Consider the bond dissociation energies listed below in kcal/mol. CH3-Br 70 CH3CH2-Br 68 (CH3)2CH-Br 68 (CH3)3C-Br 65 These data show that the carbon-bromine bond is weakest when bromine is bound to a __________.

Answers

Answer 1

Answer:

The answer is "Tertiary carbon".

Explanation:

Accent to the results, the carbon-bromine bond is weak, whenever, the bromine is connected to tertiary carbon so, bonding energy is separation for methyl-carbon, which is connected to the bromine = 70 kcal/mol and for the primary energy to the secondary energy is=  68 kcal/mol, and for tertiary CO2 = 65 kcal/mol.

The stronger the energy dissociating connection and the weaker, its power dissociation connection and its weaker bond becomes connecting with a tertiary carbon, that's why "Tertiary carbon" is the correct answer.


Related Questions

A student determines the value of the equilibrium constant to be 1.5297 x 107 for the following reaction: HBr(g) + 1/2 Cl2(g) --> HCl(g) +1/2 Br2(g) Based on this value of Keq, calculate the Gibbs free energy change for the reaction of 2.37 moles of HBr(g) at standard conditions at 298 K.

Answers

Answer:

[tex]\Delta G=-97.14kJ[/tex]

Explanation:

Hello,

In this case, the relationship between the equilibrium constant and the Gibbs free energy of reaction is:

[tex]\Delta G=-RTln(K)[/tex]

Hence, we compute it as required:

[tex]\Delta G=-8.314\frac{J}{mol\times K}*298K*ln(1.5297x10^7)\\\\\Delta G=-40.99kJ/mol[/tex]

And for 2.37 moles of hydrogen bromide, we obtain:

[tex]\Delta G=-40.99kJ/mol*2.37mol\\\\\Delta G=-97.14kJ[/tex]

Best regards.

Candle wax melts low temperature, it is not conductive to electricity, it is insoluble in water and partially soluble in solvents nonpolar, like gasoline. Than type of links are present in the candle wax?

A. Electrostatics.
B. Apolar.
C. lónicos.
D. Hydrogen bridges.

Answers

electrostatic and ionic are definitely not the answer because they have high melting point

hydrogen bonds are too weak and not permanent.

so the answer is apolar as it is soluble in polar solvents (water)

Answer:

B. Nonpolar

Explanation:

The low melting point tells you the compound is not ionic, metallic, or a network solid.

It is almost certainly a molecular solid.

It does not conduct electricity, so it is not metallic (which we have already ruled out).

It is insoluble in polar solvents (water) and soluble in nonpolar solvents (gasoline).

Since like dissolves like, the molecule is nonpolar.

The type of links must be nonpolar.

11mg of cyanide per kilogram of body weight is lethal for 50% of domestic chickens. How many grams per kilogram of body weight is a lethal dose for 50% of domestic chickens?

Answers

Answer:

[tex]0.033g[/tex]

Explanation:

Hello,

In this case, since 11 mg per kilogram of body weight has the given lethality, the mg that turn out lethal for a chicken weighting 3 kg is computed by using a rule of three:

[tex]11mg\longrightarrow 1kg\\\\x\ \ \ \ \ \ \longrightarrow 3kg[/tex]

Thus, we obtain:

[tex]x=\frac{3kg*11mg}{1kg}\\ \\x=33mg[/tex]

That in grams is:

[tex]=33mg*\frac{1g}{1000mg} \\\\=0.033g[/tex]

Regards.

Calculate the molar solubility of CaF2 at 25°C in a solution that is 0.010 M in Ca(NO3)2. The Ksp for CaF2 is 3.9 x 10-11.

Answers

Answer:

[tex]Molar \ solubility=3.12x10^{-5}M[/tex]

Explanation:

Hello,

In this case, for the dissociation of calcium fluoride:

[tex]CaF_2(s)\rightleftharpoons Ca^{2+}+2F^-[/tex]

The equilibrium expression is:

[tex]Ksp=[Ca^{2+}][F^-]^2[/tex]

In such a way, via the ICE procedure, including an initial concentration of calcium of 0.01 M (due to the calcium nitrate solution), the reaction extent [tex]x[/tex] is computed as follows:

[tex]3.9x10^{-11}=(0.01+x)(2*x)^2\\\\x=0.0000312M[/tex]

Thus, the molar solubility equals the reaction extent [tex]x[/tex], therefore:

[tex]Molar \ solubility=3.12x10^{-5}M[/tex]

Regards.

