Answer:
D. The Ca[OH]2 solution may have been unsaturated
Explanation:
The solubility product constant Ksp of any given chemical compound is a term used to describe the equilibrium between a solid and the ions it contains solution. The value of the Ksp indicates the extent to which any compound can dissociate into ions in water. A higher the Ksp, implies more greater solubility of the compound in water.
If the Ksp is more than the value in literature, this false value must have arisen from the fact that the solution was unsaturated hence it appears to be more soluble than it should normally be when saturated.
When scientists are ready to publish the result of their experiments why is it important for them to include a description of the procedure they used
Answer: So other scientist can replicate the experiment and see if they get the same results in other words, test reliability.
Explanation:
An aqueous solution of potassium bromide, KBr, contains 4.34 grams of potassium bromide and 17.4 grams of water. The percentage by mass of potassium bromide in the solution is 20 %.
Answer:
True
Explanation:
The percentage by mass of a substance in a solution can be calculated by dividing the mass of the substance dissolved in the solution by the total mass of the solution. This can be expressed mathematically as:
Percentage by mass = mass of substance in solution/mass of solution x 100
In this case;
mass of KBr = 4.34 grams
mass of water = 17.4 grams
mass of solution = mass of KBr + mass of water = 4.34 + 17.4 = 21.74
Percentage by mass of KBr = 4.34/21.74 x 100
= 19.96 %
19.96 is approximately 20%.
Hence, the statement is true.
By heating a 93% pure kclo3 sample, what percentage of its mass is reduced?
2KCLO3---->2KCL+3O2
Explanation:
free your mind drink water and go outside take fresh air you will get answers
What happens to the rate of dissolution as the temperature is increased in a gas solution?
A.
The rate stays the same.
B.
The rate decreases.
C.
The rate increases.
D.
There is no way to tell.
Answer:
The rate decreases
Explanation:
When we dissolve a gas in a water, the process is exothermic. This implies that heat is evolved upon dissolution of a gas in water.
Recall from Le Chateliers principle that for exothermic reactions, an increase in temperature favours the reverse reaction. The implication of these is that when the temperature of the gas is increased, less gas will dissolve in water.
Hence increase in temperature decreases the rate of solubility of a gas in water.
Answer:
B.
The rate decreases.
Explanation:
An unknown gas diffuses 5 times slower than that of H2.The moleculer mass of unknown gas is??
Answer:
50.
Explanation:
We can write Graham's Law of Diffusion as:
(Rate 1)^2 = Molecular Mass 2
-------------- -------------------------
(Rate 2)^2 Molecular Mass 1
So using the Given Information:
1^2 / (1/5)^2 = Molecular Mass of unknown gas / 2, so:
25 = M/2
M = 50.
g What is the molarity of hydrochloric acid if 40.95 mL of HCl is required to neutralize 0.550 g of sodium oxalate, Na2C2O4
Answer:
0.0002 M
Explanation:
The molarity of the HCl required would be 0.0002 M.
First, let us consider the balanced equation of the reaction:
[tex]Na_2C_2O_4 + 2HCl = 2NaCl + H_2 + 2CO_2[/tex]
Stoichiometrically, 1 mole of [tex]Na_2C_2O_4[/tex] reacts with 2 moles of [tex]HCl[/tex] for a complete neutralization reaction.
Recall that: mole = [tex]\frac{mass}{molar mass}[/tex]
Mole of 0.550 g sodium oxalate = 0.550/134 = 0.0041 mole
If 1 mole [tex]Na_2C_2O_4[/tex] requires 2 moles HCl, then 0.0041 mole will require:
0.0041 x 2 = 0.0082 mole HCl
Volume of the HCl = 40.95 L
Molarity = mole/volume
Hence, molarity of the HCl = 0.0082/40.95 = 0.0002 M
Why can gasses change volume?
A. The forces holding the gas particles together are
stronger than gravity.
B. The gas particles have no mass, so they can change volume.
C. Gravity has no effect on gas particles, so they can float away.
O D. There are no forces holding the gas particles together.
Answer:
There are no forces holding the gas particles together.
Explanation:
How much work (in Joules) is required to expand the volume of a pump from 0.00 L to 2.50 L against an external pressure of 1.10 atm
Answer:
W = 278.64375 Joules
Explanation:
The information given in this problem are;
Initial volume = 0L
Final volume = 2.50L
ΔV = 2.50 - 0 = 2.50 L
External pressure, P = 1.10 atm
Work = ?
