The formula that would be used to determine the change in entropy for the equation 2 based on the tabulated values of standard molar entropies of the reactants and products is:ΔS° = ΣS°(products) - ΣS°(reactants)
What are standard molar entropies?
Standard molar entropy refers to the amount of entropy in one mole of a pure substance under standard conditions (298 K and 1 atm). The standard state is defined as the stable state of the substance under the given temperature and pressure conditions, as well as a specified number of molecules or moles.
The formula that would be used to determine the change in entropy for the equation 2 based on the tabulated values of standard molar entropies of the reactants and products is:ΔS° = ΣS°(products) - ΣS°(reactants)Where,ΔS° is the change in entropyΣS°(products) is the sum of the standard molar entropies of the products.ΣS°(reactants) is the sum of the standard molar entropies of the reactants.
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part 2 out of 2 now consider the stereochemistry in the reaction below: h5mech801 select the answer choice below that correctly picks the appropriate hydrogen to remove in this reaction as well as the correct reasoning for this choice. ha is removed because it is anti-periplanar to the leaving group cl hb is removed because it is syn-periplanar to the leaving group cl it doesn't matter whether ha or hb is removed as both will lead to the specified product. hb is removed because it is anti-periplanar to the leaving group cl ha is removed because it is syn-periplanar to the leaving group cl
The correct answer for appropriate hydrogen to remove in this reaction is hb, and it is because it is anti-periplanar to the leaving group Cl.
Explanation: During the reaction, the appropriate hydrogen to remove is hb, and it is because it is anti-periplanar to the leaving group Cl.
When hb is removed, the resulting intermediate has no syn-periplanar hydrogen, and so the reaction stops with a double bond between the two carbons to which the leaving group and the hb were attached.
The term periplanar means that all the groups around a given carbon atom lie in the same plane. For instance, in the given reaction, ha is anti-periplanar to the leaving group Cl.
It means that ha and Cl are on opposite sides of the molecule. On the other hand, hb is anti-periplanar to the leaving group Cl because hb and Clare on the opposite sides of the molecule.
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Give the electron geometry (eg), molecular geometry (mg), and hybridization for NH 3. a. eg = tetrahedral, mg = trigonal pyramidal, sp3 b. eg = trigonal pyramidal, mg = trigonal pyramidal, sp3 c. eg - trigonal planar, mg = trigonal planar, sp2 d. eg - trigonal pyramidal, mg - tetrahedral, sp3 e. eg = tetrahedral, mg - trigonal planar, sp2
The correct electron geometry (eg) and molecular geometry (mg) for [tex]NH_3[/tex] is a. eg = tetrahedral, mg = trigonal pyramidal, [tex]sp^3[/tex].
There are four electron regions around the central nitrogen atom, making a tetrahedral electron geometry, but because of the lone pairs of electrons, the molecular geometry is a trigonal pyramidal shape. The hybridization is [tex]sp^3[/tex], which means the orbitals used to form bonds and lone pairs are an s orbital and three p orbitals. Electron geometry shows the arrangement of electrons in space around the central atom, whereas molecular geometry shows the arrangement of atoms in a given molecule.Therefore,[tex]NH_3[/tex] have tetrahedral electron geometry, trigonal pyramidal molecular geometry and sp^3 hybridization.Learn more about electron geometry: https://brainly.com/question/7283835
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Question 16: June 2019 CR
6 Poly(chloroethene) is a polymer.
It is made from its monomer, chloroethene.
(a) Chloroethene has the percentage composition by mass
C= 38.4% H = 4.8%
Cl=56.8%
I
Show, by calculation, that the empirical formula of chloroethene is C₂H,Cl
(3)
The empirical formula of chloroethene is C₂H₃Cl, which can be simplified to C₂H₃Cl.
What is empirical formula?The probably the easiest whole number ratio of atoms in a compound is an empirical formula. It gives the relative number of atoms of each element in the compound, but not the actual number of atoms or the arrangement of the atoms. The empirical formula is determined based on the experimental data of the percentage composition by mass or the molar ratios of the elements in the compound.
To find the empirical formula of chloroethene, we need to determine the simplest whole number ratio of the atoms present in the compound.
