Will a precipitate (ppt) form when 300. mL of 2.0 × 10 –5 M AgNO 3 are added to 200. mL of 2.5 × 10 –9 M NaI? Answer yes or no, and identify the precipitate if there is one

Answers

Answer 1

Answer:

A precipitate will form, AgI

Explanation:

When Ag⁺ and I⁻ ions are in an aqueous media, AgI(s), a precipitate, is produced or not based on its Ksp expression:

Ksp = 8.3x10⁻¹⁷ = [Ag⁺] [I⁻]

Where the concentrations of the ions are the concentrations in equilibrium

For actual concentrations of a solution, you can define Q, reaction quotient, as:

Q = [Ag⁺] [I⁻]

If Q > Ksp, the ions will react producing BaCO₃, if not, no precipitate will form.

Actual concentrations of Ag⁺ and I⁻ are:

[Ag⁺] = [AgNO₃] = 2.0x10⁻⁵ × (300mL / 500.0mL) = 1.2x10⁻⁵M

[I⁻] = [NaI] = 2.5x10⁻⁹ × (200mL / 500.0mL) = 1.0x10⁻⁹M

500.0mL is the volume of the mixture of the solutions

Replacing in Q expression:

Q = [Ag⁺] [I⁻]

Q = [1.2x10⁻⁵M] [1.0x10⁻⁹M]

Q = 1.2x10⁻¹⁴

As Q > Ksp

A precipitate will form, AgI


Related Questions

please help guys the question is

give reasons

a. we have to separate the mixture

b. All impure substances are not harmful.

c. A mixture of iron fillings and sand can be separated by using a magnet

d. A sentences "shake before well use" is written on the bottle of the medicine.

Answers

Answer:

(a )people separate mixtures in order to ger a specific substance that they need.

"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"

Answers

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

pKa NH₃/NH₄⁺

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = 4.74

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

Moles NH₃

2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃

H-H equation:

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Refer to the figure.
30. How many planes are shown in the figure?
31. How many planes contain points B, C, and E?
32. Name three collinear points.
3. Where could you add point G on plane N
so that A, B, and G would be collinear?
4. Name a point that is not coplanar with
A, B, and C.
5. Name four points that are coplanar.
BN

Answers

Answer:

  30. 5 planes are shown

  31. 1 plane

  32. CEF

  33. on line AB

  34. E or F

   35. ABCD or BCEF or CDEF or ACEF

Explanation:

30. Each of the surfaces of the rectangular pyramid is a plane. There are 5 planes.

__

31. 3 points define one plane only.

__

32. The only points shown on the same line segment are points E, F, and C.

__

33. If G is to be collinear with A and B, it must lie on line AB.

__

34. The only points shown that are not on plane N are points E and F. Either of those will do.

__

35. There are three planes that have 4 points shown on them. The four points that are on the same plane are any of ...

ABCDBCEFCDEF

Plane ACEF is not shown on the diagram, but we know that those 4 points are also coplanar. (Any point not on line CE, together with the three points on that line, will define a plane with 4 coplanar points.)

Identify the compound that does NOT have hydrogen bonding.
A) CH3NH2
B) H2O
C) (CH3)3N
D) CH3OH
E) HF

Answers

Answer:

(CH3)3N

Explanation:

Hydrogen bonding can be called a type of intracellular force of the attraction. It is the force that occur between molecules. It is the bonding between the molecules and of hydrogen and electronegative items in the covalent bond. This is called the hydrogen donor. An electro-negative hydrogen atoms may be a hydrogen bonded. It is also called a hydrogen acceptor.

Thus in (CH3)3N, the hydrogen atoms becomes bonded with carbon. Carbon is not electronegative atoms. Thus it does not play as donor. Nitrogen is electronegative and play as hydrogen acceptor. But there is no presence of hydrogen acceptor. Thus there is no molecules that exhibit hydrogen molecules bonding.

[tex]\bold {(CH_3)_3N}[/tex] does not have hydrogen bonding because of the absence of electronegativity difference.

