Answer:
[tex]pH=10.45[/tex]
Explanation:
Hello,
In this case, for the dissociation of the given base, we have:
[tex]base\rightleftharpoons OH^-+CA[/tex]
Whereas CA accounts for conjugated acid and OH⁻ for the conjugated base. In such a way, equilibrium expression is:
[tex]Kb=\frac{[OH^-][CA^+]}{[base]}[/tex]
And in terms of the reaction extent [tex]x[/tex] we can write:
[tex]1.6x10^{-6}=\frac{x*x}{0.05M-x}[/tex]
For which the roots are:
[tex]x_1=-0.000284M\\x_2=0.000282M[/tex]
For which clearly the result is the positive root which also equals the concentration of hydroxyl ions and we can compute the pOH:
[tex]pOH=-log([OH^-])=-log(0.000282)\\\\pOH=3.55[/tex]
And the pH:
[tex]pH=14-pOH=14-3.55\\\\pH=10.45[/tex]
Regards.
The pH of the solution is 10.45.
Let us represent codeine with the generic formula BH. We can set up the ICE table as follows;
:B(aq) + H2O(l) ⇄ BH(aq) + OH^-(aq)
I 0.05 0 0
C -x +x +x
E 0.05 - x x x
We know that the Kb of codeine is 1.6 x 10^-6, Hence;
1.6 x 10^-6 = x^2/0.05 - x
1.6 x 10^-6 (0.05 - x ) = x^2
8 x 10^-8 - 1.6 x 10^-6x = x^2
x^2 + 1.6 x 10^-6x - 8 x 10^-8 = 0
x = 0.00028 M
The concentration of hydroxide ions = 0.00028 M
Given that pOH = - log[0.00028 M]
pOH = 3.55
pH + pOH = 14
pH = 14 - 3.55
pH = 10.45
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Determine the percent water in Cuso4.5H20 to 3 significant figures
Answer:
Molar mass is the mass of one mole of a substance and is ontained by adding atomic mases of all the constituent atoms and group of atoms.
Atomic masses: Cu = 63.55 g/mol,
S = 32.07 g/mol
O x 4 = 16.00 g/mol x 4 = 64.00 g/mol
H = 1.008 g/mol,
So, H2O = (2*1.008+16.00)*5 = 90.10 g/mol
Molar mass of CuSO4,5H2O = 249.72 g/mol.
Out of that 249.72 grams, 90.10 grams is water,
So, percentage by mass of water in CuSO4,5H2O
= 90.10*100/249.72 = 36.08.
I think this is what you are asking. hope this helps
How many valence electrons must two atoms share to form a single covalent bond? answers A.2 B.4 C.3 D.1
Answer:
2
Explanation:
A single covalent bond is formed when two electrons are shared between the same two atoms, one electron from each atom.
Answer:
the answer is 2
Explanation:
A spontaneous galvanic cell consists of a Pb electrode in a 1.0 M Pb(NO3)2 solution and a Cd electrode in a 1.0 M Cd(NO3)2 solution. What is the standard cell potential for this galvanic cell
Answer:
0.27 V
Explanation:
Given that the both half cells contain 1.0 molar solutions of their respective electrolytes.
E°Pb= -0.13 V
E°Cd = -0.40 V
Since it is a galvanic cell, the electrode having a more negative electrode potential will serve as the anode and the electrode having a less negative electrode potential will serve as the cathode.
Hence cadmium will serve as the anode and lead will serve as the cathode.
E°cell = E°cathode - E°anode
E°cell = -0.13 - (-0.40)
E°cell = 0.27 V
All of the following are examples of allotropes of carbon EXCEPT Choose the one alternative that best completes the statement or answers the question. Choose the one alternative that best completes the statement or answers the question. diamond amorphous carbon quartz graphene all of the above
Answer:
quartz
Explanation:
The correct option would be quartz.
Allotropy is a phenomenon that describes the natural existence of the same element in different forms with different physical characteristics. Allotropes are therefore different forms of the same element.
Carbon as an element has several allotropes which include diamond, graphite, graphene, amorphous carbon, and fullerenes. Quartz is a crystalline solid that is composed of silicon dioxide and not carbon.
Hence, all the options are carbon allotropes except quartz.
