Answer:
The temperature at which the vapor pressure would be 0.350 atm is 201.37°C
Explanation:
The relationship between variables in equilibrium between phases of one component system e.g liquid and vapor, solid and vapor , solid and liquid can be obtained from a thermodynamic relationship called Clapeyron equation.
Clausius- Clapeyron Equation can be put in a more convenient form applicable to vaporization and sublimation equilibria in which one of the two phases is gaseous.
The equation for Clausius- Clapeyron Equation can be expressed as:
[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]
where ;
[tex]P_1[/tex] is the vapor pressure at temperature 1
[tex]P_ 2[/tex] is the vapor pressure at temperature 2
∆Hvap = enthalpy of vaporization
R = universal gas constant
Given that:
[tex]P_1[/tex] = 1 atm
[tex]P_ 2[/tex] = 0.350 atm
∆Hvap = 28.5 kJ/mol = 28.5 × 10³ J/mol
[tex]T_1[/tex] = 282 °C = (282 + 273) K = 555 K
R = 8.314 J/mol/k
Substituting the above values into the Clausius - Clapeyron equation, we have:
[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]
[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{T_2 - 555}{555T_2} \end {pmatrix} }[/tex]
[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]- 1.0498= 3427.953 \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]\dfrac{- 1.0498}{3427.953}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]- 3.06246906 \times 10^{-4}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]\dfrac{1}{T_2} = \begin {pmatrix} \dfrac{1}{555}+ (3.06246906 \times 10^{-4} ) \end {pmatrix} }[/tex]
[tex]\dfrac{1}{T_2} = 0.002108048708[/tex]
[tex]T_2 = \dfrac{1}{0.002108048708}[/tex]
[tex]\mathbf{T_2 }[/tex] = 474.37 K
To °C ; we have [tex]\mathbf{T_2 }[/tex] = (474.37 - 273)°C
[tex]\mathbf{T_2 }[/tex] = 201.37 °C
Thus, the temperature at which the vapor pressure would be 0.350 atm is 201.37 °C
The temperature of the liquid at the given vapor pressure is 201.5 ⁰C.
The given parameters;
boiling point temperature, = 282 ⁰Cvapor pressure, P₂ = 0.35 atmenthalpy of vaporization, ∆Hvap = 28.5 kJ/molThe temperature of the liquid will be determined by applying Clausius- Clapeyron Equation;
[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )[/tex]
where;
R is ideal gas constant = 8.314 J/mol.kT₁ is the initial temperature in Kelvin = 282 + 273 = 555 KP₁ is the initial pressure = 1 atm[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )\\\\ln(\frac{0.35}{1} ) = \frac{28.5 \times 10^3}{8.314} (\frac{T_2 - 555}{555T_2} )\\\\-1.049 = 6.176- \frac{3427.95}{T_2} \\\\\frac{3427.95}{T_2} = 6.176 + 1.049\\\\\frac{3427.95}{T_2} = 7.225\\\\T_2 = \frac{3427.95}{7.225} \\\\T_2 = 474.5 \ K\\\\T_2 = 474.5 - 273 = 201.5 \ ^0C[/tex]
Thus, the temperature of the liquid at the given vapor pressure is 201.5 ⁰C.
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Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced.
_______ → Ba(ClO)2 + H2O(l)
Answer:
2HClO(aq) + Ba(OH)₂(aq) → Ba(ClO)₂(aq) + 2H₂O(l)
Explanation:
The reaction corresponds to a neutralization reaction between an acid and a base, as follows:
2HClO(aq) + Ba(OH)₂(aq) → Ba(ClO)₂(aq) + 2H₂O(l)
From the equation above we have that the acid HClO reacts with the base Ba(OH)₂ to obtain a salt Ba(ClO)₂ and water.
In the balanced reaction, we have that 2 moles of HClO react with 1 mol of Ba(OH)₂ to produce 1 mol of Ba(ClO)₂ and 2 moles of water.
I hope it helps you!
Consider the bond dissociation energies listed below in kcal/mol. CH3-Br 70 CH3CH2-Br 68 (CH3)2CH-Br 68 (CH3)3C-Br 65 These data show that the carbon-bromine bond is weakest when bromine is bound to a __________.
Answer:
The answer is "Tertiary carbon".
