The given statement is a correct explanation of why the fulminate ion is less stable and more reactive than the cyanate ion.
The formal charge can be defined as the difference between the number of valence electrons present in the free atom and the number of valence electrons present in the Lewis structure. A stable molecule has the lowest possible formal charge on each atom in its structure. Use formal charge to explain why the fulminate ion is less stable and therefore more reactive than the cyanate ion. The given statement can be explained as follows: When we analyze the formal charge of the fulminate ion, it becomes clear that the formal charge of the fulminate ion is +1 on nitrogen and -1 on two oxygens.
But when the electronegativity values are compared, nitrogen is found to be more electronegative than carbon, thus structures with a negative formal charge on C are stable and structures with a positive formal charge on N are stable. This means that the given octet rule is not obeyed, which leads to the instability of the fulminate ion. Since formal charge distribution is unfavored, this molecule is less stable and therefore more reactive. The resonance structure of the fulminate ion requires more resonance contributors to stabilize the molecule, and it does not obey the octet rule. Thus, it can be concluded that the fulminate ion is unstable mainly because it needs more resonance contributors and the formal charge distribution is unfavored.
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what happens when zinc chloride reacts with potassium hydroxide and what formed?
Answer:
when the solution of potassium hydroxide and zinc chloride are mixed,the double-displacement reaction occur ,resulting in precipitation and the reaction forms potassium chloride and zinc hydroxide .
Which transition metal can form both a high and low spin complex? Zn2+, Cu2+, Mn3+, Ti2+
Answer: Manganese
Explanation:
With titanium, it only has two d electrons, so it can't form different high and low spin complexes. It doesn't matter because it will never fill the higher-energy orbitals. The total spin state turns out to be +1 (two unpaired d electrons, no matter what). Therefore, manganese will form both a high and low spin complex.
What is the theoretical oxygen for 100 moles of propane undergoing the following combustion reaction? CsHs+502->3CO2+4 H20 O 350 moles O 21 moles O 500 moles O 400 moles
When 100 moles of propane undergo the given combustion reaction, 500 moles of oxygen will be required.
The combustion reaction of propane is given by:C₃H₈ + 5O₂ → 3CO₂ + 4H₂OFor every mole of propane, five moles of oxygen are required to complete the combustion reaction. Therefore, for 100 moles of propane, 500 moles of oxygen will be required.Theoretical oxygen for 100 moles of propane undergoing the combustion reaction is 500 moles of oxygen. Thus, the correct option is (C) 500 moles. The theoretical oxygen required is different from the actual oxygen required, which may vary due to incomplete combustion or other factors that affect the reaction.
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According to the Bronsted-Lowry concept of acids and bases, which of the following statements about a base is NOT true? If a base is strong, then its conjugate acid will be relatively weaker. A base must contain a hydroxide group. A base will share one of its electron pairs to bind H+. A base reacts with an acid to form a salt.
According to the Bronsted-Lowry concept of acids and bases, the statement "If a base is strong, then its conjugate acid will be relatively weaker" is NOT true.
The Bronsted-Lowry concept defines an acid as a proton (H+) donor and a base as a proton acceptor. The strength of an acid or base is determined by the extent to which it is willing to donate or accept a proton. Therefore, when a strong acid donates a proton, the resulting conjugate base is also strong; likewise, when a strong base accepts a proton, the resulting conjugate acid is also strong.
Other characteristics of bases include the presence of a hydroxide group (OH-), and the ability to accept a proton (H+) to form a salt. However, the strength of a base does not necessarily depend on its presence or absence of a hydroxide group.
In conclusion, the Bronsted-Lowry concept of acids and bases states that the strength of a base does not determine the strength of its conjugate acid; therefore, the statement "If a base is strong, then its conjugate acid will be relatively weaker" is NOT true.
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Calculate the buffer ratio (base/acid) required for a buffer of pH = 5.68 that is prepared by mixing sodium hydrogen oxalate and sodium oxalate. A table of pKa values can be found here. Report your answer to 2 significant figures in scientific notation. Calculate the pH (to two decimal places) of the buffer solution after the addition of 7.77 g of sodium hydrogen carbonate (NaHOCOO) to the buffer solution above. Assume 5% approximation is valid and that the volume of solution does not change.
