1. Use the bond enthalpies to calculate the enthalpy change for this reaction. Is the reaction exothermic or endothermic?

C2H6O + 3 O2 = 2 CO2 + 3 H2O

(S)-2-butanol will undergo an SN2 reaction with HBr to produce a racemic mixture of alkyl bromides. Here option B is the correct answer.

When optically active alcohol is treated with HBr, the reaction follows an SN1 or SN2 mechanism. In the case of SN1, a carbocation intermediate is formed, and in SN2, a backside attack by the nucleophile occurs. The stereochemistry of the product depends on the configuration of the intermediate and the direction of attack.

In the case of (S)-2-butanol, the hydroxyl group is attached to the second carbon atom, which makes it a primary alcohol. When treated with HBr, it undergoes an SN2 reaction, where the hydroxyl group is replaced by the bromine atom. The nucleophile attacks from the backside of the molecule, leading to an inversion of configuration.

This results in the formation of a racemic mixture of alkyl bromides, as both enantiomers have an equal chance of being attacked from either side. On the other hand, (R)-2-butanol, being the enantiomer of (S)-2-butanol, will also undergo the same reaction and produce the same racemic mixture of alkyl bromides.

In the case of (R)-1-phenyl ethanol and (S)-1-phenyl ethanol, they are secondary alcohols and can undergo either SN1 or SN2 reactions depending on the reaction conditions. However, the reaction mechanism will lead to the formation of a mixture of diastereomers, rather than a racemic mixture of enantiomers.

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Complete question:

Which of the following optically active alcohols, when treated with HBr, results in a racemic mixture of alkyl bromides?

a) (R)-2-butanol

b) (S)-2-butanol

c) (R)-1-phenyl ethanol

d) (S)-1-phenyl ethanol

Substance       intermolecular force

CH2OH   --->   Hydrogen bonding

CH3F       -->    Dipole-dipole forces

C3H8       -->    Dispersion forces

CaCL2      -->   Ionic bonding

The intermolecular force present in CH2OH is hydrogen bonding. The intermolecular force present in CH3F is  Dipole-dipole forces. Ionic bonding is defined as a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions or between two atoms with sharply different electronegativities. It is the primary interaction occurring in ionic compounds. Hydrogen bonding results from the attractive force between a hydrogen atom covalently bonded to a very electronegative atom such as a N, O, or F atom and another very electronegative atom.

Dipole-dipole forces are defined as a attractive forces between the positive end of one polar molecule and the negative end of another polar molecule.  Dispersion force is defined as a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

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The complete question is,

Match each substance correctly to the principal type(s) of intermolecular force(s) present, other than covalent bonding.

CH2OH          Ionic bonding

CH3F              Hydrogen bonding

C3H8              Dispersion forces

CaCL2            Dipole-dipole forces

The net ionic equation for the given reaction is: 1 Cr3+(aq) + 3OH-(aq) → Cr(OH)3(s)

2. The formula for the precipitate formed in this reaction is Cr(OH)3.

3. The sum of all coefficients in the net ionic equation is 4.

Consider the reaction between aqueous solutions of potassium hydroxide and chromium (III) chloride. The balanced chemical equation for the given reaction is:KOH(aq) + CrCl3(aq) → KCl(aq) + Cr(OH)3(s)1) Spectator ionsThe ions that do not take part in the reaction are known as spectator ions.

These ions are present on both sides of the equation without undergoing any chemical changes.The ionic equation for the given reaction is:3K+(aq) + 3OH-(aq) + Cr3+(aq) + 3Cl-(aq) → 3K+(aq) + 3Cl-(aq) + Cr(OH)3(s)The spectator ions are K+ and Cl-.2)

PrecipitateThe precipitate is formed when the two reactants are combined together, and it can be identified from the ionic equation. In this reaction, the precipitate is formed when KOH is added to the aqueous solution of chromium(III) chloride.The formula for the precipitate formed in this reaction is Cr(OH)3.3) Sum of all coefficientsThe net ionic equation represents the actual chemical change occurring in the reaction.

The spectator ions are removed, and only the ions that participate in the reaction are shown. The net ionic equation for the given reaction is:Cr3+(aq) + 3OH-(aq) → Cr(OH)3(s)The sum of all coefficients in the net ionic equation is 4.

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The quaternary structure of hemoglobin is responsible for the increased oxygen-carrying capacity and stability of the molecule. This structure allows hemoglobin to better transport oxygen throughout the body and is essential to life.