 

Hydrogen bond:

It is an inter-molecular bond. It is due to the difference in electronegativities of constituent atoms. This creates dipole in the atoms so, atoms start to attract each other.

In [tex]\bold {(CH_3)_3N}[/tex], the hydrogen atoms are bonded with carbon. The difference between the electronegativities Carbon and hydrogen is very less.

Therefore, [tex]\bold {(CH_3)_3N}[/tex] does not have hydrogen bonding because of the absence of electronegativity difference.

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Heterocyclic aromatic compounds undergo electrophilic aromatic substitution in a similar fashion to that undergone by benzene with the formation of a resonance-stabilized intermediate. Draw all of the resonance contributors expected when the above compound undergoes bromination

Answers

Answer:

See explanation

Explanation:

When we talk about electrophilic substitution, we are talking about a substitution reaction in which the attacking agent is an electrophile. The electrophile attacks an electron rich area of a compound during the reaction.

The five membered furan ring is aromatic just as benzene. This aromatic structure is maintained during electrophilic substitution reaction. The attack of the electrophile generates a resonance stabilized intermediate whose canonical structures have been shown in the image attached.

Half-cells were made from a nickel rod dipping in nickel sulfate solution and a copper rod dipping in copper sulfate solution. The cells were combined to construct a voltaic electrochemical cell. Sketch the cell and label anode and cathode with charges, electrode material and electrolyte solutions, half-reactions and overall reaction, give direction of electron flow and movement of ions.

Answers

Answer:

Check the Attachment.

Half-reactions:

Anode: (OXIDATION) Ni --> Ni2+ + 2e-

Cathode: (REDUCTION) Cu2+ +2e- --> Cu

Overall reaction: Ni + Cu2+ --> Ni2+ + Cu

Explanation:

Overall, reaction is basically Anode + Cathode, where electrons on both sides cancel out  (if not, you need to multiply the equation in a way you can cancel them out).

Hope this helps.

What are the conjugate acid-base pairs in the following chemical reaction? HBr(aq)+ CH3COOH(aq) ⇌ CH3C(OH)2+(aq) + Br-(aq)

Answers

Answer:

HBr, CH3C(OH)2 and CH3COOH, Br-

Explanation:

The conjugate acid-base pairs acid reacts with base to form a conjugate acid and conjugate base.

Conjugate acid is formed when a bases receives a proton  (H+) and a conjugate base is formed when an acid losses a proton (H+).

From the given equation:

HBr, CH3C(OH)2 and CH3COOH, Br- are conjugate acid-base pair, where HBr is an acid and CH3C(OH)2 is a conjugate acid while CH3COOH and Br- is the conjugate base.

A student is using a coffee-cup calorimeter to determine the enthalpy change of the endothermic reaction of two aqueous solutions. After both solutions are added to the cup, the student neglects to put the lid on the cup. This would cause the magnitude of the calculated ΔH° value to be: the answer is: too small, since the solution will absorb heat from the room. But why? Wouldn't depend on if the reaction releases or absorbs heat. Wouldn't it be too large because heat escapes the cup? I'm so confused

Answers

Answer:

Explanation:

In all calorimetric experiment , the calorimeter must be isolated from the surrounding . Otherwise the heat change in the experiment can not be determined with precision .

The reaction is endothermic . Hence, there is lowering of temperature due to absorption of heat in the reaction equal to ΔH°. The value of ΔH° can be calculated by measuring fall in the temperature of the content . The fall in the temperature will be less when heat is allowed to come from the surrounding . Less fall of temperature will result in less ΔH° to be calculated .

Hence in the given experiment , if the student neglects to put lid on the cup , the experiment will give less value of ΔH°.

When we react a weak acid with a strong base of equal amounts and concentration, the component of the reaction that will have the greatest effect on the pH of the solution is:______.
a. the acid.
b. the base.
c. the conjugate acid.
d. the conjugate base.

Answers

Answer:

d. the conjugate base.

Explanation:

The general reaction of a weak acid, HA, with a strong base YOH, is:

HA + YOH → A⁻ + H₂O + Y⁻

Where A⁻ is the conjugate base of the weak acid and Y⁻ usually is a strong electrolyte.

