Answer:
a. eletrophile
b. able to impose regioselectivity and stereo selectivity.
c. faster
Explanation:
Necleophile reaction is chemical reaction in which electron rich chemical specie replaces functional group with another electron deficient molecule. Lewis acid catalyst is organic chemical reaction which lewis acid act as electron pair acceptor. Nucleophile reaction proceeds about 25 times more faster than benzene.
How many grams of solute are present in 635mL of 0.450 M KBr?
Answer:
34.03 g
Explanation:
We'll begin by converting 635 mL to L. This can be obtained as follow:
1000 mL = 1 L
Therefore,
635 mL = 635 mL × 1 L / 1000 mL
635 mL = 0.635 L
Thus, 635 mL is equivalent to 0.635 L
Next, we shall determine the number of mole of the solute (KBr) in the solution. This can be obtained as follow:
Volume = 0.635 L
Molarity = 0.450 M
Mole of KBr =?
Mole = Molarity × Volume
Mole of KBr = 0.450 × 0.635
Mole of KBr = 0.286 mole
Finally, we shall determine the mass of 0.286 mole of KBr. This can be obtained as follow:
Mole of KBr = 0.286 mole
Molar mass of KBr = 39 + 80
= 119 g/mol
Mass of KBr =?
Mass = mole × molar mass
Mass of KBr = 0.286 × 119
Mass of KBr = 34.03 g
Thus, the mass of the solute (KBr) in the solution is 34.03 g
A chemist measures the energy change
ΔH during the following reaction:
2NH3(g)→N2(g)+3H2(g)
ΔH=160kJUse the information to answer the following questions.This reaction is:__________.
a. endothermic
b. exothermic
Suppose 70.9 g of NH3 react. Will any heat be released or absorbed?
a. Yes, absorbed
b. Yes, released
c. No.
If you said heat will be released or absorbed in the second part of this question, calculate how much heat will be released or absorbed. Round your answer to 3 significant digits.
Answer:
For (1): The correct option is (a)
For (2): The correct option is (a) and 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts.
Explanation:
There are 2 types of reactions that are classified based on enthalpy change:
Endothermic reactions: These are the reactions where heat is absorbed by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is positive for these reactions.
Exothermic reactions: These are the reactions where heat is released by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is negative for these reactions.
For (1):For the given chemical reaction:
[tex]2NH_3(g)\rightarrow N_2(g)+3H_2(g);Delta H=160kJ[/tex]
As the change in enthalpy or heat of the reaction is positive. Thus, the reaction is an endothermic reaction because heat is absorbed by the reaction.
For (2):When ammonia reacts, some amount of heat will be absorbed by the reaction. Thus, we can say the heat will be absorbed.
The number of moles is calculated by using the equation:
[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)
Given mass of ammonia = 70.9 g
Molar mass of ammonia = 17 g/mol
Using equation 1:
[tex]\text{Moles of ammonia}=\frac{70.9g}{17g/mol}=4.17mol[/tex]
By stoichiometry of the reaction:
If 2 mole of ammonia reacts, the heat absorbed is 160 kJ
So, if 4.17 moles of ammonia reacts, the heat absorbed will be = [tex]\frac{160kJ}{2mol}\times 4.17mol=333.6kJ[/tex]
Hence, 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts
what mass of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol
Answer: A mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.
Explanation:
Given: Mass of naphthalene = 25.0 g
Molality = 0.22 m
This means that 0.22 moles of solute is present per kg of solvent.
As 25.0 g of naphthalene is there that will be 25.0 g per 1000 g (1 kg) is equal to 0.025 kg.
Hence, moles of phenol are calculated as follows.
[tex]Molality = \frac{moles}{mass (in kg)}\\0.22 m = \frac{moles}{0.025 kg}\\moles = 0.0055 mol[/tex]
Also, molar mass of phenol is 94.11 g/mol. This means that 1 mole of phenol contains 94.11 g.
Therefore, mass contained by 0.0055 moles of phenol is as follows.
[tex]0.0055 mol \times 94.11 g/mol \\= 0.518 g[/tex]
Thus, we can conclude that a mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.
The mass of a single tantalum atom is 3.01×10-22 grams. How many tantalum atoms would there be in 37.1 milligrams of tantalum?
Answer: There are [tex]1.23 \times 10^{22}[/tex] atoms present in 37.1 mg of tantalum.
