20. What volume of 0.350M KMnO4 solution must be diluted to prepare 600. mL of
0.150M KMnO4 solution?​

Answers

Answer 1

Answer:

25.7 mL

Explanation:

Step 1: Given data

Initial volume (V₁): ?Initial concentration (C₁): 0.350 MFinal volume (V₂): 600 mLFinal concentration (C₂): 0.150 M

Step 2: Calculate the volume of the initial solution

We have a concentrated solution and we want to prepare a diluted one. We can calculate the initial volume using the dilution rule.

C₁ × V₁ = C₂ × V₂

V₁ = C₂ × V₂ / C₁

V₁ = 0.150 M × 600 mL / 0.350 M

V₁ = 25.7 mL


Related Questions

Calculate the energy required to heat 566.0mg of graphite from 5.2°C to 23.2°C. Assume the specific heat capacity of graphite under these conditions is ·0.710J·g−1K−1 . Be sure your answer has the correct number of significant digits.

Answers

Answer:

7.23 J

Explanation:

Step 1: Given data

Mass of graphite (m): 566.0 mgInitial temperature: 5.2 °CFinal temperature: 23.2 °CSpecific heat capacity of graphite (c): 0.710J·g⁻¹K⁻¹

Step 2: Calculate the energy required (Q)

We will use the following expression.

Q = c × m × ΔT

Q = 0.710J·g⁻¹K⁻¹ × 0.5660 g × (23.2°C-5.2°C)

Q = 7.23 J

Cesium-137 is part of the nuclear waste produced by uranium-235 fission. The half-life of cesium-137 is 30.2 years. How much time is required for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value?

Answers

Answer:

There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value

Explanation:

The radioactive decay follows always first-order kinetics where its general law is:

Ln[A] = -Kt + ln[A]₀

Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.

We can find rate constant from half-life as follows:

Rate constant:

t(1/2) = ln 2 / K

As half-life of Cesium-137 is 30.2 years:

30.2 years = ln 2 / K

K = 0.02295 years⁻¹

Replacing this result and with the given data of the problem:

Ln[A] = -Kt + ln[A]₀

Ln[A] = -0.02295 years⁻¹* t + ln[A]₀

Ln ([A] / [A₀]) = -0.02295 years⁻¹* t

As you want time when [A] is 20% of [A]₀, [A] / [A]₀ = 0.2:

Ln (0.2) = -0.02295 years⁻¹* t

70.1 years = t

There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value

1. Explain what the police siren sounds like to Jane:
2. Explain what the police siren sounds like to John:
3. Explain why the police siren sounds different between Jane and John:

Answers

Answer:

1. the siren has a lower pitch to Jane

2. the siren has a higher pitch to John

3. sound different due to moving away from Jane making the sound wave lengths longer and moving toward John making the wave lengths shorter

Explanation:

The Doppler effect expresses that sound is comparative with the spectator or observer. This is demonstrated valid by the model given with Jane and John. To one individual it could sound low and to someone else it could sound high, in light of where they are tuning in from. To John, the police alarm playing is a higher pitch. Be that as it may, to Jane this equivalent alarm is a totally extraordinary pitch and is heard lower than in comparison to the john.

This is a prime case of the Doppler Effect. They sound distinctive on the grounds that the sound is moving far from Jane making the sound frequencies longer and it is advancing toward John making the frequencies shorter. This impacts how the sound is heard by the human ear.

A sample is found to contain 1.29×10-11 g of salt. Express this quantity in picograms

Answers

Answer:12.9e-12g or in short 12.9pg

Explanation:as p=1e-12

The argon atoms are excited into an excited state before emitting the 488.0 nm laser. It is known that the energy of the first ionization energy of argon is 1520 kJ mol-1. What is the energy level of the excited state (in unit eV) lies below the vacuum energy level (0 eV)

Answers

Answer:

Explanation:

Given that:

The argon atoms are excited into an excited state before emitting the 488.0 nm laser.

the energy of the first ionization energy of argon is 1520 kJ mol-1.

