Answer:
Explanation:
We shall apply Arrhenius equation which is given below .
[tex]ln\frac{k_2}{k_1} = \frac{E_a}{R} [\frac{1}{T_1} -\frac{1}{T_2} ][/tex]
K₂ and K₁ are rate constant at temperature T₂ and T₁ , Ea is activation energy .
Putting the given values
[tex]ln\frac{5.9}{1} = \frac{39500}{8.3} [\frac{1}{298} -\frac{1}{T_2} ][/tex]
[tex].000373= [\frac{1}{298} -\frac{1}{T_2} ][/tex]
T₂ = 335.27 K
= 62.27 °C
The higher temperature is 62.27°C.
Calculating the higher temperature:Given that the activation energy of the reaction is:
Eₐ = 39.5 kJ/mol
initial temperature T₁ = 25°C = 298K
Let the final temperature be T₂
The rate constant at temperature T₁ be K₁, and at a temperature T₂ be K₂.
According to the question: K₂/K₁ = 5.9
Now, applying the Arrhenius equation we get:
[tex]\ln\frac{K_2}{K1}=\frac{E_a}{R}[\frac{1}{T_1} -\frac{1}{T_2}]\\\\\ln(5.9)= \frac{39.5}{8.3}[\frac{1}{298} -\frac{1}{T_2}]\\\\0.000373=\frac{1}{298} -\frac{1}{T_2}[/tex]
T₂ = 335.27K
T₂ = 335.27 -273
T₂ = 62.27°C
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Acetonitrile (CH3CN) is an important industrial chemical. Among other things, it is used to make plastic moldings, which have multiple uses, from car parts to Lego bricks. Which one of the following statements about acetonitrile is not correct?a. Acetonitrile has 16 valence electrons in its Lewis structure. b. Acetonitrile has one triple bond. c. Acetonitrile has one pair of nonbonding electrons. d. All atoms satisfy the octet rule in acetonitrile. e. One carbon atom and the nitrogen atom have nonzero formal charges.
Answer:
One carbon atom and the nitrogen atom have nonzero formal charges.
Explanation:
The compound Acetonitrile has sixteen valence electrons as is easily San from its structure. It contains a carbon nitrogen triple bond with a lone pair of electrons on nitrogen. All atoms satisfy the octet rule and there is no hyper valent atom in the molecule.
The formal charge an carbon and nitrogen is calculated as follows;
No. of valence electron on atom - [non bonded electrons + no. of bonds]
Therefore, for carbon and nitrogen, we have;
formal charge on carbon = 4 - (0 + 4) = 0
formal charge on nitrogen = 5 - (2 + 3) = 0
Hence carbon and nitrogen both possess zero formal charges.
The argon atoms are excited into an excited state before emitting the 488.0 nm laser. It is known that the energy of the first ionization energy of argon is 1520 kJ mol-1. What is the energy level of the excited state (in unit eV) lies below the vacuum energy level (0 eV)
Answer:
Explanation:
Given that:
The argon atoms are excited into an excited state before emitting the 488.0 nm laser.
the energy of the first ionization energy of argon is 1520 kJ mol-1.
SInce 1 eV = 96.49 kJ/mol
Therefore, the energy of the first ionization energy of argon in eV is = ( 1520/ 96.49) eV
= 15.75 eV
To find where the energy level of the excited state lies below the vacuum energy level, let's first determine, the energy liberated by using planck expression.
[tex]E = \dfrac{hc}{\lambda}[/tex]
[tex]E = \dfrac{6.6 \times 10^{-34} \times 3 \times 10^8}{488 \times 10^{-9}}[/tex]
[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]
[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]
[tex]E =4.057 \times 10^{-19} \ J[/tex]
Converting Joules (J) to eV ; we get,
[tex]E =\dfrac{4.057 \times 10^{-19}}{1.6 \times 10^{-19}}[/tex]
E = 2.53 eV
The energy levels of the first exited state = -13.223 eV
The literature value for the Ksp of Ca(OH)2 at 25 °C is 4.68E−6. Imagine you ran the experiment and got a calculated value for Ksp which was too high. Select all of the possible circumstances which would cause this result.
