For a process Arightwards harpoon over leftwards harpoonB, at 25 °C there is 10% of A at equilibrium while at 75 °C, there is 80% of A at equilibrium. Estimate enthalpy change of this reaction in kJ/mol

Answers

Answer 1

This question is describing the following chemical reaction at equilibrium:

[tex]A\rightleftharpoons B[/tex]

And provides the relative amounts of both A and B at 25 °C and 75 °C, this means the equilibrium expressions and equilibrium constants can be written as:

[tex]K_1=\frac{90\%}{10\%}=9\\\\K_2=\frac{20\%}{80\%} =0.25[/tex]

Thus, by recalling the Van't Hoff's equation, we can write:

[tex]ln(K_2/K_1)=-\frac{\Delta H}{R}(\frac{1}{T_2} -\frac{1}{T_1} )[/tex]

Hence, we solve for the enthalpy change as follows:

[tex]\Delta H=\frac{-R*ln(K_2/K_1)}{(\frac{1}{T_2} -\frac{1}{T_1} ) }[/tex]

Finally, we plug in the numbers to obtain:

[tex]\Delta H=\frac{-8.314\frac{J}{mol*K} *ln(0.25/9)}{[\frac{1}{(75+273.15)K} -\frac{1}{(25+273.15)K} ] } \\\\\\\Delta H=4,785.1\frac{J}{mol}[/tex]

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Related Questions

Suppose that in an equilibrium mixture of HCl, Cl2, and H2, the concentration of H2 is 1.0 x 10-11 mol-L-1and that of Cl2 is 2.0 x 10-10 mol-L-1. What is the equilibrium molar concentration of HCl at 500 K, given Kc = 4.0 x 1018 for H2(g) +Cl2(g) ⇆ 2HCl(g).

Answers

Considering the definition of Kc, the equilibrium molar concentration of HCl at 500 K is 0.0894 [tex]\frac{mol}{L}[/tex].

The balanced reaction is:

H₂(g) +Cl₂(g) ⇆ 2 HCl(g)

Equilibrium is a state of a reactant system in which no changes are observed as time passes, despite the fact that the substances present continue to react with each other. In other words, reactants become products and products become reactants and they do so at the same rate.

In other words, chemical equilibrium is established when there are two opposite reactions that take place simultaneously at the same speed.

The concentration of reactants and products at equilibrium is related by the equilibrium constant Kc. Its value in a chemical reaction depends on the temperature and the expression of a generic reaction aA + bB ⇄ cC is

[tex]K_{c} =\frac{[C]^{c} x[D]^{d} }{[A]^{a} x[B]^{b} }[/tex]

That is, the constant Kc is equal to the multiplication of the concentrations of the products raised to their stoichiometric coefficients by the multiplication of the concentrations of the reactants also raised to their stoichiometric coefficients.

In this case, the constant Kc can be expressed as:

[tex]K_{c} =\frac{[HCl]^{2} }{[H_{2} ]x[Cl_{2} ] }[/tex]

You know that in an equilibrium mixture of HCl, Cl₂, and H₂:

the concentration of H₂ is 1.0×10⁻¹¹ [tex]\frac{mol}{L}[/tex]the concentration of Cl₂ is 2.0×10⁻¹⁰ [tex]\frac{mol}{L}[/tex]Kc=4×10¹⁸

Replacing in the expression for Kc:

[tex]4x10^{18} =\frac{[HCl]^{2} }{[1x10^{-11} ]x[2x10^{-10} ] }[/tex]

Solving:

[tex]4x10^{18} =\frac{[HCl]^{2} }{2x10^{-21} }[/tex]

[tex]4x10^{18} x 2x10^{-21}=[HCl]^{2}[/tex]

[tex]8x10^{-3} =[HCl]^{2}[/tex]

[tex]\sqrt[2]{8x10^{-3}} =[HCl][/tex]

0.0894 [tex]\frac{mol}{L}[/tex]= [HCl]

Finally, the equilibrium molar concentration of HCl at 500 K is 0.0894 [tex]\frac{mol}{L}[/tex].