These parameters are related by the equation;
w = - P ΔV
W = - (1.10 )(2.50)
W = 2.75 L atm
Upon conversion to joules;
1 liter atmosphere is equal to 101.325 joule
W = 278.64375 Joules
A small amount of solid calcium hydroxide is shaken vigorously in a test tube almost full of water until no further change occurs and most of the solid settles out. The resulting solution is:______.
Answer:
Lime water, [tex]Ca(OH)_{2}_({aq} )[/tex] is formed.
Explanation:
Lime-water is a clear and colourless dilute solution of aqueous calcium hydroxide salt.
Small amounts of calcium hydroxide salt, [tex]Ca(OH)_{2}_(s)[/tex] is sparsely soluble at room temperature when dispersed vigorously. if in excess, a white suspension called 'milk of lime'is formed.
I hope this explanation is helpful.
Compound A is an alkene that was treated with ozone to yield only (CH3CH2CH2)2C=O. Draw the major product that is expected when compound A is treated with a peroxy acid (RCO3H) followed by aqueous acid (H3O+).
Answer:
2,2,3,3-tetrapropyloxirane
Explanation:
In this case, we have to know first the alkene that will react with the peroxyacid. So:
What do we know about the unknown alkene?
We know the product of the ozonolysis reaction (see figure 1). This reaction is an oxidative rupture reaction. Therefore, the double bond will be broken and we have to replace the carbons on each side of the double bond by oxygens. If [tex](CH_3CH_2CH_2)_2C=O[/tex] is the only product we will have a symmetric molecule in this case 4,5-dipropyloct-4-ene.
What is the product with the peroxyacid?
This compound in the presence of alkenes will produce peroxides. Therefore we have to put a peroxide group in the carbons where the double bond was placed. So, we will have as product 2,2,3,3-tetrapropyloxirane. (see figure 2)
Atoms are indivisible spheres. 1.plum pudding model 2.Dalton model 3.Bohr model
Answer: 2. Dalton Model
Explanation:
John Dalton proposed that atoms are indivisible spheres. Although his model of an atom was not entirely new to the scientific world since the ancient Greeks has made a similar statement in the past ( all matter are made up of small indivisible particle called atom).
As of when Dalton proposed his model of an atom, electrons and nucleus where yet to be discovered.
1. Explain what the police siren sounds like to Jane:
2. Explain what the police siren sounds like to John:
3. Explain why the police siren sounds different between Jane and John:
Answer:
1. the siren has a lower pitch to Jane
2. the siren has a higher pitch to John
3. sound different due to moving away from Jane making the sound wave lengths longer and moving toward John making the wave lengths shorter
Explanation:
The Doppler effect expresses that sound is comparative with the spectator or observer. This is demonstrated valid by the model given with Jane and John. To one individual it could sound low and to someone else it could sound high, in light of where they are tuning in from. To John, the police alarm playing is a higher pitch. Be that as it may, to Jane this equivalent alarm is a totally extraordinary pitch and is heard lower than in comparison to the john.
This is a prime case of the Doppler Effect. They sound distinctive on the grounds that the sound is moving far from Jane making the sound frequencies longer and it is advancing toward John making the frequencies shorter. This impacts how the sound is heard by the human ear.
When balancing redox reactions under basic conditions in aqueous solution, the first step is to:________.
a. balance oxygen
b. balance hydrogen
c. balance the reaction as though under acidic conditions
d. none of the above
Answer:
When balancing redox reactions under basic conditions in aqueous solution, the first step is to balance oxygen.
Explanation:
Oxidation-reduction reactions or redox reactions are those in which an electron transfer occurs between the reagents. An electron transfer implies that there is a change in the number of oxidation between the reagents and the products.
The gain of electrons is called reduction and the loss of electrons oxidation. That is to say, there is oxidation whenever an atom or group of atoms loses electrons (or increases its positive charges) and in the reduction an atom or group of atoms gains electrons, increasing its negative charges or decreasing the positive ones.
The oxidation and reduction half-reactions, in a basic medium, adjust the oxygens and hydrogens as follows:
In the member of the half-reaction that presents excess oxygen, you add as many water molecules as there are too many oxygen. Then, in the opposite member, the necessary hydroxyl ions are added to fully adjust the half-reaction. Normally, twice as many hydroxyl ions, OH-, are required as water molecules have previously been added.
In short, you first adjust the oxygens with OH-, then you adjust the H with H₂O, and finally you adjust the charge with e-
So, when balancing redox reactions under basic conditions in aqueous solution, the first step is to balance oxygen.