A. The HCl was more concentrated than the labeled molarity (0.0500 M).
B. The Ca[OH]2 solution may have been supersaturated.
C. The HCl was less concentrated than the labeled molarity (0.0500 M).
D. The Ca[OH]2 solution may have been unsaturated.
E. The titration flask may have not been clean and had a residue of a basic solution.
F. The titration flask may have not been clean and had a residue of an acidic solution.
Answer:
D. The Ca[OH]2 solution may have been unsaturated
Explanation:
The solubility product constant Ksp of any given chemical compound is a term used to describe the equilibrium between a solid and the ions it contains solution. The value of the Ksp indicates the extent to which any compound can dissociate into ions in water. A higher the Ksp, implies more greater solubility of the compound in water.
If the Ksp is more than the value in literature, this false value must have arisen from the fact that the solution was unsaturated hence it appears to be more soluble than it should normally be when saturated.
If 2.9g of water is heated from 23.9C to 98.9C, how much heat (in calories) was added to the water?
Answer:
Explanation:
we know that
ΔH=m C ΔT
where ΔH is the change in enthalpy (j)
m is the mass of the given substance which is water in this case
ΔT IS the change in temperature and c is the specific heat constant
we know that given mass=2.9 g
ΔT=T2-T1 =98.9 °C-23.9°C=75°C
specific heat constant for water is 4.18 j/g°C
therefore ΔH=2.9 g*4.18 j/g°C*75°C
ΔH=909.15 j
Please Help! Use Hess’s Law to determine the ΔHrxn for: Ca (s) + ½ O2 (g) → CaO (s) Given: Ca (s) + 2 H+ (aq) → Ca2+ (aq) + H2 (g) ΔH = 1925.9 kJ/mol 2 H2 (g) + O2 (g) → 2 H2O (l) ΔH = −571.68 kJ/mole CaO (s) + 2 H+ (aq) → Ca2+ (aq) + H2O (l) ΔH = 2275.2 kJ/mole ΔHrxn =
Answer:
ΔHrxn = -635.14kJ/mol
Explanation:
We can make algebraic operations of reactions until obtain the desire reaction and, ΔH of the reaction must be operated in the same way to obtain the ΔH of the desire reaction (Hess's law). Using the reactions:
(1)Ca(s) + 2 H+(aq) → Ca2+(aq) + H2(g) ΔH = 1925.9 kJ/mol
(2) 2H2(g) + O2 g) → 2 H2O(l) ΔH = −571.68 kJ/mole
(3) CaO(s) + 2 H+(aq) → Ca2+(aq) + H2O(l) ΔH = 2275.2 kJ/mole
Reaction (1) - (3) produce:
Ca(s) + H2O(l) → H2(g) + CaO(s)
ΔH = 1925.9kJ/mol - 2275.2kJ/mol = -349.3kJ/mol
Now this reaction + 1/2(2):
Ca(s) + ½ O2(g) → CaO(s)
ΔH = -349.3kJ/mol + 1/2 (-571.68kJ/mol)
ΔHrxn = -635.14kJ/molA monoprotic weak acid, HA , dissociates in water according to the reaction HA(aq)+H2O(l)↽−−⇀H3O+(aq)+A−(aq) The equilibrium concentrations of the reactants and products are [HA]=0.260 M , [H3O+]=4.00×10−4 M , and [A−]=4.00×10−4 M . Calculate the Ka value for the acid HA.
Answer:
Ka = 6.15x10⁻⁷
Explanation:
Ka is defined as dissociation constant in the equilibrium of a weak acid with water. The general reaction is:
HA(aq) + H₂O(l) ⇆ H₃O⁺(aq) + A⁻(aq)
And Ka is defined as the ratio between molar concentrations in equilibrium of products over reactants as follows:
Ka = [H₃O⁺] [A⁻] / [HA]
You don't take water in the equilibrium beacuse is a pure liquid
Replacing with the concentrations of the problem:
Ka = [H₃O⁺] [A⁻] / [HA]
Ka = [4.00x10⁻⁴] [4.00x10⁻⁴] / [0.260]
Ka = 6.15x10⁻⁷
A balloon has an initial volume of 2.954 L containing 5.50 moles of helium. More helium is added so that the balloon expands to 4.325 L. How much helium (moles) has been added if the temperature and pressure stay constant during this process.
Answer:
8.05 moles
Explanation:
5.50 / 2.954 = x / 4.325
x = 8.05
According to ideal gas equation, if the temperature and pressure stay constant during the process 0.520 moles have been added so that the balloon expands to 4.325 L.
