Answer:
Explanation:
Can you provide a picture? I can outline the reactions though. a) will make a Z double bond from a triple bond and then peroxyacid can do epoxidation. b) will make the Z double bond then ozonolysis to double bond will create to aldehyde compounds. c) is essentially useless unless there is a ketone or aldehyde in the compound already since H2/Pd will fully reduce the alkyne (which I am assuming is present) and so the peroxyacid can't do epoxidation and can only do baeyer villiger oxidation, and d) reduces the alkyne to an E alkene and then do epoxidation to give an epoxide (with trans steroechemistry)
What is the molality of a glucose solution prepared by dissolving 16.7 g of glucose, C6H12O6, in 133.6 g of water
Answer:
0.696 m
Explanation:
We'll begin by calculating the number of mole in 16.7 g of C₆H₁₂O₆. This can be obtained as follow:
Mass of C₆H₁₂O₆ = 16.7 g
Molar mass of C₆H₁₂O₆ = (6×12) + (12×1) + (6×16)
= 72 + 12 + 96
= 180 g/mol
Mole of C₆H₁₂O₆ =?
Mole = mass / molar mass
Mole of C₆H₁₂O₆ = 16.7 / 180
Mole of C₆H₁₂O₆ = 0.093 mole
Next, we shall convert 133.6 g of water to Kg. This can be obtained as follow:
1000 g = 1 Kg
Therefore,
133.6 g = 133.6 g × 1 Kg / 1000 g
133.6 g = 0.1336 Kg
Thus, 133.6 g is equivalent to 0.1336 Kg.
Finally, we shall determine the molality of the solution. This can be obtained as illustrated below:
Mole of C₆H₁₂O₆ = 0.093 mole
Mass of water = 0.1336 Kg
Molality =?
Molality = mole / mass of water (in Kg)
Molality = 0.093 / 0.1336
Molality = 0.696 m
Therefore, the molality of the solution is 0.696 m
A 12.37 g sample of Mo2O3(s) is converted completely to another molybdenum oxide by adding oxygen. The new oxide has a mass of 13.197 g. Identify the empirical formula of the new oxide
Answer:
MoO2
Explanation:
The empirical formula is defined as the simplest whole number ratio of atoms present in a molecule.
To solve this question we need to find the moles of Mo2O3. Twice these moles = Moles of Mo. With the moles of Mo we can find its mass.
The difference in masses between mass of new oxide and mass of Mo = Mass of oxygen. With the mass of oxygen we can find its moles and the empirical formula as follows:
Moles Mo2O3 -Molar mass: 239.9g/mol-
12.37g * (1mol / 239.9g) = 0.05156 moles Mo2O3 * (2mol Mo / 1mol Mo2O3) = 0.1031 moles of Mo
Mass Mo -95.95g/mol-:
0.1031 moles of Mo * (95.95g/mol) = 9.895g of Mo
Mass oxygen in the oxide:
13.197 - 9.895g = 3.302g Oxygen
Moles oxygen -Molar mass: 16g/mol-:
3.302g Oxygen * (1mol / 16g) = 0.206 moles O
Now, the ratio of moles O / moles Mo is:
0.206 moles O / 0.1031 moles Mo = 2
That means there are 2 moles of O per mole of Mo and the empirical formula of the new oxide is:
MoO2For the titration of 50. mL of 0.10 M ammonia with 0.10 M HCl, calculate the pH. For ammonia, NH3, Kb
Answer:
11.12 → pH
Explanation:
This is a titration of a weak base and a strong acid.
In the first step we did not add any acid, so our solution is totally ammonia.
Equation of neutralization is:
NH₃ + HCl → NH₄Cl
Equilibrium for ammonia is:
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻ Kb = 1.8×10⁻⁵
Initially we have 50 mL . 0.10M = 5 mmoles of ammonia
Our molar concentration is 0.1 M
X amount has reacted.
In the equilibrium we have (0.1 - x) moles of ammonia and we produced x amount of ammonium and hydroxides.
Expression for Kb is : x² / (0.1 - x) = 1.8×10⁻⁵
As Kb is so small, we can avoid the x to solve a quadratic equation.
1.8×10⁻⁵ = x² / 0.1
1.8×10⁻⁵ . 0.1 = x²
1.8×10⁻⁶ = x²
√1.8×10⁻⁶ = x → 1.34×10⁻³
That's the value for [OH⁻] so:
1×10⁻¹⁴ = [OH⁻] . [H⁺]
1×10⁻¹⁴ / 1.34×10⁻³ = [H⁺] → 7.45×10⁻¹²
- log [H⁺] = pH
- log 7.45×10⁻¹² = 11.12 → pH
Tick (√) the statements that are correct.
a) By eating rice alone, we can fulfil nutritional requirement of our body. ( )
b) Deficiency Diseases can be prevented by eating a balanced diet. ( )
c) Balanced diet for the body should contain a variety of food items. ( )
d) Meat alone. is sufficient to provide all nutrients to the body. ( )
b) (√)
c)(✓)
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here is the question
Answer:
1. Nitrate ions, NaNO3 - Sodium nitrate.
2. Sulphide ions, K2S - Potassium sulphide.
3. Sulphate ions, CaSO4 - Calcium sulphate.
4. Hydrogensulphite ions, NaHSO3 - Sodium hydrogensulphite.
5. Carbonate ions, CaCO3 - Calcium carbonate.
6. Hydrogencarbonate ions, KHCO3 - Potassium hydrogencarbonate.
7. Phosphite ions, PH3 - Hydrogen phosphite.
8. Nitride ions, NH3 - Hydrogen nitride ( ammonia ).
9. Ethanoate ions, CH3COONa - Sodium ethanoate.
10. Methanoate ions, HCOONa - Sodium methanoate.
11. Fluoride ions, HF - Hydrogen fluoride.
12. Chloride ions, KCl - Potassium chloride.
13. Bromide ions, HBr - Hydrogen bromide.
14. Iodide ions, NaI - Sodium iodide.
15. Phosphate ions, K3PO3 - potassium phosphate.
The Tollen's test is the reaction of aldehydes with silver(l) ions in basic solution to form silver metal and a carboxylate. 2 Ag+ + + 3 OH- - HR 2 Ag +_ W + 2 H2O ÃR Which species is being oxidized in the reaction? Choose... Which species is being reduced in the reaction? Choose... Which species is the visual indicator of a positive test? v Choose... Carboxylate ion Aldehyde Silver metal Water Silver(1) ion Hydroxide ion
Answer:
Explanation:
When Tollen's test is done by aldehyde , silver ion is converted into silver which forms a layer which looks like a mirror.
Ag⁺ + e = Ag
It is a reduction process where silver(1) ion is reduced to metallic silver.
Aldehyde is oxidized to carboxylate ion.
CH₃CHO + 2 OH⁻ = CH₃COO⁻ + H₂O + H⁺ + 2e
Visual indicator is silver metal which forms silver mirror at the bottom of test tube .
tea contains approximately 2% caffeine by weight. assuming that you started with 18g of tea leaves, calculate your percent yield of extraced caffeine
Determine whether each of the following statements is true or false. If false, correct the statement to make it true: (a) The nucleus has most of the mass and comprises most of the volume of an atom. (b) Every atom of a given element has the same number of protons. (c) The number of electrons in an atom equals the number of neutrons in the atom. (d) The protons in the nucleus of the helium atom are held together by a force called the strong nuclear force.
Answer:
Every atom of a given element has the same number of protons
The protons in the nucleus of the helium atom are held together by a force called the strong nuclear force.
Explanation:
Atoms are composed of electrons, protons and neutrons. The electron is negatively charged, protons are positively charged and the neutrons have no charge.
Electrons are found in shells while protons are found inside the atomic nucleus. Similar to electrostatic forces between electron and proton, protons of helium are held together by a strong nuclear blinding force.
Note that, all isotopes must have the same atomic number. This shows that they are all the same atom changed by differences in number of neutrons.
A gas at 273K temperature has a pressure of 590 MM Hg. What will be the pressure if you change the temperature to 273K? 
Explanation:
here's the answer to your question
The following pairs of soluble solutions can be mixed. In some cases, this leads to the formation of an insoluble precipitate. Decide, in each case, whether or not an insoluble precipitate is formed.
a. K2S and NH4Cl
b. CaCl2 and NH4CO3
c. Li2S and MnBr2
d. Ba(NO3)2 and Ag2SO4
e. RbCO3 and NaCl
Answer:
a) [tex]K_{2} S[/tex] and [tex]NH_{4} Cl[/tex] :
There are no insoluble precipitate forms.
b) [tex]Ca Cl_{2}[/tex] and [tex](NH_{4} )_{2} Co_{3}[/tex] :
There are the insoluble precipitates of [tex]CaCo_{3}[/tex] forms.
c) [tex]Li_{2}S[/tex] and [tex]MnBr_{2}[/tex] :
There are the insoluble precipitates of [tex]MnS[/tex] forms.
d) [tex]Ba(No_{3} )_{2}[/tex] and [tex]Ag_{2} So_{4}[/tex] :
As [tex]Ag_{2} So_{4}[/tex] is insoluble, therefore no precipitate forms.
e) [tex]Rb_{2}Co_{3}[/tex] and [tex]NaCl[/tex]:
There are no insoluble precipitates forms.
Explanation:
a)
Solubility rule suggests:- [tex]K_{2} S[/tex] ⇒ soluble, [tex]NH_{4} Cl[/tex] ⇒ soluble.
KCl ⇒ soluble, [tex](NH_{4})_{2} S[/tex] ⇒ soluble.
There are no insoluble precipitate forms.
b)
Solubility rule suggests:- [tex]Ca Cl_{2}[/tex] ⇒ soluble, [tex](NH_{4} )_{2} Co_{3}[/tex] ⇒ soluble.
[tex]CaCo_{3}[/tex] ⇒ insoluble, [tex]NH_{4} Cl[/tex] ⇒ soluble.
There are the insoluble precipitates of [tex]CaCo_{3}[/tex] forms.
c)
Solubility rule suggests:- [tex]Li_{2}S[/tex] ⇒ soluble, [tex]MnBr_{2}[/tex] ⇒ soluble.
[tex]LiBr[/tex] ⇒ soluble, [tex]MnS[/tex] ⇒ insoluble.
There are the insoluble precipitates of [tex]MnS[/tex] forms.
d)
Solubility rule suggests:- [tex]Ba(No_{3} )_{2}[/tex] ⇒ soluble, [tex]Ag_{2} So_{4}[/tex] ⇒insoluble.
As [tex]Ag_{2} So_{4}[/tex] is insoluble, therefore no precipitate forms.
e)
Solubility rule suggests:- [tex]Rb_{2}Co_{3}[/tex] ⇒ soluble, [tex]NaCl[/tex] ⇒ soluble.
[tex]RbCl[/tex] ⇒ soluble, [tex]Na_{2} Co_{3}[/tex] ⇒ soluble.
There are no insoluble precipitates forms.
Please help thank you
Answer:
[tex]K=1.7x10^{-3}[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to solve this problem by firstly setting up the equilibrium expression for the given reaction, in agreement to the law of mass action:
[tex]K=\frac{[NO]^2}{[N_2][O_2]}[/tex]
Next, we plug in the given concentrations on the data table to obtain:
[tex]K=\frac{(0.034)^2}{(0.69)(0.98)}\\\\K=1.7x10^{-3}[/tex]
Regards!
Chromium-51 is a radioisotope that is used to assess the lifetime of red blood cells The half-life of chromium-51 is 27.7 days. If you begin with 39.7 mg of this isotope, what mass remains after 48.2 days have passed?
Answer:
11.9g remains after 48.2 days
Explanation:
All isotope decay follows the equation:
ln [A] = -kt + ln [A]₀
Where [A] is actual amount of the isotope after time t, k is decay constant and [A]₀ the initial amount of the isotope
We can find k from half-life as follows:
k = ln 2 / Half-Life
k = ln2 / 27.7 days
k = 0.025 days⁻¹
t = 48.2 days
[A] = ?
[A]₀ = 39.7mg
ln [A] = -0.025 days⁻¹*48.2 days + ln [39.7mg]
ln[A] = 2.476
[A] = 11.9g remains after 48.2 days
How do I do this? What are the answers to the 5 questions shown?
Answer:
1. C₃H₆O₃
2. C₆H₁₂
3. C₆H₂₄O₆
4. C₆H₆
5. N₂O₄
Explanation:
1. Determination of the molecular formula.
Empirical formula => CH₂O
Mass of compound = 90 g
Molecular formula =?
Molecular formula = n × Empirical formula = mass of compound
[CH₂O]ₙ = 90
[12 + (2×1) + 16]n = 90
[12 + 2 + 16]n = 90
30n = 90
Divide both side by 30
n = 90/30
n = 3
Molecular formula = [CH₂O]ₙ
Molecular formula = [CH₂O]₃
Molecular formula = C₃H₆O₃
2. Determination of the molecular formula.
Empirical formula => CH₂
Mass of compound = 84 g
Molecular formula =?
Molecular formula = n × Empirical formula = mass of compound
[CH₂]ₙ = 84
[12 + (2×1)]n = 84
[12 + 2]n = 84
14n = 84
Divide both side by 14
n = 84/14
n = 6
Molecular formula = [CH₂]ₙ
Molecular formula = [CH₂]₆
Molecular formula = C₆H₁₂
3. Determination of the molecular formula.
Empirical formula => CH₄O
Mass of compound = 192 g
Molecular formula =?
Molecular formula = n × Empirical formula = mass of compound
[CH₄O]ₙ = 192
[12 + (4×1) + 16]n = 192
[12 + 4 + 16]n = 192
32n = 192
Divide both side by 32
n = 192/32
n = 6
Molecular formula = [CH₄O]ₙ
Molecular formula = [CH₄O]₆
Molecular formula = C₆H₂₄O₆
4. Determination of the molecular formula.
Empirical formula => CH
Mass of compound = 78 g
Molecular formula =?
Molecular formula = n × Empirical formula = mass of compound
[CH]ₙ = 78
[12 + 1]n = 78
13n = 78
Divide both side by 13
n = 78/13
n = 6
Molecular formula = [CH]ₙ
Molecular formula = [CH]₆
Molecular formula = C₆H₆
5. Determination of the molecular formula.
Empirical formula => NO₂
Mass of compound = 92 g
Molecular formula =?
Molecular formula = n × Empirical formula = mass of compound
[NO₂]ₙ = 92
[14 + (2×16)]n = 92
[14 + 32]n = 92
46n = 92
Divide both side by 46
n = 92/46
n = 2
Molecular formula = [NO₂]ₙ
Molecular formula = [NO₂]₂
Molecular formula = N₂O₄
Which of the following would tell you that a weak base is present?
A. If the pH of the solution is close to 14.
B. If the solution is a good conductor of electricity.
C. An indicator added to the solution turns green-blue.
D. If there is a high reaction rate.
Answer:
An indicator added to the solution turns green-blue.
Explanation:
An indicator is a substance which shows the degree of acidity or alkalinity of a solution by change in colour of the solution.
The universal indicator changes colour as the pH of the solution changes. Looking at the colour ranges for the universal indicator, the green-blue colour indicates a weak base.
how many ml of 0.032 molar kmno4 are required to react with 50.0 ml of 0.100 molar h2c2o4 in the presence of excess h2so4
Answer:
62.5 ml of 0.032 M KMnO₄ are required to react with 50.0 ml of 0.100 molar H₂C₂O₄ in the presence of excess H₂SO₄
Explanation:
The balanced reaction is:
2 KMnO₄ + 5 H₂C₂O₄ + 3 H₂SO₄ → K₂SO₄ + 2 MnSO₄ + 8 H₂O + 10 CO₂
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:
KMnO₄: 2 moles H₂C₂O₄: 5 moles H₂SO₄: 3 moles K₂SO₄: 1 mole MnSO₄: 2 moles H₂O: 8 moles CO₂: 10 molesMolarity or Molar Concentration is the number of moles of solute that are dissolved in a certain volume.
The molarity of a solution is calculated by dividing the moles of the solute by the volume of the solution:
[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]
Molarity is expressed in units [tex]\frac{moles}{liter}[/tex]
In this case, 50 mL (0.05 L) of 0.1 M H₂C₂O₄ react. So, replacing the data in the definition of molarity:
[tex]0.1 M=\frac{number of moles of solute}{0.05 L}[/tex]
Solving:
number of moles of solute= 0.1 M*0.05 L
number of moles of solute= 0.005 moles
So, 0.005 moles of H₂C₂O₄ react. Then you can apply the following rule of three: if by stoichiometry 5 moles of H₂C₂O₄ react with 2 moles of KMnO₄, 0.005 moles of H₂C₂O₄ react with how many moles of KMnO₄?
[tex]moles of KMnO_{4} =\frac{0.005moles of H_{2} C_{2} O_{4}* 2moles of KMnO_{4} }{5moles of H_{2} C_{2} O_{4} }[/tex]
moles of KMnO₄= 0.002 moles
Knowing that the molarity of KMnO₄ is 0.032 M, replacing in its definition and solving:
[tex]0.032 M=\frac{0.002 moles}{volume}[/tex]
[tex]volume=\frac{0.002 moles}{0.032 M}[/tex]
volume= 0.0625 L= 62.5 mL
62.5 ml of 0.032 M KMnO₄ are required to react with 50.0 ml of 0.100 molar H₂C₂O₄ in the presence of excess H₂SO₄
Stalactites and stalagmites form as ________ precipitates out of the water evaporating in underground caves.
Stalactites and stalagmites form as ________ precipitates out of the water evaporating in underground caves.
Group of answer choices
hydrochloric acid
sodium bicarbonate
calcium carbonate
sodium chloride
sodium hydroxide
Answer:
calcium carbonate
Explanation:
A stalactite is an icicle-looking mould that is formed by the precipitation of natural minerals as a result of water dripping from the ceiling, hanging from a cave.
A stalagmites in the other hand, grows upwards and is also a mound that is formed by the deposits of minerals gotten by the water dripping on the floor of a cave.
Therefore, stalactites and stalagmites form as calcium carbonate precipitates out of the water evaporating in underground caves.
A calorimeter measures the Choose... involved in reactions or other processes by measuring the Choose... of the materials Choose... the process. The calorimeter is Choose... to prevent transfer of heat to outside the device.
Answer:
heat; temperature; surrounding; insulated.
Explanation:
A calorimeter can be defined as a scientific instrument (device) that is designed and developed for measurement of the heat involved in chemical reactions or other processes, especially by taking the measurement of the temperature of the materials surrounding the process.
Basically, a calorimeter is insulated using materials with a very high level of resistivity, so as to prevent heat transfer to the outside of the device (calorimeter).
Some of the components that make up a simple calorimeter are; thermometer, an interior styrofoam cup, an exterior styrofoam cup, cover, etc.
Additionally, a calorie refers to the amount of heat required to raise the temperature of a gram of water by one degree Celsius (°C)
A calorimeter measures the heat involved in reactions or other processes by measuring the temperature of the materials surrounding the process. The calorimeter is insulated to prevent transfer of heat to outside the device.
What is calorimeter?Calorimeter is an instrument used in chemical reactions for measuring the heat, physical changes as well as heat capacity of the chemical reaction.
From the definition of calorimeter it is clear that it checks the temperature of the reaction and calculates the heat of the chemical reaction. It is insulated by those materials which are bad conductors of heat so that no heat will loss from this apparatus.
Hence, correct options are heat, temperature, surroundings and insulated.
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Kati was in the kitchen when she heard a crash. She went into her bedroom and found her window broken and a baseball lying on the ground. Kati said "this baseball broke my window." This statement is an
Answer: inference because she drew a conclusion based on evidence.
why?:
Because the evidence was that she heard the crashing sound, and then when she came into her room saw the broken window and baseball.
It was not an observation because she did not directly see the baseball going through the window
Melanie has completed the analysis of her data for the reaction of KMnO4 with malonic acid and data for a reaction of KMnO4 with tartaric acid. She compared the activation energies, Ea, she calculated for the two reactions and found the Ea for the malonic acid reaction to be greater than the Ea for the tartaric acid reaction.
Required:
What does this mean about the magnitude of the rate constant, k, and the rate of the reaction?
Answer:
See explanation
Explanation:
The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation;
k= Ae^-Ea/RT
Where;
k= rate constant
A= pre-exponential factor
Ea=activation energy
R= gas constant
T= temperature
We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.
Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
The study of chemistry and bonds is called chemistry. There are two types of elements metal and nonmetals.
The correct answer is mentioned below.
What is the Arrhenius equation?The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equationThe equation is as follows:-
[tex]k= Ae^{-Ea/RT[/tex] Where;
k= rate constantA= pre-exponential factorEa=activation energyR= gas constantT= temperatureWe can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have very high activation energy are markedly slow. Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
Hence, the correct answer is mentioned above.
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A sample of a compound is analyzed and found to contain 0.420 g nitrogen, 0.480g oxygen, 0.540 g carbon and 0.135 g hydrogen. What is the empirical formula of the compound? a. C2H5NO b. CH3NO c. C3H9N2O2 d. C4HN3O4 e. C4H13N3O3
Answer:
c. C3H9N2O2
Explanation:
The empirical formula of a compound is defined as the simplest whole number ratio of atoms present in a molecule. To solve this question we need to convert the mass of each atom to moles. With the moles we can find the ratio as follows:
Moles N -Molar mass: 14.01g/mol-
0.420g N * (1mol/14.01g) = 0.0300 moles N
Moles O -Molar mass: 16g/mol-
0.480g O * (1mol/16g) = 0.0300 moles O
Moles C -Molar mass: 12.01g/mol-
0.540g C * (1mol/12.01g) = 0.0450 moles C
Moles H -Molar mass: 1.0g/mol-
0.135g H * (1mol/1g) = 0.135moles H
Dividing in the moles of N (Lower number of moles) the ratio of atoms is:
N = 0.0300 moles N / 0.0300 moles N = 1
O = 0.0300 moles O / 0.0300 moles N = 1
C = 0.0450 moles C / 0.0300 moles N = 1.5
H = 0.135 moles H / 0.0300 moles N = 4.5
As the empirical formula requires whole numbers, multiplying each ratio twice:
N = 2, O = 2, C = 3 and H = 9
And the empirical formula is:
c. C3H9N2O2
Proteins are:
amino acids.
carbohydrates.
minerals.
sugars.
A major component of gasoline is octane (C8H8). When liquid octane is burned in air it reacts with oxygen (O2) gas to produce "0.050 mol" carbon dioxide gas and water vapor. Calculate the moles of octane needed to produce of carbon dioxide.
Answer:
0.0063 mol
Explanation:
Step 1: Write the balanced combustion equation
C₈H₁₈(l) + 12.5 O₂(g) ⇒ 8 CO₂(g) + 9 H₂O(g)
Step 2: Establish the appropriate molar ratio
According to the balanced equation, the molar ratio of C₈H₁₈ to CO₂ is 1:8.
Step 3: Calculate the number of moles of C₈H₁₈ needed to produce 0.050 moles of CO₂
0.050 mol CO₂ × 1 mol C₈H₁₈/8 mol CO₂ = 0.0063 mol C₈H₁₈
The sanlinity of ocean water
Answer:
35g/l
Explanation:
Salinity is practically the saltiness of the water, in basic terms. It's basically the amount of salt dissolved in water. Ocean water has a salinity of around 35g/l (that's about 3.5% of which is dissolved salt in water!). However, Atlantic Ocean (the ocean with the saltiest water), can range up to 37g/l.
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If the starting material has no stereogenic centers, when carbonyl compounds are reduced with a reagent such as LiAlH4 or NaBH4 and a new stereogenic center is formed, what will the composition of the product mixture be?
A) Forms a racemic mixture of the two possible enantiomers.
B) Forms more of one enantiomer than another because of steric reasons around the carbonyl.
C) Forms more of one enantiomer than another depending on the temperature of the reaction.
D) Forms different products depending on the solvent used.
Answer:
A) Forms a racemic mixture of the two possible enantiomers
When carbonyl compounds are reduced with a reagent such as LiAlH₄ or NaBH₄ and new stereogenic center is formed chemical change will lead to products that form a racemic mixture of the two possible enantiomers.
What is a chemical change?
Chemical changes are defined as changes which occur when a substance combines with another substance to form a new substance.Alternatively, when a substance breaks down or decomposes to give new substances it is also considered to be a chemical change.
There are several characteristics of chemical changes like change in color, change in state , change in odor and change in composition . During chemical change there is also formation of precipitate an insoluble mass of substance or even evolution of gases.
There are three types of chemical changes:
1) inorganic changes
2)organic changes
3) biochemical changes
During chemical changes atoms are rearranged and changes are accompanied by an energy change as new substances are formed.
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A weather balloon contains 9.7 moles of helium at a pressure of 0.955 atm and a temperature of 25 °C at ground level. What is the volume (in L) of the balloon under these conditions?
Answer:
2.5 × 10² L
Explanation:
Step 1: Given and required data
Moles of He (n): 9.7 molPressure (P): 0.955 atmTemperature (T): 25 °CIdeal gas constant (R): 0.0821 atm.L/mol.KStep 2: Convert 25 °C to Kelvin
We will use the following expression.
K = °C + 273.15 = 25 + 273.15 = 298 K
Step 3: Calculate the volume (V) of the balloon
We will use the ideal gas equation.
P × V = n × R × T
V = n × R × T / P
V = 9.7 mol × (0.0821 atm.L/mol.K) × 298 K / 0.955 atm = 2.5 × 10² L
A dehydration reaction starting with 3.0 g cyclohexanol produces 1.9 g cyclohexene. Calculate the theoretical yield for this reaction. Report your answer with two significant figures.
Answer:
77%
Explanation:
First we convert 3.0 g of cyclohexanol (C₆H₁₂O) to moles, using its molar mass:
Molar mass of C₆H₁₂O = 100.158 g/mol3.0 g ÷ 100.158 g/mol = 0.030 molThen we convert 1.9 g of cyclohexene (C₆H₁₀) to moles, using its molar mass:
Molar mass of C₆H₁₀ = 82.143 g/mol1.9 g ÷ 82.143 g/mol = 0.023 molFinally we calculate the theoretical yield:
0.023 mol / 0.030 mol * 100% = 77%Compound X has a molar mass of 266.64 g/mol and the following composition: aluminum 20.24% chlorine 79.76% Write the molecular formula of X
Answer:
Explanation:
Assume we have 100g of this substance. That means we would have 20.24g of Cl and 79.76g of Al. Now we can find how many moles of each we have:
[tex]\frac{79.76 \:g}{35.45 \: g/mol}[/tex] = 2.25 mol of chlorine
[tex]\frac{20.24 \: g}{26.98 \: g/mol}[/tex] = 0.750 mol of Al.
To form a integer ratio, do 2.25/0.75 = 2.99999 ~= 3.
So the ratio is essentially Al : Cl => 1 : 3. To the compound is possibly [tex]AlCl_3[/tex].
However, it says it has a molar mass of 266.64 g/mol, and since AlCl3 has a molar mass of 133.32, it must be [tex]Al_2Cl_6[/tex].
Actually this molecule isn't exactly AlCl3 (which is ionic). Al2Cl6 forms a banana bond where Cl acts as a hapto-2 ligand. But that's a bit advanced. All you need to know is X = Al2Cl6
The molecular formula of the compound is Al₂Cl₆
To solve the question given above, we'll begin by obtaining the empirical formula of the compound. This can be obtained as follow:
Aluminum (Al) = 20.24%
Chlorine (Cl) = 79.76%
Empirical formula =?Al = 20.24%
Cl = 79.76%
Divide by their molar mass
Al = 20.24 / 27 = 0.75
Cl = 79.76 / 35.5 = 2.25
Divide by the smallest
Al = 0.75 / 0.75 = 1
Cl = 2.25 / 0.75 = 3
Thus, the empirical formula of the compound is AlCl₃
Finally, we shall determine the the molecular formula of the compound.
Molar mass of compound = 266.64 g/mol
Empirical formula = AlCl₃
Molecular formula =? Molecular formula = [AlCl₃]ₙ = molar mass of compound[AlCl₃]ₙ = 266.64
[27 + (3×35.5)]n = 266.64
[27 + 106.5]n = 266.64
133.5n = 266.64
Divide both side by 133.5
n = 266.64 / 133.5
n = 2Molecular formula = [AlCl₃]ₙ
Molecular formula = [AlCl₃]₂
Molecular formula = Al₂Cl₆Therefore, the molecular formula of the compound is Al₂Cl₆
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What is the mass of a piece of iron if its density is 1.98 g/mL and its volume is 2.45 mL?
0.80 g
4.858
1.248
5.998
2.71 g
Answer:
4.858 g
Explanation:
Start with the formula
density = [tex]\frac{mass}{volume}[/tex]
density = 1.98 g/mL
volume = 2.45 mL
mass = ??
rearrange the formula to solve for mass
(density) x (volume) = mass
Add in the substitutes and solve for mass
1.98 g/mL x 2.45 mL = 4.858 g
The standard enthalpies of combustion of fumaric acid and maleic acid (to form carbon dioxide and water) are - 1336.0 kJ moJ-1 and - 1359.2 kJ moJ-1, respectively. Calculate the enthalpy of the following isomerization process:
maleic acid ----> fumaric acid
Answer:
Explanation:
maleic acid ⇒ fumaric acid
ΔHreaction = ΔHproduct - ΔHreactant
ΔHproduct = -1336.0 kJ mol⁻¹
ΔHreactant = - 1359.2 kJ mol⁻¹.
ΔHreaction = -1336.0 kJ mol⁻¹ - ( - 1359.2 kJ mol⁻¹.)
= 1359.2 kJ mol⁻¹ -1336.0 kJ mol⁻¹
= 23.2 kJ mol⁻¹ .
Enthalpy of isomerization from maleic to fumaric acid is 23.2 kJ per mol.
Kingsley then adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution. The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO left in solution. Determine the pH of the resulting solution. Which of the following acids would produce the highest pH at the equivalence point in a weak acid-strong base titration?
Ka(HF) =6.8x10-4
Ka(HNO2) =4.5x10-4
Ka(HCIO2) =1.1x10-2
K(CH3COOH) =1.8x10-5
i. HCIO2
ii. CH3COOH
iii. HF
iv. HNO2
Answer:
i. HCIO2 - 2.9
ii. CH3COOH - 2.64
iii. HF - 3.27
iv. HNO2 - 2.67
Explanation:
The Ph value differ for base and acid. A neutral solution will have Ph value of 7. For acid the Ph value is less than 7 and for base Ph value is greater than 7. The highest Ph value for the given acids is 3.27 for hydroflouric acids.
The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.
Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.
The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO⁻ left in the solution.
We have to determine the pH of the resulting solution and identify the acid that would produce the highest pH at the equivalence point in a weak acid-strong base titration.
What is pH?pH, a quantitative measure of the acidity or basicity of aqueous or other liquid solutions.
Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.
Total volume of the solution = 49.28 mL + 250.0 mL = 299.28 mL = 0.29928 L
At neutralization point, HCOOH = 0.098 mol = [tex]\frac{0.098\ mol}{0.29928\ L} = 0.32745\ M[/tex]
So, Concentration of HCOOH at neutralization point = 0.32745 M
And [tex]HCOO^-[/tex] at neutralization point = 0.025 mol = [tex]\frac{0.025\ mol}{0.29928\ L} = 0.08353\ M[/tex]
So, Concentration of HCOO⁻ at neutralization point = 0.08353 M
Now, [tex]K_a[/tex] value of HCOOH = [tex]1.77\times10^{-4}[/tex] (reference value}
We know that [tex]pK_a = -logK_a[/tex]
[tex]pK_a = -log(1.77\times10^{-4}) = 3.75[/tex]
Now, HCOOH is acid and HCOO⁻ is the conjugate base.
According to Henderson Hasselblach equation:
[tex]pH = pK_a + log\frac{[conjugate\ base]}{[acid]}\\ \therefore pH = 3.75 + log\frac{[HCOO^-]}{[HCOOH]}\\pH = 3.75 + log(\frac{0.08353}{0.32745})\\pH = 3.75 +(-0.59)\\pH = 3.16[/tex]
Therefore, the pH of the resulting solution is 3.16.
When weak acid is titrated with a strong base, the pH at the neutralization point is always greater than 7. It is because the conjugate base produced by weak acid in neutralization reaction is comparatively stronger in nature which produces [tex]OH^-[/tex] at neutralization point after reacting with water. so the solution is basic. As a result, pH is more than 7.
Now, the weaker is the acid, the stronger is the conjugate base, and vice-versa. Therefore, the concentration of [tex]OH^-[/tex] ions is more at the neutralization point. So more will be the pH value.
Given acids with the corresponding [tex]K_a[/tex] value are shown below:
[tex]K_a(HF) =6.8\times10^{-4}\\K_a(HNO_2) =4.5\times10^{-4}\\K_a(HClO_2) =1.1\times10^{-2}\\K_a(CH_3COOH) =1.8\times10^{-5}[/tex]
We know that lower the value of [tex]K_a[/tex] of acid, the weaker is the acid and vice-versa. Hence, [tex]CH_3COOH[/tex] has lowest [tex]K_a[/tex] value compared to other acids. Therefore, [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.
Hence, The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.
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