Answer:
We can then determine that a reaction will shift to the right if Q<K
Explanation:
Comparing Q with K allows to find out the status and evolution of the system:
If the reaction quotient is equal to the equilibrium constant, Qc = Kc, the system has reached chemical equilibrium. If the reaction quotient is greater than the equilibrium constant, Qc> Kc, the system is not in equilibrium and will evolve spontaneously, decreasing the value of Qc until it equals the equilibrium constant. In this way, the concentrations of the products will decrease and the concentrations of the reagents will increase. In other words, the reverse reaction is favored to achieve equilibrium. Then the system will evolve to the left (ie products will be consumed and more reagents will be formed).If the reaction quotient is less than the equilibrium constant, Qc <Kc, the system is not in equilibrium and will evolve spontaneously increasing the value of Qc until it equals the equilibrium constant. This implies that the concentrations of the products will increase and those of the reagents will decrease. In other words, to achieve balance, direct reaction is favored. Then the reaction will shift to the right, that is, reagents will be consumed and more products will be formed.In this case, we can then determine that a reaction will shift to the right if Q<K
A student ran the following reaction in the laboratory at 242 K: 2NOBr(g) 2NO(g) Br2(g) When she introduced 0.143 moles of NOBr(g) into a 1.00 liter container, she found the equilibrium concentration of NOBr(g) to be 0.108 M. Calculate the equilibrium constant, Kc, she obtained for this reaction. Kc
Answer:
1.84 × 10⁻³
Explanation:
Step 1: Write the balanced equation
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
Step 2: Calculate the initial concentration of NOBr
0.143 moles of NOBr(g) are introduced into a 1.00 liter container. The molarity is:
M = 0.143 mol / 1.00 L = 0.143 M
Step 3: Make an ICE chart
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
I 0.143 0 0
C -2x +2x +x
E 0.143-2x 2x x
Step 4: Find the value of x
The equilibrium concentration of NOBr(g) was 0.108 M. Then,
0.143-2x = 0.108
x = 0.0175
Step 5: Calculate the concentrations at equilibrium
[NOBr] = 0.108 M
[NO] = 2x = 0.0350 M
[Br₂] = x = 0.0175 M
Step 6: Calculate the equilibrium constant (Kc)
Kc = [0.0350]² × [0.0175] / [0.108]²
Kc = 1.84 × 10⁻³
2NH3 → N2 + 3H2 If 2.22 moles of ammonia (NH3) decomposes according to the reaction shown, how many moles of hydrogen (H2) are formed? A) 2.22 moles of H2 B) 1.11 moles of H2 C) 3.33 moles of H2 D) 6.66 moles of H2
Answer:
C
Explanation:
According to the mole ratio, using 2NH3 will give you 3H2. Which means in order to find the moles of H2 you would only need to divide 2 and multiply 3 to get the amount of moles of H2 produced.
Answer:
I think it's C
Explanation:
Please, tell me if I'm incorrect.
I add a 50. g piece of Al (c = 0.88 J/g-deg) that is at 225°C to 100. mL of water at 20°C. What is the final temperature of the water in °C? The density of water is approximately 1g/mL.
Answer:
THE FINAL TEMPERATURE OF WATER IS -4.117 °C
Explanation:
Mass of the aluminium = 50 g
c = 0.88 J/g C
Initial temperature of aluminium = 225 °C
Volume of water = 100 ml
Density of water = 1 g/ml
Mass of water = density * volume of water
Mass of water = 1 * 100 = 100 g of water
Initial temperature of water = 20 C
It is worthy to note that the heat of a system is constant and conserved as no heat is lost or gained by a closed system,
So therefore,
heat lost by aluminium = heat gained by water
H = mass * specific heat capacity * temeprature change
So:
m c ( T2- T1) = m c (T2-T1)
50 * 0.88 * ( T2 - 225) = 100 * 4.18 *( T2 - 20)
44 ( T2 - 225 ) = 418 ( T2 - 20)
44 T2 - 9900 = 418 T2 - 8360
-9900 + 8360 = 418 T2 - 44 T2
-1540 = 374 T2
T2 = - 4.117
So therefore the final temperature of water is -4.117 °C
A sample is found to contain 1.29×10-11 g of salt. Express this quantity in picograms
Answer:12.9e-12g or in short 12.9pg
Explanation:as p=1e-12
Describe the similarities between H3O and NH3. Compare/contrast their shapes and polarities within the context of your answer. These molecules are called isoelectronic. Why
Answer:
Explanation:
[tex]H_3O^+[/tex] also known as hydronium ion is formed as a result of the reaction between an hydrogen proton and a water molecules.