Answer:
c. balance the reaction as though under acidic conditions
Explanation:
When balancing redox reactions under basic conditions, a good technique is to first balance the reaction as though under acidic conditions. We then adjust the result to reflect the basic conditions.
Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus. The reactant is H2NCNHCH2CH2CH2CHCO minus, with an NH group, with a lone pair at the N atom, double-bonded to the first (from left to right) carbon, an NH2 group attached to the fifth carbon, an O atom double-bonded to the sixth carbon and a lone pair of electrons at the first and the second N atoms of the chain. The product has the same structure as the reactant, except that not an NH group with a lone pair, but an NH2 plus group is double-bonded to the first carbon. In addition, an NH3 plus group is attached to the fifth carbon instead of the NH2 group.
Answer:
Due to the resonance structures
Explanation:
In the question:
"Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus"
We have to take into account the structure of the amino acid arginine. In which, we have the amino and the carboxylic groups in the right and the guanidine group in the left.
In this group, we have a central carbon with three nitrogen atoms around and a double bond with the nitrogen on the top. This nitrogen on the top will accept the proton because the structure produced will have a positive charge on this nitrogen. Then, the double bond with the carbon can be delocalized into the nitrogen producing a positive charge in the carbon.
In this structure (the carbocation), we can have several resonance structures. In the blue option, we can produce a double bond with the nitrogen on the right. In the purple option, we can produce a double bond with the nitrogen on the left.
In conclusion, if the nitrogen in the top on the guanidine group accepts an hydrogen atom and we will have several resonance structures that can stabilize the molecule. Due to this, the nitrogen in the top its the best option to accept hydrogens.
See figure 1
I hope it helps!
Write the equation for the reaction described: A solid metal oxide, , and hydrogen are the products of the reaction between metal and steam. (Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
Answer:
Pb + 2H2O --> PbO2 + 2H2
Explanation:
Products:
Solid metal; PbO2
Hydrogen; H
Reactants:
Metal; Pb
Steam; H2O
Reactants --> Products
Pb + H2O --> PbO2 + H2
Upon balancing we have;
Pb + 2H2O --> PbO2 + 2H2
1.) A sample of neon gas at a pressure of 0.646 atm and a temperature of 242 °C, occupies a volume of 515 mL. If the gas is cooled at constant pressure until its volume is 407 mL, the temperature of the gas sample will be ________°C.
2.) A sample of argon gas at a pressure of 0.633 atm and a temperature of 261 °C, occupies a volume of 694 mL. If the gas is heated at constant pressure until its volume is 796 mL, the temperature of the gas sample will be___________°C.
3.) 0.962 mol sample of carbon dioxide gas at a temperature of 20.0 °C is found to occupy a volume of 21.5 liters. The pressure of this gas sample ismm ____________ Hg.
Answer:1 )T2=134°C 2) T2=339.48°C. 3)
P=817.59 mmHg.
Explanation:
1.Given ;
pressure, P1 of neon gas = 0.646 atm
temperature, T1 =242oC + 273=515oC
Volume, V1 =515ml
Volume V2= 407ml
temperature , T 2= ?
Solution;
And at constant pressure, the volume cools at V2=407 mL at T2=?
From ideal gas equation, PV=nRT
V/T=constant
therefore
V1/V2=T1/T2 = T2=(V2 xT1)/V1
T2=(407 mL x 515 K)/515 mL= 407K.
T2= 407K -273= 134°C. recall 0°C=273 K)
2..Given ;
pressure, P1 of neon gas = 0.633 atm
temperature, T1 =261oC + 273=534oC
Volume, V1 =694ml
Volume V2= 796ml
temperature , T 2= ?
Solution;
And at constant pressure, the volume expands at V2=796mL at T2=?
From ideal gas equation, PV=nRT
V/T=constant
therefore
V1/V2=T1/T2 = T2=(V2 xT1)/V1
T2=(796 mL x 534 K)/694mL= 612.48K.
T2= 612.48K -273= 339.48°C. recall 0°C=273 K
3
Given;
moles of CO2= n=0.962 mol,
temperature T=20°C=20+273 K =293 K,
volume V=21.5 L,
gas constant R at L·mmHg/mol·K= 62.3637 L mmHg mol^-1 K^-1
Using ideal gas equation PV=nRT
P=nRT/V
P=(0.962 mol)x(62.3637mmHg mol^-1 K^-1)x(293 K)/(21.5L)
P=817.59 mmHg.
Two elements represents by the letter Q and R atomic number 9 and 12 respectively.