Explanation:
Given: Mass of single tantalum atom = [tex]3.01 \times 10^{-22} g[/tex]
Mass of tantalum atoms = 37.1 mg (1 mg = 0.001 g) = 0.0371 g
Therefore, number of tantalum atoms present in 0.0371 grams is calculated as follows.
[tex]No. of atoms = \frac{0.0371 g}{3.01 \times 10^{-22}}\\= 1.23 \times 10^{20}[/tex]
Thus, we can conclude that there are [tex]1.23 \times 10^{22}[/tex] atoms present in 37.1 mg of tantalum.
There are [tex]1.23\times 10^{20}[/tex] atoms of tantalum in 37.1 mg of tantalum.
Explanation:
Given:
Mass of single atom of tantalum =[tex]3.01\times 10^{-22} g[/tex]
To find:
The number of atoms of tantalum in 37.1 milligrams.
Solution:
Mass of tantalum = 37.1 mg
[tex]1 mg = 0.001 g\\37.1 mg=37.1\times 0.001 g=0.0371 g[/tex]
The number of atoms in 0.0371 grams of tantalum = N
Mass of a single atom of tantalum = [tex]3.01\times 10^{-22} g[/tex]
Then a mass of N atoms of tantalum will be:
[tex]0.0371 g=N\times 3.01\times 10^{-22} g\\N=\frac{0.0371 g}{ 3.01\times 10^{-22} g}\\=1.23\times 10^{20}[/tex]
There are [tex]1.23\times 10^{20}[/tex] atoms of tantalum in 37.1 mg of tantalum.
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The concentration ratio of conjugate acid to conjugate base for a 20 mM solution at pH 7.0 of an amino acid is 20:1.
Required:
a. What is the pK of the side chain?
b. What amino acid might this be?
Answer:
a. 8.3= pKa of the aminoacid
b. Cysteine
Explanation:
The pH of an acid can be obtained using the H-H equation:
pH = pKa + log [A-] / [HA]
Where pH is the pH of the buffer = 7.0
pKa is the pka of the conjugate acid = ?
[A-] / [HA] is the ratio between conjugate base and conjugate acid. As the ratio of conjugate acid to conjugate base = 20:1, the [A-] / [HA] = 1/20
Replacing:
7 = pKa + log 1/20
7 = pKa - 1.30
7+1.30 = 8.3 = pKa of the aminoacid
The only aminoacid with a side chain with pKa = 8.3 is:
Cysteine. Allowing its identification.
What evidence supports the law of conservation of energy?
Light energy is converted to chemical energy during photosynthesis.
Oxygen is made from the breakdown of carbon dioxide during photosynthesis.
Energy is absorbed by chlorophyll during photosynthesis.
The sun gives off light energy that is absorbed by plants.
Answer:
light energy is converted to chemical energy during photosynthesis.
Explanation:
Law of conservation of energy says: Energy can neither be created nor destroyed-only converted from one form of energy to another.
Answer:
A. Light energy is converted to chemical energy during photosynthesis.
Which mechanisms is most significant in returning the ion concentrations to the resting state?
Answer:
Active transport by the Na+-K+ pump
Explanation:
Active transport by the Na+-K+ pump
Maintenance (and restoration) of the resting ion concentrations depends on the Na+-K+ pump. Once gated ion channels are closed, the combined action of the pump and ion leakage (particularly that of K+) establishes a resting membrane potential in a typical neuron of around âˆ'70 mV.
How does a scientist form a hypothesis?
Explanation: The hypothesis is a prediction, but it involves more than a guess. Most of the time, the hypothesis begins with a question which is then explored through background research. It is only at this point that researchers begin to develop a testable hypothesis.
(Unless you are creating an exploratory study, your hypothesis should always explain what you expect to happen)
4. If matter goes through a chemical change, are the physical properties likely to stay the same?
•
Please say yes or no and explain why.
Answer: If matter goes through a chemical change then the physical properties are not likely to stay the same.
Explanation:
When chemical composition of a substance changes during a chemical reaction then it is called a chemical change.
Chemical change always leads to the formation of new substances. Properties like chemical reactivity, combustion, rusting etc are chemical changes.
For example, [tex]N_{2} + 3H_{2} \rightarrow 2NH_{3}[/tex]
Here, [tex]NH_{3}[/tex] will have different chemical as well as physical properties as compared to [tex]N_{2}[/tex] and [tex]H_{2}[/tex].