What is ideal gas equation?The ideal gas equation is a equation which is applicable in a hypothetical state of an ideal gas.It is a combination of Boyle's law, Charle's law,Avogadro's law and Gay-Lussac's law . It is given as, PV=nRT where R= gas constant whose value is 8.314.The law has several limitations.The law was proposed by Benoit Paul Emile Clapeyron in 1834.
In the given example if pressure and temperature are constant then V=nR substituting V=4.325 l and R=8.314 so n=V/R=4.325/8.314=0.520 moles.
Thus, 0.520 moles of helium are added if the temperature and pressure stay constant during this process.
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A sailor on a trans-Pacific solo voyage notices one day that if he puts 735.mL of fresh water into a plastic cup weighing 25.0g, the cup floats in the seawater around his boat with the fresh water inside the cup at exactly the same level as the seawater outside the cup (see sketch at right).
Calculate the amount of salt dissolved in each liter of seawater. Be sure your answer has a unit symbol, if needed, and round it to 2 significant digits.
You'll need to know that the density of fresh water at the temperature of the sea around the sailor is 0.999/gcm3. You'll also want to remember Archimedes' Principle, that objects float when they displace a mass of water equal to their own mass.
Answer:
Amount of salt in 1 L seawater = 34 g
Explanation:
According to Archimedes' principle, mass of freshwater and cup = mass of equal volume of seawater
mass of freshwater = density * volume
1 cm³ = 1 mL
mass of freshwater = 0.999 g/cm³ * 735 cm³ = 734.265 g
mass of freshwater + cup = 734.265 + 25 = 759.265 g
Therefore, mass of equal volume of seawater = 759.265 g
Volume of seawater displaced = 735 mL = 0.735 L (assuming the cup volume is negligible)
1 liter = 1000 cm³ = 1000 mL;
Density of seawater = mass / volume
Density of seawater = 759.265 g / 0.735 L = 1033.01 g/L
Density of freshwater in g/L = 0.999 g/ (1/1000) L = 999 g/L
mass of 1 Liter seawater = 1033.01 g
mass of 1 Liter freshwater = 999 g
mass of salt dissolved in 1 L of seawater = 1033.01 g - 999 g = 34.01 g
Therefore, amount of salt in 1 L seawater = 34 g
Write the equation for the reaction described: A solid metal oxide, , and hydrogen are the products of the reaction between metal and steam. (Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
Answer:
Pb + 2H2O --> PbO2 + 2H2
Explanation:
Products:
Solid metal; PbO2
Hydrogen; H
Reactants:
Metal; Pb
Steam; H2O
Reactants --> Products
Pb + H2O --> PbO2 + H2
Upon balancing we have;
Pb + 2H2O --> PbO2 + 2H2
1. Explain what the police siren sounds like to Jane:
2. Explain what the police siren sounds like to John:
3. Explain why the police siren sounds different between Jane and John:
Answer:
1. the siren has a lower pitch to Jane
2. the siren has a higher pitch to John
3. sound different due to moving away from Jane making the sound wave lengths longer and moving toward John making the wave lengths shorter
Explanation:
The Doppler effect expresses that sound is comparative with the spectator or observer. This is demonstrated valid by the model given with Jane and John. To one individual it could sound low and to someone else it could sound high, in light of where they are tuning in from. To John, the police alarm playing is a higher pitch. Be that as it may, to Jane this equivalent alarm is a totally extraordinary pitch and is heard lower than in comparison to the john.
This is a prime case of the Doppler Effect. They sound distinctive on the grounds that the sound is moving far from Jane making the sound frequencies longer and it is advancing toward John making the frequencies shorter. This impacts how the sound is heard by the human ear.
Using the data: C2H4(g), = +51.9 kJ mol-1, S° = 219.8 J mol-1 K-1 CO2(g), = ‑394 kJ mol-1, S° = 213.6 J mol-1 K-1 H2O(l), = ‑286.0 kJ mol-1, S° = 69.96 J mol-1 K-1 O2(g), = 0.00 kJ mol-1, S° = 205 J mol-1 K-1 calculate the maximum amount of work that can be obtained, at 25.0 °C, from the process: C2H4(g) + 3 O2(g) → 2 CO2(g) + 2 H2O(l)
Answer:
The correct answer is 1332 KJ.