The structural change from myoglobin to hemoglobin includes an additional quaternary structure, which is the arrangement of two or more myoglobin subunits into a single, functional entity. This structural change allows for the cooperative binding of oxygen, meaning that the hemoglobin molecule can carry more oxygen than a single myoglobin molecule can. This is due to the increased surface area of the hemoglobin molecule, which provides more oxygen-binding sites. Additionally, the quaternary structure of hemoglobin increases the stability of the molecule, meaning it can better resist changes in pH or temperature. This is important because it allows hemoglobin to function in the wide range of temperatures and environments that are found within the human body.  

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(a) one radial node the Number of radial nodes = n - l - 1

And number of angular nodes = l

n = 3 and l = 1

Orbital is 3p.

(b) It has zero angular node hence s-orbital and there is 1 radial node . 1 = n - 0 - 1 ; n = 2 and l = 0

The orbital is 2s.

(c) the shape of the orbital is that of dz². There is two angular nodes and there is no radial node.

n = 3 and l = 2

Hence the orbital is 3dz².

In atomic physics, a radial node is a point in space where the probability density of finding an electron in an atom is zero. It is a type of nodal plane that occurs in atomic orbitals, which are regions of space where electrons are most likely to be found.

Radial nodes occur in the radial distribution function of an atomic orbital, which describes the probability density of finding an electron at a given distance from the nucleus. The number of radial nodes in an atomic orbital is equal to n - l - 1, where n is the principal quantum number and l is the azimuthal quantum number.

Radial nodes represent regions of space where the radial wave function of the electron changes sign.

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The SI unit of pressure is the Pascal (Pa).

The boiling point of water is lower on Mount McKinley than the boiling point of water in NYC.

What is Pressure?

Pressure is defined as the amount of force applied perpendicular to the surface of an object per unit area over which that force is distributed. In other words, it is the force per unit area that an object exerts on another object. Pressure can be measured in various units such as pascal (Pa), bar, pounds per square inch (psi), and atmospheres (atm), among others. It is an important concept in physics and is used to describe many phenomena, including fluid dynamics, weather patterns, and even the behavior of gases in space.

At lower elevations, atmospheric pressure is higher compared to higher elevations.

Standard atmosphere or standard atmospheric pressure is equal to 101325 Pa.

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Answer: Cleavage

Explanation:

When a mineral breaks along a weekly bonded plane it is called cleavage

The first two statements are false, whereas the last statement, which says that pressure and volume of a gas are inversely related, is true.

Statement 1: This claim was incorrect because, according to the ideal gas law, PV=nRT, pressure (P) and volume (V) are inversely proportional to each other at a constant temperature (T) and amount of gas (n). This means that as pressure increases, volume decreases. This relationship is known as Boyle's law. Therefore, the statement that pressure has no effect on volume of a gas is false.

Statement 2: This claim was incorrect because, pressure and volume of a gas are inversely related according to Boyle's law, which states that at a constant temperature, the pressure of a gas is inversely proportional to its volume. This means that if the pressure of a gas increases, its volume will decrease, and if the pressure decreases, the volume will increase, as long as the temperature remains constant.

Statement 3: This claim was correct because, According to Boyle's law, the pressure and volume of a gas are inversely proportional to each other, which means that when the pressure of a gas increases, its volume will decrease and vice versa, as long as the temperature and the number of particles in the gas are kept constant. This relationship is expressed mathematically as P₁V₁ = P₂V₂, where P₁ and V₁ are the initial pressure and volume, and P₂ and V₂ are the final pressure and volume.

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The correct Lewis structures of the compounds that we have in the question have been shown in the images attached.

A Lewis structure is a diagram that shows the bonding between atoms in a molecule and the arrangement of electrons around the atoms. It is also known as a Lewis dot structure, Lewis dot diagram, or electron dot structure.

Lewis structures are useful in predicting the geometry of molecules and determining the polarity of molecules. They are also helpful in understanding the reactivity of molecules and how they interact with other molecules.

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A few statements may be true regarding a biochemical oxidation-reduction (redox) reaction. The statements are as follows: A redox reaction occurs when there is a transfer of electrons between molecules or atoms.

The electron donor becomes oxidized, and the electron acceptor is reduced, causing a transfer of energy. A redox reaction produces ATP, which is the primary energy currency of the cell. Oxidation and reduction are complementary reactions that occur simultaneously in the same reaction, resulting in the release of energy. Redox reactions are vital in metabolic pathways, and the electron carriers NAD+ and FAD+ are essential in these reactions. Oxygen is frequently used as a final electron acceptor in redox reactions. Redox reactions can also occur in non-cellular environments, such as photosynthesis, respiration, and combustion. The significance of redox reactions is enormous, and they play an essential role in sustaining life on earth. They help in generating energy, breaking down complex molecules, synthesizing molecules, and many other cellular processes.

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When the pressure is 0.72 atm, the temperature in Kelvin is 156 K.

To determine the Kelvin temperature when the pressure is 0.72 atm, you will need to use the trendline equation given in Fig 6.2. First, find the equation of the trendline by using the graph's two points, (300 K, 1 atm) and (500 K, 2 atm).

The equation for the trendline is:

y = mx + b

Where y is pressure, x is the temperature in Kelvin, m is the slope, and b is the y-intercept. We can find the slope of the trendline by using the two points provided in the graph:

Slope (m) = (y2 - y1) / (x2 - x1)

Slope = (2 atm - 1 atm) / (500 K - 300 K)

Slope = 0.005 atm/K

The equation for the trendline can now be written: y = 0.005x + b. To find the y-intercept, b, we can use one of the two points: Solving for b:

1 atm = 0.005(300 K) + bb = 1.5 atm

Now we can use the equation for the trendline to find the temperature (x) at which the pressure (y) equals 0.72 atm:

0.72 atm = 0.005x + 1.5 atm

0.72 atm - 1.5 atm = 0.005x

-0.78 atm = 0.005xx

= -0.78 atm / 0.005x

= 156K

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The major organic product of an SN2 substitution reaction is an alkene, which may be either in retention or inversion of configuration relative to the original substrate.

The reaction you are asking about is an SN2 substitution reaction, in which a nucleophile (Nu) displaces a leaving group (LG) from a molecule with an alkyl halide substrate. The major organic product of this reaction will be an alkene, which has the same carbon chain as the alkyl halide substrate. Depending on the relative configuration of the substrate, the alkene product may be the same as the original substrate (retention) or have its configuration inverted (inversion). If stereochemistry is relevant to the question, then it should be specified in the answer.

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a balanced equation for the redox reaction: 2 Ca(s) + O2(g) → 2 CaO(s)

A redox reaction is a type of chemical reaction that involves the transfer of electrons between species. One species undergoes oxidation (loses electrons) while another species undergoes reduction (gains electrons).

In the reaction between calcium metal and oxygen gas, the calcium metal is being oxidized (loses electrons) and the oxygen gas is being reduced (gains electrons). This can be seen in the balanced equation where the calcium atoms go from having an oxidation state of 0 to +2, while the oxygen atoms go from having an oxidation state of 0 to -2.

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The claim was correct . All elements  have same number of particles in one mole and have different number of particles  in a mole based on atomic number .

In the International System of Units, the mole (symbol mol) is the unit of substance amount (SI). The amount of substance is a measurement of how many elementary entities of a given substance are present in an object or sample. An elementary entity can be an atom, a molecule, an ion, an ion pair, or a subatomic particle such as an electron, depending on the substance. For example, despite having different volumes and masses, 10 moles of water (a chemical compound) and 10 moles of mercury (a chemical element) contain equal amounts of substance, and the mercury contains exactly one atom for each molecule of water.

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Answer:

First, we need to calculate the change in temperature:

ΔT = final temperature - initial temperature

ΔT = 85 °C - 35 °C

ΔT = 50 °C

Next, we can use the following formula to calculate the heat energy required:

Q = m·C·ΔT

where Q is the heat energy in calories, m is the mass of the sample in grams, C is the specific heat in cal/g °C, and ΔT is the change in temperature in °C.

Plugging in the given values, we get:

Q = 35.0 g · 0.108 cal/g °C · 50 °C

Q = 189.0 calories

Therefore, 189.0 calories are required to raise the temperature of the sample from 35 °C to 85 °C

Answer:

Explanation:

2-bromopropane is the major product because the reaction mechanism involves the formation of the most stable carbocation intermediate. When hydrogen bromide reacts with propene, the hydrogen atom from HBr adds to the carbon atom of the double bond that has fewer hydrogen atoms attached, resulting in the formation of a carbocation intermediate. The intermediate can either form 1-bromopropane or 2-bromopropane depending on the position of the carbocation. The 2-bromopropane is the major product because the secondary carbocation formed in this case is more stable than the primary carbocation formed in the case of 1-bromopropane.

To test for an alkene, bromine water can be used. When an alkene reacts with bromine water, the bromine molecule adds across the double bond, forming a colorless dibromoalkane product. The mechanism for the reaction between hex-1-ene and bromine involves the formation of a cyclic bromonium ion intermediate, followed by the attack of water on the intermediate, resulting in the formation of the dibromoalkane product.

a) Addition polymerization is a process in which unsaturated monomers are joined together to form a polymer. The process involves breaking the double bond of the monomer and joining the monomers together to form a long-chain polymer. The process requires a catalyst to initiate the reaction.

b) The repeating unit of the polymer formed from the addition polymerization of chloroethene monomers is -CH2-CHCl-. This polymer is called polyvinyl chloride (PVC), and it has a wide range of uses, including pipes, electrical cables, and vinyl flooring.

Answer:

See below.

Explanation:

The atomic number of lead (Pb) is 82, which means it has 82 electrons. The electronic configuration of lead is

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p²

The orbital diagram for the valence electrons of lead (Pb) is

↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓

s s p p p p d d

2 1 6 2 6 2 10 10

|||||||||

1 2 3 4 5 6 7 8

The notation ↑↓ represents a pair of electrons with opposite spins.

To determine if lead (Pb) is diamagnetic or paramagnetic, we need to look at whether there are any unpaired electrons. Based on the orbital diagram, we can see that all the electrons in the valence shell are paired, meaning that lead (Pb) is diamagnetic.

The atoms that are cis to the hydroxyl (OH) substituent are the two carbon atoms in the ring that are directly adjacent to the OH group.

Cis-trans isomerism is a word used in chemistry that refers to the spatial arrangement of atoms within molecules. It is also known as geometric isomerism or configurational isomerism. The Latin prefixes "cis" and "trans" mean, respectively, "this side of" and "the other side of." Trans conveys that the functional groups (substituents) are on the opposite (transverse) sides of some plane, whereas cis implies that they are on the same side of some plane in the context of chemistry.

Cis-trans isomers are examples of stereoisomers, which are pairs of molecules with the same formula but distinct functional groups oriented in three dimensions. The absolute stereochemical explanation of E-Z isomerism does not necessarily equate to cis-trans notation.

The hydroxyl group (-OH) is attached to carbon number 1. The cis atoms are those that are attached to the same side of the ring. There are two atoms that are cis to the hydroxyl (OH) substituent, and these are atoms number 2 and 3. Therefore, the atoms that are cis to the hydroxyl (OH) substituent are atoms number 2 and 3 .

Thus, the cis to the hydroxyl (OH)  is (B) 2 and 3.

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Using CH3NH2 and CH3NH3Cl, one may simulate the blood's buffering properties. A weak acid and its conjugate base, or a weak base and its conjugate acid, make up a buffer system.

Carbonic acid and sodium bicarbonate. Hint: Human blood has a buffer of bicarbonate anion (HCO3) and carbonic acid (H2CO3) to keep the blood's pH between 7.35 and 7.45. Blood pH values higher or lower than 7.8 or 6.8 can be fatal.

Bicarbonate anion and hydronium are in equilibrium with carbonic acid in this buffer. A weak acid and its conjugate base, or a weak base and its conjugate acid, make up a buffer.

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Answer:

CH3NH2 and CH3NH3Cl

Explanation:

Methylamine (CH3NH2) is an organic base. In order to produce a basic buffer solution similar to blood, we can combine this base with a soluble salt of its conjugate acid, such as CH3NH3Cl. The solution of KOH and H2O would not be a good buffer because KOH is a strong base. The solution of HF and NaF is a buffer, but the pKa of HF is about 3.2, which is far from the pH of blood, 7.4.

Answer:

Transcribed Image Text: Rank the following substances in order of increasing acid strength. (1 as least and 4 as most in acid strength) ✓ H₂Se ✓ HBr HI ✓ AsH3 Expert Solution

Explanation:

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Answer:

1.03 mol of dihydrogen gas will evolve, with a volume slightly over 22.4 dm3 at ST P. Explanation: Moles of magnesium: 50.0 ⋅ g 24.31 ⋅ g ⋅ mol−1 = 2.06 mol Moles of hydrogen chloride gas: 75.0 ⋅ g 36.2⋅ g ⋅ mol−1 = 2.07 mol

Explanation:

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Scientists would research the impacts of marble monuments and acid rain. A chemist. Hoping this is useful.

The correct answer is :C.

Surface sediments are transported and large stones are broken up through wind, water, and ice. Years are often needed for weathering, erosion, and deposition to cause noticeable changes. Nonetheless, certain things change the Planet's surface far more quickly than others. Extreme events, earthquakes, and volcanic eruptions are a few of them.

Weathering and erosion caused by water movement change the properties of the terrain. Regional wind patterns and climate are defined by several interactions, including the role of the ocean. The unique physical and chemical properties of water have a profound effect on the planet's dynamics.

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The molecule that is drawn in a conformation that has a proton and a leaving group anti-periplanar is H₂C, Br.

The A, B, C, and D bond angles of a molecule are referred to as anti-periplanar, or antiperiplanar, in organic chemistry. The dihedral angles of the A–B and C–D bonds in this conformer are larger than +150° or less than 150°. In textbooks, the term "anti-periplanar" is frequently used to refer to a strictly anti-coplanar structure with a 180° AB CD dihedral angle. The anti-periplanar functional groups will be 180° apart from one another and in a staggered configuration in a Newman projection of the molecule.  

Conformation is an essential factor in predicting reactivity in organic molecules. The anti-periplanar conformation of a molecule is one that occurs when two atoms in a molecule are in the same plane and are separated by 180 degrees. In this case, the proton and leaving group are placed in a perpendicular plane to the atoms directly in between them. This is the most stable conformer of the molecule. A significant factor in predicting reactivity in organic molecules is conformation. In this case, the molecule H₂C, Br is drawn in a conformation that has a proton and a leaving group anti-periplanar.

Therefore, the correct option is H₂C, Br.

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To produce ammonia (NH₃) from thin air, the reactants required are N₂ and H₂. So the correct option is b).

Ammonia is one of the most abundantly produced inorganic chemicals. In 2016, there are a number of large ammonia plants around the world that produced a total of 144 million tons of nitrogen (equivalent to 175 million tons of ammonia). That number will rise to 235 million tonnes of ammonia in 2021. China produced 31.9% of its global production, followed by Russia at 8.7%, India at 7.5% and the United States at 7.1%. More than 80% of the ammonia produced is used as fertilizer for agricultural crops.

Today, most ammonia is produced on a large scale using the Haber process, with capacities of up to 3,300 tons per day. Gases N₂ and H₂ are reacted at a pressure of 200 bar. A typical modern ammonia production plant first converts natural gas, LPG, or petroleum gas into gaseous hydrogen. The process of producing hydrogen from hydrocarbons is known as steam reforming. Hydrogen then combines with nitrogen to produce ammonia by the Haber-Bosch process.

One way to produce green ammonia is to use hydrogen from the electrolysis of water and nitrogen separated from air. These are fed into the Haber Process (aka Haber-Bosch), all of which produce sustainable power.

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If we use the Gizmo to find the freezing, melting, and boiling points of water at 5,000 meters (16,404 feet) then,

Freezing point: 32 ºF (0ºC)

Melting point: 32 ºF (0ºC)

Boiling point: 203°F (95°C)

The freezing point is defined as the temperature at which a liquid becomes a solid. Increased pressure usually raises the freezing point with the melting point of the solid. The boiling point of a pure substance is defined as the temperature at which the substance transitions from a liquid to the gaseous phase. At the boiling point the vapor pressure of the liquid is equal to the applied pressure on the liquid. The melting point of a substance is defined as the temperature at which the substance changes from a solid to a liquid.

Melting occurs at a single temperature for the pure substances. The normal and average melting point and boiling point of water at 1 atmospheric pressure are 0°C and 100°C respectively. Decreasing the pressure under 1 atm. will lower the boiling point since the external pressure will be lower so it will become equal with the vapor pressure at a lower temperature.

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The electron representation shows the electrons in the atoms as dots as in the image attached.

An electron dot representation, also known as a Lewis dot structure or electron dot diagram, is a way of representing the valence electrons of an atom using dots around the symbol of the element.

Valence electrons are the outermost electrons of an atom, and they play an important role in chemical bonding. The electron dot representation shows the valence electrons as dots around the symbol of the element, with each dot representing one valence electron.

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The average value of the molar volume of hydrogen is 24.0 liters per mole (L/mol).

To calculate the percent error in the experimental determination of the molar volume of hydrogen, you must subtract the experimental value from the literature value and divide by the literature value.

One liter of hydrogen gas at STP has a mass of 0.090 grams, which is the experimental value of the density of hydrogen. This value is lower than the literature value, which is 0.089 grams per liter (g/L).
In this experiment, if a bubble of air leaked into the graduated cylinder when it was placed in the water bath, the calculated molar volume of hydrogen would be too high as a result of this error.

This is because the presence of the bubble of air would increase the measured volume of hydrogen gas.If the magnesium ribbon appeared to be oxidized, the calculated molar volume of hydrogen would be too low as a result of this error.

This is because the oxidation of the magnesium ribbon would reduce the amount of hydrogen gas produced, resulting in a lower measured volume of hydrogen gas. For demonstration purposes, the ideal gas law may be used to calculate the maximum amount or length of magnesium ribbon that may be used.

The ideal gas law equation is PV = nRT, where P is the pressure, V is the volume, n is the amount of substance, R is the ideal gas constant, and T is the temperature. Knowing the desired volume of the gas, the amount of substance can be calculated.

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