what will be the ph change when 20.0 ml of 0.100 m naoh is added to 80.0 ml of a buffer solution consisting of 0.166 m nh3 and 0.186 m nh4cl? (assume that there is no change in total volume when the two solutions mix.)

The volume of the solution is 1.84 × [tex]10^{4}[/tex] L.

The formula used to get the molarity of the solution is used to determine the volume of the solution:

Molarity= [tex]\frac{Mass of the solute}{molar mass of solute * Volume of solution(in L)}[/tex]

We are given:

Molarity of solution = 8.75 × [tex]10^{-5}[/tex] M

Given the mass of silver (II) oxide = 200 g

Molar mass of silver (II) oxide = 124 g/mol

Put the values in the formula:

8.75 × [tex]10^{-5}[/tex][tex]10^{-5}[/tex] = [tex]\frac{200}{124* Volume}[/tex]

Volume= 1.84 × [tex]10^{4}[/tex] M

A chemical species' concentration in a solution, specifically the amount of a solute per unit volume of solution, is measured by its molar concentration. The most used molarity unit in chemistry is the number of moles per liter, denoted by the unit symbol mol/L or mol/dm3 in SI units.

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The adding of an acid or base to a buffer seems to have no effect on the pH of the buffer. In contrast, going to add acid or base to unbuffered water drastically changes the pH.

Any hydrogen-containing substance skilled of making a donation a proton (hydrogen ion) to that other substance is defined as an acid. A base is a compound or ion that really can accept an acid's hydrogen ion. The sour flavours of weak acids is generally described by the contaminant that emits hydrogen ions in water and formation salts by incorporating with these metals. Acids have a bitter aftertaste and cause certain dyes to turn red. buffer is an aqueous solution that withstands adjustments in pH upon on the addition of either an acid or a base". Furthermore, adding water to a buffer or going to allow it to evaporate from of the buffer has no significant effect just on pH of the buffer.

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Ammonium nitrite, NH4NO2, will decompose to yield nitrogen gas and water Vapor by the following equation:

NH4NO2(s)--->2H2O(g)+N2(g)

A decomposition reaction can be defined as a chemical reaction in which one reactant breaks down into two or more products. As per law of conservation of mass, the mass of your initial substances (reactants) will be the same as the mass of the substances that you get after the reaction has occurred (products). The mass will stay the same because the number of each kind of atom stays the same. The mass will increase because a new kind of molecule is formed. The principle is that the mass of matter, in a closed system, will always be the same no matter what type of change happens to the matter. Whether it's a change in state, or dissolving, or a chemical reaction, or any combination of these, the amount of mass will not change.

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The formal charge on phosphorus in a lewis structure for the phosphate ion that satisfies the octet rule is 0.

What is a Lewis structure?

All valence electrons are represented by Lewis structures, which are structural formulas for molecules and polyatomic ions. These structural formulas are commonly referred to as Lewis dot structures since valence electrons are frequently shown as dots.

Why is Lewis structure used?

Chemical bonds and atomic structures are examined and understood using Lewis structures. The type of bonds created between atoms using valence electrons or/and lone pairs, as well as the number of bonds an atom can or will form with other atoms, can all be determined using Lewis dot diagrams.

Formal charge= no. of valence electrons - no. of non bonding valence electrons- [tex]\frac{total no. of bonded electrons }{2}[/tex]    

Formal charge of P= 5-0-[tex]\frac{10}{2}[/tex] = 0

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Answer: The answer is false

Explanation:

The nickel has a face-centered cubic (fcc) structure and has a density of 8.90 g/cm3. its atomic radius is 1.36 × 10⁻⁸ cm.

given that :

density = 8.90 g/ cm³

the density is given as :

density = mass / volume

no. of atoms = 8 (1/8) + 6(1/2)

volume = (r ×  8 (1/8))³

mass = 4 atoms ×  mol / 6.022 × 10²³ atoms × 58.68 g /mol

density = mass / volume

8.90 g/ cm³ = (4 atoms ×  mol / 6.022 × 10²³ atoms × 58.68 g /mol ) /  (r ×  8 (1/8))³

r = 1.36 × 10⁻⁸ cm

Thus, the atomic radius is  1.36 × 10⁻⁸ cm.

