To solve the ultraviolet catastrophe, Planck applied quantization to: Select the correct answer below:
A. vibrational energies of atoms
B. orbital energies of electrons
C. kinetic energies of photons
D. temperature of the system

Answer:

Partial pressures:

PCl₅ = 0.558 atm

PCl₃ = 0.22 atm

Cl₂ = 0.22 atm

Explanation:

From the given information:

The number of moles of PCl₅ associated with the evaporation is:

[tex]n_{PCl_5}= \dfrac {weight \ of \ PCl_5} {M.Wt. \ of \ PCl_5}[/tex]

[tex]n_{PCl_5}= \dfrac {2.69 \ g} {208.5 \ g/mol}[/tex]

[tex]n_{PCl_5}= 0.013 \ mol[/tex]

Temperature of the gas = 250° C = (250 + 273.15) K

= 523.15 K

Using the Ideal gas equation to determine the pressure exerted by the completely vaporized PCl₅

PV = nRT

[tex]P = \dfrac{nRT}{V}[/tex]

[tex]P = \dfrac{0.0013 \ mol \times 0.082 \ Latm^0 K^{-1} . mol ^{-1} \times 523.15 \ K}{1.0 \ L}[/tex]

P = 0.558 atm

Thus, at  250° C, decomposition of PCl₅ occurs.

In the container, PCl₅  decomposes to PCl₃ and Cl₂.

i.e.

[tex]PCl_{5(g)} \to PCl_{3(g)}+ Cl_{2(g)}[/tex]

Using Dalton's Law:

[tex]P_{total } =P_1 + P_2+P_3 +...[/tex]

[tex]P_1 = P_{Total} \times X_1[/tex]

where;

X = mole fraction

Then, the total no. of moles in the container is:

[tex]n = \dfrac{PV} {RT}[/tex]

[tex]n = \dfrac{1\ atm \times 1.0\ L}{0.0821 \ L \ atm \ K^{-1}.mol \times 523.15\ K}[/tex]

n = 0.023 mol

Now, the container contains a total amount of 0.023 mol where initially 0.013 mol are that of PCl₅ and remaining 0.005 mol of PCl₃ and 0.005 mol of Cl₂.

Thus, the partial pressure of  PCl₃  is:

[tex]P__{PCL_3} }= P_{total} \times \dfrac{no. \ of \ moles \ of PCl_5}{total \ no. \ of \ moles}[/tex]

[tex]P__{PCL_3}} = 1 \ atm \times \dfrac{0.005}{0.023}[/tex]

[tex]P__{PCL_3}} = 0.22 \ atm[/tex]

Thus, since the no of moles of PCl₃ and Cl₂ are the same, then the partial pressure for Cl₂ is = 0.22 atm

Answer:

25.8 g/dL

Explanation:

A chemist prepares a solution of aluminum sulfate by weighing out 116.0 g of aluminum sulfate into a 450. mL volumetric flask and filling the flask to the mark with water. Calculate the concentration in g/dL of the chemist's aluminum sulfate solution. Be sure your answer has the correct number of significant digits.

Step 1: Given data

Step 2: Convert "V" to dL

We will use the following conversion factors.

450. mL × 1 L/1000 mL × 10 dL/1 L = 4.50 dL

Step 3: Calculate the concentration (C) of aluminum sulfate if g/dL

We will use the following expression.

C = m/V = 116.0 g/4.50 dL = 25.8 g/dL

Answer:

[tex]10\, {\rm Fe}\rm SO_4 + 2\, \rm K {Mn} O_4 + 8\, H_2SO_4\\ \to 5\, {Fe} (SO_4)_3 + K_2SO_4 + 2\, {Mn}SO_4 + 8\, H_2O[/tex].

Explanation:

Identify the elements with oxidation state changes:

Oxidation states of iron, [tex]\rm Fe[/tex]:

Oxidation state of manganese, [tex]\rm Mn[/tex]:

The change in the oxidation state of [tex]\rm Mn[/tex] is five times the opposite of the change to the oxidation state of [tex]\rm Fe[/tex]. If there are one mole of [tex]\rm Mn\![/tex] atoms in each mole of this reaction, there would be five times as many [tex]\rm Fe\![/tex] atoms per mole reaction. In other words:

[tex]\displaystyle 5\, \overset{+2}{\rm Fe}\rm SO_4 + 1\, \rm K \overset{+7}{Mn} O_4 + ?\, H_2SO_4\\ \to \frac{5}{2}\, \overset{+3}{Fe} (SO_4)_3 + ?\, K_2SO_4 + 1\, \overset{+2}{Mn}SO_4 + ?\, H_2O[/tex].

(Notice that each mole of this reaction would include five times as many [tex]\rm Fe[/tex] atoms as [tex]\rm Mn[/tex] atoms.)

Multiply the coefficients by [tex]2[/tex] to eliminate the fraction:

[tex]\displaystyle 10\, {\rm Fe}\rm SO_4 + 2\, \rm K {Mn} O_4 + ?\, H_2SO_4\\ \to 5\, {Fe} (SO_4)_3 + ?\, K_2SO_4 + 2\, {Mn}SO_4 + ?\, H_2O[/tex].

Find the unknown coefficients using the conservation of atoms.

Reactants:

Therefore, among the products:

[tex]\displaystyle 10\, {\rm Fe}\rm SO_4 + 2\, \rm K {Mn} O_4 + ?\, H_2SO_4\\ \to 5\, {Fe} (SO_4)_3 + {1}\, K_2SO_4 + 2\, {Mn}SO_4 + ?\, H_2O[/tex].

Products:

Reactants:

[tex]\displaystyle 10\, {\rm Fe}\rm SO_4 + 2\, \rm K {Mn} O_4 + 8\, H_2SO_4\\ \to 5\, {Fe} (SO_4)_3 + {1}\, K_2SO_4 + 2\, {Mn}SO_4 + ?\, H_2O[/tex].

Products:

Therefore, among the products:

[tex]\displaystyle 10\, {\rm Fe}\rm SO_4 + 2\, \rm K {Mn} O_4 + 8\, H_2SO_4\\ \to 5\, {Fe} (SO_4)_3 + {1}\, K_2SO_4 + 2\, {Mn}SO_4 + 8\, H_2O[/tex].

Answer:

e. I, At

Explanation:

Hello!

In this case, since the periodic trends of a series of elements belonging to the same group towards physical and chemical properties tend to be the same when closer in period, we notice that Mg and Al, Br and Kr and As and Br are close but in period, not in the same group; therefore e. I, At, iodine and astatine, are going to tend to exhibit the greatest similarity in their physical  and chemical properties.

Best regards!

Answer:

c

Explanation:

ok than not c than b maybe

Answer:

See explanation

Explanation:

The valence electrons are electrons found on the valence (outermost) shell of an atom.

When an atoms form compounds, there is an exchange of valence electrons between the atoms of one element and the atoms of another element.

Let us consider a typical example, sodium has one valence electron and chlorine has seven valence electrons. This means that chlorine needs one electron to complete its octet while sodium needs to release one electron in order to attain the octet structure.

So, sodium gives out its one electron and becomes a stable sodium ion and chlorine accepts that electron and becomes a stable chloride ion. This is how the compound sodium chloride is formed.

Answer:

Lead

Explanation:

The subatomic particles within an atom can be used to know the atom or element given.

Of particular interest is the number of protons within the atom.

The periodic table is based on the atomic number of atoms. This atomic number is the number of protons within an atomic space.

So; If we know the number of protons within an atom, we can know the element.

The number of protons given is 82, the element is  therefore lead.

Answer:

The atomic number of polonium is 84. The atomic number lead is 82.

Explanation:

Answer:

hello your question is incomplete attached below is the complete question

answer :

we use Isomerization because conjugated allylic carbocation  is more stable when compared to a Non-conjugated Allylic carbocation

Explanation:

Reason for the mechanism

we use Isomerization because conjugated allylic carbocation  is more stable when compared to a Non-conjugated Allylic carbocation

attached below is the detailed mechanism

Answer:

0.696 atoms of oxygen

Explanation:

We'll begin by calculating the number of mole in 50 g of scheelite CaWO₄. This can be obtained as follow:

Mass of CaWO₄ = 50 g

Molar mass of CaWO₄ = 40 + 184 + (4×16)

= 40 + 184 + 64

= 288 g/mol

Mole of CaWO₄ =?

Mole = mass / Molar mass

Mole of CaWO₄ = 50 / 288

Mole of CaWO₄ = 0.174 mole

Finally, we shall determine the number of oxygen atom in 50 g (i.e 0.174 mole) of CaWO₄. This can be obtained as follow:

1 mole of CaWO₄ contains 4 atoms of oxygen.

Therefore, 0.174 mole of CaWO₄ will contain = 0.696 atoms of oxygen.

Thus, 50 g (i.e 0.174 mole) of CaWO₄ contains 0.696 atoms of oxygen.

Answer:

B

Explanation:

Answer:

% Free space in water = [tex]\frac{9.945* 10^{-7} }{1*10^{-6} }[/tex]×100 = 99.45%

% Free space in ice  = [tex]\frac{9.98* 10^{-7} }{1*10^{-6} }[/tex]×100 = 99.8%

Explanation:

As given ,

Density for ice at 0⁰C = 0.917 g/ml

Density for water at 0⁰C = 0.999 g/ml

Radii of H atoms = 37 pm

Radii of O atoms = 66 pm

Now,

Consider 1 ml of water = 1 cm²

As , we know that mass of water in 1 cm² = 0.999 g

Moles of water = [tex]\frac{0.999}{18} = 0.056[/tex]

Volume of H₂O = 1.624×[tex]10^{-31}[/tex] m²

Now,

Volume occupied by water = 0.056×6.022×[tex]10^{23}[/tex]× 1.624×[tex]10^{-31}[/tex] m²

                                              = 5.48×[tex]10^{-9}[/tex] m²

⇒Volume occupied by water = 5.48×[tex]10^{-9}[/tex] m²

Now,

Free space = 1×[tex]10^{-6}[/tex]  - 5.48×[tex]10^{-9}[/tex] = 9.95×[tex]10^{-7}[/tex] m²

% Free space = [tex]\frac{9.945* 10^{-7} }{1*10^{-6} }[/tex]×100 = 99.45%

Now,

Consider 1 ml of ice  = 1 cm²

S.I unit of ice = 1×[tex]10^{-6}[/tex] m²

As , we know that mass of water in 1×[tex]10^{-6}[/tex] m² = 0.917 g

Moles of ice = [tex]\frac{0.917}{18} = 0.012[/tex]

Volume of H₂O = 6.022×[tex]10^{23}[/tex] ×0.012

Volume of ice unit = [tex]\frac{4}{3} \pi (37*10^{-12})^{3} *2 + \frac{4}{3} \pi (66*10^{-12})^{3} = 1.624*10^{-31}m^{3}[/tex]

Now,

Volume occupied by water = 0.012×6.022×[tex]10^{23}[/tex]× 1.624×[tex]10^{-31}[/tex] m²

                                              = 1.17×[tex]10^{-9}[/tex] m²

⇒Volume occupied by water = 1.17×[tex]10^{-9}[/tex] m²

Now,

Free space = 1×[tex]10^{-6}[/tex]  - 1.17×[tex]10^{-9}[/tex] = 9.98×[tex]10^{-7}[/tex] m²

% Free space = [tex]\frac{9.98* 10^{-7} }{1*10^{-6} }[/tex]×100 = 99.8%

Answer:

1.51×10²³ atoms.

Explanation:

From the question given above, the following data were obtained:

Mass of Calcium (Ca = 10 g

Number of atom of Calcium (Ca) =?

The number of atoms present in 10 g of Ca be obtained as follow:

From Avogadro's hypothesis, we understood that 1 mole of any substance contains 6.02×10²³ atoms. This implies that 1 mole Ca contains 6.02×10²³ atoms.

1 mole of Ca = 40 g.

Now, if 40 g of Ca contains 6.02×10²³ atoms.

Therefore, 10 g of Ca will contain = (10 × 6.02×10²³) / 40 = 1.51×10²³ atoms.

Thus, 10 g of calcium contains 1.51×10²³ atoms.

Answer: 7.77 g/ml

Explanation:

Volume of cylinder with only water = 3.28 mL

Volume of cylinder with water and metal = 8.72 mL

Volume of metal = (Volume of cylinder with water and metal ) -(Volume of cylinder with only water)

=8.72-3.28

=5.44 ml

Mass of metal = 42.26 g

Formula of Density =  [tex]\dfrac{\text{Mass}}{\text{Volume}}[/tex]

i.e. the density of the metal = [tex]\dfrac{42.26}{5.44}\approx7.77\text{ g/ml}[/tex]

Hence, the density of metal = 7.77 g/ml

Answer:

See explanation below

Explanation:

First, let's write the reaction:

NH₄SH(s)   <------> H₂S(g) + NH₃(g)

The reaction is already balanced so we don't need to do anything else.

Second, let's take into account the following. The Kc expression for this reaction, only compounds in gaseous state are the only ones that contribute to the equilibrium. Solid and liquid do not contribute to the Kc expression. This is because solid and liquid have a constant concentration near to 1, so, it won't do any difference.

Knowing this, the Kc expression for this reaction is:

Kc = [H₂S] [NH₃]

Now, to calculate Kp from Kc, there's an expression that helps a lot to do this. The expression is the following:

Kp = Kc (RT)ᵃⁿ    (1)

Where:

R: universal constant of gases

T: Temperature in K

ᵃⁿ = difference of the coefficients of the reaction.

This expression comes from the fact that Kp is an expression that instead of working with concentrations, it works with pressure.

If we use the ideal gas equation we have:

PV = nRT

Solving for P:

P = nRT/V        and C = n/V   so

P = CRT

If we now replace this, in the Kp expression of equilibrium we have:

Kp = pH₂S * pNH₃

Kp = ([H₂S]RT)¹ ([NH₃]RT)¹

Kp = (RT)¹⁺¹ ([H₂S] [NH₃])

Kp = (RT)²Kc

So finally the expression for Kp would be:

Hope this helps

Answer:

60.0mL of the diluted solution are needed

6.00mL of the 1.00M NaOH stock solution is the minimum volume needed to prepare the diluted solution.

Explanation:

As in each titration we need to use 20.0mL of the diluted 0.100M solution. As there are 3 titration, the volume must be:

3 * 20.0mL = 60.0mL of the diluted solution are needed

Now, to prepare a 0.100M NaOH solution from a 1.00M NaOH stock solution the dilution must be of:

1.00M / 0.100M = 10 times must be diluted the solution.

As we need at least 60.0mL, the minimum volume of the stock solution must be:

60.0mL / 10 times =

Answer:

In the 5th cycle rinse, the residual concentration of the solution is < 0.00001M

Explanation:

In each rinse cycle, the dilution that you are doing of the solution is from 1.00mL to 10.00mL, that is a dilution of 10

In the first rinse the concentration must be of 0.9M  10 = 0.09M

2nd = 0.009M

3rd = 0.0009M

4th = 0.00009M

5th = 0.000009M →

Answer:

[tex]\%N=26.2\%\\\\\%H=7.5\%\\\\\%Cl=66.3\%[/tex]

Explanation:

Hello!

In this case, since the calculation of the percent composition of an element in a chemical compound is computing considering its atomic mass, subscript in the formula and molecular mass of the compound it is; for nitrogen, hydrogen and chlorine we have that ammonium chloride has a molar mass of 53.49 g/mol so the percent compositions are:

[tex]\%N=\frac{14.01*1}{53.49}*100\% =26.2\%\\\\\%H=\frac{1.01*4}{53.49}*100\% =7.5\%\\\\\%Cl=\frac{35.45*1}{53.49}*100\% =66.3\%[/tex]

Best regards!

Answer:

See explanation below

Explanation:

There are several ways to know if an acid or base is strong. One method is calculating the pH. If the pH is really low, is a strong acid, and if it's really high is a strong base.

However we do not have a pH value here.

The other method is using bronsted - lowry theory. If an acid is strong, then his conjugate base is weak. Same thing with the bases.

Now, Looking at the 4 compounds, we can say that only two of them is weak and the other two are strong compounds. Let's see:

LiOH ---> Strong. If you try to dissociate :

LiOH ------> Li⁺ + OH⁻     The Li⁺ is a weak conjugate acid.

HF -----> Weak

HF --------> H⁺ + F⁻   The Fluorine is a relatively strong conjugate base.

HCl -----> Strong

This is actually one of the strongest acid.

NH₃ ------> Weak

Now writting the Ka and Kb expressions:

Ka = [H⁺] [F⁻] / [HF]

Kb = [NH₄⁺] [OH⁻] / [NH₃]

Finally, to calculate the [OH⁻] we need to use the following expression:

Kw = [H⁻] [OH⁻]

Solving for [OH⁻] we have:

[OH⁻] = Kw / [H⁺]

Remember that the value of Kw is 1x10⁻¹⁴. So replacing:

[OH⁻] = 1x10⁻¹⁴ / 7x10⁻⁶

[OH⁻] = 1.43x10⁻⁹ M

And now, multiplying by 10¹⁰ we have:

[OH⁻] = 1.429x10⁻⁹ * 1x10¹⁰

Hope this helps

Strong acids and bases are those which completely ionized in body fluid, and weak acids and bases are those who does not completely ionized in body fluid.

Ka expression is used to differentiate between strong and weak acids.

[tex]\bold{\dfrac{[H+][F-]}{[HF]}}[/tex]

[tex]\bold{\dfrac{[NH_4^+] [OH^-]}{[NH_3]} }[/tex]

Given, [tex]\bold{ [H^+]=1\times10^-^6\; at \;25^oC}[/tex]

We know, [tex]\bold{ [H^+]\times[OH^-]=1\times10^-^6\; at \;25^oC}[/tex]

[tex]\bold{[OH^-]=\dfrac{1\times10^-^1^4}{6.2\times10^-^6} = 1.43\times10^-^9}[/tex]

Now, multiplying the value by [tex]10^1^0[/tex]

[tex]\bold{( 1.429\times10^-^9) \times 1\times10^1^0= 14.29}[/tex]

Thus, the value is 14.29.

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Answer:

0.41 atm

Explanation:

A reaction between liquid reactants takes place at 10.0 °C in a sealed, evacuated vessel with a measured volume of 5.0 L. Measurements show that the reaction produced 13. g of sulfur hexafluoride gas. Calculate the pressure of sulfur hexafluoride gas in the reaction vessel after the reaction. You may ignore the volume of the liquid reactants. Round your answer to 2 significant digits.

Step 1: Given data

Step 2: Convert "T" to Kelvin

We will use the following expression.

K = °C + 273.15

K = 10.0 °C + 273.15 = 283.2 K

Step 3: Calculate the moles (n) of SF₆

The molar mass of SF₆ is 146.06 g/mol.

13. g × 1 mol/146.06 g = 0.089 mol

Step 4: Calculate the pressure (P) of SF₆

We will use the ideal gas equation.

P × V = n × R × T

P = n × R × T/V

P = 0.089 mol × (0.0821 atm.L/mol.K) × 283.2 K/5.0 L = 0.41 atm

Answer:

A. This allows the plants to conserve water and not bloom during the heat of the day

Explanation:

Most desert plants only bloom at night because they take advantage of animals like moths and insects that fly at night for pollination and reproduction.

Because these plants are in the desert and do not get enough water except from short occasional rainfalls, they conserve water and not bloom during the heat of the day. They bloom at night when the temperature is low and this enhances their water conservation and survival.

The ocean is not a part of Earth's layers.

Answer:

Ocean

Explanation:

Answer:

Answer:

Reversible

Explanation:

Changes of state are physical changes in matter. Common changes of the state include melting, freezing, sublimation, deposition, condensation, and vaporization.

Answer:

(a) 1s; has one orbital

(b) 4d; has five orbitals

(c) 3p; has three orbitals

(d) n=3 has nine orbitals

Explanation:

Electrons in an atom are always in constant motion, making it hard to predict there exact position. However, the most probable locations electrons can be be found are described with the terms shells, subshells and orbitals. A shell contains subshells and orbitals are found within subshells. The shells are given names such as K, L, M, N, which correspond to the principal quantum numbers, n = 1, 2, 3, and 4 respectively. There are 4 major types of subshells that can be found in a shell. They are named as s, p, d, f. Each subshell is composed of several orbitals.

a. 1s; the s subshell has only one orbital. Therefore, the 1s subshell has one orbital

b. 4d; the d subshell has five orbitals. Therefore, the 4d subshell has five orbitals

c. 3p; the p subshell has three orbitals. Therefore, the 3d subshell has  three orbitals

d. n = 3; the shell with n = 3 has the following subshells, 3s, 3p, 3d.the number of orbitals will be 1 + 3 + 5 = 9 orbitals. Therefore, the number of orbitals in n = 3 is nine orbitals

Answer:

No

Explanation:

This does not mean that vinegar is insoluble totally. In fact, vinegar is soluble in water because water is a polar solvent.

For a substance to be soluble in another, it must obey the rule of solubility.

The rule states that "like dissolves like"

It implies that polar solvent will only dissolve polar solute.

Also, non-polar solvent will only dissolve non-polar solute.

Therefore, the answer is no, vinegar will dissolve in water.

Answer:

Ideal Gas

The ideal gas is extremely small and the mass is almost zero and no volume Ideal gas is also considered as a point mass.

Real Gas

The molecules of real gas occupy space though they are small particles and also have volume.

anation:

The differences between an ideal gas and a real gas are that the ideal gas follows the gas laws perfectly under all conditions. Whereas a real gas deviates from ideal gas behaviors.

The ideal gas law, also known as the general gas equation, is a fundamental principle in thermodynamics and relates the pressure, volume, temperature, and number of moles of an ideal gas.

An ideal gas is a theoretical gas that follows the gas laws perfectly under all conditions of temperature and pressure. It is assumed to have no volume, no intermolecular forces, and elastic collisions between its particles. An ideal gas also obeys the ideal gas law.

On the other hand, a real gas is a gas that does not follow the gas laws perfectly under all conditions of temperature and pressure. Real gases have volume and intermolecular forces that affect their behavior. These forces cause deviations from ideal gas behavior, especially at high pressures and low temperatures.

In summary, while an ideal gas is a theoretical gas that follows the gas laws perfectly under all conditions, a real gas is a gas that deviates from ideal gas behavior due to its volume, intermolecular forces, and non-elastic collisions between its particles.

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Answer:

Explanation:

From the information given;

Consider using Lande's Interval rule which can be expressed as:

[tex]\Delta E = E_{j+1} - E_jj \ = \alpha (j+1)[/tex]

here;

[tex]j+1[/tex]  = highest level of j

and

[tex]\dfrac{\Delta E_1}{\Delta E_2} = \dfrac{(j+2)}{(j+1)}[/tex]

[tex]\dfrac{5}{3} = \dfrac{(j+2)}{(j+1)}[/tex]

[tex]5(j+1) = 3(j+2)[/tex]

[tex]5j+5 = 3j+6[/tex]

[tex]2j = 1\\ \\ j = \dfrac{1}{2}[/tex]

recall that:

[tex]j = |S-L| \ \to \ |S+L |[/tex]

So;

[tex]S-L = \dfrac{1}{2} --- (1)[/tex]; &

[tex]S+L = \dfrac{5}{2} --- (1)[/tex]

Using the elimination method, we have:

[tex]2S = \dfrac{6}{2}[/tex]

[tex]S = \dfrac{3}{2}[/tex]

Since [tex]S = \dfrac{3}{2}[/tex]; then from (1)

[tex]\dfrac{3}{2} -L = \dfrac{1}{2}[/tex]

[tex]L = \dfrac{2}{2}[/tex]

[tex]L = 1[/tex]

Answer:

the change in energy when one substance dissolves in another

Explanation:

The enthalpy changes are the heat changes accompanying physical and chemical changes. Actually, an enthalpy change is the difference between the sum of the heat contents of products (final state) and sum of the heat contents of reactants (initial state).

There are basically two types of heat changes that accompanies are reaction which are:

Therefore, the change in energy when one substance dissolves in another defines the enthalpy of solution.

Enthalpy of solution is the heat liberated or absorbed when one mole of a substance (solute) is dissolved in a specified volume of solvent (water).

Answer:

What volume of water is produced when the CO2 reacts with the excess LiOH

X = 360 mL H2O

Explanation:

CO2 (g)       + 2 LiOH(s) ⇒ Li2CO3  (aq) + H2O(l)

20.0 mol        excess                                   x g

X = 360 mL H2O

x mL H20 = 20.0 mol CO2  (1 mol H2O /1 mol CO2)(18 g H2O/1 mol H2O)

(1 mL H2O /1 g H2O)

X = 360 mL H2O