122.5 grams of oxalic add dihydrate (MW = 126.07 g/mole) and disodium oxalate (MW = 133.99 g/mole) were required to prepare this buffer if the total oxalate concentration is 0.115 M.
Weak acids are defined as acids that don't completely dissociate in solution. It can be explained as any acid that is not a strong acid. The strength of a weak acid depends on how much it gets dissociates and the more it dissociates, the stronger the acid. The mass of the weak acid in a solution of a certain pH can be determined by calculating the original concentration of the acid after calculating the concentration of the hydrogen ions with the help of the pH value of the solution.
The Concentration of oxalate ion is 0.115 M.
pKa1 is 1.250.
pKa2 is 4.266.
pH is 5.193.
Molarity = (mass / molar mass) / 1 / volume in liter
The molar mass is 126.07g/mole.
Mass = Molarity × molar mass × Volume in liter
Mass=0.972 M × 126.07 g/mole × 1.00 L
= 122.5 gram
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The complete question is,
A buffer prepared by dissolving oxalic add dihydrate (H2C2O4⋅2H2O) and disodium oxalate (Na2C2O4) in 1.00 L of water has a pH of 5.193. How many grams of oxalic add dihydrate (MW = 126.07 g/mole) and disodium oxalate (MW = 133.99 g/mole) were required to prepare this buffer if the total oxalate concentration is 0.115 M? Oxalic acid has pKa values of 1.250 (pKa1) and 4.266 (pKa2).
What is the amount of pi?
However, it is commonly approximated as 3.14159.
What is an irrational number ?An irrational number is a number that cannot be expressed as a simple fraction or ratio of two integers. It is a non-repeating, non-terminating decimal. Examples of irrational numbers include pi (π), the square root of 2 (√2), and the golden ratio (∅).
What is a termination ?In mathematics, a terminating decimal is a decimal number that has a finite number of digits after the decimal point, i.e., the decimal representation ends in a finite number of zeroes. For example, 0.75, 2.0, and 0.0625 are terminating decimals.
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The principle of polymers. polymers clearly plan an important role in the molecular economy of the cell. for each statement below, state why it is false and change it to a correct description.
a. polymers are assembled from monomers in an extracellular compartment and are transported into the cell when required.
b. polysaccharides are one of the three main macromolecular polymers in the cell. a polysaccharide molecule contains a number of different monomers, which gives rise to millions of polysaccharide sequences.
Polysaccharides are a type of carbohydrate polymer composed of repeating units of monosaccharides. They are not one of the three main types of macromolecular polymers in the cell.
The reason for false statement are as following :-
a. The statement is false because polymers are assembled from monomers within the cell, not in an extracellular compartment. Cells have the ability to synthesize a variety of polymers, including nucleic acids, proteins, and carbohydrates, to perform specific functions within the cell. The assembly of polymers from monomers is an energy-intensive process that requires enzymes and specific conditions, such as the appropriate temperature and pH level. Therefore, the synthesis of polymers typically occurs within the cell.
A correct description would be: Polymers are assembled from monomers within the cell, and the synthesis of polymers is an energy-intensive process that requires enzymes and specific conditions.
b. The statement is false because polysaccharides are not one of the three main macromolecular polymers in the cell. The three main types of macromolecular polymers in the cell are nucleic acids, proteins, and carbohydrates. Polysaccharides are a type of carbohydrate polymer, but they are not one of the three main types of macromolecular polymers. Polysaccharides are composed of repeating units of monosaccharides, which gives rise to a limited number of polysaccharide sequences.
A correct description would be: Polysaccharides are a type of carbohydrate polymer composed of repeating units of monosaccharides. They are not one of the three main types of macromolecular polymers in the cell.
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According to Table F, which substance is least soluble?
