Sodium metal reacts rapidly with water to form a solution of sodium hydroxide (NaOH) and hydrogen gas (H2). This reaction is exothermic.
Equation:
2Na + 2H²0 --------}- 2NaOH + H²
7.23 One equivalent of sodium methanethiolate is added to an electrophile that has two leaving groups. Which product will be major
The question is incomplete, the complete question is shown in the image attached to this answer
Answer:
A
Explanation:
We can see from the conditions of the reaction that the incoming nucleophile is -SCH3 and there are two possible leaving groups in the substrate.
First of all, we have to look at the conditions of the reaction. We can see that the reaction is taking place in DMF, a polar aprotoc solvent. This condition favours the SN2 synchronous mechanism over the SN1 ionic mechanism.
Hence, the nucleophile at the 1-position is preferentially substituted owing to the conditions of the reaction.
Thus, option A is the major product of the reaction.
ELECTROLYSIS OF MOLTEN NaCl IS DONE IN A DOWNS CELL OPERATING AT 7.0 VOLTS AND 4.0X10^4A. HOW MUCH Na(s) AND Cl2(g) CAN BE PRODUCED IN 8 HOURS IN SUCH A CELL?
Answer:
Mass of sodium produced = 2.74 × 10⁵ g of Na
Mass of chlorine produce = 4.24 × 10⁵ g of Cl₂
Explanation:
In the electrolysis of molten NaCl as described above, the quantity of charge used is given by the formula, Q = I × t
Where I isnthe current passed in amperes and t is time in seconds.
Q = 4.0 × 10⁴ A × (8 × 60 × 60) s = 1.152 × 10⁹ C
Equation for the discharge of sodium is; Na+ + e- ---> Na (s)
One mole of electrons is required to discharge one mole of Na
One mole of electron = 1 faraday = 96500 C
One mole of Na has a mass of 23 g
96500 C produces 23 g of Na
1.152 × 10⁹ C will produce 23 g × 1.152 × 10⁹ C / 96500 C = 2.74 × 10⁵ g of Na
Equation for the discharge of chlorine gas is; 2 Cl- ---> Cl₂(g) + 2e-
Two mole of electrons are required to discharge one mole of chlorine gas
Two moles of electron = 2 faraday = 2 × 96500 C = 193000
One mole of Cl₂ has a mass of 71 g
193000 C produces 71 g of Cl₂
1.152 × 10⁹ C will produce 71 g × 1.152 × 10⁹ C / 193000 C = 4.24 × 10⁵ g of Cl₂
The amount of Na produced is 274551 g and the amount of Cl₂ produced is 423763.5 g.
Current passed through the cell = [tex]4.0\times10^4 A[/tex]
Time = 8 Hours
We have to calculate the amount of Na and [tex]Cl_2[/tex] produced in 8 hours in the downs cell.
What is a down cell?The Downs process is an electrochemical method for the commercial preparation of metallic sodium, in which molten NaCl is electrolyzed in a special apparatus called the Downs cell.
The total charge passed through the cell is calculated by the given formula as
Charge(Q) = Current(I) × time(t)
Q = [tex]4.0\times10^4 A \times t[/tex]
[tex]t = 8 \times 60\times 60[/tex] sec
t = 28800 sec
Q = [tex]4.0\times10^4 A \times 28800[/tex] sec
Q = [tex]115200\times 10^4 A\ sec[/tex]
We know that, Ampere = Coulombs per sec
Q = [tex]115200\times 10^4\ C[/tex]
1 mol of electrons 96500 C charge
Therefore, the number of mols of electrons carries this [tex]115200\times 10^4\ C[/tex] charge = [tex]\frac{115200\times10^4}{96500}[/tex] = 1.1937 × 10⁴ = 11937 mol electrons
In the Down's cell
Half cell reactions are:
Reduction half-reaction: [tex]2Na^+(aq)+2e^- \to 2Na(s)[/tex]
Oxidation half-reaction: [tex]2Cl^-(aq)\to Cl_2(g) + 2e^-[/tex]
We know that no. of moles = [tex]\frac{given \ mass}{molar \ mass}[/tex]
Molar mass of Na = 23 g/mol
The mass of Na formed = 11937 mol × 23 g/mol = 274551 grams
The molar mass of Cl₂ = 71 g/mol
The mass of Cl₂ = [tex]\frac{11937}{2}\times 71 = 423763.5 \ grams[/tex]
Hence, the amount of Na produced is 274551 g and the amount of Cl₂ produced is 423763.5 g.
