Which acid or base (along with its corresponding salt) should be used to generate a buffer solution with pH around 3.5

Answers

Answer 1

Answer:

Formic acid

Sodium formiate

Explanation:

To determine acid or base that can generate a buffer solution with pH around 3.5, we have to think in the acid whose pKa = pH.

Although we have to also think in buffer capacity, a measure which can cause a change of 1 pH unit in 1 L of solution.

Buffer capacity does not only depend on the concentration of its components but also of the relationship between that concentrations.

When pH = pKa, buffer capacity is maximum which means that the concentration of conjugated species is the same and the ability to oppose pH changes is maximum.

One example with pH = pKa or nearly if:

COOH⁻  + Na⁺ →  NaCOOH

HCOOH  +  H₂O  →  COOH⁻  + H₃O⁺     Ka: 1.8×10⁻⁴

pKa = 3.74


Related Questions

Evaluate the exponential expression (−2)6.

Answers

A general exponential expression is something like:

A^n

This means that we need to multiply the number A by itself n times.

Using that we will get (-2)^6 = 64

With that definition, we can rewrite:

(-2)^6 = (-2)*(-2)*(-2)*(-2)*(-2)*(-2)

So we just need to solve the above expression.

Also, remember the rule of signs:

(-)*(-) = (+)

We will get:

(-2)*(-2)*(-2)*(-2)*(-2)*(-2) =  [(-2)*(-2)]*[(-2)*(-2)]*[(-2)*(-2)]

                                        =  4*4*4 = 16*4 = 64

Then we got:

(-2)^6 = 64

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balance equation of aluminium chloride+ hydrogen​

Answers

[tex]\boxed{\sf {AlCl_3\atop Aluminium\:Chloride}+{H_2\atop Hydrogen}\longrightarrow {Al\atop Aluminium}+{HCl\atop Hydrochloric\:acid}}[/tex]

Balanced Equation:-

[tex]\boxed{\sf {2AlCl_3\atop Aluminium\:Chloride}+{3H_2\atop Hydrogen}\longrightarrow {2Al\atop Aluminium}+{6HCl\atop Hydrochloric\:acid}}[/tex]

What volume of each solution contains 0.14 mol of KCl? Express your answer using two significant figures.
1.8 M KCl

Answers

Answer:

Solution given:

1 mole of KCl[tex]\rightarrow [/tex]22.4l

1 mole of KCl[tex]\rightarrow [/tex]74.55g

we have

0.14 mole of KCl[tex]\rightarrow [/tex]74.55*0.14=10.347g

74.55g of KCl[tex]\rightarrow [/tex]22.4l

10.347 g of KCl[tex]\rightarrow [/tex]22.4/74.55*10.347=3.11litre

volume of each solution contains 0.14 mol of KCl contain 3.11litre.

[tex]\:[/tex]

1 mole of KCl → 22.4l

1 mole of KCl → 74.55g

we have

0.14 mole of KCl → 74.55*0.14=10.347g

74.55g of KCl  → 22.4l

10.347 g of KCl → 22.4/74.55*10.347=3.11litre

volume of each solution contains 0.14 mol of KCl contain 3.11litre.

It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of by-product formed. What is the by-product

Answers

Answer:

Biphenyl

Explanation:

The reaction of bromo benzene with magnesium-ether solution yields a Grignard reagent.

The byproduct of this reaction is biphenyl. It is formed when two unreacted bromobenzene molecules are coupled together.

Hence, It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of biphenyl by-product formed.

What must happen to uranium before it can be used as a fuel source?

Answers

Answer: Uranium enrichment. Uranium is used to fuel nuclear reactors; however, uranium must be enriched before it can be used as fuel. Enriching uranium increases the amount of uranium-235 (U235) that can sustain the nuclear reaction needed to release energy and produce electricity at a nuclear power plant.

There are three isotopes of carbon. They have mass number of 12, 13 and 14. The average atomic mass of carbon is 12.0107 amu. What does this say about the relative abundances of the three isotopes?​

Answers

Answer:

lots more of the carbon 12 than the others

havent calculated it percentage-wise but you can see its very close to 12 meaning it is of far greater abundance that carbon 13 and 14

Explanation:

A hot pot of water is set on the counter to cool. After a few minutes it has lost 495 J of heat energy. How much heat energy has the surrounding air gained?