NaNO3
BaSO4
KCl
KSO4
FILL IN THE BLANK. Use the Gizmo to find the freezing, melting, and boiling points of water at 5,000 meters (16,404 feet). Write these values below. Freezing point: _______ Melting point: _______ Boiling point: _______
If we use the Gizmo to find the freezing, melting, and boiling points of water at 5,000 meters (16,404 feet) then,
Freezing point: 32 ºF (0ºC)
Melting point: 32 ºF (0ºC)
Boiling point: 203°F (95°C)
The freezing point is defined as the temperature at which a liquid becomes a solid. Increased pressure usually raises the freezing point with the melting point of the solid. The boiling point of a pure substance is defined as the temperature at which the substance transitions from a liquid to the gaseous phase. At the boiling point the vapor pressure of the liquid is equal to the applied pressure on the liquid. The melting point of a substance is defined as the temperature at which the substance changes from a solid to a liquid.
Melting occurs at a single temperature for the pure substances. The normal and average melting point and boiling point of water at 1 atmospheric pressure are 0°C and 100°C respectively. Decreasing the pressure under 1 atm. will lower the boiling point since the external pressure will be lower so it will become equal with the vapor pressure at a lower temperature.
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DNA is said to be the organism's genetic fingerprint. What does it mean? Give one application of this concept
Answer:
DNA is an organism's genetic fingerprint because it contains unique genetic information that determines its development, function, and reproduction. This unique DNA sequence can be used for identification purposes, such as establishing paternity or maternity, identifying suspects in criminal investigations, and identifying remains in forensic investigations. The field of forensic science uses DNA analysis to compare DNA profiles from crime scenes to those of potential suspects, resulting in the conviction of many criminals who would have otherwise gone unpunished.
Write the electronic configuration and draw the orbital diagram for the element: lead (Z=82) State if it is diamagnetic/paramagnetic. Please decide the diamagnetic/paramagnetic property based on the orbital diagram only! (It is okay to use the noble gas in square brackets here)
Answer:
See below.
Explanation:
The atomic number of lead (Pb) is 82, which means it has 82 electrons. The electronic configuration of lead is
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p²
The orbital diagram for the valence electrons of lead (Pb) is
↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
s s p p p p d d
2 1 6 2 6 2 10 10
|||||||||
1 2 3 4 5 6 7 8
The notation ↑↓ represents a pair of electrons with opposite spins.
To determine if lead (Pb) is diamagnetic or paramagnetic, we need to look at whether there are any unpaired electrons. Based on the orbital diagram, we can see that all the electrons in the valence shell are paired, meaning that lead (Pb) is diamagnetic.
A gas is at 35.0°C and 4.50 L. What is the temperature of the gas if the volume is increased to 9.00 L?
A gas is at 35.0°C and 4.50 L. What is the temperature of the gas if the volume is increased to 9.00 L?
65.0°C
343°C
17.5°C
1.16°C
614°C
Answer: 343 Celsius
Explanation:
Gay lussac law
T2=T1V2/V1 Temp must be in Kelvin
T2= 308.15 X 9.00 / 4.50 =616.30 K - 273.15 to get back in celsius
=343.15 C
There are 7.68 × 1025 atoms of phosphorous in how many moles of diphosphorous pentoxide?
Answer:
7.68 x 1025 atoms of phosphorous correspond to 1.06 mole of diphosphorous pentoxide. This can also be written as 1.06 mol of P2O5.
which the following optically active alcohol is treated with hbr, a racemic mixture of alkyl bromides is obtained
(S)-2-butanol will undergo an SN2 reaction with HBr to produce a racemic mixture of alkyl bromides. Here option B is the correct answer.
When optically active alcohol is treated with HBr, the reaction follows an SN1 or SN2 mechanism. In the case of SN1, a carbocation intermediate is formed, and in SN2, a backside attack by the nucleophile occurs. The stereochemistry of the product depends on the configuration of the intermediate and the direction of attack.
In the case of (S)-2-butanol, the hydroxyl group is attached to the second carbon atom, which makes it a primary alcohol. When treated with HBr, it undergoes an SN2 reaction, where the hydroxyl group is replaced by the bromine atom. The nucleophile attacks from the backside of the molecule, leading to an inversion of configuration.
This results in the formation of a racemic mixture of alkyl bromides, as both enantiomers have an equal chance of being attacked from either side. On the other hand, (R)-2-butanol, being the enantiomer of (S)-2-butanol, will also undergo the same reaction and produce the same racemic mixture of alkyl bromides.