To learn more about electrochemistry, click here:
https://brainly.com/question/13891856
A scientist is conducting a Sanger's sequencing experiment to determine the number of polypeptides present in an oligomeric protein. The molecular weight of the protein is 18000 g/mol . After the reaction of 520 mg of the protein with 1‑fluoro‑2,4‑dinitrobenzene, the peptide bonds were hydrolyzed with an acid. As a result, the scientist obtained 39 mg of 2,4‑dinitrophenyl serine. What is the number of the polypeptide chains present in the oligomer?
Answer:
Depends on molecule.
Explanation:
The number of the polypeptide chains present in the oligomer depends on the molecule. Some molecules have more polypeptide chains whereas some of them have less polypeptide chains. For example, Hemoglobin is a oligomer that consists of four Polypeptide Chains, two of these Polypeptide Chains are α-globin molecules, each comprise of 141 amino acids, and the other two are (β, γ, δ, or ε) globins, each consist of 146 amino acids.
Determine whether each of the properties described applies to volumetric or graduated glassware. 1. Used for applications in which great accuracy is needed_____.a. volumetricb. graduated 2. Capable of measuring a range of volumes of liquid_____.a. volumetric
b. graduated 3. Designed to measure one specific volume of liquid_____.a. volumetric
b. graduated
Answer:
1) volumetric
2) graduated
3) volumetric
Explanation:
A volumetric glassware is a glassware that is marked at a particular point. A typical example of a volumetric glassware is the volumetric flask. A volumetric glassware is capable of measuring only a specific volume of a liquid.
On the other hand, graduated glassware can measure a range of volumes of liquid. However, a volumetric glassware is still required where a high degree of accuracy is important.
Calculate the mass percent of carbon in the following molecule: Mn3[Mn(CO)4]3
Answer:
21.63 %
Explanation:
The molar mass of Mn₃[Mn(CO)₄]₃ is 665.64 g/mol.
Let's assume we have 1 mol of Mn₃[Mn(CO)₄]₃, if that were the case then we would have 665.64 grams.
There are 12 C moles per Mn₃[Mn(CO)₄]₃, with that in mind we calculate the weight of 12 C moles:
12 mol C * 12 g/mol = 144 gFinally we calculate the mass percent of carbon:
144 g / 665.64 g * 100% = 21.63 %In order for a substitution reaction to take place, at a minimum, __________ and ___________ are needed. carbocation rearrangement proton transfer loss of a leaving group nucleophilic attack
Answer: In order for a substitution reaction to take place, at a minimum, loss of a leaving group and nucleophilic attack are needed.
Explanation:
When one group in a molecule is replaced by another one then it is called a substitution reaction.
For a substitution reaction reaction to occur at a minimum, it is necessary to have a leaving group that helps in creating a carbocation and hence a nucleophile can easily attack.
For example, [tex]CH_{4} + Cl_{2} + h\nu \rightarrow CH_{3}Cl + HCl[/tex]
Thus, we can conclude that in order for a substitution reaction to take place, at a minimum, loss of a leaving group and nucleophilic attack are needed.
Green plants use light from the Sun to drive photosynthesis, a chemical reaction in which liquid water and carbon dioxide gas form aqueous glucose (CH1206) and oxygen (O2) gas. Calculate the moles of glucose produced by the reaction of 2.40 mol of carbon dioxide. Be sure your answer has a unit symbol, if necessary, and round it to 3 significant digits.
Answer:
.
Explanation:
What is Heisnberg's uncertainity principle? Why it make sense only for microscopic particles.
Answer:
The uncertainty principle is one of the most famous (and probably misunderstood) ideas in physics. It tells us that there is a fuzziness in nature, a fundamental limit to what we can know about the behavior of quantum particles and, therefore, the smallest scales of nature.
What is the volume of a flask containing 0.199mol of Cl2at a temperature of 313K and a pressure of 1.19atm
Answer:
43.0 L
Explanation:
Step 1: Given and required data
Moles of chlorine gas (n): 0.199 molTemperature (T): 313 KPressure (P): 1.19 atmIdeal gas constant (R): 0.0821 atm.L/mol.KStep 2: Calculate the volume of the flask (V)
We will use the ideal gas equation.