Let's assume we have a 100 g sample of chloroethene. Then, we can calculate the mass of each element present in the sample:
Mass of carbon (C) = 38.4 g
Mass of hydrogen (H) = 4.8 g
Mass of chlorine (Cl) = 56.8 g
Next, we need to convert these masses to moles by dividing by their respective atomic masses:
Moles of carbon (C) = 38.4 g / 12.01 g/mol = 3.196 mol
Moles of hydrogen (H) = 4.8 g / 1.01 g/mol = 4.752 mol
Moles of chlorine (Cl) = 56.8 g / 35.45 g/mol = 1.601 mol
We can then divide each of these mole values by the smallest mole value to get the simplest whole number ratio:
Carbon: 3.196 mol / 1.601 mol = 1.998 ≈ 2
Hydrogen: 4.752 mol / 1.601 mol = 2.969 ≈ 3
Chlorine: 1.601 mol / 1.601 mol = 1
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based on the chromatogram, which amino acids or substances were present in the hydrolyzed equal sample?
Answer: Based on the Chromatogram, the amino acids or substances present in the hydrolyzed equal sample are alanine, glycine, leucine, valine, isoleucine, and tyrosine.
Explanation:
Chromatogram is a graph or visual representation of the separated components of a mixture produced by chromatography. It provides information about the sample components, including their identity and relative amounts.
Based on the given chromatogram, Leucine, Tyrosine, and Phenylalanine amino acids or substances were present in the hydrolyzed equal sample. These amino acids are identified by their retention times, which can be compared to reference standards or databases to determine their identity.
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Determine the overall reaction and its standard cell potential at 25 �C for the reaction involving the galvanic cell made from a half-cell consisting of a silver electrode in 1 M silver nitrate solution and a half-cell consisting of a zinc electrode in 1 M zinc nitrate. Is the reaction spontaneous at standard conditions?
The reaction involved in the galvanic cell made from a half-cell consisting of a silver electrode in 1 M silver nitrate solution and a half-cell consisting of a zinc electrode in 1 M zinc nitrate is given as follows:2 Ag(s) + Zn2+ (aq) → Zn(s) + 2 Ag+ (aq)The standard cell potential at 25 °C for the given reaction can be determined using the following formula: E°cell
= E°cathode - E°anodeHere, the E°cathode and E°anode represent the standard reduction potentials of cathode and anode respectively. The values of these standard reduction potentials can be obtained from the standard reduction
potentials table.Using the values of standard reduction potentials from the table, we have:E°cell = E°Ag+ / Ag - E°Zn2+ / Zn= +0.80 V - (-0.76 V)= +1.56 VThe reaction is spontaneous at standard conditions because the calculated standard
cell potential is positive (+1.56 V). Therefore, the reaction will proceed spontaneously from left to right direction.The bolded non-consecutive keywords are: spontaneous, standard conditions, galvanic cell, reduction potentials.
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what is the effect of changing the...nature of the halide?nature of the solvent?relative concentrations of the reactants?temperature of the reaction?nature of the nucleophile?
Changing the nature of the halide, the nature of the solvent, the relative concentrations of the reactants, altering the temperature, and the nature of the nucleophile will affect the reaction rate.
The effects of changing the nature of the halide, solvent, relative concentrations of the reactants, temperature of the reaction, and nature of the nucleophile can vary depending on the specific chemical reaction being considered.
a) Nature of the halide: Changing the halide can affect the reactivity and selectivity of a reaction.
b) Nature of the solvent: The choice of solvent can affect the solubility, reactivity, and selectivity of a reaction.
c) Relative concentrations of the reactants: Changing the relative concentrations of reactants can affect the rate and outcome of a reaction.
d) Temperature of the reaction: The temperature can affect the rate and selectivity of a reaction by altering the energy barrier for the reaction.
e) The effect of changing the nature of the nucleophile: The nature of the nucleophile influences the selectivity and the mechanism of the reaction.
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Q1. Sulphur burns in air upon gentle heating with a pale blue flame. It
produces colourless and poisonous sulphur dioxide gas.
a) What are the reactants and products in this reaction? Write as a
word equation.
Sulfur and oxygen are the reactants in this process, and sulfur dioxide is the end result. Sulfur + Oxygen = Sulfur Dioxide is the word equation for this process.
What is the chemical formula for oxygen and sulfur dioxide?Chemical equation writing. Sulfur trioxide is created when sulfur dioxide and oxygen are combined. Sulfur trioxide, often known as SO3, is the result of the reaction between sulfur dioxide and oxygen (SO2+O2).
The reaction between sulfur dioxide and sulfur oxygen is what kind?This reaction is a combination reaction, which is the type of chemical reaction it is. Balanced Approaches: S and O2 combine to generate SO2 in this reaction of combination. Make sure the number of atoms on either side of the equation is equal by carefully counting them up.
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If four molecules of carbon dioxide enter the Calvin cycle (four "turns" of the cycle), how many G3P molecules are produced and how many are exported? a. 4 G3P made, 1 G3P exported b. 4 G3P made, 2 G3P exported c. 8 G3P made, 1 G3P exported d. 8 G3P made, 4 G3P exported
If four molecules of carbon dioxide enter the Calvin cycle (four "turns" of the cycle), eight G3P molecules are produced, and four G3P molecules are exported is d. 8 G3P made, 4 G3P exported.
The Calvin cycle is the collection of chemical reactions that occur in chloroplasts during photosynthesis. The Calvin cycle transforms CO2, using the energy from ATP and NADPH produced in the light reactions, into the sugar G3P. Three G3P molecules are created for every three CO2 molecules that enter the cycle. Every G3P molecule has three carbon atoms. If four molecules of CO2 enter the Calvin cycle (four "turns" of the cycle), eight G3P molecules are produced, and four G3P molecules are exported.
In the first step of the Calvin cycle, three CO2 molecules are combined with three RuBP molecules to form six 3-PGA molecules, which are then converted into six G3P molecules. However, five of the six G3P molecules must be recycled into RuBP so that the cycle can continue. As a result, only one G3P molecule out of the six created is exported from the cycle. So, every four CO2 molecules that enter the Calvin cycle create two G3P molecules that are exported out of the cycle.
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An acid donates a proton to form its ________ , which therefore has one less _______ , and one more _______ than its acid.
conjugate base, hydrogen atom, negative charge
An acid donates a proton to form its conjugate base, which therefore has one less hydrogen atom and one more negative charge than its acid. The strength of an acid depends on its ability to donate a proton to form its conjugate base. The weaker the acid, the stronger the conjugate base, and the stronger the acid, the weaker the conjugate
base.The conjugate base of a strong acid is weak because it has a very low ability to accept another proton since it is already carrying a negative charge. A weak acid has a strong conjugate base since it has a high ability to accept
another proton. Thus, an acid and its conjugate base are related to each other in terms of their ability to donate or accept a proton. For example, hydrochloric acid (HCl) dissociates in water to form H+ and Cl-. Its conjugate base is
chloride (Cl-) which is strong since it cannot accept another proton to form HCl again.
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Which of the following is an Arrhenius base?
A) CH3CO2H
B) LiOH
C) CH3OH
D) NaBr
E) More than one of these compounds is an Arrhenius base
The correct option is (B) LiOH. An Arrhenius base is one that dissociates in water to produce hydroxide ions (OH⁻). LiOH is an example of an Arrhenius base.
Arrhenius acid-base theoryAccording to the Arrhenius acid-base theory, acids are compounds that dissolve in water to form H⁺ (hydrogen ion) while bases are compounds that dissolve in water to form OH⁻ (hydroxide ion).
Arrhenius Acid: A substance that dissociates in water to give H⁺ (hydrogen ion) ions is called an Arrhenius acid. They release hydrogen ions when dissolved in water. For example, HCl, HNO₃, H₂SO₄, HClO₄, etc.
Arrhenius Base: A substance that dissociates in water to give OH⁻ (hydroxide ion) ions is called an Arrhenius base. They release hydroxide ions when dissolved in water. Examples include NaOH, KOH, Mg(OH)₂, Ca(OH)₂, etc.
Let's now analyze the given options.
A) CH₃CO₂H is an organic acid called acetic acid. It is a weak acid and not an Arrhenius base.
B) LiOH dissociates in water to form Li⁺ and OH⁻ ions. Hence, it is an Arrhenius base.
C) CH₃OH is an alcohol called methanol. It is a weak acid and not an Arrhenius base.
D) NaBr is an ionic compound consisting of Na⁺ and Br⁻ ions. It is neither an acid nor a base.
E) More than one of these compounds is an Arrhenius base. This statement is incorrect because only option B (LiOH) is an Arrhenius base.
Hence, option B is the correct answer.
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The materials or compounds converted into new compounds in a chemical reaction are known as
The materials or compounds that are converted into new compounds in a chemical reaction are known as reactants.
Reactants are the starting materials for a chemical reaction and are consumed or used up during the reaction to form new products. In a chemical equation, reactants are written on the left-hand side of the arrow and products are written on the right-hand side. The reactants in a chemical reaction can be solids, liquids, or gases, and can be composed of elements or compounds. Understanding the reactants and products involved in a chemical reaction is important in predicting the outcome of a reaction and determining the stoichiometry, or the relative amounts of each substance involved.
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A: Branched Group Type and Location:
(Hint: There are two, but they are the same type)
b. Longest Chain:
c. Functional Group:
d. Full Name of Compound:
The longest chain is pentane
The functional group is alkene
The name of the compound would be based on the kinds of substituents present.
What are the types of branching in organic compounds?In organic chemistry, there are two main types of branching in organic compounds: chain branching and positional branching.
Chain branching: Chain branching occurs when a side chain (alkyl group) is attached to the main carbon chain of a molecule. This results in a change in the chemical and physical properties of the molecule, such as boiling point, melting point, and solubility. Examples of chain-branched compounds include isobutane (2-methylpropane), isopentane (2-methylbutane), and neopentane (2,2-dimethylpropane).
Positional branching: Positional branching occurs when a substituent is attached to a specific position on the main carbon chain of a molecule. This type of branching can occur in cyclic or acyclic molecules, and can have a significant impact on the properties and reactivity of the molecule. Examples of positional-branched compounds include tert-butyl alcohol (2-methyl-2-propanol), 1-chloro-3-methylbutane, and 2,4-dimethylhexane.
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What change did you observe in the hot water when you poured it in the mixing bowl?
Answer: You should add a picture but just put that the mixing bowl will get water vapor around the bowl
Explanation: the mixing bowl will get water vapor around the bowl
A Read each question carefully. Write your response in the space provided for each part of each question. Answers must be written out in paragraph form. Outlines, bulleted lists, or diagrams alone are not acceptable and will not be scored. Scientists are testing substance L to determine how it enters mammalian cells in a culture. The cells maintain a 120 millimolar (mM) intracellular concentration of substance L. The scientists determined the rate of entry of substance L into the cells at various external concentrations of substance L (10 to 100 mM) in culture medium (Table 1). Table 1. Rate of entry of substance L into mammalian cells in culture External concentration of substance L (MM) Rate of entry of substance L into cell as a percent of maximum 10 5% 20 25% 30 45% 40 65% 50 80% 60 90% 70 95% 80 100% 40 65% 50 80% 60 90% 70 95% 80 100% 90 100% 100 100% The cells maintain substance L at an internal concentration of 120 mM. (a) Identify the most likely mode of transport across the membrane for substance L. Explain how information provided helps determine the most likely mode of transport. BI y = 0 / 10000 Word (b) On the axes provided, construct an appropriately labeled line graph with correct scale and units to illustrate the data in Table 1. (b) On the axes provided, construct an appropriately labeled line graph with correct scale and units to illustrate the data in Table 1. 0/2 File Limit (c) Determine the external concentration of substance L that will result in one-half of the maximal entry rate. BI VE (d) Predict the likely effect on the ability of substance L to enter the cells if substance L is attached to a large protein instead of free in the culture. B I USE 0
(a) The most likely mode of transport across the membrane for substance L is facilitated diffusion.
What is transport?Transport is the movement of people, animals and goods from one location to another. It is a key factor in economic growth as it allows for the exchange of people, goods and services between different locations.
This can be determined from the data in Table 1 which shows that the rate of entry is directly related to the external concentration of substance L. As the external concentration increases, so does the rate of entry, indicating that the transport is not mediated by active transport and instead is dictated by the concentration gradient.
(b) The line graph below illustrates the data in Table 1, with the external concentration of substance L on the x-axis and the rate of entry of substance L into the cell as a percent of maximum on the y-axis.
(c) The external concentration of substance L that will result in one-half of the maximal entry rate is 50 mM. This can be determined from the graph, which shows that the rate of entry reaches half the maximum value at 50 mM.
(d) If substance L is attached to a large protein, it is likely to have a reduced ability to enter the cells. This is because the larger size of the protein will make it more difficult for it to pass through the membrane, thus reducing the rate of entry of the substance L into the cell.
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Elemento de la aplicación de Visio que se usa para organizar formas en grupos visuales, siendo afectados también cuando sus formas o elementos se mueven, copian o eliminan
Visio application element used to organize shapes into visual groups, also being affected when their shapes or elements are moved, copied, or deleted is called Grouping.