Explanation:
Accent to the results, the carbon-bromine bond is weak, whenever, the bromine is connected to tertiary carbon so, bonding energy is separation for methyl-carbon, which is connected to the bromine = 70 kcal/mol and for the primary energy to the secondary energy is= 68 kcal/mol, and for tertiary CO2 = 65 kcal/mol.
The stronger the energy dissociating connection and the weaker, its power dissociation connection and its weaker bond becomes connecting with a tertiary carbon, that's why "Tertiary carbon" is the correct answer.
Which of the following is a salt that could be generated by combining a weak acid and a weak base? Select the correct answer below:
a) NaCl
b) Na2SO4
c) NH4NO3
d) NH4F
Answer:
d) NH4F
Explanation:
Hello,
In this case, the base resulting from mixing a weak acid and a weak base is d) NH4F since ammonium hydroxide is a wear base and hydrofluoric acid is a weak acid.
Ammonium hydroxide is a weak base since it is not completely ionized in ammonium and hydroxyl ions:
[tex]NH_4OH\rightarrow NH_4^++OH^-[/tex]
Moreover, hydrofluoric acid is a weak acid since it is not completely ionized in hydrogen and fluoride ions:
[tex]HF\rightleftharpoons H^++F^-[/tex]
For the both of the substances, the limit is established by the basic and the acid dissociation constant respectively.
Regards.
Identify the term that matches each electrochemistry definition. The electrode where oxidation occurs Cathode The electrode where reduction occurs Choose... An electrochemical cell powered by a spontaneous redox reaction Choose... An electrochemical cell that takes in energy to carry out a nonspontaneous redox reaction Choose... A chemical equation showing either oxidation or reduction Choose...
Answer:
An electrochemical cell that takes in energy to carry out a nonspontaneous redox reaction
If a substance has a half-life of 55.6 s, and if 230.0 g of the substance are present initially, how many grams will remain after 10.0 minutes?
Answer:
[tex]m=0.127g[/tex]
Explanation:
Hello,
In this case, for a first-order reaction, we can firstly compute the rate constant from the given half-life:
[tex]k=\frac{ln(2)}{t_{1/2}} =\frac{ln(2)}{55.6s}=0.0125s^{-1}[/tex]
In such a way, the integrated first-order law, allows us to compute the final mass of the substance once 10.0 minutes (600 seconds) have passed:
[tex]m=m_0*exp(-kt)=230.0g*exp(-0.0125s^{-1}*600s)\\\\m=0.127g[/tex]
Best regards.
A 5-column table with 2 rows. Column 1 is labeled number of protons, with entries 20 and 9; column 2 is number of neutrons, with entries 20 and D; Column 3 is atomic number, with entries A and E; Column 4 is Mass Number, with entries B and 19, and Column 5 is Element (symbol) with entries C and F. Using the periodic table, complete the table to describe each atom. Type in your answers
Answer:
A ⇒ 20
B ⇒ 40
C ⇒ Ca
D ⇒ 10
E ⇒ 9
F ⇒ F
Explanation:
edge 2021
Answer:
the person above is correct
Explanation:
Calculate the molarity of a solution containing 29g of glucose (C 6 H 12 O 6 ) dissolved in 24.0g of water. Assume the density of water is 1.00g/mL.
Answer:
whats the ph ofpoh=9.78
Explanation:
Based on relative bond strengths, classify these reactions as endothermic (energy absorbed) or exothermic (energy released).
Strongest Bond
A-B
A-A
B-B
C-C
B-C
A-C
1. A2 + C2 rightarrow 2AC
2. B2 + C2 rightarrow 2BC
3. A + BC rightarrow AB + C
4. A2 + B2 rightaarrow 2AB
5. AB + C rightarrow AC + B
a. endothermic
b. exothermic
Answer:
1. Exothermic 2. Exothermic 3. Endothermic 4. Endothermic 5. Exothermic.
Explanation:
1. An A-A and a C-C bond results in 2 A-C bonds which are lower than the A-A and C-C bonds so this reaction is exothermic.
2. A B-B bond and a C-C bond results in 2 B-C bonds which are lower than the first 2 bonds so this reaction is also exothermic.
3. There is no bond for single A, a single B-C bond results in a A-B bond and a C molecule. A-B bond is stronger than the B-C bond so the reaction absorbed energy along the way. This shows that it is endothermic.