The molar solubility of Calcium fluoride has been calculated as [tex]3.12\;\times\;10^-^5\;\rm M[/tex].

The dissociation of calcium fluoride has been given by:

[tex]\rm CaF_2\;\rightarrow\;Ca^2^+\;+\;2\;F^-[/tex]

The solubility constant, ksp has been given as:

[tex]ksp=\rm[Mg^2^+]\;[F^-]^2[/tex]

From the dissociation of Calcium nitrate, the concentration of Ca ion in the solution has been 0.01 M.

The dissociation of Calcium fluoride x M has been resulted in x M Ca and 2x M F ions.

The concentration of Ca in the solution has been resulted as x + 0.01 M.

The solubility product can be given as:

[tex]3.9\;\times\;10^-^1^1=[x+0.01]\;[2x]^2\\3.9\;\times\;10^-^1^1=[x+0.01]\;4x^2\\x=3.12\;\times\;10^-^5[/tex]

The molar solubility of Calcium fluoride has been calculated as [tex]3.12\;\times\;10^-^5\;\rm M[/tex].

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i) Briefly discuss the strengths and weaknesses of the four spectroscopy techniques listed below. Include in your answer the specific structural information you get from each method.
 IR
 UV-VIS
 NMR
 Mass Spec

Answers

delete please .....................................

Which of the following happens to a molecule of an object when the object is heated? (1 point)

Answers

Answer:

They get more energy, so they vibrate!

Explanation:

Testbank Question 47 Consider the molecular orbital model of benzene. In the ground state how many molecular orbitals are filled with electrons?

Answers

Answer:

There are fifteen molecular orbitals in benzene filled with electrons.

Explanation:

Benzene is an aromatic compound. Let us consider the number of bonding molecular orbitals that should be present in the molecule;

There are 6 C-C σ bonds, these will occupy six bonding molecular orbitals filled with electrons.

There are 6 C-H σ bonds, these will occupy another six molecular orbitals filled with electrons

The are 3 C=C π bonds., these will occupy three bonding molecular pi orbitals.

All these bring the total number of bonding molecular orbitals filled with electrons to fifteen bonding molecular orbitals.

At standard temperature and pressure conditions, the volume of an ideal gas contained in a jar is 55.3 L. How many molecules are in the jar. This question is to be answered in scientific notation.(eg. 1.5 e5)

Answers

Answer:

1.49e24

Explanation:

Standars temperature and pressure are 273.15K and 1atm, respectively.

Using ideal gas law, we can find moles of an ideal gas if we know its pressure, temperature and volume as follows:

PV = nRT

PV / RT = n

Where P is pressure (1atm), V is volume (55.3L), R is gas constant (0.082atmL/molK), T is temperature (273.15K) and n moles of the ideal gas.

Replacing:

PV / RT = n

1atm*55.3L / 0.082atmL/molK*273.15K = n

2.47 moles = n

Now, the question is about the number of molecules in the jar. By definition, 1 mole = 6.022x10²³ molecules.

As we have 2.47 moles:

2.47 mol × (6.022x10²³ molecules / 1 mole) =

1.49x10²⁴ molecules that are in the jar

In scientific notation:

1.49e24

A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) <----> N2(g) 3H2(g) At equilibrium, it was found that the concentration of H2 was 0.0484 M, the concentration of N2 was 0.0161 M, and the concentration of NH3 was 0.295 M. What was the initial concentration of ammonia

Answers

Answer:

0.327 M

Explanation:

Step 1: Write the balanced equation

2 NH₃(g) ⇄ N₂(g) + 3H₂(g)

Step 2: Make an ICE chart

        2 NH₃(g) ⇄ N₂(g) + 3 H₂(g)

I              x             0            0

C          -2y            +y         +3y

E         x-2y             y           3y

Step 3: Find the value of y

The concentration of N₂ at equilibrium is 0.0161 M. Then,

y = 0.0161

Step 4: Find the value of x

The concentration of NH₃ at equilibrium is 0.295 M. Then,

x-2y = 0.295

x-2(0.0161) = 0.295

x = 0.327

The complex ion Fe(CN)63- is paramagnetic with one unpaired electron. The complex ion Fe(SCN)63- has five unpaired electrons. Where does SCN- lie in the spectrochemical series with respect to CN-?

Answers

Answer:

SCN- is a weak field ligand while CN- is a strong field ligand

Explanation:

The spectrochemical series is an arrangement of ligands according to their magnitude of crystal field splitting. Ligands that cause only a small degree of crystal field splitting are called weak field ligands while ligands that cause large crystal field splitting are called strong field ligands.

Strong field ligands often lead to the formation of low spin complexes with the least number of unpaired electrons while high spin complexes are formed by weak field ligands.

CN- is a strong field ligand as it lies towards the right hand side of the spectrochemical series.

SCN- is a weak field ligand hence it forms a high spin complex having the maximum number of unpaired electrons for Fe^3+, hence the answer.

SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

CN⁻ is a strong field ligand with a large splitting constant, and it is high up in the spectrochemical series.

Conversely, SCN⁻ is a weak field ligand with a low splitting constant, and it is lower in the spectrochemical series.

Hence, SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

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Why will the conjugate base of a weak acid affect pH? Select the correct answer below: it will react with hydroxide

Answers

Answer:

It will react with water

Explanation:

I know this is an older question, but I just wanted to provide the correct answer.

Since we are dealing with a weak base, and the acid is somewhat stronger, it will react with the water molecules to produce hydronium, which will affect the pH of the solution.

The conjugate base of a weak acid affect pH because it will react with hydronium ion.

A weak acid is an acid that does not dissociate completely in water. On the other hand, a strong acid achieves almost 100% dissociation in water.

Acids dissociate in water to yield the hydronium ion and a conjugate base. For instance, the weak acid, acetic acid is dissociated as follows;

CH3COOH(aq) + H2O(l) ⇄ CH3COO-(aq) + H3O+(aq)

We can see that the conjugate base( CH3COO-) could react with the hydronium ions thereby moving the equilibrium position to the left hand side and affecting the pH by decreasing the hydronium ion concentration.

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Missing parts;

Why will the conjugate base of a weak acid affect pH? Select the correct answer below: O it will react with hydroxide O it will react with water O it will react with hydronium O none of the above

I add a 50. g piece of Al (c = 0.88 J/g-deg) that is at 225°C to 100. mL of water at 20°C. What is the final temperature of the water in °C? The density of water is approximately 1g/mL.

Answers

Answer:

THE FINAL TEMPERATURE OF WATER IS -4.117 °C

Explanation:

Mass of the aluminium = 50 g

c = 0.88 J/g C

Initial temperature of aluminium = 225 °C

Volume of water = 100 ml

Density of water = 1 g/ml

Mass of water = density * volume of water

Mass of water = 1 * 100 = 100 g of water

Initial temperature of water = 20 C

It is worthy to note that the heat of a system is constant and conserved as no heat is lost or gained by a closed system,

So therefore,

heat lost by aluminium = heat gained by water

H = mass * specific heat capacity * temeprature change

So:

m c ( T2- T1) = m c (T2-T1)

50 * 0.88 * ( T2 - 225) = 100 * 4.18 *( T2 - 20)

44 ( T2 - 225 ) = 418 ( T2 - 20)

44 T2 - 9900 = 418 T2 - 8360

-9900 + 8360 = 418 T2 - 44 T2

-1540 = 374 T2

T2 = - 4.117

So therefore the final temperature of water is -4.117 °C

Which of the following types of electromagnetic radiation have higher frequencies than visible light and which have shorter frequencies than visible light? Sort them accordingly. ltems (6 items) (Drag and drop into the appropriate area below)
a. Gamma rays
b. Infrared radiation
c. Ultraviolet liht
d. X-rays
e. Microwaves
f. Radio waves

Answers

Answer:

Higher frequency than visible light -  Ultraviolet light, X-rays, and Gamma rays

Lower frequency than visible light - Infrared radiation, microwaves, and Radio waves

Explanation:

The frequencies of electromagnetic radiations vary according to their wavelengths. The relationship between the frequency and wavelength of the waves is expressed such that:

      λ = c/f, where λ = wavelength, c = speed of light, and f = frequency.

