The volume occupied by 0.108 mol of helium gas at a pressure of 0.92 atm and a temperature of 313 K is 2.3 L.
What is the volume of gas?The gas laws involve the relationship between the pressure, volume, and temperature of a gas. The ideal gas law can be used to determine the volume of gas that a certain amount of substance occupies at a particular pressure and temperature. The ideal gas law equation is:
PV = nRT
where, P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin (K).
To determine the volume of helium gas that is occupying 0.108 moles at 0.92 atm and 313 K, we need to rearrange the ideal gas law equation to solve for V:
V = (nRT)/P
Substituting the values given, we have:
V = (0.108 mol)(0.08206 L atm/mol K)(313 K)/(0.92 atm)
V = 2.28 L
The volume of gas to two significant figures, the volume is 2.3 L.
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buffers are made from weak conjugate acid-base pairs. in part 1 of this experiment, a solution of weak acid is mixed with another solution of weak acid to which the strong base naoh has been added.
Buffers are made from weak conjugate acid-base pairs. In part 1 of this experiment, a solution of weak acid is mixed with another solution of weak acid to which the strong base NaOH has been added.
What is a buffer?
A buffer is a solution that can resist changes in pH when acid or base is added. They are used to keep the pH of solutions stable in various chemical and biological systems, including industrial processes, drugs, and the human body. A buffer is a mixture of a weak acid and its conjugate base or a weak base and its conjugate acid.The following are the features of a buffer:It is a solution that resists changes in pH.It consists of a weak acid and its corresponding base.The buffering effect is maximized when the ratio of weak acid to its corresponding base is 1:1.A buffer resists pH changes in either direction, and it has a maximum buffering capacity when pH is within one unit of its pKa. The buffering capacity of the solution is increased by increasing the buffer concentration.
A weak acid is one that only partially dissociates in water to produce hydrogen ions (H+) and anions. Its conjugate base is the species that results from the removal of a proton from the acid. As an example, ammonia (NH3) is a weak base, and its conjugate acid is ammonium (NH4+). The reverse reaction produces the acid and base when the acid is added to water.
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what distinguishes a saturated solution from a supersaturated solution?
The main difference between a saturated solution and a supersaturated solution is concentration of the solute.
A saturated solution contains the maximum amount of solute that can be dissolved under the given conditions, while a supersaturated solution contains more solute than is normally possible. A saturated solution contains the maximum amount of solute that can be dissolved in a given solvent at a specific temperature and pressure. In a saturated solution, the concentration of solute is in equilibrium with the concentration of undissolved solute, which is in dynamic equilibrium with the dissolved solute. A supersaturated solution, on the other hand, is a solution that contains more solute than is normally possible to dissolve in the solvent under the given conditions.
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The chemical formula Al2SiO5 can form any of these three minerals, given different combinations of temperature and pressure conditions: a. marble, quartzite, and hornfels b. quartz, feldspar, and mica c. hematite, magnetite, and goethite d. andalusite, kyanite, and sillimanite e. granite, sandstone, and marble
The chemical formula [tex]Al_2SiO_5[/tex] can form the three minerals, andalusite, kyanite, and sillimanite under different combinations of temperature and pressure conditions. Option D is correct.
What are minerals? Minerals are solid inorganic materials with a specific chemical formula and crystalline structure. Most minerals are naturally occurring substances. Some minerals are silicates, while others are carbonates, oxides, sulfides, or halides, among other groups.What is the chemical formula? The chemical formula refers to the formula that represents the atoms in a compound's molecule. The chemical formula of a mineral is a shorthand description of the relative proportions of a mineral's primary chemical constituents. [tex]Al_2SiO_5[/tex] is a chemical formula. It means that for every two aluminum atoms, there is one silicon atom, and five oxygen atoms in a mineral.What is the significance of temperature and pressure in mineral formation? Temperature and pressure are essential factors in mineral formation. A mineral can only form under certain temperature and pressure conditions. Because the temperature and pressure conditions vary depending on the type of mineral, each mineral has unique characteristics. The pressure and temperature requirements for the formation of some minerals are so unique that they can only form under extreme conditions.The chemical formula [tex]Al_2SiO_5[/tex] can form andalusite, kyanite, and sillimanite under different combinations of temperature and pressure conditions. Hence, option D is correct.Learn more about the chemical formula: https://brainly.com/question/11574373
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which of the following could be added to a solution of sodium acetate to produce a buffer?group of answer choiceshydrochloric acid onlypotassium acetate onlyacetic acid or hydrochloric acidacetic acid only
Adding either hydrochloric acid or acetic acid to a solution of sodium acetate can produce a buffer. The chemical equation for the reaction between sodium acetate and hydrochloric acid is NaAc + HCl → NaCl + HAc, and for the reaction between sodium acetate and acetic acid is NaAc + HAc → NaCl + AcOH.
