]\rm Ag[/tex]:

[tex]\text{Oxidation state of $\rm Ag$} = 1[/tex].

Similarly, because there are one sulfur [tex]\rm S[/tex] atom and two oxygen [tex]\rm O[/tex] atoms in each [tex]\rm SO_2[/tex] molecules:

[tex]\begin{aligned}&\rm 1\times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of [tex]\rm O[/tex] in [tex]\rm SO_2[/tex] is also [tex]-2[/tex], not an exception, either.

Therefore:

[tex]\begin{aligned}&\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the oxidation state of [tex]\rm S[/tex] here:

[tex]\text{Oxidation state of $\rm S$} = 4[/tex].

Answer:

A. Ka = [CO2] / [C] [O2]^1/2

B. Kb = [CO2] / [CO] [O2]^1/2

Explanation:

Equilibrium constant is simply defined as the ratio of the concentration of the products raised to their coefficient to the concentration of the reactants raised to their coefficient.

Now, we shall obtain the expression for the equilibrium constant for the reaction as follow:

A. Determination of the expression for equilibrium constant Ka.

This is illustrated below:

C(s) + 1/2 O2(g) <==> CO(g)

Ka = [CO2] / [C] [O2]^1/2

B. Determination of the expression for equilibrium constant Kb.

This is illustrated below:

CO(g) + 1/2 O2(g) <==> CO2(g)

Kb = [CO2] / [CO] [O2]^1/2

The given question is incomplete, the complete question is:

How does the spontaneity of the process below depend on temperature? PCI5(9)+H2O(g)POCI3(g) +2HCI(g) -126 kJ mol1, AS = 146 J K-'mol1 ΔΗ Select the correct answer below: nonspontaneous at all temperatures spontaneous at all temperatures spontaneous at high temperatures and nonspontaneous at low temperatures spontaneous at low temperatures and nonspontaneous at high temperatures

Answer:

The correct answer is spontaneous at all the temperatures.

Explanation:

Gibbs Free energy is an essential relation that determines the spontaneity of any reaction, that is, ΔG = ΔH - TΔS

When ΔG is less than zero, that is, negative, the reaction is considered to be in spontaneous state. Based on the given information, ΔH = -126 kJ/mol

= -126000 J/mol, it is negative

ΔS = 146 J/K/mol, it is positive

Now, ΔG = ΔH-TΔS

= (-ve) - T (+ve), Thus, when ΔH, is -ve, ΔS is +ve, -TΔS is -ve, the ΔG will be -ve. Therefore, reaction will be spontaneous at all the temperatures.  

Answer:

B) geminal diol

Explanation:

Hello,

In this case, considering the attached picture, you can see that the substance resulting from the hydrolysis of an aldehyde or a ketone is a geminal diol since the two hydroxyl groups are in the same carbon. Such hydrolysis could be carried out in either acidic or basic conditions depending upon the equilibrium constant.

Regards.

Answer:

Cu2 + 2Mg-> 2Cu+ Mg2

Explanation:

Balance the equation and make sure both the reactant and the products are the same

Hope it will be helpful

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex]  is the correct half-reactions.

A balanced equation is an equation for a chemical reaction in which the number of atoms for each element in the reaction and the total oxidation numbers is the same for both the reactants and the products.

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex] is the correct half-reactions.

Magnesium is oxidized because its oxidation state increased from 0 to +2 while Cu is reduced because its oxidation state decreased from +2 to 0.

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Answer:

[tex]\large \boxed{\text{0.57 g/mL; 3.7 mL; 6.6 g; 0.366 g/mL}}[/tex]

Explanation:

1. Density from mass and volume

[tex]\text{Density} = \dfrac{\text{mass}}{\text{volume}}\\\\\rho = \dfrac{m}{V}\\\\\rho = \dfrac{\text{8.6 g}}{\text{15 mL}} = \text{0.57 g/mL}\\\text{The density is $\large \boxed{\textbf{0.57 g/mL}}$}[/tex]

2. Volume from density and mass

[tex]V = \text{9.7 g}\times\dfrac{\text{1 mL}}{\text{2.6 g}} = \text{3.7 mL}\\\\\text{The volume is $\large \boxed{\textbf{3.7 mL}}$}[/tex]

3. Mass from density and volume

[tex]\text{Mass} = \text{4.1 cm}^{3} \times \dfrac{\text{1.6 g}}{\text{1 cm}^{3}} = \textbf{6.6 g}\\\\\text{The mass is $\large \boxed{\textbf{6.6 g}}$}[/tex]

4. Density by displacement

Volume of water + object = 24.6 mL

Volume of water                = 12.8 mL

Volume of object               = 11.8 mL

[tex]\rho = \dfrac{\text{4.3 g}}{\text{11.8 mL}} = \text{0.36 g/mL}\\\text{The density is $\large \boxed{\textbf{0.36 g/mL}}$}[/tex]

Your drawing showing water displacement using a graduated cylinder should resemble the figure below.

Answer:

(a) when a reaction system reaches a state of equilibrium, the concentration of the products is equal to the concentration of the reactants

Determining whether the statements about equilibrium is True or False

A) The concentration of the products is equal to the concentration of the reactants at equilibrium : TRUE

B) When a system is at equilibrium, Keq = 1 : TRUE

C) The rates of the forward reaction and the reverse reaction are equal at equilibrium :  TRUE

D) Adding a catalyst to a reaction system will shift the position of equilibrium to the right : FALSE

In a chemical reaction at equilibrium the value of Keq will be equal to 1 because the concentration of the products is equal to the concentration of the reactants in the chemica reaction. Also at equilibrium the rate of forward reaction is same as the rate of reverse reaction.

A catalyst can only affect the rate of reaction and not the amount of product ( yield of reaction).

Hence we can conclude that the answers to your questions are as listed above.

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Answer:

pH of solution B is 5

Explanation:

A weak acid, HA, is in equilibrium with water as follows:

HA(aq) + H₂O(l) ⇄ A⁻(aq) + H₃O⁺(aq)

Where Ka (10^-pKa = 1x10⁻⁹) is:

Ka = 1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

Where concentrations of this species are equilibrium concentrations

As initial concentration of HA is 0.1M, the equilibrium concentrations of the species are:

[HA] = 0.1M - X

[A⁻] = X

[H₃O⁺] = X

Where X is the amount of HA that reacts until reach the equilibrium, X is reaction coordinate.

Replacing in Ka expression:

1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

1x10⁻⁹ = [X] [X] / [0.1 - X]

1x10⁻¹⁰ - 1x10⁻⁹X = X²

1x10⁻¹⁰ - 1x10⁻⁹X - X² = 0

Solving for X:

X = -0.00001 → False solution, there is no negative concentrations.

X = 1x10⁻⁵ → Right solution.

As [H₃O⁺] = X

[H₃O⁺] = 1x10⁻⁵M

And pH = -log[H₃O⁺]

pH = 5

Answer:

1. Zinc sulfide : about the same solubility, no common ion is found.

2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.

3. Lead iodide  : about the same solubility, no common ion is found.

4. Silver hydroxide : about the same solubility, no common ion is found.

Explanation:

Hello,

In this case, we first must remember that adding a common ion (which is related with the dissolving solid) decreases the solubility of the insoluble solid due to the fact Le Chatelier's principle states the reaction will shift leftwards (reactants) to reestablish equilibrium, therefore, we have:

1. Zinc sulfide : about the same solubility, no common ion is found.

2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.

3. Lead iodide  : about the same solubility, no common ion is found.

4. Silver hydroxide : about the same solubility, no common ion is found.

Best regards.