Answer:
why are people s opinions and prejudices her greatest obstacles
Arrange the following compounds in order of increasing reactivity (least reactive first.) to electrophilic aromatic substitution:.
Bromobenzene Nitrobenzene Benzene Phenol
a. Bromobenzene < Nitrobenzene < Benzene < Phenol
b. Nitrobenzene < Bromobenzene < Benzene < Phenol
c. Phenol < Benzene < Bromobenzene < Nitrobenzene
d. Nitrobenzene < Benzene < Bromobenzene < Phenol
Answer:
Nitrobenzene < Bromobenzene < Benzene < Phenol
Explanation:
Aromatic compounds undergo electrophilic aromatic substitution reaction in the presence of relevant electrophiles. Certain substituents tend to increase or decrease the tendency of an aromatic compound towards electrophilic aromatic substitution reaction.
Substituents that increase the electron density around the ring such as in phenol tends to make the ring more reactive towards electrophilic substitution. Halogens such as bromine has a -I inductive effect as well as a +M mesomeric effect.
However the -I(electron withdrawing effect) of the halogens supersedes the +M electron donation due to mesomeric effect.
Putting all these together, the order of increasing reactivity of the compounds towards electrophilic aromatic substitution is;
Nitrobenzene < Bromobenzene < Benzene < Phenol
A gas within a piston–cylinder assembly undergoes an isothermal process at 400 K during which the change in entropy is −0.3 kJ/K. Assuming the ideal gas model for the gas and negligible kinetic and potential energy effects, evaluate the work, in kJ.
Answer:
W = -120 KJ
Explanation:
Since the piston–cylinder assembly undergoes an isothermal process, then the temperature is constant.
Thus; T1 = T2 = 400K
change in entropy; ΔS = −0.3 kJ/K
Formula for change in entropy is written as;
ΔS = Q/T
Where Q is amount of heat transferred.
Thus;
Q = ΔS × T
Q = -0.3 × 400
Q = -120 KJ
From the first law of thermodynamics, we can find the workdone from;
Q = ΔU + W
Where;
ΔU is Change in the internal energy
W = Work done
Now, since it's an ideal gas model, the change in internal energy is expressed as;
ΔU = m•C_v•ΔT
Where;
m is mass
C_v is heat capacity at constant volume
ΔT is change in temperature
Now, since it's an isothermal process where temperature is constant, then;
ΔT = T2 - T1 = 0
Thus;
ΔU = m•C_v•ΔT = 0
ΔU = 0
From earlier;
Q = ΔU + W
Thus;
-120 = 0+ W
W = -120 KJ
What is the balanced form of the following equation?
Br2 + S2O32- + H2O → Br1- + SO42- + H+
Answer:
5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺
Explanation:
We will balance the redox reaction through the ion-electron method.
Step 1: Identify both half-reactions
Reduction: Br₂ ⇒ Br⁻
Oxidation: S₂O₃²⁻ ⇒ SO₄²⁻
Step 2: Perform the mass balance, adding H⁺ and H₂O where appropriate
Br₂ ⇒ 2 Br⁻
5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺
Step 3: Perform the charge balance, adding electrons where appropriate
2 e⁻ + Br₂ ⇒ 2 Br⁻
5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻
Step 4: Make the number of electrons gained and lost equal
5 × (2 e⁻ + Br₂ ⇒ 2 Br⁻)
1 × (5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻)
Step 5: Add both half-reactions
5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺
What volume of each solution contains 0.14 mol of KCl? Express your answer using two significant figures.
1.8 M KCl
Answer:
Solution given:
1 mole of KCl[tex]\rightarrow [/tex]22.4l
1 mole of KCl[tex]\rightarrow [/tex]74.55g
we have
0.14 mole of KCl[tex]\rightarrow [/tex]74.55*0.14=10.347g
74.55g of KCl[tex]\rightarrow [/tex]22.4l
10.347 g of KCl[tex]\rightarrow [/tex]22.4/74.55*10.347=3.11litre
volume of each solution contains 0.14 mol of KCl contain 3.11litre.
[tex]\:[/tex]
1 mole of KCl → 22.4l
1 mole of KCl → 74.55g
we have
0.14 mole of KCl → 74.55*0.14=10.347g
74.55g of KCl → 22.4l
10.347 g of KCl → 22.4/74.55*10.347=3.11litre
volume of each solution contains 0.14 mol of KCl contain 3.11litre.