SInce 1 eV = 96.49 kJ/mol

Therefore, the energy of the first ionization energy of argon in eV is = ( 1520/ 96.49) eV

=  15.75 eV

To find where  the energy level of the excited state lies below the vacuum energy level, let's first determine, the energy liberated by using planck expression.

[tex]E = \dfrac{hc}{\lambda}[/tex]

[tex]E = \dfrac{6.6 \times 10^{-34} \times 3 \times 10^8}{488 \times 10^{-9}}[/tex]

[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]

[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]

[tex]E =4.057 \times 10^{-19} \ J[/tex]

Converting Joules (J) to eV ; we get,

[tex]E =\dfrac{4.057 \times 10^{-19}}{1.6 \times 10^{-19}}[/tex]

E = 2.53 eV

The energy levels of the first exited state = -13.223 eV

When equation for neutralization of HBr by Ca(OH)2 is correctly balanced, how many molecules of water will be formed

Answers

Answer:

When equation for neutralization of HBr by Ca(OH)₂ is correctly balanced, 1.2046*10²⁴ molecules of water will be formed

Explanation:

A neutralization reaction is one in which an acid (or acidic oxide) reacts with a base (or basic oxide). In the reaction a salt is formed and in most cases water is formed. A Salt is an ionic compound formed by the union of ions and cations through ionic bonds.

In the reactions of a strong acid (those substances that completely dissociate) with a strong base (they dissociate completely, giving up all their OH-), the complete neutralization of the species is carried out:

2 HBr (aq) + Ca(OH)₂ (s) → CaBr₂ (aq) + 2 H₂O (l)

The reaction is already balanced, complying with the law of conservation of matter. This law states that since no atom can be created or destroyed in a chemical reaction, the number of atoms that are present in the reactants must be equal to the number of atoms present in the products.

By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), 2 moles of water H₂O are formed.

On the other hand, Avogadro's Number or Avogadro's Constant is called the number of particles that make up a substance (usually atoms or molecules) and that can be found in the amount of one mole of said substance. Its value is 6.023 * 10²³ particles per mole. Avogadro's number applies to any substance.

Then you can apply the following rule of three: if 1 mole of H₂O contains 6.023*10²³ molecules, 2 moles of H₂O, how many molecules does it contain?

[tex]amount of molecules=\frac{2moles*6.023*10^{23}molecules }{1 mole}[/tex]

amount of molecules= 1.2046*10²⁴ molecules

When equation for neutralization of HBr by Ca(OH)₂ is correctly balanced, 1.2046*10²⁴ molecules of water will be formed

Complete the following equation of nuclear transmutation.
23892U + 126C → 24498Cf + 6 ______
Complete the following equation of nuclear transmutation.
U + C → Cf + 6 ______
A) 1n
B) 0 e
C) 0 e
D) 1H
E) 0g 0 -1 +1 1 0

Answers

Answer:

Option A. 1 0n

Explanation:

Details on how to balanced the equation for the reaction given in the question above can be found in the attached photo.

The missing part of the transmutation equation as it has been shown is 1/o n. Option A

What is nuclear transmutation?

Nuclear transmutation is the process of shifting the number of protons in an atom's nucleus to change one element into another. Nuclear processes that change one atomic nucleus into another with a different atomic number are involved.

The production of nuclear energy, radioactive decay, and the creation of new isotopes for use in science and industry all depend on nuclear transmutation, a fundamental idea in nuclear physics.