Explanation:
Based on the given information,
ΔH°f of C2H4 is 51.9 KJ/mol, ΔH°O2 is 0.0 KJ/mol, ΔH°f of CO2 is -394 KJ/mol, and ΔH°f of H2O is -286 KJ/mol.
Now the balanced equation is:
C2H4 (g) + 3O2 (g) ⇔ 2CO2 (g) + 2H2O (l)
ΔH°rxn = 2 × ΔH°f CO2 + 2 × ΔH°fH2O - 1 × ΔH°fC2H4 - 3×ΔH°fO2
ΔH°rxn = 2 (-394) + 2(-286) - 1(51.9) - 3(0)
ΔH°rxn = -1411.9 KJ
Now, the given ΔS°f of C2H4 is 219.8 J/mol.K, ΔS°f of O2 is 205 J/mol.K, ΔS°f of CO2 is 213.6 J/mol.K, and ΔS°f of H2O is 69.96 J/mol.K.
Now based on the balanced chemical reaction,
ΔS°rxn = 2 × ΔS°fCO2 + 2 ΔS°fH2O - 1 × ΔS°f C2H4 - 3 ΔS°fO2
ΔS°rxn = 2 (213.6) + 2(69.96) - 1(219.8) -3(205)
ΔS°rxn = -267.68 J/K or -0.26768 KJ/K
T = 25 °C or 298 K
Now putting the values of ΔH, ΔS and T in the equation ΔG = ΔH-TΔS, we get
ΔG = -1411.9 - 298.0 × (-0.2677)
ΔG = -1332 KJ.
Thus, the maximum work, which can obtained is 1332 kJ.
Atomic mass is calculated by _____. subtracting protons from neutrons averaging the mass of isotopes adding protons and neutrons subtracting neutrons from protons
Answer:
Atomic mass is calculated by adding protons and neutrons.
Explanation:
Atomic mass is the sum of protons and neutrons in an atomic nucleus. For example, the element Oxygen has 8 protons (derived from the atomic number) and 8 neutrons (derived from subtracting the amount of protons from the atomic mass).
We can craft an equation to show the relationship between these variables.
M - N = P, where M = Mass, N = Neutrons, and P = Protons
This equation can be rearranged to show the relationship between the neutrons and protons leading to the atomic mass. Simply add N to both sides of the equation.
M = N + P
This shows that atomic mass is equivalent to the sum of protons and neutrons in an atom's nucleus.
Define the following terms - you may need to consult your lecture text or other suitable resource:
a. monomer,
b. repeating unit,
c. condensation polymerization,
d. cross-linked polymer
Answer:
a) Monomers: monomers are unit molecules, that can react together with other monomers, to form a long chain molecule called a polymer. Th polymer formed can also be in a three dimensional network. The process of this conversion of monomers to polymers is called polymerization.
b) Repeating unit: A repeating unit is a unit of the polymer formed, whose repetition would produce a long complete polymer chain. A polymer is made up of these repeating links of molecules that form a long chain of molecules.
c) Condensation polymerization: This is a form of condensation reaction, that involves the combination of molecules into polymers with the loss of small molecules such as water or methanol as by products.
d) Cross-linked polymer: This is a polymer formed from a type of bonding of molecules. The bonding is usually in the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural polymers. The cross-links leads to an alteration in the physical properties of the polymer.
The definition of following terms are :
a) Monomers:
The monomers are unit atoms, that can respond in conjunction with other monomers, to create a long chain molecule called a polymer.
The polymer shaped can too be in a three dimensional arrange.
b) Repeating unit:
A rehashing unit may be a unit of the polymer shaped, whose reiteration would produce a long total polymer chain.
A polymer is made up of these rehashing joins of atoms that shape a long chain of molecules.
c) Condensation polymerization:
This is often a frame of condensation response, that includes the combination of particles into polymers with the misfortune of little particles such as water or methanol as by products.
d) Cross-linked polymer:
This can be a polymer shaped from a sort of holding of particles.
The cross-links leads to an modification within the physical properties.
DefinitionsDefinition is a rhetorical style that uses various techniques to impress upon the reader the meaning of a term, idea, or concept.
Definition may be used for an entire essay but is often used as a rhetorical style within an essay that may mix rhetorical styles.
