A chemist requires a large amount of 1-bromo-4-phenyl-2-butene as starting material for a synthesis and decides to carry out the following NBS allylic bromination reaction in the presence of UV light. Draw the structures of all of the observed products.
NBS
(C6H5)CH2CH = CHCH3 → ?
CCI4
Draw one additional resonance structure for the species below:
CH3CH=CHCH=CHCH=CHCH2

Answer:

The mole is defined as a collection of 6.022 × 1023 particles.

The atomic mass given on a periodic table that is given in grams is the mass of

one mole (6.022 × 1023 particles) of that element

Explanation:

Answer: The millimoles of potassium iodide the chemist has added to the flask is 522 millimoles.

Explanation:

Given: Volume of KI = 370.0 mL (1 mL = 0.001 L) = 0.37 L

Molarity of KI solution = 1.41 mol/L

Now, moles of KI (potassium iodide) is calculated as follows.

[tex]Moles = Volume \times Molarity \\= 0.37 L \times 1.41 M\\= 0.5217 mol[/tex]

Convert moles into millimoles as follows.

1 mol = 1000 millimoles

0.5217 mol = [tex]0.5217 mol \times \frac{1000 millimoles}{1 mol} = 521.7 millimoles[/tex]

This can be rounded off to the value 522 millimoles.

Thus, we can conclude that the millimoles of potassium iodide the chemist has added to the flask is 522 millimoles.

Answer: The mass of sample that remained is 0.127 mg

Explanation:

The integrated rate law equation for first-order kinetics:

[tex]k=\frac{2.303}{t}\log \frac{a}{a-x}[/tex] ......(1)

Given values:

a = initial concentration of reactant = 0.500 mg

a - x = concentration of reactant left after time 't' = ?mg

t = time period = 28 s

k = rate constant = [tex]0.049s^{-1}[/tex]

Putting values in equation 1:

[tex]0.049s^{-1}=\frac{2.303}{28s}\log (\frac{0.500}{(a-x)})\\\\\log (\frac{0.500}{(a-x)})=\frac{0.049\times 28}{2.303}\\\\\frac{0.500}{a-x}=10^{0.5957}\\\\frac{0.500}{a-x}=3.94\\\\a-x=\frac{0.500}{3.942}=0.127mg[/tex]

Hence, the mass of sample that remained is 0.127 mg

Answer:

Mg will be the limiting reagent.

Explanation:

The balanced reaction is:

Mg + 2 HCl → MgCl₂ + H₂

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

Being the molar mass of each compound:

By reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

0.0350 g of Mg is reacted with 10.00 mL (equal to 0.01 L) of 6 M HCl.

Molarity being the number of moles of solute that are dissolved in a certain volume, expressed as:

[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]

in units [tex]\frac{moles}{liter}[/tex]

then, the number of moles of HCl that react is:

[tex]6 M=\frac{number of moles of HCl}{0.01 L}[/tex]

number of moles of HCl= 6 M*0.01 L

number of moles of HCl= 0.06 moles

Then you can apply the following rule of three: if by stoichiometry 2 moles of HCl react with 24.3 grams of Mg, 0.06 moles of HCl react with how much mass of Mg?

[tex]mass of Mg=\frac{0.06 moles of HCl* 24.3 grams of Mg}{2 moles of HCl}[/tex]

mass of Mg= 0.729 grams

But 0.729 grams of Mg are not available, 0.0350 grams are available. Since you have less mass than you need to react with 0.06 moles of HCl, Mg will be the limiting reagent.

The limiting reactant in the reaction is Magnesium (Mg)

From the question,

We are to determine the limiting reactant in the reaction.

The given balanced chemical equation for the reaction is

Mg(s) + 2HCl(aq) → MgCl₂(aq) + H₂(g)

This means

1 mole of Mg is required to react completely with 2 moles of HCl

Now, we will determine the number of moles of each reactant present

Mass = 0.0350 g

Using the formula

[tex]Number\ of\ moles = \frac{Mass}{Atomic\ mass}[/tex]

Atomic mass of Mg = 24.305 g/mol

∴ Number of moles of Mg present = [tex]\frac{0.0350}{24.305}[/tex]

Number of moles of Mg present = 0.00144 mole

Concentration = 6M

Volume = 10.00 mL = 0.01 L

Using the formula

Number of moles = Concentration × Volume

∴ Number of moles HCl present = 6 × 0.01

Number of moles HCl present = 0.06 mole

Since,

1 mole of Mg is required to react completely with 2 moles of HCl

Then

0.00144 mole of Mg is required to react completely with 2×0.00144 mole of HCl

2×0.00144 = 0.00288

∴ The number of moles of HCl required to react completely with the Mg is 0.00288 mole

Since the number of moles of HCl present is more than 0.00288 mole, then HCl is the excess reactant and Mg is the limiting reactant.