_____unit_____

Answers

Answer:

495 J

Explanation:

When the hot pot was set on the counter to cool, heat energy was lost from the pot. Note that according to the first law of thermodynamics, heat is neither created nor destroyed.

This implies that, the heat energy lost from the pot must be gained by the surrounding air. Therefore, if 495 J of energy is lost from the pot, then 495 J of energy is gained by the surrounding air.

What functional group is found in an alcohol?
A. Ester
B. Amino
C. Carbonyl
D. Hydroxyl ​

Answers

Answer:

an alcohol is a Hydroxyl group due to the OH~ that is associated with it's molecules

The functional group found in an alcohol is Hydroxyl . Therefore, the correct option is option D.

What is functional group?

A functional group in organic chemistry is a substituent and moiety inside a molecule that triggers the molecule's distinctive chemical processes. No matter how the rest of a molecule is made up, the very same functional group would experience the same or a similar set of chemical events.

This permits the design of synthetic chemistry as well as the methodical forecasting of chemical reactions as well as the behaviour of chemical molecules. Other functional groups close by can affect a functional group's reactivity. Retrosynthetic analysis can be used to design organic synthesis by using functional group interconversion. The functional group found in an alcohol is Hydroxyl .

Therefore, the correct option is option D.

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A sample of gas occupies 10.0 L at 240°C under a pressure of
80.0 kPa. At what temperature would the gas occupy 20.0 L if
we increased the pressure to 107 kPa?

Answers

Answer: 1090°C

Explanation: According to combined gas laws

(P1 × V1) ÷ T1 = (P2 × V2) ÷ T2

where P1 = initial pressure of gas = 80.0 kPa

V1 = initial volume of gas = 10.0 L

T1 = initial temperature of gas = 240 °C = (240 + 273) K = 513 K

P2 = final pressure of gas = 107 kPa

V2 = final volume of gas = 20.0 L

T2 = final temperature of gas

Substituting the values,

(80.0 kPa × 10.0 L) ÷ (513 K) = (107 kPa × 20.0 L) ÷ T2

T2 = 513 K × (107 kPa ÷80.0 kPa) × (20.0 L ÷ 10.0 L)

T2 = 513 K × (1.3375) × (2)

T2 = 1372.275 K

T2 = (1372.275 - 273) °C

T2 = 1099 °C

1090 degree Celsius

hope it helps

What is the balanced form of the following equation?
Br2 + S2O32- + H2O → Br1- + SO42- + H+

Answers

Answer:

5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺

Explanation:

We will balance the redox reaction through the ion-electron method.

Step 1: Identify both half-reactions

Reduction: Br₂ ⇒ Br⁻

Oxidation: S₂O₃²⁻ ⇒ SO₄²⁻

Step 2: Perform the mass balance, adding H⁺ and H₂O where appropriate

Br₂ ⇒ 2 Br⁻

5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺

Step 3: Perform the charge balance, adding electrons where appropriate

2 e⁻ + Br₂ ⇒ 2 Br⁻

5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻

Step 4: Make the number of electrons gained and lost equal

5 × (2 e⁻ + Br₂ ⇒ 2 Br⁻)

1 × (5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻)

Step 5: Add both half-reactions

5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺

Conversion Problem (show all work):
1. A patient required 3.0 pints of blood during surgery. How many liters does this correspond
to? Show all work. Use conversion factors available in the text or the exam packet. (4)

Answers

1.42liters, which is equivalent to 3pints, of blood is required for the surgery

Pints is a unit of measurement for volume in the United States. However, it can be converted to litres using the following equation:

1 US pint = 0.473 liters

Hence, according to this question which states that a patient required 3.0 pints of blood during surgery. This means that the patient required:

3 × 0.473

= 1.419 liters of blood for the surgery

1.42liters, which is equivalent to 3pints, of blood is required for the surgery

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Consider the reaction: NaNO3(s) + H2SO4(l) NaHSO4(s) + HNO3(g) ΔH° = 21.2 kJ

How much heat must absorbed by the reaction system to convert 100g of NaNO3 into NaHSO4(s)?

Answers

Answer:

endet nach selam nw

4gh7

Part A
When the following liquids are poured into the same container, they separate as shown in the image. Based on the data
in the table below, what caused the order of the layers?
rubbing alcohol
vegetable oil
water
corn syrup
Mass
Liquid
corn syrup
water
Volume Used
95 cm
90 cm
85 cm
105 cm?
130.158
90.00 8
77.358
81.908
Density
1.37 g/cm
1 g/cm
0.91 g/cm
0.78 g/cm
vegetable oil
rubbing alcohol
I
B
X
Font Sizes
A- A -
E 3

Answers

Answer: The layers are ordered by density, with the least dense layer on top, and the densest layer on the bottom.