In the case of (R)-1-phenyl ethanol and (S)-1-phenyl ethanol, they are secondary alcohols and can undergo either SN1 or SN2 reactions depending on the reaction conditions. However, the reaction mechanism will lead to the formation of a mixture of diastereomers, rather than a racemic mixture of enantiomers.
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Complete question:
Which of the following optically active alcohols, when treated with HBr, results in a racemic mixture of alkyl bromides?
a) (R)-2-butanol
b) (S)-2-butanol
c) (R)-1-phenyl ethanol
d) (S)-1-phenyl ethanol
How many atoms of lithium are in 18.7 g?
The atoms of lithium that are in 18.7 g is 16 × 10²³ atoms . This is taken out by mole concept .
What is mole concept ?The mole is a unit of measurement similar to the pair, dozen, gross, and so on. It provides a precise count of the atoms or molecules in a bulk sample of matter. A mole is the amount of substance that contains the same number of discrete entities (atoms, molecules, ions, etc.)
if 7 grams of lithium contain 6 × 10²³ atoms
then 18.7 will contain 16 × 10²³ atoms
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It is advantageous for a predator to prey exclusively on a single prey species
Answer: It is not necessarily advantageous for a predator to prey exclusively on a single prey species, as this can limit their options and make them vulnerable if the population of that prey species declines or becomes extinct. Predators that are more flexible and able to switch between different prey species may be better equipped to survive and thrive in changing environments.
However, there are some advantages to specializing in a single prey species. For example, a predator that is well adapted to hunting a particular prey species may be more efficient and successful at capturing and consuming that prey, which could provide a reliable source of energy. Additionally, if the predator and prey have co-evolved, the predator may have adaptations that specifically allow it to exploit the weaknesses or vulnerabilities of its prey, giving it an advantage over predators that are less specialized.
To a beaker weighing 263.2 g, you add 87.10 g of water and 0.549 g of sugar. Determine the combined
mass of the beaker, water and sugar (in grams).
Answer: 350.849 g
Explanation:
The question is asking the masses of water, sugar, and the beaker to be added together. So, it can be understood that we need to add all of the masses up as follows to get the combined mass:
263.2 g + 87.10 g + 0.549 g = 350.849 g
From this, we can determine that the combined mass of the beaker, water, and sugar (in grams) is 350.849 g.
A student sets up a titration with a * 1 point buret filled with 0.5 M NaOH. In the flask below they place the phenolphthalein indicator and 6.2 mL of the unknown acid. The solution in the beaker turns pink after exactly 24.8 mL of NaOH have been added. Find the exact concentration of the unknown acid.
Which equation is a correctly written thermochemical equation?
OC3H8 (g) +502 (g) → 3CO2 (g) + 4H₂O (1), AH= -2,220 kJ/mol
OFe (s) + O2 (g) → Fe₂O3 (s), AH= -3,926 kJ
ONH₂Cl → NH₂ + + Cl
O2C8H18 + 250216CO2 + 18H₂O, AH=-5,471 kJ/mol
Answer:
The correctly written thermochemical equation is:
C3H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2O (l), ΔH = -2,220 kJ/mol
This equation represents the combustion of propane (C3H8) in the presence of oxygen (O2) to produce carbon dioxide (CO2) and water (H2O), with a heat release of -2,220 kJ/mol. The state symbols (g) for gases and (l) for liquids indicate the physical state of each substance at standard conditions.
Explanation:
ABOVE
Chemistry Help Please! It's worth a lot of points
1.Write the equilibrium expression for the following reactions
a. H2SO4(aq) + H2O(L) ⇆ HSO4-(aq) + H3O+(aq)
b. 4NH3(g) + 5O2(g) ⇆ 4NO(g) + 6H2O(g)
c. NH4Cl(s) ⇆ NH3(g) + HCl(g)
d. N2O4(g) ⇆ 2NO2(g)
2. The following reaction has a K value of 0.050. What does that mean about the concentrations of the reactants as compared to the products? Be specific in your answer.