That means after he complete reaction you don't have weak acid nor strong base, just conjugate base that will be in equilibrium with water, thus (Strong electrolyte doesn't change pH:

A⁻ + H₂O ⇄ HA + OH⁻

As the equilibrium is producing OH⁻, the pH of the solution is being affected for the conjugate base

Right option:

d. the conjugate base.

The normal boiling point of a liquid is 282 °C. At what temperature (in °C) would the vapor pressure be 0.350 atm? (∆Hvap = 28.5 kJ/mol)

Answers

Answer:

The temperature at which the vapor pressure would be 0.350 atm is 201.37°C

Explanation:

The relationship between variables in equilibrium between phases of one component system e.g liquid and vapor, solid and vapor , solid and liquid can be obtained from a thermodynamic relationship called Clapeyron equation.

Clausius- Clapeyron Equation can be put in a more convenient form applicable to vaporization and sublimation equilibria in which one of the two phases is gaseous.

The equation for Clausius- Clapeyron Equation can be expressed as:

[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]

where ;

[tex]P_1[/tex] is the vapor pressure at temperature 1

[tex]P_ 2[/tex] is the vapor pressure  at temperature 2

∆Hvap = enthalpy of vaporization

R = universal gas constant

Given that:

[tex]P_1[/tex] = 1 atm

[tex]P_ 2[/tex]  = 0.350 atm

∆Hvap = 28.5 kJ/mol = 28.5 × 10³ J/mol

[tex]T_1[/tex] = 282 °C  = (282 + 273) K = 555 K

R = 8.314 J/mol/k

Substituting the above values  into the Clausius - Clapeyron equation, we have:

[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]

[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{T_2 - 555}{555T_2} \end {pmatrix} }[/tex]

[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]

[tex]- 1.0498= 3427.953 \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]

[tex]\dfrac{- 1.0498}{3427.953}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]

[tex]- 3.06246906 \times 10^{-4}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]

[tex]\dfrac{1}{T_2} = \begin {pmatrix} \dfrac{1}{555}+ (3.06246906 \times 10^{-4} ) \end {pmatrix} }[/tex]

[tex]\dfrac{1}{T_2} = 0.002108048708[/tex]

[tex]T_2 = \dfrac{1}{0.002108048708}[/tex]

[tex]\mathbf{T_2 }[/tex] =  474.37 K

To °C ; we have [tex]\mathbf{T_2 }[/tex] =   (474.37 - 273)°C

[tex]\mathbf{T_2 }[/tex] =  201.37 °C

Thus, the temperature at which the vapor pressure would be 0.350 atm is 201.37 °C

The temperature of the liquid at the given vapor pressure is 201.5 ⁰C.

The given parameters;

boiling point temperature, = 282 ⁰Cvapor pressure, P₂ = 0.35 atmenthalpy of vaporization, ∆Hvap = 28.5 kJ/mol

The temperature of the liquid will be determined by applying Clausius- Clapeyron Equation;

[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )[/tex]

where;

R is ideal gas constant = 8.314 J/mol.kT₁ is the initial temperature in Kelvin = 282 + 273 = 555 KP₁ is the initial pressure = 1 atm

[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )\\\\ln(\frac{0.35}{1} ) = \frac{28.5 \times 10^3}{8.314} (\frac{T_2 - 555}{555T_2} )\\\\-1.049 = 6.176- \frac{3427.95}{T_2} \\\\\frac{3427.95}{T_2} = 6.176 + 1.049\\\\\frac{3427.95}{T_2} = 7.225\\\\T_2 = \frac{3427.95}{7.225} \\\\T_2 = 474.5 \ K\\\\T_2 = 474.5 - 273 = 201.5 \ ^0C[/tex]

Thus, the temperature of the liquid at the given vapor pressure is 201.5 ⁰C.

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Calculate the amount of heat that must be absorbed by 10.0 g of ice at –20°C to convert it to liquid water at 60.0°C. Given: specific heat (ice) = 2.1 J/g·°C; specific heat (water) = 4.18 J/g·°C; ΔH fus = 6.0 kJ/mol.