We have the equation as;

238/92 U + 12/6 C  ----> 244/98 Cf + 6 1/0 n

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What is the mole fraction of urea, CO(NH2)2, in a solution prepared by dissolving 4.0 g of urea in 32.0 g of methanol, CH3OH

Answers

Answer:

0.0630

Explanation:

The molar mass of urea = 60 g/mol

we all know that:

[tex]\mathtt{number \ of \ moles = \dfrac{mass }{molar \ mass}}[/tex]

Then; the number of moles of urea

= [tex]\mathtt{\dfrac{4.0 \ g}{60 \ g/mol}}[/tex]

= 0.0667 mol

Similarly; the number of moles of methanol

= [tex]\mathtt{\dfrac{32 \ g}{32.04 \ g/mol}}[/tex]

= 0.9988 mol

The total number of moles = (0.0667 + 0.9988) mol

= 1.0655 mol

Finally,the mole fraction of urea  [tex]\mathtt{(X_{urea})}[/tex] = [tex]\mathtt{\dfrac{ n_{urea}}{(n_{urea}+n_{methanol})}}[/tex]

[tex]\mathtt{(X_{urea})}[/tex] = [tex]\mathtt{\dfrac{0.0667 \ mole}{1.0655 \ mole}}[/tex]

= 0.0630

If 2.9g of water is heated from 23.9C to 98.9C, how much heat (in calories) was added to the water?

Answers

Answer:

Explanation:

we know that

ΔH=m C ΔT

where ΔH is the change in enthalpy (j)

m is the mass of the given substance which is water in this case

ΔT IS the change in temperature and c is the specific heat constant  

we know that given mass=2.9 g

ΔT=T2-T1 =98.9 °C-23.9°C=75°C

specific heat constant for water is 4.18 j/g°C

therefore ΔH=2.9 g*4.18 j/g°C*75°C

ΔH=909.15 j

A balloon has an initial volume of 2.954 L containing 5.50 moles of helium. More helium is added so that the balloon expands to 4.325 L. How much helium (moles) has been added if the temperature and pressure stay constant during this process.

Answers

Answer:

8.05 moles

Explanation:

5.50 / 2.954 = x / 4.325

x = 8.05

According to ideal gas equation, if the temperature and pressure stay constant during the process 0.520 moles have been added  so that the balloon expands to 4.325 L.

What is ideal gas equation?

The ideal gas equation is a equation which is applicable in a hypothetical state of an ideal gas.It is a combination of Boyle's law, Charle's law,Avogadro's law and Gay-Lussac's law . It is given as, PV=nRT where R= gas constant whose value is 8.314.The law has several limitations.The law was proposed by Benoit Paul Emile Clapeyron in 1834.

In the given example if pressure and temperature are constant then V=nR substituting V=4.325 l and R=8.314  so n=V/R=4.325/8.314=0.520 moles.

Thus, 0.520 moles of helium are added if the temperature and pressure stay constant during this process.

Learn more about ideal gas equation,here:

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Using the data: C2H4(g), = +51.9 kJ mol-1, S° = 219.8 J mol-1 K-1 CO2(g), = ‑394 kJ mol-1, S° = 213.6 J mol-1 K-1 H2O(l), = ‑286.0 kJ mol-1, S° = 69.96 J mol-1 K-1 O2(g), = 0.00 kJ mol-1, S° = 205 J mol-1 K-1 calculate the maximum amount of work that can be obtained, at 25.0 °C, from the process: C2H4(g) + 3 O2(g) → 2 CO2(g) + 2 H2O(l)

Answers

Answer:

The correct answer is 1332 KJ.

Explanation:

Based on the given information,  

ΔH°f of C2H4 is 51.9 KJ/mol, ΔH°O2 is 0.0 KJ/mol, ΔH°f of CO2 is -394 KJ/mol, and ΔH°f of H2O is -286 KJ/mol.  

Now the balanced equation is:  

C2H4 (g) + 3O2 (g) ⇔ 2CO2 (g) + 2H2O (l)

ΔH°rxn = 2 × ΔH°f CO2 + 2 × ΔH°fH2O - 1 × ΔH°fC2H4 - 3×ΔH°fO2

ΔH°rxn = 2 (-394) + 2(-286) - 1(51.9) - 3(0)

ΔH°rxn = -1411.9 KJ

Now, the given ΔS°f of C2H4 is 219.8 J/mol.K, ΔS°f of O2 is 205 J/mol.K, ΔS°f of CO2 is 213.6 J/mol.K, and ΔS°f of H2O is 69.96 J/mol.K.  