"Grouping" is an essential feature in the Microsoft Visio application that allows users to organize shapes into visual groups. With this feature, users can select multiple shapes and group them together, making them behave as a single entity. When one shape in the group is moved, copied, or deleted, the other shapes in the group are also affected.
This feature is particularly useful when creating complex diagrams or flowcharts, as it allows users to manipulate multiple shapes as a single unit. Overall, "Grouping" in Visio is a simple but powerful tool that helps users to organize and manage their shapes and diagrams with ease.
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--The complete question is, Visio application element used to organize shapes into visual groups, also being affected when their shapes or elements are moved, copied, or deleted is called ________.--
how is burning gasoline in an automobile engine part of the carbon cycle?
Burning gasoline in an automobile engine is part of the carbon cycle as the gasoline contains carbon that is released into the atmosphere as carbon dioxide, which is then taken up by plants during photosynthesis.
When gasoline is burned in an automobile engine, the carbon in the gasoline is converted into carbon dioxide gas, which is released into the atmosphere. This carbon dioxide then becomes available to plants during photosynthesis, where it is used to create organic compounds such as sugars and starches. This process is a part of the carbon cycle, which is the natural process by which carbon is cycled through the Earth's atmosphere, oceans, and land. The carbon cycle is essential for life on Earth, as it allows carbon to be used and reused by living organisms in a sustainable way.
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when nitrogen reacts with oxygen to form dinitrogen pentoxide, calculate the mass of dinitrogen pentoxide that could be formed from 104.0 grams of oxygen and 204.0 grams of nitrogen.
140.4 grams of dinitrogen pentoxide are produced from 104.0 grams of oxygen and 204.0 grams of nitrogen.
Chemical StoichiometryTo calculate the mass of dinitrogen pentoxide that could be formed from 104.0 grams of oxygen and 204.0 grams of nitrogen, we need to use stoichiometry.
From the balanced equation, we can see that 2 moles of nitrogen react with 5 moles of oxygen to produce 2 moles of dinitrogen pentoxide. Therefore, we need to determine the limiting reactant in this reaction, which is the reactant that is completely consumed and determines the amount of product that can be formed.
2N₂ + 5O₂ = 2N₂O₅To do this, we can calculate the number of moles of each reactant:
Number of moles of oxygen = 104.0 g / 32.00 g/mol = 3.25 molNumber of moles of nitrogen = 204.0 g / 28.02 g/mol = 7.29 molThe ratio of moles of nitrogen to moles of oxygen is 7.29/3.25 ≈ 2.24/1. Therefore, oxygen is the limiting reactant because we need 5 moles of oxygen for every 2 moles of nitrogen.
Now we can use the amount of oxygen to calculate the amount of dinitrogen pentoxide that can be formed:
Number of moles of dinitrogen pentoxide = (3.25 mol O₂) / (5 mol O₂/2 mol N₂O₅) = 1.30 mol N₂O₅Finally, we can calculate the mass of dinitrogen pentoxide using its molar mass:
Mass of dinitrogen pentoxide = (1.30 mol) x (108.01 g/mol) = 140.4 gTherefore, 104.0 grams of oxygen and 204.0 grams of nitrogen can produce a maximum of 140.4 grams of dinitrogen pentoxide.
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Pls help if u cannn!!
Answer:
proofs attached to answer
Explanation:
proofs attached to answer
Democritus and dalton both proposed that matter consists of atoms. How did their approaches to reaching that conclusion differ
Dalton employed the scientific method—reasoning based on the findings of experiments—whereas Democritus exclusively relied on his own logic and mental inferences.
Democritus developed his ideas about atoms by intellectual inquiry, whereas Dalton developed his ideas through experimentation and meticulous assessment. Democritus had no verifiable truths to support his beliefs and no means of testing them because he relied solely on ideas and did not conduct controlled tests.
Dalton tested his theories and took exact measurements to refine them. Democritus lacked empirical evidence to back up his beliefs and no way to test them because he relied solely on intellect and did not conduct scientific experiments.
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Explain the significance of the line spectrum observed for the hydrogen atom by Neil bohr. What were the inadequacies of the bohr model? calculate the energy required to excite a hydrogen electron from level n=1 to n=3
The line spectrum observed for the hydrogen atom by Niels Bohr is significant because it provided evidence for the quantization of energy levels in atoms.
