Consider the following: Li(s) + ½ I₂(g) --> LiI(s) ΔH = –292 kJ. LiI(s) has a lattice energy of –753 kJ/mol. The ionization energy of Li(g) is 520 kJ/mol, the bond energy of I₂(g) is 151 kJ/mol, and the electron affinity of I(g) is –295 kJ/mol. Use these data to determine the heat of sublimation of Li(s).

Answers

Answer 1

Answer:

Heat of sublimation of Li(s) = 160.5 kJ/mol

Explanation:

Given that:

[tex]\mathtt{2Li(s) + \dfrac{1}{2} I_2(g) \to 2LiI(s)}[/tex]

ΔH = –292 kJ

The heat of formation for the above reaction =  –292 kJ × 2 =  -584 kJ/mol

[tex]\mathtt{Li^+_{(g)} + I^-_{(g)} \to LiI_{(s)}}[/tex]

The lattice energy of LiI(s) = -753 kJ/mol

[tex]\mathtt{Li(g)\to Li^+(g) + e^- }[/tex]

The ionization energy of LiI(s) = +520 kJ/mol

[tex]\mathtt{I_2_{(g)} \to 2I_{(g)} }[/tex]

The Bond Energy of I₂(g) = 151 kJ/mol

[tex]\mathtt{I_{(g)} + e^- \to I^-_{(g)}}[/tex]

The electron affinity of I(g) = -295 kJ/mol

Heat of sublimation: Sublimation is the process of changing of a solid matter into gas without passing through the liquid stage, Now, the molar heat of sublimation is the amount of energy that must be added to a mole of solid  to turn it directly into a gas without any interference through the liquid phase provided the pressure is  constant.

From  the above reactions: The heat of sublimation  of Li(s) can be calculated by the sum total of the following.

[tex]\mathtt{Li_{(s)} + \dfrac{1}{2} I_2_{(g)} \to LiI_{(s)} \ \ -292 kJ/mol} \\ \\\mathtt{I_{(g)} \to \dfrac{1}{2} I2(g) \ \ -75.5 kJ/mol} \\ \\ \mathtt{I^-(g) \to I(g) + e^- \ \ +295 kJ/mol} \\ \\ \mathtt{LiI(s) \to Li^+_{(g)} + I^-_{(g)} \ \ +753 kJ/mol} \\ \\ \mathtt{Li^+_{(g)} + e^- \to Li(s) \ \ -520 kJ/mol} \\ \\[/tex]

[tex]\mathtt{Li(s) \to Li(g)}[/tex] = (-292 +(-75.5)+295+753+(-520)) kJ/mol

[tex]\mathtt{Li(s) \to Li(g)}[/tex] =  160.5 kJ/mol

Heat of sublimation of Li(s) = 160.5 kJ/mol


Related Questions

A straight chain hydrocarbon with the formula C^3H^4 _____.

has a triple C-C bond
has a double C-C bond
is essentially inert
has two double C-C bonds

Answers

Answer:

has two double C-C bonds

Explanation:

A saturated compound is a compound having the full complement of hydrogen atoms for every carbon atom while an unsaturated compound does not contain the full complement of hydrogen atoms for every atom of carbon.

If we look at C3H4, the only possible structure of the compound is H2C=C=CH2. We can see from this arrangement that the compound contains a cumulative double bond. This is the specific structure that fits into one of the descriptions in the options, the compound contains two double bonds.

A hot metal plate at 150°C has been placed in air at room temperature. Which event would most likely take place
over the next few minutes?
Molecules in both the metal and the surrounding air will start moving at lower speeds.
Molecules in both the metal and the surrounding air will start moving at higher speeds.
The air molecules that are surrounding the metal will slow down, and the molecules in the metal will speed up
The air molecules that are surrounding the metal will speed up, and the molecules in the metal will slow down

Answers

Answer:

d

Explanation:

Ethane- (-89) Butane- (0) Methanol- (64.7) Hexane- (69) Pentadecane- (270) Heptadecane- (302) a) A mixture of pendtadecane and heptadecane can be separated by______ b) Which pair of compounds are easiest to separate (i) Ethane and Pentadecane (ii) Ethane and Heptadecane (iii) Butane and Hexane (iv) Butane and Heptadecane

Answers

Answer:

(ii) Ethane and Heptadecane

Explanation:

The separation of all the species listed in the answer options for the question depends on the molar mass of each specie.