1. Write the electronic configuration of R
2. To what group does Q belongs to in the periodic table
3. Write the formula of the compound formed when Q combines with R
Answer:
The two elements with atomic number 9 and 12 are represented by letter Q and R respectively, where Q represents fluorine atom and R represents magnesium atom.
1. Electronic configuration of R that is magnesium (atomic number 12) is:
1s2 2s2 2p6 3s2
2. Q represents fluorine atom, which belongs to group 17 in periodic table that is the most reactive and lightest member of the group.
3. Q and R that is fluorine and magnesium combinely form magnesium fluoride or MgF2.
A runner can cover 2.0 miles in 31 minutes, how long would it take for this runner to cover 6.0 Km. Hint (1 mile= 1.609 Km)
The answer to this question is approximately equal to 57.8
A flask contains 6g hydrogen gas and 64 g oxygen at rtp the partial pressure of hydrogen gas in the flask of the total pressure (p)will be
A.2/3p
B.3/5p
C.2/5p
D.1/3p
Answer this with reason
Answer:
B.3/5p
Explanation:
For this question, we have to remember "Dalton's Law of Partial Pressures". This law says that the pressure of the mixture would be equal to the sum of the partial pressure of each gas.
Additionally, we have a proportional relationship between moles and pressure. In other words, more moles indicate more pressure and vice-versa.
[tex]P_i=P_t_o_t_a_l*X_i[/tex]
Where:
[tex]P_i[/tex]=Partial pressure
[tex]P_t_o_t_a_l[/tex]=Total pressure
[tex]X_i[/tex]=mole fraction
With this in mind, we can work with the moles of each compound if we want to analyze the pressure. With the molar mass of each compound we can calculate the moles:
moles of hydrogen gas
The molar mass of hydrogen gas ([tex]H_2[/tex]) is 2 g/mol, so:
[tex]6g~H_2\frac{1~mol~H_2}{2~g~H_2}=~3~mol~H_2[/tex]
moles of oxygen gas
The molar mass of oxygen gas ([tex]O_2[/tex]) is 32 g/mol, so:
[tex]64g~H_2\frac{1~mol~H_2}{32~g~H_2}=~2~mol~O_2[/tex]
Now, total moles are:
Total moles = 2 + 3 = 5
With this value, we can write the partial pressure expression for each gas:
[tex]P_H_2=\frac{3}{5}*P_t_o_t_a_l[/tex]
[tex]P_O_2=\frac{2}{5}*P_t_o_t_a_l[/tex]
So, the answer would be 3/5P.
I hope it helps!
The K sp for silver(I) phosphate is 1.8 × 10 –18. Determine the silver ion concentration in a saturated solution of silver(I) phosphate.
Answer:
[tex][Ag^+]=4.82x10^{-5}M[/tex]
Explanation:
Hello,
In this case, the dissociation reaction for silver phosphate is:
[tex]Ag_3PO_4(s)\rightleftharpoons 3Ag^+(aq)+PO_4^{3-}(aq)[/tex]
Therefore, the equilibrium expression is:
[tex]Ksp=[Ag^+]^3[PO_4^{3-}][/tex]
And in terms of the reaction extent [tex]x[/tex] is:
[tex]Ksp=1.8x10^{-18}=(3x)^3(x)[/tex]
Thus, [tex]x[/tex] turns out:
[tex]1.8x10^{-18}=27x^4\\\\x=\sqrt[4]{\frac{1.8x10^{-18}}{27} } \\\\x=1.61x10^{-5}M[/tex]
In such a way, the concentration of the silver ion is:
[tex][Ag^+]=3x=3*1.61x10^{-5}M=4.82x10^{-5}M[/tex]
Best regards.
A 10.00-mL aliquot of vinegar requires 16.95 mL of the 0.4874 M standardized NaOH solution to reach the end point of the titration. Demonstrate how to calculate the molarity of the vinegar solution (HC2H3O2). Show complete work below. Answer: 0.8261 M.
Answer:
0.8261 M.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
HC2H3O2 + NaOH —> NaC2H3O2 + H2O
From the balanced equation above, we obtained the following:
Mole ratio of the acid, HC2H3O2 (nA) = 1
Mole ratio of the base, NaOH (nB) = 1
Data obtained from the question include the following:
Volume of acid, HC2H3O2 (Va) = 10 mL
Molarity of acid, HC2H3O2 (Ma) =..?