Answers

Answer:

The amount of heat to absorb is 6,261 J

Explanation:

Calorimetry is in charge of measuring the amount of heat generated or lost in certain physical or chemical processes.

The total energy required is the sum of the energy to heat the ice from -20 ° C to ice of 0 ° C, melting the ice of 0 ° C in 0 ° C water and finally heating the water to 60 ° C.

So:

Heat required to raise the temperature of ice from -20 °C to 0 °C

Being the sensible heat of a body the amount of heat received or transferred by a body when it undergoes a temperature variation (Δt) without there being a change of physical state (solid, liquid or gaseous), the expression is used:

Q = c * m * ΔT

Where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation (ΔT=Tfinal - Tinitial).

In this case, m= 10 g, specific heat of the ice= 2.1 [tex]\frac{J}{g*C}[/tex] and ΔT=0 C - (-20 C)= 20 C

Replacing: Q= 10 g*2.1 [tex]\frac{J}{g*C}[/tex] *20 C and solving: Q=420 J

Heat required to convert 0 °C ice to 0 °C water

The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:

Q= m* ΔHfusion

In this case, being 1 mol of water= 18 grams: Q= 10 g*[tex]6.0 \frac{kJ}{mol} *\frac{1 mol of water}{18 g}[/tex]= 3.333 kJ= 3,333 J (being kJ=1,000 J)

Heat required to raise the temperature of water from 0 °C to 60 °C

In this case the expression used in the first step is used, but being: m= 10 g, specific heat of the water= 4.18 [tex]\frac{J}{g*C}[/tex] and ΔT=60 C - (0 C)= 60 C

Replacing: Q= 10 g*4.18 [tex]\frac{J}{g*C}[/tex] *60 C and solving: Q=2,508 J

Finally, Qtotal= 420 J + 3,333 J + 2,508 J

Qtotal= 6,261 J

The amount of heat to absorb is 6,261 J

The amount of heat to absorb is 6,261 J.

Calculation for heat:

Heat required to raise the temperature of ice from -20 °C to 0 °C.

The formula for specific heat is used to calculate the amount of heat

Q = c * m * ΔT

Where,

Q =heat exchanged by a body,

m= mass of the body

c= specific heat

ΔT= change in temperature

Given:

m= 10 g,

specific heat of the ice= 2.1

ΔT=0 C - (-20 C)= 20 C

On substituting the values:

Q= 10 g*2.1  *20 C

Q=420 J

Heat required to convert 0 °C ice to 0 °C water.

The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:

Q= m* ΔHfusion

Heat required to raise the temperature of water from 0 °C to 60 °C

m= 10 g,

Specific heat of the water= 4.18  

ΔT=60 C - (0 C)= 60 C

On substituting:

Q= 10 g*4.18  *60 C

Q=2,508 J

Thus, Qtotal= 420 J + 3,333 J + 2,508 J

Qtotal= 6,261 J

The amount of heat to absorb is 6,261 J

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Which of the following is a salt that will form from the combination of a strong base with a weak acid?

Select the correct answer below:
A. NaHCO3
B. H2O
C. CH3CO2H
D. NH4Cl

Answers

Answer:

A. NaHCO₃

Explanation:

NaHCO₃ ⇒ NaOH + H₂CO₃

NaOH is a strong base and H₂CO₃ is a weak acid. Therefore, NaHCO₃ is a salt of a strong base-weak acid reaction. The salt is basic because carbonic acid (H₂CO₃) is a weak acid so it remains undissociated. So, there is a presence of additional OH⁻ ions that makes the solution basic.

Hope that helps.

What is the ph of 0.36M HNO3 ?

Answers

Answer:

0.44

Explanation:

We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.

For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M

pH= -log [H^+]

pH= - log[0.36]

pH= 0.44

Question 14 (5 points)
What's the acid ionization constant for an acid with a pH of 2.11 and an equilibrium
concentration of 0.30 M?
O A) 4.87x10-8
B) 1.99x10-6
C) 3.32x10-4
OD) 2.01x10-4

Answers

Answer:

D) 2.01 x 10⁻⁴ .