P × V = n × R × T
V = n × R × T / P
V = 1.99 mol × (0.0821 atm.L/mol.K) × 313 K / 1.19 atm = 43.0 L
The answer is 4.30 L
A chemistry student needs 90.0mL of carbon tetrachloride for an experiment. By consulting the CRC Handbook of Chemistry and Physics, the student discovers that the density of carbon tetrachloride is 1.59g*cm3- Calculate the mass of carbon tetrachloride the student should weigh out. Be sure your answer has the correct number of significant digits.
Answer:
volume = mass/density
Here, volume = 80g/1.59gcm-3 → 50.314 cm3
Explanation:
Consider the arrangement of gases shown below. If the value between the gases is opened and the temperature is held constant, determine the following.
Answer:
I don't know what to say . just for points
A cylinder contains 26.5 L of oxygen gas at a pressure of 1.7 atm and a temperature of 280 K. How much gas (in moles) is in the cylinder?
Answer:
The appropriate answer is "1.96 mol".
Explanation:
The given values are:
Volume,
V = 26.5 L
Pressure,
P = 1.7 atm
Temperature,
T = 280 K
Now,
The number of moles (n) will be:
= [tex]\frac{PV}{RT}[/tex]
By substituting the values, we get
= [tex]\frac{1.7\times 26.5}{0.0821\times 280}[/tex]
= [tex]\frac{45.05}{22.988}[/tex]
= [tex]1.96 \ mol[/tex]
Consider equimolar samples of different ideal gases at the same volume and temperature. Gas A has a higher molar mass than gas B.
1. Compare the pressure
a. A > B
b. A= B
c. A < B
2. Compare the speed.
a. A > B
b. A= B
c. A < B
Answer:
I don't understand the question
Explanation:
1. c
2. c
Answer:
1. b. A = B
2. c. A < B
Explanation:
Consider equimolar samples of different ideal gases at the same volume and temperature. (nA = nB)
Gas A has a higher molar mass than gas B. (MA > MB)
1. We can calculate the pressure using the ideal gas equation.
P = n × R × T / V
Since n, T and V are equal, the pressure of both gases are equal as well.
2. We can calculate the root-mean-square of the velocity using the following expression.
v(rms) = √(3RT/M)
There is an inverse relationship between speed and molar mass. Since A has a higher molar mass, it has a lower speed.
The rate law for the following reaction: H2SiF6(aq)+2NaF(aq)+3H2O(aq)⟶Na2SiO3(s)+8HF(aq) is second order in H2SiF6, zero order in NaF and first order in H2O. By what factor will the reaction rate change if the concentrations of all reactants are tripled?
Answer:
The rate law for the following reaction:
H2SiF6(aq)+2NaF(aq)+3H2O(aq)⟶Na2SiO3(s)+8HF(aq)
is second order in H2SiF6, zero order in NaF and first order in H2O.
The number of mol of oxygen in 2.5 mol of caffeine
Answer:
5.0molO
Explanation:
To find the moles of oxygen in 2.5 moles of caffeine, we will first research caffeine's molecular formula: C8H10N4O2. From the molecular formula, we can see there are 2 oxygen atoms in every 1 molecule of C8H10N4O2.We can therefore multiply by the following mole ratio to get the moles of oxygen.
2.5molC8H10N4O2×2molO/1molC8H10N4O2 = 5.0molO.
write Balance chemical reaction for preparation of chlorine with or without application heat
Answer:
2KMnO4(aq) + 16HCl(aq) ------> 2MnCl2(aq) + 2KCl(aq) + 8H2O(l) + 5Cl2(g)
Explanation:
Chlorine is a diatomic halogen gas known for its greenish-yellow colour. It has a pungent smell and is only moderately soluble in water.
It is a very reactive gas and is never found in free state in nature.
Chlorine can be prepared in the laboratory by oxidation of hydrochloric acid using KMnO4 as follows;
2KMnO4(aq) + 16HCl(aq) ------> 2MnCl2(aq) + 2KCl(aq) + 8H2O(l) + 5Cl2(g)
The set up does not need to be heated.
Which substrate is used in the last step of glycolysis
Pyruvate Kinase
Pyruvate Kinase performs a substrate level phosphorylation on ADP to generate an ATP and pyruvate, the final product of glycolysis.
