Rectangular cube 3.2 m length 1.2 m in height and 5 m in length is split into two parts. The container has a movable airtight divider that divides its length as necessary. Part A has 58 moles of gas and part B has 165 moles of a gas.

Required:
At what length will the divider to equilibrium?

Answer:

your answer is given below

Explanation:

Take it stepwise, and you are going to have to look up the various heat values.

You have 36.5grams of ice, presumably at 0C.  You will need to add heat to take the ice at 0 C to water at 0 C. (Latent heat of melting)  Then you add in a different heat value to take the water at 0 C to water at 82.3 C. (Specific heat of water)

Add the two heat amounts together.

According to specific heat capacity, to calculate the amount of heat needed to melt ice given mass of ices is multiplied by specific heat of ice and the temperature change which it undergoes.

Specific heat capacity is defined as the amount of energy required to raise the temperature of one gram of substance by one degree Celsius. It has units of calories or joules per gram per degree Celsius.

It varies with temperature and is different for each state of matter. Water in the liquid form has the highest specific heat capacity among all common substances .Specific heat capacity of a substance is infinite as it undergoes phase transition ,it is highest for gases and can rise if the gas is allowed to expand.

It is given by the formula ,

Q=mcΔT

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A 1.0-L buffer solution contains 0.100 mol  HC2H3O2 and 0.100 mol  NaC2H3O2. The value of Ka for HC2H3O2 is 1.8×10−5.

Calculate the pH of the solution, upon addition of 0.035 mol of NaOH to the original buffer.

Answer:

The pH of this solution = 5.06  

Explanation:

Given that:

number of moles of CH3COOH = 0.100 mol

volume of the buffer solution = 1.0 L

number of moles of NaC2H3O2 = 0.100 mol

The objective is to Calculate the pH of the solution, upon addition of 0.035 mol of NaOH to the original buffer.

we know that concentration in mole = Molarity/volume

Then concentration of [CH3COOH] = [tex]\mathtt{ \dfrac{0.100 \ mol}{ 1.0 \ L }}[/tex]  = 0.10 M

The chemical equation for this reaction is :

[tex]\mathtt{CH_3COOH + OH^- \to CH_3COO^- + H_2O}[/tex]

The conjugate base is CH3COO⁻

The concentration of the conjugate base [CH3COO⁻] is  = [tex]\mathtt{ \dfrac{0.100 \ mol}{ 1.0 \ L }}[/tex]  

= 0.10 M

where the pka (acid dissociation constant)for CH3COOH = 4.74

If 0.035 mol of NaOH is added  to the original buffer, the concentration of NaOH added will be = [tex]\mathtt{ \dfrac{0.035 \ mol}{ 1.0 \ L }}[/tex] = 0.035 M

The ICE Table for the above reaction can be constructed as follows:

                  [tex]\mathtt{CH_3COOH \ \ \ + \ \ \ \ OH^- \ \ \to \ \ CH_3COO^- \ \ \ + \ \ \ H_2O}[/tex]

Initial             0.10               0.035         0.10                  -

Change        -0.035          -0.035       + 0.035              -

Equilibrium    0.065              0              0.135               -

By using  Henderson-Hasselbalch equation:

The pH of this solution = pKa + log [tex]\mathtt{\dfrac{CH_3COO^-}{CH_3COOH}}[/tex]

The pH of this solution = 4.74 + log [tex]\mathtt{\dfrac{0.135}{0.065}}[/tex]

The pH of this solution = 4.74 + log (2.076923077 )

The pH of this solution = 4.74 + 0.3174

The pH of this solution = 5.0574

The pH of this solution = 5.06    to two decimal places

Answer:

1.12 × 10⁻⁴ M

Explanation:

Step 1: Write the reaction for the solution of Mg(OH)₂

Mg(OH)₂(s) ⇄ Mg²⁺(aq) + 2 OH⁻(aq)

Step 2: Make an ICE chart

We can relate the solubility product constant (Ksp) with the solubility (S) through an ICE chart.

       Mg(OH)₂(s) ⇄ Mg²⁺(aq) + 2 OH⁻(aq)

I                                0                    0

C                              +S                +2S

E                                S                  2S

The solubility product constant is:

Ksp = 5.61 × 10⁻¹² = [Mg²⁺] × [OH⁻]² = S × (2S)² = 4S³

S = 1.12 × 10⁻⁴ M

Answer:

CO2

Explanation:

Mass of carbon = 27.29

Mass of oxygen = 72.21

Step 1:

We have to first convert these masses to moles

Carbon = 2.29/2.01 = 2.274

Oxygen = 72.71/16 = 4.544

Step 2:

We have to divide the mols by the smallest mol to get simplest ratio of whole number.

The smallest mol is 2.274. we have to divide the mols by this.

2.274/2.274 = 1

4.544/2.274 = 2

Our empirical formula is therefore CO2

Answer:

A precipitate will form, BaCO₃

Explanation:

When Ba²⁺ and CO₃²⁻ ions are in an aqueous media, BaCO₃(s), a precipitate, is produced following its Ksp expression:

Ksp = 5.1x10⁻⁹ = [Ba²⁺] [CO₃²⁻]

Where the concentrations of the ions are the concentrations in equilibrium

For actual concentrations of a solution, you can define Q, reaction quotient, as:

Q = [Ba²⁺] [CO₃²⁻]

If Q > Ksp, the ions will react producing BaCO₃, if not, no precipitate will form.

Actual concentrations of Ba²⁺ and CO₃²⁻ are:

[Ba²⁺] = [Ba(NO₃)₂] = 1.1x10⁻³ × (20.0mL / 100.0mL) = 2.2x10⁻⁴M

[CO₃²⁻] = [Na₂CO₃] = 8.4x10⁻⁴ × (80.0mL / 100.0mL) = 6.72x10⁻⁴M

100.0mL is the volume of the mixture of the solutions

Replacing in Q expression:

Q = [Ba²⁺] [CO₃²⁻]

Q = [2.2x10⁻⁴M] [6.72x10⁻⁴M]

Q = 1.5x10⁻⁷

As Q > Ksp

Answer:

Bakelite is a polymer made up of the monomers phenol and formaldehyde. This phenol-formaldehyde resin is a thermosetting polymer.

Answer: The monomers of bakelite are formaldehyde and phenol

Explanation:

Explanation:

According to your question,

no. a. ans would be like; chemical formula is defined as the an expression which determines no. and type of molecule of a compound.

b. no. ans; it tells that what type of compound is formed with the type and no. of atoms present in the atom.

c. no ans; the formulation of h2so4 states that it is acid named as hydrochloric acid which is formed by reacting of hydrogen (2 atoms ) ,sulpher (*1atom) and oxygen(4atoms).

Hope it helps...

Answer:

b) the Ka of NH₄⁺ to find the hydronium concentration

Explanation:

The equilbrium of NH₄⁺ (The conjugate acid of NH₃, a weak base), is:

NH₄⁺ ⇄ NH₃ + H⁺

Where Ka of the conjugate acid is:

Ka = [NH₃] [H⁺] / [NH₄⁺]

Thus, if you know Ka of NH₄⁺ and its molar concentration you can calculate  [H⁺], the hydronium concentration, to find pH (Because pH =  -log [H⁺])

Thus, right option is:

Answer:

The reaction is given as:

[tex]NaOH(s)\rightarrow Na^+(aq)+OH^-(aq)[/tex]

Explanation:

Bases are defined as those chemical substances which give hydroxide ions in their aqueous solutions.

[tex]BOH(s)\rightarrow B^+(aq)+OH^-(aq)[/tex]

When sodium hydroxide is added to water it gets dissociated into two ions that are sodium ions and hydroxide ions. Along with this heat energy also releases during this reaction.

The reaction is given as:

[tex]NaOH(s)\rightarrow Na^+(aq)+OH^-(aq)[/tex]

The equation to show how NaOH behaves in water is NaOH → Na⁺ + (OH)⁻

The compound that produce negative hydroxide (OH−) ions when dissolved

in water are called bases .

This compounds NaOH (sodium hydroxide) is an example of a base.

When it dissolves in water it dissociate to form  negative hydroxide (OH−)

ions  and positive sodium (Na+) ions.

It can be represented by the following equation:

NaOH → Na⁺ + (OH)⁻

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Answer:

measure the parallax and use it in calculations

Explanation:

got it right on test

There are many more stars at different distances from the earth. The distance to the stars calculated in light years and it is measured using parallax method.Thus option a is correct.

Parallax method is used to measure the approximate distance of stars from earth. It uses the position of nearby star from two points opposite to earth and the small angular displacement observed from the remote stars are noted.

The orbit radius of earth and distance to the stars can be calculated from the parallactic angle p, that is one second of arc. Thus the distance is described in the units parsec.

The distance to the stars are usually calculated in light years. One parsec equals 3.26 light years. The nearest star to earth is named as proxima century having the distance parallax 0.76813'' which equals 4.24 light years. Thus, parallax is inversely proportional to the distance.

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Answer:

Option D. A lipid with three unsaturated fatty acid.

Explanation:

The molecule in the diagram above contains three fatty acid.

A careful observation of the molecule reveals that each of the three fatty acids contains a double bond.

The presence of a double bond in a compound shows that the compound is unsaturated.

Thus, we can say that the molecule is a lipid with three unsaturated fatty acid.

answer is oxygen .

oxygen is an exception in octet rule

Among the following given elements,oxygen is an element which cannot have an expanded octet.

Expanded octet is a condition where an octet has more than 8 electrons and which is called as hyper-valency state. This concept is related to hybrid orbital theory and Lewis theory. Hyper-valent compounds  are not less common  and are of equal stability as the compounds which obey octet rule.

Expansion of octet is possible for elements from third period on wards only as they have low-lying empty d - orbitals which can accommodate more than eight electrons.

Expanded octet is not applicable to oxygen as it is second period of periodic table and has less than ten electrons and even does  not have the 2d -orbitals   due to which it  does not fulfill the criteria of an element to have an expanded octet.

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Answer:

Explanation:

mass of W in gram  = mole x molecular weight

= .02 x 74 = 1.48 gm

mass of V in gram

first of all we shall calculate the no of moles of V

1 mole = 6.0 x  10²³ atoms

1 x 10²³ atoms = 1 / 6 moles

mass of V in grams

= 40 / 6

= 6.67 grams .

So V has greater mass .

ii )

molecular weight of sodium chloride

= 58.5 gm

14.63 gram of sodium chloride

= 14.63 / 58.5 = .25 moles

250 cm³ = 250 x 10⁻³ dm³

So 250 x 10⁻³ dm³ of solution contains .25 moles of salt

1 dm³ of solution will contain .25 / 250 x 10⁻³ mole

= 1 mole

so concentration of solution is 1 mole per dm³

Answer:

0.52 g of chromium(II) hydroxide, Cr(OH)2.

Explanation:

We'll begin by calculating the number of mole of chromium (ii) chloride, CrCl2 in 35.9 mL of 0.258 M chromium(II) chloride solution.

This can be obtained as follow:

Molarity of CrCl2 = 0.258 M

Volume = 35.9 mL = 35.9/1000 = 0.0359 L

Mole of CrCl2 =?

Molarity = mole /Volume

0.258 = mole of CrCl2 /0.0359

Cross multiply

Mole of CrCl2 = 0.258 x 0.0359

Mole of CrCl2 = 0.0093 mole

Next, we shall determine the number of mole of potassium hydroxide, KOH in 35.8 mL 0.338 M potassium hydroxide solution.

This can be obtained as follow:

Molarity of KOH = 0.338 M

Volume = 35.8 mL = 35.8/1000 = 0.0358 L

Mole of KOH =.?

Molarity = mole /Volume

0.338 = mole of KOH /0.0358

Cross multiply

Mole of KOH = 0.338 x 0.0358

Mole of KOH = 0.0121 mole.

Next, we shall write the balanced equation for the reaction. This is given below:

2KOH + CrCl2 → Cr(OH)2 + 2KCl

From the balanced equation above,

2 mole of KOH reacted with 1 mole of CrCl2 to produce 1 mole of Cr(OH)2.

Next, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

2 mole of KOH reacted with 1 mole of CrCl2.

Therefore, 0.0121 mole of KOH will react with = (0.0121 x 1)/2 = 0.00605 mole of CrCl2.

From the calculations made above, we can see that only 0.00605 mole out of 0.0093 mole of CrCl2 is needed to react completely with 0.0121 mole of KOH.

Therefore, KOH is the limiting reactant.

Next, we shall determine the number of mole of Cr(OH)2 produced from the reaction.

In this case, we shall be using the limiting reactant because it will give the maximum yield of Cr(OH)2.

The limiting reactant is KOH and the number of mole of Cr(OH)2 produced can be obtained as illustrated below:

From the balanced equation above,

2 mole of KOH reacted to produce 1 mole of Cr(OH)2.

Therefore, Therefore, 0.0121 mole of KOH will react with = (0.0121 x 1)/2 = 0.00605 mole of Cr(OH)2.

Finally, we shall convert 0.00605 mole of Cr(OH)2 to grams.

This is illustrated below:

Mole of Cr(OH)2 = 0.00605 mole

Molar mass of Cr(OH)2 = 52 + 2(16 + 1) = 52 + 2(17) = 86 g/mol

Mass of Cr(OH)2 =..?

Mole = mass /Molar mass

0.00605 = mass of Cr(OH)2/86

Cross multiply

Mass of Cr(OH)2 = 0.00605 x 86

Mass of Cr(OH)2 = 0.52 g

Therefore, 0.52 g of chromium(II) hydroxide, Cr(OH)2 was produced.

Answer:

a. Rate = k×[A]

b. k = 0.213s⁻¹

Explanation:

a. When you are studying the kinetics of a reaction such as:

A + B → Products.

General rate law must be like:

Rate = k×[A]ᵃ[B]ᵇ

You must make experiments change initial concentrations of A and B trying to find k, a and b parameters.

If you see experiments 1 and 3, concentration of A is doubled and the Rate of the reaction is doubled to. That means a = 1

Rate = k×[A]¹[B]ᵇ

In experiment 1 and to the concentration of B change from 1.50M to 2.50M but rate maintains the same. That is only possible if b = 0. (The kinetics of the reaction is indepent to [B]

Rate = k×[A][B]⁰

b. Replacing with values of experiment 1 (You can do the same with experiment 3 obtaining the same) k is:

Rate = k×[A]

0.320M/s = k×[1.50M]

Answer:

Explanation:

mass -  15.8 g = 0.0158 kg

volume = 32.5 - 22.5 = 10.2 ml

density = mass / volume

= 0.0158 / 10.2

= 0.00154 kg/ml

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Answer:

ΔG°  = 1022. 8 kJ

Explanation:

ΔH° = –199 kJ/mol

ΔS° = –4.1 J/K·mol

T = 25°C = 25 + 273 = 298K (Converting to kelvin temperature)

ΔG° = ?

The relationship between these varriables are;

ΔG° = ΔH°  - TΔS°

ΔG° = –199 - 298 (–4.1)

ΔG° = -199 + 1221.8

ΔG°  = 1022. 8 kJ

To calculate ΔG, the following equation should be used:

ΔG° = ΔH°  - TΔS°

Given:

ΔH° = –199 kJ/mol,  

ΔS° = –4.1 J/K·mol

T=25+273K=298K  

Substitute the respective values:

ΔG° = ΔH°  - TΔS°

       =–199 kJ/mol-(298K×(-4.1 J/K·mol*(1KJ/1000J)))

       =-197.78kJ/mol

Thus, we can conclude the value of ΔG°=-197.78kJ/mol  

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Answer:

It would increase by a factor of 2

Explanation:

The rate law for a fist order reaction is given as;

A --> B

rate = k [A]

upon doubling the concentration, we have;

rate = k [A]

rate 2 = k 2 [A]

Dividing both equations;

rate 2 / rate 1 = k 2 [A] / k [A]

rate 2 / rate 1  = 2 / 1

The ratio between rate 2 and rate 1 is 2 : 1. This means that the reaction rate would also increase by a factor of 2.

Explanation:

Entropy refers to the degree of disorderliness in a system. Generally solids have  a greater degree of order when compared to gas in which the molecules/particles move randomly in all directions.

The change in entropy from solid to gaseous phase is a positive change. Because there is increase disorderliness of the system.

Answer:

Any ionic molecule formed of a base and an acid, which dissolves in water to produce ions is known as a salt. The four common types of salts are:  

1. NaCl or sodium chloride is the most common kind of salt known. It is also known as table salt.  

2. K2Cr2O7 or potassium dichromate refers to an orange-colored salt formed of chromium, potassium, and oxygen. It is toxic to humans and is also an oxidizer, which is a fire hazard.  

3. CaCl2 or calcium chloride looks like table salt due to its white color. It is broadly used to withdraw ice from roads. It is hygroscopic.  

4. NaHSO4 or sodium bisulfate produces from hydrogen, sodium, oxygen, and sulfur. It is also known as dry acid. It has commercial applications like reducing the pH of swimming pools and spas and others.  

Answer:

[tex]6.4knips[/tex]

Explanation:

Hello,

In this case, given the stated equivalences, we can use the following proportional factor in order to compute the required knips:

[tex]knips=1.00knop*\frac{6bippy}{1knop} *\frac{8pringle}{10bippy}* \frac{3blip}{18pringle} *\frac{4clips}{5blips} *\frac{10knip}{1clip} \\\\=6.4knips[/tex]

Regards.

1 knop=6.4 knips

First convert knop to bippy:-

[tex]1\ knop\times\frac{6\ bippy}{1\ knop} =6\ bippy[/tex]

Now, Convert 6 bippy to pringle:-

[tex]6\ bippy\times\frac{8\ pringle}{10\ bippy} =4.8\ pringle[/tex]

Now, convert 4.8 pringle to blip:-

[tex]4.8\ pringle\times\frac{3\ blip}{18\ priangle} =0.8\ blip[/tex]

Now, convert 0.8 blip to clips as follows:-

[tex]0.8\ blip\times\frac{4\ clips}{5\ blip} =0.64\ clip[/tex]

Now, convert 0.64 clip to knips:-

[tex]0.64\ clip\times\frac{10\ knip}{1\ clip} =6.4\ knip[/tex]

Hence, the following conversion is as follows:-

1.00 knop=6.4 knips

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Answer:

the option e is correct I think

The solution is either saturated or supersaturated with solute

Answer:

the option e is correct I think

The solution is either saturated or supersaturated with solute

Explanation:

Answer:

The correct answer is: 0.064 V

Explanation:

In a oxidation-reduction reaction, the relation between Gibbs free energy (ΔGº) and cell potential (Eºcell) is given by:

[tex]\Delta G^{0} = -nFE^{0} _{cell}[/tex]

where n is the number of electrons that are transferred in the reaction and F is the Faraday constant (96,500 C/mol e-). Given: ∆G° = +18.55 kJ and n= 3 mol e-, we calculate Eºcell as follows:

+18.55 kJ = (-3 mol e-) x (96500 C/mol e-) x Eºcell

Eºcell= (+18.55 kJ)/(-3 mol e-) x (96500 C/mol e-)

Eºcell= (18550 J)/ (289500 C)

Eºcell= 0.064 J/C

Since 1 Volt= 1 Joule/1 Coulomb, thus:

Eºcell= 0.064 J/C = 0.064 V

Answer:

The best reducing agent is Zn(s)

Explanation:

A reducing agent must to be able to reduce another compound, by oxidizing itself. Consequently, the oxidation potential must be high. The oxidation potential of a compound is the reduction potential of the same compound  with the opposite charge. Given the reduction potentials, the best reducing agent will be the compound with the most negative reduction potential. Among the following reduction potentials:

Cd₂⁺(aq)|Cd(s) ⇒ -0.40 V

Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

Ni²⁺(aq)|Ni(s) ⇒‑0.25 V

Cu²⁺(aq)|Cu(s) ⇒ +0.34 V

Ag⁺(aq)|Ag(s) ⇒ +0.80 V

The most negative is Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

From this, the most reducing agent is Zn. Zn(s) is oxidized to Zn²⁺ ions with the highest oxidation potential (0.76 V).

Answer: The volume of liquid used will be 18.055 mL.

Answer:

d

Explanation:answer is d on edg 2020

Answer:

D. Rare

Explanation:

Qualitative research has to do with non-numerical data and is used to understand the beliefs of a group of people which can be gotten from surveys, questionnaires, interviews, etc.

A qualitative researcher may select a RARE case that is unusually rich in information pertaining to the research question.

This is because he wants to get an insight into the why, how, where and when of that particular ase as it's not a usual occurrence.

Answer:

[tex]pH=10.45[/tex]

Explanation:

Hello,

In this case, for the dissociation of the given base, we have:

[tex]base\rightleftharpoons OH^-+CA[/tex]

Whereas CA accounts for conjugated acid and OH⁻ for the conjugated base. In such a way, equilibrium expression is:

[tex]Kb=\frac{[OH^-][CA^+]}{[base]}[/tex]

And in terms of the reaction extent [tex]x[/tex] we can write:

[tex]1.6x10^{-6}=\frac{x*x}{0.05M-x}[/tex]

For which the roots are:

[tex]x_1=-0.000284M\\x_2=0.000282M[/tex]

For which clearly the result is the positive root which also equals the concentration of hydroxyl ions and we can compute the pOH:

[tex]pOH=-log([OH^-])=-log(0.000282)\\\\pOH=3.55[/tex]

And the pH:

[tex]pH=14-pOH=14-3.55\\\\pH=10.45[/tex]

Regards.

The pH of the solution is 10.45.

Let us represent codeine with the generic formula BH. We can set up the ICE table as follows;

              :B(aq) + H2O(l) ⇄ BH(aq)  + OH^-(aq)

I            0.05                        0                0

C           -x                            +x                +x

E        0.05 - x                      x                  x

We know that the Kb of codeine is 1.6 x 10^-6, Hence;

1.6 x 10^-6 = x^2/0.05 - x

1.6 x 10^-6 (0.05 - x ) =  x^2

8 x 10^-8 - 1.6 x 10^-6x =  x^2

x^2 +  1.6 x 10^-6x - 8 x 10^-8 = 0

x = 0.00028 M

The concentration of hydroxide ions = 0.00028 M

Given that pOH = - log[0.00028 M]

pOH = 3.55

pH + pOH = 14

pH = 14 - 3.55

pH = 10.45

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Answer:

2Cl——>Cl2+2e-

Explanation:

It shows an electron loss or gain

Answer: A

Explanation: Calculate the molar hydrogen ion concentration of each of the following biological solutions given the pH, Urine pH= 4.90