Ethane is a low molecular mass gas. It exists in the gaseous state at room temperature. However, heptadecane appears as a liquid because it has a greater relative molecular mass.

It is very easily to distinguish between the gas, ethane and the liquid heptadecane which is a high molecular mass alkane, hence the answer.

A gas has a volume of 25.0 mL at 2.50 atm. What is the volume at 457 mmHg if the temperature remains constant?

Answers

Answer:

≈ 0.104 liters  

Explanation:

We can use Boyle's Law: [tex]P_{1}V_{1} = P_{2}V_{2}[/tex]

P₁ = 2.50 atm

V₁ = 25.0 mL

P₂ = 457 mmHg

V₂ = ?

Because pressure should be in atm we will convert 457 mmHg to units in atm:

1 atm = 760mmHg so we can divide 457 by 760 and we get ≈ 0.601atm

Next we can plug in the units to the equation for Boyle's Law:

(2.50)(25.0) = (0.601)(V₂)

Solve for V₂

V₂ will give you ≈ 104mL or 0.104L

Either is correct depending on which unit they are asking you to use

Which of the following is an example of a consumer? Tree Sun Rabbit Mushroom

Answers

Answer:

rabbit

Explanation:

Answer:

rabbit

Explanation:

the rabbit is the consumer because the sun "produces" the tree and mushroom, the rabbit comes along and eats the mushroom which was produced by the sun.

0.10 moles of sodium sulfate is dissolved into 12 mL of solution. What is the molar concentration of the solution?
Your answer should have two significant figures (round your answer to one decimal place).

Answers

the molar concentration should be atleast 5mL off the solution since its disolved

Answer:

8.3

Explanation:

Convert mL to L.

12 mL×1 L1000 mL=0.012 L

Solve for molarity.

Molarity=moles of solute

liters of solution=0.10 mol0.012 L=8.3 M

Given that the density of air is 14.4, then the vapour of sulphur IV oxide is A. 16 B. 32 C. 64 D. 128
Thank you.

Answers

Answer:

32

Explanation:

The vapour density of a gas is the number of times a given volume of gas or vapour is as heavy as the same volume of hydrogen at a particular temperature and pressure.

Vapour density = 2 × relative molecular mass of the gas or vapour

Relative molecular mass of SO2 = 32 + 2(16) = 64

Hence;

Vapour density of SO2 = 64/2

Vapour density of SO2 = 32

What is 9.871 x 10^-3 in standard form? *

Answers

Answer:

0.009871

Explanation:

[tex] 9.871\times 10^{-3} = 0.009871[/tex]

Answer:

.009871

Explanation:

3. Prepare a saturated solution of common salt in hot water. Suspend a thick cotton wick into this solution. Keep it undisturbed for a few days. You will find that common salt crystals will deposit on the wick. Is the change physical or chemical?

Answers

Answer:

physical

Explanation:

The change is physical.

A physical change involves a reversible change to the physical properties of substances, whereas a chemical change involves an irreversible change to the chemical properties of substances through a chemical reaction.

The dissolution of common salt is a physical change because the common salt can be retrieved by evaporating off the water. This is what was manifested by the deposition of common salt crystals on the wick.

Determinación de pH Expresa las siguientes concentraciones de [H+ ] en función del pH • [H+] = 0.001 M • [H+] = 0.002 M • [H+] = 2.45X10-4 M • [H+] = 5.2X10-9 M • [H+] = 0.04 M

Answers

Answer:

• pH = 3.0

• pH = 2.70

• pH = 3.61

• pH = 8.28

• pH = 1.40

Explanation:

El pH es una medida en química usada para determinar el grado de acidez o basicidad en una solución.

Se define como:

pH = -log₁₀ [H⁺]

El - logaritmo de la concentración molar de H⁺

Para las concentraciones de H⁺ dadas:

• [H+] = 0.001 M

pH = -log (0.001M) = 3

pH = 3.0

• [H+] = 0.002 M

pH = -log (0.002M)

pH = 2.70

• [H+] = 2.45X10-4 M

pH = -log (2.45X10-4 M )

pH = 3.61

• [H+] = 5.2X10-9 M

pH = -log (5.2X10-9 M)

pH = 8.28

• [H+] = 0.04 M

pH = -log (0.04M)

pH = 1.40

Use the following steps to balance the redox reaction using half-reactions. Zn(s) + Fe3+ Zn2+ + Fe(s) (unbalanced) a. Write balanced oxidation and reduction half-reactions. Indicate which is the oxidation reaction and which is the reduction reaction. (6 points) b. Balance the charge in the two half-reactions by multiplying the half-reactions by the correct multiplication factors. (4 points) c. Add the equations and simplify to get the balanced equation.