In which pair do both compounds exhibit predominantly ionic bonding? A) KCl and CO2 B) SO2 and BaF2 C) F2 and N2O D) N2O3 and Rb2O E) NaF and SrO
Answer:
E) NaF and SrO
Explanation:
The ionic bonding occurs between atoms with a great difference in electronegativity. This usually happens between a metal and a non-metal.
In which pair do both compounds exhibit predominantly ionic bonding?
A) KCl and CO₂. NO. C and O are non-metals and present covalent bonding.
B) SO₂ and BaF₂. NO. S and O are non-metals and present covalent bonding.
C) F₂ and N₂O. NO. Both compounds contain non-metals and present covalent bonding.
D) N₂O₃ and Rb₂O. NO. N and O are non-metals and present covalent bonding.
E) NaF and SrO. YES. Na and Sr are metals while F and O are non-metals.
A student completed the experiment but found that the total amount of material recovered weighed more than the original sample. What is the most likely source of error and how may it be corrected?
Answer:
This is due to the water moisture present in the recovered sample.
Explanation:
The total amount of material recovered isn’t meant to weigh more than the original sample. However when this happens then it means there is the presence of water moisture in the recovered sample.
The recovered samples however needs to be heated to make it dry and eliminate the water moisture through evaporation.
An atom of 108Te has a mass of 107.929550 amu. Calculate the binding energy per MOLE in kJ. Use the values: mass of 1H atom
Answer:
The binding energy = 8.64972649×10¹⁰ kJ/mole
Explanation:
Given that:
An atom of 108Te has a mass of 107.929550 amu.
In a 108 Te atom, there are 52 protons and 56 neutrons
where;
mass of proton= 1.007825 amu
mass of neutron= 1.008665 amu
Similarly; The atomic number of Te = 52
the mass of 52 protons = 52 × 1.007825 amu
the mass of 52 protons = 52.4069 amu
the mass of 56 neutrons = 56 × 1.008665 amu
the mass of 56 neutrons = 56.48524 amu
The total mass can now be = the mass of 52 protons + the mass of 56 neutrons
The total mass = 52.4069 amu + 56.48524 amu
The total mass = 108.89214 amu
Recall : it is given that An atom of 108Te has a mass of 107.929550 amu.
Therefore, the mass defect will be = 108.89214 amu - 107.929550 amu
the mass defect = 0.96259amu
where 1 amu = 1.66× 10⁻²⁷ kg
Therefore, 0.96259amu = (0.96259 × 1.66× 10⁻²⁷) kg
= 1.5978994 × 10⁻²⁷kg
The binding energy = mass defect × (speed of light)²
where;
speed of light c = 2.99792 × 10⁸ m/s
The binding energy = 1.5978994 × 10⁻²⁷kg × 2.99792 × 10⁸ m/s
The binding energy = 1.43611597 × 10⁻¹⁰ J
The binding energy = 1.43611597 × 10⁻¹³ kJ/atom
since 1 mole = 6.023 × 10²³ atom (avogadro's constant)
Then;
The binding energy = ( 1.43611597 × 10⁻¹³ )× (6.023 × 10²³) kJ/mole
The binding energy = 8.64972649×10¹⁰ kJ/mole
Will a precipitate (ppt) form when 300. mL of 2.0 × 10 –5 M AgNO 3 are added to 200. mL of 2.5 × 10 –9 M NaI? Answer yes or no, and identify the precipitate if there is one
Answer:
A precipitate will form, AgI
Explanation:
When Ag⁺ and I⁻ ions are in an aqueous media, AgI(s), a precipitate, is produced or not based on its Ksp expression:
Ksp = 8.3x10⁻¹⁷ = [Ag⁺] [I⁻]
Where the concentrations of the ions are the concentrations in equilibrium
For actual concentrations of a solution, you can define Q, reaction quotient, as:
Q = [Ag⁺] [I⁻]
If Q > Ksp, the ions will react producing BaCO₃, if not, no precipitate will form.
