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Hydrazine, , emits a large quantity of energy when it reacts with oxygen, which has led to hydrazine used as a fuel for rockets: How many moles of each of the gaseous products are produced when 20.1 g of pure hydrazine is ignited in the presence of 20.1 g of pure oxygen
Answer:
[tex]1.25~mol~H_2O[/tex] and [tex]0.627~mol~N_2[/tex]
Explanation:
Our goal for this question is the calculation of the number of moles of the molecules produced by the reaction of hydrazine ([tex]N_2H_4[/tex]) and oxygen ([tex]O_2[/tex]). So, we can start with the reaction between these compounds:
[tex]N_2H_4~+~O_2~->~N_2~+~H_2O[/tex]
Now we can balance the reaction:
[tex]N_2H_4~+~O_2~->~N_2~+~2H_2O[/tex]
In the problem, we have the values for both reagents. Therefore we have to calculate the limiting reagent. Our first step, is to calculate the moles of each compound using the molar masses values (32.04 g/mol for [tex]N_2H_4[/tex] and 31.99 g/mol for [tex]O_2[/tex]):
[tex]20.1~g~N_2H_4\frac{1~mol~N_2H_4}{32.04~g~N_2H_4}=0.627~mol~N_2H_4[/tex]
[tex]20.1~g~O_2\frac{1~mol~O_2}{31.99~g~O_2}=0.628~mol~O_2[/tex]
In the balanced reaction we have 1 mol for each reagent (the numbers in front of [tex]O_2[/tex] and [tex]N_2H_4[/tex] are 1). Therefore the smallest value would be the limiting reagent, in this case, the limiting reagent is [tex]N_2H_4[/tex].
With this in mind, we can calculate the number of moles for each product. In the case of [tex]N_2[/tex] we have a 1:1 molar ratio (1 mol of [tex]N_2[/tex] is produced by 1 mol of [tex]N_2H_4[/tex]), so:
[tex]0.627~mol~N_2H_4\frac{1~mol~N_2}{1~mol~N_2H_4}=~0.627~mol~N_2[/tex]
We can follow the same logic for the other compound. In the case of [tex]H_2O[/tex] we have a 1:2 molar ratio (2 mol of [tex]H_2O[/tex] is produced by 1 mol of [tex]N_2H_4[/tex]), so:
[tex]0.627~mol~N_2H_4\frac{2~mol~H_2O}{1~mol~N_2H_4}=~1.25~mol~H_2O[/tex]
I hope it helps!
The condition that a reaction takes place without outside help Choose... Solution in which no more solute can be dissolved in the solvent Choose... Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature Choose... The extent of randomness in a system Choose... Sum of the internal energy plus the product of the pressure and volume for a reaction
Answer:
Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature
Explanation:
The basis of spontaneity in a chemical reaction is that ∆G must be negative. ¡∆G is known as the change in free energy of a system. If ∆G is negative, then the reaction will occur without any external help (the reaction is spontaneous at room temperature).
∆G is given by;
∆G= ∆H -T∆S
Where;
∆H= change in enthalpy of the system
T= absolute temperature of the system
∆S= change in entropy
Hence; when ∆H -T∆S gives a negative result, the reaction proceeds without any external help.
Calculate the entropy change in the surroundings associated with this reaction occurring at 25∘C. Express the entropy change to three significant figures and include the appropriate units.
Answer:
That means that if you are calculating entropy change, you must multiply the enthalpy change value by 1000. So if, say, you have an enthalpy change of -92.2 kJ mol-1, the value you must put into the equation is -92200 J mol-1
The entropy change in the surroundings associated with this reaction occurring at 25 degree C is calculated as ΔS = -ΔH/T J/K.
What is entropy?Entropy is a quantity which gives idea about the randomness or arrangement of atoms or molecules present in any sample.