Conversion Problem (show all work):
1. A patient required 3.0 pints of blood during surgery. How many liters does this correspond
to? Show all work. Use conversion factors available in the text or the exam packet. (4)
1.42liters, which is equivalent to 3pints, of blood is required for the surgery
Pints is a unit of measurement for volume in the United States. However, it can be converted to litres using the following equation:1 US pint = 0.473 liters
Hence, according to this question which states that a patient required 3.0 pints of blood during surgery. This means that the patient required:3 × 0.473
= 1.419 liters of blood for the surgery
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An ice cube, measured at 260 Kelvin, is dropped into a cup of tea that is 350 Kelvin. The temperature of the tea is recorded every 30 seconds and shows the temperature dropping for 4 minutes. After 4 minutes the temperature stays steady at 300 Kelvin. What is this called?
A. Thermal equilibrium
B. Specific heat capacity
C. Latent heat
D. Temperature transfer
Answer:
Specific Heat Capacity
385 x 42.13 x 0.079 is (consider significant figures):
385 x 42.13 x 0.079 = 1281.38395
100 mL of 0.2 mol/L sodium carbonate solution and 200 mL of 0.1 mol/L calcium nitrate solution are mixed together. Calculate the mass of calcium carbonate that would precipitate and the concentration of the sodium nitrate solution that will be produced.
Answer:
Explanation:
Na2CO3+Ca(NO3)2=CaCO3+2NaNO3
nNa2CO3=0.02
nCa(NO3)2=0.02
mCaCO3=0.02*100=2 gram
nNaNo3=0.04
Cm=2/15
From the calculation, the mass of the product is 2 g.
What is a reaction?A chemical reaction occurs when two more substances are mixed together. In this case, the reaction is shown by; Ca(NO3)2 + Na2CO3 ----> CaCO3(s) + 2NaNO3.
Number of moles of Na2CO3 = 100/1000 L * 0.2 mol/L = 0.02 moles
Number of moles of Ca(NO3)2 = 200/1000 L * 0.1 mol/L = 0.02 moles
Since the reaction is equimolar, amount of the product = 0.02 moles * 100 g/mol = 2 g
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Write a balanced chemical equation for the reaction that occurs
when:
(a) titanium metal reacts with O21g2;
(b) silver(I) oxide decomposes into silver metal and oxygen gas when heated;
(c) propanol, C3H7OH1l2 burns in air;
(d) methyl tert-butyl ether, C5H12O1l2, burns in air.
Answer:
Explanation:
A balanced chemical equation refers to the reaction taking place whereby the number of atoms associated in the reactants side is equivalent to the number of atoms on the products side.
From the given information, the balanced equations are as follows:
[tex]\mathbf{(a) \ \ \ Ti(s) + O_{2(g)} \to TiO_{2(s)}}[/tex]
[tex]\mathbf{(b) \ \ \ 2Ag_{2}O \to 4Ag_{(s)} + O_{2(g)}}[/tex]
[tex]\mathbf{(c) \ \ \ 2C_3H_7OH + 9O_2 \to 6CO_2+8H_2O}[/tex]
[tex]\mathbf{(d) \ \ \ 2C_5 H_{12}O \to 10 CO_2 + 12 H_2O}[/tex]
15.27
The following equilibria were attained at 823 K:
COO(s) + H2() Co(s) + H2O(g) K = 67
COO(s) + CO(8) = Co(s) + CO2(8) K = 490
Based on these equilibria, calculate the equilibrium con-
stant for
H2(g) + CO2(g) = CO(g) + H2O(g) at 823 K.
The equilibrium constant for the reaction is K = 0.137
We obtain the equilibrium constant considering the following equilibria and their constants:
COO(s) + H₂(g) → Co(s) + H₂O(g) K₁ = 67
COO(s) + CO(g) → Co(s) + CO₂(g) K₂ = 490
We write the first reaction in the forward direction because we need H₂(g) in the reactants side:
(1) COO(s) + H₂(g) → Co(s) + H₂O(g) K₁ = 67
Then, we write the second reaction in the reverse direction because we need CO₂(g) in the reactants side. Thus, the equilibrium constant for the reaction in the reverse direction is the reciprocal of the constant for the reaction in the forward direction (K₂):
(2) Co(s) + CO₂(g) → COO(s) + CO(g) K₂ = 1/490
From the addition of (1) and (2), we obtain:
COO(s) + H₂(g) → Co(s) + H₂O(g) K₁ = 67
+
Co(s) + CO₂(g) → COO(s) + CO(g) K₂ = 1/490
-------------------------------------------------
H₂(g) + CO₂(g) → CO(g) + H₂O(g)
Notice that Co(s) and COO(s) are removed that appear in the same amount at both sides of the chemical equation.
