Answer:
Exothermic ProcessExplanation:
Prepare a flow diagram for extraction of 2-chlorobenzoic acid and 1,4-dichlorobenzene.
Answer:
See explanation below
Explanation:
To do aflow diagram for extraction of these two components of a sample, we need to analize both reagents so we can make a great diagram and separate both reagents.
First, let's see the acid. The 2-chlorobenzoic acid is a relativel strong acid, so, in order to separate this from a sample we need to use a base to do so. However, it's very important the use of the base here, we cannot use any base to do it, for the main reason that the sample has other component, and this component may react too with the base and the separation will not be succesfull. So, as the chlorobenzoic acid is a relatively strong acid, if we use a strong base such as NaOH, this will react with the acid, but it will also react with the 1,4-dichlorobenzene forming a Sn2 product and a salt like this.
C₆H₄Cl₂ + NaOH ---------> C₆H₅OCl + NaCl
This is the reason which we cannot use NaOH, because it's a strong base that may react with other compounds in the sample.
To solve this, we can use a weak base such as NaHCO₃. This weak base has the strength enough to react with the benzoic acid, but not strong enough to react with the dichlorobenzene.
So, the first step is dissolve the sample in an organic solvent like ether. The next step is mixing the sample with NaHCO₃. This will cause the layer to divide into two layers. One aqueous layer that will have the product of the acid with the base, and an organic layer with the dichlobenzene. Afterward, we just need to use a strong acid like HCl, but dilluted in the aqueous layer to regenerate the acid, and in the organic layer, just heat the solution til the whole solvent evaporates completely.
The flow diagram is below in the attached picture.
You weighed out 0.020 g of your crude aspirin product in order to determine the amount of salicylic acid impurity. Following the procedure outlined in the manual, you dissolved the solid and diluted the solution to a final volume of 10.0 mL. If the absorbance of your sample solution was 1.07, what was the percent salicylic acid in your product
Answer:
The correct answer is 7.8 percent.
Explanation:
As mentioned in the given question, the absorbance (A) of the sample solution is 1.07. To find the concentration of aspirin, Beer's law is used, that is, A = ebc
Here, e is the extinction coefficient, which is equal to 139.322 M^-1cm^-1 as per the standard value for salicylic acid, b is the pathlength, which is equivalent to 1 cm. Now putting the values we get,
A = ebc
c = A / (eb)
c = 1.07 / (139.322 × 1)
c = 0.00768 M
Now to determine the percent salicylic acid in the sample, there is a need to compare the value of concentration determined with the concentration of aspirin given initially.
0.02 grams is the initial concentration of aspirin mentioned in the question. The molar mass of aspirin is 240 g/mol.
Therefore, the moles of aspirin will be,
0.02 / 240 = 8.33 × 10^-5 moles
The final volume of the diluted solution given is 10 ml or 0.01 liters.
The molarity of aspirin in the diluted solution will be,
c1 = 8.33 × 10^-5 / 0.01 = 8.33 × 10^-3 M or 0.00833 M
Now, the percent of salicylic acid in the product will be,
c1 - c / c1 × 100
(0.00833 - 0.00768) / 0.00833 × 100 = 7.8 %
Absorbance is directly proportional to the concentration of the solution. The absorbance can be calculated if the molar absorptivity, path length, and concentration of the absorbing species are known.
The percent of salicylic acid in the solution is 7.8%
Given that:
Absorbance of the solution is = 1.07
Path length = 1 cm.
Applying Beer's Law,
A = ε b c
where,
c = concentration, A = absorbance, ε = constant, and b = path length
Now, putting the values in above equation
c = [tex]\dfrac{\text{A}}{\text {(e b)}}[/tex]
c = [tex]\dfrac{1.07}{139.32 \times 1}[/tex] ( ε = 139.32)
c = 0.00768 M
Now, to calculate the percent of the salicylic acid in the solution, we will compare the given concentration of the aspirin.
As we know:
Given mass of aspirin = 0.02 g
Molar mass of aspririn = 240
Number of moles of aspirin = 0.02 / 240 = 8.33 x 10⁻⁵
Now, the molarity of aspirin is:
[tex]\text{Molarity}&= \dfrac{8.33 \times 10^{-5}}{0.01}\\\\\text{Molarity}&= 8.33 \times 10^{-5}[/tex]
Now, the percent of the salicylic acid is:
[tex]\dfrac{\text {C}_1 - \text C}{\text {C}_1 \times 100}[/tex]
[tex]\dfrac{(0.00833 - 0.00768)}{0.00833 \times 100}[/tex]
Percent of Salicyclic acid = 7.8%.
Thus, the percentage of the salicylic acid in the given solution is 7.8%.
To know more about Absorbance, refer to the following link:
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The percent yield of a reaction in which 52 grams of a reactant is expected to yield 30 grams of product is 25%. What is the actual yield of the reaction? A) 13 grams B) 120 grams C) 208 grams D) 7.5 grams
Answer:
D) 7.5 grams
Explanation:
Hello,
In this case, since the percent yield is defined by:
[tex]Y=\frac{m^{actual}}{m^{theoretical}} *100\%[/tex]
In such a way, since the percent yield is up to 25% and the expected or theoretical amount is 30 g of the product, the actual yield of the reaction is:
[tex]m^{actual}=\frac{Y*m^{theoretical}}{100\%} =\frac{25\%*30g}{100\%} \\\\m^{actual}=7.5g[/tex]
Therefore the answer is D) 7.5 grams.
Best regards.
How many grams do 4.8 x 1026 atoms of silicon
weigh?
Answer in units of g.
Common additives to drinking water include elemental chlorine, chloride ions, and phosphate ions. Recently, reports of elevated lead levels in drinking water have been reported in cities with pipes that contain lead, Pb(s). When Cl2(aq) flows through a metal pipe containing Pb(s), some of the lead atoms oxidize, losing two electrons each, and aqueous chloride ions form. (a) Write a balanced, net-ionic equation for the reaction between Pb(s) , and Cl2(aq).
Answer:
See explaination
Explanation:
Balanced net ionic reaction.
Pb(s) + Cl2(g) ----- Pb2+ + 2Cl-
oxidation reaction :Pb(s) --- Pb2+ + 2e-
Reduction reaction:Cl2 + 2e- -----Cl-
What is the ideal pH level for your blood?
What is the concentration of a solution in which 0.99 g of KOH are dissolved in 500 mL?
Answer:
.00352mol/L
Explanation:
molarity (concentration) = number of moles / volume of solvent (in L)
M = .99g / 56.108g/mol / .5L
M = .0176mol / .5L
M = .00352mol/L
methane Express your answer as a condensed structural formula omitting all bonds (e.g CH3CH2CH3). nothing Request Answer Part B ethane Express your answer as a condensed structural formula omitting all bonds (e.g CH3CH2CH3). nothing Request Answer Part C pentane Express your answer as a condensed structural formula omitting all bonds (e.g CH3CH2CH3). nothing Request Answer Part D cyclopropane Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. Include all hydrogen atoms.
Answer:
a
The condensed structural formula for methane is
[tex]CH_4[/tex]
b
The condensed structural formula for ethane is
[tex]CH_3 CH_3[/tex]
c
The condensed structural formula for pentane is
[tex]CH_2(CH_2)_3CH_3[/tex]
d
The diagram for the structural formula for cyclopropane is shown on the first uploaded image
Explanation:
1. A substance that gets dissolved to create a solution is best described as to
as
Answer:
Solute
Explanation
A substance that gets dissolved to create a solution is best described as to as
A child shivers in a cold rain but does not feel cold, what is the biochemistry behind it
Due to prokaryote
Explanation:
Problem PageQuestion Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 500. mL flask with 1.3 atm of sulfur dioxide gas and 4.1 atm of oxygen gas, and when the mixture has come to equilibrium measures the partial pressure of sulfur trioxide gas to be 0.91 atm. Calculate the pressure equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits.
Answer:
SO₂: 0.39atm
O₂: 3.645atm
Explanation:
Based on the reaction:
2 SO₂(g) + O₂(g) → 2 SO₃(g)
2 moles of sulfur dioxide react per mole of oxygen to produce 2 moles of sulfur trioxide.
When the reaction occurs an comes to equilbrium, the partial pressure of each gas is:
SO₂: 1.3atm - 2X
O₂: 4.1atm -X
SO₃: 2X
Where X is the reaction coordinate.
As pressure at equilibrium of SO₃ is 0.91 atm:
0.91atm = 2X
Thus: X = 0.455atm.
Replacing, pressures at equilibrium of the gases are:
SO₂: 1.3atm - 2×0.455atm = 0.39 atm
O₂: 4.1atm -0.455atm = 3.645 atm
Gaseous butane will react with gaseous oxygen to produce gaseous carbon dioxide and gaseous water . Suppose 42. g of butane is mixed with 150. g of oxygen. Calculate the maximum mass of carbon dioxide that could be produced by the chemical reaction. Round your answer to significant digits.
Answer:
127 grams of carbon dioxide
Explanation:
We need to determine the chemical equation first. Butane has a chemical formula of [tex]C_4H_{10}[/tex], oxygen is [tex]O_2[/tex], carbon dioxide is [tex]CO_2[/tex], and water is [tex]H_2O[/tex]. The reactants are butane and oxygen and the products are carbon dioxide and water. So we write:
[tex]C_4H_{10}+O_2[/tex] ⇒ [tex]CO_2+H_2O[/tex]
But remember! We need to balance this. Currently, there are 4 carbon atoms (C), 10 hydrogen atoms (H), and 2 oxygen atoms (O) on the left, while there are 1 carbon atom (C), 2 hydrogen atoms (H), and 3 oxygen atoms (O) on the right. Let's place a coefficient of 4 in front of the carbon dioxide and a coefficient of 5 on the water, so that we have equal numbers of carbon and hydrogen atoms on each side:
[tex]C_4H_{10}+O_2[/tex] ⇒ [tex]4CO_2+5H_2O[/tex]
However, we need to ensure that there are equal numbers of O atoms, as well. On the left, we have 2 and on the right we have 13, so let's put a coefficient of 6.5 on the oxygen:
[tex]C_4H_{10}+6.5O_2[/tex] ⇒ [tex]4CO_2+5H_2O[/tex]
Finally, multiply everything by 2 to get whole number coefficients:
[tex]2C_4H_{10}+13O_2[/tex] ⇒ [tex]8CO_2+10H_2O[/tex]
Ah, now we can actually get to the problem!
We need to determine the limiting reactant, so let's convert the 42 g of butane and 150 g of oxygen into moles of any product, say, carbon dioxide. To convert to moles, we need to find the molar mass of each compound.
The molar mass of butane is 4 * 12.01 + 10 * 1.01 = 58.14 g/mol, while the molar mass of oxygen is 2 * 16 = 32 g/mol. We can now set up the equations:
[tex]42 gC_4H_{10}*\frac{1molC_4H_{10}}{58.14gC_4H_{10}} *\frac{8molCO_2}{2molC_4H_{10}} =2.8896molCO_2[/tex]
[tex]150 gO_2*\frac{1molO_2}{32gO_2} *\frac{8molCO_2}{13molO_2} =2.8846molCO_2[/tex]
Clearly, we see that 2.8846 < 2.8896, which means that oxygen is the limiting reactant. In other words, the most products can be made when the oxygen is all used up.
Now let's finally convert moles of carbon dioxide into grams by multiplying by its molar mass, which is 12.01 + 2 * 16 = 44.01 g/mol:
[tex]2.8846molCO_2*\frac{44.01gCO_2}{1molCO_2} =127gCO_2[/tex]
Notice that we have 3 significant figures because we had 3 significant figures at the start with 150. grams of oxygen.
~ an aesthetics lover
0.5 moles of CO2 have a volume of 50 L and a pressure of 0.8210 atm. What must be the temperature of the gas?
Answer:
1000 K
Explanation:
Given data
Moles of carbon dioxide (n): 0.5 molesVolume of carbon dioxide (V): 50 litersPressure of carbon dioxide (P): 0.8210 atmospheresTemperature of carbon dioxide (T): ?We can find the temperature of carbon dioxide using the ideal gas equation.
[tex]P \times V = n \times R \times T\\T = \frac{P \times V}{n \times R} = \frac{0.8210atm \times 50L}{0.5mol \times \frac{0.08206atm.L}{mol.K} }=1000 K[/tex]
The temperature of the gas is 1000 K.
If you start with 6 mol of nitrogen gas (N2+) what mass (g) of ammonia (NH4) will be produced?
Answer:
204g of NH3
Explanation:
The balanced equation for the reaction is given below:
N2 + 3H2 —> 2NH3
Next, we shall determine the number of mole NH3 produced by reacting 6moles of N2. This is illustrated below:
From the balanced equation above,
1 mole of N2 reacted to produce 2 moles of NH3.
Therefore, 6 moles of N2 will react to produce = 6 x 2 = 12 moles of NH3.
Finally, we shall convert 12 moles of NH3 to grams. This is illustrated below:
Number of mole of NH3 = 12 moles.
Molar mass of NH3 = 14 + (3x1) = 17g/mol
Mass of NH3 =..?
Mass = mole x molar mass
Mass of NH3 = 12 x 17
Mass of NH3 = 204g.
Therefore, 204g of NH3 will be produced from the reaction.
You have 0.00891 g of platinum. What is this in micrograms?
A sample of gas at occupies 10m3 at a pressure of 120 kPa. If the volume of the sample is changed to 3m3, what is the new pressure of the gas?
Answer:
400 kPa
Explanation:
Please see the step-by-step solution in the picture attached below.
Hope this answer can help you. Have a nice day!
Answer:
400 kPa
The answer is right since its from ck12
2. What happens to the pH when you add more H+ ions to a solution that has no buffers?
How is a niche different than a habitat?
A habitat is more than a physical place; it's a species' role in a specific place and it can change from niche to niche.
A niche is more than a physical place; it's a species' role in a specific place and it can change from habitat to habitat.
A niche and a habitat are the same.
A niche is just a physical place; a habitat is a species' role in a specific place.
Answer:
A niche is more than a physical place; it's a species' role in a specific place and it can change from habitat to habitat.
Explanation:
Niche: In biology, the term "niche" is described as a process through which different organisms tends to fit-in into a specific ecosystem or an ecological community. However, a niche is considered as the "evolutionary result" of a specific species behavioral, morphological, and physiological adaptations associated with its surroundings.
Habitat: In biology, the term "habitat" is described as an environmental or ecological area that is being inhabited by a specific species of plants, animals, or other organisms.
Therefore, a niche is entirely different from a habitat because an organism's niche tends to explain every different aspect of its life whereas its habitat explains the place it lives.
In a titration, 100 mL of 0.026 M HCl (aq) is neutralized by 13 mL of KOH(aq). Calculate the molarity of KOH (aq).
Answer:
0.2M
Explanation:
Step 1:
Data obtained from the question.
Volume of acid (Va) = 100mL
Molarity of the acid (Ma) = 0.026 M
Volume of base (Vb) = 13mL
Molarity of the base (Mb) =..?
Step 2:
The balanced equation for the reaction. This is given below:
HCl + KOH —> KCl + H2O
From the balanced equation above,
The mole ratio of the acid (nA) = 1
The mole ratio of the base (nB) = 1
Step 3:
Determination of the molarity of the base, KOH. This can be obtained as follow:
MaVa/MbVb = nA/nB
0.026 x100 / Mb x 13 = 1
Cross multiply to express in linear form
Mb x 13 = 0.026 x 100
Divide both side by 13
Mb = 0.026 x 100 / 13
Mb = 0.2M
Therefore, the molarity of the base, KOH is 0.2M
Answer:
0.2M
Explanation:
KOH(aq) + HCl(aq) ⇒ KCl(aq) + H2O(l)
We express the moles of analyte (HCl) and titrant based (KOH) on their molar concentration:
M1 * V1 = M2 * V2
The molarity of the solution is calculated with the following equation:
M2 = V1 x M1 / V2
Where:
V2 = valued sample volume
V1 = volume of titrant consumed (measured with the burette)
M1 = concentration of titrant solution
M2 = concentration of sample
M2 = 100mL * 0.026M / 13mL = 0.2M
a fertilizer manufacturer makes a batch of 20kg of ammonium nitrate. what mass of ammonia in kg, does the manufacturer need to start with?
Answer:
[tex]m_{NH_3}=4.25kgNH_3[/tex]
Explanation:
Hello,
In this case, for the production of ammonium nitrate we shall consider the following chemical reaction:
[tex]NH_3+HNO_3\rightarrow NH_4NO_3[/tex]
Hence, since the molar mass of ammonium nitrate is 80 g/mol and the molar mass of ammonia is 17 g/mol, we could compute the required mass of ammonia to produce 20 kg of ammonium nitrate by using kilo-based units:
[tex]m_{NH_3}=20kgNH_4NO_3*\frac{1kmol}{80kgNH_4NO_3}*\frac{1kmolNH_3}{1kmolNH_4NO_3}*\frac{17kgNH_3}{1kmolNH_3} \\\\m_{NH_3}=4.25kgNH_3[/tex]
Best regards.
The temperature of a 350. mL sample of gas increases from 27 °C to 227 °C. What is the final volume of the sample of gas, if the pressure and amount of gas in the container is kept constant?
Group of answer choices
Answer:
[tex]V_2=583.3mL[/tex]
Explanation:
Hello,
In this case, for the given constant amount and pressure of the, we apply the Charles' law which allows us to understand the volume-pressure behavior as a directly proportional relationship:
[tex]\frac{V_1}{T_1} =\frac{V_2}{T_2}[/tex]
Thus, since we need to compute the volume after the temperature increase (which must be expressed in absolute Kelvins), we obtain V2 as:
[tex]V_2=\frac{V_1T_2}{T_1} =\frac{350.0mL*(227+273.15)K}{(27+273.15)K}\\ \\V_2=583.3mL[/tex]
Best regards.
Draw the structure of a compound with the molecular formula CgH1002 that exhibits the following spectral data.
(a) IR: 3005 cm-1, 1676 cm-1, 1603 cm-1
(b) H NMR: 2.6 ppm (singlet, I = 3H), 3.9 ppm (singlet, I = 3H), 6.9 ppm (doublet, I = 2H), 7.9 ppm (doublet, I = 2H)
(c) 13C NMR: 26.2, 55.4, 113.7, 130.3, 130.5, 163.5, 196.6 ppm ?
Answer:
The answer you are looking for is A
what is the reaction?
Answer:
A chemical reaction is a process in which one or more substances, also called reactants, are converted to one or more different substances, known as products. ... A chemical reaction rearranges the constituent atoms of the reactants to create different substances as products.
Explanation:
Hopefully this is what you needed
Identifying the Body's Responses to
Quick
Check
Which type of response identifies a specific pathogen in the body?
A(n)
response
Answer:
Specific Immune Response
Explanation:
A specific immune response identifies the pathogen which then allows it to produce antibodies that protect against that SPECIFIC pathogen.
Answer:
immuneExplanation:
Why did the Mt. Pinatubo eruption result in global temperatures dropping almost two degrees?
Answer:
In the case of Mount Pinatubo, the result was a measurable cooling of the Earth's surface for a period of almost two years. Because they scatter and absorb incoming sunlight, aerosol particles exert a cooling effect on the Earth's surface.
Explanation:
Temperature measures the average kinetic energy of particles of the substances. Therefore, the Mt. Pinatubo eruption result in global temperatures dropping almost two degrees.
What is temperature?Temperature is used to measure degree or intensity of heat of a particular substance. Temperature is measured by an instrument called thermometer.
Temperature can be measured in degree Celsius °c, Kelvin k or in Fahrenheit. Temperature is a physical quantity. Heat always flow from higher temperature source to lower temperature source.
We can convert these units of temperature into one another. The relationship between degree Celsius and Fahrenheit can be expressed as:
°C={5(°F-32)}÷9
The Mt. Pinatubo eruption result in global temperatures dropping almost two degrees because they scatter and absorb incoming sunlight, aerosol particles exert a cooling effect on the Earth's temperature.
Therefore, the Mt. Pinatubo eruption result in global temperatures dropping almost two degrees.
To know more about temperature, here:
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What should happen if a good experiment is replicated?
The results will decrease.
The results will increase.
The results will be different.
The results will be similar.
Answer:
The results will be similar.
Question 17 In the Haber reaction, patented by German chemist Fritz Haber in 1908, dinitrogen gas combines with dihydrogen gas to produce gaseous ammonia. This reaction is now the first step taken to make most of the world's fertilizer. Suppose a chemical engineer studying a new catalyst for the Haber reaction finds that 786. liters per second of dinitrogen are consumed when the reaction is run at 222.°C and 0.35atm. Calculate the rate at which ammonia is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits.
Answer:
Explanation:
N₂ + 3H₂ = 2 NH₃
1 vol 2 vol
786 liters 1572 liters
786 liters of dinitrogen will result in the production of 1572 liters of ammonia
volume of ammonia V₁ = 1572 liters
temperature T₁ = 222 + 273 = 495 K
pressure = .35 atm
We shall find this volume at NTP
volume V₂ = ?
pressure = 1 atm
temperature T₂ = 273
[tex]\frac{P_1V_1}{T_1} =\frac{P_2V_2}{T_2}[/tex]
[tex]\frac{.35\times 1572}{495} =\frac{1\times V_2}{ 273 }[/tex]
[tex]V_2 =303.44[/tex] liter .
mol weight of ammonia = 17
At NTP mass of 22.4 liter of ammonia will have mass of 17 gm
mass of 303.44 liter of ammonia will be equal to (303.44 x 17) / 22.4 gm
= 230.28 gm
=.23 kg / sec .
Rate of production of ammonia = .23 kg /s .
dentify the missing information for each atom or ion. Note that the atoms and ions are not necessarily neutral. A Se ion has a mass number of 78 and a charge of −2 . Determine the number of neutrons, protons, and electrons in this ion. number of neutrons: 44 number of protons: 34 number of electrons: 36 An ion has a mass number of 65, 36 neutrons, and a charge of +1 . Identify the element symbol, and determine the number of protons and electrons in this ion. element symbol: Cu number of protons: 30 number of electrons: 29 An atom or ion has 43 neutrons , 36 protons, and 36 electrons. Identify the element symbol, and determine the mass number and charge for this atom or ion. element symbol: Au mass number: 79 charge: 0
Answer:
Check the explanation
Explanation:
1)
Atomic number of Se = 34
So, number of proton = 34
use:
charge = number of proton - number of electron
-2 = 34 - number of electron
number of electron = 36
number of neutron = mass number - atomic number
= 78 - 34
= 44
Answer:
44
34
36
2)
number of proton = mass number - number of neutron
= 65 - 36
= 29
29 is atomic number for Cu
use:
charge = number of proton - number of electron
+1 = 29 - number of electron
number of electron = 28
Answer:
Cu
29
28
3)
Atomic number is 36 for Kr
use:
charge = number of proton - number of electron
= 36 - 36
= 0
use:
mass number = number of proton + number of neutron
= 36 + 42
= 78
Answer:
Kr
78
0
CH³C⁴HCOCH³ how many atoms of each element are in one molecule of 2-heptanone
Answer:
- 7 carbon atoms.
- 14 hydrogen atoms.
- 1 oxygen atom.
Explanation:
Hello,
In this case, for the given compound, heptanone, whose chemical formula is:
[tex]CH_3COCH_2CH_2CH_2CH_2CH_3[/tex]
We can write the molecular formula showing the present atoms of each element:
[tex]C_7H_{14}O[/tex]
In such a way we have:
- 7 carbon atoms.
- 14 hydrogen atoms.
- 1 oxygen atom.
Best regards.
Metamorphic rocks directly form from
Answer:
Metamorphic rocks are formed from pre-existing rock and sediment materials. They are formed when igneous, sedimentary, or other pre-existing metamorphic rocks are exposed to the heat and pressure as well as super-heated mineral-rich fluids. They are compacted together to form a new rock altogether. Metamorphism does not include the melting or liquefaction of the pre-existing rock. Instead, it compacts them and crushes them, pushing them together at extreme heat and pressure to form a new rock altogether composed of sedimentary, igneous, and other metamorphic rock. It's the rock hybrid of the geologic world.
Metamorphism is similar to when you squish playdough together, it doesn't form a new playdough color (unless you REALLY mixed that poor playdough together). It forms an amalgamation of different colors and patterns made from the other rock.
Taken from a paper I once wrote I explained this again:
"Metamorphic rocks are formed when pre-existing rocks and their minerals are compressed and altered by Earth’s internal processes; interior pressure, temperature (heat), and chemical reactions. The minerals and pre-existing rock necessary for the creation of metamorphic rock must then also be located deep underground if such processes are expected to make an impact and create a metamorphic rock."