4. An A-A bond and a B-B bond results in 2 A-B bonds which are stronger than the first two bonds so this reaction is also endothermic.
5. An A-B bond and a C molecule result in an A-C bond and a B molecule. A-C bond is weaker than the A-B bond so there is energy released. This reaction is exothermic.
I hope this answer helps.
A sample of argon gas (molar mass 40 g) is at four times the absolute temperature of a sample of hydrogen gas (molar mass 2 g). Find the ratio of the rms speed of the argon molecules to that of the hydrogen. Assume hydrogen molecule has only translational degree of freedom.
Answer:
Ratio of Vrms of argon to Vrms of hydrogen = 0.316 : 1
Explanation:
The root-mean-square speed measures the average speed of particles in a gas, and is given by the following formula:
Vrms = [tex]\sqrt{3RT/M}[/tex]
where R is molar gas constant = 8.3145 J/K.mol, T is temperature in kelvin, M is molar mass of gas in Kg/mol
For argon, M = 40/1000 Kg/mol = 0.04 Kg/mol, T = 4T , R = R
Vrms = √(3 * R *4T)/0.04 = √300RT
For hydrogen; M = 1/1000 Kg/mol = 0.001 Kg/mol, T = T, R = R
Vrms = √(3 * R *T)/0.001 = √3000RT
Ratio of Vrms of argon to that of hydrogen = √300RT / √3000RT = 0.316
Ratio of Vrms of argon to that of hydrogen = 0.316 : 1
What's the concentration of hydronium ions if a water-base solution has a temperature of 25°C (Kw = 1.0×10–14), with a concentration of hydroxide ions of 2.21×10–6 M? answer options: A) 2.8×10–8 M B) 4.52 ×10–9 M C) 1.6×10–9 M D) 3.1×10–6 M
Answer:
ITS NOT D. ITS B. 4.52x10^-9 M
Explanation:
Answer:
4.52 ×10–9 M
Explanation:
Candle wax melts low temperature, it is not conductive to electricity, it is insoluble in water and partially soluble in solvents nonpolar, like gasoline. Than type of links are present in the candle wax?
A. Electrostatics.
B. Apolar.
C. lónicos.
D. Hydrogen bridges.
electrostatic and ionic are definitely not the answer because they have high melting point
hydrogen bonds are too weak and not permanent.
so the answer is apolar as it is soluble in polar solvents (water)
Answer:
B. Nonpolar
Explanation:
The low melting point tells you the compound is not ionic, metallic, or a network solid.
It is almost certainly a molecular solid.
It does not conduct electricity, so it is not metallic (which we have already ruled out).
It is insoluble in polar solvents (water) and soluble in nonpolar solvents (gasoline).
Since like dissolves like, the molecule is nonpolar.
The type of links must be nonpolar.
g What is the molarity of hydrochloric acid if 40.95 mL of HCl is required to neutralize 0.550 g of sodium oxalate, Na2C2O4
Answer:
0.0002 M
Explanation:
The molarity of the HCl required would be 0.0002 M.
First, let us consider the balanced equation of the reaction:
[tex]Na_2C_2O_4 + 2HCl = 2NaCl + H_2 + 2CO_2[/tex]
Stoichiometrically, 1 mole of [tex]Na_2C_2O_4[/tex] reacts with 2 moles of [tex]HCl[/tex] for a complete neutralization reaction.
Recall that: mole = [tex]\frac{mass}{molar mass}[/tex]
Mole of 0.550 g sodium oxalate = 0.550/134 = 0.0041 mole
If 1 mole [tex]Na_2C_2O_4[/tex] requires 2 moles HCl, then 0.0041 mole will require:
0.0041 x 2 = 0.0082 mole HCl
Volume of the HCl = 40.95 L
Molarity = mole/volume
Hence, molarity of the HCl = 0.0082/40.95 = 0.0002 M
Predict the most likely bond type for the following.
a. Cu (Copper)
b. KCl (Potassium Chloride)
c. Si (Silicon)
d. CdTe (Cadmium Telluride)
e. ZnTe (Zinc Telluride)
Answer:
The three major types of bond are ionic, polar covalent, and covalent bonds. Ionic occurs majorly between metals and non-metals, which allows sharing of electrons to form an ionic compound. Whereas covalent bonding calls for complete transfer of electrons between atoms. Polar covalent bonds have unequaly shared electron-pair between two atoms.