Thus, there is an inverse relationship between the wavelength and the frequency of electromagnetic waves.

The order of the electromagnetic waves based on their frequency from the lowest to the highest is radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma-rays

Hence, electromagnetic waves with higher frequencies than visible light include ultraviolet light, X-rays, and Gamma rays while those with lower frequencies include Infrared radiation, microwaves, and Radio waves.

Answer:

need points

Explanation:

We discussed the different types of intermolecular forces in this lesson, which can affect the boiling point of a substance.
1. Which of these has the highest boiling point?
A) Ar
B) Kr
C) Xe
D) Ne
2. Which substance has the highest boiling point?
A) CH4
B) He
C) HF
D) Cl2

Answers

Answer:

1, C, Xe 2, B,He

Explanation:

1, cause as u go down a group the boiling point increases.

2, boiling point of single element is greater than a compound

According to  periodic trends in periodic table boiling point increases down the  group and hence Xe has highest boiling point and more amount of heat is required to boil an element hence He has highest boiling point.

What is periodic table?

Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.

It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.

Elements present in the same group have same number of valence electrons and hence have similar properties while elements present in the same period show gradual variation in properties due to addition of one electron for each successive element in a period.

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If the heat of combustion for a specific compound is −1320.0 kJ/mol and its molar mass is 30.55 g/mol, how many grams of this compound must you burn to release 617.30 kJ of heat?

Answers

Answer:

14.297 g

Explanation:

From the question;

1 mo of the compound requires 1320.0 kJ

From the molar mass;

1 ml of the compound weighs 30.55g

How many grams requires 617.30kJ?

1 ml = 1320

x mol = 617.30

x = 617.30 / 1320

x = 0.468 mol

But 1 mol = 30.55

0.468 mol = x

x = 14.297 g

Identify a homogeneous catalyst. Identify a homogeneous catalyst. Pd in H2 gas N2 and H2 catalyzed by Fe SO2 over vanadium (V) oxide Pt with methane H2SO4 with concentrated HCl

Answers

Answer:

H2SO4 with concentrated HCl

What is advertising used for? Check all that apply. influencing consumer tastes tracking product popularity increasing product awareness promoting company branding gathering data about potential consumers

Answers

Answer:

influencing consumer tastes

increasing product awareness

promoting company branding

Explanation:

Advertising is basically a form of communication using creative ideas and communicating benefits of the products. Advertising plays a very crucial role in product business and some of the important uses of advertising are as follows:

Creative advertisements, influence customers or consumers to buy the product.Advertisings involve information regarding the product and so increases product awareness.Advertising on social media platforms, TVs, radio and newspapers, promotes company branding.

Hence, the correct options are:

influencing consumer tastesincreasing product awarenesspromoting company branding

Answer:

1,3,4

Explanation:

I took the test

Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 200.0 mL of 0.12 M NH3. The Kb for NH3 is 1.8 × 10-5.

Answers

Answer:

The pH of the solution is 9.06.

Explanation:

The reaction of the dissociation of NH₃ in water is:

NH₃(aq) + H₂O(l)  ⇄  NH₄⁺(aq) + OH⁻(aq)     (1)

[NH₃] - x                     [NH₄⁺] + x     x  

The concentration of NH₃ and NH₄⁺ is:

[tex] [NH_{3}] = \frac{n_{NH_{3}}}{V_{T}} = \frac{C_{i}_{(NH_{3})}*Vi_{NH_{3}}}{V_{NH_{3}} + V_{NH_{4}^{+}}} = \frac{0.12 M*0.2 L}{0.2 L + 0.25 L} = 0.053 M [/tex]