Bohr's model proposed that electrons in atoms occupy specific energy levels or orbits around the nucleus, and that they can only absorb or emit energy in discrete amounts as they transition between these energy levels. When an electron in hydrogen is excited to a higher energy level by absorbing energy, it eventually returns to its original energy level by emitting energy in the form of light, which is observed as the line spectrum.
However, the Bohr model had some inadequacies. It couldn't explain the spectral lines of atoms other than hydrogen, and it couldn't account for the fine structure of spectral lines due to electron spin. Also, the model violated the Heisenberg uncertainty principle, which states that it is impossible to simultaneously determine the exact position and momentum of an electron.
To calculate the energy required to excite a hydrogen electron from level n=1 to n=3, we can use the formula:
ΔE = E3 - E1 = (-13.6 eV/n²) [(1/3²) - (1/1²)]
where E1 and E3 are the energy levels corresponding to n=1 and n=3, respectively. Plugging in the values gives:
ΔE = (-13.6 eV/n²) [(1/3²) - (1/1²)] = (-13.6 eV) [(1/9) - 1] = 10.2 eV
Therefore, the energy required to excite a hydrogen electron from level n=1 to n=3 is 10.2 eV.
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Could someone help me with this? URGENT
Answer:
The number of protons in a water molecule (H2O) is equal to the number of hydrogen atoms in the molecule, which is 2. The molar mass of water is approximately 18.015 g/mol, which means that one mole of water contains Avogadro's number (6.022 x 10^23) molecules. Therefore, the number of protons in one mole of water is:
2 x 6.022 x 10^23 = 1.2044 x 10^24
To find the number of protons in 306 mL of water, we need to first convert the volume to moles. The density of water is approximately 1 g/mL, so the mass of 306 mL of water is:
306 mL x 1 g/mL = 306 g
The number of moles of water is then:
306 g / 18.015 g/mol = 16.991 mol
Multiplying this by the number of protons per mole, we get:
16.991 mol x 1.2044 x 10^24 protons/mol = 2.049 x 10^25 protons
Therefore, the answer is option D, 1 * 10 ^ 25
Identify the major mechanistic pathway when 1-chloropentane is treated with KCN.a. E1
b. E2
c.SN1
d. SN2
The major mechanistic pathway when 1-chloropentane is treated with KCN is [tex]SN^2[/tex]. So, the correct option is d.
A mechanistic pathway is the sequence of steps that leads to the formation of a specific product from the reactants.
The mechanism of a chemical reaction is typically portrayed using chemical equations and mathematical models.
The [tex]SN^2[/tex] mechanism is the primary mechanistic pathway when 1-chloropentane is treated with KCN.
In an [tex]SN^2[/tex] mechanism, the nucleophile competes with the leaving group in a concerted step in the formation of a new bond. This mechanism is common in primary halides with excellent leaving groups, and the reaction rate is largely determined by the nucleophile's concentration and accessibility.
The term "SN" refers to the nucleophilic substitution reaction in organic chemistry. It stands for "Substitution Nucleophilic."
The [tex]SN^1, SN^2, E1[/tex], and E2 mechanisms are four common mechanisms in organic chemistry. The SN^1 mechanism is a two-step reaction, with the leaving group first leaving, leaving a carbocation intermediate, which is then attacked by a nucleophile.
The elimination reaction that follows the SN1 reaction mechanism is E1.
The elimination reaction that follows the [tex]SN^2[/tex] reaction mechanism is E2. Therefore, the correct option is d.
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What is the PH of a solution if [H3O]= 1. 7×10-3 M
Answer: 2.77
Explanation: pH=-log[H+] (=-log[H3O+])
pH=-log[1.7*10^-3]=2.77
In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture? (A) CO(g) + H2O (8) CO2 (g) + H2(g) (B) 2NO(g) + Cl2 (g) + 2NOCI (8) (C) 250, (g) = 2502(g) + O2(g) (D) PCIs () PC13 (8) + Cl2 (8) 6. K, for the reaction of SO2 (g) with O2 to produce SO; (g) is 3 x 1024 Calculate K, for this reaction at 25°C. 2SO2 (g) + O2(g) 250 (8) (A) 3 x 1024 (B) 5 x 1021 (C) 2 x 1020 (D) 5 x 1022 (E) 7 x 102 7. The molar solubility of magnesium carbonate is 1.8 x 10 mol/L. What is Kp for this compound? (A) 1.8 x 10 (B) 3.6 x 10-4 (C) 1.3 x 10-7 (D) 3.2 x 10 (E) 2.8 x 10-14
The correct answer is (B) 2NO(g) + Cl2 (g) + 2NOCI (8). Increasing the total pressure on the reaction mixture will increase the yield of products. For the second question, the correct answer is (E) 7 x 102. Kp for the molar solubility of magnesium carbonate is 3.6 x 10-4.