As physical properties are the properties that cause change in state of a substance.
Properties like boiling point, state of substance etc are physical properties.
Thus, we can conclude that if matter goes through a chemical change then the physical properties are not likely to stay the same.
How do I answer the question in bold? Thank you!
Answer:
6.7855 * 10^18
Explanation:
There are 2 moles in H2
Avagadro's number: 6.022E23
8.14E42*1/6.022E23 * 1/2
=6.7855 * 10^18
g Calculate the percent yield when you start with 0.50 grams of salicylic acidand end with 0.33 grams of aspirin. The molecular weight of salicylic acid is 138.12 g/mol, and the molecular weight of aspirin is 180.157 g/mol.
Explanation:
hope the picture above helps you to understand:)
Write the balanced half-equations for silver + oxygen= silver oxide:
Answer: The balanced half-equations for silver + oxygen= silver oxide are:
Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]
Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]
Explanation:
The word equation is as follows.
silver + oxygen = silver oxide
In terms of chemical formulas this equation can be written as follows.
[tex]Ag + O_{2} \rightarrow Ag_{2}O[/tex]
The removal on electron(s) from an atom, ion or molecule in a chemical reaction is called oxidation.
The gain of electron(s) by an atom, ion or molecule in a chemical reaction is called reduction.
Hence, half-reaction equations for the given reaction is as follows.
Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]
Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]
As the number of atoms participating in the reaction are equal. Hence, the half-equations are balanced.
Thus, we can conclude that the balanced half-equations for silver + oxygen = silver oxide are:
Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]
Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]
Which substance has nonpolar covalent bonds?
CO
NO2
H2
NaBr
Answer:
H2
Explanation:
Answer:
[tex]{ \bf{H _{2} }} \\ { \tt{hydrogen \: gas}}[/tex]
Suppose a 48. L reaction vessel is filled with 1.6 mol of Br2 and 1.6 mol of OCl2. What can you say about the composition of the mixture in the vessel at equilibrium
Answer:
There will be very little of BrOCl BrCl
Explanation:
Based on the equilibrium:
Br2(g) + OCl2(g) ⇄ BrOCl(g) + BrCl(g)
The equilibrium constant, Kc, is:
Kc = 1.58x10⁻⁵ = [BrOCl] [BrCl] / [Br2] [OCl2]
As Kc is <<< 1, in equilibrium, the concentration of products will remain lower regard to the concentration of the reactants. That means, right answer is;
There will be very little of BrOCl BrClDuring a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)
Group of answer choices
It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.
It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.
It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.
It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.
Answer: The statement it is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed, is true.
Explanation:
A chemical reaction in which heat energy is released is called an exothermic reaction. For exothermic reactions, the value of [tex]\Delta H[/tex] is always negative.
A chemical reaction in which heat energy is absorbed is called an endothermic reaction. For endothermic reaction, the value of [tex]\Delta H[/tex] is always positive.
In endothermic reactions, energy required for breaking the bonds between reactants is less than the energy when products are formed due to which the value of [tex]\Delta H[/tex] remains positive.
Thus, we can conclude that the statement it is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed, is true.
It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed. The correct option is B.
The above reaction is endothermic because more energy is produced when new bonds form in the products (H = 920 kJ/mol) than is required to break bonds in the reactants (H = -750 kJ/mol).
In an endothermic process, more energy than is generated during bond creation is absorbed from the environment to dissolve existing bonds. This causes a net absorption of energy, which cools the system.
The reaction takes more energy than it releases, proving its endothermic nature, as seen by the positive difference between the energy needed to dissolve bonds and the energy released during bond formation.
Thus, the correct option is B.
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Your question seems incomplete, the probable complete question is:
During a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)
Group of answer choices
A. It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.
B. It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.
C. It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.
D. It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.
An unknown weak acid with a concentration of 0.530 M has a pH of 5.600. What is the Ka of the weak acid
Answer:
Ka = 3.45x10⁻⁶
Explanation:
First we calculate [H⁺], using the given pH:
pH = -log[H⁺][H⁺] = [tex]10^{-pH}=10^{-5.6}[/tex] [H⁺] = 2.51x10⁻⁶ MTo solve this problem we can use the following formula describing a monoprotic weak acid:
[H⁺] = [tex]\sqrt{C*Ka}[/tex]We input the data that we already know:
2.51x10⁻⁶ = [tex]\sqrt{0.530*Ka}[/tex]And solve for Ka:
Ka = 3.45x10⁻⁶1. Show that heat flows spontaneously from high temperature to low temperature in any isolated system (hint: use entropy change that occurs during the process for your proof).