Actual concentrations of Ag⁺ and I⁻ are:
[Ag⁺] = [AgNO₃] = 2.0x10⁻⁵ × (300mL / 500.0mL) = 1.2x10⁻⁵M
[I⁻] = [NaI] = 2.5x10⁻⁹ × (200mL / 500.0mL) = 1.0x10⁻⁹M
500.0mL is the volume of the mixture of the solutions
Replacing in Q expression:
Q = [Ag⁺] [I⁻]
Q = [1.2x10⁻⁵M] [1.0x10⁻⁹M]
Q = 1.2x10⁻¹⁴
As Q > Ksp
A precipitate will form, AgIA compound is found to contain 30.45 % nitrogen and 69.55 % oxygen by weight. To answer the questions, enter the elements in the order presented above. 1. What is the empirical formula for this compound? 2. The molecular weight for this compound is 46.01 g/mol. What is the molecular formula for this compound?
Answer:
Empirical formulae is NO2
Molecular Formulae is NO2
Which element always exists in monatomic form? silicon, a metalloid oxygen, a nonmetal calcium, a metal neon, a noble gas
Answer:
[tex]\huge\boxed{A \ noble \ gas}[/tex]
Explanation:
A noble gas always exists in a mono-atomic form. This is because the valency of noble gas is zero and thus they don't tend to lose, gain or share electrons. They are inert gases and do not react.
Answer:
a noble gas
Explanation:
the the noble gases exist as mono atomic elements that is helium, neon ,argon, Krypton,etc.
mono atomic elements exist as stable single atoms
The combination of a carbonyl group and a hydroxyl group on the same carbon atom is called a ________ group.
a. carbamate group
b. carbonate
c. carboxlate
d. carboxyl
Answer:
d. carboxyl
Explanation:
The presence of carbonyl group (>C=O)) and a hydroxyl group ( (−OH) on the same carbon atom is called a "carboxyl" group. A carboxyl group is represented as COOH and acts as the functional group part of carboxylic acids.
For example:
Formic acid or Methanoic acid (H-COOH) Butanoic acid (C3H7-COOH)Hence, the correct option is "d. carboxyl ".
Which option draws the correct conclusion from the following case study?
A patient with sickle-cell anemia and a fever goes to the emergency room and is given Tylenol to reduce
the fever. The patient has seizures and dies after taking the Tylenol. The physician writes up this case as
an interesting outcome for a patient with sickle-cell anemia.
The case study's validity is obvious because it describes a real-life situation.
The case study was influenced by bias, and led to incorrect conclusions being drawn
The case study was not intended to produce a generalized conclusion about treatment
Upon reading this case study, physicians should stop treating sickle cell patients with fevers using Tylenol
Answer:
I believe the answer The case study was influenced by bias, and led to incorrect conclusions being drawn. plz correct me if I am wrong
Explanation:
Answer: options B
Explanation:
Compare and contrast an electrolytic cell with a voltaic cell. Provide one example where both are present in daily life.
Answer:
ELECTROLYTIC CELL
An electrochemical cell in which a non-spontaneous chemical reaction takes place when electric current is passed through the solution,is called an electrolytic cell.
EXAMPLE
Nelsons cell and Downs cell
VOLTAIC CELL OR GALVANIC CELL
The electrochemical cell in which a spontaneous chemical reaction takes place and generates electric current is called galvanic and voltaic cell.
EXAMPLE
Daniel cell
Explanation:
Electrolytic cell by the non-spontaneous reactions covert the chemical energy into electical and volataic cells are those in which spontaneous redox reaction takes place.
What is cell?Cell is a device which converts chemical energy into electrical energy.
Electrolytic Cell: An electrolytic cell is an electrochemical cell in which a non-spontaneous redox chemical reaction occurs when an electric current is conducted through the solution.
Example- Electrolysis of sodium chloride, by which formation of sodium metal and chlorine gas takes place.
Voltaic cell: Voltaic cells are electrochemical cells in which a spontaneous redox chemical reaction occurs and creates electric current. These cells are also known by the name of Galvanic cells.
Example- It is used in the form of batteries which can be portable easily.
Hence, in electrolytic cells non - spontaneous reaction occur and in voltaic cell spontaneous reaction is occured.