Explanation:

pH = 2.11

[ H⁺ ] = [tex]10^{-2.11}[/tex]  

Let the acid be HA

It will ionise as follows .

                                        HA       ⇄       H⁺       +        A⁻

in equilibrium                 .30               [tex]10^{-2.11}[/tex]          [tex]10^{-2.11}[/tex]         

Acid ionisation constant Ka  =   [tex]\frac{(10^{-2.11})^2}{0.3}[/tex]

= 2 x 10⁻⁴                

Answer:

D) 2.01 x 10⁻⁴ is correct!

Explanation:

I got it in class!

Hope this Helps!! :))

3,3-dibromo-4-methylhex-1-yne​

Answers

Explanation:

see the attachment. hope it will help you...

a boy capable of swimming 2.1m/a in still water is swimming in a river with a 1.8 m/a current. At what angle must he swim in order to end up directly opposite his starting point?

Answers

Answer:

The boy must swim at an angle of 59°northwest to get to a position directly opposite his starting point.

Explanation:

To get to a point directly opposite his starting point, the boy must travel at an angle x, in a direction northwest of his starting point. The speed of the boy and the speed of the river current forms a right-angled triangle with an an opposite side of 1.8 m/a and a hypotenuse of 2.1 m/a having an angle x.

Sin x = opp/ hyp

Sin x = 1.8/2.1

x = sin⁻¹ (1.8/2.10

x = 58.99

x = 59°

Therefore, the boy must swim at an angle of 59° in the northwesterly direction to get to a position directly opposite his starting point.

An electrolysis cell has two electrodes. Which statement is correct? A. Reduction takes place at the anode, which is positively charged. B. Reduction takes place at the cathode, which is positively charged. C. Reduction takes place at the dynode, which is uncharged. D. Reduction takes place at the cathode, which is negatively charged. E. Reduction takes place at the anode, which is negatively charged.

Answers

Answer:

D. Reduction takes place at the cathode, which is negatively charged.

Explanation:

In an electrolytic cell there are two electrodes; the cathode and the anode. The anode is the positive electrode while the cathode is the negative electrode. Oxidation occurs at the anode while reduction occurs at the cathode.

At the anode, species give up electrons and become positively charged ions while at the cathode species accept electrons and become reduced.

is a polyprotic acid. Write balanced chemical equations for the sequence of reactions that carbonic acid can undergo when it's dissolved in water.

Answers

Answer:

H₂CO₃   H₂O  ⇄  HCO₃⁻  +  H₃O⁺          Ka1

HCO₃⁻  +  H₂O  ⇄  CO₃⁻²  +  H₃O⁺        Ka2

CO₃⁻²  +  H₂O  ⇄  HCO₃⁻   +  OH⁻       Kb1

HCO₃⁻  +  H₂O  ⇄   H₂CO₃  +  OH⁻     Kb2

Explanation:

Formula for carbonic acid is: H₂CO₃

It is a dyprotic acid, because it can release two protons. We can also mention that is a weak one. The equilibrums are:

H₂CO₃   H₂O  ⇄  HCO₃⁻  +  H₃O⁺          Ka1

HCO₃⁻  +  H₂O  ⇄  CO₃⁻²  +  H₃O⁺        Ka2

When the conjugate strong bases, carbonate and bicarbonate take a proton from water, the reactions are:

CO₃⁻²  +  H₂O  ⇄  HCO₃⁻   +  OH⁻       Kb1

HCO₃⁻  +  H₂O  ⇄   H₂CO₃  +  OH⁻     Kb2

Notice, that bicarbonate anion can release or take a proton to/from water. This is called amphoteric,

9
What might happen if acidic chemicals were emitted into
the air by factories? Choose the best answer.
A
The acid would destroy metallic elements in the air
B
The acid would be neutralized by bases within clouds
C
Acid rain might destroy ecosystems and farmland
D
Violent chemical reactions would take place within the
atmosphere
co search
O
BI

Answers

Your answer is B. Acid rain might destroy ecosystems and farmland

Which of the following contains a nonpolar covalent bond?
O A. Co
B. NaCl
O C. 02
O D. HE

Answers

I think the answer is C. 02

Answer:

The answer is o2

Explanation:

I took the test

Compounds A and B (both C10H14) show prominent peaks in their mass spectrum at m/z 134 and 119. Compound B also shows a less prominent peak at m/z 91. On vigorous oxidation with chromic acid, compound A is nonreactive while compound B yielded terephthalic acid.