Chemical equilibrium refers to the situation in a chemical reaction where both the reactants and products are present in concentrations that have no further tendency to change over time, preventing any discernible change in the system's properties. When the forward reaction and the reverse reaction go forward at the same speed, this condition results. The forward and backward reactions typically have equal, if not zero, reaction rates. The concentrations of the reactants and products do not change on a net basis as a result. Dynamic equilibrium is the name given to such a situation.
The reaction's Gibbs free energy, G, must be taken into account at constant temperature and pressure. The Helmholtz free energy, A, must be taken into account at constant temperature and volume. The reaction's entropy, S, must be taken into account at constant internal energy and volume.
In geochemistry and atmospheric chemistry, where pressure changes are considerable, the constant volume case is crucial.
It is thought about the case of constant pressure. By taking into account chemical potentials, the relationship between the Gibbs free energy and the equilibrium constant can be discovered.
The Gibbs free energy for the reaction, G, under constant temperature and pressure in the absence of an applied voltage, depends only on the degree of the reaction: (Greek letter xi), and can only decrease in accordance with the second law of thermodynamics. That indicates that if the reaction occurs, the derivative of G with respect to must be negative; at equilibrium, this derivative equals zero.
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rank the following alkyl halides in order of their increasing rate of reaction with triethylamine: iodoethane 1-bromopropane 2-bromopropane
The rate of reaction of alkyl halides with triethylamine increases with the electron-releasing effect of the halide group, which increases in the order - Iodoethane < 1-bromopropane < 2-bromopropane.
The strength of nucleophiles and the weakness of leaving groups decide the rate of SN2 reactions. This is what determines the reactivity of alkyl halides.
Alkyl halides are classified as primary, secondary, or tertiary based on the number of carbons that the halogen is bonded to. Because primary alkyl halides have more accessibility to their halogen and less steric hindrance around it, the speed of the reaction is greater.
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Rank the following items in order of decreasing radius: K, K^+, and K^-. Rank from largest to smallest radius. To rank items as equivalent, overlap them.
K, K^+, and K^-
Largest radius Smallest radius
______________ ______________
In isoelectronic species, the species that have the least number of electrons will have the smallest radius. Therefore, K+ has the smallest radius amongst K, K+ and K-.The order of the radius of the given species can be given as follows:
K > K⁻ > K⁺
The effective nuclear charge experienced by the K atom is +1, as it has one valence electron which can shield 18 electrons. Therefore, the attraction between the valence electron and the nucleus is weak which makes the atomic size larger than that of K- and K+.
The effective nuclear charge experienced by the K-atom is +1, as it has one valence electron which can shield 17 electrons. The attraction between the valence electron and the nucleus is stronger than in K due to less screening effect by electrons. Therefore, the atomic size is smaller than that of K.
The effective nuclear charge experienced by the K⁺ atom is +1, as it has one valence electron which can shield 19 electrons. The attraction between the valence electron and the nucleus is maximum in K+ due to the absence of one electron from the 4s orbital. Therefore, the atomic size is the smallest among the given species.
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How much cesium (half-life = 2 years) would remain from a 10 g sample after 2 years?
5 g of cesium(half-life = 2 years) would remain from a 10 g sample after 2 years.
Cesium has a half-life of 2 years. The half-life of a material is the length of time necessary for half of it to degrade or react. Half-life is a property of a chemical that is commonly represented by the sign "t½".
To find out how much cesium (half-life = 2 years) would remain from a 10 g sample after 2 years, we can use the formula
N = N0(1/2)^(t/t1/2) where N is the final amount, N0 is the initial amount, t is the time passed, and t1/2 is the half-life period.
In this case, N0 = 10 g, t = 2 years, and t1/2 = 2 years.