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A brittle white crystalline solid  reacts with when added to water is Quartz. It is a metamorphic solid.

Quartz is the most abundant silica mineral. Pure Quartz is colorless and transparent. It occurs in most igneous and practically all metamorphic and sedimentary rocks. It is used as a component of numerous industrial materials. Silicon (Si) has the atomic number 14 and is closely related to carbon. It is a relatively inert metalloid. Silicon is often used for microchips, glass, cement, and pottery. Silica is the most abundant mineral found in the crust of the earth. One of the most common uses of silica quarts is the manufacturer of glass. Quartz is the second most abundant mineral in the Earth's crust. Its chemical name is SiO2.

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The given double displacement reaction can be balanced as written below:

[tex]\rm 3CaCl_{2} + 2Na_{3}PO_{4} \rightarrow Ca_{3}PO_{4} + 6 NaCl \\[/tex]

Displacement reactions are those in which one or two groups are replaced to form the new products. There are both single displacement reaction and double double displacement reactions.

In single displacement reactions, only one reactant will be replaced in the reaction whereas in double displacement reactions, two groups from the reactants are exchanged each other.

In the given reaction, the phosphate group is replaced to Ca and the Cl is group is shifted to Na metal as written in the chemical equation.

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There are two moles of oxygen in cassiterite (tin ore), SnO2, for every mole of tin. As a result, if we have 13 moles of tin, we should have 13 * 2 moles of oxygen. This results in 26 moles of oxygen.

Cassiterite (SnO2) is the most essential tin ore, and it is frequently located in granite veins, granite pegmatites, and greisen. The name is derived from the Greek kassiteros, which means tin.

Cassiterite is a tin oxide mineral with the chemical formula SnO2. It is the primary significant source of tin, accounting for the majority of the world's supply. Primary cassiterite is found in trace amounts in igneous and metamorphic rocks all over the world. It is a mineral that can be found in soils and sediments. Cassiterite is more resistant to deterioration than many other minerals, so it is found in stream and shoreline sediments. Colors include black, brownish black, reddish brown, brown red, yellow, gray, and white.

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Nonmetal oxides form acid solutions. SO2, Cl2O, and N2O5 are acid solutions.

A chemical that offers off hydrogen ions in water and paperwork salts through combining with positive metals. Acids have a sour flavor and turn positive dyes purple. a few acids made by using the body, such as gastric acid, can assist organs work the way they must. An example of an acid is hydrochloric acid.

An acidic solution has a high attention of hydrogen ions, H +start superscript, plus, stop superscript, greater than that of pure water. An acidic solution is a liquid combination that happens when hydrogen ions are launched while mixed with water. This definition is known as the Brønsted-Lowry theory: acids provide hydrogen protons, at the same time as bases "accept" hydrogen protons. some answers are more acidic than others.

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When total ammonium ion is 50% dissociated, The pH is 9.25.

Given, the pKₐ of ammonium ion (NH₄⁺) is 9.25.

The dissociation of NH₄⁺ to ammonia (NH₃) and H⁺ in aqueous solution is represented below.

It is stated that the ammonium ion is 50% dissociated in the solution. Therefore the concentration of each species at that instant [if started with 1M conc. of NH4+ (aq)] is summarized as follows:

                                              NH4+ (aq) ⇌ NH3 (aq) + H+ (aq)

Initial conc. (in M)                     1                   -                 -

At 50% dissociation 1-0.5, i.e., 0.5          0.5          0.5

The given value of pKₐ immediately reminds us of the form of Henderson-Hasselbalch equation containing pKₐ , i.e.,

pH = pKₐ + log₁₀ [tex]\frac{[salt]}{[acid]}[/tex]  _ _ _(i)

But, NH₄⁺ (aq) exists as the conjugate acid form, as well as the salt (ionized) form. Hence, we cannot use equation. (i) for our calculations.