To know more about cells, visit the below link:
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For the following reaction, 22.8 grams of diphosphorus pentoxide are allowed to react with 13.5 grams of water . diphosphorus pentoxide(s) water(l) phosphoric acid(aq) What is the maximum mass of phosphoric acid that can be formed
Answer:
[tex]m_{H_3PO_4}=31.5gH_3PO_4[/tex]
Explanation:
Hello,
In this case, the undergoing chemical reaction is:
[tex]P_2O_5(s)+3H_2O(l)\rightarrow 2H_3PO_4(aq)[/tex]
Thus, since the diphosphorus pentoxide to water molar ratio is 1:3 and we are given the mass of both of them, for the calculation of the maximum mass phosphoric acid that is yielded, one could first identify the limiting reactant, for which we compute the available moles of diphosphorus pentoxide (molar mass 142 g/mol):
[tex]n_{P_2O_5}=22.8gP_2O_5*\frac{1molP_2O_5}{142gP_2O_5}=0.161molP_2O_5[/tex]
And the moles of diphosphorus pentoxide that are consumed by 13.5 g of water (molar mass 18 g/mol):
[tex]n_{P_2O_5}^{consumed}=13.5gH_2O*\frac{1molH_2O}{18gH_2O}*\frac{1molP_2O_5}{3molH_2O} =0.25molP_2O_5[/tex]
Hence, since less moles of diphosphorus pentoxide are available, we sum up it is the limiting reactant, therefore, the maximum mass of phosphoric acid (molar mass 98 g/mol) is computed by considering the 1:2 molar ratio between them as follows:
[tex]m_{H_3PO_4}=0.161molP_2O_5*\frac{2molH_3PO_4}{1molP_2O_5} *\frac{98gH_3PO_4}{1molH_3PO_4} \\\\m_{H_3PO_4}=31.5gH_3PO_4[/tex]
Regards.
A student ran the following reaction in the laboratory at 242 K: 2NOBr(g) 2NO(g) Br2(g) When she introduced 0.143 moles of NOBr(g) into a 1.00 liter container, she found the equilibrium concentration of NOBr(g) to be 0.108 M. Calculate the equilibrium constant, Kc, she obtained for this reaction. Kc
Answer:
1.84 × 10⁻³
Explanation:
Step 1: Write the balanced equation
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
Step 2: Calculate the initial concentration of NOBr
0.143 moles of NOBr(g) are introduced into a 1.00 liter container. The molarity is:
M = 0.143 mol / 1.00 L = 0.143 M
Step 3: Make an ICE chart
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
I 0.143 0 0
C -2x +2x +x
E 0.143-2x 2x x
Step 4: Find the value of x
The equilibrium concentration of NOBr(g) was 0.108 M. Then,
0.143-2x = 0.108
x = 0.0175
Step 5: Calculate the concentrations at equilibrium
[NOBr] = 0.108 M
[NO] = 2x = 0.0350 M
[Br₂] = x = 0.0175 M
Step 6: Calculate the equilibrium constant (Kc)
Kc = [0.0350]² × [0.0175] / [0.108]²
Kc = 1.84 × 10⁻³
2. Which one is the odd one
out and why?
o Water
• Hydrogen
Chlorine
o Aluminum
Answer:
Reaction of Chlorine with Hydrogen Chlorine and Hydrogen mixed together explodes when exposed to sunlight, which produces Hydrogen Chloride. In the dark away from sunlight, no reaction occurs, so light energy is required for a reaction. Cl2 + H2 = 2 HCl Reaction of Chlorine with Non-Metals Chlorine directly combines with most non-metals.
Explanation:
I hope this helps bro
What is the relationship between concentration and rate of reaction?
not related
directly proportional
Inversely proportional
partially related
Explanation:
The answer is directly proportional, because when there is more concentration their will more reactants to react fast diring the chemical reaction which increases the rate of chemical reaction.
So, we can state that the relationship between them are directly proportional.
Hope it helps...
A sample of radioactive silver contains two isotopes, 108Ag (denoted A) and 110Ag (denoted B). The second of these (B) has a half life of 24 seconds, whereas the first (A) has a half life of 2.3 minutes. If a sample contains equal numbers of each of these isotopes at the beginning of an experiment that runs for an hour, which of the following statements is correct?
A. At the end of the hour, isotope B has a greater decay constant λ than isotope A
B. At the end of the hour, isotope A has the same decay constant λ as isotope B
C. At the end of the hour, isotope A has a greater decay constant λ than isotope B
Answer:
A : At the end of the hour, isotope B has a greater decay constant λ than isotope A
Explanation:
Firstly, we need to understand that radioactive decay follows a first order rate law.