Volume of base, NaOH (Vb) = 16.95 mL Molarity of base, NaOH (Mb) = 0.4874 M
Finally, we shall determine the molarity of the acid solution, as follow:
MaVa/MbVb = nA/nB
Ma x 10 / 0.4874 x 16.95 = 1
Cross multiply
Ma x 10 = 0.4874 x 16.95
Divide both side by 10
Ma = (0.4874 x 16.95) /10
Ma = 0.8261 M.
Therefore, the molarity of the vinegar solution (HC2H3O2) is 0.8261 M.
In a buffer solution made of acetic acid and sodium acetate, if a small amount of acid is added, the added acid will react with whome?
Answer:
The acid reacts with the conjugate base producing more weak acid.
Explanation:
A buffer solution is defined as the mixture of a weak acid and its conjugate base or a weak base with its conjugate acid.
The acetic buffer, CH₃COOH/CH₃COO⁻, is in equilibrium with water as follows:
CH₃COOH(aq) + H₂O(l) ⇄ CH₃COO⁻(aq) + H₃O⁺
When an acid HX (Source of H₃O⁺) is added to the buffer, the reaction that occurs is:
CH₃COO⁻ + HX → CH₃COOH
The acid reacts with the conjugate base producing more weak acid.In fact, this is the principle of the buffer:
An acid reacts with the conjugate base producing weak acid. And the weak acid reacts with a base producing conjugate base
If a small amount of acid is added to an acetic acid-sodium acetate buffer, the acid will react with the acetate ion from sodium acetate.
We have a buffer formed by acetic acid and sodium acetate.
What is a buffer?A buffer is a solution used to resist abrupt changes in pH when an acid or a base is added.
How are buffers formed?They can be formed in 1 of 2 ways:
By a weak acid and its conjugate base.By a weak base and its conjugate acid.Our buffer is formed by a weak acid (acetic acid) and its conjugate base (acetate ion from sodium acetate).
When an acid (HX) is added, it is neutralized by the basic component of the buffer. The generic net ionic equation is:
H⁺ + CH₃COO⁻ ⇄ CH₃COOH
If a small amount of acid is added to an acetic acid-sodium acetate buffer, the acid will react with the acetate ion from sodium acetate.
Learn more about buffers here: https://brainly.com/question/24188850
The heat of vaporization of water is 40.66 kJ/mol. How much heat is absorbed when 3.11 g of water boils at atmospheric pressure?
Answer:
The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.
Explanation:
A molar heat of vaporization of 40.66 kJ / mol means that 40.66 kJ of heat needs to be supplied to boil 1 mol of water at its normal boiling point.
To know the amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure, the number of moles represented by 3.11 g of water is necessary. Being:
H: 1 g/moleO: 16 g/molethe molar mass of water is:
H₂O= 2* 1 g/mole + 16 g/mole= 18 g/mole
So: if 18 grams of water are contained in 1 mole, 3.11 grams of water in how many moles are present?
[tex]moles of water=\frac{3.11 grams*1 mole}{18 gramos}[/tex]
moles of water= 0.1728
Finally, the following rule of three can be applied: if to boil 1 mole of water at its boiling point it is necessary to supply 40.66 kJ of heat, to boil 0.1728 moles of water, how much heat is necessary to supply?
[tex]heat=\frac{0.1728 moles*40.66 kJ}{1 mole}[/tex]
heat= 7.026 kJ
The amount of heat that is absorbed when 3.11 g of water boils at atmospheric pressure is 7.026 kJ.
What is the mole fraction of urea, CO(NH2)2, in a solution prepared by dissolving 4.0 g of urea in 32.0 g of methanol, CH3OH
Answer:
0.0630
Explanation:
The molar mass of urea = 60 g/mol
we all know that:
[tex]\mathtt{number \ of \ moles = \dfrac{mass }{molar \ mass}}[/tex]
Then; the number of moles of urea
= [tex]\mathtt{\dfrac{4.0 \ g}{60 \ g/mol}}[/tex]
= 0.0667 mol
Similarly; the number of moles of methanol
= [tex]\mathtt{\dfrac{32 \ g}{32.04 \ g/mol}}[/tex]
= 0.9988 mol
The total number of moles = (0.0667 + 0.9988) mol
= 1.0655 mol
Finally,the mole fraction of urea [tex]\mathtt{(X_{urea})}[/tex] = [tex]\mathtt{\dfrac{ n_{urea}}{(n_{urea}+n_{methanol})}}[/tex]
[tex]\mathtt{(X_{urea})}[/tex] = [tex]\mathtt{\dfrac{0.0667 \ mole}{1.0655 \ mole}}[/tex]
= 0.0630
2. In what part of an atom can protons be found?
a. Inside the electrons
b. Inside the neutrons
C. Inside the atomic nucleus
d. Inside the electron shells
Answer:
c
Explanation:
it's found inside the atomic nucleus
Cesium-137 is part of the nuclear waste produced by uranium-235 fission. The half-life of cesium-137 is 30.2 years. How much time is required for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value?