2. Work out the entropy change for the decomposition of mercuric oxide using mathematical and graphical arguments.
Answer:
1 ) Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
Explanation:
1) To show that heat flows spontaneously from high temperature to low temperature
example :
Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )
Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment
Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )
Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
2) Entropy change for Decomposition of mercuric oxide
2HgO (s) → 2Hg(l) + O₂ (g)
Δs = positive
there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C
hence ΔSdecomposition = S⁻ Hg - S⁻ HgO =
Δh of reaction = 181.6 KJ
Temp = 500 + 273 = 773 k
hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
i.What are organic fertilizers?
ii.State three advantages of organic fertilizers over inorganic fertilizers.
Answer:
Organic fertilizers are those fertilizers that are not artificially produced but are natural and has carbon in them.
Fertilizers in the broad term are used to provide nutrient to the soil and boost growth of crops.
Some of the advantages of organic fertilizers to inorganic fertilizers are:
They do not make crusts on the soil, unlike inorganic fertilizers.
They help add structure to the soil because of the good water movement into the soil
They are easier on the soil because they feed good microbes.
An electron in the ground state absorbs a single photon of light and then relaxes back to the ground state by emitting an infrared photon (1200 nm) followed by an orange photon (600 nm). What is the wavelength of the absorbed photon?
A. 400 nm
B. 600 nm
C. 1800 nm
g 0.500 L of a solution with a concentration of 0.25 M is needed. To prepare this solution, a stock solution with a concentration of 1.25 M is prepared. What volume of the stock solution is needed to create the desired solution
Answer:
0.1 L
Explanation:
From the question given above, the following data were obtained:
Concentration of stock solution (C₁) = 1.25 M
Volume of diluted solution (V₂) = 0.5 L
Concentration of diluted solution (C₂) = 0.25 M
Volume of stock solution needed solution (V₁) =?
The volume of the stock solution needed can be obtained as follow:
C₁V₁ = C₂V₂
1.25 × V₁ = 0.25 × 0.5
1.25 × V₁ = 0.125
Divide both side by 1.25
V₁ = 0.125 / 1.25
V₁ = 0.1 L
Therefore, the volume of the stock solution needed is 0.1 L
Help pls!!!
For groups 13 through 18, the number of valence electrons is equal to the group number
a. minus 10
b. minus the period number
c. plus 1
d. plus the period number
Answer:
a. minus 10
Explanation:
An element in group 13 = Boron ,valence electrons = 3 , therefore, valence electrons in group 13 = group no. -10
An element in group 18 = Neon, valence electrons = 8 , therefore, valence electrons in group 18 = group no. - 10
For groups 13 through 18, the number of valence electrons in an atom is equal to the group number minus 10. Therefore, option (A) is correct.
What is a valence electron?Valence electrons in an atom can be described as the electrons occupying the outer most electron shell of an atom while the electrons in the inner shell are core electrons. Lewis structures can be helpful to calculate the number of valence electrons.
Valence electrons can be filled in several electron shells as they are caused interaction between atoms and responsible for the formation of chemical bonds. Only valence electrons can contribute to the formation of a chemical bond and decide the reactivity of the element.
The general electronic configuration of group 13 is ns²np¹ has three valence electrons. It can be determined as group number - 10 = 13 - 10 = 3.
The general electronic configuration of group 18 is ns²np⁶ has eight valence electrons. It can be determined as group number - 10 = 18 - 10 = 8.
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Question 4: Biological Molecules (5 points)
A. Pepsin is an enzyme used by the human body to break down food in the stomach.
i. Explain, in terms of a chemical reaction, how pepsin helps a person. (3 points)
ii. What are the building blocks of the pepsin macromolecule? (2 points)
Answer: the answer is A
Explanation: add me hope i helped
Which is a property of all bases?
Answer: The property of all bases is that they are substances which neutralizes an acid to form a salt and water only.
Explanation:
A base is also s substance that can accept or combine with a proton; a proton acceptor.