Now, the equilibrium constant K for the reaction that is the sum of other two reactions is calculated as the product of the equilibrium constants, as follows:
K = K₁ x K₂ = 67 x 1/490 = 67/490 = 0.137
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Please help fast
All four referenced Greek thinkers: Democritus, Aristotle, Archimedes, and Anaxagoras, observed Nature and argued for his theory of
the composition of matter and natural laws. Only one of them tested his hypothesis and proposed a natural laws based on reproducible
observations, controlled experiments, and mathematical reasoning. All others used logic and thought experiments, as philosophers do,
to support their theories. Who is the experimental scientist in this group?
O Democritus
O Aristotle
O Archimedes
O Anaxagoras
Answer:
Anaxagoras was perhaps the first literate person to attempt to explain physical phenomena rationally, basing his ideas upon careful observations and simple experiments. This is fundamental to modern science and is the sine qua non of environmental study.
Determine what product will be produced at the negative electrode for the following reaction:
2KCl(aq) + 2H20(1) -> H2(g) + Cl2(g) + 2KOH(aq)
A. H2
B. Cl2
с. КОН
D. K
Answer:
Choice A. [tex]\rm H_{2}[/tex] would be produced at the negative electrode.
Explanation:
Ionic equation for this reaction:
[tex]2\, {\rm K^{+}} + 2\, {\rm Cl^{-}} + {2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm K^{+}} + {\rm 2\, OH^{-}}[/tex].
Net ionic equation:
[tex]2\, {\rm Cl^{-}} + 2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm OH^{-}}[/tex].
Half-equations:
[tex]2\, {\rm Cl^{-}} \to {\rm Cl_{2}} + 2\, {e^{-}}[/tex].
(Electrons travel from the solution to an electrode.)
[tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex].
(An electrode supply electrons to the solution to reduce some of the [tex]\rm H[/tex] atoms from [tex]\rm H_{2}O[/tex].)
In a DC circuit, electrons always enter the circuit from the negative terminal of the power supply and return to the power supply at the positive terminal.
The negative electrode is connected to the negative terminal of the power supply. Electrons from the power supply would flow into the solution through this electrode.
This continuous supply of electrons at the negative electrode would drive a reduction half-reaction. In this question, that corresponds to the reduction of water: [tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {\rm e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex]. Hence, [tex]\rm H_{2}[/tex] would be produced at the negative electrode.
9. Consider a magnesium atom with charge +2. How many overall electrons are on this particle?
Hint: Magnesium's atomic number is 12.
10
12
14
Chad drew a diagram to compare animal cells and bacterial cells.
Which label belongs in the area marked X?
Explanation:
Don't know wwwwmkbnkkkoo
A solution is made by dissolving 0.565 g of potassium nitrate in enough water to make up 250. mL of solution. What is the molarity of this solution?
Please explain and show work.
[tex]\\ \large\sf\longmapsto KNO_3[/tex]
[tex]\\ \large\sf\longmapsto 39u+14u+3(16u)[/tex]
[tex]\\ \large\sf\longmapsto 53u+48u[/tex]
[tex]\\ \large\sf\longmapsto 101u[/tex]
[tex]\\ \large\sf\longmapsto 101g/mol[/tex]
Now
[tex]\boxed{\sf No\:of\:moles=\dfrac{Given\:mass}{Molar\:mass}}[/tex]
[tex]\\ \large\sf\longmapsto No\:of\:moles=\dfrac{0.565}{101}[/tex]
[tex]\\ \large\sf\longmapsto No\:of\:moles=0.005mol[/tex]
We know
[tex]\boxed{\sf Molarity=\dfrac{Moles\:of\:solute}{Vol\:of\:Solution\:in\:L}}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{\dfrac{250}{1000}L}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{0.250}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=0.02M[/tex]
[tex] \: \: \: \: \: \: \: \: \: [/tex]
Select the correct relationship among the concentrations of species present in a 1.0 M aqueous solution of the weak acid represented by HA. A. [H2O] > [HA] > [A-] > [H3O ] > [OH-] B. [H2O] > [A-] ~ [H3O ] > [HA] > [OH-] C. [HA] > [H2O] > [A-] > [H3O ] > [OH-] D. [H2O] > [HA] > [A-] ~ [H3O ] > [OH-] E. [HA] > [H2O] > [A-] ~ [H3O ] > [OH-]
Answer:
D
Explanation:
We have to bear in mind that the acid is a weak acid. A weak acid does not dissociate completely in solution. We will have more concentration of undissociated acid than A^- and H3O^+ and OH^- in the system at equilibrium.