What this means is that we can calculate the radioactive decay constant using the following formula from the half-life
Mathematically;
[tex]t_{1/2}[/tex] = 0.693/λ
where λ represents the radioactive decay constant.
Rearranging the equation, we can have
λ = 0.693/[tex]t_{1/2}[/tex]
Now, to have a fair level playing ground, it is best that the half-life of both isotopes are in the same unit of time(seconds)
For A, the half-life = 2.3 minutes which is same as 2.3 × 60 = 138 seconds
For B, the half-life is 24 seconds
Thus, at the end of the hour, the decay constant for isotope A will be;
λ = 0.693/138 = 0.0050 [tex]s^{-1}[/tex]
For isotope B, the decay constant will be;
λ = 0.693/24 = 0.028875 [tex]s^{-1}[/tex]
We can see that the decay constant of isotope B is higher than that of A at the end of the experiment
When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many
The given question is incomplete.
The complete question is:
When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many grams of methane were needed for the reaction?
Answer: 4 grams of methane were needed for the reaction
Explanation:
According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.
{tex]CH_4+2O_2\rightarrow CO_2+H_2O[/tex]
Given: mass of oxygen = 16 g
Mass of carbon dioxide = 11 g
Mass of water = 9 g
Mass of products = Mass of carbon dioxide + mass of water = 11 g +9 g = 20 g
Mass or reactant = mass of methane + mass of oxygen = mass of methane + 16 g
As mass of reactants = mass of products
mass of methane + 16 g= 20 g
mass of methane = 4 g
Thus 4 grams of methane were needed for the reaction
One hundred fifty joules of heat are removed from a heat reservoir at a temperature of 150 K. What is the entropy change of the reservoir (in J/K)?
Answer:
ΔS surrounding (entropy change of the reservoir) = -1 J/K
Explanation:
Given:
Change in heat (ΔH) = 150 joules
Temperature (T) = 150 K
Find:
ΔS surrounding (entropy change of the reservoir)
Computation:
ΔS surrounding (entropy change of the reservoir) = - ΔH / T
ΔS surrounding (entropy change of the reservoir) = - 150 / 150
ΔS surrounding (entropy change of the reservoir) = -1 J/K
Read the chemical equation. Mg + 2HCl → MgCl2 + H2 How many moles of MgCl2 are produced from 1 mole of HCl? 0.2 0.5 1.0 1.5
Answer:
0.5 mol MgCl₂
Explanation:
Step 1: Write the balanced equation
Mg + 2 HCl → MgCl₂ + H₂
In words, 1 mole of Mg reacts with 2 moles of HCl to form 1 mole of MgCl₂ and 1 mole of H₂.
Step 2: Establish the appropriate molar ratio
The molar ratio of HCl to MgCl₂ is 2:1.
Step 3: Calculate the moles of MgCl₂ produced from 1 mole of HCl
1 mol HCl × (1 mol MgCl₂/2 mol HCl) = 0.5 mol MgCl₂
Answer:
it is 2.0, the above one is wrong
Explanation:
I did the test :
The second law of thermodynamics predicts that heat flow from a cooler object to a hotter object:________
a) will be spontaneous at high pressure
b) will be spontaneous at low pressure
c) will never be spontaneous at any pressure
d) will always be spontaneous
Answer:
c) will never be spontaneous at any pressure.
Explanation:
Hello,
In this case, we need to remember that the second law of thermodynamics states that heat flow is transferred from a hot object to a cold object only, never the other way around, therefore, the answer is c) will never be spontaneous at any pressure. This is supported by driving force that in this case is the temperature difference which must be negative for the hot object (it gets eventually cold) and positive for the cold object (it gets eventually hot) until they reach the equilibrium temperature.
Best regards.
An enzyme is discovered that catalyzes the chemical reaction:SAD -------->HAPPY
<-------A team of motivated researchers sets out to study the enzyme which they call Happyase. They find that the Kcat for happyase is 600s-1. They carry out several experiments. When [Et]=20 nM and [SAD]=40 \mu M, the reaction velocity, Vo is 9.6 \mu Ms^{-1} . Calculate the Km for the substrate SAD.
Answer: Km = 10μM
Explanation: Michaelis-Menten constant (Km) measures the affinity a enzyme has to its substrate, so it can be known how well an enzyme is suited to the substrate being used. To determine Km another value associated to an eznyme is important: Turnover number (Kcat), which is the number of time an enzyme site converts substrate into product per unit time.