i.e [tex]\mathtt{H^+ + H_2O \to H_3O^+}[/tex]
(molecular geometry for the hydronium ion shows that the lewis structure of hydronium ion possess a three hydrogen ion bonded to a central atom known as oxygen. The oxygen possess a lone pair with a positive ion. So we have three hydrogen atoms and a lone pair attached to the oxygen. We can now say that there are four groups as the steric number in which one of them is a lone pair. This give rise to the trigonal pyramidal shape of the [tex]H_3O^+[/tex] (hydronium ion) with a bond angle of about 109,5°
Similarly, [tex]NH_3[/tex] on the other hand also known as ammonia has a shape that can be also determined by the Lewis structure.
IN ammonia, there are three hydrogen and a lone pairs of electron spreading out as far away from each other from the centre nitrogen. In essence, the valence shell electron pair around hydrogens tend to repel each other. Hence, giving it a trigonal pyramidal shape.
From above the similarities between H3O and NH3 is in their molecular geometry in which both H3O and NH3 have the same shape.
These molecules are called isoelectronic. Why?
Isoelectronic molecules are molecules having the same number of electrons and same electronic configuration structure. As a result H3O and NH3 possess the same number of electrons in the same orbitals and they also posses the same structure.
A sample of ice absorbs 15.6kJ of heat as it undergoes a reversible phase transition to form liquid water at 0∘C. What is the entropy change for this process in units of JK? Report your answer to three significant figures. Use −273.15∘C for absolute zero.
Answer:
Entropy change of ice changing to water at 0°C is equal to 57.1 J/K
Explanation:
When a substance undergoes a phase change, it occurs at constant temperature.
The entropy change Δs, is given by the formula below;
Δs = q/T
where q is the quantity of heat absorbed or evolved in Joules and T is temperature in Kelvin at which the phase change occur
From the given data, T = 0°C = 273.15 K, q = 15.6 KJ = 15600 J
Δs = 15600 J / 273.15 K
Δs = 57.111 J/K
Therefore, entropy change of ice changing to water at 0°C is equal to 57.1 J/K
The entropy change of ice changing to water will be "57.1 J/K".
Entropy changeThe shift in what seems like a thermodynamic system's condition of confusion is caused by the transformation of heat as well as enthalpy towards activity. Entropy seems to be greater mostly in a network with a high quantity or measure of chaos.
According to the question,
Temperature, T = 0°C or,
= 273.15 K
Heat, q = 15.6 KJ or,
= 15600 J
We know the formula,
Entropy change, Δs = [tex]\frac{q}{T}[/tex]
By substituting the values, we get
= [tex]\frac{15600}{273.15}[/tex]
= 57.11 J/K
Thus the above answer is correct.
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When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many
The given question is incomplete.
The complete question is:
When methane is burned with oxygen, the products are carbon dioxide and water. If you produce 9 grams of water and 11 grams of carbon dioxide from 16 grams of oxygen, how many grams of methane were needed for the reaction?
Answer: 4 grams of methane were needed for the reaction
Explanation:
According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.
{tex]CH_4+2O_2\rightarrow CO_2+H_2O[/tex]
Given: mass of oxygen = 16 g
Mass of carbon dioxide = 11 g
Mass of water = 9 g
Mass of products = Mass of carbon dioxide + mass of water = 11 g +9 g = 20 g
Mass or reactant = mass of methane + mass of oxygen = mass of methane + 16 g
As mass of reactants = mass of products
mass of methane + 16 g= 20 g
mass of methane = 4 g
Thus 4 grams of methane were needed for the reaction
If the heat of combustion for a specific compound is −1320.0 kJ/mol and its molar mass is 30.55 g/mol, how many grams of this compound must you burn to release 617.30 kJ of heat?