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There are 2.4g of calcium hydroxide reacted with nitric acid. Calculate the number of moles of calcium hydroxide used. Write your answer using proper significant digits and units. Show all your work.
Answer:
0.032 moles
Explanation:
no of moles =
[tex] \frac{mass \: in \: grams}{relative \: molecular \: mass} [/tex]
=
[tex] \frac{2.4}{40 + 32 + 2} [/tex]
= 0.032
Calcium hydroxide reacted with nitric acid the total number of moles will be 0.032 moles.
What is a mole?
A mole is Avogadro's number of particles, which is exactly 6.02214076×1023.
The mole is widely used in chemistry as a convenient way to express amounts of reactants and products of chemical reactions. For example, the chemical equation 2H2 + O2 → 2H2O can be interpreted to mean that for each 2 mol dihydrogen (H2) and 1 mol dioxygen (O2) that react 2 mol of water (H2O) form.
Number of moles = Mass of substance / Mass of one mole Number of moles
mass of substance = 2.4g
molar mass of calcium hydroxide is (1 ×40.078g/mol Ca) +(2 × 15.999g/mol O) + (2 × 1.008g/mol H) = 74.092 g/mol Ca (OH)2
substituting the value,
number of moles = 2.4 / 74.029
= 0.032 moles
Therefore, moles of calcium hydroxide will be 0.032 moles
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Cesium-137 is part of the nuclear waste produced by uranium-235 fission. The half-life of cesium-137 is 30.2 years. How much time is required for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value?
Answer:
There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value
Explanation:
The radioactive decay follows always first-order kinetics where its general law is:
Ln[A] = -Kt + ln[A]₀
Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.
We can find rate constant from half-life as follows:
Rate constant:
t(1/2) = ln 2 / K
As half-life of Cesium-137 is 30.2 years:
30.2 years = ln 2 / K
K = 0.02295 years⁻¹
Replacing this result and with the given data of the problem:
Ln[A] = -Kt + ln[A]₀
Ln[A] = -0.02295 years⁻¹* t + ln[A]₀
Ln ([A] / [A₀]) = -0.02295 years⁻¹* t
As you want time when [A] is 20% of [A]₀, [A] / [A]₀ = 0.2:
Ln (0.2) = -0.02295 years⁻¹* t
70.1 years = t
There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original valueA. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
Br(g)
Cl2(g)
I2(g)
F2(g)
B. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2S(g)
H2O(g)
H2O2(g)
C. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous)
C(s, diamond)
C(s, graphite)
Answer:
A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy
I2(g)>Br2(g)>Cl2(g)>F2(g)
B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2O2(g)>H2S(g) >H2O(g)
C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous) >C(s, graphite)>C(s, diamond)
Explanation:
Hello,
In this case, we can apply the following principles to explain the order:
- The greater the molar mass, the larger the standard molar entropy.
- The greater the molar mass and the structural complexity, the larger the standard molar entropy.
- The greater the structural complexity, the larger the standard molar entropy.
A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy
I2(g)>Br2(g)>Cl2(g)>F2(g)
This is due to the fact that the greater the molar mass, the larger the standard molar entropy.
B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2O2(g)>H2S(g) >H2O(g)
This is due to the fact that the greater the molar mass and the structural complexity, the larger the standard molar entropy as the hydrogen peroxide has four bonds and weights 34 g/mol as well as hydrogen sulfide that has two bonds only.
C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous) >C(s, graphite)>C(s, diamond)
Since the molecular complexity is greater in the amorphous carbon (messy arrangement), mid in the graphite and lower in the diamond (well organized).
Regards.
Calculate the energy required to heat 566.0mg of graphite from 5.2°C to 23.2°C. Assume the specific heat capacity of graphite under these conditions is ·0.710J·g−1K−1 . Be sure your answer has the correct number of significant digits.
Answer:
7.23 J
Explanation:
Step 1: Given data
Mass of graphite (m): 566.0 mgInitial temperature: 5.2 °CFinal temperature: 23.2 °CSpecific heat capacity of graphite (c): 0.710J·g⁻¹K⁻¹Step 2: Calculate the energy required (Q)
We will use the following expression.