Entropy change will be calculated as:
ΔS = -ΔH/T, where
ΔH = chnage in enthalpy (J/mole)
T = temperature (K)
So to calculate the entropy change first we have to know about the value of enthalpy in joules and then divide it by the temperature.
Hence the unit of entropy is joule per kelvin.
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A galvanic cell consists of a Cu(s)|Cu2+(aq) half-cell and a Cd(s)|Cd2+(aq) half-cell connected by a salt bridge. Oxidation occurs in the cadmium half-cell. The cell can be represented in standard notation as
Answer:
[tex]Cd(s)|Cd^{2+}(aq) || Cu^{2+}(aq)|Cu(s)[/tex]
Explanation:
A galvanic cell is composed of two electrodes immersed in a suitable electrolyte and connected via a salt bridge. One of the electrodes serves as a cathode where reduction or gain of electrons takes place. The other half cell functions as an anode where oxidation or loss of electrons occurs.
The representation is given by writing the anode on left hand side followed by its ion with its molar concentration. It is followed by a salt bridge. Then the cathodic ion with its molar concentration is written and then the cathode.
As it is given that cadmium acts as anode, it must be on the left hand side and copper must be on right hand side.
[tex]Cd(s)|Cd^{2+}(aq) || Cu^{2+}(aq)|Cu(s)[/tex]
I add a 50. g piece of Al (c = 0.88 J/g-deg) that is at 225°C to 100. mL of water at 20°C. What is the final temperature of the water in °C? The density of water is approximately 1g/mL.
Answer:
THE FINAL TEMPERATURE OF WATER IS -4.117 °C
Explanation:
Mass of the aluminium = 50 g
c = 0.88 J/g C
Initial temperature of aluminium = 225 °C
Volume of water = 100 ml
Density of water = 1 g/ml
Mass of water = density * volume of water
Mass of water = 1 * 100 = 100 g of water
Initial temperature of water = 20 C
It is worthy to note that the heat of a system is constant and conserved as no heat is lost or gained by a closed system,
So therefore,
heat lost by aluminium = heat gained by water
H = mass * specific heat capacity * temeprature change
So:
m c ( T2- T1) = m c (T2-T1)
50 * 0.88 * ( T2 - 225) = 100 * 4.18 *( T2 - 20)
44 ( T2 - 225 ) = 418 ( T2 - 20)
44 T2 - 9900 = 418 T2 - 8360
-9900 + 8360 = 418 T2 - 44 T2
-1540 = 374 T2
T2 = - 4.117
So therefore the final temperature of water is -4.117 °C
The direction of the functional group is called?
Explanation:
they are called hydrocarbyls
pls mark me brainliest
Answer:
The first carbon atom that attaches to the functional group is referred to as the alpha carbon.
A baseball has a mass of 0.145 kilograms. If acceration due to gravity is 9.8m/s,what is the weight of the baseball in newtons?
Answer:
I hope it works
Explanation:
As we know that
w=m*g
given m=0.145 , g=9.8
hence we get
w= (9.8)*(0.145)
w=1.421 m/sec 2
if its help-full thank hit the stars and brain-list it thank you
Candle wax melts low temperature, it is not conductive to electricity, it is insoluble in water and partially soluble in solvents nonpolar, like gasoline. Than type of links are present in the candle wax?
A. Electrostatics.
B. Apolar.
C. lónicos.
D. Hydrogen bridges.
electrostatic and ionic are definitely not the answer because they have high melting point
hydrogen bonds are too weak and not permanent.
so the answer is apolar as it is soluble in polar solvents (water)
Answer:
B. Nonpolar
Explanation:
The low melting point tells you the compound is not ionic, metallic, or a network solid.
It is almost certainly a molecular solid.
It does not conduct electricity, so it is not metallic (which we have already ruled out).
It is insoluble in polar solvents (water) and soluble in nonpolar solvents (gasoline).
Since like dissolves like, the molecule is nonpolar.