Answer:
14.297 g
Explanation:
From the question;
1 mo of the compound requires 1320.0 kJ
From the molar mass;
1 ml of the compound weighs 30.55g
How many grams requires 617.30kJ?
1 ml = 1320
x mol = 617.30
x = 617.30 / 1320
x = 0.468 mol
But 1 mol = 30.55
0.468 mol = x
x = 14.297 g
The tosylate of (2R,3S)-3-phenylbutan-2-ol undergoes an E2 elimination on treatment with sodium ethoxide. Draw the structure of the alkene that is produced.
Answer:
(R)-but-3-en-2-ylbenzene
Explanation:
In this reaction, we have a very strong base (sodium ethoxide). This base, will remove a hydrogen producing a double bond. We know that the reaction occurs through an E2 mechanism, therefore, the hydrogen that is removed must have an angle of 180º with respect to the leaving group (the "OH"). This is known as the anti-periplanar configuration.
The hydrogen that has this configuration is the one that placed with the dashed bond (red hydrogen). In such a way, that the base will remove this hydrogen, the "OH" will leave the molecule and a double bond will be formed between the methyl and the carbon that was previously attached to the "OH", producing the molecule (R) -but-3- en-2-ylbenzene.
See figure 1
I hope it helps!
A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
Br(g)
Cl2(g)
I2(g)
F2(g)
B. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2S(g)
H2O(g)
H2O2(g)
C. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous)
C(s, diamond)
C(s, graphite)
Answer:
A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy
I2(g)>Br2(g)>Cl2(g)>F2(g)
B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2O2(g)>H2S(g) >H2O(g)
C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous) >C(s, graphite)>C(s, diamond)
Explanation:
Hello,
In this case, we can apply the following principles to explain the order:
- The greater the molar mass, the larger the standard molar entropy.
- The greater the molar mass and the structural complexity, the larger the standard molar entropy.
- The greater the structural complexity, the larger the standard molar entropy.
A. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy
I2(g)>Br2(g)>Cl2(g)>F2(g)
This is due to the fact that the greater the molar mass, the larger the standard molar entropy.
B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2O2(g)>H2S(g) >H2O(g)
This is due to the fact that the greater the molar mass and the structural complexity, the larger the standard molar entropy as the hydrogen peroxide has four bonds and weights 34 g/mol as well as hydrogen sulfide that has two bonds only.
C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous) >C(s, graphite)>C(s, diamond)
Since the molecular complexity is greater in the amorphous carbon (messy arrangement), mid in the graphite and lower in the diamond (well organized).
Regards.
Write the equation for the reaction described: A solid metal oxide, , and hydrogen are the products of the reaction between metal and steam. (Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
Answer:
Pb + 2H2O --> PbO2 + 2H2
Explanation:
Products:
Solid metal; PbO2
Hydrogen; H
Reactants:
Metal; Pb
Steam; H2O
Reactants --> Products
Pb + H2O --> PbO2 + H2
Upon balancing we have;
Pb + 2H2O --> PbO2 + 2H2
Identify four general properties that make an NSAID unique as compared to the NSAID aspirin. List specific properties that make aspirin, naproxen, and ibuprofen unique from one another
Answer:
NSAIDs are steroidal anti-inflammatories, their action is on the phospholipase A2 enzyme, this enzyme is responsible for breaking down the phospholipids of the membrane to trigger an inflammatory response. This is how steroidal anti-inflammatory drugs inhibit ALL inflammatory pathways (not like NSAIDs that they only inhibit the COX pathway).
These corticosteroid drugs cannot exceed the systemic mineralocorticoid value 1 in the body, since this corticosteroid hormone is also released by the adrenal cortex.
The NSAIDs generate: sporadic peaks in blood glucose, hypertension, fluid retention, increase in body fat mass, possible suppression of the adrenal cortex over time, inhibiting endogenous synthesis of corticosteroids.
On the other hand, naproxen and ibuprofen are NSAIDs, that is, non-steroidal anti-inflammatory drugs that do not influence both routes of inflammation, but only COX, this enzyme is abbreviated as COX but is called cyclooxygenase, and is responsible for a single route of inflammation.
NSAIDs such as naproxen and ibuprofen can cause gastric disorders such as ulcers or gastritis if they are consumed in a very repetitive manner.
In addition, both drugs are anti-inflammatory, analgesic and antipyretic. Although its two main functions are the first two, it was shown to have an effect in lowering body temperature.
That they are anti-inflammatory means that they inhibit the path of inflammation and analgesics the path of pain.
Explanation:
Both types of drugs generate the same effect but by different mechanisms.
Some are steroids and others are not, although steroids are considered to have a greater risk of benefit that is why they are administered against more systematically compromised instances such as anaphylactic shock.
NSAIDs such as naproxen and ibuprofen are the most prescribed today, since they have few risks and very good benefits, meaning that their adverse effects are not lethal or highly relevant and have a good effect on symptoms.
Both must be administered with care when treating a diabetic patient since corticosteroids generate glycemic peaks or increase in blood glucose, and NSAIDs compete for plasma protein with oral hypoglycemic agents, thus generating that these are in higher free concentrations. high diffusing better through the tissues and increases the potency of the adverse effects of these.
How has the work of chemists affected the environment over the years?
Answer:
Chemistry is one of the causes for global warming, and in some cases it can even cause certain illnesses.
Answer:
Chemists have both hurt the environment and helped the environment by their actions.
Explanation:
<3
What is the energy of a photon of electromagnetic radiation with a wavelength of 963.5 nm? (c = 3.00 × 108 m/s, h = 6.63 × 10–34 J · s
Answer:
[tex]E=2.06\times 10^{-19}\ J[/tex]
Explanation:
Given that,
The wavelength of electromagnetic radiation is 963.5 nm.
We need to find the energy of a photon with this wavelength.
The formula used to find the energy of a photon is given by :
[tex]E=\dfrac{hc}{\lambda}\\\\E=\dfrac{6.63\times 10^{-34}\times 3\times 10^8}{963.5\times 10^{-9}}\\\\E=2.06\times 10^{-19}\ J[/tex]
So, the energy of a photon is [tex]2.06\times 10^{-19}\ J[/tex].
Determine which set of properties correctly describes copper (Cu)?
A. Giant structure, conducts electricity, high melting point, soluble in water, malleable
B. Malleable, brittle, soluble in oil or gasoline, high melting point, simple structure
C. Ionic lattice, conducts electricity, soluble in oil or gasoline, low melting point, ductile
D. Malleable, conducts electricity, high melting point, giant structure, metallic lattice
Answer:
D. Malleable, conducts electricity, high melting point, giant structure, metallic lattice
Explanation:
Copper is a metal with an atomic number of 29. This metal is soft and reddish in color which explains why it is very malleable(beaten to form various shapes without breaking).
All metals are good conductors of electricity including copper which is also a metal. Metals generally are insoluble in water. Copper also has a high melting point which is a characteristic of metals due to their giant structure and metallic lattice which makes it difficult to be broken down.
What is the mass number of an element
Answer:
A (Atomic mass number or Nucleon number)
Explanation:
The mass number is the total number of protons and nucleons in an atomic nucleus.
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1.) A sample of neon gas at a pressure of 0.646 atm and a temperature of 242 °C, occupies a volume of 515 mL. If the gas is cooled at constant pressure until its volume is 407 mL, the temperature of the gas sample will be ________°C.
2.) A sample of argon gas at a pressure of 0.633 atm and a temperature of 261 °C, occupies a volume of 694 mL. If the gas is heated at constant pressure until its volume is 796 mL, the temperature of the gas sample will be___________°C.
3.) 0.962 mol sample of carbon dioxide gas at a temperature of 20.0 °C is found to occupy a volume of 21.5 liters. The pressure of this gas sample ismm ____________ Hg.
Answer:1 )T2=134°C 2) T2=339.48°C. 3)
P=817.59 mmHg.
Explanation:
1.Given ;
pressure, P1 of neon gas = 0.646 atm
temperature, T1 =242oC + 273=515oC
Volume, V1 =515ml
Volume V2= 407ml
temperature , T 2= ?
Solution;
And at constant pressure, the volume cools at V2=407 mL at T2=?
From ideal gas equation, PV=nRT
V/T=constant
therefore
V1/V2=T1/T2 = T2=(V2 xT1)/V1
T2=(407 mL x 515 K)/515 mL= 407K.
T2= 407K -273= 134°C. recall 0°C=273 K)
2..Given ;
pressure, P1 of neon gas = 0.633 atm
temperature, T1 =261oC + 273=534oC
Volume, V1 =694ml
Volume V2= 796ml
temperature , T 2= ?
Solution;
And at constant pressure, the volume expands at V2=796mL at T2=?
From ideal gas equation, PV=nRT
V/T=constant
therefore
V1/V2=T1/T2 = T2=(V2 xT1)/V1
T2=(796 mL x 534 K)/694mL= 612.48K.
T2= 612.48K -273= 339.48°C. recall 0°C=273 K
3
Given;
moles of CO2= n=0.962 mol,
temperature T=20°C=20+273 K =293 K,
volume V=21.5 L,
gas constant R at L·mmHg/mol·K= 62.3637 L mmHg mol^-1 K^-1
Using ideal gas equation PV=nRT
P=nRT/V
P=(0.962 mol)x(62.3637mmHg mol^-1 K^-1)x(293 K)/(21.5L)
P=817.59 mmHg.
If one pound is the same as 454 grams, then convert the mass of 78 grams to pounds.
Answer:
0.17 lb
Explanation:
78 g * (1 lb/454 g)=0.17 lb
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Fill in the blanks with the words given below- [Atoms, homogeneous, metals, true, saturated, homogeneous, colloidal, compounds, lustrous] 1.An element which are sonorous are called................ 2.An element is made up of only one kind of .................... 3.Alloys are ............................. mixtures. 4.Elements chemically combines in fixed proportion to form ........................ 5. Metals are................................... and can be polished. 6. a solution in which no more solute can be dissolved is called a .................... solution. 7. Milk is a .............. solution but vinegar is a .................. solution. 8. A solution is a ................... mixture. pls help, could not get these answers
Answer:
1. metals
2. atom
3. homogeneous
4. compounds
5. lustrous
6. saturated
7. colloidal
8. homogeneous
Explanation:
We discussed the different types of intermolecular forces in this lesson, which can affect the boiling point of a substance.
1. Which of these has the highest boiling point?
A) Ar
B) Kr
C) Xe
D) Ne
2. Which substance has the highest boiling point?
A) CH4
B) He
C) HF
D) Cl2
Answer:
1, C, Xe 2, B,He
Explanation:
1, cause as u go down a group the boiling point increases.
2, boiling point of single element is greater than a compound
According to periodic trends in periodic table boiling point increases down the group and hence Xe has highest boiling point and more amount of heat is required to boil an element hence He has highest boiling point.
What is periodic table?
Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.
It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.
Elements present in the same group have same number of valence electrons and hence have similar properties while elements present in the same period show gradual variation in properties due to addition of one electron for each successive element in a period.
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When balancing redox reactions under basic conditions in aqueous solution, the first step is to:________.
a. balance oxygen
b. balance hydrogen
c. balance the reaction as though under acidic conditions
d. none of the above
Answer:
When balancing redox reactions under basic conditions in aqueous solution, the first step is to balance oxygen.
Explanation:
Oxidation-reduction reactions or redox reactions are those in which an electron transfer occurs between the reagents. An electron transfer implies that there is a change in the number of oxidation between the reagents and the products.
The gain of electrons is called reduction and the loss of electrons oxidation. That is to say, there is oxidation whenever an atom or group of atoms loses electrons (or increases its positive charges) and in the reduction an atom or group of atoms gains electrons, increasing its negative charges or decreasing the positive ones.
The oxidation and reduction half-reactions, in a basic medium, adjust the oxygens and hydrogens as follows:
In the member of the half-reaction that presents excess oxygen, you add as many water molecules as there are too many oxygen. Then, in the opposite member, the necessary hydroxyl ions are added to fully adjust the half-reaction. Normally, twice as many hydroxyl ions, OH-, are required as water molecules have previously been added.
In short, you first adjust the oxygens with OH-, then you adjust the H with H₂O, and finally you adjust the charge with e-
So, when balancing redox reactions under basic conditions in aqueous solution, the first step is to balance oxygen.
Answer:
c. balance the reaction as though under acidic conditions
Explanation:
When balancing redox reactions under basic conditions, a good technique is to first balance the reaction as though under acidic conditions. We then adjust the result to reflect the basic conditions.
An aqueous solution of potassium bromide, KBr, contains 4.34 grams of potassium bromide and 17.4 grams of water. The percentage by mass of potassium bromide in the solution is 20 %.
Answer:
True
Explanation:
The percentage by mass of a substance in a solution can be calculated by dividing the mass of the substance dissolved in the solution by the total mass of the solution. This can be expressed mathematically as:
Percentage by mass = mass of substance in solution/mass of solution x 100
In this case;
mass of KBr = 4.34 grams
mass of water = 17.4 grams
mass of solution = mass of KBr + mass of water = 4.34 + 17.4 = 21.74
Percentage by mass of KBr = 4.34/21.74 x 100
= 19.96 %
19.96 is approximately 20%.
Hence, the statement is true.
Testbank Question 47 Consider the molecular orbital model of benzene. In the ground state how many molecular orbitals are filled with electrons?
Answer:
There are fifteen molecular orbitals in benzene filled with electrons.
Explanation:
Benzene is an aromatic compound. Let us consider the number of bonding molecular orbitals that should be present in the molecule;
There are 6 C-C σ bonds, these will occupy six bonding molecular orbitals filled with electrons.
There are 6 C-H σ bonds, these will occupy another six molecular orbitals filled with electrons
The are 3 C=C π bonds., these will occupy three bonding molecular pi orbitals.
All these bring the total number of bonding molecular orbitals filled with electrons to fifteen bonding molecular orbitals.
what are the monomers of bakelite
Answer:
Bakelite is a polymer made up of the monomers phenol and formaldehyde. This phenol-formaldehyde resin is a thermosetting polymer.
Answer: The monomers of bakelite are formaldehyde and phenol
Explanation:
In a reversible reaction, the endothermic reaction absorbs ____________ the exothermic reaction releases. A. less energy than B. None of these, endothermic reactions release energy C. the same amount of energy as D. more energy than
Answer: C. the same amount of energy as
Explanation:
A reversible reaction is a chemical reaction where the reactants form products that, in turn, react together to give the reactants back.
Reversible reactions will reach an equilibrium point where the concentrations of the reactants and products will no longer change.
[tex]A+B\rightleftharpoons C+D[/tex]
Thus if forward reaction is exothermic i.e. the heat is released , the backward reaction will be endothermic i.e. the heat is absorbed and in same amount.
The amount of energy released will be equal and opposite in sign to the energy absorbed in that reaction.
Answer:
C.) the same amount of energy as
Explanation:
I got it correct on founders edtell
A student determines the value of the equilibrium constant to be 1.5297 x 107 for the following reaction: HBr(g) + 1/2 Cl2(g) --> HCl(g) +1/2 Br2(g) Based on this value of Keq, calculate the Gibbs free energy change for the reaction of 2.37 moles of HBr(g) at standard conditions at 298 K.
Answer:
[tex]\Delta G=-97.14kJ[/tex]
Explanation:
Hello,
In this case, the relationship between the equilibrium constant and the Gibbs free energy of reaction is:
[tex]\Delta G=-RTln(K)[/tex]
Hence, we compute it as required:
[tex]\Delta G=-8.314\frac{J}{mol\times K}*298K*ln(1.5297x10^7)\\\\\Delta G=-40.99kJ/mol[/tex]
And for 2.37 moles of hydrogen bromide, we obtain:
[tex]\Delta G=-40.99kJ/mol*2.37mol\\\\\Delta G=-97.14kJ[/tex]
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Which of the following processes have a ΔS < 0? Which of the following processes have a ΔS < 0? carbon dioxide(g) → carbon dioxide(s) water freezes propanol (g, at 555 K) → propanol (g, at 400 K) methyl alcohol condenses All of the above processes have a ΔS < 0.
Answer:
All of the above processes have a ΔS < 0.
Explanation:
ΔS represents change in entropy of a system. Entropy refers to the degree of disorderliness of a system.
The question requests us to identify the process that has a negative change of entropy.
carbon dioxide(g) → carbon dioxide(s)
There is a change in state from gas to solid. Solid particles are more ordered than gas particles so this is a negative change in entropy.
water freezes
There is a change in state from liquid to solid. Solid particles are more ordered than liquid particles so this is a negative change in entropy.
propanol (g, at 555 K) → propanol (g, at 400 K)
Temperature is directly proportional to entropy, this means higher temperature leads t higher entropy.
This reaction highlights a drop in temperature which means a negative change in entropy.
methyl alcohol condenses
Condensation is the change in state from gas to liquid. Liquid particles are more ordered than gas particles so this is a negative change in entropy.
An actacide tablet containing Mg(OH)2 (MM = 58.3g / (mol)) is titrated with a 0.100 M solution of HNO3. The end point is determined by using an indicator. Based on 20.00mL HNO3 being used to reach the endpoint, what was the mass of the Mg * (OH) in the antacid tablet? * 0.0583 g 0.583 5.83 g 58.3 g
Answer:
0.0583g
Explanation:
The equation of the reaction is;
2HNO3(aq) + Mg(OH)2(aq) -------> Mg(NO3)2(aq) + 2H2O(l)
From the question, number of moles of HNO3 reacted= concentration × volume
Concentration of HNO3= 0.100 M
Volume of HNO3 = 20.00mL
Number of moles of HNO3= 0.100 × 20/1000
Number of moles of HNO3 = 2×10^-3 moles
From the reaction equation;
2 moles of HNO3 reacts with 1 mole of Mg(OH)2
2×10^-3 moles reacts with 2×10^-3 moles ×1/2 = 1 ×10^-3 moles of Mg(OH)2
But
n= m/M
Where;
n= number of moles of Mg(OH)2
m= mass of Mg(OH)2
M= molar mass of Mg(OH)2
m= n×M
m= 1×10^-3 moles × 58.3 gmol-1
m = 0.0583g
Does the amount of methanol increase, decrease, or remain the same when an equilibrium mixture of reactants and products is subjected to the following changes?
a. the catalyst is removed
b. the temp is increased
c. the volume is decreased
d. helium is added
e. CO is added
Answer:
a. Methanol remains the same
b. Methanol decreases
c. Methanol increases
d. Methanol remains the same
e. Methanol increases
Explanation:
Methanol is produced by the reaction of carbon monoxide and hydrogen in the presence of a catalyst as follows; 2H2+CO→CH3OH.
a) The presence or absence of a catalyst makes no difference on the equilibrium position of the system hence the methanol remains constant.
b) The amount of methanol decreases because the equilibrium position shifts towards the left and more reactants are formed since the reaction is exothermic.
c) If the volume is decreased, there will be more methanol in the system because the equilibrium position will shift towards the right hand side.
d) Addition of helium gas has no effect on the equilibrium position since it does not participate in the reaction system.
e) if more CO is added the amount of methanol increases since the equilibrium position will shift towards the right hand side.
11mg of cyanide per kilogram of body weight is lethal for 50% of domestic chickens. How many grams per kilogram of body weight is a lethal dose for 50% of domestic chickens?
Answer:
[tex]0.033g[/tex]
Explanation:
Hello,
In this case, since 11 mg per kilogram of body weight has the given lethality, the mg that turn out lethal for a chicken weighting 3 kg is computed by using a rule of three:
[tex]11mg\longrightarrow 1kg\\\\x\ \ \ \ \ \ \longrightarrow 3kg[/tex]
Thus, we obtain:
[tex]x=\frac{3kg*11mg}{1kg}\\ \\x=33mg[/tex]
That in grams is:
[tex]=33mg*\frac{1g}{1000mg} \\\\=0.033g[/tex]
Regards.