Sodium acetate can be used to make buffer solutions. A buffer is a solution that resists changes in pH when an acid or base is added. The two most important components of a buffer are a weak acid and its corresponding conjugate base. Acetic acid and sodium acetate are two such components that can be used to create a buffer. As a result, the answer to the question is acetic acid. Hence, option (c) acetic acid or hydrochloric acid is correct. Therefore, adding acetic acid to a sodium acetate solution would produce a buffer. The buffer solution can withstand pH changes when hydrochloric acid is added. Since hydrochloric acid is a strong acid, it ionizes completely in the solution and lowers the pH significantly. Acetic acid is a weak acid, on the other hand. It ionizes partially in solution, resulting in a small decrease in pH. When hydrochloric acid is added to the acetic acid-sodium acetate buffer, the additional hydrogen ions react with the buffer's acetate ion to form more acetic acid, which consumes the hydrogen ions and prevents a drastic decrease in pH. This is how a buffer works.
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A 50.0 mL sample of a 1.00 M solution of a diprotic acid H_2A (K_a1 = 1.0 times 10^-6 and Ka_2 = 10^-10) is titrated with 2.00 M NaOH. What is the minimum volume of 2.00 M NaOH needed to reach a ph of 10.00? (A) 12.5 mL (B) 37.5 m (C) 25.0 m (D) 50.0 mL
The correct option is 'A' 12.5 mL of the minimum volume of 2.00 M NaOH needed to reach a pH of 10.00.
To reach a pH of 10.00, what is the minimum volume of 2.00 M NaOH needed to titrate 50.0 mL of a 1.00 M solution of a diprotic acid [tex]H_2A[/tex], where [tex]Ka_1[/tex] = 1.0 × [tex]10^-^6[/tex] and [tex]Ka_2[/tex] = [tex]10^-^1^0[/tex].
The reaction can be written as:
[tex]H_2A[/tex](aq) + 2 NaOH(aq) → [tex]Na_2A[/tex](aq) + 2 [tex]H_2O[/tex]
(l)In this diprotic acid, there are two stages of dissociation:
Therefore, the dissociation constant can be calculated as follows:
Ka1 = [H+][HA-] / [[tex]H_2A[/tex]]
= 1.0 × [tex]10^-^6[/tex]
Ka2 = [H+][[tex]A^2^-[/tex]] / [HA-]
= [tex]10^-^1^0[/tex]
The number of moles of the [tex]H_2A[/tex] solution = 50.0 mL * 1.00 M = 0.050 moles.
Since NaOH is a strong base, the number of moles of OH- ions in 1.00 M solution = 2 * 1.00 = 2.00 M.
The total number of moles of OH- ions that can react with 0.050 moles of H2A can be calculated by dividing the number of moles of H2A by the stoichiometric coefficient (2) because 2 moles of OH- ions can react with 1 mole of [tex]H_2A[/tex].
0.050 / 2 = 0.025 moles of OH- ions, which are available to react.
To react completely, 0.025 moles of OH- ions require 0.025 * 50 = 1.25 mL of 2.00 M NaOH.
Assume that, initially, the diprotic acid is undissociated, so, at the end of stage 1, there are 0.025 moles of [tex]H_2A[/tex] and 0.025 moles of H+ ions.
Using the Ka1 value, it can be calculated that:
[H+][HA-] / [[tex]H_2A[/tex]] = 1.0 × [tex]10^-^6[/tex]
[H+][0.025] / [0.025] = 1.0 × [tex]10^-^6[/tex]
[H+] = [tex]10^-^8[/tex]
The number of moles of NaOH required to react with [tex]H^+[/tex] ions can be calculated by dividing the concentration of NaOH by the volume of the solution.
2.00 M NaOH * V = [tex]10^-^8[/tex] moles of [tex]H^+[/tex] ions
V = 5.00 × [tex]10^-^9[/tex]mL
This is the minimum amount of NaOH required to react with [tex]H^+[/tex] ions.
So, the total amount of NaOH required to reach a pH of 10.00 is 1.25 mL + 5.00 × [tex]10^-^9[/tex] mL = 1.25 mL
Therefore, the minimum volume of 2.00 M NaOH required to reach a pH of 10.00 is 12.5 mL.
[tex]H^+[/tex]
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what is the ph at the equivalence point in the titration of a 23.4 ml sample of a 0.427 m aqueous nitrous acid solution with a 0.494 m aqueous potassium hydroxide solution?
The pH at the equivalence point in the titration of a 23.4 mL sample of a 0.427 M aqueous nitrous acid solution with a 0.494 M aqueous potassium hydroxide solution is 7.00.
What is titration?Titration is a chemical analysis method that measures the amount of a chemical compound in a solution by using a standard solution (a solution of known concentration).
Titration can be used to determine the concentration of an unknown solution, the quantity of a particular substance in a sample, or the identity of a substance. Titration is frequently utilized in chemistry labs to test acid or base solutions' strength.