The type of links must be nonpolar.
In the experiment students will create solutions with different ratios of ethanol and water. What is the mole fraction of ethanol when 10.00 mL of pure ethanol is combined with 2.00 mL of water
Answer:
[tex]x_{et}=0.6068[/tex]
Explanation:
Hello,
In this case, since the mole fraction of a compound, in this case ethanol, in a binary mixture, in this constituted by both water and ethanol, is mathematically defined as follows:
[tex]x_{et}=\frac{n_{et}}{n_{et}+n_{w}}[/tex]
Whereas [tex]n[/tex] accounts for the moles in the solution for each species, we must first compute the moles of both ethanol (density: 0.789 g/mL and molar mass: 46.07 g/mol) and water (density: 1g/mL and molar mass: 18.02 g/mol)
[tex]n_{et}=10.00mL\ et*\frac{0.789g\ et}{mL\ et} *\frac{1mol\ et}{46.07g\ et}=0.1713mol\ et\\ \\n_w=2.00mL\ w*\frac{1g\ w}{mL\ w} *\frac{1mol\ w}{18.02g\ w}=0.1110mol\ w[/tex]
Therefore, the mole fraction turns out:
[tex]x_{et}=\frac{0.1713mol}{0.1713mol+0.1110mol}\\\\x_{et}=0.6068[/tex]
Best regards.
Which of the following types of electromagnetic radiation have higher frequencies than visible light and which have shorter frequencies than visible light? Sort them accordingly. ltems (6 items) (Drag and drop into the appropriate area below)
a. Gamma rays
b. Infrared radiation
c. Ultraviolet liht
d. X-rays
e. Microwaves
f. Radio waves
Answer:
Higher frequency than visible light - Ultraviolet light, X-rays, and Gamma rays
Lower frequency than visible light - Infrared radiation, microwaves, and Radio waves
Explanation:
The frequencies of electromagnetic radiations vary according to their wavelengths. The relationship between the frequency and wavelength of the waves is expressed such that:
λ = c/f, where λ = wavelength, c = speed of light, and f = frequency.
Thus, there is an inverse relationship between the wavelength and the frequency of electromagnetic waves.
The order of the electromagnetic waves based on their frequency from the lowest to the highest is radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma-rays
Hence, electromagnetic waves with higher frequencies than visible light include ultraviolet light, X-rays, and Gamma rays while those with lower frequencies include Infrared radiation, microwaves, and Radio waves.
Answer:
need points
Explanation:
What is advertising used for? Check all that apply. influencing consumer tastes tracking product popularity increasing product awareness promoting company branding gathering data about potential consumers
Answer:
influencing consumer tastes
increasing product awareness
promoting company branding
Explanation:
Advertising is basically a form of communication using creative ideas and communicating benefits of the products. Advertising plays a very crucial role in product business and some of the important uses of advertising are as follows:
Creative advertisements, influence customers or consumers to buy the product.Advertisings involve information regarding the product and so increases product awareness.Advertising on social media platforms, TVs, radio and newspapers, promotes company branding.Hence, the correct options are:
influencing consumer tastesincreasing product awarenesspromoting company branding
Answer:
1,3,4
Explanation:
I took the test
Consider the following reaction at 298.15 K: Co(s)+Fe2+(aq,1.47 M)⟶Co2+(aq,0.33 M)+Fe(s) If the standard reduction potential for cobalt(II) is −0.28 V and the standard reduction potential for iron(II) is −0.447 V, what is the cell potential in volts for this cell? Report your answer with two significant figures.