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Oil does not dissolve in water because

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Explanation:

Oils are made up of long hydrocarbon chains which are non polar. Since water is a polar solvent oil doesn't dissolve in water well.( Polar solutes dissolve in polar solvents and non polar solutes dissolve in non polar solvents) The hydrocarbon chains are hydrophobic.

an expression of Avogradros law

Answers

Answer:

The formula for Avagadro's law is V1/n1 = V2/n2, where V = volume and n = amount of gas (in moles).

Explanation:

the solubility of nitrogen gas is 1.90 mL/dL of blood at 1.00 atm. what is the solubility of nitrogen gas in a deepsea divers blood at a depth of 200 feet and pressure of 7.00 atm

Answers

The solubility of nitrogen gas in water is 1.90 mL/dL at 1.00 atm and 13.3 mL/dL at 7.00 atm.

We want to relate the solubility of a gas with its partial pressure.

We can do so using Henry's law.

What does Henry's law state?

Henry's law states that the amount of dissolved gas in a liquid is proportional to its partial pressure above the liquid.

C = k × P

where,

C is the concentration of a dissolved gas. k is the Henry's Law constant. P partial pressure of the gas.

The solubility of nitrogen gas is 1.90 mL/dL of blood at 1.00 atm.

Since the solvent is basically water, we can understand that the concentration of nitrogen gas is 1.90 mL/dL at 1.00 atm.

We can use this information to calculate Henry's Law constant.

k = C/P = (1.90 mL/dL)/1.00 atm = 1.90 mL/dL.atm

We want to calculate the solubility of nitrogen gas at a pressure of 7.00 atm.

We will use Henry's law.

C = k × P = (1.90 mL/dL.atm) × 7.00 atm = 13.3 mL/dL

The solubility of nitrogen gas in water is 1.90 mL/dL at 1.00 atm and 13.3 mL/dL at 7.00 atm.

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3.00 L of a gas is collected at 35.0 C and 0.93 atm. What is the volume at STP

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2.47L

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A chemical property is a change in _____.

density

physical state

hardness

composition of matter

Answers

Answer:

composition of an element

HELP!! what are the usual products of combustion reactions?

Answers

Explanation:

Carbon dioxide and water

I hope it helps

Answer:

The usual products of combustion reactions are carbon dioxide and water.

Explanation:

Combustion reaction is when a substance reacts with oxygen gas, resulting in a release of energy in the form of light and heat. Combustion reactions must have oxygen (O2) as one of the reactants.

Convert 1.36x10 to standard form​

Answers

Answer:

13.6 is the correct answer written in standard form.

Explanation:

1.36, move the decimal once to the right to get 13.6

Answer:

13.6

Explanation:

The standard form is 13.6

A beaker containing a green liquid is left uncovered in a laboratory for one week., After the liquid evaporates, the beaker contains a dry green solid. Was the original liquid in the beaker an element, a compound, or a mixture?

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The original liquid is regarded as a mixture.

A mixture is regarded as a material which comprises of two or more

substances which are combined physically. An example is the mixture of

dye and water.

A compound on the other hand is combined chemically and not physically

which when  exposed to the same type of situation either remains in the

beaker or nothing at all is found. Since the water evaporates and a green

solid was present then it means the material was a solution in which

water(solvent) and the green solid(solute) was physically combined and not

chemically combined together.

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2 nitrogen atoms and five chlorine atoms what compound does that make

Answers

Answer:

dinitrogen pentachloride

The boiling point of a substance is tested. After 10 tests, the result is given as 37+/−3°C. Which conclusion can be drawn from this result? (1 point)

The scientists do not need to collect more data because they have narrowed down the range of the results.

The scientists should not report these results until they have the exact number.

The actual boiling point is either 34°C or 40°C.

The actual boiling point is probably between 34°C and 40°C.

Answers

Answer:

Explanation:

The actual boiling point is probably between 34C and 40C.

Temperature measures the average kinetic energy of particles of the substances. Therefore, the correct option is option D that is the actual boiling point is probably between 34°C and 40°C.

What is temperature?

Temperature is used to measure degree or intensity of heat of a particular substance. Temperature is measured by an instrument called thermometer.

Temperature can be measured in degree Celsius °c, Kelvin k or in Fahrenheit. Temperature is a physical quantity. Heat always flow from higher temperature source to lower temperature source.

We can convert these units of temperature into one another. The relationship between degree Celsius and Fahrenheit can be expressed as:

°C={5(°F-32)}÷9

The actual boiling point is probably between 34°C and 40°C.

Therefore, the correct option is option D.

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To what pH should you adjust a standard hydrogen electrode to get an electrode potential of -0.128 V ? (Assume that the partial pressure of hydrogen gas remains at 1 atm.) Express your answer using two decimal places.\

Answers

The pH of the standard hydrogen electrode that has electrode potential of -0.128 V  is 4.3.

The equation of the hydrogen electrode is;

2H^+(aq) + 2e ⇄ H2(g)

The standard electrode potential of hydrogen is 0.00 V

Using the Nernst equation;

Ecell = E°cell - 0.0592/n log Q

Now;

E°cell = 0.00 V

n = 2

Q = 1/[H^+]

-0.128 = 0.00 - 0.0592/2 log  1/[H^+]

-0.128 = 0.00 - 0.0296 log 1/[H^+]

 -0.128 =  - 0.0296 log 1/[H^+]

-0.128/  - 0.0296  =  log 1/[H^+]

1/[H^+] = Antilog (4.32)

[H^+] = 4.79 × 10^-5

Now;

pH = -log[H^+]

pH = -log (4.79 × 10^-5)

pH = 4.3

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How could you tell if a substance has undergone a physical change or a chemical one?

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Answer: Chemical changes occur when a substance combines with another to form a new substance, called chemical synthesis or, alternatively, chemical decomposition into two or more different substances. These processes are called chemical reactions and, in general, are not reversible except by further chemical reactions.

A physical change is are changes affecting the form of a chemical substance, but not its chemical composition. Physical changes are used to separate mixtures into their component compounds, but can not usually be used to separate compounds into chemical elements or simpler compounds.

Thin-layer chromatography explain ?????​

Answers

Answer:

Explanation:

Thin-layer chromatography (TLC) is a chromatography technique used to separate non-volatile mixtures. ... After the sample has been applied on the plate, a solvent or solvent mixture (known as the mobile phase) is drawn up the plate via capillary action.

If 38.6 grams of iron react with an excess of bromine gas, what mass of FeBr2 can form?

Answers

Answer:

›› FeBr2 molecular weight. Molar mass of FeBr2 = 215.653 g/mol. This compound is also known as Iron(II) Bromide. Convert grams FeBr2 to moles or moles FeBr2 to grams. Molecular weight calculation: 55.845 + 79.904*2 ›› Percent composition by element

Explanation:

If 38.6 grams of iron react with an excess of bromine gas, the mass of FeBr2 can form is 149 grams.

What is mass?

Mass is defined as a way to gauge how much matter there is in a substance or thing. The kilogram (kg) is the fundamental SI unit of mass, while lower masses can also be measured in grams (g). Atoms make up everyday matter. A majority of an atom's mass is contained in its nucleus.

Given Fe = 38.6 g.

Fe has a molar mass = 55.845 g/mol.

Given mass/molar mass equals 38.6g/55.845gmol-1, or 0.6912 moles of iron.

The reaction is described as Fe + Br2 FeBr2.

One mole Fe yields 1 mole of FeBr2.

FeBr2 would be produced from 0.6912 moles of Fe.

FeBr2 has a molar mass of 215.65 g/mol.

Moles of FeBr2 x Molar mass of FeBr2

= 215.65 g/mole x 0.6912 mole

= 149.06 g FeBr2 produced is the formula.

Thus, if 38.6 grams of iron react with an excess of bromine gas, the mass of FeBr2 can form is 149 grams.

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Pleeeeasee someone who’s good at chemistry?! 10 grade

ASAP
I’ll give points, just help please

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Answer:

where is the question????????????

he hybridization of carbon in diamond is _________. Enter your answer with no superscripts or subscripts, i.e., ab3.