Titration calculations involve the use of formulas that relate the concentration of the standard solution to the concentration of the unknown solution. Acid-base titration, which measures the concentration of an acidic or basic solution, is one of the most popular types of titration.
The pH at the equivalence point in the titration of a 23.4 mL sample of a 0.427 M aqueous nitrous acid solution with a 0.494 M aqueous potassium hydroxide solution is 7.00 because nitrous acid (HNO2) is a weak acid with a Ka value of 4.5 x 10-4. At the equivalence point, the quantity of moles of the potassium hydroxide solution added is equal to the quantity of moles of the nitrous acid solution. The pH of the solution is determined by the salt produced during the titration's neutralization reaction.
The salt produced during this titration is potassium nitrite (KNO2), which is a salt of a strong base and a weak acid. When dissolved in water, potassium nitrite undergoes hydrolysis and produces a solution with a pH of about 7.00. As a result, at the equivalence point, the pH of the solution is 7.00.
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what is the theoretical absolute minimum number of molar equivalents one could use in a sodium borohydride reduction of a ketone like camphor?
The theoretical absolute minimum number of molar equivalents for a sodium borohydride reduction of a ketone like camphor is 1.
This is because sodium borohydride reduces ketones by forming an intermediate complex with the ketone, which then undergoes a boron-carbon bond cleavage to form an alkoxide and hydride ion. The hydride ion can then be abstracted from the alkoxide to form the alcohol product. Therefore, one equivalent of sodium borohydride is necessary to reduce one equivalent of ketone.
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How much potassium chloride will dissolve in 50 grams of water at 50°C?
The amount of potassium chloride that will dissolve in 50 grams of water at 50°C depends on the solubility of the salt at that temperature. The solubility of potassium chloride in water at 50°C is approximately 42 grams per 100 grams of water. Therefore, about 21 grams of potassium chloride will dissolve in 50 grams of water at 50°C.
water, h2o, and hexane, c6h14, are commonly used as laboratory solvents because they have different physical properties and are able to dissolve different types of solutes. 32. explain, in terms of the molecular polarity, why hexane is nearly insoluble in water
Hexane, C6H14, is a non-polar molecule, meaning that its electric charge is evenly distributed. On the other hand, water (H2O) is a polar molecule, with an uneven distribution of electric charge. Since the two molecules have opposite polarities, they do not interact with one another, leading to the nearly insoluble nature of hexane in water.
When explaining, in terms of the molecular polarity, why hexane is nearly insoluble in water, it's crucial to consider the nature of the molecules, their polarity, and their ability to interact with one another.
What is hexane?Hexane, with the chemical formula C6H14, is a saturated hydrocarbon with a boiling point of 69°C. It's an odorless liquid that's colorless, and it's frequently utilized as a solvent in the laboratory. When hexane molecules are considered, they are all nonpolar molecules, meaning that the electrons are distributed uniformly among the atoms, and there is no permanent charge on any part of the molecule.
What is water?Water (H2O) is a polar molecule with a partial positive charge on its hydrogen atoms and a partial negative charge on its oxygen atoms. It's a very common solvent in laboratories because it's extremely polar and can dissolve a wide range of substances. It's because of the difference in the polarity of water and hexane molecules that hexane is nearly insoluble in water.
The reason hexane is insoluble in water is that water is an incredibly polar substance, while hexane is a nonpolar substance. The polar water molecules are attracted to other polar substances and repelled by nonpolar substances like hexane, which has no charge to attract polar water molecules.
Therefore, as a result, hexane does not dissolve in water and is nearly insoluble.
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The specific heat capacity of water is 1.00 cal/g °C. 700.00 cal is required to raise the temperature of 25.0g water from 22.0°C to 50°C.
What is the final temperature of the above water sample if 1.00kcal of heat is provided?
When 1.00 kcal of heat is applied, the water sample's final temperature is T = 50.0°C + 40.0°C = 90.0°C.
What does "specific heat" mean?The amount of energy required to raise a substance's temperature is measured in terms of specific heat. It is the amount of energy (measured in joules) required to increase a substance's temperature by one degree Celsius per gram.
We must first determine the water sample's original temperature. The formula is as follows:
Q = mcΔT
Inputting the values provided yields:
700.00 cal = 25.0 g x 1.00 cal/g °C x (50°C - 22.0°C)
When we simplify this equation, we obtain:
ΔT = 700.00 cal / (25.0 g x 1.00 cal/g °C) = 28.0°C
Therefore, the initial temperature of the water sample is 22.0°C + 28.0°C = 50.0°C.
Inputting the values provided yields:
1.00 kcal = 25.0 g x 1.00 cal/g °C x (T - 50.0°C)
When we simplify this equation, we obtain:
T - 50.0°C = 1.00 kcal / (25.0 g x 1.00 cal/g °C) = 40.0°C
Therefore, When 1.00 kcal of heat is applied, the water sample's final temperature is T = 50.0°C + 40.0°C = 90.0°C.
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During _____ , the temperature _____ but the entropy change can be large as molecules _____ their degrees of freedom and motion. Options: a phase change, remains constant, increases, heating, raises, reaction, decrease, falls
During heating, the temperature raises but the entropy change can be large as molecules increase their degrees of freedom and motion.
Entropy is a thermodynamic quantity that measures the disorder or randomness of a system. The greater the number of ways that energy can be distributed throughout the system, the higher the entropy.
Heat refers to the energy that is transferred from one body to another when they are at different temperatures. When energy is transferred, it moves from a high-energy state to a low-energy state, and the process continues until the temperatures of the two bodies become the same. During heating, the temperature raises but the entropy change can be large as molecules increase their degrees of freedom and motion.
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the reaction of magnesium metal with hcl yields hydrogen gas and magnesium chloride. what is the volume, in liters, of the gas formed at 720 torr and 34 oc from 1.30 g of mg in excess hcl? (hint, first write the balanced equation.)
The volume of H₂ gas produced from 1.30 g of Mg in excess HCl is 0.0019 L.
The balanced equation for the reaction of magnesium metal with HCl is:
Mg + 2HCl → MgCl₂ + H₂
The molar mass of Mg is 24.31 g/mol.
The mass of Mg that reacted = 1.30 g
The moles of Mg that reacted = 1.30 g ÷ 24.31 g/mol = 0.0535 mol
According to the balanced equation, 1 mol of Mg reacts with 1 mol of H₂
Therefore, 0.0535 mol of Mg will produce 0.0535 mol of H₂.
Since, the volume of gas produced is proportional to the number of moles of the gas, we can use the ideal gas equation to find the volume of H₂
PV = nRT
Where, P = 720 torr = 720/760 atm (1 atm = 760 torr)
T = 34 + 273 = 307 K
R = 0.0821 L·atm/mol·K
V = n × 0.0821 L·atm/mol·K × 307 K/ 720 torr = 0.0535 mol/ 720 torr × 25.2047 L/molK =0.0019 L
At 720 torr and 34 °C, 0.0535 mol of hydrogen occupies a volume of 0.0019 L.
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How do you write a chemical formula for the following scenario:
Nitric acid is a component of acid rain that forms when gaseous Nitrogen dioxide pollutant reacts with gaseous Oxygen and liquid water to form aqueous Nitric acid?
The balanced chemical formula for the given scenario is 2{\rm NO}_2(g)\ +\ O_2(g)\ +\ 2H_2O(l)\ \rightarrow\ 2H{\rm NO}_3(aq)
To write the chemical formula for the given scenario, it is necessary to balance the chemical reaction equation by following the law of conservation of mass.
Nitric acid is a component of acid rain. Acid rain is caused by air pollution, and it occurs when the nitrogen dioxide pollutant \left({\rm NO}_2\right) reacts with gaseous oxygen \left(O_2\right) and liquid water \left(H_2O\right) to form aqueous nitric acid (HNO3).The balanced chemical equation for this reaction is:
2{\rm NO}_2(g)\ +\ O_2(g)\ +\ 2H_2O(l)\ \rightarrow\ 2H{\rm NO}_3(aq)
The balanced equation states that two molecules of nitrogen dioxide gas react with one molecule of oxygen gas and two molecules of liquid water to produce two molecules of aqueous nitric acid. The coefficients ensure that the equation is balanced according to the law of conservation of mass.
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What are situations that reduce the dissolved oxygen content of water
1. PART A: Which TWO of the following best identify the main ideas of this article?
Fingerprints are still the most accurate way to identify a person.
Blood vessels have the same structure as fingerprints.
Biometric features are slightly different in everyone.
Biometrics is the measurement of life.
A
B.
C.
D.
E.
F.
Biometric technology can help in areas of security, privacy, and health.
Children in West Africa desperately need vaccines.
The statement that best identify the main idea of the article are, A and C
A) Fingerprints are still the most accurate way to identify a person.
C) Biometric features are slightly different in everyone.
What is the article about?The article seems to focus on biometric technology and the different ways it can be used for identification, security, and health purposes.
It explains that fingerprints remain the most accurate way to identify a person, but also discusses the unique features of other biometric identifiers such as facial recognition and blood vessels.
Lastly, the article emphasizes the importance of recognizing that biometric features are unique to each individual.
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Which of the following are the best examples of foods within the protein group that can also increase intake of unsaturated fats? a. Organic 0% fat Greek Yogurt, All Natural raisins, Apples b. Lean chicken, skim milk, sugar-free sodac. Salmon, nuts, seeds, legumes d. Steak, bacon, pepperoni pizza
The best examples of foods within the protein group that can also increase intake of unsaturated fats are salmon, nuts, seeds, legumes. The correct option is (c).