Q = c × m × ΔT
Q = 0.710J·g⁻¹K⁻¹ × 0.5660 g × (23.2°C-5.2°C)
Q = 7.23 J
Sulfur dioxide reacts with oxygen to form sulfur trioxide. What change in hybridization of the sulfur occurs in this reaction ? g
Answer:
PLEASE LOOK INN TO THE FILE YOU WILL GET ANSWER AND ALSO SUMMARY THANKS FOR ASKING QUESTION.
Explanation:
How are animals used in vaccine development?
Answer:
Animals whose certain organs closely match those of humans or have similar genetic makeup are used in vaccine tests because the results can closely resemble those same results on humans.
Explanation:
Answer:
they use them to test the effectiveness of the vaccine.
Explanation:
What would be the voltage (Ecell) of a voltaic cell comprised of Cd(s)/Cd2+(aq) and Zr(s)/Zr4+(aq) if the concentrations of the ions in solution were [Cd2+] = 0.5 M and [Zr4+] = 0.5 M at 298K?
Answer:
1.05 V
Explanation:
Since;
E°cell= E°cathode- E°anode
E°cathode= -0.40 V
E°anode= -1.45 V
E°cell= -0.40-(-1.45) = 1.05 V
Equation of the process;
2Zr(s) + 4Cd^2+(aq) ---->2Zr^4+(aq) + 4Cd(s)
n= 8 electrons transferred
From Nernst's equation;
Ecell = E°cell - 0.0592/n log Q
Ecell= E°cell - 0.0592/8 log [0.5]/[0.5]
Since log 1=0
Ecell= E°cell= 1.05 V
Compound A is an alkene that was treated with ozone to yield only (CH3CH2CH2)2C=O. Draw the major product that is expected when compound A is treated with a peroxy acid (RCO3H) followed by aqueous acid (H3O+).
Answer:
2,2,3,3-tetrapropyloxirane
Explanation:
In this case, we have to know first the alkene that will react with the peroxyacid. So:
What do we know about the unknown alkene?
We know the product of the ozonolysis reaction (see figure 1). This reaction is an oxidative rupture reaction. Therefore, the double bond will be broken and we have to replace the carbons on each side of the double bond by oxygens. If [tex](CH_3CH_2CH_2)_2C=O[/tex] is the only product we will have a symmetric molecule in this case 4,5-dipropyloct-4-ene.
What is the product with the peroxyacid?
This compound in the presence of alkenes will produce peroxides. Therefore we have to put a peroxide group in the carbons where the double bond was placed. So, we will have as product 2,2,3,3-tetrapropyloxirane. (see figure 2)
Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na 2CrO 4 are added to 250 mL of 0.12 M AgNO 3? [K sp(Ag 2CrO 4) = 1.1 × 10 –12] What is the concentration of the silver ion remaining in solution?
Answer:
A precipitate will form.
[Ag⁺] = 2.8x10⁻⁵M
Explanation:
When Ag⁺ and CrO₄²⁻ are in solution, Ag₂CrO₄(s) is produced thus:
Ag₂CrO₄(s) ⇄ 2 Ag⁺(aq) + CrO₄²⁻(aq)
Ksp is defined as:
Ksp = 1.1x10⁻¹² = [Ag⁺]² [CrO₄²⁻]
Where the concentrations [] are in equilibrium
Reaction quotient, Q, is defined as:
Q = [Ag⁺]² [CrO₄²⁻]
Where the concentrations [] are the actual concentrations
If Q < Ksp, no precipitate will form, if Q >= Ksp, a precipitate will form,
The actual concentrations are -Where 500mL is the total volume of the solution-:
[Ag⁺] = [AgNO₃] = 0.12M ₓ (250mL / 500mL) = 0.06M
[CrO₄²⁻] = [Na₂CrO₄] = 0.33M × (250mL / 500mL) = 0.165M
And Q = [0.06M]² [0.165M] = 5.94x10⁻⁴
As Q > Ksp; a precipitate will form
In equilibrium, some Ag⁺ and some CrO₄⁻ reacts decreasing its concentration until the system reaches equilibrium. Equilibrium concentrations will be:
[Ag⁺] = 0.06M - 2X
[CrO₄²⁻] = 0.165M - X
Where X is defined as the reaction coordinate
Replacing in Ksp expression:
1.1x10⁻¹² = [0.06M - 2X]² [0.165M - X]
Solving for X:
X = 0.165M → False solution. Produce negative concentrations.