Answer:
There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value
Explanation:
The radioactive decay follows always first-order kinetics where its general law is:
Ln[A] = -Kt + ln[A]₀
Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.
We can find rate constant from half-life as follows:
Rate constant:
t(1/2) = ln 2 / K
As half-life of Cesium-137 is 30.2 years:
30.2 years = ln 2 / K
K = 0.02295 years⁻¹
Replacing this result and with the given data of the problem:
Ln[A] = -Kt + ln[A]₀
Ln[A] = -0.02295 years⁻¹* t + ln[A]₀
Ln ([A] / [A₀]) = -0.02295 years⁻¹* t
As you want time when [A] is 20% of [A]₀, [A] / [A]₀ = 0.2:
Ln (0.2) = -0.02295 years⁻¹* t
70.1 years = t
There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original valueUsing only sodium carbonate, Na2CO3, sodium bicarbonate, NaHCO3, and distilled water determine how you could prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3. The total molarity of the ions should be 0.20 M. The Ka of the hydrogen carbonate ion, HCO3 - , is 4.7 x 10-11 .
Answer:
Weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.
Explanation:
The pH of a buffered solution can be calculated using the Henderson-Hasselbalch equation:
[tex] pH = pKa + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]
We have that pH = 10.3 and the Ka is 4.7x10⁻¹¹, so:
[tex] 10.3 = -log(4.7 \cdot 10^{-11}) + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]
[tex] \frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex] (1)
Also, we know that:
[tex] [Na_{2}CO_{3}] + [NaHCO_{3}] = 0.20 M [/tex] (2)
From equation (2) we have:
[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] [/tex] (3)
By entering (3) into (1):
[tex] \frac{0.20 - [NaHCO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex]
[tex] 0.94*[NaHCO_{3}] + [NaHCO_{3}] = 0.20 [/tex]
[tex] [NaHCO_{3}] = 0.103 M [/tex]
Hence, the [Na_{2}CO_{3}] is:
[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] = 0.20 M - 0.103 M = 0.097 M [/tex]
Now, having the concentrations and knowing the volume of the buffer solution we can find the mass of the sodium carbonate and the sodium bicarbonate, as follows:
[tex]m_{Na_{2}CO_{3}} = C*V*M = 0.097 mol/L*0.050 L*105.99 g/mol = 0.5141 g[/tex]
[tex]m_{NaHCO_{3}} = C*V*M = 0.103 mol/L*0.050 L*84.007 g/mol = 0.4326 g[/tex]
Therefore, to prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3 we need to weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.
I hope it helps you!
Acetonitrile (CH3CN) is an important industrial chemical. Among other things, it is used to make plastic moldings, which have multiple uses, from car parts to Lego bricks. Which one of the following statements about acetonitrile is not correct?a. Acetonitrile has 16 valence electrons in its Lewis structure. b. Acetonitrile has one triple bond. c. Acetonitrile has one pair of nonbonding electrons. d. All atoms satisfy the octet rule in acetonitrile. e. One carbon atom and the nitrogen atom have nonzero formal charges.
Answer:
One carbon atom and the nitrogen atom have nonzero formal charges.
Explanation:
The compound Acetonitrile has sixteen valence electrons as is easily San from its structure. It contains a carbon nitrogen triple bond with a lone pair of electrons on nitrogen. All atoms satisfy the octet rule and there is no hyper valent atom in the molecule.
The formal charge an carbon and nitrogen is calculated as follows;
No. of valence electron on atom - [non bonded electrons + no. of bonds]
Therefore, for carbon and nitrogen, we have;
formal charge on carbon = 4 - (0 + 4) = 0
formal charge on nitrogen = 5 - (2 + 3) = 0
Hence carbon and nitrogen both possess zero formal charges.
2) What is the concentration (M) of CH3OH in a solution prepared by dissolving 11.7 g of CH3OH in sufficient water to give exactly 230 mL of solution?
A sample is found to contain 1.29×10-11 g of salt. Express this quantity in picograms
Answer:12.9e-12g or in short 12.9pg
Explanation:as p=1e-12