Required:
From this information, deduce the structures of both compounds, and then draw the structure of B.

Answers

How many mono-, di- and trichloro derivatives are possible for cyclopentane?

What is silica gel commonly used for? A. Absorbing moisture to protect goods from damage. B. As insulation in buildings. C. As a lacquer on wood to make it water-resistant. D. A soft, flexible padding, such as on pen grips or mouse pads.

Answers

Answer:

A

Explanation:

Absorbing moisture to protect goods from damage. Hence, option A is correct.

What is silica gel?

Silica gel is a desiccant, or drying agent, that manufacturers often place in little packets to keep moisture from damaging certain food and commercial products.

Silica Gel is a good drying agent for preventing corrosion, contamination, spoilage, and mould growth in many commodities and products due to its physical properties.

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Calculate the pH of a 0.20 M NH3/0.20 M NH4Cl buffer after the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.

Answers

Answer:

Explanation:

For pH of a buffer solution , the formula is

pH = pKa + log [ Base ] / [ conjugate acid ]

=   pKa + log [ NH₃ ] / [ NH₄⁺ ]

Ka = Kw / Kb

Kb for NH₄OH = 1.8 x 10⁻⁵

Ka = 10⁻¹⁴ / 1.8 x 10⁻⁵

= 5.6 x 10⁻¹⁰

pH = - log ( 5.6 x 10⁻¹⁰ ) + log 0.2 / 0.2

= 10 - log 5.6

= 9.25

Effect of addition of HCl

H⁺ of HCl will react with NH₃ to produce NH₄⁺

25 mL of .1 HCl = 2.5 mM of HCl

25 mL of .1 NH₄⁺ = 2.5 mM of NH₄⁺

65 mL of .2 M NH₃ = 13 mM of NH₃

65 mL of .2 M NH₄⁺ = 13 mM of NH₄⁺

NH₃ + H⁺ = NH₄⁺

NH₄⁺ formed = 2.5 + 13  mM

15.5 mM of NH₄⁺

NH₃ = 13 mM

Concentration of NH₃ = 13 / 90

Concentration of NH₄⁺ = 15.5 / 90

pH of final buffer mixture

= 9.6 + log 13 / 15.5

= 9.25 - .076

= 9.174

The pH value  is mathematically given as

pH= -6.332.

What is the pH of a 0.20 M NH3/0.20 M NH4Cl buffer?

Question Parameters:

the pH of a 0.20 M NH3/0.20 M NH4Cl buffer

the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.

Generally, the equation for the Chemical Reaction  is mathematically given as

HCl + NH3 --> NH4^+ + Cl^-

Therefore

pH= pka + log(13/14).

pH= -6.3 + log 0.93.

pH= -6.3+ (-0.032).

pH= -6.332.

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Which of the following combinations will result in a reaction that is spontaneous at all temperatures?
Negative enthalpy change and negative entropy change
Negative enthalpy change and positive entropy change
Positive enthalpy change and negative entropy change
Positive enthalpy change and positive entropy change
PLS EXPLAIN WHAT EACH MEANS AND THE VARIABLES AND THE EXPLANATION BEHIND IT

Answers

Answer:

[tex]\huge\boxed{Option \ 2}[/tex]

Explanation:

A reaction is spontaneous at all temperatures by the following combinations:

=> A negative enthalpy change ( [tex]\triangle H < 0[/tex] )

=> A positive entropy change ( [tex]\triangle S > 0[/tex] )

See the attached file for more better understanding!

from Gibbs Equation, [tex] \Delta G = \Delta H - T\Delta S [/tex]

reaction is spontaneous if $\Delta G$ is negative.

so, first option is not valid at high temperature, ($-h+ts$)

second, is always a spontaneous reaction, ($-h-ts$)

third, is never spontaneous ($+h+ts$)

4th is similar to second, spontaneous at higher temperatures ($+h-ts$)

A hypothetical metal crystallizes with the face-centered cubic unit cell. The radius of the metal atom is 198 picometers and its molar mass is 195.08 g/mol. Calculate the density of the metal in g/cm3.