X = 0.0299986M
Replacing, equilibrium concentrations are:
[Ag⁺] = 0.06M - 2(0.0299986M)
[CrO₄²⁻] = 0.165M - 0.0299986M
[Ag⁺] = 2.8x10⁻⁵M[CrO₄²⁻] = 0.135M
What are some geographic features that could be found in the hydrosphere?
Lakes, oceans, glaciers, clouds, etc. It categorizes all forms of water on earth.
hydro = water
Answer:
Lakes, streams, ground water, polar ice caps, glaciers, water vapor, and rivers!
Explanation:
The hydrosphere is made up of all the water on Earth. So anything that is water, like oceans, can be found in the hydrosphere:)
A 25.00 mL sample of unknown concentration of HNO3 solution requires 22.62 mL of 0.02000 M NaOH to reach the equivalence point. What is the concentration of the unknown HNO3 solution
Answer:The concentration of the unknown HNO3 solution = 0.01809 M
Explanation:
For the acid-base reaction, HNO3 + NaOH-----> NaN03 + H20
we have that
C1 V1 = C2 V2
Where ,
C1 = concentration of HNO3=?
V1 = volume of HNO3 = 25.00 mL,
V2 = volume of NaOH = 22.62 mL,
C2 = concentration of NaOH = 0.02000 M
Therefore ,
25.00 mL x C1 = 22.62 mL x 0.02000 M
= (22.62 mL / 25.00 mL) x 0.02000 M = 0.01809 M
The concentration of the unknown HNO3 solution = 0.01809 M
Human blood typically contains 1.04 kg/L of platelets. A 1.89 pints of blood would contain what mass (in grams) of platelets
A 1.89 pints of blood would contain 873 grams of platelets.
To calculate the amount of platelets present in 1.89 pints, it is first necessary to transform this unit of volume into liters:
1 pint = 473.2 mL[tex]1.89 \times 473.2 = 894.3 mL[/tex]
1000 L = 1mL
[tex]\frac{894.3}{1000}= 0.84L[/tex]
Now, just calculate the amount of platelets present in 0.84L:
[tex]\frac{1.04\times10^{3}g}{xg}=\frac{1L}{0.84L}[/tex]
x = 873 grams
So, a 1.89 pints of blood would contain 873 grams of platelets.
Learn more about transformation of units in: brainly.com/question/10667910
When equation for neutralization of HBr by Ca(OH)2 is correctly balanced, how many molecules of water will be formed
Answer:
When equation for neutralization of HBr by Ca(OH)₂ is correctly balanced, 1.2046*10²⁴ molecules of water will be formed
Explanation:
A neutralization reaction is one in which an acid (or acidic oxide) reacts with a base (or basic oxide). In the reaction a salt is formed and in most cases water is formed. A Salt is an ionic compound formed by the union of ions and cations through ionic bonds.
In the reactions of a strong acid (those substances that completely dissociate) with a strong base (they dissociate completely, giving up all their OH-), the complete neutralization of the species is carried out:
2 HBr (aq) + Ca(OH)₂ (s) → CaBr₂ (aq) + 2 H₂O (l)
The reaction is already balanced, complying with the law of conservation of matter. This law states that since no atom can be created or destroyed in a chemical reaction, the number of atoms that are present in the reactants must be equal to the number of atoms present in the products.
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), 2 moles of water H₂O are formed.
On the other hand, Avogadro's Number or Avogadro's Constant is called the number of particles that make up a substance (usually atoms or molecules) and that can be found in the amount of one mole of said substance. Its value is 6.023 * 10²³ particles per mole. Avogadro's number applies to any substance.
Then you can apply the following rule of three: if 1 mole of H₂O contains 6.023*10²³ molecules, 2 moles of H₂O, how many molecules does it contain?
[tex]amount of molecules=\frac{2moles*6.023*10^{23}molecules }{1 mole}[/tex]
amount of molecules= 1.2046*10²⁴ molecules
When equation for neutralization of HBr by Ca(OH)₂ is correctly balanced, 1.2046*10²⁴ molecules of water will be formed
3. What is the mass of an object with a volume of 4 L and a density of 1.25 g/mL?
Answer:
5000g
Explanation:
mass= density × volume
Since the unit of density here is g/mL, we need to convert the volume to mL.