[tex] [NH_{4}^{+}] = \frac{C_{i}_{(NH_{4}^{+})*V_{NH_{4}^{+}}}}{V_{NH_{3}} + V_{NH_{4}^{+}}} = \frac{0.15 M*0.25 L}{0.2 L + 0.25 L} = 0.083 M [/tex]

From equation (1) we have:

[tex]Kb = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]}[/tex]

[tex] 1.8 \cdot 10^{-5} = \frac{(0.083 + x)*x}{0.053 - x} [/tex]

[tex] 1.8 \cdot 10^{-5}(0.053 - x) - (0.083 + x)*x = 0 [/tex]

By solving the above equation for x we have:

x =  1.15x10⁻⁵ = [OH⁻]

The pH of the solution is:

[tex] pOH = -log([OH^{-}]) = -log(1.15 \cdot 10^{-5}) = 4.94 [/tex]

[tex] pH = 14 - pOH = 14 - 4.94 = 9.06 [/tex]

Therefore, the pH of the solution is 9.06.

I hope it helps you!

The direction of the functional group is called?

Answers

Explanation:

they are called hydrocarbyls

pls mark me brainliest

Answer:

The first carbon atom that attaches to the functional group is referred to as the alpha carbon.

what is ammonium nitrate

Answers

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

Does the amount of methanol increase, decrease, or remain the same when an equilibrium mixture of reactants and products is subjected to the following changes?

a. the catalyst is removed
b. the temp is increased
c. the volume is decreased
d. helium is added
e. CO is added

Answers

Answer:

a. Methanol remains the same

b. Methanol decreases

c. Methanol increases

d. Methanol remains the same

e. Methanol increases

Explanation:

Methanol is produced by the reaction of carbon monoxide and hydrogen in the presence of a catalyst as follows; 2H2+CO→CH3OH.

a) The presence or absence of a catalyst makes no difference on the equilibrium position of the system hence the methanol remains constant.

b) The amount of methanol decreases because the equilibrium position shifts towards the left and more reactants are formed since the reaction is exothermic.

c) If the volume is decreased, there will be more methanol in the system because the equilibrium position will shift towards the right hand side.

d) Addition of helium gas has no effect on the equilibrium position since it does not participate in the reaction system.

e) if more CO is added the amount of methanol increases since the equilibrium position will shift towards the right hand side.

Beginning with Na, record the number of energy levels, number of protons, and atomic radius for each element in period 3.

Answers

Answer:

Sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon are the elements of third period.

Explanation:

There are three energy levels in sodium atom. It has 11 electrons revolving around the nucleus. the atomic radius of sodium atom is 227 ppm. Magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon has also three energy levels like sodium because all these elements belongs to third period. There are 12 electrons present in magnesium, 13 in aluminium, 14 in silicon, 15 in phosphorus, 16 in sulfur, 17 in chlorine, and 18 electrons in argon. The atomic radius of magnesium atom is 173 ppm.  The atomic radius of aluminium atom is 143 ppm.  The atomic radius of silicon atom is 111 ppm.  The atomic radius of phosphorus atom is 98 ppm.  The atomic radius of sulfur atom is 87 ppm. The atomic radius of chlorine atom is 79 ppm and the atomic radius of argon atom is 71 ppm.

Increasing which factor will cause the gravitational force between two objects to decrease?
weights of the objects
distance between the objects
acceleration of the objects
masses of the objects

Answers

Answer:

B

Explanation:

Increasing distance between the objects factor will cause the gravitational force between two objects to decrease. Therefore, option B is correct.

What causes gravitational force to decrease?

The gravitational force grows in proportion to the size of the masses . The gravitational force weakens rapidly as the distance between masses grows. Unless at least one of the objects has a lot of mass, detecting gravitational force is extremely difficult.

Gravity is affected by object size and distance between objects. Mass is a unit of measurement for the amount of matter in an object.

The force of gravity is proportional to the masses of the two objects and inversely proportional to the square of the distance between them. This means that the force of gravity increases with mass but decreases as the distance between objects increases.

Thus, option B is correct.