Answers

Answer:

7.38 g/cm³ is the density of the metal

Explanation:

In a Face-centered cubic unit cell you have 4 atoms. Also, the edge length is √8×r (r is radius of the atom).

To solve this problem, we need first to calculate the volume of the unit cell and then, with molar mass calculate the mass of 4 atoms. As density is the ratio between mass and volume we can obtain this value.

Volume of the unit cell

Volume = a³

a = √8×r

(r = 198x10⁻¹²m)

a = 5.6x10⁻¹⁰ m

Volume = 1.756x10⁻²⁸ m³

1m = 100cm → 1m³ = (100cm)³:

1.756x10⁻²⁸ m³× ((100cm)³ / 1m³) =

1.756x10⁻²² cm³ → Volume of the unit cell in cm³Mass of the unit cell:

There are 4 atoms of gold:

4 atoms × (1mol / 6.022x10²³ atoms) = 6.64x10⁻²⁴ moles of gold

As 1 mole weighs 195.08g:

6.64x10⁻²⁴ moles of gold × (195.08g / mol) =

1.296x10⁻²¹g is the mass of the unit cellDensity of the metal:

1.296x10⁻²¹g / 1.756x10⁻²² cm³ =

7.38 g/cm³ is the density of the metal

The density of the metal is 7.40 g/cm³

In cubic crystal system, face-centered cubic FFC is the name given to sort of atom arrangement observed in which structure is made up of atoms organized in a cube with a portion of an atom in each corner and six extra atoms in the center of each cube face.

It is expressed by using the formula:

[tex]\mathbf{\rho = \dfrac{Z \times M}{N_A\times a^}}[/tex]

where;

[tex]\rho[/tex] = density of the metalZ = atoms coordination no = 4 (for FCC)Molar mass (M) = 195.8 g/molAvogadro's constant (NA) = 6.022 × 10²³ /mola = edge length

For face-centered cubic FFC;

The edge length  [tex]\mathbf{a =2 \sqrt{2}\times r }[/tex]

[tex]\mathbf{a =2 \sqrt{2}\times 198 \ pm }[/tex]

[tex]\mathbf{a =560.0285 \ pm }[/tex]

a = 5.60 × 10⁻⁸ cm

Replacing it into the previous equation, we have:

[tex]\mathbf{\rho = \dfrac{4 \times 195.8}{6.022 \times 10^{23} \times( 5.60 \times 10^{-8} )^3}}[/tex]

[tex]\mathbf{\rho = 7.40\ g/cm^3 }[/tex]

Learn more about face-centered cubic arrangement here:

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Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced.

_______ → Ba(ClO)2 + H2O(l)

Answers

Answer:

2HClO(aq) + Ba(OH)₂(aq) →  Ba(ClO)₂(aq) + 2H₂O(l)

Explanation:

The reaction corresponds to a neutralization reaction between an acid and a base, as follows:

2HClO(aq) + Ba(OH)₂(aq)  →  Ba(ClO)₂(aq) + 2H₂O(l)            

From the equation above we have that the acid HClO reacts with the base Ba(OH)₂ to obtain a salt Ba(ClO)₂ and water.

In the balanced reaction, we have that 2 moles of HClO react with 1 mol of Ba(OH)₂ to produce 1 mol of Ba(ClO)₂ and 2 moles of water.

I hope it helps you!    