Protein is a vital macro nutrient that is required to build and repair tissues, produce enzymes and hormones, and maintain healthy muscles and bones. Unhealthy fats can increase the risk of heart disease, stroke, and other chronic health problems. A diet that contains a good balance of carbohydrates, protein, and healthy fats is recommended for overall health and well-being. Unsaturated fats are a type of healthy fat that can improve heart health by reducing bad cholesterol levels and increasing good cholesterol levels.
Foods that are high in protein and unsaturated fats are ideal for promoting overall health and wellness. Salmon is a good source of protein and contains omega-3 fatty acids, which are a type of unsaturated fat that can reduce inflammation and improve brain function. Nuts and seeds are high in protein and also contain healthy fats that can help reduce the risk of heart disease and other chronic health problems. Legumes, such as lentils, beans, and chickpeas, are high in protein and fiber and also contain healthy fats that can help improve heart health.In conclusion, salmon, nuts, seeds, and legumes are the best examples of foods within the protein group that can also increase intake of unsaturated fats.
Therefore, Salmon, nuts, seeds, and legumes are the best examples of protein-rich meals that can also enhance unsaturated fat intake. The right option is (c).
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what should you do with unused chemicals? group of answer choices dispose of them as instructed on the safety sheet return to their original containers throw away with regular trash dump them down the sink
The best thing to do with unused chemicals is to dispose of them as instructed on the safety sheet. This may involve returning the chemicals to their original containers or throwing them away with the regular trash. Never dump unused chemicals down the sink, as this could be hazardous to the environment and to your health.
Unused chemicals should be disposed of as instructed on the safety sheet. It is important to dispose of chemicals in a safe and responsible manner to avoid harm to the environment and human health.
What are chemicals?
Chemicals are substances that are made up of molecules, which are made up of atoms. Chemicals can be found in nature or synthesized by humans. Chemicals have a wide range of uses, from pharmaceuticals to household cleaning products.
Why should you dispose of unused chemicals as instructed on the safety sheet?
Unused chemicals can pose a hazard if they are not disposed of correctly. Many chemicals are hazardous and can be dangerous to human health and the environment if they are not disposed of properly. Chemicals that are poured down the drain or thrown in the trash can contaminate the environment and cause harm to animals and humans. Examples of hazardous chemicals are corrosive, flammable, reactive, and toxic. It is essential to follow the safety sheet's instructions on how to dispose of unused chemicals to protect the environment and human health. In addition, it is important to ensure that unused chemicals are not mixed with other chemicals, as this can cause a dangerous reaction.
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Can you explain in terms of Le Chatelier's principle why the concentration of NH3 decreases when the temperature of the equilibrium system increases?
Le Chatelier's principle predicts that when a stress or change is added to a system at equilibrium, the system will adjust in order to counteract the stress or change. The principle can be used to describe the shift in the direction of the chemical equilibrium in response to changes in pressure, temperature, or concentration.
What is Le Chatelier's principle?Le Chatelier's principle states that when the temperature is increased, the equilibrium system will absorb the heat by shifting the equilibrium position in the direction that uses up the heat energy. If heat is a product of the reaction, the equilibrium will shift to the left. If heat is a reactant, the equilibrium will shift to the right.
Here, in the case of the reaction of nitrogen and hydrogen to create ammonia:
N₂(g) + 3H₂(g) ⇌ 2NH₃(g), ∆H = −92 kJ/mol
The reaction produces heat, therefore the reaction is exothermic. An increase in temperature will cause a shift in equilibrium to the left, as the reaction will try to use up the excess heat. This means that the reaction will reduce the amount of NH₃ in the system, leading to a decrease in the concentration of NH₃.
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In an open manometer with an atmospheric pressure of 780 mm Hg, the mercury level in the arm connected to the gas is 45 mm Hg higher than in the arm connected to the atmosphere. What is the pressure of the gas sample? (answer in mm Hg)
The pressure of the gas sample is 825 mm Hg.
How to find the pressure of the gas sample?
In an open manometer, the pressure of the gas sample can be determined by measuring the difference in height of the mercury levels in the two arms of the manometer. The pressure of the gas sample is equal to the difference in height between the two mercury levels, plus the atmospheric pressure.
In this case, the mercury level in the arm connected to the gas is 45 mm Hg higher than in the arm connected to the atmosphere. This means that the pressure of the gas sample is 45 mm Hg higher than the atmospheric pressure.
So, the pressure of the gas sample can be calculated as:
Pressure of gas sample = atmospheric pressure + height difference between the two mercury levels
Pressure of gas sample = 780 mm Hg + 45 mm Hg
Pressure of gas sample = 825 mm Hg
Therefore, the pressure of the gas sample is 825 mm Hg.
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valency of aluminum is 3 give reason
Answer:
The valency of an element refers to the number of electrons an atom can gain, lose or share to attain a stable configuration.
Aluminum (Al) is a metal with an atomic number of 13, which means it has 13 electrons in its neutral state. In its outermost shell, aluminum has three valence electrons.