Enzyme veolcity is calculated as:
[tex]V_{0} = \frac{E_{t}.K_{cat}.[substrate]}{K_{m}+[substrate]}[/tex]
where Et is concentration of enzyme catalitic sites and has to have the same unit as velocity of enzyme, so Et = 20nM = 0.02μM;
To calculate Km:
[tex]V_{0}*K_{m} + V_{0}*[substrate] = E_{t}.K_{cat}.[substrate][/tex]
[tex]K_{m} = \frac{E_{t}.K_{cat}.[substrate]-V_{0}*[substrate]}{V_{0}}[/tex]
[tex]K_{m} = \frac{0.02*600*40-9.6*40}{9.6}[/tex]
Km = 10μM
The Michaelis-Menten for the substrate SAD is 10μM.
If the amount of radioactive iodine-123, used to treat thyroid cancer, in a sample decreases from 3.2 to 0.4 mg in 39.6 h, what is the half-life of iodine-123?
Answer:
Half life = 13.197 hour
Explanation:
Given:
Old amount (A₀) = 3.2
New amount (A) = 0.4
Radiation decay time (t) = 39.6 hour
Half life = T(1/2)
Find:
Half life = T(1/2) = T
Computation:
A = A₀[tex]e^{-(\frac{0.693t}{T} )}[/tex]
[tex]e^{-(\frac{0.693t}{T} )}[/tex] = 0.4 / 3.2
-[27.4428 / T] = In (0.125)
-[27.4428 / T] = -2.0794
[27.4428 / T] = 2.0794
T = 13.197
Half life = 13.197 hour
Methyl iodide reacts irreversibly with azide ion with rate = k[CH3I][N3–]. CH3I(aq) + N3–(aq) → CH3N3(aq) + I–(aq) The reaction is carried out with an initial concentration of CH3I of 0.01 M. Which statement about the reaction is correct?
Answer:
(D) The reaction cannot take place in a single elementary step
Explanation:
Statements are:
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I].
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution.
(D) The reaction cannot take place in a single elementary step.
The rate of the reaction is:
rate = k[CH3I][N3–].
That means rate depends of concentration of CH₃I as much as N₃⁻ concentration
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I]. FALSE. The reaction rate depends of N₃⁻ as much as CH₃I
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M. FALSE. Reaction is second-order. Half-life is 1/K[A]₀. If initial concentration is 0.1M, to a concentration of 0.005M it takes:
1/K*0.1. If initial concentration is 0.005M it takes 1/K*0.005. That means it takes half to decrease from 0.005M to 0.0025 as it does for it to decrease from 0.01M to 0.005M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution. FALSE. Reaction rate is independent of I⁻
(D) The reaction cannot take place in a single elementary step. TRUE. As this reaction is a single-replacement reaction implies the formation of 1 C-N bond. But also the rupture of the C-I bond is impossible to explain this kind of reaction in a single elementary step.
In a buffer solution made of acetic acid and sodium acetate, if a small amount of acid is added, the added acid will react with whome?
Answer:
The acid reacts with the conjugate base producing more weak acid.
Explanation:
A buffer solution is defined as the mixture of a weak acid and its conjugate base or a weak base with its conjugate acid.
The acetic buffer, CH₃COOH/CH₃COO⁻, is in equilibrium with water as follows:
CH₃COOH(aq) + H₂O(l) ⇄ CH₃COO⁻(aq) + H₃O⁺
When an acid HX (Source of H₃O⁺) is added to the buffer, the reaction that occurs is:
CH₃COO⁻ + HX → CH₃COOH
The acid reacts with the conjugate base producing more weak acid.In fact, this is the principle of the buffer:
An acid reacts with the conjugate base producing weak acid. And the weak acid reacts with a base producing conjugate base
If a small amount of acid is added to an acetic acid-sodium acetate buffer, the acid will react with the acetate ion from sodium acetate.
We have a buffer formed by acetic acid and sodium acetate.
What is a buffer?A buffer is a solution used to resist abrupt changes in pH when an acid or a base is added.
How are buffers formed?They can be formed in 1 of 2 ways:
By a weak acid and its conjugate base.By a weak base and its conjugate acid.Our buffer is formed by a weak acid (acetic acid) and its conjugate base (acetate ion from sodium acetate).