Assume that you are provided with the following materials:
• Strips of metallic zinc, metallic copper, metallic iron
• 1M aqueous solutions of ZnSO4, CuSO4, FeSO4, and aqueous iodine(I2)
• Other required materials to create Voltaic cells such as beakers, porous containers, graphite rods, a voltmeter, and a few wires with alligator clips.
In this modified version of the lab, after thoroughly studying the lab hand out and watching the videos,identify 4 different combinations of Voltaic cells that are possible to be created with the above materials.For each cell created, include the following details.
A) Which electrode was the anode,and which was the Cathode?
B) The anode and cathode half reactions.
C) Balanced equation for each cell you propose to construct.
D) Calculated Eocelle Short hand notation (line notation) for each cell (be sure to include the inactive electrode if needed).

Answers

Answer:

See explanation

Explanation:

First voltaic cell;

Zn(s)|Zn^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Zinc

Cathode;

Copper

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Zn(s) + Cu^2+(aq) -----> Zn^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.76) =1.1 V

Second voltaic cell;

Zn(s)|Zn^2+(aq)||Fe^2+(aq)|Fe(s)

Anode;

Zinc

Cathode;

Iron

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Fe^2+(aq) +2e -----> Fe(s)

Overall; Zn(s) + Fe^2+(aq) -----> Zn^2+(aq) + Fe(s)

E°cell = (-0.44) -(-0.76) = 0.32 V

Third voltaic cell;

Fe(s)|Fe^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Iron

Cathode;

Copper

Oxidation half equation;

Fe(s)------> Fe^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Fe(s) + Cu^2+(aq) -----> Fe^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.44) = 0.78 V

Fourth voltaic cell

Cu(s)|Cu^2+(aq)||I2(aq)|C(s)|I^-(aq)

Anode;

Copper

Cathode;

Graphite rod

Oxidation half equation;

Cu(s)------> Cu^2+(aq) + 2e

Reduction half equation;

I2(aq) +2e -----> 2I^-(aq)

Overall; Cu(s) + I2(aq) -----> Cu^2+(aq) + 2I^-(aq)

E°cell = 0.54 -0.34 = 0.20 V

place the following substances in Order of decreasing boiling point H20 N2 CO

Answers

Answer:

-195.8º < -191.5º < 100º

Explanation:

Water, or H20, starts boiling at 100ºC.

Nitrogen, or N2, starts boiling at -195.8ºC.

Carbon monoxide, or C0, starts boiling at -191.5ºC.

When we place these in order from decreasing boiling point:

-195.8º goes first, then -191.5º, and 100º goes last.

Answer:

therefore, N2, CO, H20

Decreasing boiling point

Explanation:

the bond existing in H2O is hydrogen bond

bond existing in N2 is covalent bond, force existing is dipole-dipole-interaction

bond existing in CO is covalent bond , force existing between is induced -dipole- induced dipole-interaction

hydrogen bond is the strongest , followed by dipole-dipole-interaction and induced -dipole- induced dipole-interaction

the stronger the bond , the higher the boiling point

therefore, N2, CO, H20

-------------------------------------->

Decreasing boiling point

Consider these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)|Cu(s) Ag+(aq)|Ag(s) -0.40 V -0.76 V ‑0.25 V +0.34 V +0.80 V Based on the data above, which species is the best reducing agent?

Answers

Answer:

The best reducing agent is Zn(s)

Explanation:

A reducing agent must to be able to reduce another compound, by oxidizing itself. Consequently, the oxidation potential must be high. The oxidation potential of a compound is the reduction potential of the same compound  with the opposite charge. Given the reduction potentials, the best reducing agent will be the compound with the most negative reduction potential. Among the following reduction potentials:

Cd₂⁺(aq)|Cd(s) ⇒ -0.40 V

Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

Ni²⁺(aq)|Ni(s) ⇒‑0.25 V

Cu²⁺(aq)|Cu(s) ⇒ +0.34 V

Ag⁺(aq)|Ag(s) ⇒ +0.80 V

The most negative is Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

From this, the most reducing agent is Zn. Zn(s) is oxidized to Zn²⁺ ions with the highest oxidation potential (0.76 V).

Im really confused and select all that apply questions scare me.

Answers

Answer:

The 3rd one

Explanation:

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