Answer:
The answer is "Option B"
Explanation:
From the query, the following knowledge is derived:
Yield in percentage = 47%
Performance of theory = 4860 g
Actual yield Rate =?
The percentage return is defined simply by the ratio between both the real return as well as the conceptual return multiplied by the 100. It's also represented as numerically:
[tex]Rate = \frac{Existing \ Rate} {Theoretical \ Rate} \times 100[/tex]
Now We can obtain the percent yield as followed using the above formula:
[tex]\text{Yield in percentage}= \frac{Actual \ yield \ Rate} {Theorical \ Rate} \times 100[/tex]
[tex]47\% = \frac{Actual \ yield \ Rate}{4860}[/tex]
The value of the Actual yield Rate =[tex]47\% \times 4860[/tex]
[tex]= \frac{47}{100} \times 4860 \\\\ = 2284.2 g[/tex]
The Actual yield Rate= 2284.2 g.
What is the equilibrium constant of aA+bB cC +dD?
Explanation:
{c}^C . {d}^D / {a}^A . {b}^B
The pH of a solution decreases by 2.0. How does the hydronium ion concentration of the solution change? Increases to 2 times the original concentration increases to 100 times the original concentration decreases to one one hundredth. Of the original concentration decreases to one half. Of the original concentration
Answer:
The hydronium ion concentration increases to 100 times the original concentration
Explanation:
The pH of a solution is defined as the negative logarithm of the hydrogen or hydronium ion concentration of that solution. It is given by the expression below:
pH = -log[H₃O⁺] = log[H₃O⁺]⁻¹
Assuming the solution was at neutral with original pH = 7;
The new pH of the solution will be = 7 - 2 = 5
At pH = 7;
log[H₃O⁺]⁻¹ = 7
[H₃O⁺]⁻¹ = 10⁷
[H₃O⁺] = 10⁻⁷
At pH = 5
log[H₃O⁺]⁻¹ = 5
[H₃O⁺]⁻¹ = 10⁵
[H₃O⁺] = 10⁻⁵
10⁻⁵ = 10⁻⁷ * 10²
But 10² = 100
Therefore, the hydronium ion concentration increases to 100 times the original concentration
Answer:
B
Explanation:
On Edge
How many gram of zinc will have to be treated with dilute hydrochloric acid to liberate 1.85 dm³ of hydrogen at 27°C and 750mmHg?
Answer:
Explanation:
given
volume=1.85 d m^3
T=27 degree C=27+273 k=300 k
P=750 mmHg
mass of zinc=?
we know that PV=nRT
n=m/M
PV=mRT/M
M for zinc=65.4
PVM=mRT
m=PVM/RT
m=750*1.85*65.4/0.0821*300
m=90742.5/24.63
m=3684
hope this will help u
What are half reaction
Answer:
When you don't have a complete reaction.
Explanation:
Happens a lot between a solvent and a solute. The solute may not bind well with the solvent I.e. water.
What is the independent variable of Smithers experience?
Please help controls and variables simpson? Smithers thinks that a special juice will increase the productivity of workers. He creates two groups of 50 workers each and assigns each group the same task (in this case, they're supposed to staple a set of papers). Group A is given the special juice to drink while they work. Group B is not given the special...
Answer:
Smithers thinks that a special juice will increase the productivity of workers. He creates two groups of 50 workers each and assigns each group the same task (in this case, they're ... Group A is given the special juice to drink while they work. Group ... 1. Control Group. Group B. 2. Independent Variable. volume of special juice.
Explanation:
Answer:
1. Group B
2. The juice
3. The number of stacks of paper
4. the juice did not help improve a quicker process
5. Group A can be given the juice, Group B can be given the juice without the special ingredient
USE QUIZLET FLASH CARDS IT CAN HELP YOU WITH A LOT OF QUESTION
if 193 ml of chlorine gas was collected at 21 celsius, what volume would it have if the temperature dropped to 0 celsius
Answer:
New volume of chlorine gas (V2) = 179 ml (Approx)
Explanation:
Given:
Volume of chlorine gas (V1) = 193 ml
Temperature of chlorine gas (T1) = 21°C = 21 + 273 = 294 k
New temperature of chlorine gas (T2) = 0°C = 0 + 273 = 273 k
Find:
New volume of chlorine gas (V2) = ?