Hence, the limiting reactant in the reaction is Magnesium (Mg)

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Answer:

d

Explanation:

cuaase that it sirhal

The chemical formula PbCl₂(s) represented by:

A) a substance

The chemical formula PbCl₂(s) represents a substance. A substance is a single, pure chemical entity with a definite composition. It can be an element, a compound, or an alloy.

A solution is a homogeneous mixture of two or more substances. A homogeneous mixture is a mixture in which the components are evenly distributed throughout the mixture.

A heterogeneous mixture is a mixture in which the components are not evenly distributed throughout the mixture.

A reaction is a process in which one or more substances are transformed into one or more new substances.

Therefore, the chemical formula PbCl₂(s) represents a substance, and the answer is (A).

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Answer:

hi I used your code you got it

Answer:

Explanation:

[H+] = 0.1x0.03x2 + 0.2x0.03 = 0.012 mol

[OH-] = 0.001x0.05x2 = 0.0001 mol

=> [H+] dư = 0.012 - 0.0001 =0.0119 mol

pH = -log[H+] = 1.92

Answer: A volume of 20.49 milliliters of sodium formate do you need to measure to make this buffer (assuming the rest is formic acid).

Explanation:

Given: Total volume of the buffer = 21.0 mL

[tex]\frac{[HCOONa]}{[HCOOH]} = 4[/tex] ... (1)

It is assumed that the volume of HCOONa is x. Hence, volume of HCOOH is (21.0 - x) mL.

Hence,

[HCOONa] = Molarity [tex]\times[/tex] Volume

= 0.10 [tex]\times[/tex] x

= 0.1x mmol

Similarly, [HCOOH] = Molarity [tex]\times[/tex] Volume

= 0.10 [tex]\times[/tex] (21.0 - x) mmol

Using equation (1),

[tex]\frac{[HCOONa]}{[HCOOH]} = 4\\\frac{0.1x}{(21.0 - x)} = 4\\0.1x = 84.0 - 4x\\4.1x = 84.0\\x = 20.49 mL[/tex]

As x is the volume of sodium formate. Hence, 20.49 mL of sodium formate is required to make the buffer.

Thus, we can conclude that a volume of 20.49 milliliters of sodium formate do you need to measure to make this buffer (assuming the rest is formic acid).

Answer:

i think C  is the answer

Explanation:

The change in average annual temperatures on earth will be due to "photosynthesis by plants and algae".

Photosynthesis can be defined as a process in which plants, as well as other organisms, as well as other organisms, utilize to transform sunlight into chemical energy which can then be released to power the organism's activities using cellular respiration.

Plants seem to be mostly photosynthetic eukaryotes belonging to the plantae kingdom.

Therefore, photosynthesis cannot change in average annual temperature on Earth.

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Answer:

C) isoleucine

Explanation:

Isoleucine is among nine necessary amino acids in humans (found in dietary proteins). It has a variety of physiological activities, including aiding tissue repair, nitrogenous waste detoxification, immunological stimulation, and hormonal production promotion. When attached at a binding site, they are capable of providing a side chain thereby increasing the hydrophobicity at the binding site.

Answer: Pair 1 has Mg and Sr, Pair 2 has Kr and Ne, Pair 3 has As and P.

Explanation:

A periodic table is a group of elements presented in a tabular form where elements are arranged in a series of 7 rows and 18 columns.

The vertical columns are known as groups and horizontal rows are known as periods.

The elements having similar chemical properties are arranged in one group.

Magnesium (Mg) is the 12th element of periodic table placed at Group 2 and Period 3

Strontium (Sr) is the 38th element of periodic table placed at Group 2 and Period 5

Krypton (Kr) is the 36th element of periodic table placed at Group 18 and Period 4

Neon (Ne) is the 10th element of periodic table placed at Group 18 and Period 2

Arsenic (As) is the 33rd element of periodic table placed at Group 15 and Period 4

Phosphorus (P) is the 15th element of periodic table placed at Group 15 and Period 3

As magnesium and strontium are present in the same group, they will have similar chemical properties. Similarly, krypton and neon will form the second pair. Likewise, arsenic and phosphorus will form a pair.

Hence, Pair 1 has Mg and Sr, Pair 2 has Kr and Ne, Pair 3 has As and P.

The question is incomplete, the complete question is:

A certain liquid X has a normal freezing point of [tex]0.80^oC[/tex] and a freezing point depression constant [tex]K_f=7.82^oC.kg/mol[/tex] . Calculate the freezing point of a solution made of 81.1 g of iron(III) chloride () dissolved in 850. g of X. Round your answer to significant digits.

Answer: The freezing point of the solution is [tex]-17.6^oC[/tex]

Explanation:

Depression in the freezing point is defined as the difference between the freezing point of the pure solvent and the freezing point of the solution.