Answers

Answer:

Explanation:

a )

Zn = Zn²⁺ + 2e   ( oxidation reaction )

Fe³⁺ + 3e = Fe( s ) ( reduction reaction )

b )

[ Zn = Zn²⁺ + 2e ] x 3

[ Fe³⁺ + 3e = Fe( s ) ] x 2

-------------------------------------------------------------------

3 Zn + 2 Fe³⁺ + 6e = 3 Zn²⁺ + 2 Fe ( s ) + 6e

3 Zn + 2 Fe³⁺  = 3 Zn²⁺ + 2 Fe ( s )

A solution of HCL has percent by mass of 5%. What does it mean?​

Answers

This means that in 100g of solution, there are 5g of HCl and 95g of water

What group is calcium and sodium in?

Answers

Answer:

Calcium: Alkaline Earth

Sodium: Alkali Metal

Hope it helps!

Answer:

Calcium is in Alkaline Earth

Sodium is in Alkali Metal

Potatoes are cut into many parts, making sure that each part has at least one eye (bud). Each piece of potato will usually grow into a new potato plant. Will a new potato plant grow, if planted only with the eye? A. Yes, a full new potato plant can grow from it. B. Yes, but the new plant will take a slightly longer time to germinate. C. No, a new potato plant will not grow because the food needed for germination comes from the potato piece. D. No, a new potato plant will not grow because the leaves emerge only from the potato piece.

Answers

Answer:

b

Explanation:

the eye is the most important so it would grow but it will take some time because if we plant it with piece it has some food

3.0 cm x 4.0 cm x 1.0 cm

[?]cm^3​

Answers

Explanation:

Hi there!!

you asked to multiply these all right,

you can simply multiply it ,

=3cm × 4 cm × 1cm

= 12cm^2×1cm (4×3=12)

= 12cm^3 (12×1=12)

Therefore, theanswer is 12 cm^3.

Hope it helps..

what is the question tag for Lynne speaks french and German

Answers

Answer:here is it...

Explanation:

The question tag for the statement "Lynne speaks French and German" would be "doesn't she?"

The question tag is a short question added to the end of a statement to turn it into a question and seek confirmation or agreement. It is usually formed by using an auxiliary verb opposite in polarity to the main verb in the statement.

In the given statement, "Lynne speaks French and German," the main verb is "speaks." Since the main verb is in the affirmative form, the question tag should use the negative form.

Therefore, we use the auxiliary verb "doesn't" (the negative form of "does") and add the pronoun "she" to match the subject of the statement.

Know more about question tag:

https://brainly.com/question/33778833

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Balance the equation: "Sodium oxide reacts with water to form sodium hydroxide and hydrogen." I can't find the correct coefficients to balance the equation. I have written my unbalanced equation in the file attached.

Answers

Answer:

So, sodium oxide + water = sodium hydroxide + hydrogen is written Na2O+H2O-->NaOH+H.

To balance the equation it should read NaO+H2O-->2NaOH

Explanation:

Na2O+H2O-->2NaOH+0H2.......the 0H2 is dropped because there is no value

The correct balance of equation will be

Na2O + H2O - - > 2NaOH

What is a balanced chemical equation?

A chemical equation where the number of atoms on both the reactant side and the product side of the reaction are equal is called a balanced chemical equation.

In a balanced chemical equation, not only the number of atoms but the charge and the mass is the same on both sides of the equation.

A chemical equation needs to be balanced to validate the law of conservation of mass. The law of conservation of mass states that the 'mass can neither be created nor destroyed in a chemical reaction'.

If the chemical equation is not balanced, it will go against the fundamental law of law of conservation of mass.

Thus, the chemical equations need to be balanced.

Therefore to balanced the given chemical equation, we equate the number of atoms on both the reactant and the product side of the reaction.

It will be written as

Na2O + H2O - - > 2NaOH

Read more about balanced chemical equations, here

https://brainly.com/question/8062886

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brainliest to whoever gets it the soonest, what SI unit do you use to measure the length of a book, and what tool and unit for the volume of a box?

Answers

The most appropriate SI unit used to measure the length of a book would be Centimeters.

The most appropriate SI unit to use for the volume of a book is centimeters cubed

PS: I am also a JoJo fan

Answer:

The SI unit of volume is the cubic meter (m 3 ), which is the volume occupied by a cube that measures 1 m on each side. This very large volume is not very convenient for typical use in a chemistry laboratory. A liter (L) is the volume of a cube that measures 10 cm (1 dm) on each side.

Scientific method quick check

Answers

Answer:

Quick you said:

-Purpose/Question

Ask a question.

-Research

Conduct background research. Write down your sources so you can cite your references. In the modern era, a lot of your research may be conducted online. Scroll to the bottom of articles to check the references. Even if you can't access the full text of a published article, you can usually view the abstract to see the summary of other experiments. Interview experts on a topic. The more you know about a subject, the easier it will be to conduct your investigation.

-Hypothesis

Propose a hypothesis. This is a sort of educated guess about what you expect. It is a statement used to predict the outcome of an experiment. Usually, a hypothesis is written in terms of cause and effect. Alternatively, it may describe the relationship between two phenomena. One type of hypothesis is the null hypothesis or the no-difference hypothesis. This is an easy type of hypothesis to test because it assumes changing a variable will have no effect on the outcome. In reality, you probably expect a change but rejecting a hypothesis may be more useful than accepting one.

-Experiment

Design and perform an experiment to test your hypothesis. An experiment has an independent and dependent variable. You change or control the independent variable and record the effect it has on the dependent variable. It's important to change only one variable for an experiment rather than try to combine the effects of variables in an experiment. For example, if you want to test the effects of light intensity and fertilizer concentration on the growth rate of a plant, you're really looking at two separate experiments.

-Data/Analysis

Record observations and analyze the meaning of the data. Often, you'll prepare a table or graph of the data. Don't throw out data points you think are bad or that don't support your predictions. Some of the most incredible discoveries in science were made because the data looked wrong! Once you have the data, you may need to perform a mathematical analysis to support or refute your hypothesis.

-Conclusion

Conclude whether to accept or reject your hypothesis. There is no right or wrong outcome to an experiment, so either result is fine. Accepting a hypothesis does not necessarily mean it's correct! Sometimes repeating an experiment may give a different result. In other cases, a hypothesis may predict an outcome, yet you might draw an incorrect conclusion. Communicate your results. The results may be compiled into a lab report or formally submitted as a paper. Whether you accept or reject the hypothesis, you likely learned something about the subject and may wish to revise the original hypothesis or form a new one for a future experiment.

Difference between atomic number and atomic weight any 2 points

Answers

Answer:

According to the definitions given, atomic mass which is also called atomic weight is the measured total mass of an element's atom. Whereas, atomic number is nothing but the total number of neutrons and protons in the nucleus of an atom....

can u talk to in comment section

What is 16.30 to the 100th gram

Answers

Answer:

1.65485688 × 10121 grams

Explanation:

Aside from those discrete items, anything like rice or flour can be measured out to make up 100 grams. For example, 1/2 cup (125 ml or about 4 and 1/2 fl. oz) of dry rice weighs very close to 100 grams.

A student made the Lewis dot diagram of a compound as shown. Mg is written with two dots shown on its top. Cl is written on the right side of Mg. Cl has seven dots around it. An arrow is shown from one dot on Mg toward the vacant space around Cl. Another arrow is shown from the other dot on Mg toward the vacant space around Cl. On the top, the art title is written as Students Lewis Dot Model. What is the error in the Lewis dot diagram?

Answers

Answer:

The dots were not properly located and arrows are not used in Lewis structures

Explanation:

If we intend to write a Lewis structure for a compound, that lewis structure must consist of only dots. These dots actually show the valence electrons on the outermost shell of the molecule.

We do not involve arrows when writing dot electron structures for compounds. The valence electrons of magnesium ought not to be written together because they are not a lone pair, rather they are two unpaired electrons. The use of an arrow suggests a coordinate covalent bond which is not the case here.

The correct lewis structure for MgCl2 is shown in the image attached to this answer.

Answer: B is the answer took the test

Explanation: both electrons of Mg should be transferred to one O atom...

which statement best describes a mole? it is 12 units of a given substance. it contains 6.02 1023 grams of sodium chloride. it is the mass of 12 carbon atoms. it contains 6.02 1023 particles of a given substance.

Answers

Answer:

The correct option is;

It contains 6.02 × 10²³ particles of a given substance

Explanation:

A mole of substance is the standard scientific unit of measurement for the quantity of the substance which is made up of a large number of small particles such as molecules, ions, atoms, electrons or other entities.

The General Conference on Weights and Measures defines the mole as the amount of a substance that contains 6.02214076 × 10²³ units of entities

The number 6.02214076 × 10²³, is also known as Avogadro's number.

The statement which correctly describes the mole is; it contains 6.02 × 10^23 particles of a given substance.

The mole refers to the amount of substance that contains the same number of elementary entities as 12 g of carbon - 12. According to Avogadro's law, the number of elementary entities in a substance is 6.02 × 10^23. These elementary entities could be atoms, ions, molecules etc.

Therefore, the statement which correctly describes the mole is; it contains 6.02 × 10^23 particles of a given substance.

Learn more: https://brainly.com/question/12108425

why is carbon iv oxide used in fire extinguishers

Answers

Answer:

Carbon dioxide extinguishes work by displacing oxygen, or taking away the oxygen element of the fire triangle. The carbon dioxide is also very cold as it comes out of the extinguisher, so it cools the fuel as well.

According to the table, a 23-30 watt CFL provides __________ lumens and is equivalent to a ________ incandescent bulb.

Answers

Answer:

The correct options are;

1. 1,600

2. 100 Watts

A 23-30 watt CFL provides 1,600 lumens and is equivalent to a 100 Watts incandescent bulb

Explanation:

Brightness is measured in lumens and watts measure energy usage therefore with the use of an energy saving light bulb, the same lumination can be obtained at a lower energy usage.

According to a comparison chart for LED Lights vs. Incandescent Light Bulbs vs. Compact Fluorescents (CFLs) from USAI lightening website 23-30 watts CFL has a light output of 1,600 and is therefore produces enough light as a 100 Watts Incandescent Light Bulb

Also according to energy.gov website, CFLs save up to 75% energy such that a 23-30 watt CFL can produce the same illumination as a 100 watt incandescent bulb

Therefore we have, a 23-30 watt CFL provides 1,600 lumens and is equivalent to a 100 Watts incandescent bulb.

Answer:

1600 lumens, 100 watt incandescent

Explanation:

100% on edge (:

Why is particle size the main parameter used in selecting a mechanical phase-separation device?

Answers

Answer:

This is because mechanical phase-separation device such as filtration, centrifugation etc operate according to the unique particle size feature in which they are designed to separates.

The process of centrifugation separates particles of size range between 0.1 μm to 5.0 μm efficiently.

The process of filtration however varies as there are different types of pore sizes which covers a wide range of particle sizes.

calculate the amount in moles of a gas which occupies 250cm3 at s.t.p​

Answers

Answer: 0.01 moles (I am guessing)

Explanation:

Firstly, cm3 and ml are equal to one another, therefore 250cm3 can also be written as 250 ml. I Googled and found that ideally, one mole of gas will occupy a volume of 22.4 L (22,400 ml) at s.t.p. 250 ml out of 22,400 ml is 0.01 rounded, therefore I assume that is the answer. About 0.01 mole occupies 250 cm3 at s.t.p.

A mixture of gasoline and air explodes when it encounters a spark. This is
known as
O A. a synthesis reaction
O O O
B. a precipitation reaction
C. fuel efficiency
o
D. a combustion reaction
SUBMI

Answers

Answer:

D. A combustion reaction

Explanation:

What is an empirical formula?​

Answers

Answer:

a formula giving the proportions of the elements present in a compound but not the actual numbers or arrangement of atoms.

Hope this helped!!!

Answer:

Empirical formulas show the simplest whole-number ratio of atoms in a compound

Explanation:

explain why ply(ethene) can become a pollutant? ​

Answers

Answer:

ipotseeeeeeeeeeeeeeee

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