Therefore, we need to convert the above value of Kₐ to the equivalent Kb (for NH₃), corresponding to the reverse equilibrium.

This is achieved by using the relation

Kb = [tex]\frac{Kw}{Ka}[/tex]

or,  -log₁₀ Kb = -log₁₀ Kw + log₁₀ Ka

or,  pKb = pKw - pKa = 14 - 9.25 = 4.75

where, pKw = 1 x 10⁻¹⁴ (at 298 K).

Therefore, pKb of ammonia (NH₃) = 4.75

Now, we need to use the form of Henderson-Hasselbalch equation which uses Kb; which is in fact

pOH = pKb + log₁₀ [tex]\frac{[salt]}{[base]}[/tex]  _ _ _(ii)

where the salt is NH₄⁺, and the base is NH₃. Further, we know that

Kw = [H⁺][OH⁻]  or,  pOH + pH = pKw = 14    or,   pOH = 14 - pH

Substituting this relation in eq. (ii) gives

14 - pH = pKb + log₁₀ [tex]\frac{[NH4+]}{[NH3]}[/tex]

or, pH = 14 - pKb — log₁₀ [tex]\frac{[NH4+]}{[NH3]}[/tex]

As calculated, pKb = 4.75, [NH₄⁺] = 0.50 M, while [NH₃] = 0.50 M, assuming we start with a conc. of 1M NH₄⁺. Hence,

pH = 14 – 4.75 – log₁₀ [tex]\frac{0.50}{0.50}[/tex]

     = 9.25 - log₁₀ ( 1 )

     = 9.25 - 0

pH = 9.25

Hence, the pH of a solution consisting of 50% NH₃ and 50% NH₄⁺ will be equal to 9.25.

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Methyl esters are created when carboxylic acids and diazomethane interact. Diazomethane is used to create methyl esters and has a high degree of reactivity.

Diazomethane reacts swiftly and extremely effectively, producing just N2 as a byproduct, making it an appealing alkylating agent for carboxylic and phenols (Black, 1983). As it responds, its inherent yellow color releases, automatically indicating the status of the reaction. Methyl esters are created when carboxylic acids and diazomethane interact. Diazomethane is created in-situ and then interacted with the carboxyl group right away to create the methyl ester due to its high reactivity. Diazomethane has mostly been used to transform carboxylic acids into esters (diazoalkales) that may be examined using GC/MS or HPLC-MS. In etherate solutions, methyl esters can be produced at room temperature quickly, thoroughly, and quantitatively.

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a. hcl, hno3, hf, hclo4 b. h2so4  list contains only strong acids.

Chloric acid, hydrochloric acid, hydrochloric acid, hydroiodic acid, nitric acid, perchloric acid, and sulfuric acid are the 7 main acids. These are strong acids since they can completely dissociate in water. A strong acid is described as an acetone that completely disintegrates when added to water. Because the hydrochloric acid inside the preceding example donates every one of its protons to the remedy and totally dissolves, it is classified as a strong acid.

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SF6 molecular geometry will be octahedral because if we look at the structure sulphur hexafluoride has a central sulphur atom around which12 electrons or 6 electron pairs are present and there are no lone pairs.

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The given equation is a double displacement reaction. It can be balanced as follows:

[tex]\rm 2HI + Rb_{2}S \rightarrow H_{2}S + RbI_{2}[/tex]

Displacement reaction is a type of reaction in which one or two group from the reactants displaces by other groups. There are both single displacement and double displacement.

In single displacement reaction, only one group is displaced. Whereas, in double displacement reactions, two groups are displaced each other between reactants.

In the given reaction, the iodine atom and sulphide group are displacing as written in the equation.

