Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus. The reactant is H2NCNHCH2CH2CH2CHCO minus, with an NH group, with a lone pair at the N atom, double-bonded to the first (from left to right) carbon, an NH2 group attached to the fifth carbon, an O atom double-bonded to the sixth carbon and a lone pair of electrons at the first and the second N atoms of the chain. The product has the same structure as the reactant, except that not an NH group with a lone pair, but an NH2 plus group is double-bonded to the first carbon. In addition, an NH3 plus group is attached to the fifth carbon instead of the NH2 group.

Answer:

Explanation:

For pH of a buffer solution , the formula is

pH = pKa + log [ Base ] / [ conjugate acid ]

=   pKa + log [ NH₃ ] / [ NH₄⁺ ]

Ka = Kw / Kb

Kb for NH₄OH = 1.8 x 10⁻⁵

Ka = 10⁻¹⁴ / 1.8 x 10⁻⁵

= 5.6 x 10⁻¹⁰

pH = - log ( 5.6 x 10⁻¹⁰ ) + log 0.2 / 0.2

= 10 - log 5.6

= 9.25

Effect of addition of HCl

H⁺ of HCl will react with NH₃ to produce NH₄⁺

25 mL of .1 HCl = 2.5 mM of HCl

25 mL of .1 NH₄⁺ = 2.5 mM of NH₄⁺

65 mL of .2 M NH₃ = 13 mM of NH₃

65 mL of .2 M NH₄⁺ = 13 mM of NH₄⁺

NH₃ + H⁺ = NH₄⁺

NH₄⁺ formed = 2.5 + 13  mM

15.5 mM of NH₄⁺

NH₃ = 13 mM

Concentration of NH₃ = 13 / 90

Concentration of NH₄⁺ = 15.5 / 90

pH of final buffer mixture

= 9.6 + log 13 / 15.5

= 9.25 - .076

= 9.174

The pH value  is mathematically given as

pH= -6.332.

Question Parameters:

the pH of a 0.20 M NH3/0.20 M NH4Cl buffer

the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.

Generally, the equation for the Chemical Reaction  is mathematically given as

HCl + NH3 --> NH4^+ + Cl^-

Therefore

pH= pka + log(13/14).

pH= -6.3 + log 0.93.

pH= -6.3+ (-0.032).

pH= -6.332.

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The advantage of a resource person would be that it will provide a hands-on activity that will allow the students to experience spacing between organs and on the body of the person.

It will also allow them to identify challenges when doing this and will engage them more in the activity and lesson.

Answer:A resource person add knowledge to the course

Explanation:

Answer:

1000ml=1l

35ml. = ?

Explanation:

35×1/1000

0.035litres

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

Answer:

While balancing a chemical equation, we change the coefficient  to balance the number of atoms on each side of the equation

Explanation:

While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

To summarize in chemistry terms, a chemical equation depicts the initial chemicals, or reactants, on the left-hand side and the final compounds, or products, just on right-hand side, divided by an arrow. In the chemical equation, the number of atoms in each element as well as the total charge are the same on opposite of the equation's sides.

Chemical equations are used in chemistry to depict chemical processes by writing the reactants and products in terms of their corresponding chemical formulas. While balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

Therefore, while balancing a chemical equation, we change the coefficient to balance the number of atoms on each side of the equation.

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Answer:

No precipitate is formed.

Explanation:

Hello,

In this case, given the dissociation reaction of magnesium fluoride:

[tex]MgF_2(s)\rightleftharpoons Mg^{2+}+2F^-[/tex]

And the undergoing chemical reaction:

[tex]MgCl_2+2NaF\rightarrow MgF_2+2NaCl[/tex]

We need to compute the yielded moles of magnesium fluoride, but first we need to identify the limiting reactant for which we compute the available moles of magnesium chloride:

[tex]n_{MgCl_2}=0.3L*1.1x10^{-3}mol/L=3.3x10^{-4}molMgCl_2[/tex]

Next, the moles of magnesium chloride consumed by the sodium fluoride:

[tex]n_{MgCl_2}^{consumed}=0.5L*1.2x10^{-3}molNaF/L*\frac{1molCaCl_2}{2molNaF} =3x10^{-4}molMgCl_2[/tex]

Thus, less moles are consumed by the NaF, for which the moles of formed magnesium fluoride are:

[tex]n_{MgF_2}=3x10^{-4}molMgCl_2*\frac{1molMgF_2}{1molMgCl_2}=3x10^{-4}molMgF_2[/tex]

Next, since the magnesium fluoride to magnesium and fluoride ions is in a 1:1 and 1:2 molar ratio, the concentrations of such ions are:

[tex][Mg^{2+}]=\frac{3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =3.75x10^{-4}M[/tex]

[tex][F^-]=\frac{2*3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =7.5x10^{-4}M[/tex]

Thereby, the reaction quotient is:

[tex]Q=(3.75x10^{-4})(7.5x10^{-4})^2=2.11x10^{-10}[/tex]

In such a way, since Q<Ksp we say that the ions tend to be formed, so no precipitate is formed.

Regards.

Answer:

Volume : 1.25 L

Explanation:

We are given here that the volume ( V[tex]_1[/tex] ) = 1.50 Liters, the initial moles ( held at 25 °C ) = 3.00 mol, and the final moles ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol. The final mol is calculated given that 0.50 mol of gas are released from the prior 3.00 moles of gas.

Volume ( V[tex]_1[/tex] ) = 1.50 L,

Initial moles ( n[tex]_1[/tex] ) = 3.00 mol,

Final Volume ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol

Applying the combined gas law, we can calculate the final volume ( V[tex]_2[/tex] ).

P[tex]_1[/tex]V[tex]_1[/tex] / n[tex]_1[/tex]T[tex]_1[/tex] = P[tex]_2[/tex]V[tex]_2[/tex] / n[tex]_2[/tex]T[tex]_2[/tex] - we know that the pressure and temperature are constant, and therefore we can apply the following formula,

V[tex]_1[/tex] / n[tex]_1[/tex] = V[tex]_2[/tex] / n[tex]_2[/tex] - isolate V[tex]_2[/tex],

V[tex]_2[/tex] = V[tex]_1[/tex] n[tex]_2[/tex] / n[tex]_1[/tex] = 1.50 L [tex]*[/tex] 2.5 mol / 3.00 mol = ( 1.5 [tex]*[/tex] 2.5 / 3 ) L = 1.25 L

The volume of the balloon will be 1.25 L.

Answer: 3 bromite ions and [tex]Sc(BrO_2)_3[/tex]

Explanation:

For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.  

Here scandium is having an oxidation state of +3 called as [tex]Sc^{3+}[/tex] cation and bromite is an anion with oxidation state of -1 called as [tex]BrO_2^-[/tex]. Thus 1 Scandium ion combines with three bromite ions and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Sc(BrO_2)_3[/tex]

Answer:

3 bromite ions and

Explanation:

Answer:

8.6×10^-2

Explanation:

The reaction is;

Mg(s) + Fe^2+(aq) -----> Mg^2+(aq) + Fe(s)

This implies that;

Q = [Mg^2+]/[Fe^2+]

But;

[Fe2+]= 3.60 M

[Mg2+]= 0.310 M

Q= [0.310 M]/[3.60 M]

Q= 0.086

Q= 8.6×10^-2

Answer:

a. 3.8856x10⁻³M HCl

b. 1.23x10⁻⁴M OH⁻

c. 1.23x10⁻⁴M Ag⁺

d. Ksp = [Ag⁺] [OH⁻]

Explanation:

a. The reaction that you are studying is:

HCl(aq) + AgOH(aq) → H₂O(l) + AgCl(s)

The HCl solution is diluted from 10.00mL to 250.00mL, that is:

250.00mL / 10.00mL = 25 -The solution is diluted 25 times-

As original concentration of HCl is 0.09714M, the concentration of the diluted solution is:

0.09714M / 25 =

b. 1 mole of HCl reacts per mole of AgOH, moles of HCl that reacts are:

7.93mL = 7.93x10⁻³L × (3.8856x10⁻³mol HCl / L) = 3.0813x10⁻⁵ moles of HCl.

Based on the reaction, you have in solution

3.0813x10⁻⁵ moles of AgOH = Ag⁺ = OH⁻

The AgOH solution was 250.0mL = 0.2500L, its concentration is:

3.0813x10⁻⁵ moles OH⁻ / 0.2500L =

c. In solution, AgOH produce Ag⁺ and OH⁻ in equals proportions, that means:

1.23x10⁻⁴M OH⁻ =

d. The solubility product reaction of AgOH(s) is:

AgOH(s) ⇄ Ag⁺(aq) + OH⁻(aq)

Where Ksp for this reaction is defined as:

Answer:

Since the relationship between amino acid and codon bases would be the values of 3 nitrogenous bases per 1 amino acid.

knowing this relationship what you would do is simply multiply 146 x 3 to find the number of codon bases which would be C. 438.

A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.

mRNA or messenger RNA is a single stranded RNA molecule. It is complementary to the DNA and carries genetic information present in the DNA. It is translated to form proteins. The genetic codes (triplet) present on mRNA get translated to amino acids, giving rise to the functional product of a gene.

So mRNA really is a form of nucleic acid, which helps the human genome which is coded in DNA to be read by the cellular machinery. mRNA is actually the translated form of DNA that the machinery can recognize and use to assemble amino acids into proteins.

Each strand has 3 bases, so 146 × 3 = 438 bases

Therefore, A strand of messenger RNA coding the synthesis of a protein with 146 amino acids must have a string of 438 bases along its backbone and the correct option is option C.

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It starts with a charge of 0 and is oxidized. Hence, option A is correct.

A chemical reaction is a representation of symbols of the elements to indicate the number of substances and moles of reactant and product.

[tex]Cl_2 + NaBr[/tex] ->[tex]NaCl + Br_2[/tex]

The oxidation number of bromine changes from -1 (in  NaBr) to 0 (in Br

2). Thus, NaBr is oxidized.

The oxidation number of chlorine changes from 0 to -1. Thus, chlorine is reduced.

Hence, option A is correct.

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Answer:

Au^3+(aq) +3e ------> Au(s). 1.50 V

Explanation:

When we construct the galvanic cell, our intention is to produce energy by spontaneous electrochemical reactions. In order to have a spontaneous electrochemical reaction, E°cell must be positive. The more positive the value of E°cell, the more spontaneous the reaction is.

E°cell= E°cathode - E°anode

If E°cathode= 1.50 V

E°anode= -0.25 V

E°cell= 1.50 -(-0.25)

E°cell= 1.75 V

Hence the process; Au^3+(aq) +3e ------> Au(s) yields the highest standard cell potential

Answer:

Ka = 6.15x10⁻⁷

Explanation:

Ka is defined as dissociation constant in the equilibrium of a weak acid with water. The general reaction is:

HA(aq) + H₂O(l) ⇆ H₃O⁺(aq) + A⁻(aq)

And Ka is defined as the ratio between molar concentrations in equilibrium of products over reactants as follows:

Ka = [H₃O⁺] [A⁻] / [HA]

You don't take water in the equilibrium beacuse is a pure liquid

Replacing with the concentrations of the problem:

Ka = [H₃O⁺] [A⁻] / [HA]

Ka = [4.00x10⁻⁴] [4.00x10⁻⁴] / [0.260]

Answer: The standard cell potential for the cell is +0.51 V

Explanation:

Given : [tex]E^0_{Ni^{2+}/Ni}=-0.25V[/tex]

[tex]E^0_{Zn^{2+}/Zn}=-0.76V[/tex]

The given reaction is:

[tex]Ni^{2+}(aq)+Zn(s)\rightarrow Zn^{2+}(aq)+Ni(s)[/tex]

As nickel is undergoing reduction, it acts as cathode and Zinc is undergoing oxidation, so it acts as anode.

[tex]E^0_{cell}=E^0_{cathode}-E^0_{anode}[/tex]

where both [tex]E^0[/tex]  are standard reduction potentials.

Thus putting the values we get:

[tex]E^0_{cell}=-0.25-(-0.76)[/tex]

[tex]E^0_{cell}=0.51V[/tex]

Thus the standard cell potential for the cell is +0.51 V

The graph is not given in the question, so, the required graph is attached below:

Answer:

According to the graph, the relationship between the density of the sugar solution and the concentration of the sugar solution is directly proportional to each other as they both are increasing exponentially.

The graph shows that, the density of sugar solution will increase with the increase in concentration of sugar in the solution.

Answer:

-297.67 °F

Explanation:

Oxygen condenses into a liquid at approximately 90 K. We can convert any temperature in the Kelvin scale (absolute scale) to the Fahrenheit scale using the following expression.

°F = (K − 273.15) × 9/5 + 32

°F = (90 − 273.15) × 9/5 + 32

°F = (-183.15) × 9/5 + 32

°F = -329.67 + 32

°F = -297.67 °F

Explanation:

they are called hydrocarbyls

pls mark me brainliest

Answer:

The first carbon atom that attaches to the functional group is referred to as the alpha carbon.

Answer:

The coefficients are; 4, 0, 2, 2

Explanation:

The equation is given as;

HCl + O2 --> H2O + Cl2

Upon balancing the equation, we have;

4HCl + O2 --> 2H2O + 2Cl2

Answer:

[tex]K^{2000K}=0.774\\\\K^{3000K}=12.56[/tex]

Explanation:

Hello,

In this case, considering the reaction, we can compute the Gibbs free energy of reaction at each temperature, taking into account that the Gibbs free energy for the diatomic element is 0 kJ/mol:

[tex]\Delta _rG=\Delta _fG_{X}-\frac{1}{2} \Delta _fG_{X_2}=\Delta _fG_{X}[/tex]

Thus, at 2000 K:

[tex]\Delta _rG=\Delta _fG_{X}^{2000K}=4.25kJ/mol[/tex]

And at 3000 K:

[tex]\Delta _rG=\Delta _fG_{X}^{3000K}=-63.12kJ/mol[/tex]

Next, since the relationship between the equilibrium constant and the Gibbs free energy of reaction is:

[tex]K=exp(-\frac{\Delta _rG}{RT} )[/tex]

Thus, at each temperature we obtain:

[tex]K^{2000K}=exp(-\frac{4250J/mol}{8.314\frac{J}{mol\times K}*2000K} )=0.774\\\\K^{3000K}=exp(-\frac{-63120J/mol}{8.314\frac{J}{mol\times K}*3000K} )=12.56[/tex]

In such a way, we can also conclude that at 2000 K reaction is unfavorable (K<1) and at 3000 K reaction is favorable (K>1).

Best regards.

Answer:

Atomic no = 12 = Mg

Explanation:

It is given that,

The atomic number of two elements that are represented by letter Q and R are 9 and 12.

We need to write the electronic configuration of R. Atomic number shows the number of protons in atom.

For R, atomic number = 12

Its electronic configuration is : 2,8,2

It has two valance electrons in its outermost shell. The element is Magnesium (Mg).

According to the concept of redox reactions, the answer to this question is option C.

When the cell potential is positive. A redox reaction is spontaneous when the cell potential is positive.The cell potential is the measure of the driving force of the chemical reaction occurring in the electrochemical cell. In an electrochemical cell, a redox reaction occurs, which leads to the production of an electric potential.

If this potential is positive, then the redox reaction is considered spontaneous. However, if the potential is negative, then the reaction is non-spontaneous.In general, a redox reaction is spontaneous if the potential difference between the two electrodes of the cell is positive. This means that the reaction will occur spontaneously without any external energy input.

Thus, the correct option is C.

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Answer:

Gay lussacs law

Explanation:

Answer:

Toxins

Explanation:

Answer: [tex]\Delta H = -272.25kJ[/tex] for 1 mole of NO.

Explanation: Hess' Law of Constant Summation or Hess' Law states that the total enthalpy change of a reaction with multiple stages is the sum of the enthalpies of all the changes.

For this question:

1) [tex]N_{2}_{(g)} + 3H_{2}_{(g)}[/tex] => [tex]2NH_{3}_{(g)}[/tex]       [tex]\Delta H=-92kJ[/tex]

2) [tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex]       [tex]\Delta H=-905kJ[/tex]

Amonia ([tex]NH_{3}_{(g)}[/tex]) appeares as product in the first equation and as reagent in the 2 reaction, so when adding both, there is no need to inverse reactions. However, in the 2nd, there are 4 moles of that molecule, so to cancel it, you have to multiply by 2 the first chemical equation and enthalpy:

[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex]     [tex]\Delta H=-184kJ[/tex]

Now, adding them:

[tex]2N_{2}_{(g)} + 6H_{2}_{(g)}[/tex] => [tex]4NH_{3}_{(g)}[/tex]     [tex]\Delta H=-184kJ[/tex]  

[tex]4NH_{3}_{(g)}+5O_{2}_{(g)}[/tex] => [tex]4NO_{(g)}+6H_{2}O_{(g)}[/tex]       [tex]\Delta H=-905kJ[/tex]

[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex]  [tex]\Delta H = -185-905[/tex]

[tex]2N_{2}_{(g)}+6H_{2}_{(g)}+5O_{2}_{(g)}=>4NO_{(g)}+6H_{2}O_{(g)}[/tex]  [tex]\Delta H = -1089kJ[/tex]

Note net enthalpy is for the formation of 4 moles of nitric oxide.

For 1 mole:

[tex]\Delta H = \frac{-1089}{4}[/tex]

[tex]\Delta H=-272.25kJ[/tex]

To form 1 mol of nitric oxide from nitrogen, oxygen and hydrogen, net change in enthalpy is [tex]\Delta H=-272.25kJ[/tex].