Explanation:

Plato

Given the following balanced reaction: 2Na(s) + F2(g) --> 2NaF(s)
a) How many moles of NaF will be made from 2.6 moles of F2?

b) How many moles of NaF will be made from 4.8 moles of Na?

Answers

Answer:

yes it is corrwect iyt is absolitle correct

Explanation:

The density of toluene (C7H8) is 0.867 and that of thiophene (C4H4S) is 1.065 g/ml. A solution is made by dissolving 10.00g thiophene in 250.00ml of toluene. a)Calculate the molarity of the solution
b)Assuming the volume are addictive ,calculate the molarity of the solution

Answers

Answer:

Calcular la molaridad de una solución que se preparó disolviendo 14 g de KOH en suficiente  

agua para obtener 250 mL de solución. (masa molar del KOH = 56 g/mol).

Resolución: de acuerdo a la definición de “molaridad” debemos calcular primero, el número de mol de soluto (KOH) que  

se han disuelto en el volumen dado, es decir, “se transforma g de soluto a mol de soluto” por medio de la masa molar,  

así:

56 g de KOH 14 g de KOH

----------------- = ------------------- X = 0,25 mol de KOH

1 mol X

Ahora, de acuerdo con la definición de molaridad, el número de mol debe estar contenido en 1000 mL (o 1 L) de  

solución, que es el volumen estándar para esta unidad de concentración, lo que se determina con el siguiente planteamiento:

0,25 mol X

----------------------- = ------------------------- X = 1 mol de KOH

250 mL de solución 1000 mL de solución

Explanation:

What volume of 1.50 mol/L stock solution is needed to make 125 mL of 0.60 mol/L solution?

Answers

Chemistry 11 Solutions

978Ͳ0Ͳ07Ͳ105107Ͳ1Chapter 8 Solutions and Their Properties • MHR | 85

Amount in moles, n, of the NaCl(s):

NaCl

2.5 g

m

n

M

58.44 g

2

4.2778 10 m l

ol

o

/m

u

Molar concentration, c, of the NaCl(aq):

–2 4.2778 × 10 mol

0.100

0.42778 mol/L

0.43 mol

L

/L

n

c

V

The molar concentration of the saline solution is 0.43 mol/L.

Check Your Solution

The units are correct and the answer correctly shows two significant digits. The

dilution of the original concentrated solution is correct and the change to mol/L

seems reasonable.

Section 8.4 Preparing Solutions in the Laboratory

Solutions for Practice Problems

Student Edition page 386

51. Practice Problem (page 386)

Suppose that you are given a stock solution of 1.50 mol/L ammonium sulfate,

(NH4)2SO4(aq).

What volume of the stock solution do you need to use to prepare each of the

following solutions?

a. 50.0 mL of 1.00 mol/L (NH4)2SO4(aq)

b. 2 × 102 mL of 0.800 mol/L (NH4)2SO4(aq)

c. 250 mL of 0.300 mol/L NH4

+

(aq)

What Is Required?

You need to calculate the initial volume, V1, of (NH4)2SO4(aq) stock solution

needed to prepare each given dilute solution.

The dilution gives the relationship between the molarity and the volume of the solution. The volume of stock solution with a molarity of 1.50 mol/L is 50 mL.

What is dilution?

Dilution is said to be the addition of more volume to the concentrated solution to make it less in molar concentration. This tells about the inverse and indirect relationship between the volume and the molar concentration of the solution.

Given,

Initial volume = V₁

Initial molar concentration (M₁) = 1.50 mol/L

Final volume (V₂) = 125 mL = 0.125 L

Final molar concentration (M₂)= 0.60 mol/L

The dilution is calculated as:

M₁V₁ = M₂V₂

V₁ = M₂V₂ ÷ M₁

Substituting the values in the above formula as

V₁ = M₂V₂ ÷ M₁

V₁ = (0.60 mol/L × 0.125 L) ÷ 1.50 mol/ L

V₁ = 0.05 L

= 50 mL

Therefore, 50 mL of stock solution is needed to make a 0.60 mol/L solution.