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An ion is an atom with an unbalanced ratio of protons to electrons. Atoms or molecules having associated net charges greater than zero are referred to as "ions."

a charged molecule or atom is referred to as an ion. It charges up or down depending on whether one or more electrons are gained or lost. Because of this, it can have a positive or negative charge. Consequently, an ion becomes charged when there is an imbalance between the proportion of positively charged protons to negatively charged electrons. Ions can be categorised into one of two major types. Cations and anions are what they are.A superscript with a plus sign and the number before the plus sign is applied to the chemical formula to represent the symbol for a cation.Anions are represented similarly to cations by the charge number followed by a negative sign.Another subatomic particle with a positive electrical charge is the proton. They are present in the atom's nucleus.

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Molecular compounds are termed by using the stem of the first element's name plus the suffix -ide, followed by the second element. Numerical prefixes are used to specify the number of atoms in a molecule.

The IUPAC defines a common name as one that clearly identifies a chemical but does not adhere to the current systematic naming convention. Acetone, which bears the scientific term, serves as an illustration of a common name. 2-propanone

A chemical is any substance whose composition is known. A chemical always consists of the same "substance," to put it another way. Water is one of the substances found in nature.

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The pH of acid is between 0-7 on pH scale while for base pH range is from 7-14. Therefore, the pH of this buffer is  5.14. pH is a unitless quantity.

pH is a measurement of amount of hydronium ion H₃O⁺ in a given sample. More the value of hydronium ion concentration, more will be the solution acidic.

On subtracting pH from 14, we get pOH which measures the concentration of hydroxide ion in a given solution. pH depend on the temperature. At room temperature pH scale is between 0 to 14. pH of neutral solution is 7.

0.18 M =NH₃

0.27 M= NH₄Cl.

Kb of NH₃ = 1.8 × 10⁻⁵

pKb = - log (kb)

      = - log (1.8 × 10⁻⁵)

       = 4.74

Using Henderson equation

pH = Pkb +ln [ NH₄Cl ]/ [NH₃]

    = 4.74 + ln (0.27 /0.18)

    = 5.14

Therefore, the pH of this buffer is 5.14.

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The periodic properties of elements are directly related to the energy levels of the atoms of the elements.

The correct option is C.

The periodicity of elements in the periodic table is the regular variation of the properties of the elements in the periodic table both down the group and across the periodic.

The properties of elements that show periodicity include;

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The principle quantum number(n) for this atom is 5

The position in an atom's shells and the size of an electron orbital are described by the primary quantum number, which is the most significant. The quantum number connected to the angular momentum of an atomic electron is called the azimuthal quantum number.

The energy of the electron in a hydrogen atom [tex]E_{n} = -0.544eV[/tex]

For hydrogen, Z = 1

The principal quantum number for [tex]n[/tex] for this atom is calculated by for this atom is determined using Bohr's atomic model,

So that [tex]E_{n} = \frac{-13.6(Z)^{2}}{n^{2}}eVatom^{-1}[/tex]

Where [tex]n[/tex] is the principal quantum number, [tex]E[/tex] is the energy, and [tex]Z[/tex] is the atomic number The values are substituted,

=> [tex]-0.544eV = -\frac{13.6(1)^{2}}{n^{2}} eVatom^{-1}[/tex]

[tex]n^{2} = -\frac{13.6}{-0.544} \\n^{2} = 25\\n = 5[/tex]

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One grain of calcium carbonate, or 64.8 milligrams, is dissolved in one US gallon of water to represent one grain per gallon (gpg), a measure of water hardness (3.785412 L).

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3.74 moles of Na will be produced after the decomposition of Na₂O.

The decomposition reaction of Na2 is as follows:

2Na₂o → 4Na + o₂

Given, moles of Na₂o = 1.87

From stoichiometric coefficient 2 in Na₂o, after decomposition we get coefficient as 4 of Na. That means the yield of Na is double the reactant.