Being a weak acid, there is maximum concentration of water molecules followed by that of undissiociated acid.
Hence, for this solution, the concentration of ions in solution follows the order;
[H2O] > [HA] > [A-] ~ [H3O ] > [OH-]
It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of by-product formed. What is the by-product
Answer:
Biphenyl
Explanation:
The reaction of bromo benzene with magnesium-ether solution yields a Grignard reagent.
The byproduct of this reaction is biphenyl. It is formed when two unreacted bromobenzene molecules are coupled together.
Hence, It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of biphenyl by-product formed.
convert 100kcals to kilojoules
Answer:
Explanation:
418.4kj is the correct answer
Based on the standard EMF series and your knowledge of half-reactions, determine the cell potential and spontanei ty of a cell that consists of a pure cobalt electrode in a solution of Co^2+ ions; the other half is a lead electrode immersed in a Pb^2+ solution.
Pb +2e- Pb Sn +2e Sn Ni 2e Ni Co 2e -0.126 -0.136 -0.250 -0.277 Co
a. +0.403, spontaneous
b. -0.403, nonspontaneous
c. +0.151, spontaneous
d. -0.151, nonspontaneous
Answer:
+0.151, spontaneous
Explanation:
Given that;
Co^2+(aq) + 2e ---->Co(s) -0.28 V
Pb^2+(aq) + 2e ---->Pb(s). -0.13 V
Hence Co is the anode and Pb is the cathode
E°cell = E°cathode - E°anode
So;
E°cell = -0.13 V - (-0.28 V)
E°cell = 0.15 V
The cell reaction is spontaneous since E°cell is positive.
What Volume of silver metal will weigh exactly 2500.0g. The density of silver
Answer:
cm3 = 2500.0 g / 10.5 g/cm3 = 238 cm3
You have been contracted to determine how different salts affect the pH of water. Which of the solids in the following set should you test to investigate for the effects of cations on pH?
a. AlBr3
b. Rb2SO3
c. MgCl2
d. RbBrO
e. CH3NH3Br
Answer:
Hence the solids that should test to investigate the effects of cations on pH is
[tex]AlBr_{3}[/tex] (Cation is Al 3+)
[tex]MgCl_{2}[/tex] ( Cation is Mg 2+)
[tex]CH_{3} NH_{3} Br[/tex] ( Cation is NH2+).
Explanation:
The solids in the following should you test to investigate the effects of cations on pH.
[tex]AlBr_{3}[/tex] contains (Cation is Al 3+)
[tex]MgCl_{2}[/tex] contains ( Cation is Mg 2+)
[tex]CH_{3} NH_{3} Br[/tex] contains( Cation is NH2+ )
The atoms or the molecules containing the positive charge that gets attracted to the cathode are called cations. The compounds a. [tex]\rm AlBr_{3}[/tex], c. [tex]\rm MgCl_{2}[/tex] and e. [tex]\rm CH_{3}NH_{3}Br[/tex] should be investigated.
What are cations and pH?Cations are the positive charge containing molecules and atoms that have more protons in their nucleus than the number of electrons in their shells. They are formed when they lose one or more electrons to another atom.
The addition or release of the electrons of the cations and anions affects the pH system as absorption of the cation decreases the pH and absorption of the anions increases the pH.
Hence, [tex]\rm Al^{3+}[/tex], [tex]\rm Mg^{2+}[/tex] and [tex]\rm NH^{2+}[/tex] are the cation that should be investigated. The addition of the cations will reduce the pH of the reaction.
Therefore, absorption of the cation reduces the pH.
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HELP ASAP 15 POINTS
Why was Dalton's theory of the atom incorrect?
