Answer:
Half-life at 629K = 252.4min
Explanation:
Using Arrhenius equation:
[tex]ln\frac{K_1}{K_2} = \frac{Ea}{R} (\frac{1}{T_2} -\frac{1}{T_1})[/tex]
And as Half-life in a first order reaction is:
[tex]t_{1/2}=\frac{ln2}{K}[/tex]
We can convert the half-life of 58.0min to know K₁ adn replacing in Arrhenius equation find half-life at 629K:
[tex]58.0min=\frac{ln2}{K}[/tex]
K = 0.01195min⁻¹ = K₁
[tex]ln\frac{0.01195min^{-1}}{K_2} = \frac{218kJ/mol}{8.314x10^{-3}kJ/molK} (\frac{1}{629K} -\frac{1}{652K})[/tex]
[tex]ln\frac{0.01195min^{-1}}{K_2} =1.47[/tex]
[tex]\frac{0.01195min^{-1}}{K_2} =4.35[/tex]
K₂ = 2.75x10⁻³ min⁻¹
And, replacing again in Half-life expression:
[tex]t_{1/2}=\frac{ln2}{2.75x10^{-3}min^{-1}}[/tex]
Half-life at 629K = 252.4minThe half-life of the first-order reaction of ethylene oxide decomposition at 629 K is 251.1 min when the half-life at 652 K is 58.0 min and the activation energy is 218 kJ/mol.
The activation energy of a reaction is related to its rate constant as follows:
[tex] k = Ae^{-\frac{E_{a}}{RT}} [/tex] (1)
Where:
k: is the rate constant A: is the pre-exponential factor[tex]E_{a}[/tex]: is the activation energy of the reaction = 218 kJ/mol R: is the gas constant = 8.314 J/(K*mol)T: is the temperature
We can find the rate constant of the first-order reaction at 652 K with the half-life as follows:
[tex]k_{652} = \frac{ln(2)}{t_{1/2}_{(652)}}[/tex] (2)
Where [tex]t_{1/2}_{(652)}[/tex] is the half-life at 652 K= 58.0 min
Hence, the rate constant at 652 K is:
[tex] k_{652} = \frac{ln(2)}{58.0 min} = 0.012 min^{-1} [/tex]
Now, from equation (1) we can find the pre-exponential factor (A):
[tex]A = \frac{k_{652}}{e^{(-\frac{E_{a}}{RT_{1}})}} = \frac{0.012 \:min{-1}}{e^{(-\frac{218\cdot 10^{3} \:J/mol}{8.314 \:J/(K*mol)*652 \:K})}} = 3.51 \cdot 10^{15} min^{-1}[/tex]
With the pre-exponential factor we can calculate the rate constant at 629 K (eq 1):
[tex]k_{629} = 3.51 \cdot 10^{15} min^{-1}*e^{(-\frac{218 \cdot 10^{3} J/mol}{8.314 J/(K*mol)*629 K})} = 2.76 \cdot 10^{-3} min^{-1}[/tex]
Finally, the half-life at 629 K is (eq 2):
[tex] t_{1/2}_{629} = \frac{ln(2)}{2.76\cdot 10^{-3} min^{-1}} = 251.1 min [/tex]
Therefore, the half-life at 629 K is 251.1 min.
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How has the work of chemists affected the environment over the years?
Answer:
Chemistry is one of the causes for global warming, and in some cases it can even cause certain illnesses.
Answer:
Chemists have both hurt the environment and helped the environment by their actions.
Explanation:
<3
The front curve of a spectacle lens is called?
Answer:
Corrective lense or just lens.
Explanation:
Sulfur dioxide reacts with oxygen to form sulfur trioxide. What change in hybridization of the sulfur occurs in this reaction ? g
Answer:
PLEASE LOOK INN TO THE FILE YOU WILL GET ANSWER AND ALSO SUMMARY THANKS FOR ASKING QUESTION.
Explanation:
A student sets up the following equation to convert a measurement. The (?) Stands for a number the student is going to calculate. Fill in the missing part of this equation. (0.030 cm^3) x ? =m^3
Answer:
\text{0.30 cm}^{3} \times \left (\dfrac{10^{-2}\text{ m}}{\text{1 cm}}\right )^{3} = 3.0 \times 10^{-7} \text{ m}^{3}
Explanation:
0.030 cm³ × ? = x m³
You want to convert cubic centimetres to cubic metres, so you multiply the cubic centimetres by a conversion factor.
For example, you know that centi means "× 10⁻²", so
1 cm = 10⁻² m
If we divide each side by 1 cm, we get 1 = (10⁻² m/1 cm).
If we divide each side by 10⁻² m, we get (1 cm/10⁻² m) = 1.
So, we can use either (10⁻² m/1 cm) or (1 cm/10⁻² m) as a conversion factor, because each fraction equals one.
We choose the former because it has the desired units on top.
The "cm" is cubed, so we must cube the conversion factor.
The calculation becomes
[tex]\text{0.30 cm}^{3} \times \left (\dfrac{10^{-2}\text{ m}}{\text{1 cm}}\right )^{3} = 0.30 \times 10^{-6}\text{ m}^{3} = \mathbf{3.0 \times 10^{-7}} \textbf{ m}^{\mathbf{3}}\\\\\textbf{0.30 cm}^{\mathbf{3}} \times \left (\dfrac{\mathbf{10^{-2}}\textbf{ m}}{\textbf{1 cm}}\right )^{\mathbf{3}} = \mathbf{3.0 \times 10^{-7}} \textbf{ m}^{\mathbf{3}}[/tex]
Beginning with Na, record the number of energy levels, number of protons, and atomic radius for each element in period 3.
Answer:
Sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon are the elements of third period.
Explanation:
There are three energy levels in sodium atom. It has 11 electrons revolving around the nucleus. the atomic radius of sodium atom is 227 ppm. Magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon has also three energy levels like sodium because all these elements belongs to third period. There are 12 electrons present in magnesium, 13 in aluminium, 14 in silicon, 15 in phosphorus, 16 in sulfur, 17 in chlorine, and 18 electrons in argon. The atomic radius of magnesium atom is 173 ppm. The atomic radius of aluminium atom is 143 ppm. The atomic radius of silicon atom is 111 ppm. The atomic radius of phosphorus atom is 98 ppm. The atomic radius of sulfur atom is 87 ppm. The atomic radius of chlorine atom is 79 ppm and the atomic radius of argon atom is 71 ppm.
105/22 • (1.251 - 0.620)=
Answer:
105/22*(1.251-0.620)
105/22*0.631
4.772*0.631
3.011132
Hope it helps
Answer:
3.0
Explanation:
First, complete the operations inside the parenthesis according to the normal rules for significant figures. Because there are subsequent calculations, keep at least one extra significant figure when possible: (4.7727) × (0.631).
The final product will be rounded to two significant figures because it can’t be more precise than the least precise number in the problem, 22. The final product is 3.0.
a. Name a chemical or product that was once considered safe but is now considered
harmful. (1 point)
-
Answer:
Bisphenol A (BPA)
Explanation:
Bisphenol A (BPA) is a chemical additive commonly found in resins and plastics, such as water bottles or food containers. It can also be found in household electronics, medical devices, dental fillings and sales receipts, just to name a few other applications.
What are the conjugate acid-base pairs in the following chemical reaction? HBr(aq)+ CH3COOH(aq) ⇌ CH3C(OH)2+(aq) + Br-(aq)
Answer:
HBr, CH3C(OH)2 and CH3COOH, Br-
Explanation:
The conjugate acid-base pairs acid reacts with base to form a conjugate acid and conjugate base.
Conjugate acid is formed when a bases receives a proton (H+) and a conjugate base is formed when an acid losses a proton (H+).
From the given equation:
HBr, CH3C(OH)2 and CH3COOH, Br- are conjugate acid-base pair, where HBr is an acid and CH3C(OH)2 is a conjugate acid while CH3COOH and Br- is the conjugate base.
When 91.96g of Na reacts with 32.o g of O2 how many grams of NaO2 are produced
Answer:
123.96 g Na₂O
Explanation:
4 Na + O₂ ⇒ 2 Na₂O
You first need to find the limiting reagent. Convert the reactants to moles and see which produces the least amount of product using the mole ratios in the chemical equation.
(91.96 g Na)/(22.99 g/mol Na) = 4 mol Na
(4 mol Na) × (2 mol Na₂O/4 mol Na) = 2 mol Na₂O
(32.0 g O₂)/(32.0 g/mol) = 1 mol O₂
(1 mol O₂) × (2 mol Na₂O/1 mol O₂) = 2 mol Na₂O
Since they both produce the same amount of product, you don't need to pick a limiting reagent. Now, convert moles of Na₂O to grams.
(2 mol Na₂O) × (61.98 g/mol Na₂O) = 123.96 g Na₂O
Which of the following is required for the flow of current in all systems?
a) the presence of ions
b) an electrical potential ofo
c) a closed circuit
d) a short circuit
Answer:
I would say c) a closed circuit.
Hope I was right.
Fireworks are chemical reactions that release energy. Which of these phenomena are caused by chemical reactions that release energy? If you’re not sure, make a guess.
Answer:
All chemical reactions involve energy. Energy is used to break bonds in reactants, and energy is released when new bonds form in products. Endothermic reactions absorb energy, and exothermic reactions release energy. The law of conservation of energy states that matter cannot be created or destroyed.
What chemical bonds hold atoms?
The argon atoms are excited into an excited state before emitting the 488.0 nm laser. It is known that the energy of the first ionization energy of argon is 1520 kJ mol-1. What is the energy level of the excited state (in unit eV) lies below the vacuum energy level (0 eV)
Answer:
Explanation:
Given that:
The argon atoms are excited into an excited state before emitting the 488.0 nm laser.
the energy of the first ionization energy of argon is 1520 kJ mol-1.
SInce 1 eV = 96.49 kJ/mol
Therefore, the energy of the first ionization energy of argon in eV is = ( 1520/ 96.49) eV
= 15.75 eV
To find where the energy level of the excited state lies below the vacuum energy level, let's first determine, the energy liberated by using planck expression.
[tex]E = \dfrac{hc}{\lambda}[/tex]
[tex]E = \dfrac{6.6 \times 10^{-34} \times 3 \times 10^8}{488 \times 10^{-9}}[/tex]
[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]
[tex]E = \dfrac{1.98 \times 10^{-25}}{488 \times 10^{-9}}[/tex]
[tex]E =4.057 \times 10^{-19} \ J[/tex]
Converting Joules (J) to eV ; we get,
[tex]E =\dfrac{4.057 \times 10^{-19}}{1.6 \times 10^{-19}}[/tex]
E = 2.53 eV
The energy levels of the first exited state = -13.223 eV
An ice cube at 0.00C with a mass of 8.32g is placed Into 55g of water, initially at 25C. If no heat is lost to the surroundings, what is the final temperature of the entire water sample after all the ice is melted (answer must be in 3 sig figs)
Answer:
The final temperature of the entire water sample after all the ice is melted, is 12,9°C. We should realize that if there is no loss of heat in our system, the sum of lost or gained heat is 0. It is logical to say that the temperature has decreased because the ice gave the water "heat" and cooled it
Thats all i know
The reaction of butadiene gas (C4H6) with itself produces C8H12 gas as follows: The reaction is second order with a rate constant equal to 5.76 × 10−2 L/mol/min under certain conditions. If the initial concentration of butadiene is 0.200 M, what is the concentration in molarity remaining after 10.0 min? Report your answer to 3 decimal places.
Answer:
[tex]C_{C_4H_6}=0.179M[/tex]
Explanation:
Hello,
In this case, the undergoing chemical reaction is:
[tex]2C_4H_6\rightarrow C_8H_{12}[/tex]
And the rate law is:
[tex]\frac{dC_{C_4H_6}}{dt}=kC_{C_4H_6}^2[/tex]
Which integrated is:
[tex]\frac{1}{C_{C_4H_6}} =\frac{1}{C_{C_4H_6}^0}+kt[/tex]
In such a way, the concentration after 10.0 min is:
[tex]\frac{1}{C_{C_4H_6}} =\frac{1}{0.200M}}+5.76x10^{-2}\frac{L}{mol*min}*10.0min\\ \\\frac{1}{C_{C_4H_6}}=5.58\frac{L}{mol} \\\\C_{C_4H_6}=\frac{1}{5.58\frac{L}{mol} } \\\\C_{C_4H_6}=0.179M[/tex]
Regards.
What would happen to the measured cell potentials if 30 mL solution was used in each half-cell instead of 25 mL
Answer:
The answer is "[tex]\bold{\log \frac{[0] mole}{[R]mole}}[/tex]"
Explanation:
[tex]E_{cell} =E_{cell}^{\circ} - \frac{0.0591}{n}= \log\frac{[0]}{[R]}\\[/tex]
In the above-given equation, we can see from [tex]E_{ceu}[/tex], of both oxidant [tex]conc^n[/tex]as well as the reactant were connected. however, weight decreases oxidant and reduction component concentration only with volume and the both of the half cells by the very same factor and each other suspend
[tex]\to \log \frac{\frac{\text{oxidating moles}}{25 \ ml}}{\frac{\text{moles of reduction}}{25 ml}} \ \ = \ \ \log \frac{\frac{\text{oxidating moles}}{30 \ ml}}{\frac{\text{moles of reduction}}{30 ml}} \\\\\\[/tex]
[tex]\to {\log \frac{[0] mole}{[R]mole}}[/tex]
The cell potential of the electrochemical reaction has been the same when the volume has been reduced from 30 mL to 25 mL in each half cells.
The cell potential has been given as the difference in the potential of the two half cells in the electrochemical reaction.
The two cells has been set with the concentration of solutions in the oxidation and reduction half cells.
Cell potential changeThe cell potential has been changed when there has been a change in the potential of the half cells.
The volume of 30 mL to the solution has been, resulting in the cell potential difference of x.
With the volume of 25 mL, there has been the difference in the potential being similar to the 30 mL solution, i.e. x.
Thus, the cell potential of the electrochemical reaction has been the same when the volume has been reduced from 30 mL to 25 mL in each half cells.
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According to the following reaction, how many moles of ammonia will be formed upon the complete reaction of 31.2 grams of nitrogen gas with excess hydrogen gas ? nitrogen(g) + hydrogen(g) ammonia(g)
Answer:
4.46 mol of NH3
Explanation:
The equation of he reaction is given as;
2N + 3H2 --> 2NH3
From the stochiometry of the reaction, 1 mol of Nitrogen produces 2 mol of Ammonia.
Mass of Nitrogen = 31.2g
Molar mass of Nitrogen = 14g/mol
Number of moles = Mass / Molar mass = 31.2 / 14 = 2.23 mol
Since 1 mol of N = 2 mol of NH3;
2.23 mol of N2 would produce x
x = 2.23 * 2 = 4.46 mol of NH3
The ΔHvap of nitrous oxide is 16.53 kJ · mol−1 and its ΔSvap is 89.51 J · mol−1 · K−1. What it the boiling point of nitrous oxide?
Answer:
[tex]T_b=-88.48\°C[/tex]
Explanation:
Hello,
In this case, since the entropy of vaporization is defined in terms of the enthalpy of vaporization and the boiling point of the given substance, nitrous oxide, as shown below:
[tex]\Delta _{vap}S=\frac{\Delta _{vap}}{T_b}[/tex]
Solving for the boiling point of nitrous oxide, we obtain:
[tex]T_b=\frac{\Delta _{vap}H}{\Delta _{vap}S}=\frac{16.53\frac{kJ}{mol}*\frac{1000J}{1kJ} }{89.51\frac{J}{mol} } \\ \\T_b=184.67K[/tex]
Which in degree Celsius is also:
[tex]Tb=184.67-273.15\\\\T_b=-88.48\°C[/tex]
Best regards.
21. What are the two main ways of working with clay?
Answer:
Diferentes tipos de arcilla
ARCILLA DE LADRILLOS. Contiene muchas impurezas. ...
ARCILLA DE ALFARERO. Llamada también barro rojo y utilizada en alfarería y para modelar. ...
ARCILLA DE GRES. Es una arcilla con gran contenido de feldespato. ...
ARCILLAS “BALL CLAY” O DE BOLA. ...
CAOLIN. ...
ARCILLA REFRACTARIA. ...
BENTONITA.
Explanation:
Answer:
Coil method and the slab method.
Explanation:
The intermolecular forces present in CH 3NH 2 include which of the following? I. dipole-dipole II. ion-dipole III. dispersion IV. hydrogen bonding
Answer:
I. dipole-dipole
III. dispersion
IV. hydrogen bonding
Explanation:
Intermolecular forces are weak attraction force joining nonpolar and polar molecules together.
London Dispersion Forces are weak attraction force joining non-polar and polar molecules together. e.g O₂, H₂,N₂,Cl₂ and noble gases. The attractions here can be attributed to the fact that a non -polar molecule sometimes becomes polar because the constant motion of its electrons may lead to an uneven charge distribution at an instant.
Dispersion forces are the weakest of all electrical forces that act between atoms and molecules. The force is responsible for liquefaction or solidification of non-polar substances such as noble gas an halogen at low temperatures.
Dipole-Dipole Attractions are forces of attraction existing between polar molecules ( unsymmetrical molecules) i.e molecules that have permanent dipoles such as HCl, CH3NH2 . Such molecules line up such that the positive pole of one molecule attracts the negative pole of another.
Dipole - Dipole attractions are more stronger than the London dispersion forces but weaker than the attraction between full charges carried by ions in ionic crystal lattice.
Hydrogen Bonding is a dipole-dipole intermolecular attraction which occurs when hydrogen is covalently bonded to highly electronegative elements such as nitrogen, oxygen or fluorine. The highly electronegative elements have very strong affinity for electrons. Hence, they attracts the shared pair of electrons in the covalent bonds towards themselves, leaving a partial positive charge on the hydrogen atom and a partial negative charge on the electronegative atom ( nitrogen in the case of CH3NH2 ) . This attractive force is know as hydrogen bonding.
Answer:
The intermolecular forces present in CH_3NH_2 includes
II. (ion-dipole) and IV. (hydrogen bonding)Explanation:
The intermolecular forces present in CH_3NH_2 includes II. (ion-dipole) and IV. (hydrogen bonding)
It is a polar molecule due to NH polar bond and it can form Hydrogen bond also due to NH bond.
Interaction will be dipole- dipole and Hydrogen dispersion forces can always be taken into account.
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2.Which of the alcohols listed below would you expect to react most rapidly with PBr3?A)CH3CH2CH2CH2CH2CH2OHB)(CH3CH2)2CH(OH)CH2CH3C)(CH3CH2)2CHOHCH3D)(CH3CH2)3COHE)(CH3CH2)2C(CH3)OH
Answer:
A) CH3CH2CH2CH2CH2CH2OH
Explanation:
For this question, we have the following answer options:
A) CH3CH2CH2CH2CH2CH2OH
B) (CH3CH2)2CH(OH)CH2CH3
C) (CH3CH2)2CHOHCH3
D) (CH3CH2)3COH
E) (CH3CH2)2C(CH3)OH
We have to remember the reaction mechanism of the substitution reaction with [tex]PBr_3[/tex]. The idea is to generate a better leaving group in order to add a "Br" atom.
The [tex]PBr_3[/tex] attacks the "OH" generation new a bond to P (O-P bonds are very strong), due to this new bond we will have a better leaving group that can remove the oxygen an allow the attack of the Br atom to generating a new C-Br bond. This is made by an Sn2 reaction. Therefore we will have a faster reaction with primary substrates. In this case, the only primary substrate is molecule A. So, "CH3CH2CH2CH2CH2CH2OH" will react faster.
See figure 1
I hope it helps!
What's the name for the part of Earth made of rock?
A. Geosphere
B. Atmosphere
C. Hydrosphere
D. Biosphere
SUBMIT
Answer:I think it's Geosphere
Explanation:
Answer:
A
Explanation:
Geo means rock, or earth. Hydro means water, Atmosphere is space, and Bio global ecosystem composed of living organisms
A student is using a coffee-cup calorimeter to determine the enthalpy change of the endothermic reaction of two aqueous solutions. After both solutions are added to the cup, the student neglects to put the lid on the cup. This would cause the magnitude of the calculated ΔH° value to be: the answer is: too small, since the solution will absorb heat from the room. But why? Wouldn't depend on if the reaction releases or absorbs heat. Wouldn't it be too large because heat escapes the cup? I'm so confused
Answer:
Explanation:
In all calorimetric experiment , the calorimeter must be isolated from the surrounding . Otherwise the heat change in the experiment can not be determined with precision .
The reaction is endothermic . Hence, there is lowering of temperature due to absorption of heat in the reaction equal to ΔH°. The value of ΔH° can be calculated by measuring fall in the temperature of the content . The fall in the temperature will be less when heat is allowed to come from the surrounding . Less fall of temperature will result in less ΔH° to be calculated .
Hence in the given experiment , if the student neglects to put lid on the cup , the experiment will give less value of ΔH°.
Calculate the entropy change in the surroundings associated with this reaction occurring at 25∘C. Express the entropy change to three significant figures and include the appropriate units.
Answer:
That means that if you are calculating entropy change, you must multiply the enthalpy change value by 1000. So if, say, you have an enthalpy change of -92.2 kJ mol-1, the value you must put into the equation is -92200 J mol-1
The entropy change in the surroundings associated with this reaction occurring at 25 degree C is calculated as ΔS = -ΔH/T J/K.
What is entropy?Entropy is a quantity which gives idea about the randomness or arrangement of atoms or molecules present in any sample.
Entropy change will be calculated as:
ΔS = -ΔH/T, where
ΔH = chnage in enthalpy (J/mole)
T = temperature (K)
So to calculate the entropy change first we have to know about the value of enthalpy in joules and then divide it by the temperature.
Hence the unit of entropy is joule per kelvin.
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A piece of solid metal is put into an aqueous solution of . Write the net ionic equation for any single-replacement redox reaction. Assume that the oxidation state of in the resulting solution is 2 .
The question is incomplete,the complete question is as follows:
A piece of solid Fe metal is put into an aqueous solution of Cu(NO3)2. Write the net ionic equation for any single-replacement redox reaction that may be predicted. Assume that the oxidation state of in the resulted solution is 2 . (Use the lowest possible coefficients for the reaction. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank. If no reaction occurs, leave all boxes blank and click on Submit.)
Answer:
Fe(s) + Cu^2+(aq) => Fe^2+(aq) + Cu(s)
Explanation:
An ionic equation is a chemical equation which shows clear image of reactions of the electrolytes in aqueous solution.
Molecular reaction equation for the reaction between iron and copper II nitrate is as follows:
Fe(s) + Cu(NO3)2(aq) => Fe(NO3)2(aq) +Cu(s)
The net ionic equation for any single-replacement redox reaction is as follows:
Fe(s) + Cu^2+(aq) => Fe^2+(aq) + Cu(s)
To find the pH of a solution of NaNO2, one would have to construct an ICE chart using:
a. the Kb of NO−2 to find the hydroxide concentration.
b. the Kb of HNO2 to find the hydronium concentration.
c. the Kb of NO-2, to find the hydronium concentration.
d. the Kb of HNO2, to find the hydroxide concentration.
Answer:
a. the Kb of NO₂⁻ to find the hydroxide concentration.
Explanation:
When sodium nitrite is dissolved in water, it dissociates in sodium cation and nitrite anion according to the following equation.
NaNO₂(s) ⇒ Na⁺(aq) + NO₂⁻(aq)
Na⁺ comes from NaOH (strong base) so it doesn't react with water.
NO₂⁻ comes from HNO₂ (weak acid) so it reacts with water according to the following equation.
NO₂⁻(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq)
This is the basic reaction of nitrite ion, so we need the Kb of NO₂⁻ to find the hydroxide concentration.
Divers often inflate heavy duty balloons attached to salvage items on the sea floor. If a balloon is filled to a volume of 1.20 L at a pressure of 6.25 atm, what is the volume of the balloon when it reaches the surface?
Answer:
7.50 L
Explanation:
The balloon has a volume of 1.20 L (V₁) when the pressure at the sea floor is 6.25 atm (P₁). When it reaches the surface, the pressure is that of the atmosphere, that is, 1.00 atm (P₂). If we consider the gas to behave as an ideal gas and the temperature to be constant, we can calculate the final volume (V₂) using Boyle's law.
P₁ × V₁ = P₂ × V₂
V₂ = P₁ × V₁ / P₂
V₂ = 6.25 atm × 1.20 L / 1.00 atm
V₂ = 7.50 L
f a substance has a half-life of 8.10 hr, how many hours will it take for 75.0 g of the substance to be depleted to 3.90 g?
Answer:
35 hrs
Explanation:
half life of the substance [tex]t_{1/2 }[/tex] = 8.1 hr
initial amount [tex]N_{0}[/tex] = 75 g
The final amount [tex]N[/tex] = 3.9 g
The time elapsed [tex]t[/tex] = ?
we use the relationship
[tex]N[/tex] = [tex]N_{0}[/tex] [tex](\frac{1}{2} )^{\frac{t}{t_{1/2} } }[/tex]
substituting values, we have
3.9 = 75 x [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
0.052 = [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
take the log of both side
log 0.052 = log [tex]\frac{1}{2}^{\frac{t}{8.1} }[/tex]
log 0.052 = [tex]\frac{t}{8.1}[/tex] log 1/2
-1.284 = [tex]\frac{t}{8.1}[/tex] x -0.301
1.284 = 0.301t/8.1 =
1.284 = 0.0372t
t = 1.284/0.037 = 34.5 ≅ 35 hrs
Comparing the 2-bromobutane + methoxide and 2-bromobutane + t-butoxide reactions, choose the statements that BEST describe the data and mechanism. a. the mechanism for this reaction is E2 b. an increase in 1-butene was observed when t-butoxide was used c. an increase in 1-butene was observed when methoxide was used d. the mechanism for this reaction is E1 e. no significant difference was observed
Answer:
an increase in 1-butene was observed when t-butoxide was used
Explanation:
When a base reacts with an alkyl halide, an elimination product is formed. This reaction is an E2 reaction.
Here we are to compare the reaction of two different bases with one substrate; 2-bromobutane. Both reactions occur by the E2 mechanism but follow different transition states due to the size of the base.
The Saytzeff product, 2-butene, is obtained when the methoxide is used while the non Saytzeff product, 1-butene, is obtained when t-butoxide is used.
The Saytzeff rule is reliable in predicting the major products of simple elimination reactions of alkyl halides given the fact that a small/strong bases is used for the elimination reaction. Therefore hydroxide, methoxide and ethoxide bases give similar results for the same alkyl halide substrate. Bulky bases such as tert-butoxide tend to yield a higher percentage of the non Saytzeff product and this is usually attributed to steric hindrance.
A solution containing a unknown ionic compound, vigorously bubbles when hydrochloric acid (HCl) is added to the solution. This might indicate that the solution contains which anion?
Answer:
CO3^2-
Explanation:
In qualitative analysis, we try to use chemical reactions to determine the composition of an unknown substance. The addition of certain reagents to the unknown solution gives certain results that show the presence or absence of certain species from the unknown sample.
When dilute HCl is added to an unknown sample and effervescence is observed, then the unknown sample must contain CO3^2- or HCO3^-. The presence of these species is confirmed if the gas evolved is passed through limewater and the gas turns limewater milky.