The expression for the calculation of depression in freezing point is:

[tex]\text{Freezing point of pure solvent}-\text{freezing point of solution}=i\times K_f\times m[/tex]

OR

[tex]\text{Freezing point of pure solvent}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times w_{solvent}\text{(in g)}}[/tex] ......(1)

where,

Freezing point of pure solvent = [tex]0.80^oC[/tex]

Freezing point of solution = [tex]?^oC[/tex]

i = Vant Hoff factor = 4 (for iron (III) chloride as 4 ions are produced in the reaction)

[tex]K_f[/tex] = freezing point depression constant = [tex]7.82^oC/m[/tex]

[tex]m_{solute}[/tex] = Given mass of solute (iron (III) chloride) = 81.1 g

[tex]M_{solute}[/tex] = Molar mass of solute (iron (III) chloride) = 162.2 g/mol

[tex]w_{solvent}[/tex] = Mass of solvent (X) = 850. g

Putting values in equation 1, we get:

[tex]0.8-(\text{Freezing point of solution})=4\times 7.82\times \frac{81.1\times 1000}{162.2\times 850}\\\\\text{Freezing point of solution}=[0.8-18.4]^oC\\\\\text{Freezing point of solution}=-17.6^oC[/tex]

Hence, the freezing point of the solution is [tex]-17.6^oC[/tex]

Answer:

Gains

Explanation:

It gets more electrons

Answer:

[tex]4.67\times 10^{-4}[/tex]

Explanation:

Given that,

The pH of a certain orange juice is 3.33.

We need to find the +ion concentration.

We know that,

[tex]pH=-log[H^+][/tex]

So,

[tex]3.33=-log[H^+]\\\\\[H^+=10^{-3.33}\\\\=4.67\times 10^{-4}[/tex]

So, the +ion concentraion is equal to [tex]4.67\times 10^{-4}[/tex].

Answer:

For the neutralization reaction between pyridine and propanoic acid, draw curved arrows to indicate the direction of electron flow.

Draw curved arrows to show the movement of electrons in this step of the mechanism.

Explanation:

According to Bronsted acid-base theory, an acid is a substance which is a proton donor.

Base is the proton acceptor.

In the given example, acid is propanoic acid and it loses the proton.

Pyridine is the base and it accepts the proton from propanoic acid.

The entire reaction is shown below:

Answer:

bleh

Explanation:

Answer:

The most stable conformation of the following compound has

A. An axial methyl group and an axial ethyl group.

B. An axial methyl group and an equatorial ethyl group.

C. An axial tert-butyl group.

D. An equatorial methyl group and an equatorial ethyl group.

E. An equatorial methyl group and an axial ethyl group.

Explanation:

The most stable conformation in the cyclohexane ring is the one in which both the substituents are in the equatorial position.

Among the given options,

option D  An equatorial methyl group and an equatorial ethyl group.

When the substituents in the cyclohexane ring are in equatorial positions then, the steric repulsions will be reduced.

Answer is option D.

Answer:

The volume of the sample is 17.4L

Explanation:

The reaction that occurs requires the same amount of CO and NO. As the moles added of both reactants are the same you don't have any limiting reactant. The only thing we need is the reaction where 4 moles of gases (2mol CO + 2mol NO) produce 3 moles of gases (2mol CO2 + 1mol N2). The moles produced are:

0.1800mol + 0.1800mol reactants =

0.3600mol reactant * (3mol products / 4mol reactants) = 0.2700 moles products.

Using Avogadro's law (States the moles of a gas are directly proportional to its pressure under constant temperature and pressure) we can find the volume of the products:

V1n2 = V2n1

Where V is volume and n moles of 1, initial state and 2, final state of the gas

Replacing:

V1 = 23.2L

n2 = 0.2700 moles

V2 = ??

n1 = 0.3600 moles

23.2L*0.2700mol = V2*0.3600moles

17.4L = V2

Answer:

MgO

Explanation:

Answer:

33.8 g Solution

Explanation:

A chemistry student needs 15.0 g of methanol for an experiment. The concentration of ethanol in the solution is 44.4% w/w, that is, there are 44.4 g of methanol every 100 g of solution. The mass of solution that would contain 15.0 g of methanol is:

15.0 g Methanol × 100 g Solution/44.4 g Methanol = 33.8 g Solution

Since 33.8 g are required and 320. g are available, there is enough solution for the requirements.

Answer:

LIBs have had a huge impact on our society. They enabled modern portable electronics such as laptops and mobile phones. And they are now enabling clean and low-carbon transport, be it via electric cars or even flying taxis, and grid-scale storage of renewable energy

Explanation:

Answer: The ion that contribute to water hardness are:

--> a. Ca2+

--> b. (HCO)3^- and

--> c. Mg2+

While K+ DOES NOT contribute to water hardness.