When an acid (HX) is added, it is neutralized by the basic component of the buffer. The generic net ionic equation is:
H⁺ + CH₃COO⁻ ⇄ CH₃COOH
If a small amount of acid is added to an acetic acid-sodium acetate buffer, the acid will react with the acetate ion from sodium acetate.
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Calculate LaTeX: \DeltaΔGº for a voltaic cell with Eºcell = +0.24 V if the overall reaction involves a 3 electron reduction.
Answer:
-69 kJ
Explanation:
Step 1: Given data
Standard cell potential (E°cell): +0.24 V
Electrons involved (n): 3 mol
Step 2: Calculate the standard Gibbs free energy change (ΔG°) for the voltaic cell
We will use the following expression.
ΔG° = -n × F × E°cell
where,
F is Faraday's constant (96,485 C/mol e⁻)
ΔG° = -n × F × E°cell
ΔG° = -3 mol e⁻ × 96,485 C/mol e⁻ × 0.24 V
ΔG° = -69 kJ
Wine goes bad soon after opening because the ethanol dissolved in it reacts with oxygen gas to form water and aqueous acetic acid , the main ingredient in vinegar. Calculate the moles of oxygen needed to produce of acetic acid. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.
Answer:
0.500 moles of oxygen
Explanation:
Full question says: "Calculate the moles of oxygen needed to produce 0.500 moles of acetic acid.
The reaction of ethanol (C₂H₅OH) with oxygen (O₂) is:
C₂H₅OH + O₂ → CH₃COOH + H₂O
Where 1 mole of ethanol reacts per mole of oxygen to produce 1 mole of acetic acid (CH₃COOH) and 1 mole of water
Based on the chemical equation (1 mole of oxygen produce 1 mole of acetic acid; Ratio 1:1). Thus, if you want to produce 0.500 moles of acetic acid you will need:
0.500 moles of oxygen. You have two solutions, both with a concentration of 0.1M. Solution A contains a weak acid with a pKa of 5. ThepH of solution A is 3. Solution B contains a weak acid with a pKa of 9. The pH of solution B is:
Answer:
pH of solution B is 5
Explanation:
A weak acid, HA, is in equilibrium with water as follows:
HA(aq) + H₂O(l) ⇄ A⁻(aq) + H₃O⁺(aq)
Where Ka (10^-pKa = 1x10⁻⁹) is:
Ka = 1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]
Where concentrations of this species are equilibrium concentrations
As initial concentration of HA is 0.1M, the equilibrium concentrations of the species are:
[HA] = 0.1M - X
[A⁻] = X
[H₃O⁺] = X
Where X is the amount of HA that reacts until reach the equilibrium, X is reaction coordinate.
Replacing in Ka expression:
1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]
1x10⁻⁹ = [X] [X] / [0.1 - X]
1x10⁻¹⁰ - 1x10⁻⁹X = X²
1x10⁻¹⁰ - 1x10⁻⁹X - X² = 0
Solving for X:
X = -0.00001 → False solution, there is no negative concentrations.
X = 1x10⁻⁵ → Right solution.
As [H₃O⁺] = X
[H₃O⁺] = 1x10⁻⁵M
And pH = -log[H₃O⁺]
pH = 5
pH of solution B is 5
Determine whether the following statement about reaction rates is true or false. If the statement is false, select the reason why?
Increasing the temperature of a reaction system decreases the activation energy of the reaction.
Answer:
False
Explanation:
Reaction rates is a field under chemical kinetics that deals with the measure of speed of a chemical reaction. It is the change in the concentration of a reactant or product per unit time.
Activation Energy is a theory been put forward to explain why different chemical reactions proceed at different rates.
Activation Energy theory postulates that for a reactant to transform into a product , the colliding particles or molecules of the reactant must possess a certain amount of energy so as to overcome the reaction barrier.
An important factor which may influence the attainment of activation energy by colliding particles of reactants is the temperature at which the reaction is carried out. The higher the temperature, the greater is the fraction of the reactant particles which possess the activation energy and thus the faster the reaction becomes. SO , in essence increasing the temperature of a reaction system do not decreases the activation energy of the reaction but rather also increases the activation energy of the reaction.