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15.27
The following equilibria were attained at 823 K:
COO(s) + H2() Co(s) + H2O(g) K = 67

COO(s) + CO(8) = Co(s) + CO2(8) K = 490

Based on these equilibria, calculate the equilibrium con-
stant for
H2(g) + CO2(g) = CO(g) + H2O(g) at 823 K.

Answers

The equilibrium constant for the reaction is K = 0.137

We obtain the equilibrium constant considering the following equilibria and their constants:

COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

COO(s) + CO(g) → Co(s) + CO₂(g)   K₂ = 490

We write the first reaction in the forward direction because we need H₂(g) in the reactants side:

(1)     COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

Then, we write the second reaction in the reverse direction because we need CO₂(g) in the reactants side. Thus, the equilibrium constant for the reaction in the reverse direction is the reciprocal of the constant for the reaction in the forward direction (K₂):

(2)   Co(s) + CO₂(g) → COO(s) + CO(g)   K₂ = 1/490

From the addition of (1) and (2), we obtain:

COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

+

Co(s) + CO₂(g) → COO(s) + CO(g)   K₂ = 1/490

-------------------------------------------------

H₂(g) +  CO₂(g) → CO(g) + H₂O(g)

Notice that Co(s) and COO(s) are removed that appear in the same amount at both sides of the chemical equation.

Now, the equilibrium constant K for the reaction that is the sum of other two reactions is calculated as the product of the equilibrium constants, as follows:

K = K₁ x K₂ = 67 x 1/490 = 67/490 = 0.137

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Heating water makes most solids in it

soluble, and it makes gases

soluble.

Increasing the pressure on a gas above water makes the gas

soluble. Compounds with comparatively stronger ionic bonds are

soluble.

Answers

Answer:

1. more

2. less

3. more

4. less

Explanation:

11. An isotope Q has 18 neutrons a mass number of 34. (a) (i) What is an isotope? An isotope is one of two or C (b) Write its electron arrangement. Mass number=34 Number of neutrons=18 Number of Protons = 34-15-16 (c) To which period and group does Q belong? Protors - Electons - Atomic number Period - Group (d) How does Q form its ion?

Answers

An isotope is an element with the same atomic number but different mass number due to differences in number of neutrons.

electron configuration is 2,8,6.

Belongs to group 6 and period group 3.

It forms an ion by accepting 2 electrons

A solution is made by dissolving 5.84 grams of NaCl in enough distilled water to give a final volume of 1.00 L. What is the molarity of the solution
Group of answer choices

0.0250 M

0.400 M

0.100 M

1.00 M

Answers

Answer:

Explanation:

1. A solution is made by dissolving 5.84g of NaCl is enough distilled water to a give a final volume of 1.00L. What is the molarity of the solution? a. 0.100 M b. 1.00 M c. 0.0250 M d. 0.400 M 2. A 0.9% NaCl (w/w) solution in water is a. is made by mixing 0.9 moles of NaCl in a 100 moles of water b. made and has the same final volume as 0.9% solution in ethyl alcohol c. a solution that boils at or above 100°C d. All the above (don't choose this one) 3. In an exergonic process, the system a. gains energy b. loses energy c. either gains or loses energy d. no energy change at all

Answer:

[tex]\boxed {\boxed {\sf 0.100 \ M }}[/tex]

Explanation:

Molarity is a measure of concentration in moles per liter.

[tex]molarity = \frac{moles \ of \ solute}{liters \ of \ solution}}[/tex]

The solution has 5.84 grams of sodium chloride or NaCl and a volume of 1.00 liters.

1. Moles of Solute

We are given the mass of solute in grams, so we must convert to moles. This requires the molar mass, or the mass of 1 mole of a substance. These values are found on the Periodic Table as the atomic masses, but the units are grams per mole, not atomic mass units.

We have the compound sodium chloride, so look up the molar masses of the individual elements: sodium and chlorine.

Na: 22.9897693 g/mol Cl: 35.45 g/mol

The chemical formula (NaCl) contains no subscripts, so there is 1 mole of each element in 1 mole of the compound. Add the 2 molar masses to find the compound's molar mass.

NaCl: 22.9897693 + 35.45 = 58.4397693 g/mol

There are 58.4397693 grams of sodium chloride in 1 mole. We will use dimensional analysis and create a ratio using this information.