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2NH3 → N2 + 3H2 If 2.22 moles of ammonia (NH3) decomposes according to the reaction shown, how many moles of hydrogen (H2) are formed? A) 2.22 moles of H2 B) 1.11 moles of H2 C) 3.33 moles of H2 D) 6.66 moles of H2

Answers

Answer:

C

Explanation:

According to the mole ratio, using 2NH3 will give you 3H2. Which means in order to find the moles of H2 you would only need to divide 2 and multiply 3 to get the amount of moles of H2 produced.

Answer:

I think it's C

Explanation:

Please, tell me if I'm incorrect.

A soft drink contains 63 g of sugar in 378 g of H2O. What is the concentration of sugar in the soft drink in mass percent

Answers

Answer:

[tex]\% m/m= 14.3\%[/tex]

Explanation:

Hello,

In this case, the by mass percent is computed as shown below:

[tex]\% m/m=\frac{m_{solute}}{m_{solute}+m_{solvent}} *100\%[/tex]

Whereas the solute is the sugar and the solvent the water, therefore, the concentration results:

[tex]\% m/m=\frac{63g}{63g+378g} *100\%\\\\\% m/m= 14.3\%[/tex]

Best regards.

If 1 mol of a pure triglyceride is hydrolyzed to give 2 mol of RCOOH, 1 mol of R'COOH, and 1 mol of glycerol, which of the following compounds might be the triglyceride?
CHOC(O)R
A. CHOC(O)R
CHOC(O)R
CH,OC(O)R
B. CHOC(O)R
CH2OC(O)R
CHOC(O)R
C. CHOC(O)R
CHOC(O)R
CHOC(O)R
D. CHOC(O)R
CHOC(O)R

Answers

Answer:

The correct option is C.

Note the full question and structure of the moleculesis found in the attachment below.

Explanation:

Triglycerides or triacylglycerols are non-polar, hydrophobic lipid molecules composed of three fatty acids linked by ester bonds to a molecule of glycerol.

The fatty acids linked to the glycerol molecule are denoted by R and may be of the same kind or different. when the R group is the same, the R is attached in all the three positions for ester bonding in the glycerol molecule but when they are different are denoted by R, R' and R'' respectively.

During the hydrolysis of triglycerides, the three fatty acids molecules are obtained as well as a glycerol molecule.

From the question, when 1 mole of the triglyceride is hydrolysed, 2 moles of RCOOH, 1 mole of R'COOH and 1 mole of glycerol is obtained. The triglyceride must then be composed of two fatty acids which are the same denoted by R, and a different fatty acid molecule denoted by R'.

The correct option therefore, is C

What is the pOH of a solution at 25.0∘C with [H3O+]=4.8×10−6 M?

Answers

Answer:

8.68

Explanation:

pOH = 8.68

all you need is contained in the sheet

Answer:

Approximately [tex]8.68[/tex].

Explanation:

The [tex]\rm pOH[/tex] of a solution can be found from the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] with the following equation:

[tex]\displaystyle \rm pOH = -\log_{10} \rm \left[OH^{-}\right][/tex].

On the other hand, the ion-product constant of water, [tex]K_{\text{w}}[/tex], relates the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] of a solution to its hydronium ion concentration [tex]\rm \left[{H_3O}^{+}\right][/tex]:

[tex]K_\text{w} = \rm \left[{H_3O}^{+}\right] \cdot \rm \left[OH^{-}\right][/tex].

At [tex]25 \; ^\circ \rm C[/tex], [tex]K_{\text{w}} \approx 1.0 \times 10^{-14}[/tex]. For this particular [tex]25 \; ^\circ \rm C[/tex] solution, [tex]\rm \left[{H_3O}^{+}\right] = 4.8 \times 10^{-6}\; \rm mol \cdot L^{-1}[/tex].

Hence the [tex]\rm \left[OH^{-}\right][/tex] of this solution:

[tex]\begin{aligned}\left[\mathrm{OH}^{-}\right] &= \frac{K_\text{w}}{\rm \left[{H_3O}^{+}\right]} \\ &= \frac{1.0 \times 10^{-14}}{4.8 \times 10^{-6}}\; \rm mol\cdot L^{-1} \approx 2.08333 \times 10^{-9}\; \rm mol\cdot L^{-1}\end{aligned}[/tex].

Therefore, the [tex]\rm pOH[/tex] of this solution would be:

[tex]\begin{aligned}\rm pOH &= -\log_{10} \rm \left[OH^{-}\right] \\ &\approx -\log_{10} \left(4.8 \times 10^{-6}\right) \approx 8.68\end{aligned}[/tex].

Note that by convention, the number of decimal places in [tex]\rm pOH[/tex] should be the same as the number of significant figures in [tex]\rm \left[OH^{-}\right][/tex].

For example, because the [tex]\rm \left[{H_3O}^{+}\right][/tex] from the question has two significant figures, the [tex]\rm \left[OH^{-}\right][/tex] here also has two significant figures. As a result, the [tex]\rm pOH[/tex] in the result should have two decimal places.

Calculate the equilibrium constant K c for the following overall reaction: AgCl(s) + 2CN –(aq) Ag(CN) 2 –(aq) + Cl –(aq) For AgCl, K sp = 1.6 × 10 –10; for Ag(CN) 2 –, K f = 1.0 × 10 21.

Answers

Answer:

1.6x10¹¹ = Kc

Explanation:

For the reaction:

AgCl(s) + 2CN⁻(aq) ⇄ Ag(CN)₂⁻(aq) + Cl⁻(aq)

Kc is defined as:

Kc = [Ag(CN)₂⁻] [Cl⁻] / [CN⁻]²

Ksp of AgCl is:

AgCl(s) ⇄ Ag⁺(aq) + Cl⁻(aq)

Where Ksp is:

Ksp = [Ag⁺] [Cl⁻] = 1.6x10⁻¹⁰

In the same way, Kf of Ag(CN)₂⁻ is:

Ag⁺(aq) + 2CN⁻ ⇄ Ag(CN)₂⁻

Kf = [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = 1.0x10²¹

The multiplication of Kf with Ksp gives:

[Ag⁺] [Cl⁻] *  [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺] = Ksp*Kf

[Ag(CN)₂⁻] [Cl⁻] / [CN⁻]² = Ksp*Kf

Obtaining the same expression of the first reaction

That means Ksp*Kf = Kc

1.6x10⁻¹⁰*1.0x10²¹ = Kc

1.6x10¹¹ = Kc

Given that π = n M R T, rearrange the equation to solve for V

Answers

Answer:

V= n/M

Explanation:

From;

π = nRT/V = MRT

Where;

n= number of moles

R= gas constant

T= absolute temperature

M= molar mass

V= volume of the solution

π= osmotic pressure

Thus;

nRT/V = MRT

nRT = VMRT

V= nRT/MRT

V= n/M

Consider the following reaction at 298.15 K: Co(s)+Fe2+(aq,1.47 M)⟶Co2+(aq,0.33 M)+Fe(s) If the standard reduction potential for cobalt(II) is −0.28 V and the standard reduction potential for iron(II) is −0.447 V, what is the cell potential in volts for this cell? Report your answer with two significant figures.

Answers

Answer:

The correct answer is 0.186 V

Explanation:

The two hemirreactions are:

Reduction: Fe²⁺ + 2 e- → Fe(s)  

Oxidation : Co(s)  → Co²⁺ + 2 e-

Thus, we calculate the standard cell potential (Eº) from the difference between the reduction potentials of cobalt and iron, respectively,  as follows:

Eº = Eº(Fe²⁺/Fe(s)) - Eº(Co²⁺/Co(s)) = -0.28 V - (-0.447 V) = 0.167 V

Then, we use the Nernst equation to calculate the cell potential (E) at 298.15 K:

E= Eº - (0.0592 V/n) x log Q

Where:

n: number of electrons that are transferred in the reaction. In this case, n= 2.

Q: ratio between the concentrations of products over reactants, calculated as follows:

[tex]Q = \frac{ [Co^{2+} ]}{[Fe^{2+} ]} = \frac{0.33 M}{1.47 M} = 0.2244[/tex]

Finally, we introduce Eº= 0.167 V, n= 2, Q=0.2244, to obtain E:

E= 0.167 V - (0.0592 V/2) x log (0.2244) = 0.186 V

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