N2(g) + 3H2(g) ⇆ 2NH3(g)
3. The following reaction has a K value of 6.8 x 103. What does that mean about the concentrations of the reactants as compared to the products? Be specific in your answer.
2SO3(g) ⇆ 2SO2(g) + O2(g)
4. When dissolving substances in water, the degree of solubility of a substance is often represented as the solubility product constant (Ksp). The solubility product constant is the same thing as the equilibrium constant for the dissolving reaction. Two substances that dissociate in water are shown below alone with the Ksp.
NaCl(s) ⇆ Na+(aq) + Cl-(aq) Ksp = 36
BaSO4(s) ⇆ Ba2+(aq) + SO42-(aq) Ksp = 1.1 x 10-16
5. Identify and label the Brønsted-Lowry acid, its conjugate base, the Brønsted-Lowry base, and its conjugate acid in each of the following equations:
a. HNO3 + H2O ⟶ H3O+ + NO3−
b. CN− + H2O ⟶ HCN + OH−
c. H2SO4 + Cl− ⟶ HCl + HSO4−
d. HSO4− + OH− ⟶ SO42− + H2O
e. O2− + H2O ⟶2OH−
6. What is the conjugate acid of each of the following? What is the conjugate base of each of the following?
a. OH-
b. H2O
c. HCO3-
d. NH3
e. HSO4-
7. The following acids are shown with their equilibrium constants (also known as the acid dissociation constant). Rank these acids from strongest to weakest. Explain your ranking.
HCN(aq) + H2O(L) ⇆ H3O+(aq) + CN-(aq) K = 6.2 x 10-10
HC2H3O2(aq) + H2O(L) ⇆ H3O+(aq) + C2H3O-(aq) K = 1.75 x 10-5
H2CO3(aq) + H2O(L) ⇆ H3O+(aq) + HCO3-(aq) K = 4.5 x 10-7
HIO4(aq) + H2O(L) ⇆ H3O+(aq) + IO4-(aq) K = 2.3 x 10-2
8. Calculate the pH and the pOH of each of the following solutions.
a. 0.200 M HCl
b. 0.0143 M NaOH
c. 3.0 M HNO3
d. 0.0031 M Ca(OH)2
9. Wine has a pH of 3.6. What are the hydronium and hydroxide ion concentrations?
10. The hydroxide ion concentration in household ammonia is 3.2 x 10-3 M. What is the concentration of hydronium ions?
Answer:
1. Equilibrium expressions:
a. K = [HSO4-][H3O+]/[H2SO4][H2O]
b. K = [NO]^4[H2O]^6/[NH3]^4[O2]^5
c. K = [NH3][HCl]/[NH4Cl]
d. K = [NO2]^2/[N2O4]
2. Since K = 0.050, the concentrations of the reactants (N2 and H2) are larger than the concentrations of the products (NH3).
3. Since K = 6.8 x 10^3, the concentrations of the products (SO2 and O2) are larger than the concentrations of the reactant (SO3).
4. The Ksp expression for each of the reactions is:
a. Ksp = [Na+][Cl-]
b. Ksp = [Ba2+][SO42-]
5. Brønsted-Lowry acids and bases:
a. Acid: HNO3; Conjugate base: NO3-; Base: H2O; Conjugate acid: H3O+
b. Acid: HCN; Conjugate base: CN-; Base: H2O; Conjugate acid: HCN
c. Acid: H2SO4; Conjugate base: HSO4-; Base: Cl-; Conjugate acid: HCl
d. Acid: NH3; Conjugate base: NH2-; Base: H2O; Conjugate acid: NH4+
e. Acid: H2O; Conjugate base: OH-; Base: O2-; Conjugate acid: OH-
6. Conjugate acids and bases:
a. Acid: H2O; Conjugate base: OH-
b. Acid: H3O+; Conjugate base: H2O
c. Acid: H2CO3; Conjugate base: HCO3-
d. Acid: NH4+; Conjugate base: NH3
e. Acid: HSO4-; Conjugate base: SO42-
7. The strongest acid is HIO4 (highest K value), followed by HCN, HC2H3O2, and H2CO3 (lowest K value). The K values represent the degree to which the acids dissociate in solution. HIO4 is a strong acid, meaning it dissociates almost completely in solution, while H2CO3 is a weak acid, meaning it only dissociates partially.