Now based on the balanced chemical reaction,  

ΔS°rxn = 2 × ΔS°fCO2 + 2 ΔS°fH2O - 1 × ΔS°f C2H4 - 3 ΔS°fO2

ΔS°rxn = 2 (213.6) + 2(69.96) - 1(219.8) -3(205)

ΔS°rxn = -267.68 J/K or -0.26768 KJ/K

T = 25 °C or 298 K

Now putting the values of ΔH, ΔS and T in the equation ΔG = ΔH-TΔS, we get

ΔG = -1411.9 - 298.0 × (-0.2677)

ΔG = -1332 KJ.  

Thus, the maximum work, which can obtained is 1332 kJ.  

Human blood typically contains 1.04 kg/L of platelets. A 1.89 pints of blood would contain what mass (in grams) of platelets

Answers

A 1.89 pints of blood would contain 873 grams of platelets.

To calculate the amount of platelets present in 1.89 pints, it is first necessary to transform this unit of volume into liters:

1 pint = 473.2 mL

                                  [tex]1.89 \times 473.2 = 894.3 mL[/tex]

1000 L = 1mL

         

                                         [tex]\frac{894.3}{1000}= 0.84L[/tex]

Now, just calculate the amount of platelets present in 0.84L:

                                    [tex]\frac{1.04\times10^{3}g}{xg}=\frac{1L}{0.84L}[/tex]

                               

                                       x = 873 grams

So, a 1.89 pints of blood would contain 873 grams of platelets.

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How are animals used in vaccine development?

Answers

Answer:

Animals whose certain organs closely match those of humans or have similar genetic makeup are used in vaccine tests because the results can closely resemble those same results on humans.

Explanation:

Answer:

they use them to test the effectiveness of the vaccine.

Explanation:

A monoprotic weak acid, HA , dissociates in water according to the reaction HA(aq)+H2O(l)↽−−⇀H3O+(aq)+A−(aq) The equilibrium concentrations of the reactants and products are [HA]=0.260 M , [H3O+]=4.00×10−4 M , and [A−]=4.00×10−4 M . Calculate the Ka value for the acid HA.

Answers

Answer:

Ka = 6.15x10⁻⁷

Explanation:

Ka is defined as dissociation constant in the equilibrium of a weak acid with water. The general reaction is:

HA(aq) + H₂O(l) ⇆ H₃O⁺(aq) + A⁻(aq)

And Ka is defined as the ratio between molar concentrations in equilibrium of products over reactants as follows:

Ka = [H₃O⁺] [A⁻] / [HA]

You don't take water in the equilibrium beacuse is a pure liquid

Replacing with the concentrations of the problem:

Ka = [H₃O⁺] [A⁻] / [HA]

Ka = [4.00x10⁻⁴] [4.00x10⁻⁴] / [0.260]

Ka = 6.15x10⁻⁷

Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na 2CrO 4 are added to 250 mL of 0.12 M AgNO 3? [K sp(Ag 2CrO 4) = 1.1 × 10 –12] What is the concentration of the silver ion remaining in solution?

Answers

Answer:

A precipitate will form.

[Ag⁺] = 2.8x10⁻⁵M

Explanation:

When Ag⁺ and CrO₄²⁻ are in solution, Ag₂CrO₄(s) is produced thus:

Ag₂CrO₄(s) ⇄ 2 Ag⁺(aq) + CrO₄²⁻(aq)

Ksp is defined as:

Ksp = 1.1x10⁻¹² = [Ag⁺]² [CrO₄²⁻]

Where the concentrations [] are in equilibrium

Reaction quotient, Q, is defined as:

Q = [Ag⁺]² [CrO₄²⁻]

Where the concentrations [] are the actual concentrations

If Q < Ksp, no precipitate will form, if Q >= Ksp, a precipitate will form,

The actual concentrations are -Where 500mL is the total volume of the solution-:

[Ag⁺] = [AgNO₃] = 0.12M ₓ (250mL / 500mL) = 0.06M

[CrO₄²⁻] = [Na₂CrO₄] = 0.33M × (250mL / 500mL) = 0.165M

And Q = [0.06M]² [0.165M] = 5.94x10⁻⁴

As Q > Ksp; a precipitate will form

In equilibrium, some Ag⁺ and some CrO₄⁻ reacts decreasing its concentration until the system reaches equilibrium. Equilibrium concentrations will be:

[Ag⁺] = 0.06M - 2X

[CrO₄²⁻] = 0.165M - X

Where X is defined as the reaction coordinate

Replacing in Ksp expression:

1.1x10⁻¹² = [0.06M - 2X]² [0.165M - X]

Solving for X:

X = 0.165M → False solution. Produce negative concentrations.

X = 0.0299986M

Replacing, equilibrium concentrations are:

[Ag⁺] = 0.06M - 2(0.0299986M)

[CrO₄²⁻] = 0.165M - 0.0299986M

[Ag⁺] = 2.8x10⁻⁵M

[CrO₄²⁻] = 0.135M

2) What is the concentration (M) of CH3OH in a solution prepared by dissolving 11.7 g of CH3OH in sufficient water to give exactly 230 mL of solution?

Answers

Molarity is in units of moles/L. So you must determine the moles of CH3OH, then divide by the total volume.

To determine the moles of CH3OH, divide the weight in grams of CH3OH by the molecular weight

11.7g / 32g/mol = 0.366 mol CH3OH

0.366 mol CH3OH / .230 L = your molarity

Using only sodium carbonate, Na2CO3, sodium bicarbonate, NaHCO3, and distilled water determine how you could prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3. The total molarity of the ions should be 0.20 M. The Ka of the hydrogen carbonate ion, HCO3 - , is 4.7 x 10-11 .

Answers

Answer:

Weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.

Explanation:

The pH of a buffered solution can be calculated using the Henderson-Hasselbalch equation:

[tex] pH = pKa + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]  

We have that pH = 10.3 and the Ka is 4.7x10⁻¹¹, so:

[tex] 10.3 = -log(4.7 \cdot 10^{-11}) + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]  

[tex] \frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex]  (1)

Also, we know that:

[tex] [Na_{2}CO_{3}] + [NaHCO_{3}] = 0.20 M [/tex]    (2)

From equation (2) we have:

[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] [/tex]   (3)

By entering (3) into (1):

[tex] \frac{0.20 - [NaHCO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex]

[tex] 0.94*[NaHCO_{3}] + [NaHCO_{3}] = 0.20 [/tex]

[tex] [NaHCO_{3}] = 0.103 M [/tex]  

Hence, the [Na_{2}CO_{3}] is:

[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] = 0.20 M - 0.103 M = 0.097 M [/tex]  

Now, having the concentrations and knowing the volume of the buffer solution we can find the mass of the sodium carbonate and the sodium bicarbonate, as follows:

[tex]m_{Na_{2}CO_{3}} = C*V*M = 0.097 mol/L*0.050 L*105.99 g/mol = 0.5141 g[/tex]

[tex]m_{NaHCO_{3}} = C*V*M = 0.103 mol/L*0.050 L*84.007 g/mol = 0.4326 g[/tex]

Therefore, to prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3 we need to weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.      

   

I hope it helps you!

The second-order decomposition of NO2 has a rate constant of 0.255 M-1s-1. How much NO2 decomposes in 8.00 s if the initial concentration of NO2 (1.00 L volume) is 1.33 M

Answers

Answer:

0.9718M

Explanation:

Rate constant, k =  0.255 M-1s-1

time, t = 8.00 s

Initial concentration, [A]o = 1.33 M

Final concentration, [A] = ?

These quantities are represented by the equation;

1 / [A] = 1 / [A]o + kt

1 / [A] = 1 /1.33 + (0.255 * 8)

1 / [A] = 0.7519 + 2.04

[A] = 1 / 2.7919 = 0.3582 M

How much of NO2 decomposed is obtained from the change in concentration;

Change in concentration = Initial - Final

Change = 1.33 - 0.3582 = 0.9718M

A sailor on a trans-Pacific solo voyage notices one day that if he puts 735.mL of fresh water into a plastic cup weighing 25.0g, the cup floats in the seawater around his boat with the fresh water inside the cup at exactly the same level as the seawater outside the cup (see sketch at right).

Calculate the amount of salt dissolved in each liter of seawater. Be sure your answer has a unit symbol, if needed, and round it to 2 significant digits.

You'll need to know that the density of fresh water at the temperature of the sea around the sailor is 0.999/gcm3. You'll also want to remember Archimedes' Principle, that objects float when they displace a mass of water equal to their own mass.

Answers

Answer:

Amount of salt in 1 L seawater = 34 g

Explanation:

According to Archimedes' principle, mass of freshwater and cup = mass of equal volume of seawater

mass of freshwater = density * volume

1 cm³ = 1 mL

mass of freshwater = 0.999 g/cm³ * 735 cm³ = 734.265 g

mass of freshwater + cup = 734.265 + 25 = 759.265 g

Therefore,  mass of equal volume of seawater = 759.265 g

Volume of seawater displaced = 735 mL = 0.735 L (assuming the cup volume is negligible)

1 liter = 1000 cm³ = 1000 mL;

Density of seawater = mass / volume

Density of seawater = 759.265 g / 0.735 L = 1033.01 g/L

Density of freshwater in g/L = 0.999 g/ (1/1000) L = 999 g/L

mass of 1 Liter seawater = 1033.01 g

mass of 1 Liter freshwater = 999 g

mass of salt dissolved in 1 L of seawater = 1033.01 g - 999 g = 34.01 g

Therefore, amount of salt in 1 L seawater = 34 g

An aqueous solution of potassium bromide, KBr, contains 4.34 grams of potassium bromide and 17.4 grams of water. The percentage by mass of potassium bromide in the solution is 20 %.

Answers

Answer:

True

Explanation:

The percentage by mass of a substance in a solution can be calculated by dividing the mass of the substance dissolved in the solution by the total mass of the solution. This can be expressed mathematically as:

Percentage by mass = mass of substance in solution/mass of solution x 100

In this case;

mass of KBr = 4.34 grams

mass of water = 17.4 grams

mass of solution = mass of KBr + mass of water = 4.34 + 17.4 = 21.74

Percentage by mass of KBr = 4.34/21.74 x 100

                                              = 19.96 %

19.96 is approximately 20%.

Hence, the statement is true.

A 25.00 mL sample of unknown concentration of HNO3 solution requires 22.62 mL of 0.02000 M NaOH to reach the equivalence point. What is the concentration of the unknown HNO3 solution

Answers

Answer:The concentration of the unknown HNO3 solution = 0.01809 M

Explanation:

For the acid-base reaction,  HNO3 + NaOH-----> NaN03 + H20

we have that

C1 V1 = C2 V2

Where ,

C1 = concentration of HNO3=?

V1 = volume of HNO3 = 25.00 mL,

V2 = volume of NaOH = 22.62 mL,  

C2 = concentration of NaOH = 0.02000 M

Therefore ,

25.00 mL x C1 = 22.62 mL x 0.02000 M    

 = (22.62 mL / 25.00 mL) x 0.02000 M = 0.01809 M

The concentration of the unknown HNO3 solution = 0.01809 M

When 2 moles of NH3(g) react with N2O(g) to form N2(g) and H2O(g) according to the following equation, 880 kJ of energy are evolved. 2NH3(g) 3N2O(g)4N2(g) 3H2O(g) Is this reaction endothermic or exothermic

Answers

Answer:

Explanation:

This is a bit of a trick question.

Usually an exothermic reaction is written as

A + B - heat = C + D

The meaning of this equation is that when the bonds of the reactants break, heat has to be given away to the environment. On the left, exothermic means that heat has to be given.

The wording on this question means that heat is a product

A + B = C + D + heat.

In other words heat is given up to the environment. So this reaction is exothermic.

Compound A is an alkene that was treated with ozone to yield only (CH3CH2CH2)2C=O. Draw the major product that is expected when compound A is treated with a peroxy acid (RCO3H) followed by aqueous acid (H3O+).

Answers

Answer:

2,2,3,3-tetrapropyloxirane

Explanation:

In this case, we have to know first the alkene that will react with the peroxyacid. So:

What do we know about the unknown alkene?

We know the product of the ozonolysis reaction (see figure 1). This reaction is an oxidative rupture reaction. Therefore, the double bond will be broken and we have to replace the carbons on each side of the double bond by oxygens. If [tex](CH_3CH_2CH_2)_2C=O[/tex] is the only product we will have a symmetric molecule in this case 4,5-dipropyloct-4-ene.

What is the product with the peroxyacid?

This compound in the presence of alkenes will produce peroxides. Therefore we have to put a peroxide group in the carbons where the double bond was placed. So, we will have as product 2,2,3,3-tetrapropyloxirane. (see figure 2)

A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
Br(g)
Cl2(g)
I2(g)
F2(g)
B. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2S(g)
H2O(g)
H2O2(g)
C. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous)
C(s, diamond)
C(s, graphite)

Answers

Answer:

A. Rank the following substances in order of decreasing standard molar entropy (S∘).

Rank the gases from largest to smallest standard molar entropy

I2(g)>Br2(g)>Cl2(g)>F2(g)

B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

H2O2(g)>H2S(g) >H2O(g)

C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

C(s, amorphous) >C(s, graphite)>C(s, diamond)

Explanation:

Hello,

In this case, we can apply the following principles to explain the order:

- The greater the molar mass, the larger the standard molar entropy.

- The greater the molar mass and the structural complexity, the larger the standard molar entropy.

- The greater the structural complexity, the larger the standard molar entropy.

A. Rank the following substances in order of decreasing standard molar entropy (S∘).

Rank the gases from largest to smallest standard molar entropy

I2(g)>Br2(g)>Cl2(g)>F2(g)

This is due to the fact that the greater the molar mass, the larger the standard molar entropy.

B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

H2O2(g)>H2S(g) >H2O(g)

This is due to the fact that the greater the molar mass and the structural complexity, the larger the standard molar entropy as the hydrogen peroxide has four bonds and weights 34 g/mol as well as hydrogen sulfide that has two bonds only.

C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

C(s, amorphous) >C(s, graphite)>C(s, diamond)

Since the molecular complexity is greater in the amorphous carbon (messy arrangement), mid in the graphite and lower in the diamond (well organized).

Regards.

The literature value for the Ksp of Ca(OH)2 at 25 °C is 4.68E−6. Imagine you ran the experiment and got a calculated value for Ksp which was too high. Select all of the possible circumstances which would cause this result.

A. The HCl was more concentrated than the labeled molarity (0.0500 M).

B. The Ca[OH]2 solution may have been supersaturated.

C. The HCl was less concentrated than the labeled molarity (0.0500 M).

D. The Ca[OH]2 solution may have been unsaturated.

E. The titration flask may have not been clean and had a residue of a basic solution.

F. The titration flask may have not been clean and had a residue of an acidic solution.

Answers

Answer:

D. The Ca[OH]2 solution may have been unsaturated

Explanation:

The solubility product constant Ksp of any given chemical compound is a term used to describe the equilibrium between a solid and the ions it contains solution. The value of the Ksp indicates the extent to which any compound can dissociate into ions in water. A higher the Ksp, implies more greater solubility of the compound in water.

If the Ksp is more than the value in literature, this false value must have arisen from the fact that the solution was unsaturated hence it appears to be more soluble than it should normally be when saturated.