Answers

Diamond is composed of hexagonal rings in which sp3 hybridized carbon atoms are linked together.

Hybridization refers to the mixing of atomic orbitals to yield hybrid orbitals that are suitable for bonding. The energy of orbitals that combine to form hybrid orbitals must be close enough for such combination to take place.

Diamond is composed of hexagonal rings in which sp3 hbridized carbon atoms are linked together. Each carbon atom in diamond is tetrahedral.

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The mixing of the two different orbitals to form a compound is called hybridization. For example mixing of s and p orbits.

The correct answer is sp3.

The arrangement of the elements in a different manner to form a new compound is called allotropes. For example, diamond and graphite are the allotropes of carbon.

The valence electrons are in p orbitals and p orbit mixed after the s orbitals.

Therefore, the correct answer is sp3

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At 298 K, the reaction 2 HF (g) ⇌ H2 (g) + F2 (g) has an equilibrium constant Kc of 8.70x10-3. If the equlibrium concentrations of H2 and F2 gas are both 1.33x10-3 M, determine the initial concentration of HF gas assuming you only started with HF gas and no products initially.

Answers

This problem is describing the equilibrium whereby hydrofluoric acid decomposes to hydrogen and fluorine gases at 298 K whose equilibrium constant is 8.70x10⁻³, the equilibrium concentrations of all the reactants are both 1.33x10⁻³ M and asks for the initial concentration of hydrofluoric acid which turns out to be 2.86x10⁻³ M.

Then, we can write the following equilibrium expression for hydrofluoric acid once the change, [tex]x[/tex], has taken place:

[tex][HF]=[HF]_0-2x[/tex]

Now, since both products are 1.33x10⁻³ M we infer the reaction extent is also 1.33x10⁻³ M, and thus, we can calculate the equilibrium concentration of HF via the law of mass action (equilibrium expression):

[tex]8.70x10^{-3}=\frac{(1.33x10^{-3} M)^2}{[HF]} }[/tex]

[tex][HF]=\frac{(1.33x10^{-3} M)^2}{8.70x10^{-3}} }=2.03x10^{-4}M[/tex]

Finally, the initial concentration of HF is calculated as follows:

[tex][HF]_0=[HF]+2x=2.033x10^{-4}+2*(1.33x10^{-3})=2.86x10^{-3}M[/tex]

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Radio waves bounce off of _____________ before returning to Earth

Answers

Answer:   ionosphere

Explanation:       First it bounces off a top layer of the atmosphere called the ionosphere, then it bounces back to the Earth (this is reflection. It then bounces up again to the ionosphere, and continues bouncing back again until it reaches the radio receiver. This is called a skywave, which works around 3 to 30 MHz.

In experiment 9, in one operation, we heat up the alcohol with acid and do a concurrent distillation. What was the purpose of doing this

Answers

Answer:

we heat up because the component with lower boiling evaporates first,

leaving the other behind

The sum of the number of proteins and neutrons in an atoms nucleus is its __________ ___________.

Answers

Answer:

Mass Number

Explanation:

In nuclear physics, the sum of the numbers of protons and neutrons present in the nucleus of an atom.

Please vote brainliest!

Al2(SO3)3
a. Count the number of Sulfur atom
b. How many total atoms are given in the compound
Please helppp

Answers

Answer:

from the words below underline six example of rhetorical patterns

How many mL of 0.150 M HF solution are required to produce 0.0370 moles of HF

Answers

Answer:

247 ml

Explanation:

How many mL of 0.150 M HF solution are required to produce 0.0370 moles of HF 0.150 moles/ liter = 0.150/1000 moles/ml =0.000150 moles/ml

0.000150 x ? = 0.0370 moles HF

? = 0.0370/0.000150 = 247 ml

check

247 ml = 247/1000 L = 0.247

(0.247) x (0.150) =0.370 check

Tristan wraps some gifts and then brings them to the post office where they are delivered to people in different parts of the country. Which organelle is Tristan most like?