8. pH and pOH calculations:
a. pH = -log[H3O+] = -log(0.200) = 0.699; pOH = -log[OH-] = -log(1.0 x 10^-14/0.200) = 12.301
b. pOH = -log[OH-] = -log(0.0143) = 1.844; pH = 14.000 - pOH = 12.156
c. pH = -log[H3O+] = -log(3.0) = 0.522; pOH = 13.478
d. pOH = -log[OH-] = -log(0.0062) = 2.206; pH = 14.000 - pOH = 11.794
9. Hydronium and hydroxide ion concentrations:
pH = 3.6; hydronium ion concentration = 10^-pH = 3.98 x 10^-4 M; hydro
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______ is produced anytime current flows in a circuit, due to the collision between the flowing free electrons and the fixed atoms.
Heat is produced anytime current flows in a circuit, due to the collision between the flowing free electrons and the fixed atoms. When an electric current flows through a conductor, the free electrons move through the lattice of atoms.
As they move, they collide with the fixed atoms, causing the atoms to vibrate and transfer energy to neighboring atoms. This energy transfer increases the temperature of the conductor, resulting in the production of heat.
The amount of heat produced is directly proportional to the amount of current flowing through the conductor, the resistance of the conductor, and the time for which the current flows. This relationship is described by Joule's law, which states that the heat produced is equal to the product of the current, the resistance, and the time.
Mathematically, this can be expressed as H = I^2RT, where H is the heat produced, I is the current, R is the resistance, and T is the time. The collision between the flowing free electrons and the fixed atoms in a conductor leads to the production of heat, which is proportional to the current, resistance, and time for which the current flows.
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in 5 or more sentences why being able to reproduce scientific results is an important component of scientific research
Answer:
1. Reproducibility helps confirm the accuracy of research results.
2. It allows for further investigation of the same topic in different contexts.
3. Reproducibility provides assurance that the methods used were reliable.
4. It allows other researchers to build on the original research and expand upon it.
5. It allows for verification of the results and eliminates the possibility of data manipulation.
6. It helps make sure that the results are consistent and valid.
7. It enables more comprehensive understanding of the research topic.
8. It allows for the development of new theories and hypotheses based on the findings.
4. An aqueous solution contains NaNO and KBr The bromide ion is precipitated as AgBr by addition of AgNO. After an excess of the precipitating reagent has been added, a. what is the charge on the surface of the coagulated colloidal particles? b. what is the source of the charge? c. what ions make up the counter-ion layer?
The charge on the surface of the coagulated colloidal particles is negative.
The source of the charge is likely due to the dissociation of the sodium and potassium salts in water, which results in the formation of ions.
The counter-ion layer is composed of the cations that balance the charge on the negatively charged colloidal particles.
What is a Charge?Charge is a fundamental property of matter that describes the amount of electrical energy present in a particle, atom, or molecule. It is a property that can be either positive or negative and is measured in units of coulombs (C).
The charge of a particle can affect how it interacts with other charged particles. For example, particles with opposite charges are attracted to each other, while particles with the same charge repel each other. The interaction between charged particles is fundamental to many chemical and physical phenomena, such as electrostatic interactions, chemical bonding, and the behavior of electrical currents.
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Given that 4 NH3 + 5 O2 → 4 NO + 6 H2O, if 3.00 mol NH3 were made to react with excess of oxygen gas, the amount of H2O formed would be
Which statement below correctly describes their relative atomic radii and first ionization energy when comparing Se and Br? The atomic radius for Se is larger than Br, and the first ionization energy for Se is greater than Br. The atomic radius for Br is larger than Se, and the first ionization energy for Bris greater than Se. The atomic radius for Se is larger than Br, and the first ionization energy for Br is greater than Se. The atomic radius for Br is larger than Se, and the first ionization energy for Se is greater than Br.
At has a higher initial ionisation energy than Br, while Br has a bigger atomic radius. Se has a bigger atomic radius than Br, and Br has a higher initial ionisation energy than Se.