[tex]\frac {58.4397693 \ g\ \ NaCl} {1 \ mol \ NaCl}[/tex]

We are converting 5.84 grams to moles, so we multiply by that value.

[tex]5.84 \ g \ NaCl *\frac {58.4397693 \ g\ NaCl} {1 \ mol \ NaCl}[/tex]

Flip the ratio. It remains equivalent and the units of grams of sodium chloride cancel.

[tex]5.84 \ g \ NaCl *\frac {1 \ mol \ NaCl}{58.4397693 \ g\ NaCl}[/tex]

[tex]5.84 *\frac {1 \ mol \ NaCl}{58.4397693 }[/tex]

[tex]0.09993194823 \ mol \ NaCl[/tex]

2. Molarity

We can use the number of moles we just calculated to find the molarity. Remember there is 1 liter of solution.

[tex]molarity= \frac{moles \ of \ solute}{liters \ of \ solution}[/tex]

[tex]molarity= \frac{ 0.09993194823 \ mol \ NaCl}{1 \ L}[/tex]

[tex]molarity= 0.09993194823 \ mol \ NaCl/L[/tex]

3. Units and Significant Figures

The original measurements of mass and volume have 3 significant figures, so our answer must have the same. For the number we calculated, that is the thousandths place. The 9 in the ten-thousandths place tells us to round the 9 to a 0, but then we must also the next 9 to a 0, and the 0 to a 1.

[tex]molarity \approx 0.100 \ mol \ NaCl/L[/tex]

1 mole per liter is 1 molar or M. We can convert the units.

[tex]molarity \approx 0.100 \ M \ NaCl[/tex]

The molarity of the solution is 0.100 M.

What did Millikan discover

Answers

Answer:

Robert Millikan was a physicist who discovered the elementary charge of an electron using the oil-drop experiment

Answer:

the mass of an electron using the Oil-Drop experiment.

Explanation:

An ice cube, measured at 260 Kelvin, is dropped into a cup of tea that is 350 Kelvin. The temperature of the tea is recorded every 30 seconds and shows the temperature dropping for 4 minutes. After 4 minutes the temperature stays steady at 300 Kelvin. What is this called?
A. Thermal equilibrium
B. Specific heat capacity
C. Latent heat
D. Temperature transfer

Answers

Answer:

Specific Heat Capacity

17. According to Newton's first law, an object in motion will stay in what kind of
motion as long as the net forces acting on it are zero?
A. slowing motion in a straight line
B. accelerating motion in a straight line
C. constant motion in a straight line
D. constant motion in an unpredictable direction

Answers

Answer:

C

Explanation:

According to Newton's first law, an object in motion will stay in motion unless acted upon by an unbalanced force. The option which gives the same meaning is :

constant motion in a straight line

According to Newton's first law, an object in motion as long as the net forces acting on it are zero will stay in:

C. constant motion in a straight line

A constant motion in mechanics is a number that remains constant throughout the motion, effectively placing a restriction on the motion.

What is Newton's first law of motion?The foundation of classical mechanics is made up of the three laws of motion that Newton suggested. These three physical laws. In accordance with the three laws of motion, a body's connection to the forces operating on it and the motion that resulted from those forces are both described. As Galileo's law of inertia, Newton's First Law of Motion is also referred to. If a body is not forced by an outside force to change its condition, it will remain in its state of rest or uniform motion in a straight line. As a factor that has the potential to alter an object's condition, the law defines force and mentions it.In this way, Newton uses the inertia of rest, motion, and direction to describe his first law of motion.A body has an attribute called inertia that makes it resist changes to its state. A body's inertia of translational motion is measured by its mass.

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Consider the Fischer ester synthesis of methyl benzoate from benzoic acid and methanol in the presence of sulfuric acid as a catalyst. A reaction was performed in which 3.3 g of benzoic acid was reacted with excess methanol to make 1.7 g of methyl benzoate. Calculate the theoretical yield and percent yield for this reaction.

Answers

Answer:

46.2%

Explanation:

Number of moles benzoic acid reacts = 3.3g/122.12 g/mol = 0.027 moles

Since the reaction is 1:1, 0.027 moles of methyl benzoate is formed.