Hence, the moles of Na after decomposition= 2 x 1.87 = 3.74 moles

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The epicardial fat pad . a. can be mistaken for a pericardial effusion b. appears heteroechoic and moves with the heart.

It is the posterior fat pad that is a sign that indicates a pathology when one looks at an x-ray. When a crescent fat is observed in the x-ray, it indicates there is an elbow joint effusion since normally the posterior fat cannot be seen from the x-ray.

In radiography, X-rays are used to view inner parts of the body for medical observation, analysis and to know the treatment procedure to adopt.

When a non visible posterior fat pad on a well-exposed, then it generally suggests a negative study for injury. This means that the features observed are unrelated to any type of injury. This eliminates option c.

Therefore, only option a and b are correct that the epicardial fat pad . a. can be mistaken for a pericardial effusion b. appears heteroechoic and moves with the heart.

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Aufbau's principle states that an electron in an atom is filled according to the energy of orbitals, orbital with minimum energy is first filled, and so on.

so the order of filling of electrons in orbitals are 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p 8s.

so, the 4f subshell is filled after the complete filling of electrons in 6s.

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The potential energy between the nuclei is minimized and the orbital shells overlap.

We know that a covalent bond is the kind of bond that is formed when there is the combination of two atoms when there is the overlap of the orbitals of the two atoms. In the case of the hydrogen atoms, we can say that there is a bond as we notice that the two atomic orbitals have become overlapped on each other.

Let us note that when the two atoms are still far from each other, the potential energy between the atoms is high and as such the atoms of the element would tend to repel each other.

As the two atoms begin to approach each other, the repulsion between the nuclei of the elements is seen to become minimized and the bond is now seen to be formed as the atomic orbitals become overlapped.

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4.447 x10^13 J  is the nuclear binding energy per mole if the mass defect of a certain isotope is 0.1172 u per atom or 0.1172 g per mol? express your answer in joules.

BE = dleta mc^2.

Given that, delta m = mass defect = 0.4941 g per mol = 0.4941/1000 kg/mol c = 3x10^8 m/s

BE = ( 0.4941/1000) x (3x10^8)^2= 4.4469 x10^13

    = 4.447 x10^13 J

Nuclear binding energy is energy required to completely separate an atomic nucleus in with its constituting protons and neutrons, or the energy freed by combining protons and neutrons into a single nucleus. Isotopes are atoms that have the same number of protons but number of protons. They have nearly identical chemical composition but differ in volume and thus in physicochemical parameters.

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The heat of reaction for the combustion of a mole of C₆NH₂ in this calorimeter is  - 1.30 × 10³ kJ/mol.

The reaction is given as :

2CH6N2(l) + 5O2(g) ----> 2N2(g) + 2CO2(g) + 6H2O(l)

given that :

initial temperature = 25 °C

final temperature = 39.05 °C

heat capacity of the calorimeter = 7.794 kJ/°C

mass of methylhydrazine = 4 g

molar mass of methylhydrazine  = 46.1 g/mol

the heat of reaction Q = - C ΔT

                                       = - 7.794 × ( 39.05 - 25)

                                       = - 113.0 kJ

the heat of reaction of a mole = - (113.0 kJ / 4) × 46.1

                                                  = - 1.30 × 10³ kJ/mol

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The reaction that can light the thermite is the combination of methane and oxygen. Option C

There is an ignition reaction when we burn a substance in another substance. Now, we know that an exothermic reaction refers to the kind of reaction hat is able to produce heat.

Since the exothermic reaction can be able to produce heat, this is the reaction that we can use to light the reaction between the magnesium and the oxygen so that we can be able to light the thermite.

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Answer: The reaction with caesium is more vigourus.

The reaction with caesium produces different compund.

Explanation:

Cold water and cesium react to produce hydrogen gas and a mixture of cesium and hydroxide ions as byproducts.

Sp[tex]3[/tex] hybridization of a molecule with two lone pairs is present. This molecule's geometry is determined by its electron pair structure. If more than one bond angle is possible, separate each one with a space.

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