Substituting these values into the formula:
N = N0(1/2)^(t/t1/2)
N = 10 g(1/2)^(2/2)
N = 10 g(1/2)^1
N = 10 g(0.5)
N = 5 g
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Determine the percent yield of diacetyl ferrocene in the following unbalanced reaction using the data provided. Record your answer on the bubble sheet using the second significant figure. AICI Ferrocene MW: 186.03 used: 210. mg Acetyl Chloride MW: 78.50 Density: 1.104 g/ml used: 155 uL Diacetyl Ferrocene MW: 270.10 isolated: 225 mg. multiple choice: O A. 3 B. 4 C. 5 D. 6
The percent yield of diacetyl ferrocene in the given unbalanced reaction is 144.5%. The answer is option A. 3.
Explanation : To calculate the percent yield of diacetyl ferrocene in the following unbalanced reaction, use the following formula:
Percent Yield = (Mass of Isolated Product / Theoretical Mass of Product) x 100%
To find the Theoretical Mass of Product, use the following formula:
Theoretical Mass of Product = (MW of Reactant * Mass of Reactant Used) / MW of Product
Substituting in the values provided:
Theoretical Mass of Product = (186.03 * 210mg) / 270.10 = 155.46mg
Percent Yield = (225mg / 155.46mg) x 100% = 144.48%
Therefore, the percent yield of diacetyl ferrocene in the given unbalanced reaction is 144.5%.
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Why do we use anhydrous diethyl ether? Choose the right answer.
A. Since Grignard reagents react with O2 to form hydroperoxides, vapors from highly volatile diethyl ether solvent prevents O2 from reaching the reaction mixture.
B. Ether molecules coordinate with grignard Reagent
C. Ether helps stabilize the Grignard reagent
We use anhydrous diethyl ether since Grignard reagents react with O2 to form hydroperoxides, vapors from highly volatile diethyl ether solvent prevents O2 from reaching the reaction mixture. Option A is the correct answer.
Anhydrous diethyl ether is commonly used as a solvent in Grignard reactions. The main reason for using anhydrous diethyl ether is to prevent the Grignard reagent from reacting with moisture or oxygen in the air, which would lead to unwanted side reactions or a reduction in the yield of the desired product.
Diethyl ether is highly volatile, and its vapors help to exclude oxygen from the reaction mixture, preventing the formation of hydroperoxides. Additionally, diethyl ether helps to dissolve the reactants and stabilize the Grignard reagent, making it more reactive towards the substrate. Hence option A is correct.
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determine the limiting reactant, amounts of each product formed, and the amount by which the excess reactant is for a reaction between 12.0 grams of nh3 and 15.0 grams of o2.
To determine the limiting reactant, amounts of each product formed, and the amount by which the excess reactant is for a reaction between 12.0 grams of NH₃ and 15.0 grams of O₂, the balanced chemical equation and stoichiometry must be used.
The balanced chemical equation for the reaction between NH₃ and O₂ is:
4NH₃ + 5O₂ → 4NO + 6H₂O
To determine the limiting reactant, the amounts of reactants must be converted to moles. The molar mass of NH3 is 17.03 g/mol and the molar mass of O₂ is 32.00 g/mol.
12.0 g NH₃ × (1 mol NH3/17.03 g NH₃) = 0.705 mol NH
315.0 g O₂ × (1 mol O2/32.00 g O₂) = 0.469 mol O₂
The stoichiometry of the balanced chemical equation indicates that 4 moles of NH₃ reacts with 5 moles of O₂. The mole ratio of NH₃ to O₂ is 4/5 or 0.8. Since the mole ratio of NH₃ to O₂ is greater than the actual mole ratio of 0.705/0.469 or 1.50, NH₃ is the excess reactant and O₂ is the limiting reactant.
To determine the amount of each product formed, the mole ratio of products to limiting reactant must be used. The mole ratio of NO to O₂ is 4/5 or 0.8, and the mole ratio of H₂O to O₂ is 6/5 or 1.2. Since O₂ is the limiting reactant, the amount of NO and H₂O that can be produced is based on the mole ratio to O₂.
0.469 mol O₂ × (4 mol NO/5 mol O₂) × (30.01 g NO/1 mol NO) = 0.601 g NO
0.469 mol O₂ × (6 mol H₂O/5 mol O₂) × (18.02 g H₂O/1 mol H₂O) = 0.674 g H₂O
The amount of excess NH₃ is determined by subtracting the moles of NH₃ used from the moles of NH₃ added.
0.705 mol NH₃ − (0.469 mol O₂ × 4 mol NH₃ / 5 mol O₂) = 0.408 mol NH₃
Thus, the limiting reactant is O₂, 0.601 g NO and 0.674 g H₂O are produced, and there is 0.408 mol of excess NH₃.
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