PK dificiency is transmitted in an autosomal recessive disorder in which both alleles must contain the mutated gene, PK-LR.
Hope it helps you! ＼(^ᴥ^)／
What is the volume of a gas 622.7 mL at 25.1 C if the temperature is increased to 60.7 C without changing the pressure, what is the new volume of the gas?
A. 697
B. 556
C. 1510
D. 9.35
Answer:
A) 697 mL
Explanation:
First convert degrees Celsius to Kelvin.
That gives;
For T1; temp 1 (273 + 25.1)
= 298.1K
T2; temp 2 (273+60.7)
=333.7K
From the formula, (V1/T1) = (V2/T2)
To find V2 = (V1/T1) × T2
= (622.7/298.1) × 333.7.
= 697.06mL
~~ 697mL
Write the balanced dissociation equation for solid sulfur difluoride in aqueous solution. If it does not dissociate, simply write only NR.
Answer:
SF2(aq) → S²⁺(aq) + 2F-(aq)
Explanation:
The sulfur difluoride, SF2, dissolves in water because the differences in electronegativities are considerable (3.98 for Fluorine and 2.58 for S) doing the F-S bond polar. As water is a polar solvent will dissolve the SF2 as follows:
SF2(aq) → S²⁺(aq) + 2F-(aq)As Fluorine has a > electronegativity than S, the Fluorine will be negative and S will be positive. Also, all halogen ions has a charge of -1.
The Hammond Postulate describes the relationship between the energy of the transition state and the productdistribution in a reaction that is capable of following more than one pathway.
What are the appropriate labels for the sentence?
The Hammond postulate states that reactions which are thermodynamically endothermic and kinetically ___________ have transitions states that occur ___________ in the reacton time frame, and resemble the ___________ in terms of energy and structure.
define a fluid very sort answer
Answer:
A fluid is a medium that has a defined mass and volume, but no fixed shape, at a constant temperature and pressure. This may include gases, liquids, plasmas, and to some extent plastic solids. A fluid can flow and deform, preventing it from carrying loads in a static equilibrium. A fluid is always compressible and internal frictional forces always occur due to the viscosity of the fluid.
g Calculate the theoretical yield (in grams) of your product if you start with 0.50 grams of E-stilbene. The molecular weight of E-stilbene is 180.25 g/mol, and the molecular weight of the product is 340.058 g/mol. 0.5109 grams 0.9433 g 0.2342 g 0.6312 g
Answer:
0.9433g
Explanation:
Theoretical yield is defined as the mass produced assuming all reactant reacts producing the product.
Assuming the reaction is 1:1, we need to find the moles of E-stilbene (Reactant). If all reactant reacts, the moles of E-stilbene = Moles of product.
Using the molar mass of the product we can find the theoretical yield as follows:
Moles E-stilbene:
0.50g * (1mol/180.25g) = 0.00277 moles = Moles Product
Mass Product = Theoretical yield:
0.00277 moles * (340.058g/mol) = 0.9433g
compound of aspartame is a dipeptide that is often used as a sugar substitute which functional groups are present
Answer:
Carboxyl, primary amine, amide, ester, and phenyl.
Explanation:
The functional groups present in the compound of aspartame are carboxyl, primary amine, amide, ester, and phenyl. Aspartame is an artificial non-saccharide sweetener which is 200 times sweeter than sucrose. This aspartame is commonly used as a sugar substitute in many foods and beverages. It has the trade names such as NutraSweet, Equal, and Canderel.
What does the term spontaneous mean in chemical reactions?
A. Producing heat as a product
B. Occurring without added energy
C. Occurring only at high temperatures
D. Occurring in an aqueous solution
Answer:
B
Explanation:
Spontaneous in chemical reactions means without any external input.
Occurring without added energy. Hence, option B is correct.
What is a spontaneous reaction?A spontaneous reaction is a reaction that supports the formation of products under the conditions under which the reaction is happening.
Spontaneous Reaction- a reaction that favours the formation of products at the conditions under which the reaction is occurring.
A non-spontaneous reaction can be made spontaneous if it is inside a controlled environment, this is what happens in nuclear power plants that create atomic fusion and fission in chambers that are controlled to control different particles to create nuclear active rays.
Hence, option B is correct.
Learn more about the spontaneous reaction here:
brainly.com/question/23142328
#SPJ5
How many moles are contained in .984 molecules F2?
Answer:
1.6 x 10⁻²⁴ moles
Explanation:
We have 0.984 molecules of F₂. We know that 1 mol is equal to 6.022 x 10²³ molecules. Thus, we have a conversion factor: 1 mol/6.022 x 10²³ molecules
So, we multiply the molecules of F₂ by the conversion factor to calculate the moles:
0.984 molecules x 1 mol/6.022 x 10²³ molecules = 1.6 x 10⁻²⁴ moles
One of the students in lab decided to use two fractionating columns (one on top of the other) instead of just one. How would this:_________.
a) affect the separation between hexane and heptane?
b) affect the yield of recovered pure hexane?
c) affect the yield of recovered pure heptane.
Explain your reasoning.
Answer:
See detailed explanation.
Explanation:
Hello there!
In this case, according to the given description, it turns out possible for us to infer that the second fractionating column on top of the first one will favor the light product, in this case hexane as it has the lowest boiling point and molar mass; in such a way, we can tell the following:
a) The separation between hexane and heptane will be increased as a purer hexane-rich product will be obtained on the top of the second column.
b) Will be increased as well, because the second column will remove more heptane.
c) Also, more pure heptane will be obtained on the bottom of the two columns, yet the most favored yield will be that of hexane.
All of the aforementioned is possible due to the fact that the second column will remove the amount of heptane that could not be removed on the top of the first column by taking the vapor-liquid equilibrium further from the first column's maximum separation, which is known as distillation sequences.
Regards!
Please help me ASAP I’ll mark Brainly
Answer:
cell
chloroplast and cell wall
nucleus
life processes
cell membrane
shape and size
vacuole
Hope it helps
¿soy guapo?
si dices que si te doy una galletita
Answer:
Hindi ko po ma gets sinasabi nyu pwedeng pakiayus
The density of aluminum is 2.7 g/cm3.
Part A
What is its density in kilograms per cubic meter?
Express your answer in kilograms per cubic meter to two significant figures.
Answer:
2700 kg/m³
Explanation:
First let's convert 2.7 g/cm³ to kg/cm³, keeping in mind that 1 kilogram equals 1000 grams:
2.7 g/cm³ * [tex]\frac{1kg}{1000g}[/tex] = 0.0027 kg/cm³Finally we need to convert 0.0027 kg/cm³ to kg/m³, keeping in mind that 1 meter equals 100 centimeters, as follows:
0.0027 kg/cm³ * [tex](\frac{100cm}{1m} )^3[/tex] = 2700 kg/m³The answer is 2700 kg/m³.
A 1.5-m 3 insulated rigid tank contains 2.7 kg of carbon dioxide at 100 kPa. Now paddle-wheel work is done on the system until the pressure in the tank rises to 150 kPa. Determine the entropy change of carbon dioxide during this process. Assume constant specific heats
Answer:
The entropy change of carbon dioxide = 0.719 kJ/k
Explanation:
Given:
1.5 m - 3 insulated rigid tank contains 2.7 kg of carbon dioxide at 100 kPa
The objective is to determine the entropy change of carbon dioxide
Formula used:
ΔS=
Solution:
On considering,
[tex]C_{P} =0.846 kJ/kg K\\C_V=0.657 kJ/kg k\\[/tex]
ΔS=[tex]mc_{v} lu\frac{p_{2} }{P_{1} }[/tex]
On substituting the values,
ΔS=[tex]2.7*0.657lu\frac{150}{100}[/tex]
ΔS=0.719 kJ/k
The entropy change is "0.719 kJ/K".
Given values are:
Mass of tank,
m = 2.7 kgPressure,
P₁ = 100 kPaRised pressure,
P₂ = 150 kPaAssumption of constant specific heat is,
[tex]C_v = 0.657 \ kJ/kgK[/tex]As we know the formula,
→ [tex]\Delta S = mC_v \ ln(\frac{P_2}{P_1} )[/tex]
[tex]= (2.7)(0.657) \ ln (\frac{150}{100} )[/tex]
[tex]= 1.7739\times 0.4055[/tex]
[tex]= 0.7193 \ kJ/K[/tex]
Thus above answer is right.
Learn more:
https://brainly.com/question/20340354