Write the equation for the reaction described: A solid metal oxide, , and hydrogen are the products of the reaction between metal and steam. (Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)

Answers

Answer:

Pb + 2H2O --> PbO2 + 2H2

Explanation:

Products:

Solid metal; PbO2

Hydrogen; H

Reactants:

Metal; Pb

Steam; H2O

Reactants --> Products

Pb + H2O --> PbO2 + H2

Upon balancing we have;

Pb + 2H2O --> PbO2 + 2H2

What would be the voltage (Ecell) of a voltaic cell comprised of Cd(s)/Cd2+(aq) and Zr(s)/Zr4+(aq) if the concentrations of the ions in solution were [Cd2+] = 0.5 M and [Zr4+] = 0.5 M at 298K?

Answers

Answer:

1.05 V

Explanation:

Since;

E°cell= E°cathode- E°anode

E°cathode= -0.40 V

E°anode= -1.45 V

E°cell= -0.40-(-1.45) = 1.05 V

Equation of the process;

2Zr(s) + 4Cd^2+(aq) ---->2Zr^4+(aq) + 4Cd(s)

n= 8 electrons transferred

From Nernst's equation;

Ecell = E°cell - 0.0592/n log Q

Ecell= E°cell - 0.0592/8 log [0.5]/[0.5]

Since log 1=0

Ecell= E°cell= 1.05 V

Acetonitrile (CH3CN) is an important industrial chemical. Among other things, it is used to make plastic moldings, which have multiple uses, from car parts to Lego bricks. Which one of the following statements about acetonitrile is not correct?a. Acetonitrile has 16 valence electrons in its Lewis structure. b. Acetonitrile has one triple bond. c. Acetonitrile has one pair of nonbonding electrons. d. All atoms satisfy the octet rule in acetonitrile. e. One carbon atom and the nitrogen atom have nonzero formal charges.

Answers

Answer:

One carbon atom and the nitrogen atom have nonzero formal charges.

Explanation:

The compound Acetonitrile has sixteen valence electrons as is easily San from its structure. It contains a carbon nitrogen triple bond with a lone pair of electrons on nitrogen. All atoms satisfy the octet rule and there is no hyper valent atom in the molecule.

The formal charge an carbon and nitrogen is calculated as follows;

No. of valence electron on atom - [non bonded electrons + no. of bonds]

Therefore, for carbon and nitrogen, we have;

formal charge on carbon = 4 - (0 + 4) = 0

formal charge on nitrogen = 5 - (2 + 3) = 0

Hence carbon and nitrogen both possess zero formal charges.

Consider the compound hydrazine N2H4 (MW = 32.0 amu). It can react with I2 (MW = 253.8 amu) by the following reaction 2 I2 + N2H4 ------------- 4 HI + N2 (a) How many grams of I2 are needed to react with 36.7 g of N2H4? (b) How many grams of HI (MW = 127.9 amu) are produced from the reaction of 115.7 g of N2H4 with excess iodine?

Answers

Answer:Cobb

Explanation:What y'all

Which of the following chemical equations corresponds to the standard molar enthalpy of formation of Na_2CO_3(s)?
a. 2 NA(s) + C(s) + 3 O(g) ------------> Na_2CO_3(s)
b. Na_2O(s) + CO_2(g) --------------->Na_2CO_3 (s)
c. Na_2(s) + C(s) + 3 O(g) -------------> Na_2CO_3 (s)
d. Na_2O(s) + CO(g) ---------------> Na_2CO_3(s)
e. 2 Na(s)+ C(s) + 3/2 O_2(g) ------------> Na_2CO_3(s)

Answers

Answer:

2 Na(s) + C(s) + 3/2 O₂(g) → Na₂CO₃(s)

Explanation:

The molar enthalpy of formation of a chemical is defined as the change in enthalpy during the formation of 1 mole of the substance from its constituent elements (Constituent elements are pure elements you have in the periodic table)

For Na₂CO₃ constituent elements are Na(s), C(s) and O₂(g) and the chemical equation that represents the molar enthalpy is:

2 Na(s) + C(s) + 3/2 O₂(g) → Na₂CO₃(s)
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