How do atomic radii and ionisation energy relate to one another (i.e., what happens to ionisation energy as atomic radii grow)?The most loosely bound electron is further from the nucleus and thus easier to remove in bigger atoms. Hence, the ionisation energy should decrease as size (atomic radius) increases.
Why does ionisation energy rise across a period while decreasing down a group?This is because the outer electrons aren't bound as strongly because they are farther from the nucleus.
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Some metalloids are liquids at room temperature.
TRUE
FALSE
Answer:
Some metalloids are liquids at room temperature.
FALSEThey are all solid at room temperature.
Explanation:
You're welcome.
Carbenes can add to alkenes to give a cyclopropane deriverative. Draw the alkene (unknown X) that reacts with the carbene to give the following product. Be sure to clearly indicate the stereochemistry of the alkene by drawing all bonds at the sp2 carbons.
The product of the addition of the carbene to the unknown alkene X is a cyclopropane derivative, with the same stereochemistry as the alkene X.
Carbenes are molecules containing a carbon atom with two non-bonding electrons and a triple bond, and can add to alkenes to give a cyclopropane derivative. The alkene (unknown X) that reacts with the carbene to give the following product is shown in the following diagram. Note that the two sp2 carbons on either side of the double bond are stereochemically distinct, with one carbon pointed "up" and the other pointed "down".
When the carbene adds to the double bond, a three-membered ring forms. This three-membered ring adopts a chair conformation, and the alkene stereochemistry is maintained in the product.
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Predict the principal organic product of the following reaction. Specify stereochemistry where appropriate.
The major organic product of an SN2 substitution reaction is an alkene, which may be either in retention or inversion of configuration relative to the original substrate.
The reaction you are asking about is an SN2 substitution reaction, in which a nucleophile (Nu) displaces a leaving group (LG) from a molecule with an alkyl halide substrate. The major organic product of this reaction will be an alkene, which has the same carbon chain as the alkyl halide substrate. Depending on the relative configuration of the substrate, the alkene product may be the same as the original substrate (retention) or have its configuration inverted (inversion). If stereochemistry is relevant to the question, then it should be specified in the answer.
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A 106 mL solution of a dilute acid is added to 157 mL of a base solution in a coffee-cup calorimeter. The temperature of the solution increases from 22.94 oC to 27.29 oC. Assuming the mixture has the same specific heat (4.184J/goC) and density (1.00 g/cm3) as water, calculate the heat (in J) transferred to the surroundings, qsurr.
Answer:
4897 J
Explanation:
The heat transferred to the surroundings, q_surr, can be calculated using the equation:
q_surr = -q_rxn = -CmΔT
where C is the specific heat capacity of the mixture (assumed to be the same as water, 4.184 J/g°C), m is the mass of the mixture (which we can calculate using the density, assuming that the volumes are additive), and ΔT is the change in temperature (in Celsius).
First, let's calculate the mass of the mixture:
density of water = 1.00 g/cm^3
volume of mixture = volume of acid + volume of base = 106 mL + 157 mL = 263 mL = 0.263 L
mass of mixture = density of water x volume of mixture = 1.00 g/cm^3 x 0.263 L = 263 g
Next, let's calculate the change in temperature:
ΔT = final temperature - initial temperature = 27.29°C - 22.94°C = 4.35°C
Now we can calculate the heat transferred to the surroundings:
q_surr = -CmΔT
q_surr = -(4.184 J/g°C) x (263 g) x (4.35°C)
q_surr = -4897 J
Note that the negative sign indicates that heat is lost by the system to the surroundings. Therefore, the heat transferred to the surroundings, q_surr, is 4897 J.
What is the bond angle of carbonothioyl dibromide
Also what is the molecular shape
Answer:
Carbonothioyl dibromide, also known as CBr2S, has a bond angle of approximately 109.5 degrees, which is the typical tetrahedral bond angle for molecules with sp3 hybridization.
The molecular shape of CBr2S is also tetrahedral, with the two bromine atoms and the sulfur atom arranged at the corners of a tetrahedron, and the carbon atom at the center.