Answers

Answer:

Tristan wraps some gifts and then brings them to the post office where they are delivered to people in different parts of the country. Which organelle is Tristan most like?

Answer: Tristan is most like the Golgi Body

Explanation:

What identifies the number of protons in the nucleus of an atom?

Answers

Answer: Atomic number

Explanation:

I hope this helps you!

Cesium-137 is part of the nuclear waste produced by uranium-235 fission. The half-life of cesium-137 is 30.2 years. How much time is required for the activity of a sample of cesium-137 to fall to 8.32 percent of its original value

Answers

Answer:

la primera va con la última

Learning Task 2: Read each statement or question below carefully and fill in the blank(s) with the best answer by choosing the words inside the box. Write your answers in a separate sheet of paper. cation 1 -ide -ine nonmetals O ion ionic compound anion metals root name 1. Any atom or molecule with a net charge, either positive or negative, is known as en 2. An atom that gains one extra electron forms an with a 1- charge. 3. A positive ion, called a is produced when one or more electrons are lost from a neutral atom. 4. Unlike a cation, which is named for the parent atom, an anion is named by taking the of the atom and changing the ending. 5. The name of each anions is obtained by adding the suffix to the root of the atom name. 6. The always form positive ions. 7. on the other hand, form negative ions by gaining electrons. 8. It is very important to remember that a chemical compound must have a net charge of​

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Body surface area is calculated a) in m2 from weight and height. b) from height. c) from weight. d) in meters from weight and height.

A pan containing 40 grams of water was allowed to cool from a temperature of 91.0 °C. If the amount of heat released is 1,300 joules, what is the approximate final temperature of the water? 74 °C 78 °C 81 °C 83 °C

Answers

Answer:

d. 83 °c

Explanation:

Answer:

D. 83 c

Explanation:

took the test

Why we use two different methods for detection of cogulase enzyme ? Or what other reason or what basic different between them?

Answers

I’m so sorry I hope you have a wonderful day good luck

Using the Kf value of 1.2×109 calculate the concentration of Ni2+(aq) and Ni(NH3)62+ that are present at equilibrium after dissolving 1.47 gNiCl2 in 100.0 mL of NH3(aq) solution such that the equilibrium concentration of NH3 is equal to 0.20 M.
Express your answers in moles per liter to two significant figures separated by a comma.

Answers

This problem is describing the equilibrium whereby the formartion of a complex is attained when 1.47 g of nickel(II) chloride is dissolved in 100.0 mL of ammonia so that the latter's equilibium concentration is 0.20 M. Thus, it is asked to calculate the equilibrium concentrations of both nickel(II) ions and that of the complex.

Firstly, we can write out the chemical equation to be considered:

[tex]Ni^{2+}+6NH_3\rightleftharpoons Ni(NH_3)_6^{2+}[/tex]

Next, we can calculate the initial concentration of nickel(II) ions by using the concept of molarity:

[tex][Ni^{2+}]=\frac{1.47gNiCl_2*\frac{1molNiCl_2}{129.6g}*\frac{1molNi^{2+}}{1molNiCl_2} }{0.1000L}=0.113M[/tex]

Afterwards, we set up an equilibrium expression for this chemical reaction:

[tex]Kf=\frac{[Ni(NH_3)_6^{2+}]}{[Ni^{2+}][NH_3]^6}[/tex]

Which can be written in terms of the reaction extent, [tex]x[/tex]:

[tex]Kf=\frac{x}{(0.113-x)(0.2)^6}[/tex]

Now, for the calculation of [tex]x[/tex], we plug in Kf, and solve for it:

[tex]1.2x10^9=\frac{x}{(0.113-x)(0.2)^6}\\\\1.2x10^9=\frac{x}{(0.113-x)(6.4x10^{-5})}\\\\7.68x10^4(0.113-x)=x\\\\x=0.112999 M[/tex]

Which is about the same to the initial concentration of nickel(II) ions because the Kf is too large.

Thus, the required concentrations at equilibrium are about:

[tex][Ni(NH_3)_6^{2+}]=0.113M[/tex]

[tex][Ni^{2+}]=0M[/tex]

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