Computation:
Using charle's law
V1 / T1 = V2 / T2
193 / 294 = V2 / 273
V2 = 179.21
New volume of chlorine gas (V2) = 179 ml (Approx)
How would removing invasive species from an
ecosystem help reduce the chances of a native
species becoming extinct?
A
The native species would go extinct
sooner.
B
The native species would no longer be
infected by diseases
C
The native species would be better adapt
for survival.
D
The native species would not have to
compete for necessary resources,
The correct answer is D. The native species would not have to compete for necessary resources
Explanation:
Invasive species, which include any living organism that is not native in an ecosystem, contribute to the extinction of native species as they compete for resources such as food, shelter, etc. with native species. For example, the Asian Carp, which was introduced to lakes in the U.S. consumes plankton, which reduces the amount of plankton available for native fish. In this context, by removing invasive species native species would not have to compete for resources and their chances to extinct will fall.
how many significant figures are in 820 400.0 L
Answer:
7 significant numbers
Compound A, C6H12O2, was found to be optically active, and it was slowly oxidized to an optically active carboxylic acid B, C6H12O3, by Ag(NH3)2. Oxidation of A by anhydrous CrO3 gave an optically inactive compound D that reacted with Zn amalgam/HCl to give 3-methylpentane. With aqueous H2CrO4, compound A was oxidized to an optically inactive dicarboxylic acid C, C6H10O4. Give structures for compounds A, B, and C; do not specify stereochemistry.
Answer:
kindly check the attach file for the drawing of the chemical structures.
Explanation:
So, we are going to start from the compound D, which is stated in the question to be optically active. Therefore, we will have that:
STEP ONE: THE OXIDATION OF COMPOUND A, C6H12O2 TO GIVE COMPOUND C.
The oxidation of compound A,C6H12O2 gives another chemical compound that is chemical compound C which is a optical inactive di-carboxylic acid. The chemical equation is given below:
C6H12O2 + H2Cr2O4 --------------------------------------------> HOOCCH2CHCH3CH2COOH.
STEP TWO: THE OXIDATION OF COMPOUND A, C6H12O2 TO GIVE COMPOUND B.
The oxidation of compound A,C6H12O2 gives another chemical compound that is chemical compound C which is a optically active acid. The chemical equation is given below:
C6H12O2 + Ag(NH3)2^+ -----------------------------> C6H12O3.
Since the question asked us to give the structures of Compound A,B and C there is no need to to show the chemical reaction for compound D.
Kindly check the picture below for the chemical structures.
Does Na2 gas posses metallic character? Explain your answer..
Explanation:
It contains Na2 molecules and the atoms in this molecule are held together by a purely covalent bond because the electronegativity of the two atoms is identical.Metallic bonding would not kick in until you make clusters of quite a few atoms. Such clusters would likely not be very stable because thermodynamically the larger the clump of material the more stable it gets. So they tend to coalesce until you have chunk of metal.Metallic bonding is in a sense a form of covalent bonding, but it is very collective (delocalized over a great many atoms) and electron deficient (there are more states than electrons to fill them up with, leading to conductive properties. This means that “a metallic bond” is a bit of an oxymoron like a forest with only one tree.Reply me in commentsYes, Na2 gas possesses a metallic character.
Does NA contain metallic bonds?In the stable state, metal sodium functions as an array of Na+ ions which can be surrounded by way of a sea of 3s electrons. However, it would be wrong to consider metal sodium as an ion when you consider that the ocean of electrons is shared by using all of the sodium cations, quenching the nice fee.
Sodium most effective has one valence electron. So, in metallic bonding, it is able to only donate one electron to be delocalized at some point of the structure. In steel bonding, the real bonding is the electrostatic force between the effective cations and the delocalized electrons.
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Which fact was most likely discovered between the time of Mendeleev’s table and the time of Moseley’s table that helped Moseley develop his version?
Answer:
The number of protons in an atom is different than the atom’s total mass.
Explanation:
Mendeleev knew only that, with some anomalies, the properties of elements varied periodically with their atomic masses.
Moseley's X-ray experiments enabled him to remove these anomalies and to show that the properties of elements varied with their atomic numbers.
Chadwick later discovered that the mass differences were caused by the presence of neutrons.
does the tendency to gain electrons decrease as we go down grp 17?