Hence;

Theoretical yield of methyl benzoate = 0.027 moles × 136.15 g/mol = 3.68 g

% yield = actual yield/theoretical yield × 100

% yield = 1.7 g/3.68 g × 100

% yield = 46.2%

Find the volume occupied by 128g of SO2.​

Answers

The volume occupied by the given amount of sulfur dioxide will be 84 L.

please show working my dear citizen

How many moles of (CH3)3NH+ are in 6.0 g of (CH3)3NH+?

Answers

Answer:

0.1 mol

Explanation:

6/(15*3+15)

0.1 mol moles of (CH3)3NH+ are in 6.0 g of (CH3)3NH+

What is mole?

The mole, symbol mol, exists as the SI base unit of the amount of substance. The quantity amount of substance exists as a measure of how many elementary entities of a provided substance exist in an object or sample.A mole corresponds to the mass of a substance that includes 6.023 x 1023 particles of the substance. The mole exists the SI unit for the amount of a substance. Its symbol stands mol.

The compound trimethylamine, (CH3 )3N, exists as a  weak base when dissolved in water.

A mole exist expressed as 6.02214076 × 1023 of some chemical unit, be it atoms, molecules, ions, or others. The mole exists as a convenient unit to utilize because of the great number of atoms, molecules, or others in any substance.

To find the amount of the substance (CH3)3NH+ to calculate its molar mass:

M((CH3)3NH+) = (12+3)*3 + 14+1 = 60 g/mol

n((CH3)3NH+) = m/M

m((CH3)3NH+) = 6g

Thus,

n((CH3)3NH+) = 6g/60 g/mol = 0.1 mol

Hence,

n((CH3)3NH+) = 0.1 mol

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which of the following measurements is equivalent to 5.461x10^-7m?

Answers

Answer:

B. 0.0000005461m

I used the method of moving the decimal.

During electrophilic aromatic substitution, a resonance-stabilized cation intermediate is formed. Groups, already present on the benzene ring, that direct ortho/para further stabilize this intermediate by participating in the resonance delocalization of the positive charge. Assume that the following group is present on a benzene ring at position 1 and that you are brominating the ring at positon 4. Draw the structure of the resonance contributor that shows this group actively participating in the charge delocalization.

-----OCH3

Answers

Answer:

See explanation and image attached

Explanation:

Aromatic compounds undergo electrophilic aromatic substitution reactions in which the aromatic ring is maintained.

Substituted benzenes may be more or less reactive towards electrophilic aromatic substitution than benzene depending on the nature of the substituent present in the ring.

Substituents that activate the ring towards electrophilic substitution such as -OCH3 are ortho-para directing.

The major products of the bromination of anisole are p-bromoanisole and o-bromoanisole. The resonance structures leading to these products are shown in the image attached.

g Identify the process in which the entropy increases. Group of answer choices a decrease in the number of moles of a gas during a chemical reaction the phase transition from a gas to a liquid the phase transition from a solid to a gas freezing water

Answers

Answer:

phase transition from a solid to a gas

Explanation:

Entropy refers to the degree of disorderliness in a system. The more disorderly a system is, the greater the entropy of the system.

Decrease in the number of moles of a gas decreases the entropy of the system. Similarly, the entropy of solids is less than that of liquids. The entropy of liquids is less than that of gases.

Therefore, a change of phase from solid to gas represents an increase in entropy of the system.

A student was given a solid containing a mixture of nitrate salts. The sample completely dissolved in water, and upon addition of dilute HCl , no precipitate formed. The pH was lowered to about 1 and H2S was bubbled through the solution. No precipitate formed. The pH was adjusted to 8 and H2S was again bubbled in. This time, a precipitate formed. Which compounds might have been present in the unknown?
a. Ca(NO3)2
b. AgNO3
c. Fe(NO3)3
d. Cr(NO3)3
e. Cu(NO3)2
f. KNO3
g. Bi(NO3)2

Answers

Answer:

Fe(NO3)3, Cr(NO3)3, Co(NO3)3

Explanation:

According to the question, no precipitate is observed when HCl was added. This means that we must rule out AgNO3.

Again, the sulphides of Cu^2+, Bi^3+ are soluble in acidic medium but according to the question, the sulphides do not precipitate at low pH hence Cu(NO3)2 and Bi(NO3)3 are both ruled out.

The sulphides of Fe^3+, Cr^3+ and Co^3+ all form precipitate in basic solution hence Fe(NO3)3, Cr(NO3)3, Co(NO3)3 may be present.

The presence of Ca(NO3)2 and KNO3 may be confirmed by flame tests.

Other Questions
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