A. Dalton theorized that atoms were indivisible but they are actually made of smaller parts.
B. Dalton theorized that had negative charges spread throughout them but they are actually in electron shells.
C. Dalton' theory was correct.
D. Dalton theorized that atoms were too small to see but they are not.
Answer:
Answer is A.
Explanation:
The indivisibility of an atom was proved wrong: an atom can be further subdivided into protons, neutrons and electrons. According to Dalton, the atoms of same element are similar in all respects. However, atoms of some elements vary in their masses and densities. These atoms of different masses are called isotopes. :)
What must happen to uranium before it can be used as a fuel source?
Answer: Uranium enrichment. Uranium is used to fuel nuclear reactors; however, uranium must be enriched before it can be used as fuel. Enriching uranium increases the amount of uranium-235 (U235) that can sustain the nuclear reaction needed to release energy and produce electricity at a nuclear power plant.
Is a 4p S 4s transition allowed in sodium? If so, what is its wavelength? If not, why not? b. Is a 3d S 4s transition allowed in sodium? If so, what is its wavelength? If not, why not? g
Answer:
a) 4p ⇒ 4s transition is Allowed
b) 3d ⇒ 4s transition not allowed
Explanation:
a) 4p ⇒ 4s transition
This transition is allowed because for a 4p state; l = 1 and for a 4s state I = 0
hence Δl = 1 - 0 = 1
Energy of 4p ( Ei ) = 3.75eV
Energy of 4s ( E2 ) = 3.19 eV
where : λ = 1240 eV nm / ( E₂ - E₁ )
= 2214 nm ≈ 2.214 μm
b) 3d ⇒ 4s transition
This transition is not allowed
a 3d state , l = 2 while for 4s state l = 0
hence Δl = 2 - 0 = 2
therefore the transition is not allowed
A substance is tested and has a pH of 7.0. How would you classify it?
Calculate the numerical value of the equilibrium constant, Kc, for the reaction below if the equilibrium concentrations for CO, H2 , CH4 and H2O are 0.989 M, 0.993 M, 1.078 M and 0.878 M, respectively. (calculate your answer to three sig figs)
CO(g) + 3 H2(g) ⇌ CH4(g) + H2O(g)
Kc = [CH4]×[H2O] / [CO]×[H2]^3
Kc = 1.078×0.878 / (0.989×0.933^3)
Kc = 0.977
The numerical value of the equilibrium constant, Kc, for the given reaction is found to be 0.977.
What is Equilibrium constant?The Equilibrium constant may be defined as the numerical value that significantly indicated the correlation between the amounts of products and reactants present at equilibrium in a reversible chemical reaction at a definite temperature.
According to the question, the reaction is as follows:
[tex]CO +3H_2[/tex] ↔ [tex]CH_4+ H_2O[/tex].
The equilibrium concentrations are 0.989 M, 0.993 M, 1.078 M and 0.878 M, respectively.
Now, the equilibrium constant is calculated by the following formula:
Kc = [CH4]×[H2O] / [CO]×[tex][H_2]^3[/tex]= 1.078×0.878 / (0.989×0.93[tex]3^3[/tex]).
= 0.9464/(0.989 × 0.8121)
= 0.977.
Therefore, the numerical value of the equilibrium constant, Kc, for the given reaction is found to be 0.977.
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help me in my hw,wt is physical change and chemical change Answer it asap plz don't spam
Answer:
Sorry but i don't undertsnad the question.
Explanation:
Answer:
A physical change is a change to the physical—as opposed to chemical—properties of a substance. They are usually reversible. The physical properties of a substance include such characteristics as shape, color, texture, flexibility, density, and mass.
A chemical change happens when one chemical substance is transformed into one or more different substances, such as when iron becomes rust.
Do u want examples ?
A graph of gas pressure versus the number of particles in a container is a straight line. Which other relationship will have a similar graph?
Answer:
volume versus temperature, because they are also directly proportional.
Explanation:
Just took the test!
HBr can be added to an alkene in the presence of peroxides (ROOR). What function does the peroxide serve in this reaction
Answer:
Radical chain initiator
Explanation:
The peroxide here serves as a radical chain initiator. In the field of chemistry the radical initiatives are those substances that are used in industrial processes like polymer synthesis. These initiatives have weak bonds generally and they're mostly used to create free radicals. These radicals are atoms that have odd numbers of electrons. Peroxide is an example of such.
What type of bond is present in NBr?
Answer:
Covalent bonding and non-covalent bonding