To attain a stable electronic configuration, aluminum can lose these three valence electrons to become a cation with a 3+ charge (Al3+). By losing these electrons, the outermost shell of the aluminum atom becomes completely filled with eight electrons, which is a stable configuration.
Therefore, the valency of aluminum is 3 because it can lose three electrons to form a stable cation with a 3+ charge.
Explanation:
Answer:
The valency of an element refers to the number of electrons an atom can gain, lose or share to attain a stable configuration.
Aluminum (Al) is a metal with an atomic number of 13, which means it has 13 electrons in its neutral state. In its outermost shell, aluminum has three valence electrons.
To attain a stable electronic configuration, aluminum can lose these three valence electrons to become a cation with a 3+ charge (Al3+). By losing these electrons, the outermost shell of the aluminum atom becomes completely filled with eight electrons, which is a stable configuration.
Therefore, the valency of aluminum is 3 because it can lose three electrons to form a stable cation with a 3+ charge.
Explanation:
Nucleophilicity is a kinetic property. A higher nucleophilicity indicates that the nucleophile will easily donate its electrons to the electrophile and that the reaction will occur at the faster rate. The reaction rate also depends on the nature of the electrophile and solvent. Rank the following reactions from fastest to slowest based on the nucleophilicity of the nucleophile.
a. CH3NH- + CH3--Br → CH3NHCH3 + Br-
b. (CH3)2N- + CH3--Br → (CH3)2NCH3 + Br-
c. H2N- + CH3--Br → CH3NH2 +Br-
select the correct statements regarding a liquid-gas system at equilibrium that is disturbed by adding or removing vapor from the system (at constant temperature). select all that apply. multiple select question. A. adding vapor will cause a temporary increase in vapor pressure. B. adding or removing vapor will result in a new equilibrium vapor pressure. C. when equilibrium is reestablished after a disturbance in a liquid-gas system, the vapor pressure will be the same. D. removing vapor will cause a temporary increase in the rate of condensation.
A liquid-gas system at equilibrium is disturbed by adding or removing vapor from the system (at constant temperature). The correct statements for the vapor pressure regarding this situation are A, B, and D.
A. Adding vapor will cause a temporary increase in vapor pressure: When the vapor is added to the system, the total vapor pressure increases, and the vapor pressure in the system is greater than the original equilibrium vapor pressure until the system re-equilibrates.
B. Adding or removing vapor will result in a new equilibrium vapor pressure: The equilibrium vapor pressure will be affected by the addition or removal of vapor. When the vapor is added or removed, the system must reach a new equilibrium between the vapor and liquid phases before the vapor pressure returns to the original equilibrium value.
D. Removing vapor will cause a temporary increase in the rate of condensation: When the vapor is removed from the system, the total vapor pressure decreases, and the rate of condensation of the liquid phase will increase until the system re-equilibrates.
Statement C. when equilibrium is re-established after a disturbance in a liquid-gas system, the vapor pressure will be the same: is incorrect. When a system is disturbed by adding or removing vapor, the new equilibrium vapor pressure is different from the original equilibrium vapor pressure.
Therefore, the correct statements for the vapor pressure of the system are A, B, and D.
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A student is designing a new insulated drink cup using unconventional materials. They will have an inside and an outside cup with a material from the table in between the cups as insulation.Which material should they use to prevent heat loss?
The best material for insulation in this case would be Styrofoam. Styrofoam is lightweight, strong, and an excellent thermal insulator. It is composed of tiny bubbles of air that are suspended in a matrix of plastic. The air trapped inside the bubbles acts as a thermal barrier, keeping heat out or in, depending on the application.
Its lightweight nature makes it easier to manipulate, while its strength gives it the durability needed to keep a drink hot or cold. Its insulation properties also make it the perfect material for the student's insulated drink cup.
Styrofoam can be cut and shaped easily, making it a great material for use in drink cups. The material is also easy to clean and resistant to water and other liquids, which makes it ideal for frequent use. Additionally, Styrofoam is both affordable and widely available, making it an ideal choice for the student's project.
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Which of the compounds listed below, when added to water, is/are likely to increase the solubility of AgCl? A. Ammonia, B. NH3 Sodium cyanide, C. NaCN Potassium chloride,
D. KCl
AgCl is more likely to dissolve in water when ammonia (NH3) is present. This is due to the fact that ammonia and AgCl may combine to create the water-soluble complex ion, Ag(NH3)2+.
How well does AgCl dissolve in NH3 H2O?At 25°C, the solubility of AgCl in water is 0.0020 g of AgCl per litre of H2OS.
AgCl dissolves in NH3 at a rate of 14.00 g per kilogramme of NH3 when the temperature is 25°C. Due to the production of the soluble stable complex [AgNH32]+, AgCl is more soluble in NH3. Since oxygen is more electronegative than nitrogen, ammonia is less polar than water.