Explanation:

WATER in chemistry is known as a universal solvent. This is so because it is polar in nature and dissolves most inorganic solutes and some polar organic solutes to form aqueous solutions. It is composed of elements such as hydrogen and oxygen in the combined ratio of 2:1.

Water is said to be HARD if it does not lather readily with soap. There are two types of water hardness:

--> Permanent hardness: This is mainly due to the presence of CALCIUM and MAGNESIUM ions in the form of soluble tetraoxosulphate(VI) and chlorides. These ions are removed by adding washing soda or caustic soda.

--> Temporary hardness: This is due to the presence of calcium HYDROGENTRIOXOCARBONATES. It can be removed by boiling and using slaked lime.

Therefore from the above given ions, Ca2+,(HCO)3^- and Mg2+ contributes to water hardness.

Answer: The molarity of NaCl solution is 0.0489 M

Explanation:

Molarity is defined as the amount of solute expressed in the number of moles present per liter of solution. The units of molarity are mol/L. The formula used to calculate molarity:

[tex]\text{Molarity of solution}=\frac{\text{Given mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (mL)}}[/tex] .....(1)

We are given:

Given mass of NaCl = 0.8 g

Molar mass of NaCl = 58.44 g/mol

Volume of the solution = 280 mL

Putting values in equation 1, we get:

[tex]\text{Molarity of solution}=\frac{0.8\times 1000}{58.44\times 280}\\\\\text{Molarity of solution}=0.0489M[/tex]

Hence, the molarity of NaCl solution is 0.0489 M

Answer:

THE ANSWER IS: copper(I) sulfide.

hope this helped <3

Explanation:

Answer:

5 atoms form one formula unit of Fe2O3

Explanation:

2 atoms of Fe (Iron)

and 3 atoms of O ( Oxygen)

so total = 3 + 2

= 5

Answer:

fe203 the right answer is thus

Answer:

aasjajiakjka

Explanation:

Answer:

Aldehydes and Ketones

Both aldehydes and ketones contain a carbonyl group, a functional group with a carbon-oxygen double bond. The names for aldehyde and ketone compounds are derived using similar nomenclature rules as for alkanes and alcohols, and include the class-identifying suffixes -al and -one, respectively:



In an aldehyde, the carbonyl group is bonded to at least one hydrogen atom. In a ketone, the carbonyl group is bonded to two carbon atoms:





As text, an aldehyde group is represented as –CHO; a ketone is represented as –C(O)– or –CO–.

In both aldehydes and ketones, the geometry around the carbon atom in the carbonyl group is trigonal planar; the carbon atom exhibits sp2 hybridization. Two of the sp2 orbitals on the carbon atom in the carbonyl group are used to form σ bonds to the other carbon or hydrogen atoms in a molecule. The remaining sp2 hybrid orbital forms a σ bond to the oxygen atom. The unhybridized p orbital on the carbon atom in the carbonyl group overlaps a p orbital on the oxygen atom to form the π bond in the double bond.

Like the C=OC=O bond in carbon dioxide, the C=OC=O bond of a carbonyl group is polar (recall that oxygen is significantly more electronegative than carbon, and the shared electrons are pulled toward the oxygen atom and away from the carbon atom). Many of the reactions of aldehydes and ketones start with the reaction between a Lewis base and the carbon atom at the positive end of the polar C=OC=O bond to yield an unstable intermediate that subsequently undergoes one or more structural rearrangements to form the final product (Figure 1).

Figure 1. The carbonyl group is polar, and the geometry of the bonds around the central carbon is trigonal planar.

The importance of molecular structure in the reactivity of organic compounds is illustrated by the reactions that produce aldehydes and ketones. We can prepare a carbonyl group by oxidation of an alcohol—for organic molecules, oxidation of a carbon atom is said to occur when a carbon-hydrogen bond is replaced by a carbon-oxygen bond. The reverse reaction—replacing a carbon-oxygen bond by a carbon-hydrogen bond—is a reduction of that carbon atom. Recall that oxygen is generally assigned a –2 oxidation number unless it is elemental or attached to a fluorine. Hydrogen is generally assigned an oxidation number of +1 unless it is attached to a metal. Since carbon does not have a specific rule, its oxidation number is determined algebraically by factoring the atoms it is attached to and the overall charge of the molecule or ion. In general, a carbon atom attached to an oxygen atom will have a more positive oxidation number and a carbon atom attached to a hydrogen atom will have a more negative oxidation number. This should fit nicely with your understanding of the polarity of C–O and C–H bonds. The other reagents and possible products of these reactions are beyond the scope of this chapter, so we will focus only on the changes to the carbon atoms: