Answer:
Slower
Explanation:
The reaction between alkyl halides and sodium iodide-in-acetone is an SN2 reaction. The rate of reaction depends on the concentration of the alkyl halide as well as the concentration of the sodium iodide. It is a bimolecular reaction.
This means that if the concentration of any of the reactants is halved, the rate of reaction decreases accordingly.
Therefore, if the iodide solution is half as concentrated, the reaction is observed to be slower in accordance with the rate law;
Rate = k[alkyl halide] [iodide]
g in the following three compounds(1,2,3) arrange their relative reactivity towards the reagent CH3Cl / AlCl3. Justify your order
Answer:
3 > 2> 1
Explanation:
Aromatic compounds undergo electrophilic substitution reaction with several electrophiles.
Some substituted benzenes are more reactive towards electrophilic aromatic substitution than unsubstituted benzene.
Certain groups of substituents increase the ease with which an aromatic compound undergoes aromatic substitution.
If we look at the compounds closely, we will notice that only toluene leads to easy reaction with CH3Cl / AlCl3. Thus is due to the +I inductive effect of -CH3 which stabilizes the negatively charged intermediate produced in the reaction.
what are the methods used to determine the boiling point of a compound?
Answer:
There are a variety of methods by which a sample's boiling point can be determined, including distillation, reflux, and by using a Thiele tube. The most straightforward method uses a Thiele tube, and has the advantage of using less than 0.5mL of material.
Distillation Method
There are simpler methods than a distillation to measure a compound's boiling point, and it is recommended to explore other options (e.g. Thiele tube) if this is the only goal. However, if materials are limited, or if a purification is planned anyhow, a distillation can be used to determine a compound's boiling point. The distillation technique is discussed in great detail in Chapter 5.
A simple distillation should suffice for most situations and at least 5mL of sample should be used in the distilling flask along with a few boiling stones or stir bar. As the bulk of the material distills, the highest temperature noted on the thermometer corresponds to the boiling point. A major source of error with this method is recording too low a temperature, before hot vapors fully immerse the thermometer bulb. 5 Be sure to monitor the thermometer periodically, especially when the distillation is active. Record the barometric pressure along with the boiling point.
Reflux Method
A reflux setup can also be used to determine a compound's boiling point. Reflux is when a liquid is actively boiling and condensing, with the condensed liquid returning to the original flask. It is analogous to a distillation setup, with the main difference being the vertical placement of the condenser.
Thiele Tube Method
There are a variety of methods by which a sample's boiling point can be determined, including distillation, reflux and by using a Thiele tube. The most straightforward method uses a Thilele tube, and has the advantage of using less than 0.5ml of material.
g You observed the formation of several precipitates in the Reactions in Solution lab exercise. Identify the precipitate in each of the following reactions: a. The yellow precipitate formed in the reaction between KI and Pb(NO3)2 is . b. The white precipitate formed in the reaction between BaCl2 and H2SO4 is . c. The brown precipitate formed in the reaction between NaOH and FeCl3 is . d. The blue precipitate formed in the reaction between CuSO4 and NaOH is .
Answer:
For a: Lead iodide is a yellow precipitate.
For b: Barium sulfate is a white precipitate.
For c: Ferric hydroxide is a brown precipitate.
For d: Copper (II) hydroxide is a blue precipitate.
Explanation:
Precipitation reaction is defined as the reaction where a solid precipitate (solid substance) is formed at the end of the reaction. It is insoluble in water.
For the given options:
For (a):The chemical reaction between KI and lead (II) nitrate follows:
[tex]2KI(aq)+Pb(NO_3)_2(aq)\rightarrow PbI_2(s)+2KNO_3(aq)[/tex]
The iodide of lead is generally insoluble in water. Thus, lead iodide is a yellow precipitate.
For b:The chemical reaction between barium chloride and sulfuric acid follows:
[tex]BaCl_2(aq)+H_2SO_4(aq)\rightarrow BaSO_4(s)+2HCl(aq)[/tex]
The sulfate of barium is insoluble in water. Thus, barium sulfate is a white precipitate.
For c:The chemical reaction between NaOH and ferric chloride follows:
[tex]3NaOH(aq)+FeCl_3(aq)\rightarrow Fe(OH)_3(s)+3NaCl(aq)[/tex]
The hydroxide of iron is insoluble in water. Thus, ferric hydroxide is a brown precipitate.
For d:The chemical reaction between NaOH and copper sulfate follows:
[tex]CuSO_4+2NaOH\rightarrow Cu(OH)_2+Na_2SO_4[/tex]
The hydroxide of copper is insoluble in water. Thus, copper (II) hydroxide is a blue precipitate.
(a) The yellow precipitate formed in the reaction between KI and Pb(NO3)2 would be PbI2 according to the equation:
[tex]Pb(NO_3)_2(aq) + 2KI(aq) ---> PbI2(s) + 2KNO_3(aq)[/tex]
(b) The white precipitate formed in the reaction between BaCl2 and H2SO4 would be BaSO4 according to the equation:
[tex]BaCl_2 (aq) + H_2SO_4 (aq) ---> BaSO_4 (s) + 2 HCl (aq)[/tex]
(c) The brown precipitate formed in the reaction between NaOH and FeCl3 would be Fe(OH)3 according to the equation:
[tex]FeCl_3 (aq) + NaOH (aq) ---> Fe(OH)_3 (s) + NaCl (aq)[/tex]
(d) The blue precipitate formed in the reaction between CuSO4 and NaOH would be Cu(OH)2 according to the equation:
[tex]CuSO_4(aq) + 2 NaOH (aq) ---> Cu(OH)_2 (s) + Na_2SO_4 (aq)[/tex]
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Energy Changes in Reactions
Independent Practice
In a synthesis reaction, one reactant contains 256 J of chemical energy, and one reactant contains 328 J of
chemical energy. The product contains 407 J of chemical energy.
Because energy is conserved, what energy change occurs during the reaction?
A. 177 J of energy is released.
B. 177 J of energy is absorbed.
C. 335 J of energy is released,
D. 335 J of energy is absorbed.
SAVE
SAVE AND CLOSE
Explain carefully what happen to the propanol-water system if approximately
50% of propanol by mass is fractionally distilled. What will be the distillate and
the residue?
Answer:
In the case of mixtures of ethanol and water, this minimum occurs with 95.6% by mass of ethanol in the mixture. The boiling point of this mixture is 78.2°C, compared with the boiling point of pure ethanol at 78.5°C, and water at 100°C. You might think that this 0.3°C doesn't matter much, but it has huge implications for the separation of ethanol / water mixtures. The next diagram shows the boiling point / composition curve for ethanol / water mixtures. I've also included on the same diagram a vapor composition curve in exactly the same way as we looked at on the previous pages about phase diagrams for ideal mixtures.
NaCl is ___ formula of common salt
A. Empirical formula
B. Molecular formula
C. Both A and B
D. None of them
Which of the following is an alkaline earth metal?
O A. Carbon (C)
O B. Aluminum (AI)
O C. Magnesium (Mg)
O D. Silicon (Si)
Answer:
Magnesium (Mg)
Explanation:
The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.
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Answer:
The answer is C. Magnesium(Mg)
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The molar mass of a compound can be determined by the freezing point depression method. The solution must be relatively dilute and you must know the molal freezing point depression constant of the solvent, Kf. Which statement regarding Kf is true?
A. Kf should be small so that the solvent will not sublimate.
B. Kf will change depending on what solute is dissolved in the solvent.
C. Kf should be negative so the freezing point of the solution will decrease.
D. Kf should be large so the temperature change will be large enough to measure.
Answer:
K should be large so the temperature change will be large enough to measure.
Explanation:
Let us recall that;
∆T = k m I
Where;
∆T= change in boiling point
K= freezing point constant
m= molality
i= Van't Hoff factor
Since the change in temperature depends on k, the larger the value of k the larger the temperature change(Ts - Tb). Hence; K should be large so the temperature change will be large enough to measure.
Ts= freezing temperature of pure solvent
Tb= freezing temperature of solution
Draw bond-line formulas of all dichloro derivatives that might be formed when 1-chloro-2,2,3,3,-tetramethylpentane is allowed to react with Cl 2 under UV irradiation. For each structure, indicate, with an asterisk, any stereocenters that might be present. Predcit the percentage of each product using the relative reactivities 3 0 = 5.3, 2 0 = 3.6, 1 0 = 1
Answer:
Explanation:
This is a halogenation reaction i.e substitution or replacement of a single or more than a single hydrogen atom in the organic alkane compound with the halogen(here it is chlorine).
The chlorination of 1-chloro-2,2,3,3-tetramethylpentane under UV light resulted in the formation of five (5) dichloro derivatives which are shown in the image attached below.
Also, the compounds containing a stereocenter (i.e a location within the compound composing of various substituents in which the interchangeability of these substituents has the tendency of resulting into a stereoisomer) are indicated with an asterisk in the image below.
From the image below:
compound 1 ⇒ 1,1-dichloro-2,2,3,3-tetramethylpentane = 2° C
∴
The given relative reactivity rate for 2° = 3.6x
For compound 2 ⇒ 1,4-dichloro-2,2,3,3-tetramethylpentane = 2° = 3.6x
For compound 3 ⇒ 1,5-dichloro-2,2,3,3-tetramethylpentane = 1° = 1x
For compound 4 ⇒ 1-chloro-2-chloromethyl-2,3,3-trimethylpentane
= 1° = 1x
For compound 5 ⇒ 1-chloro-3-chloromethyl-2,2,3-trimethylpentane
= 1° = 1x
As such, we have:
2(3.6x) + 3(1x) = 100
7.2x + 3x = 100
10.2x = 100
x = 100/10.2
x = 9.803°
∴
For compound (1) = 3.6(9.803) = 35.3%
For compound (2) = 3.6(9.803) = 35.3%
For compound (3) = 1(9.803) = 9.803°%
For compound (4) = 1(9.803) = 9.803°%
For compound (5) = 1(9.803) = 9.803°%
why do people who do a lot of physical work need more carbohydrate?
Answer:
A person doing physical work needs lots of good carbohydrates to keep their energy levels up and proteins to repair a muscle that might get wear and tear from overexertion. Carbohydrate will help the person work for more extended periods.
1. What is the equivalent pressure measurement in mmHg of 2.50 atm?
Answer:
Atmosphere to mmHg Conversion Example. Task: Convert 8 atmospheres to mmHg (show work) Formula: atm x 760 = mmHg Calculations: 8 atm x 760 = 6,080 mmHg Result: 8 atm is equal to 6,080 mmHg.
Explanation:
This answer is helpfull for you I nowElement X has two naturally occurring isotopes, 35X and 36X . 35X has a percent natural abundance of 30%, while 36X has a percent natural abundance of 70%. What is the average atomic mass of element X
Answer:
= 35.7 amu
Explanation:
Isotopic fractional Wt Avg mass
mass (amu) abundance (= % / 100) = Isotopic mass X (= % / 100)
X-35 35 0.30 10.5 amu
X-36 36 0.70 25.2 amu
__________________________________________________________
Average Atomic Mass of Element X = ∑ Wt. Avg. Masses = 35.7 amu
Water has a density of 1.00 g/mL. If you put an object that has a density of 0.79 g/mL into water, it will sink to the bottom.
ANSWER please
True
False
Answer:
False
Explanation:
An object with a density less than the density of water will float.
And an object that is denser than water (more than 1.00g/mL) will sink when placed in water.
Which observation provided Albert Einstein the clue that he needed to explain the photoelectric effect?
Answer:
Einstein realized that the energy in electrons was caused by the frequency of light and not the intensity of light. This made him realize that he needed to explain the photoelectric effect.
Explanation:
Einstein realized that the photoelectric effect was a system that should be studied and explained in more depth, when he saw how the energy of electrons behaved in the presence of light. He saw that this energy depends entirely on the frequency of light and not on the intensity of light. From this observation, he realized that the photoelectric effect was essential for the production of an electric energy system, through light energy, such as solar energy.
It is important to note that the photoelectric effect refers to the ejection of electrons on a light surface that comes into contact with a light source.
11
Na
Sodium
22.99
What does 22.99 stand for
I need help with the practice question at the bottom. Thank you.
Explanation:
For this question, we apply the equation: Q = mCp AT Where m is the mass of the substance, Cp
is its specific heat capacity and AT is the
temperature change. Q = 896 x 0.45 x (5-94)
Q = -35884.8 Joules
So about -36 kilojoules of heat is released.
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Observe as equações e de acordo com Brönsted-Lowry, os compostos destacados são, respectivamente
answer
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Essentially all of the mass of an atom is due to the?
nucleons
electrons.
protons
Neutrons
Answer:
nucleons
Explanation:
The answer to the question is nucleons. Because there are both protons and neutrons in the nucleon, it will be heavier. Also, protons and neutrons are much heavier than the weight of an electron, because electrons float around the atom so it is not the answer. So, our final answer is actually option A.
the pressure of a sample of helium in a 0.150 L container is 1520 torr. if the helium is compressed to the volume of 0.012 L without changing the temperature what would be the pressure of the gas
Answer:
19000 torr
Explanation:
From the question given above, the following data were obtained:
Initial volume (V₁) = 0.150 L
Initial pressure (P₁) = 1520 torr
Final volume (V₂) = 0.012 L
Temperature = constant
Final pressure (P₂) =?
The final pressure of the gas can be obtained by using the Boyle's law equation as illustrated below:
P₁V₁ = P₂V₂
1520 × 0.150 = P₂ × 0.012
228 = P₂ × 0.012
Divide both side by 0.012
P₂ = 228 / 0.012
P₂ = 19000 torr
Thus, the final pressure of the gas is 19000 torr
How many molecules make up 12.8g of N2O4
Answer:
8.35 × 10 ²² molecules
Explanation:
gram molecular weight of N2O4
= 2 × 14 + 4 × 16
= 28 + 64
= 92g
1 mole N2O4 has 6 × 10²³ molecules of N2O4 and weighs 92g
therfore,
92 g has = 6 × 10²³ molecules
12.8 g has =
[tex] \frac{6 \times 10 {}^{23}}{92} \times 12.8[/tex]
= 0.835 × 10²³
= 8.35 × 10 ²² molecules
Suppose you need to prepare 138.1 mL of a 0.190 M aqueous solution of NaCl. What mass, in grams, of NaCl do you need to use to make the solution
Answer:
Explanation:
· 44 g NaCl Explanation: The problem provides you with the molarity and volume of the target
The answer is rounded to two sig figs, the number of sig figs you have for the molarity of the solution.
The mass of a solute needed to prepare a solution with given volume is find by molarity. The mass of NaCl need to make a 138.1 mL solution of 0.190 M is 1.53 grams.
What is molarity ?Molarity of a solution is a term to express its concentration. Mathematically, it is the ratio of no.of moles of solute to the volume of solution in litres.
Given that, the volume of solution is 138.1 mL. One litre solution is 1000 mL. Hence, 138.1 mL is 0.1381 L. The molarity of the solution is 0.190 M. From these data we can calculate the no.of moles of NaCl as below:
no.of moles = molarity × volume of solution in L
= 0.190 M × 0.1381 L
= 0.0262 moles.
This is the no.of moles required to make the solution.
Molecular mass of NaCl = 58.4 g/mol.
Thus mass of 0.0262 moles of NaCl = 0.0262 mol × 58.4 g/mol
= 1.53 g.
Therefore, the mass of NaCl required is 1.53 g.
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A physical chemist measures the temperature inside a vacuum chamber. Here is the result.
T= - 35.903°C
Convert T to SI units.
This is an acronym of the word Systeme International in French. Its International System of Units (SI) is a metric system that would be universally acknowledged as a measurement standard, and the further discussion can be defined as follows:
SI units play an important function in research and innovation in science and technology. In this, the temperature will be measure in the kelvin.Conversion [tex]^{\circ} \ to \ K[/tex]:
let,
[tex]\to 0^{\circ}\ C + 273.15 = 273.15\ K\\\\[/tex]
So,
[tex]\to -35.903+273.15=237.247\ K[/tex]
Therefore, the final answer is "237.247".
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What is the empirical formula of a compound that has a pseudoformula of C3.5H8?
Answer:
The ratio of carbon and hydrogen atoms = 3.5 : 8
= 7 : 16
Then,the empirical formula is C7H16
give one important characteristic of the particles of matter very sort answer give
Answer:
The important characteristics of the particles of matter are – They are very, very small. They have spaces between them. They are constantly moving.
Answer:
They are very very small
When 2.50 moles of oxygen reacts with excess hydrogen gas how many grams of water is
produced?
2 H2 + O2--> 2 H20
Answer:
90grams
Explanation:
The reaction given in this question is as follows:
2H2 + O2 → 2H20
Based on this equation, 1 mole of oxygen gas (O2) produces 2 moles of water (H2O)
Hence, 2.50moles of oxygen gas will react with excess hydrogen gas to produce (2.5 × 2) = 5.0moles of water.
Using mole = mass/molar mass
Molar mass of water (H2O) = 1(2) + 16
= 18g/mol
5 = mass/18
mass = 18 × 5
mass of H2O = 90grams
What is the empirical formula for a compound if 300.00 g of it is known to contain 82.46224 g of molybdenum, 45.741 g of chlorine and the rest is bromine
Answer:
MoClBr₂
Explanation:
First we calculate the mass of bromine in the compound:
300.00 g - (82.46224 g + 45.741 g) = 171.79676 gThen we calculate the number of moles of each element, using their respective molar masses:
82.46224 g Mo ÷ 95.95 g/mol = 0.9594 mol Mo45.741 g Cl ÷ 35.45 g/mol = 1.290 mol Cl171.79676 g Br ÷79.9 g/mol = 2.150 mol BrNow we divide those numbers of moles by the lowest number among them:
0.9594 mol Mo / 0.9594 = 11.290 mol Cl / 0.9594 = 1.34 ≅ 12.150 mol Br / 0.9594 = 2.24 ≅ 2Meaning the empirical formula is MoClBr₂.
Predict the products from reaction of 2-hexyne with the following reagents: (a) 2 equiv Br2 (b) 1 equiv HBr (c) Excess HBr (d) Li in NH3 (e) H2O, H2SO4, HgSO4
Answer:
See explanation and image attached
Explanation:
The reactions of the alkynes involved are shown in the image attached to this answer.
First of all, the reaction of two equivalents of bromine with the alkyne converts it to a saturated compound as shown. One equivalent of HBr converts the alkyne to alkene while excess HBr completely reduces the compound to a saturated compound.
Li/NH3 reduces the alkyne to an alkeneby anti addition to the triple bond.
Reaction of the alkyne with H2O, H2SO4, HgSO4 converts it to an aldehyde as shown.
An atom has 6 protons and 9 neutrons in its nucleus. Calculate the mass number of the atom
Answer:
6+9=15
mass number =15
mass number = no. protons + no. of neutrons
Which event would be impossible to explain by using John Dalton's model of the atom?
Answer:
That is, the atom is a solid and indivisible mass. However, the fenomenom by which an iron atom emits particles when it is struck by light (known as the photoelectric effect) can not be explaind by this indivisible atom model.
When the pH of a solution is 12.83, what is [H +]?
A 7.4 × 10 -12 M
B 9.7 10 -11 M
C 1.5 X 10 -13 M
D 12.8 x 10 -2 M
Answer:
B.9.710-11M
Explanation:
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