Explanation:
Hi, there!!!!
Let me simply clear you..
Yes,The tendency to gain electrons (in nonmetal) decreases when we go down group 17.
The reason for above answer is when we go downwards in periodic table then the atomic size increases with the addition of number of shells and force of attraction between the nucleus and valance shell decreases. The force of attraction between the nucleus and valance shell becomes weaker due to which the force of attracting the electrons gets decreased.
So, we can say that the tendency to gain electrons decreases as we go down in periodic table.
Hope it helps....
Chemistry is often called the __________ science because it involves the study of the materials in the universe and the changes these materials undergo
Answer:
Central
Explanation:
Chemistry is often called the central science because of connects the physical sciences, life sciences and applied sciences.
Chemistry is the study of matter and changes undergone by matter. This makes chemistry to occupy a central place in many scientific disciplines including medicine, engineering, pharmacy, geology etc. Basic knowledge of chemistry is usually required by experts in these disciplines.
A 46.9 gram sample of a substance has a volume of about 3.5 centimeters3. It is solid at a room temperature of 23ºC. Out of the four substances whose properties are given, which is the most likely identity of this substance?
THIS IS THE COMPLETE QUESTION BELOW
46.9 gram sample of a substance has a volume of about 3.5 centimeters3. It is solid at a room temperature of 23ºC. Out of the four substances whose properties are given, which is the most likely identity of this substance?
Substance Density (g/cm3) Melting Point (°C) Boiling Point (°C)
molybdenum 10.28 2,623 4,639
mercury 13.53 -39 357
hafnium 13.31 2,233 4,603
lead 11.34 327 1,749
A.
molybdenum
B.
mercury
C.
hafnium
D.
lead
Answer :
The correct option is OPTION C.
(C) Hafnium
Explanation;:
We were given the mass of substance as (m) = 46.9 g
The Volume of substance as (V) = 3.5 Cm^3
But we know Density of substance.= Mass/it's Volume
Then Density=46.9/3.5
=13.4g/Cm^3
From the questionthe given substance is solid at room temperature, and let us take Mercury as an example , Mercury is liquid at room temperature. ThenMercury cannot be the answer.
Base on the determined density which is 13.4 and the density of Hafnium also is 13.31 g/cm3 and it is solid at room temperature. Therefore, Hafnium is the only likely element here.
What does light travel in?
Answer:
Light travels as a wave.
Explanation:
But unlike sound waves or water waves, it does not need any matter or material to carry its energy along. This means that light can travel through a vacuum—a completely airless space. (Sound, on the other hand, must travel through a solid, a liquid, or a gas.)
Answer it answer it answer it
Answer:
[tex]\Large \boxed{\mathrm{A}}[/tex]
Explanation:
Rust formed from iron and oxygen combining is a chemical change, because in a chemical change, the resulting substance(s) will have different properties from the substance(s) before the chemical change.
I cant comment... So is it Right?
clearly distinguish between science and technology
Answer:
The words science and technology can and often are used interchangeably. But the goal of science is the pursuit of knowledge for its own sake while the goal of technology is to create products that solve problems and improve human life. Simply put, technology is the practical application of science.
Explanation:
Check the following images
Hope it helps!!!
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Easyyy plz
What Is the Reactivity Series? ...
Answer:
In chemistry the reactivity series is an empirical, calculated, and structurally analytical progression of a series of metals, arranged by their "reactivity" from highest to the lowest.
Answer:
In a reactivity series, the most reactive element is placed at the top and the least reactive element at the bottom. More reactive metals have a greater tendency to lose electrons and form positive ions.
A reactivity series of metals could include any elements. For example,
A list of elements from most reactive to least reactive: potassium, sodium, lithium, calcium, magnesium, aluminum, zinc, iron, copper, silver, and gold.
A good way to remember the order of a reactivity series of metals is to use the first letter of each one to make up a silly sentence. For example, People Say Little Children Make A Zebra Ill Constantly Sniffing Giraffes.
Observations of the way that these elements react with water, acids, and steam enable us to put them into this series.
The tables show how the elements react with water and dilute acids:
Element Reaction with water
Potassium Violently
Sodium Very quickly
Lithium Quickly
Calcium More slowly
Element Reaction with dilute acids
Calcium Very quickly
Magnesium Quickly
Zinc More slowly
Iron More slowly than zinc
Copper Very slowly
Silver Barely reacts
Gold Does not react
Note that aluminum can be difficult to place in the correct position in the reactivity series during these experiments. This is because its protective aluminum oxide layer makes it appear to be less reactive than it really is. When this layer is removed, the observations are more reliable.
Non-metals in the reactivity series
It is useful to place carbon and hydrogen into the reactivity series because these elements can be used to extract metals.
Here is the reactivity series including carbon and hydrogen:
A list of elements from most reactive to least reactive: potassium, sodium, lithium, calcium, magnesium, aluminum, carbon, zinc, iron, hydrogen, copper, silver, and gold.
Note that zinc and iron can be displaced from their oxides using carbon but not using hydrogen. However, copper can be extracted using carbon or hydrogen. Displacement reactions of metal oxides
A more reactive metal will displace a less reactive metal from a compound. The thermite reaction is a good example of this. It is used to produce white-hot molten (liquid) iron in remote locations for welding. A lot of heat is needed to start the reaction, but then it releases an incredible amount of heat, enough to melt the iron.
aluminium + iron(III) oxide → iron + aluminium oxide
2Al + Fe2O3 → 2Fe + Al2O3
Because aluminum is more reactive than iron, it displaces iron from iron(III) oxide. The aluminum removes oxygen from the iron(III) oxide:
iron is reduced
aluminum is oxidized
Reactions between metals and metal oxides allow us to put a selection of metals into a reactivity series. Using metals A, B, and C:
Metal A Metal B Metal C
A oxide X Displaces A Displaces A
B oxide No reaction X No reaction
C oxide No reaction Displaces C X
Metal A cannot displace either B or C - so it must be the least reactive and be at the bottom of this reactivity series.
Metal B displaces both A and C - so it must be the most reactive and be at the top of this reactivity series.
Metal C displaces A but cannot displace B - so it must be more reactive than A but less reactive than B, and be in between them in this reactivity series.
In general, the greater the difference in reactivity between two metals in a displacement reaction, the greater the amount of energy released.
Aluminum is much higher than iron in the reactivity series, so the thermite reaction releases a lot of energy. Magnesium is very high in the reactivity series, and copper is very low - so the reaction between magnesium and copper oxide is more violent.
Therefore, the order is:
A list of letters from most reactive to least reactive: B, C and A,
Displacement reactions of solutions
A more reactive metal will displace a less reactive metal from a solution of one of its salts. For example:
magnesium + copper(II) sulfate → copper + magnesium sulfate
Mg(s) + CuSO4(aq) → Cu(s) + MgSO4(aq)
In this reaction, the blue color of the copper(II) sulfate fades as it is used up (magnesium sulfate solution is colorless). We would also see copper metal forming.
Reactions between metals and solutions of metal salts allow us to put a selection of metals into a reactivity series. Using metals J, K, and L:
Metal J Metal K Metal L
J sulfate X No reaction No reaction
K sulfate Displaces K X Displaces K
L sulfate Displaces L No reaction X
Metal J displaces both K and L - so it must be the most reactive and be at the top of this reactivity series.
Metal K cannot displace either J or L - so it must be the least reactive and be at the bottom of this reactivity series.
Metal L displaces K but cannot displace J - so it must be more reactive than K but less reactive than J, and be in between them in this reactivity series.
- sorry I'm late and it's is long -_-||
If each geometric shape represents a different type of atom, and atoms that are touching have chemically bonded with each other, which best describes this model? * 1. An element 2. A compound 3. A homogeneous mixture of two compounds 4. A heterogeneous mixture of two compounds 5. A homogeneous mixture of four elements 6. A heterogeneous mixture of four elements
Answer:
The correct option is;
3. A homogeneous mixture of two compounds
Explanation:
An homogeneous mixture is one where the components of the mixture are evenly dispersed such that the individual components cannot be seen to be isolated and distinguishable and having a constant composition of the constituents
The image displays three atoms (red circle, cyan triangle, and orange rectangle). The red circle appear to be bonded in pairs while the cyan triangles are bonded to the orange rectangles making a total of two compounds
The arrangement of the compounds in the mixture appear to be very evenly distributed to suggest an homogeneous mixture
The visibility of the compounds should be for an illustrative purpose.
100 cm^3 of oxygen diffuses through a Porous in 3second how long will it take 150 cm^3 of sulphur (iv) oxide diffuse through the same pot? ( oxygen= 16 sulphur = 32)
Answer:
3.18 seconds
Explanation:
Given the following :
Volume of oxygen (V1) = 100cm^3
Time taken (t1) = 3 seconds
Volume of Sulphur (iv) oxide (v2) = 150cm^3
From Graham's Law of diffusion:
(r1/r2) = √(m1/m2)
Where r = rate of diffusion
m = molar mass
Note rate (r) = (volume / time)
[(V1/t1) ÷ (v2/t2)] = √(m1/m2)
(v1/t1) * (t2/v2) = √(m1/m2)
m1 = 02 = (16 * 2) = 32
m2 = SO2 = (32 + (16 * 2)) = 64
(100/3) * (t2/150) = √(32/64)
100t2 / 450 = √(32/64)
100t2 / 450 = √32 / 8
100t2 / 450 = √32 / 8
100t2 * 8 = 450 * √32
800t2 = 2545.5844
t2 = 2545.5844 / 800
t2 = 3.1819805
t2 = 3.18 seconds
It will take 3.18s for 150cm^3 of Sulphur (iv) oxide to diffuse through the same pot.
If two solutions with concentrations of 0.4 M sugar and 0.7 M sugar respectively are separated by a semipermeable membrane, during osmosis there is a net flow of Group of answer choices sugar molecules from the dilute to the concentrated solution sugar molecules from the concentrated to the dilute solution water molecules from the concentrated to the dilute solution water molecules from the dilute to the concentrated solution
Answer: Water molecules from the dilute to the concentrated solution
Explanation:
During Osmosis if a solution is separerated by a semipermeable membrane, the solvent (typically water) from the less concentrated solution in terms of solute goes through the semipermeable membrane to the solution with the higher concentration so that the concentrations between the solutions can be balanced.
With the above solutions therefore, water molecules would move from the solution of 0.4M of sugar to the solution with a 0.7M of sugar through the semipermeable membrane.
During osmosis, water molecules move from the dilute to the concentrated solution.
OSMOSIS:
Osmosis is the movement of water molecules from a region of higher concentration (low concentration of solute) to a region of lower concentration (higher concentration of solute). The principle of movement is based on the concentration gradient i.e. difference in concentration across a semipermeable membrane. According to this question, two solutions have sugar concentrations of 0.4 M sugar and 0.7 M respectively and are separated by a semipermeable membrane. Therefore, water molecules will move from the dilute (0.4M) to the concentrated (0.7M) solution during osmosis.Learn more at: https://brainly.com/question/13655668?referrer=searchResults
Drag each tile to the correct image. Match each hydrocarbon class to its structure. carboxylic acid amine halocarbon alcohol
Answer:
1. Amine.
2. Alcohol.
3. Carboxylic Acid.
4. Halocarbon.
Explanation:
The correct answer according to the tile are Amine, Alcohol, Carboxylic acid, Halocarbon.
How can hydrocarbons be classified based on their structure?
Hydrocarbons can be classified as either aromatic or aliphatic compounds, depending on the presence of a benzene ring.
What is the most common classification of hydrocarbons?
Alkanes are hydrocarbons in which all of the bonds are single bonds. Alkenes are hydrocarbons that contain a carbon-carbon double bond.
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formula for soda glass
Answer:
composition of soda-lime glass is 73% SiO2 – 15% Na2O − 7% CaO − 4% MgO − 1% Al2O3 [129,132,133].
The Soda glass formula is SiO2, Na2O, CaO, Al2O3, K2O, SO3, MgO, Fe2O3, TiO2
Soda glass is a chemical compound that stands out for being the most widely used material to make windows, bottles, glasses, among others.
This compound is characterized by being chemically stable, reasonably hard, and extremely versatile because it can be recycled since it can be melted to make new products.
Its chemical formula is made up of other compounds such as:
SiO2, is Silicon OxideNa2O, is sodium oxideCaO, is calcium oxideAl2O3, is aluminum oxideK2O, is potassium oxideSO3, is sulfur oxideMgO, is magnesium oxideFe2O3, is iron oxideTiO2, is Titanium OxideAdditionally, the compounds found in the highest proportion in glass are SiO2 (74 atoms) and Na2O (13 atoms).
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3. How did ethanol use affect the shortage of corn available to consumers during and
after the drought of 2012? Do you think that commodities in one sector should be used
in another economic sector? How might the concept of needs and wants affect your
analysis of this issue?
Due to drought, the production of corn decreases and shortage of it occurs.
Effects of droughtYes, commodities in one sector should be used in another sector because scientist invented methods in which one commodity is used in several sectors for the production of new products.
Corn was used for the production of ethanol which causes the shortage of corn that was available to consumers during and after the drought condition of 2012 so we can conclude that due to drought, the production of corn decreases and shortage of it occurs.
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What does empirical fomula means with examples
Find the density of a cube on Earth that weighs 1.5 kg and has a side-length of 10 cm.
Answer:
1.5g/cm³
Explanation:
density=mass÷volume
mass= 1.5kg (change into g) = 1500g
volume of the cube = 10×10×10 = 1000cm³
density= divide 1500g÷1000cm = 1.5g/cm³
Density= 1.5g/cm³YOUR WELCOME!
The density of the cube on Earth that weighs 1.5 kg and has a side length of 10 cm is 1.5g/cm³
What is density?"Density is the mass per unit volume. Density is a scalar quantity. It is denoted by d and the symbol for density is given as rho, a Greek symbol. Density is calculated as mass divided by volume."
density = mass / volume
The mass of the cube on earth is 1.5 kg
The side length of the cube is 10 cm.
The mass is given in kg. It is converted into grams.
mass= 1.5kg (change into g) = 1500g
A cube is a three-dimensional square, it has 6 faces, so its volume will be calculated completely.
Volume of the cube = 10×10×10 = 1000cm³
Putting the values in the formula of density
density= divide 1500g /1000cm = 1.5g/cm³
Thus, the density of the cube on Earth is 1.5g/cm³.
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45. The following data was collected for 3 compounds:
Mass of Nitrogen that combines with 1 g of Oxygen
Compound A 1.750 g
Compound B 0.8750 g
Compound C 0.4375 g
Show whether these are the same or different compounds. What chemical law is being observed here?
Answer:
The three compounds are different compounds
Explanation:
The mass of Nitrogen that combines with 1 gram of Oxygen in Compound A = 1.750 g
The mass of Nitrogen that combines with 1 gram of Oxygen in Compound B = 0.8750 g
The mass of Nitrogen that combines with 1 gram of Oxygen in Compound C = 0.4375 g
According to the law of multiple proportions, when atoms of two different elements react to form compounds, the masses of one of the elements that combines with a fixed mass of the other element are in small whole number ratios.
The ratio of the masses are;
Mass of Nitrogen in Compound B/(Mass of Nitrogen in Compound C = 0.8750/0.4375 = 2
Mass of Nitrogen in Compound A/(Mass of Nitrogen in Compound C = 1.750/0.4375= 4
Mass of Nitrogen in Compound A/(Mass of Nitrogen in Compound B = 1.750/0.8750= 2
Given that the masses of Nitrogen in the three compounds are in small whole number ratios, the three compounds, Compound A, Compound B, and Compound C are different compounds.
When might Accurate length measurement be important?
Answer:
When you are going to measure small lengths or objects or when you are going to measure things with great accuracy.
Explanation:
A compound that has a sea of delocalized electrons has what type of bonding?
Answer:
Metallic Bonding
Explanation:
Metallic Bonding
In metallic bonds, the valence electrons from the s and p orbitals of the interacting metal atoms delocalize. That is to say, instead of orbiting their respective metal atoms, they form a “sea” of electrons that surrounds the positively charged atomic nuclei of the interacting metal ions.
An atom of nitrogen has seven electrons. Which diagram correctly represents the arrangement of these electrons?
ОА.
OB
1112
1s 11:28 1111
2p
1s 12
2p
1s 12
12s 2p
OD. 1111s 112s
112p
Ос.
Answer:
Option C.
Explanation:
The arrangement of electrons in their orbital follows certain rules.
The Hund's rule practically explained how electrons are distributed in their orbitals.
The Hund's rule states that electrons distributed among the orbitals of the same shell singly (without partner) before pairing occurs.
In the filling of these electrons in their orbitals, we fill in the electron without pairing first because electrons tends to repel each other before filling with the opposite spin as shown in the attached photo.