Answer:
The correct answer is 0.186 V
Explanation:
The two hemirreactions are:
Reduction: Fe²⁺ + 2 e- → Fe(s)
Oxidation : Co(s) → Co²⁺ + 2 e-
Thus, we calculate the standard cell potential (Eº) from the difference between the reduction potentials of cobalt and iron, respectively, as follows:
Eº = Eº(Fe²⁺/Fe(s)) - Eº(Co²⁺/Co(s)) = -0.28 V - (-0.447 V) = 0.167 V
Then, we use the Nernst equation to calculate the cell potential (E) at 298.15 K:
E= Eº - (0.0592 V/n) x log Q
Where:
n: number of electrons that are transferred in the reaction. In this case, n= 2.
Q: ratio between the concentrations of products over reactants, calculated as follows:
[tex]Q = \frac{ [Co^{2+} ]}{[Fe^{2+} ]} = \frac{0.33 M}{1.47 M} = 0.2244[/tex]
Finally, we introduce Eº= 0.167 V, n= 2, Q=0.2244, to obtain E:
E= 0.167 V - (0.0592 V/2) x log (0.2244) = 0.186 V
Compound has a molar mass of and the following composition: elementmass % carbon47.09% hydrogen6.59% chlorine46.33% Write the molecular formula of .
The given question is incomplete. The complete question is:
Compound X has a molar mass of 153.05 g/mol and the following composition:
element mass %
carbon 47.09%
hydrogen 6.59%
chlorine 46.33%
Write the molecular formula of X.
Answer: The molecular formula of X is [tex]C_6H_{10}Cl_2[/tex]
Explanation:
If percentage are given then we are taking total mass is 100 grams.
So, the mass of each element is equal to the percentage given.
Mass of C= 47.09 g
Mass of H = 6.59 g
Mass of Cl = 46.33 g
Step 1 : convert given masses into moles.
Moles of C =[tex]\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{47.09g}{12g/mole}=3.92moles[/tex]
Moles of H =[tex]\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{6.59g}{1g/mole}=6.59moles[/tex]
Moles of Cl =[tex]\frac{\text{ given mass of Cl}}{\text{ molar mass of Cl}}= \frac{46.33g}{35.5g/mole}=1.30moles[/tex]
Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.
For C = [tex]\frac{3.92}{1.30}=3[/tex]
For H = [tex]\frac{6.59}{1.30}=5[/tex]
For Cl =[tex]\frac{1.30}{1.30}=1[/tex]
The ratio of C : H: Cl= 3: 5 :1
Hence the empirical formula is [tex]C_3H_5Cl[/tex]
The empirical weight of [tex]C_3H_5Cl[/tex] = 3(12)+5(1)+1(35.5)= 76.5g.
The molecular weight = 153.05 g/mole
Now we have to calculate the molecular formula.
[tex]n=\frac{\text{Molecular weight }}{\text{Equivalent weight}}=\frac{153.05}{76.5}=2[/tex]
The molecular formula will be=[tex]2\times C_3H_5Cl=C_6H_{10}Cl_2[/tex]
What is Non Metal?
help me find
The element which can not loose electron easily and having electronagtive character is called non-metal it has following property-
1. it can not conduct heat and electricity
2. it is netiher ductile not malleable
3. it is not lsuturous and also not sonorous
Explanation:
a nonmetal (or non-metal) is a chemical element that mostly lacks the characteristics of a metal. Physically, a nonmetal tends to have a relatively low melting point, boiling point, and density. A nonmetal is typically brittle when solid and usually has poor thermal conductivity and electrical conductivity. Chemically, nonmetals tend to have relatively high ionization energy, electron affinity, and electronegativity. They gain or share electrons when they react with other elements and chemical compounds. Seventeen elements are generally classified as nonmetals: most are gases (hydrogen, helium, nitrogen, oxygen, fluorine, neon, chlorine, argon, krypton, xenon and radon); one is a liquid (bromine); and a few are solids (carbon, phosphorus, sulfur, selenium, and iodine). Metalloids such as boron, silicon, and germanium are sometimes counted as nonmetals.
PV = nRT. If P = 1 atm, V = 5.0 liter, R = 0.0821 L.atm/mol.K, and T = 293 K; what is the value of n?