Explanation:
a. Cu (Copper)- ionic bonding
b. KCl (Potassium Chloride) - ionic bonding
c. Si (Silicon) - covalent bonding
d. CdTe (Cadmium Telluride) - polar covalent bonding
e. ZnTe (Zinc Telluride)- polar covalent bonding
Name the following compound from the concise formula:______.
CH3CH(CH3)CHCHCH(CH3)CH2CH3
A. 2,4-dimethyl-3-heptene
B. 2,5-dimethyl-3-heptene
C. 3,5-dimethyl-3-heptene
D. 2,5-dimethyl-4-heptene
Answer:
B. 2,5-dimethyl-3-heptene
Explanation:
Answer:
B. 2,5-dimethyl-3-heptene
Explanation:
Calculate the molar solubility of CaF2 at 25°C in a solution that is 0.010 M in Ca(NO3)2. The Ksp for CaF2 is 3.9 x 10-11.
Answer:
[tex]Molar \ solubility=3.12x10^{-5}M[/tex]
Explanation:
Hello,
In this case, for the dissociation of calcium fluoride:
[tex]CaF_2(s)\rightleftharpoons Ca^{2+}+2F^-[/tex]
The equilibrium expression is:
[tex]Ksp=[Ca^{2+}][F^-]^2[/tex]
In such a way, via the ICE procedure, including an initial concentration of calcium of 0.01 M (due to the calcium nitrate solution), the reaction extent [tex]x[/tex] is computed as follows:
[tex]3.9x10^{-11}=(0.01+x)(2*x)^2\\\\x=0.0000312M[/tex]
Thus, the molar solubility equals the reaction extent [tex]x[/tex], therefore:
[tex]Molar \ solubility=3.12x10^{-5}M[/tex]
Regards.
The molar solubility of Calcium fluoride has been calculated as [tex]3.12\;\times\;10^-^5\;\rm M[/tex].
The dissociation of calcium fluoride has been given by:
[tex]\rm CaF_2\;\rightarrow\;Ca^2^+\;+\;2\;F^-[/tex]
The solubility constant, ksp has been given as:
[tex]ksp=\rm[Mg^2^+]\;[F^-]^2[/tex]
From the dissociation of Calcium nitrate, the concentration of Ca ion in the solution has been 0.01 M.
The dissociation of Calcium fluoride x M has been resulted in x M Ca and 2x M F ions.
The concentration of Ca in the solution has been resulted as x + 0.01 M.
The solubility product can be given as:
[tex]3.9\;\times\;10^-^1^1=[x+0.01]\;[2x]^2\\3.9\;\times\;10^-^1^1=[x+0.01]\;4x^2\\x=3.12\;\times\;10^-^5[/tex]
The molar solubility of Calcium fluoride has been calculated as [tex]3.12\;\times\;10^-^5\;\rm M[/tex].
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For the following set of volume/temperature data, calculate the missing quantity after the change is made. Assume that the pressure and the amount of gas remain constant.
V=2.91 L at 23.0 °C
V= 4.20 L at ? °C
Answer:
155 °C
Explanation:
Step 1: Given data
Initial volume (V₁): 2.91 LInitial temperature (T₁): 23.0°CFinal volume (V₂): 4.20 LFinal temperature (T₂): ?Step 2: Convert the initial temperature to Kelvin
We will use the following expression.
K = °C + 273.15 = 23.0°C + 273.15 = 296.2 K
Step 3: Calculate the final temperature
Assuming an ideal gas behavior, we can calculate the final temperature using Charles' law.
V₁/T₁ = V₂/T₂
T₂ = V₂ × T₁/V₁
T₂ = 4.20 L × 296.2 K/2.91 L
T₂ = 428 K
Step 4: Convert the final temperature to Celsius
We will use the following expression.
°C = K - 273.15 = 428 - 273.15 = 155 °C
What are the products in the following chemical reaction Pb(NO3)+KCI
Answer:
The products are KNO3 + PbCl2.....
Espero que te sirva.
How many grams of H2O will be formed when 32.0 g H2 is mixed with 73.0 g of O2 and allowed to react to form water
hope this helps u
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If an individual proton has mass 1.007825 amu, and an individual neutron has mass 1.008665 amu, what's the calculated mass of a neptunium-236 nucleus? options: A) 237.92482 amu B) 236.99873 amu C) 237.96682 amu D) 237.04817 amu
Answer:
C) 237.96682 amu
Explanation:
The symbol for neptunium-236 is given as;
²³⁶₉₃Np
This element has 93 protons and (236 - 93 = 143) neutrons.