1L= 1000mL
4L= 4 ×1000 = 4000 mL
Mass of object
= 1.25 ×4000
= 5000g
Answer:
5,000 grams
Explanation:
The mass of an object can be found by multiplying the volume by the density.
mass= volume * density
The density is 1.25 g/mL and the volume is 4 L.
First, we must convert the volume to mL. The density is given in grams per milliliter, but the volume is given in liters.
There are 1,000 mL per L. The volume is 4 L. Therefore, we can multiply 4 and 1,000.
4 * 1,000 = 4,000
The volume is 4,000 mL.
Now, find the mass of the object.
mass= volume * density
volume = 4,000
density= 1.25
mass= 4,000 * 1.25 = 5,000
Add the appropriate units for mass, in this case, grams, or g.
mass= 5,000 g
The mass of the object is 5,000 grams.
A solution containing a unknown ionic compound, vigorously bubbles when hydrochloric acid (HCl) is added to the solution. This might indicate that the solution contains which anion?
Answer:
CO3^2-
Explanation:
In qualitative analysis, we try to use chemical reactions to determine the composition of an unknown substance. The addition of certain reagents to the unknown solution gives certain results that show the presence or absence of certain species from the unknown sample.
When dilute HCl is added to an unknown sample and effervescence is observed, then the unknown sample must contain CO3^2- or HCO3^-. The presence of these species is confirmed if the gas evolved is passed through limewater and the gas turns limewater milky.
The second-order decomposition of NO2 has a rate constant of 0.255 M-1s-1. How much NO2 decomposes in 8.00 s if the initial concentration of NO2 (1.00 L volume) is 1.33 M
Answer:
0.9718M
Explanation:
Rate constant, k = 0.255 M-1s-1
time, t = 8.00 s
Initial concentration, [A]o = 1.33 M
Final concentration, [A] = ?
These quantities are represented by the equation;
1 / [A] = 1 / [A]o + kt
1 / [A] = 1 /1.33 + (0.255 * 8)
1 / [A] = 0.7519 + 2.04
[A] = 1 / 2.7919 = 0.3582 M
How much of NO2 decomposed is obtained from the change in concentration;
Change in concentration = Initial - Final
Change = 1.33 - 0.3582 = 0.9718M
Identify four general properties that make an NSAID unique as compared to the NSAID aspirin. List specific properties that make aspirin, naproxen, and ibuprofen unique from one another
Answer:
NSAIDs are steroidal anti-inflammatories, their action is on the phospholipase A2 enzyme, this enzyme is responsible for breaking down the phospholipids of the membrane to trigger an inflammatory response. This is how steroidal anti-inflammatory drugs inhibit ALL inflammatory pathways (not like NSAIDs that they only inhibit the COX pathway).
These corticosteroid drugs cannot exceed the systemic mineralocorticoid value 1 in the body, since this corticosteroid hormone is also released by the adrenal cortex.
The NSAIDs generate: sporadic peaks in blood glucose, hypertension, fluid retention, increase in body fat mass, possible suppression of the adrenal cortex over time, inhibiting endogenous synthesis of corticosteroids.
On the other hand, naproxen and ibuprofen are NSAIDs, that is, non-steroidal anti-inflammatory drugs that do not influence both routes of inflammation, but only COX, this enzyme is abbreviated as COX but is called cyclooxygenase, and is responsible for a single route of inflammation.
NSAIDs such as naproxen and ibuprofen can cause gastric disorders such as ulcers or gastritis if they are consumed in a very repetitive manner.
In addition, both drugs are anti-inflammatory, analgesic and antipyretic. Although its two main functions are the first two, it was shown to have an effect in lowering body temperature.
That they are anti-inflammatory means that they inhibit the path of inflammation and analgesics the path of pain.
Explanation:
Both types of drugs generate the same effect but by different mechanisms.
Some are steroids and others are not, although steroids are considered to have a greater risk of benefit that is why they are administered against more systematically compromised instances such as anaphylactic shock.
NSAIDs such as naproxen and ibuprofen are the most prescribed today, since they have few risks and very good benefits, meaning that their adverse effects are not lethal or highly relevant and have a good effect on symptoms.
Both must be administered with care when treating a diabetic patient since corticosteroids generate glycemic peaks or increase in blood glucose, and NSAIDs compete for plasma protein with oral hypoglycemic agents, thus generating that these are in higher free concentrations. high diffusing better through the tissues and increases the potency of the adverse effects of these.