Answer:
n = 0.207 mole
Explanation:
We have,
P = 1 atm
V = 5 liter
R = 0.0821 L.atm/mol.K
T = 293 K
We need to find the value of n. The relation is as follows :
PV = nRT
Solving for n,
[tex]n=\dfrac{PV}{RT}\\\\n=\dfrac{1\times 5}{0.0821 \times 293}\\\\n=0.207\ \text{mol}[/tex]
So, the value of n is 0.207 mol.
clacium hydroxide is slightly soluable in water about 1 gram will dissolve in 1 liter what are the spectator ions in the reaction ions in the reaction of such a dilute solution of calcium hydroxide with hydrochloric acid
Answer:
Ca²⁺ and Cl⁻
Explanation:
In a chemical reaction, spectator ions are ions that are not involved in the reaction, that means are the same before and after the reaction.
In water, calcium hydroxide, Ca(OH)₂ is dissociated in Ca²⁺ and OH⁻. Also, hydrochloric acid, HCl, dissociates in H⁺ and Cl⁻. The reaction is:
Ca²⁺ + 2OH⁻ + 2H⁺ + 2Cl⁻ → 2H₂O + Ca²⁺ + 2Cl⁻
The ions that react are H⁺ and OH⁻ (Acid and base producing water)
And the ions that are not reacting, spectator ions, are:
Ca²⁺ and Cl⁻Draw the structure of beeswax.beeswax is made from the esterfication of a saturated 16-carbon fatty acid and a 30 carbon straight chain primary alcohol.
Answer:
Triacontyl palmitate
Explanation:
In this case, we have a reaction between an acid and an alcohol. When we put together these kind of compounds an ester is produced. This reaction is called "esterification".
In our case, the alcohol is a structure with 30 carbon in which the "OH" group is bonded on carbon 1. The name of this compound is "n-triacontanol". The acid is a structure in which we have 16 carbon in which the "COOH" group is placed on carbon 1. The name of this compound is "palmitic acid". The ester produced by the acid and the alcohol is "Triacontyl palmitate".
See figure 1.
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Why will the conjugate base of a weak acid affect pH? Select the correct answer below: it will react with hydroxide
Answer:
It will react with water
Explanation:
I know this is an older question, but I just wanted to provide the correct answer.
Since we are dealing with a weak base, and the acid is somewhat stronger, it will react with the water molecules to produce hydronium, which will affect the pH of the solution.
The conjugate base of a weak acid affect pH because it will react with hydronium ion.
A weak acid is an acid that does not dissociate completely in water. On the other hand, a strong acid achieves almost 100% dissociation in water.
Acids dissociate in water to yield the hydronium ion and a conjugate base. For instance, the weak acid, acetic acid is dissociated as follows;
CH3COOH(aq) + H2O(l) ⇄ CH3COO-(aq) + H3O+(aq)
We can see that the conjugate base( CH3COO-) could react with the hydronium ions thereby moving the equilibrium position to the left hand side and affecting the pH by decreasing the hydronium ion concentration.
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Missing parts;
Why will the conjugate base of a weak acid affect pH? Select the correct answer below: O it will react with hydroxide O it will react with water O it will react with hydronium O none of the above
There are 454 grams in one pound. How many pounds are in 700 grams
Answer:
1.543 pounds = 700 grams
We discussed the different types of intermolecular forces in this lesson, which can affect the boiling point of a substance.
1. Which of these has the highest boiling point?
A) Ar
B) Kr
C) Xe
D) Ne
2. Which substance has the highest boiling point?
A) CH4
B) He
C) HF
D) Cl2
Answer:
1, C, Xe 2, B,He
Explanation:
1, cause as u go down a group the boiling point increases.
2, boiling point of single element is greater than a compound
According to periodic trends in periodic table boiling point increases down the group and hence Xe has highest boiling point and more amount of heat is required to boil an element hence He has highest boiling point.
What is periodic table?
Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.
It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.
Elements present in the same group have same number of valence electrons and hence have similar properties while elements present in the same period show gradual variation in properties due to addition of one electron for each successive element in a period.
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If 11.2 g of naphthalene, C10H8, is dissolved in 107.8 g of chloroform, CHCl3, what is the molality of the solution
Answer:
CHC12
Explanation:
i am not really sure i am onna do a quick research 4 u tho
Write the half-reactions as they occur at each electrode and the net cell reaction for this electrochemical cell containing indium and cadmium. In(s)|
Answer:
Oxidation half equation;
3Cd(s) -------> 3Cd^2+(aq) + 6e
Reduction half equation;
2In^3+(aq) + 6e -----> 2In(s)
Explanation:
Since the reduction potentials of Indium and Cadmium are -0.34 V and - 0.40 V respectively, we can see that cadmium will be oxidized while indium will the reduced.
We arrived at this conclusion by examining the reduction potential of both species. The specie with more negative reduction potential is oxidized in the process.
Oxidation half equation;
3Cd(s) -------> 3Cd^2+(aq) + 6e
Reduction half equation;
2In^3+(aq) + 6e -----> 2In(s)
Arrange the following substances in the order of increasing entropy at 25°C. HF(g), NaF(s), SiF 4(g), SiH 4(g), Al(s) lowest → highest
Answer:
Al(s)<NaF(s)<HF(g)<SiH4(g)<SiF4(g)
Explanation:
Hello,
In this case, we can arrange the increasing order of entropy at 25 \°C by taking into account, at first, that since solids are more molecularly organized than gases, the first we have solid sodium fluoride and solid aluminium, but in this case, as the higher the molar mass, the higher the entropy, the molar mass of aluminium is 27 g/mol and 42 g/mol for sodium fluoride, therefore, we first have:
Al(s)<NaF(s)
Afterwards, since the molar mass of hydrogen fluoride (HF), silicon fluoride (SiF4) and silane (SiH4) are 20, 104 and 32 g/mol respctively, since silicon fluoride has the greater molar mass, it also has the higher entropy. In such a way, the overall order turns out:
Al(s)<NaF(s)<HF(g)<SiH4(g)<SiF4(g)
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The enthalpy change for a chemical reaction is: a. the temperature change b. the amount of heat given off or absorbed c. related to molar volume d. none of the above
Answer:
b. the amount of heat given off or absorbed
Explanation:
Hello,
In this case, we should take into account a formal definition of enthalpy change such as an energetic change that occurs in a system when matter is transformed by a given chemical reaction from reactants to products. Thus, such energetic change is macroscopically exhibited and it is related with either a temperature increase or decrease; it means that if a reaction exhibits a temperature increase, we say that heat was given off and if the temperature exhibits a decrease, we say that heat is absorbed. For that reason, answer is b. the amount of heat given off or absorbed.
Regards.
A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) <----> N2(g) 3H2(g) At equilibrium, it was found that the concentration of H2 was 0.0484 M, the concentration of N2 was 0.0161 M, and the concentration of NH3 was 0.295 M. What was the initial concentration of ammonia
Answer:
0.327 M
Explanation:
Step 1: Write the balanced equation
2 NH₃(g) ⇄ N₂(g) + 3H₂(g)
Step 2: Make an ICE chart
2 NH₃(g) ⇄ N₂(g) + 3 H₂(g)
I x 0 0
C -2y +y +3y
E x-2y y 3y
Step 3: Find the value of y
The concentration of N₂ at equilibrium is 0.0161 M. Then,
y = 0.0161
Step 4: Find the value of x
The concentration of NH₃ at equilibrium is 0.295 M. Then,
x-2y = 0.295
x-2(0.0161) = 0.295
x = 0.327
g The electronic structure of which ONE of the following species cannot be adequately described by a single Lewis formula? (In other words, the electronic structure of which one can only be described by drawing two or more resonance structures?) A) C2H4 B) SO3 2– C) SO3 D) C3H8 E) HCN
Answer:
C) SO3
Explanation:
Lewis formula shows the bonding between atoms of a molecule and expresses the lone pair present in the atoms.
SO3 or Sulfur trioxide cannot be adequately described by a single Lewis formula because it has majorly 3 resonance structures because Sulfur does not follow the octet rule and can expand electrons in its outer shell.
Hence, the correct answer is C) SO3
A sample of a hydrocarbon is found to contain 7.99g carbon and 2.01g hydrogen. What is the empirical formula for this compound
Answer:
The empirical formulae for the compound is CH3.
If the rate of formation (also called rate of production) of compound C is 2M/s in the reaction A --->2C, what is the rate of consumption of A
Answer:
[tex]r_A=-1\frac{M}{s}[/tex]
Explanation:
Hello,
In this case, given the rate of production of C, we can compute the rate of consumption of A by using the rate relationships which include the stoichiometric coefficients at the denominators (-1 for A and 2 for C) as follows:
[tex]\frac{1}{-1} r_A=\frac{1}{2}r_C[/tex]
In such a way, solving the rate of consumption of A, we obtain:
[tex]r_A=-\frac{1}{2} r_C=-\frac{1}{2}*2\frac{M}{s}\\ \\r_A=-1\frac{M}{s}[/tex]
Clearly, such rate is negative which account for consumption process.
Regards.
Which response includes all the following processes that are accompanied by an increase in entropy? 1) 2SO 2(g) + O 2(g) → SO 3(g) 2) H 2O(l) → H 2O(s) 3) Br 2(l) → Br 2(g) 4) H 2O 2(l) → H 2O(l) + 1/ 2O 2(g)
Answer: Reaction (1) , (3) and (4) are accompanied by an increase in entropy.
Explanation:
Entropy is the measure of randomness or disorder of a system. If a system moves from an ordered arrangement to a disordered arrangement, the entropy is said to decrease and vice versa.
(1) [tex]2SO_2(g)+O_2(g)\rightarrow SO_3(g)[/tex]
3 moles of reactant are changing to 1 mole of product , thus the randomness is increasing. Thus the entropy also increases.
2) [tex]H_2O(l)\rightarrow H_2O(s)[/tex]
1 mole of Liquid reactant is changing to 1 mole of solid product , thus the randomness is decreasing. Thus the entropy also decreases.
3) [tex]Br_2(l)\rightarrow Br_2(g)[/tex]
1 mole of Liquid reactant is changing to 1 mole of gaseous product , thus the randomness is increasing. Thus the entropy also increases.
4) [tex]H_2O_2(l)\rightarrow H_2O(l)+\frac{1}{2}O_2(g)[/tex]
1 mole of Liquid reactant is changing to half mole of gaseous product and 1 mole of liquid product, thus the randomness is increasing. Thus the entropy also increases.
acid-catalyzed hydration of 1-methylcyclohexene gives two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain
Answer:
Major product does not undergo oxidation since it is a tertiary alcohol whereas minor product undergoes oxidation to ketone as it is secondary alcohol.
Explanation:
Hello,
In this case, given the attached picture, the hydration of the 1 methylcyclohexene yields to alcohols; 1-methylcyclohexan-1-ol and 1-methylcyclohexan-2-ol. Thus, since the OH in the 1-methylcyclohexan-1-ol (major product) is bonded to a tertiary carbon (bonded with other three carbon atoms) it is not able to increase the number of oxygen bonds (oxidation) as it already attained the octet whereas the 1-methylcyclohexan-2-ol (minor product) is able to undergo oxidation to ketone as the carbon bonded to it is secondary (bonded with other two carbon atoms), so one extra bond the oxygen is allowed to be formed to carbonyl.
Best regards.