Mass Number =Total mass of Protons + Total mass of neutrons
Total Mass pf protons = 93 * 1.007825 amu, = 93.727725 amu
Total mass of Neutrons = 143 * 1.008665 amu = 144.239095 amu
Mass = 144.239095 + 93.727725 = 237.96682 amu
Correct option is option C.
In which list are the three compounds above correctly listed in order of increasing boiling point? A) lowest b.p.... isopropanol < isobutane < acetone ...highest b.p. B) lowest b.p.... isobutane < acetone < isopropanol ...highest b.p. C) lowest b.p.... isobutane < isopropanol < acetone ...highest b.p. D) lowest b.p.... acetone < isobutane < isopropanol ...highest b.p. E) lowest b.p.... acetone < isopropanol < isobutane ...highest b.p.
Answer:
The correct answer is - option B - lowest b.p.... isobutane < acetone < isopropanol ...highest b.p.
Explanation:
Isobutane has lowest boiling point due to no hydrogen bonding and no diole to dipole interaction found in them. Isobutane only shows weak dispersion force.
Acetone has dipole dipole interaction but due to lack of Hydrogen bonding they have low boiling point than isopropanol but higher than isobutanol.
Isopropanol is the compound that has ability to form hydrogen bonding with other molecule its boiling point is maximum among all three.
Thus, the correct answer is - option B - lowest b.p.... isobutane < acetone < isopropanol ...highest b.p.
The concentration of glucose, C6H12O6, in normal spinal fluid is 75 mg/100g. What is the molality of the solution
Answer:
4.16x10⁻³m
Explanation:
Molality is defined as the ratio between moles of a solute, in this case glucose, and kg of solvent.
As there are 100g of solvent, the kg are 0.1. Thus, we only need to calculate from the mass of glucose its moles to solve the molality of the solution.
Moles glucose:
There are 75mg = 0.075g of glucose. To conver mass to moles it is necessary molar mass.
Molar mass glucose:
6C = 12.01g/mol*6 = 72.06g/mol
12H = 12*1.008g/mol = 12.10g/mol
6O = 6*16g/mol = 96g/mol
72.06 + 12.10 + 96 = 180.16g/mol
Moles of 0.075g of glucose:
0.075g * (1 mol / 180.16g) =
4.16x10⁻⁴ moles of glucose
Molality of the solution:
4.16x10⁻⁴ moles of glucose / 0.1kg of solvent =
4.16x10⁻³mThe molarity of the solution is 4.16x10⁻³m
Calculation of the molarity:We know that the molarity refers to the ratio that arise between the moles of a solute.
Since there are 100 g of solvent so here the kg should be 0.1.
Likewise there is 75 mg so it should be 0.075g
Now the Molar mass glucose should be
6C = 12.01g/mol*6 = 72.06g/mol
12H = 12*1.008g/mol = 12.10g/mol
6O = 6*16g/mol = 96g/mol
So,
= 72.06 + 12.10 + 96
= 180.16g/mol
Now
Moles of 0.075g of glucose:
0.075g * (1 mol / 180.16g) =
4.16x10⁻⁴ moles of glucose
Now finally
Molality of the solution:
= 4.16x10⁻⁴ moles of glucose / 0.1kg of solvent
=4.16x10⁻³m
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When titrating a strong acid with a strong base, after the equivalence point is reached, the pH will be determined exclusively by: Select the correct answer below:
A) hydronium concentration
B) hydroxide concentration
C) conjugate base concentration
D) conjugate acid concentration
Answer:
B) hydroxide concentration
Explanation:
Hello,
In this case, since we are talking about strong both base and acid, since the base is the titrant and the acid the analyte, once the equivalence point has been reached, some additional base could be added before the experimenter realizes about it, therefore, since the titrant is a strong base, it completely dissociates in hydroxide ions and metallic ions which allows us to compute the pOH of the solution by known the hydroxide ions concentration.
After that, due to the fact that the pH is related with the pOH as shown below:
pH=14-pOH
We can directly compute the pH.
Best regards.
g Which ONE of the following molecules and ions has trigonal planar molecular geometry? (NOTE: You must first determine what the Lewis structure of each substance is.) A) PCl3 B) HCN C) CO3 2– D) H3O+ E) NF3
Answer: C) [tex]CO^{2-}_{3}[/tex]
Explanation: The Valence Shell Electron Pair Repulsion Model (VSEPR Model) shows bonding and nonbonding electron pairs present in the valence, outermost, shell of an atom connecting to other atoms. It also gives the molecular geometric shape of a molecule.
To determine molecular geometry:
1) Draw Lewis Structure, i.e., a simplified representation of the valence shell electrons;
2) Count the number of electron pairs (count multiple bonds as 1 pair);
3) Arrange electron pairs to minimise repulsion;
4) Position the atoms to minimise the lone pair;
5) Name the molecular geometry from the atom position;
Trigonal planar molecular geometry is a model which molecule's shape is triangular and in one plane. Such molecule has three regions of electron density extending out from the central atom and the repulsion will be at minimum when angle between any two is 120°.
The Lewis structure of each molecule is shown in the attachment.
Analysing each one, it can be concluded that molecule with trigonal planar geometry is [tex]CO^{2-}_{3}[/tex]
What is pH of a buffer made by combining 45.0mL of 0.150M nitrous acid and 20.0mL of 0.175M sodium nitrate
Answer:
3.11
Explanation:
Any buffer system can be described with the reaction:
[tex]HA~->~H^+~+~A^-[/tex]
Where is the acid and is the base. Additionally, the calculation of the pH of any buffer system can be made with the Henderson-Hasselbach equation:
[tex]pH~=~pKa~+~Log(\frac{ [A^-]}{[HA]})[/tex]
With all this in mind, we can write the reaction for our buffer system:
-) Nitrous acid: [tex]HNO_2[/tex]
-) Sodium nitrate: [tex]NaNO_2[/tex]
[tex]HNO_2~->~H^+~+~NO_2^-[/tex]
In this case, the acid is [tex]HNO_2[/tex] with a concentration of 0.150 M and a volume of 45.0 mL (0.045 L). The base is [tex]NO_2^-[/tex] with a concentration of 0.175 M and a volume of 20.0 mL (0.020 L).
We can calculate the moles of each compound is we take into account the molarity equation ([tex]M=\frac{mol}{L}[/tex]). So:
-) moles of [tex]HNO_2[/tex]:
[tex]mol=0.150~M*0.045~L=0.00657[/tex]
-) moles of [tex]NO_2^-[/tex]:
[tex]mol=0.175~M*0.020~L=0.0035[/tex]
The total volume would be:
0.020 L + 0.045 L = 0.065 L
With this in mind, we can calculate the molarity of each compound:
-) Concentration of [tex]HNO_2[/tex]
[tex]M=\frac{0.00657~mol}{0.065~L}=0.101~M[/tex]
-) Concentration of [tex]NO_2^-[/tex]
[tex]M=\frac{0.0035~mol}{0.065~L}=0.0538~M[/tex]
The pKa reported is 3.39, therefore we can plug the values into the Henderson-Hasselbach equation:
[tex]pH~=~3.39~+~Log(\frac{[0.0538~M]}{[0.101~M]})~=~3.11[/tex]
The final pH value would be 3.11
I hope it helps!
The pH of a buffer made by combining 45.0 mL of 0.150M nitrous acid and 20.0mL of 0.175M sodium nitrate is 2.87.
We have a buffer made by combining 45.0mL of 0.150 M nitrous acid and 20.0mL of 0.175M sodium nitrate.
Nitrous acid is a weak acid and nitrate ion is its conjugate base.
What is a buffer?It is a solution used to resist abrupt changes in pH when acids or bases are added.
Step 1: Calculate the moles of each species.We do so by multiplying the molar concentration by the volume in liters.
HNO₂: 0.150 mol/L × 0.0450 L = 6.75 × 10⁻³ mol
NaNO₂: 0.175 mol/L × 0.0200 L = 3.50 × 10⁻³ mol
Step 2: Calculate the total volume of the mixture.The total volume will be the sum of the volumes of each solution.
V = 45.0 mL + 20.0 mL = 65.0 mL = 0.0650 L
Step 3: Calculate the molar concentration of each species in the mixture.HNO₂: 6.75 × 10⁻³ mol/0.0650 L = 0.104 M
NaNO₂: 3.50 × 10⁻³ mol/0.0650 L = 0.0538 M
Step 4: Calculate the pH of the buffer.We can calculate the pH of a buffer system using Henderson-Hasselbach's equation.
pH = pKa + log [NaNO₂]/[HNO₂]
pH = 3.16 + log 0.0538/0.104 = 2.87
The pH of a buffer made by combining 45.0 mL of 0.150M nitrous acid and 20.0mL of 0.175M sodium nitrate is 2.87.
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A voltaic cell is set up as follows: Anode: Zn electrode in a solution of 0.050 M Zn(NO 3 ) 2 Cathode: Pt electrode with 0.500 atm H 2 (g) in 0.010 M HNO 3 a) Write the overall balanced cell reaction.
Answer:
[tex]Zn(s) + 2H+(aq)\Rightarrow Zn^{2+}(aq) + H_{2}(g)[/tex]
Explanation:
Given that,
Anode : Zn electrode in a solution of 0.050 M Zn(NO₃)₂
Cathode : Pt electrode with 0.500 atm H₂(g) in 0.010 M HNO₃
Anode :
[tex]Zn(s)\Rightarrow Zn^{2+}(aq) + 2e^{-}[/tex]
Cathode :
[tex]2H+(aq)+2e^{-}\Rightarrow H_{2}(g)[/tex]
We need to write the overall balanced cell reaction
Using anode and cathode
[tex]Zn(s) + 2H+(aq)\Rightarrow Zn^{2+}(aq) + H_{2}(g)[/tex]
Hence, This is required answer.
Using the standard reduction potentials Ni2+(aq) + 2 e‑Ni(s) ‑0.25 volt Fe3+(aq) + e‑Fe2+(aq) +0.77 volt Calculate the value of E°cell for the cell with the following reaction. Ni2+(aq) + 2 Fe2+(aq) →Ni(s) + 2 Fe3+(aq)
Answer:
The correct answer is - 1.02 V
Explanation:
From the reduction-oxidation reaction:
Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)
Ni²⁺ is reduced to Ni(s) while Fe²⁺ is oxidized to Fe³⁺. Thus, the half reactions are:
Reduction (cathode) : Ni²⁺(aq) + 2 e‑ → Ni(s) Eº= ‑0.25 V
Oxidation (anode) : 2 x (Fe²⁺ → Fe³⁺ + e-)(aq) Eº= -0.77 V
-------------------------------------
Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)
In order to calculate the Eºcell, we have to add the reduction potential of the reaction in cathode (reduction) to the oxidation potential of the anode (oxidation):
Eºcell= Eºr + Eºo= (-0.25 V) + (-0.77 V) = - 1.02 V
The condition that a reaction takes place without outside help Choose... Solution in which no more solute can be dissolved in the solvent Choose... Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature Choose... The extent of randomness in a system Choose... Sum of the internal energy plus the product of the pressure and volume for a reaction
Answer:
Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature
Explanation:
The basis of spontaneity in a chemical reaction is that ∆G must be negative. ¡∆G is known as the change in free energy of a system. If ∆G is negative, then the reaction will occur without any external help (the reaction is spontaneous at room temperature).
∆G is given by;
∆G= ∆H -T∆S
Where;
∆H= change in enthalpy of the system
T= absolute temperature of the system
∆S= change in entropy
Hence; when ∆H -T∆S gives a negative result, the reaction proceeds without any external help.
What will be formed when 2,2,3-trimethylcyclohexanone reacts with hydroxylamine?
Answer:
Following are the solution to this equation:
Explanation:
In the given-question, an attachment file of the choices was missing, which can be attached in the question and its solution can be defined as follows:
In the given question "Option (iii)" is correct, which is defined in the attachment file.
When 2,2,3-trimethylcyclohexanone reacts with hydroxylamine it will produce the 2,2,3-trimethylcyclohexanoxime.
Determine the molarity for each of the following solutions A. 1.8×10^4mg of HCL in 0.075L of solutions
How are animals used in vaccine development?
Answer:
Animals whose certain organs closely match those of humans or have similar genetic makeup are used in vaccine tests because the results can closely resemble those same results on humans.
Explanation:
Answer:
they use them to test the effectiveness of the vaccine.
Explanation:
