Answer:
pH of the buffer is 7.33
Explanation:
The mixture of the ions H₂PO₄⁻ and HPO₄²⁻ produce a buffer (The mixture of a weak acid, H₂PO₄⁻, with its conjugate base, HPO₄²⁻).
To find pH of a buffer we use H-H equation:
pH = pka + log [A⁻] / [HA]
Where A⁻ is conjugate base and HA weak acid.
For the H₂PO₄⁻ and HPO₄²⁻ buffer:
pH = pka + log [HPO₄²⁻] / [H₂PO₄⁻]
Computing values of the problem:
pH =7.21 + log [0.125M] / [0.095M]
pH = 7.33
pH of the buffer is 7.33
What is the primary source of energy in most living communities?
Answer:
The sun
Explanation:
The sun is the primary source of energy in most living communities. The producers or the green plants that prepare their own food by the use of sunlight and other natural resources. Carbon dioxide, water, and other minerals are used by the plants to make their food in the presence of chlorophyll. Plants are then consumed by the consumers. This chain helps in forming the food chain and the food web.
15. Calculate the critical angle of glass and water combination. Show your calculation. 16. What is the critical angle for the interface between Mystery A and glass
Answer:
15. Critical angle of glass and water combination, θ = 62.45°
16. Critical angle for the interface between Mystery A and glass, θ = 37.93°
Note; The question is incomplete. The complete question is as follows:
Medium Air Water Glass Mystery A Mystery B Table-2 Speed (m/s) 1.00 C 0.75 c 0.67 0.41 c 0.71 c n 1.00 1.33 1.50 Index of Refraction n of a given medium is defined as the ratio of speed of light in vacuum, c to the speed of light in a medium, v. n = c/v
Table-4: Incident Angle (degrees) Reflected Angle Refracted angle (degrees) (degrees) % Intensity of reflected ray 0 10 20 30 40 50 N/A N/A N/A 30 40 50 0 11.3 22.7 34.2 46.3 59.5 N/A N/A N/A 0.67 1.22 3.08 % Intensity of refracted ray 100 100 100 99.33 98.78 96.92
When rays travel from a denser medium to a less dense medium, we can define a critical angle of incidence θ such that refracted angle θ₂ = 90°. Applying Snell's law: Critical angle θ = sin-1(n₂/n₁).
When the angle of incidence is greater than the critical angle, 100% of the light intensity is reflected. This is called total internal reflection because all the light is reflected.
15. Calculate the critical angle of glass and water combination. Show your calculation.
16. What is the critical angle for the interface between Mystery A and glass?
Explanation:
15. Applying Snell's law; Critical angle θ = sin-1(n₂/n₁).
where n₂,refractive index of water = 1.33, n₁, refractive index of glass = 1.50 since glass is denser than water
θ = sin-1(1.33/1.50)
θ = 62.45°
Critical angle of glass and water combination, θ = 62.45°
16. Refractive index of mystery A , n = c/v
where v = 0.41 c
therefore, n = c / 0.41 c = 2.44
Critical angle for the interface between Mystery A and glass, θ = sin-1(n₂/n₁).
where n₂,refractive index of glass = 1.50, n₁, refractive index of mystery A = 2.44 since mystery A is denser than glass as seen from its refractive index
θ = sin-1(1.50/2.44)
θ = 37.93°
Critical angle for the interface between Mystery A and glass, θ = 37.93°
If a salt is formed by combining NH3 (Kb=1.8×10−5) and CH3COOH (Ka=1.8×10−5), an aqueous solution of this salt would be:
Answer:
Neutral
Explanation:
pKa of acid = -log Ka
= -log (1.8 x 10^-5)
= 4.74
pKb of base = -log Kb
= 4.74
pKa of acid = pKb of base
salt pH formula : pH = 7 + 1/2 [pKa -pKb ]
here pKa = pKb
so pH = 7
the salt it is CH3COONH4 exactly neutral solution .
If a salt is formed by combining NH₃ (Kb=1.8×10⁻⁵) and CH₃COOH (Ka=1.8×10⁻⁵), an aqueous solution of this salt would be neutral.
What information does pH convey?pH of any solution tells about the acidity or basicity or neutral nature of the solution.
pH of any solution is directly proportional to the acid dissociation constant value (Ka) and base dissociation constant (Kb). In the question it is given that,
Value of Kb for NH₃ = 1.8×10⁻⁵
Value of Ka for CH₃COOH = 1.8×10⁻⁵
Ka & Kb values for the base and acid is same means it dissociates with same extent. So the aqueous solution of this acid and base is a neutral in nature as they have same number of acid and base ions in it.