Bases include the oxides, hydroxides and carbonates of metals. These include MgO,Na2O, NaOH,Ca(OH)2. Most metals burn in oxygen to form metallic oxides which are basic. Examples are the MgO and Na2O.
Other properties or characteristics of bases includes:
--> They have a bitter taste.
--> They turn red litmus paper blue.
--> They are soapy to touch.
--> Aqueous solutions of bases are also electrolytes. Bases can be either strong or weak, just as acids can.
Bases (sodium hydroxide) can be used in the preparation of soaps, glass, paper and rayon. While some bases (magnesium hydroxide) can also be used to manufacture toothpaste and laxatives.
what class of organic compound is formed when cyclopentanone reacts with ethylamine in the presence of trace acid
The question is incomplete, the complete question is;
What functional group results when cyclopentanone reacts with ethylamine in the presence of trace acid? A) cyanohydrin B) semicarbazone C) imine D) enamine E) oxime
Answer:
imine
Explanation:
An imine is an unsaturated amine. An imine contains the carbon- nitrogen double bond.
Imines are obtained when a carbonyl compound is condensed with NH3 or an amine. The reaction involves several steps in its mechanism.
Since cyclopentanone is a ketone (carbonyl compound) and ethylamine is an amine,in the presence of trace acid, condensation of the two compounds occur to yield an imine
once a recrystallization is completed and filtered, what solvent would be suitable for transferring the leftover solids to filtration funnel
Answer:
To transfer leftover solids to the filtration funnel and wash out crystals after recrystallization, ice cold methanol should be used (the mother liquor used for recrystallization).
Explanation:
Hope this helped
3. Does entropy increase or decrease in the following processes?
A. Complex carbohydrates are metabolized by the body, converted into simple sugars.
Answer: Increase
es-lesund
B. Steam condenses on a glass surface.
Answer:
decreare
-->
MgCl2(s)
C. Mg(s) + Cl2(g)
correct
Answer:
Answer:
hope it helps much as you can
A buffer is prepared containing 0.75 M NH3 and 0.20 M NH4 . Calculate the pH of the buffer using the Kb for NH3. g
Answer:
pH=8.676
Explanation:
Given:
0.75 M [tex]NH_{3}[/tex]
0.20 M [tex]NH_{4}[/tex]
The objective is to calculate the pH of the buffer using the kb for [tex]NH_3[/tex]
Formula used:
[tex]pOH=pka+log\frac{[salt]}{[base]}\\[/tex]
pH=14-pOH
Solution:
On substituting salt=0.75 and base=0.20 in the formula
[tex]pOH=-log(1.77*10^{-5})+log\frac{0.75}{0.20}\\ =4.75+0.5740\\ =5.324[/tex]
pH=14-pOH
On substituting the pOH value in the above expression,
pH=14-5.324
Therefore,
pH=8.676
Imagine you are celebrating a birthday in December and need balloons. The temperature in the
store where you are purchasing the balloons is approximately 25°C and each balloon is filled
to a volume of 2 liters to obtain maximum pressure.
Use the gas laws to explain what will happen to the volume and pressure of the gas in the
balloon when go outside, where the temperature is 0°C. Include both Charles's Law
and Gay-
Lussac's Law in your answer.
ILL GIVE BRAINIEST PLEASE HELP
Perform the following operation and express the answer in scientific notation.
7.296×10² ÷ 9.6×10^-9
Answer:
7.6×10¹⁰
Explanation:
7.296×10²÷9.6×10⁻⁹
To solve such problem,
We group the whole number ans solved seperately and also group the indices and solve the seperately
Step1 : 7.296/9.6 = 0.76
Step 2: applying the law of indices,
10²÷10⁻⁹ = 10⁽²⁺⁹⁾ = 10¹¹
Therefore,
7.296×10²÷9.6×10⁻⁹ = 0.76×10¹¹ = 7.6×10¹⁰
When 2-methyl-3-hexene is treated with Cl2 in methanol, three products are formed (neglecting stereoisomers). Draw curved arrows to show the movement of electrons in this step of the reaction mechanism.
Answer:
Explanation:
The structural formula of 2-methyl-3-hexene is drawn in the attached image below. After then, the three possible structures were drawn and the mechanism reaction.
From the mechanism shown, methanol deprotonates methoxide proton and neutralizes the positive charge to form methoxide. This is followed by the movement of electrons that takes place from the region of higher electron density to lower electron density.