In water or acid, is AgCl soluble?AgCl is well known to be insoluble in water whereas NaCl and KCl are soluble in the pedagogical literature: implementations of Elementary studies of both qualitative and quantitative analysis make this distinction.
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The molecular formula of aspartame, the artificial sweetener marketed as NutraSweet, is C14H18N2O5. A. What is the molar mass of aspartame? b. How many moles of aspartame are present in 1. 00 mg of aspartame? c. How many molecules of aspartame are present in 1. 00 mg of aspartame? d. How many hydrogen atoms are present in 1. 00 mg of aspartame?
For the molecular formula of aspartame, the artificial sweetener marketed as NutraSweet, is [tex]C_{14}H_{18}N_2O_5[/tex],
a. the molar mass of aspartame is 294.30 g/mol.
b. there are 3.40 x [tex]10^{-6}[/tex] moles of aspartame in 1.00 mg of aspartame.
c. there are 2.05 x [tex]10^{18}[/tex] molecules of aspartame in 1.00 mg of aspartame.
d. the total number of hydrogen atoms in 1.00 mg of aspartame is 34 hydrogen atoms.
a. The molar mass of aspartame can be calculated by adding up the atomic masses of all its atoms:
Molar mass of aspartame = (14 x 12.01 g/mol) + (18 x 1.01 g/mol) + (2 x 14.01 g/mol) + (5 x 16.00 g/mol) = 294.30 g/mol
Therefore, the molar mass of aspartame is 294.30 g/mol.
b. The number of moles of aspartame present in 1.00 mg of aspartame can be calculated using the formula:
moles = mass/molar mass
moles = 1.00 mg / 294.30 g/mol = 3.40 x 10^-6 mol
Therefore, there are 3.40 x 10^-6 moles of aspartame in 1.00 mg of aspartame.
c. The number of molecules of aspartame present in 1.00 mg of aspartame can be calculated using Avogadro's number:
number of molecules = moles x Avogadro's number
number of molecules = 3.40 x [tex]10^{-6}[/tex] mol x 6.02 x [tex]10^{23}[/tex] molecules/mol = 2.05 x [tex]10^{18}[/tex] molecules
Therefore, there are 2.05 x 10^18 molecules of aspartame in 1.00 mg of aspartame.
d. The number of hydrogen atoms present in 1.00 mg of aspartame can be calculated as follows:
There are 14 carbon atoms in 1.00 mg of aspartame, and each carbon atom is bonded to two hydrogen atoms. Therefore, there are 28 hydrogen atoms bonded to carbon atoms.
There are 2 nitrogen atoms in 1.00 mg of aspartame, and each nitrogen atom is bonded to three hydrogen atoms. Therefore, there are 6 hydrogen atoms bonded to nitrogen atoms.
There are 5 oxygen atoms in 1.00 mg of aspartame, and each oxygen atom is not bonded to any hydrogen atoms.
Therefore, the total number of hydrogen atoms in 1.00 mg of aspartame is 28 + 6 + 0 = 34 hydrogen atoms.
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the absorbance of two unknown concentrations of the same substance were found to be 1.72 and 0.75. determine the concentrations of the unknowns.
For the first unknown concentration with an absorbance of 1.72, the concentration will be, c = 1.72/(ɛ × b). For the second unknown concentration with an absorbance of 0.75, the concentration will be: c = 0.75/(ɛ × b).
What is Absorbance?
Beer lambert's law states that the concentration of a solution is directly proportional to the absorbance of a solution. Mathematically, Beer's Law: A = εlc
where, A is absorbance, ε is the molar absorptivity, l is the path length, and c is the concentration.
We can rewrite the equation as, c = A / εl
where, c is the concentration, A is the absorbance, ε is the molar absorptivity, and l is the path length.
We have two absorbance values, which we will use to determine the concentration of the unknowns. Let's substitute the given values into the equation to determine the concentration of the first unknown.
where, c₁ = A₁ / εlc₁ = 1.72 / εl (1)
Now, let's substitute the second absorbance value to determine the concentration of the second unknown.
c₂ = A₂ / εlc₂ = 0.75 / εl(2)
The concentrations of the unknowns are c₁ and c₂, which we have expressed in terms of the concentration of the solution. The total concentration of the solution is not provided. Thus, we cannot determine the concentration of the unknown solutions.
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In each of the following groups, pick the substance that has the given property. Provide a BRIEF justification your answer.
a. highest boiling point: CCl4 CF4 CBr4
b. lowest freezing point: LiF F2 HCl
c. lowest vapor pressure at 25°C: CH3OCH3 CH3CH2OH CH3CH2CH3
d. greatest viscosity: H2S HF H2O2
e. greatest enthalpy of vaporization: H2CO CH3CH3 CH4 f. smallest enthalpy of fusion: I2 CsBr CaO
Highest boiling point compound is CBr4. The compound which has lowest freezing point is F2. The compound which has lowest vapor pressure is CH3CH2OH. The compound which has greatest viscosity is H2O2.
What is boiling point?