Hence resultant solution will be a neutral solution .
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Write a balanced chemical equation for the base hydrolysis of methyl butanoate with NaOH. (Use either molecular formulas or condensed structural formulas, but be consistent in your equation.)
Explanation:
C5H10O2 + NaOH = C2H5COONa + C2H5OH
your result are : sodium propanoate and ethanol
A balanced chemical equation represents atoms and their numbers with their charge. The balanced equation for base hydrolysis is C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH.
What is hydrolysis?Base hydrolysis is the splitting of the ester linkage by the basic molecule. As the result the acidic ester portion makes the salt, and also alcohol is produced as the by-product.
The base hydrolysis of methyl butanoate is shown as,
C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH
Here, sodium propanoate and ethanol are produced by the splitting of methyl butanoate in the presence of the base (NaOH).
Therefore, C₅H₁₀O₂ + NaOH → C₂H₅COONa + C₂H₅OH is balanced reaction.
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Solid cesium bromide has the same kind of crystal structure as CsCl which is pictured below: If the edge length of the unit cell is 428.7 pm, what is the density of CsBr in g/cm3.
Answer:
[tex]\mathbf {density \ d =4.4845 \ g/cm^3}[/tex]
Explanation:
Let recall the crystal structure of CsBr obtains a BCC structure. In a BCC structure, there exist only two atom per cell.
The density d of CsBr in g/cm³ can be calculated by using the formula:
[tex]\mathtt{ density \ d = \dfrac{z \times molar\ mass \ (M)}{ edge \ length \ (a) \ \times avogadro's \ number \ (N)}}[/tex]
where;
z = 1 mole of CsBr
edge length = 428.7 pm = (4.287 × 10⁻⁸)³ cm
molar mass of CsBr = 212.81 g/mol
avogadro's number = 6.023 × 10²³
[tex]\mathtt{ density \ d = \dfrac{1 \times 212.81}{(4.287 \times 10^{-8})^3 \times 6.023 \times 10^{23}}}[/tex]
[tex]\mathtt{ density \ d = \dfrac{ 212.81}{47.4540533}}[/tex]
[tex]\mathbf {density \ d =4.4845 \ g/cm^3}[/tex]
The half-life of radium-226 is 1620 years. What percentage of a given amount of the radium will remain after 900 years
Answer:
68%
Explanation:
Since we need a percentage we can use any number we want for our initial value.
5(1/2)^900/1620 = 3.40
(3.40 / 5)*100 = 68%
To make sure lets use a different initial amount
1(1/2)^900/1620 = 0.68
(0.68/1) * 100 = 68%
To solve this question, we'll assume the initial amount of radium-226 to be 1.
Now, we shall proceed to obtaining the percentage of radium-226 that will after 900 years. This can be obtained as illustrated below:
Step 1Determination of the number of half-lives that has elapsed.
Half-life (t½) = 1620 years
Time (t) = 900 years
Number of half-lives (n) =?[tex]n = \frac{t}{t_{1/2}}\\\\n = \frac{900}{1620}\\\\n = \frac{5}{9}[/tex]
Step 2:Determination of the amount remaining
Initial amount (N₀) = 1
Number of half-lives (n) = 5/9
Amount remaining (N) =?[tex]N = \frac{N_{0} }{2^{n}}\\\\N = \frac{1}{2^{5/9}}[/tex]
N = 0.68Step 3Determination of the percentage remaining.
Initial amount (N₀) = 1
Amount remaining (N) = 0.68
Percentage remaining =?Percentage remaining = N/N₀ × 100
Percentage remaining = 0.68/1 × 100
Percentage remaining = 68%Therefore, the percentage amount of radium-226 that remains after 900 years is 68%
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Calculate ΔS∘rxn for the balanced chemical equation 2H2S(g)+3O2(g)→2H2O(g)+2SO2(g) Express the entropy change to four significant figures and include the appropriate units.
Answer:
-170.65
188.8+ 256.8-205.8-(2x205.2)
-170.65 is the entropy change.
What is Entropy Change?Entropy trade is the phenomenon that is the measure of change of disorder or randomness in a thermodynamic gadget. It is associated with the conversion of heat or enthalpy completed in work. A thermodynamic device that has extra randomness means it has high entropy.
Subtract the sum of the absolute entropies of the reactants from the sum of the absolute entropies of the products, each extended by using their suitable stoichiometric coefficients, to reap ΔS° for the reaction.
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Which of the following provides a characteristic of
MgO(s) with a correct explanation?
Choose 1 answer:
А
It is hard because its ions are held together by strong
electrostatic attractions.
B
It is malleable because its atoms can easily move past
one another without disrupting the bonding.
It is a poor conductor of electricity because its
electrons are tightly held within covalent bonds and
lone pairs.
It has a high melting point because its molecules
interact through strong intermolecular forces.
Answer:
А It is hard because its ions are held together by strong electrostatic attractions.
B It is malleable because its atoms can easily move past one another without disrupting the bonding.
Explanation:
These are correct explanations of the properties of magnesium.
C is wrong. Mg is a good conductor of electricity and it has metallic bonds.
D is wrong. Mg has no molecules. It has no intermolecular forces.
Find the pH of these buffer solutions using the information provided: 1L solution containing 80g of lactic acid (MW
Answer:
pH of the solution is 2.0
Explanation:
The lactic acid is a weak acid that is in equilibrium with water as follows:
Lactic acid + H2O ⇄ Lactate + H₃O⁺
And Ka for lactic acid: 1.38x10⁻⁴
Ka = 1.38x10⁻⁴ = [Lactate] [H₃O⁺] / [Lactic acid]
Initial concentration of lactic acid is (MW: 112.06g/mol):
80g * (1mol / 112.06g) / 1L = 0.714M
The equilibrium concentration of the species in the equilibrium are:
[Lactate] = X
[H₃O⁺] = X
[Lactic acid] = 0.714-X
Replacing in Ka expression:
1.38x10⁻⁴ = [X] [X] / [0.714-X]
9.8532x10⁻⁵ - 1.38x10⁻⁴X = X²
9.8532x10⁻⁵ - 1.38x10⁻⁴X - X² = 0
Solving for X:
X = -1.0x10⁻². False solution, there is no negative concentrations
X = 9.86x10⁻³M. Right solution.
As [H₃O⁺] = X
[H₃O⁺] = 9.86x10⁻³M
and pH = -log [H₃O⁺] = -log 9.86x10⁻³M
pH = 2.0
pH of the solution is 2.0(a) Identify the name of the method used below for the separation.
(b) Give one more application of this method of separation.
(c) What is the name for the line at position B ?
(d) what conclusions can you draw about the colours present in sweets C and D ?
Answer:
(a) Chromatography
(b) DNA fingerprinting
(c) Origin
(d) Sweet C consists of more colours than sweet D.
ii. The speed of colours in sweet C are proportional to one another, while that of colours in D is not.
Explanation:
Chromatography is one of the physical method of separating mixtures. This process composed of the ability of the constituents in a mixture to separate by virtue of rate of movement through a medium, thus separates into constituents.
It can be used to determine the soluble constituents of a given mixture. And for purification purpose.
For element radon, give the chemical symbol, atomic number, and group number.
Gaseous indium dihydride is formed from the elements at elevated temperature:
In(g)+H2(g)⇌InH2(g),Kp=1.48 at 973 K
The partial pressures measured in a reaction vessel are
PIn =0.0540atm
PH2= 0.0250atm
PInH2 =0.0780atm
Calculate Qp and give equal partial pressure for In, H2, and InH2.
Answer:
The reaction given is:
In (g) + H₂ (g) ⇔ InH₂ (g), the Kp is 1.48 at 973 K.
The partial pressures measured in the reaction vessel is Partial pressure of In is 0.0540 atm, partial pressure of H₂ is 0.0250 atm, and the partial pressure of InH₂ is 0.0780 atm. By using the table given in the attachment below, the value of PInH₂ is (0.078-x), PIn is (0.054 + x), and the value of PH2 is (0.025 + x).
Kp = PInH₂/PIn × PH₂ = (0.078 - x) / (0.054 +x) (0.025 + x)
1.48 = (0.078 - x) / (0.054 +x) (0.025 + x)
x = 0.06689
Now the partial pressures of In, H₂ and InH₂ will be,
PH₂ = 0.025 + x = 0.025 + 0.0668 = 0.0918 atm
PIn = 0.054 + 0.0668 = 0.1208 atm
PInH₂ = 0.078 - 0.0668 = 0.0112 atm
Now the Qp or the reaction quotient will be,
Qp = (0.078) / (0.054) (0.025) = 57.78.
Please help, Which molecule is shown below
Answer:
Option B. 3–methylheptane.
Explanation:
To obtain the name of the compound given in the question above, we must
1. Determine the functional group of the compound.
2. Locate the longest continuous carbon chain. This gives the parent name of the compound.
3. Identify the substituent groups attached.
4. Locate the position of the substituent group attached by giving it the lowest possible count.
5. Combine the above to obtain the name.
Now let us name the compound given in the question above.
1. The compound is an alkane since it contains only single bond.
2. The longest continuous carbon chain is 7. Hence the parent name I the compound is heptane.
3. The substituent group attached is
—CH3 i.e methyl.
4. The substituent group attached is at carbon 3.
5. Therefore, the name of the compound is:
3–methylheptane.
The total kinetic energy of a body is known as:
A. Thermal energy
B. Convection
C. Potential energy
D. Temperature
The total kinetic energy of a body is known as Thermal energy. Option A
What is thermal energy?Thermal energy is the direct sum of all the available random kinetic energies of molecules.
Also note that thermal energy is directly proportional to temperature in Kelvin.
Thus, the total kinetic energy of a body is known as Thermal energy. Option A
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Answer:
A.) Thermal energy
Explanation:
I got it correct on founders edtell
The standard free energy change for a reaction can be calculated using the equation ΔG∘′=−nFΔE∘′ ΔG∘′=−nFΔE∘′ where nn is the number of electrons transferred, FF is Faraday's constant, 96.5 kJ·mol−1·V−1, and ΔE∘′ΔE∘′ is the difference in reduction potential. For each of the given reactions, determine the number of electrons transferred (n)(n) and calculate standard free energy (ΔG∘′)(ΔG∘′) . Consider the half-reactions and overall reaction for reaction 1. half-reactions:fumarate 2−+2H+CoQH2↽−−⇀succinate−↽−−⇀CoQ+2H+ half-reactions:fumarate−+2H+↽−−⇀succinate2−CoQH2↽−−⇀CoQ+2H+ overall reaction:fumarate2−+CoQH2↽−−⇀succinate2−+CoQΔE∘′=−0.009 V
Answer:
ΔG°′ = 1.737 KJ/mol
Explanation:
The reaction involves the transfer of two electrons in the form of hydride ions from reduced coenzyme Q, CoQH₂ to fumarae to form succinate and oxidized coenzyme Q, CoQ.
The overall equation of reaction is as follows:
fumarate²⁻ + CoQH₂ ↽⇀ succinate²⁻ + CoQ ; ΔE∘′=−0.009 V
Using the equation for standard free energy change; ΔG°′ = −nFΔE°′
where n = 2; F = 96.5 KJ.V⁻¹.mol⁻¹; ΔE°′ = 0.009 V
ΔG°′ = - 2 * 96.5 KJ.V⁻¹.mol⁻¹ * 0.009 V
ΔG°′ = 1.737 KJ/mol
If the theoretical yield of a reaction is 332.5 g and the percent yield for the reaction is 38 percent, what's the actual yield of product in grams? \
A. 8.74 g
B. 12616 g
C. 116.3 g
D. 126.4 g
Answer: D - 126.4g
Explanation:
% Yield = Actual Yield/Theoretical Yield
38% = Actual Yield/332.5
38/100 = Actual Yield/332.5
(.38)(332.5) = 126.35 g = 126.4 g Actual Yield
Answer:
is D. the correct answer
Explanation:
I'm not sure if it is. Please let me know if I'm mistaking.
The ΔHvap of nitrous oxide is 16.53 kJ · mol−1 and its ΔSvap is 89.51 J · mol−1 · K−1. What it the boiling point of nitrous oxide?
Answer:
[tex]T_b=-88.48\°C[/tex]
Explanation:
Hello,
In this case, since the entropy of vaporization is defined in terms of the enthalpy of vaporization and the boiling point of the given substance, nitrous oxide, as shown below:
[tex]\Delta _{vap}S=\frac{\Delta _{vap}}{T_b}[/tex]
Solving for the boiling point of nitrous oxide, we obtain:
[tex]T_b=\frac{\Delta _{vap}H}{\Delta _{vap}S}=\frac{16.53\frac{kJ}{mol}*\frac{1000J}{1kJ} }{89.51\frac{J}{mol} } \\ \\T_b=184.67K[/tex]
Which in degree Celsius is also:
[tex]Tb=184.67-273.15\\\\T_b=-88.48\°C[/tex]
Best regards.
what is non metal?
help meh
The element which can not loose electron easily and having electronagtive character is called non-metal it has following property-1. it can not conduct heat and electricity1. it is netiher ductile not malleable3. it is not lsuturous and also not sonorous
Answer:
Non-metals are the elements which form negative ions by accepting or gaining electrons. Non-metals usually have 4, 5, 6 or 7 electrons in their outermost shell. Non-metals are those which lack all the metallic attributes. They are good insulators of heat and electricity. They are mostly gases and sometimes liquid.
(9443+45−9.9) (9443+45−9.9) ×8.4× 10 6
For the following reaction, 3.76 grams of iron are mixed with excess oxygen gas . The reaction yields 4.29 grams of iron(II) oxide . iron ( s ) oxygen ( g ) iron(II) oxide ( s ) What is the theoretical yield of iron(II) oxide
Answer:
4.84g of FeO is the theoretical yield
Explanation:
The Iron, Fe(s), reacts with oxygen, O₂(g), producing Iron (II) oxide, as follows:
2Fe(s) + O₂(g) → 2FeO
Theoretical yield is the yield of a reaction in which you assume the 100% of reactants is converted in products.
To find theoretical yield we need to find moles of Iron, and, knowing 2 moles of Fe produce 2 moles of FeO (Ratio 1:1), we can find theoretical yield of FeO as follows:
Moles Fe (Molar mass: 55.845g/mol)
Using the molar mass of the compound we can convert grams to moles, thus:
3.76g Fe × (1mol / 55.845g) = 0.0673 moles of Fe
Moles and mass of FeO
As there are in reaction 0.0673 moles Fe, assuming a theoretical yield (And as ratio of the reaction is 1:1), you will obtain 0.0673 moles of FeO.
Theoretical yield is given in grams, As molar mass of FeO is 71.844g/mol, theoretical yield of the reaction is:
0.0673 moles FeO × (71.844g / mol) =
4.84g of FeO is the theoretical yieldCalculate [OH-] given [H3O+] in each aqueous solution and classify the solution as acidic or basic. [H3O+] = 2.6 x 10-8 M
Answer:
To calculate the [OH-] in the solution we must first find the pOH
That's
pH + pOH = 14
pOH = 14 - pH
First to find the pH we use the formula
pH = - log [H3O+]From the question
[H3O+]= 2.6 × 10^-8 M
pH = - log 2.6 × 10^-8
pH = 7.6
pH = 8
So we pOH is
pOH = 14 - 8 = 6
To find the [OH-] we use the formula
pOH = - log [OH-]6 = - log [OH-]
Find antilog of both sides
[OH-] = 1.0 × 10^-6 MThe solution is slightly basic since it's pH is in the basic region and slightly above the neutral point 7
Hope this helps you
Fireworks are chemical reactions that release energy. Which of these phenomena are caused by chemical reactions that release energy? If you’re not sure, make a guess.
Answer:
All chemical reactions involve energy. Energy is used to break bonds in reactants, and energy is released when new bonds form in products. Endothermic reactions absorb energy, and exothermic reactions release energy. The law of conservation of energy states that matter cannot be created or destroyed.
f a substance has a half-life of 8.10 hr, how many hours will it take for 75.0 g of the substance to be depleted to 3.90 g?
Answer:
35 hrs
Explanation:
half life of the substance [tex]t_{1/2 }[/tex] = 8.1 hr
initial amount [tex]N_{0}[/tex] = 75 g
The final amount [tex]N[/tex] = 3.9 g
The time elapsed [tex]t[/tex] = ?
we use the relationship
[tex]N[/tex] = [tex]N_{0}[/tex] [tex](\frac{1}{2} )^{\frac{t}{t_{1/2} } }[/tex]
substituting values, we have
3.9 = 75 x [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
0.052 = [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
take the log of both side
log 0.052 = log [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
log 0.052 = [tex]\frac{t}{8.1}[/tex] log 1/2
-1.284 = [tex]\frac{t}{8.1}[/tex] x -0.301
1.284 = 0.301t/8.1 =
1.284 = 0.0372t
t = 1.284/0.037 = 34.5 ≅ 35 hrs
Ammonia, methane, and phosphorus trihydride are three different compounds with three different boiling points. Rank their boiling points in order from lowest to highest.
A. CH4< NH3 < PH3
B. NH3 < PH3< CH4
C. CH4 < PH3 < NH3
D. NH3 < CH4< PH3
E. PH3< NH3 < CH4
Answer:
B. NH3 < PH3< CH4
Explanation:
Hello,
In this case, taking into account that the boiling point of ammonia, methane and phosphorous trihydrate are -33.34 °C , -161.5 °C and -87.7 °C , clearly, methane has the lowest boiling point (most negative) and ammonia the greatest boiling point (least negative), therefore, ranking is:
B. NH3 < PH3< CH4
Best regards.
The Lewis structure of N2H2 shows ________. Group of answer choices a nitrogen-nitrogen single bond each hydrogen has one nonbonding electron pair each nitrogen has one nonbonding electron pair each nitrogen has two nonbonding electron pairs a nitrogen-nitrogen triple bond
Answer:
one bond between nitrogen and hydrogen and a double bond between the nitrogen atoms.
Explanation:
H-N=N-H
When titrating a strong acid with a strong base, after the equivalence point is reached, the pH will be determined exclusively by: Select the correct answer below:
A) hydronium concentration
B) hydroxide concentration
C) conjugate base concentration
D) conjugate acid concentration
Answer:
B) hydroxide concentration
Explanation:
Hello,
In this case, since we are talking about strong both base and acid, since the base is the titrant and the acid the analyte, once the equivalence point has been reached, some additional base could be added before the experimenter realizes about it, therefore, since the titrant is a strong base, it completely dissociates in hydroxide ions and metallic ions which allows us to compute the pOH of the solution by known the hydroxide ions concentration.
After that, due to the fact that the pH is related with the pOH as shown below:
pH=14-pOH
We can directly compute the pH.
Best regards.
Which of the examples is potassium?
es )
A)
B)
B
C)
Answer:
examples of things which contain potassium are:
green vegetables
root vegetables
fruits
potassium chloride
potassium sulphate
Explanation:
if you need a specific answer please send the options
Answer:
C
Explanation:
The answer is the one with 20 protons, 20 neutrons, and 6-8-8-2 electrons.
What creation would you make if you had access to any of the chemical elements? can someone answer this for me please.
Answer:
Depends on the chemicals.
Explanation:
The creation of something depends on the chemical we have. If I have chemicals such as acid and base so I can produce salt and water by mixing acid and base. If I have ethanol, vegetable oil and sodium hydroxide which is a catalyst, I can produce biodiesel which can be used in vehicles instead of fossil fuel. If I have sodium element and chlorine gas, I can produce sodium chloride also known as table salt.
A student completed the experiment but found that the total amount of material recovered weighed more than the original sample. What is the most likely source of error and how may it be corrected?
Answer:
This is due to the water moisture present in the recovered sample.
Explanation:
The total amount of material recovered isn’t meant to weigh more than the original sample. However when this happens then it means there is the presence of water moisture in the recovered sample.
The recovered samples however needs to be heated to make it dry and eliminate the water moisture through evaporation.
Methyl iodide reacts irreversibly with azide ion with rate = k[CH3I][N3–]. CH3I(aq) + N3–(aq) → CH3N3(aq) + I–(aq) The reaction is carried out with an initial concentration of CH3I of 0.01 M. Which statement about the reaction is correct?
Answer:
(D) The reaction cannot take place in a single elementary step
Explanation:
Statements are:
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I].
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution.
(D) The reaction cannot take place in a single elementary step.
The rate of the reaction is:
rate = k[CH3I][N3–].
That means rate depends of concentration of CH₃I as much as N₃⁻ concentration
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I]. FALSE. The reaction rate depends of N₃⁻ as much as CH₃I
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M. FALSE. Reaction is second-order. Half-life is 1/K[A]₀. If initial concentration is 0.1M, to a concentration of 0.005M it takes:
1/K*0.1. If initial concentration is 0.005M it takes 1/K*0.005. That means it takes half to decrease from 0.005M to 0.0025 as it does for it to decrease from 0.01M to 0.005M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution. FALSE. Reaction rate is independent of I⁻
(D) The reaction cannot take place in a single elementary step. TRUE. As this reaction is a single-replacement reaction implies the formation of 1 C-N bond. But also the rupture of the C-I bond is impossible to explain this kind of reaction in a single elementary step.