The boiling point of a substance is directly related to the strength of the intermolecular forces between the particles of the substance. The compound with the highest boiling point in this group is CBr4 because of its stronger London dispersion forces.
The freezing point of a substance is directly related to the strength of the intermolecular forces between the particles of the substance. A covalent compound has weak van der Waal forces between its particles, and the smaller the particle, the weaker the van der Waal force. F2 has the smallest particle size and therefore the lowest freezing point.c. lowest vapor pressure at 25°C: CH3CH2OH
The vapor pressure of a substance is directly related to the strength of the intermolecular forces between the particles of the substance. The compound with the lowest vapor pressure at 25°C. is CH3CH2OH.
The compound with greatest viscosity: H2O2. Viscosity is a measure of a liquid's resistance to flow. The greater the viscosity, the greater the resistance to flow.
Enthalpy of vaporization is the amount of energy required to vaporize a unit quantity of a substance. The enthalpy of vaporization is related to the strength of the intermolecular forces between the particles of the substance. The compound with smallest enthalpy of fusion is I2.
The enthalpy of fusion is the amount of energy required to melt a unit quantity of a substance. I2 has the weakest intermolecular forces and therefore the smallest enthalpy of fusion.
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If breaking bonds requires energy IN, or takes energy, what mathematical function (+, −, ×, ÷) should we use to represent this process in a computational model?
Answer:
The mathematical function that represents breaking bonds requiring energy in a computational model is the addition symbol (+).
Breaking a bond requires the input of energy, which means that energy is being added to the system. Therefore, the energy required to break a bond can be represented as a positive value, which is added to the total energy of the system. For example, if the energy required to break a bond is 10 joules, and the initial energy of the system is 100 joules, the total energy after the bond is broken would be 110 joules.
On the other hand, when forming bonds, energy is typically released or given off by the system. This means that the energy required for bond formation can be represented by a negative value, which would be subtracted from the total energy of the system.
Explanation:
What are the free moving charged particles in a Carbon electrode made of electrode
The free moving charged particles in a Carbon electrode made of electrode are electrons.
An electrode is a substance that conducts electricity, which means it allows electric charges to travel through it. During electrolysis, an electrode is used to provide an electric current for the reduction and oxidation reactions that take place.
A carbon electrode is a type of electrode that is made of carbon. Carbon electrodes are commonly used in batteries and fuel cells because they are lightweight and can easily conduct electricity.
Electrons are free moving charged particles in a carbon electrode made of electrode. Electrons are negatively charged subatomic particles that orbit the nucleus of an atom. They are found in the outer shells of atoms and can move freely from one atom to another when they are excited by an electric current.
When an electric current is passed through a carbon electrode, the electrons in the outer shells of the carbon atoms are excited and become free moving charged particles. This allows the carbon electrode to conduct electricity and to participate in reduction and oxidation reactions during electrolysis.
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(a) Compute the specific heat at constant volume of nitrogen (N2) gas, and compare it with the specific heat of liquid water. The molar mass of N2 is 28.0 g/mol. (b) You warm 1.00 kg of water at a constant volume of 1.00 L from 20.0∘C to 30.0∘C in a kettle. For the same amount of heat, how many kilograms of 20.0∘C air would you be able to warm to 30.0∘C? What volume (in liters) would this air occupy at 20.0∘C and a pressure of 1.00 atm? Make the simplifying assumption that air is 100% N2.
Answer:
(A).Liquid water has a specific heat of 4.184J/g.k
(B)Volume = 39,420 LSo, kilograms= 44.7 kg
Explanation:
(a) The specific heat at constant volume of nitrogen (N2) gas is 20.8 J/K.mol. Compare it with the specific heat of liquid water.Liquid water has a specific heat of 4.184 J/g.K
(b) For the same amount of heat, we would be able to warm 44.7 kg of 20.0 °C air to 30.0 °C. Air has a molar mass of 28.97 g/mol. We can use the ideal gas law to determine the volume of 44.7 kg of air at 20.0 °C and 1.00 atm pressure.
We know that 1 mol of a gas at STP (standard temperature and pressure) occupies 22.4 L. Since air is 100% N2, its molar mass is 28.0 g/mol. The ideal gas law is given by PV = nRT where P = pressure, V = volume, n = number of moles, R = the universal gas constant, and T = temperature.
Substituting values, we have:
PV = nRTV = nRT/PAt
20.0 °C and 1.00 atm, T = 293 K and P = 1.00 atm.
Therefore, we have:
n = mass/molar mass = 44.7 kg / (28.97 g/mol) = 1543.8 mol
R = 0.082 L.atm/K.mol
Substituting these values into the equation, we have:
V = (1543.8 mol)(0.082 L.atm/K.mol)(293 K) / (1.00 atm)
V = 39,420 LSo, 44.7 kg of 20.0 °C air occupies a volume of 39,420 L at 20.0 °C and 1.00 atm pressure.
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