Rank the following amine derivatives from highest acidity (lowest pKa value) to lowest acidity (highest pKa value).
Highest acidity
anilinium ion
aniline
ammonium ion
secondary amine
amide
Lowest acidity

Answer:

pH = 13.7

Explanation:

A strong acid (HCl) reacts with a strong base Sr(OH)₂ producing water and a salt, thus:

2HCl + Sr(OH)₂ → 2H₂O + SrCl₂

To solve this problem, we need to find initial moles of both reactants and, with the chemical equation find limiting reactant and moles in excess to find pH as follows:

The initial moles of HCl and Sr(OH)₂ are:

100mL = 0.1L ₓ (1.0mol / L) = 0.100 moles of both HCl and Sr(OH)₂

As 2 moles of HCl reacts per mole of Sr(OH)₂, moles of Sr(OH)₂ that reacts with 0.100 moles of HCl are:

0.100 moles HCl ₓ (1 mol Sr(OH)₂ / 2 mol HCl) = 0.050 moles Sr(OH)₂

That means HCl is limiting reactant and after reaction will remain in solution:

0.100 mol - 0.050mol =

0.050 moles of Sr(OH)₂

Find pH:

1 mole of Sr(OH)₂ contains 2 moles of OH⁻, 0.050 moles contains 0.050×2 = 0.100 moles of OH⁻. In 200mL = 0.2L:, molar concentration of OH⁻ is:

0.100 moles / 0.2L =

[OH⁻] = 0.5M

As pOH of a solution is -log[OH⁻],

pOH = -log 0.5M

pOH = 0.301

And knowing:

pH = 14 - pOH

pH = 14 - 0.301

Answer:

THE EMPIRICAL FORMULA OF THE COMPOUND IS NF2

THE MOLECULAR FORMULA OF THE COMPOUND IS N2F4

Explanation:

To calculate the empirical formula for the compound, we:

1. Write out the percentage weight of each elements

N = 26.94%

F = 73.06 %

2. Divide each by its atomic mass

( N= 14, F = 19)

N = 26.94 / 14 = 1.924

F = 73.06 / 19 = 3.845

3. Divide each by the smaller of the values

N = 1.924 / 1.924 = 1

F = 3.845 / 1.924 = 1,998

4. Round up to a whole number and write the empirical formula

N= 1

F = 2

So the empirical formula of the compound is N F2

To calculate the molecular formula, we:

(N F2 )n = molecular weight

( 14 + 19*2) n = 104.02

52 n = 104.02

n = 2.000

The molecular formula of the compound will be:

(N F2)2 = N2F4

In conclusion, the empirical formula of the compound is NF2 and the molecular formula of the compound is N2F4

Answer:

the volume of the titrant used

Explanation:

Acid-base titrations are usually depicted on special graphs referred to as titration curve. A titration curve is a graph that contains a plot of the volume of the titrant as the independent variable and the pH of the system as the dependent variable.

Hence, a titration curve is a graphical plot showing the pH of the analyte solution plotted against the volume of the titrant as the reaction is in progress. The titration curve is drawn by plotting data obtained during a titration, that is, volume of the titrant added (plotted on the x-axis) and pH of the system (plotted on the y-axis).

Answer:

[ClO] = 3.48×10¯⁹ M.

Explanation:

The following data were obtained from the question:

Equilibrium constant (Kc) = 4.96×10¹¹

Concentration of Cl2O2, [Cl2O2] = 6x10¯⁶ M.

Concentration of ClO, [ClO] =.?

The equation for the reaction is given below:

2ClO(g) ⇌ Cl2O2(g)

The equilibrium constant for a reaction is simply defined as the ratio of the concentration of product raised to their coefficient to the concentration of the reactant raised to their coefficient.

The equilibrium constant, Kc for the reaction is given by:

Kc = [Cl2O2] / [ClO]²

Thus, we can calculate the concentration of ClO, [ClO] as follow:

Kc = [Cl2O2] / [ClO]²

4.96×10¹¹ = 6x10¯⁶ / [ClO]²

Cross multiply

4.96×10¹¹ × [ClO]² = 6x10¯⁶

Divide both side by 4.96×10¹¹

[ClO]² = 6x10¯⁶ / 4.96×10¹¹

[ClO]² = 1.21×10¯¹⁷

Take the square root of both side

[ClO] = √ (1.21×10¯¹⁷)

[ClO] = 3.48×10¯⁹ M

Therefore, the concentration of ClO, [ClO] is 3.48×10¯⁹ M.

Answer:

The length the divider is to  equilibrium from Part A = 1.30 m and from Part B = 3.70 m

Explanation:

Given that:

A rectangular cube with 3.2 m breadth, 1.2 m height and 5 m in length is splitted into two parts.

The diagrammatic expression for the above statement can be found in the attached diagram below.

The container has a movable airtight divider that divides its length as necessary.

Part A has 58 moles of gas

Part B has 165 moles of a gas.

Thus, the movable airtight divider will stop at a length where the pressure on it is equal on both sides.

i.e

[tex]\mathtt{P = P_A = P_B}[/tex]

Using the ideal gas equation,

PV = nRT

where, P,R,and  T are constant.

Then :

[tex]\mathsf{\dfrac{V_A}{n_A}= \dfrac{V_B}{n_B}}[/tex]

[tex]\mathsf{\dfrac{L_A \times B \times H}{n_A}= \dfrac{L_B \times B \times H}{n_B}}[/tex] --- (1)

since Volume of a cube = L × B × H

From the question; the L = 5m

i,e

[tex]\mathsf{L_A +L_B}[/tex] = 5

[tex]\mathsf{L_A = 5 - L_B}[/tex]

From equation (1) , we divide both sides by (B × H)

Then :

[tex]\mathsf{\dfrac{L_A }{n_A}= \dfrac{L_B }{n_B}}[/tex]

[tex]\mathsf{\dfrac{5-L_B}{58}= \dfrac{L_B }{165}}[/tex]

By cross multiplying; we have:

165 ( 5 - [tex]\mathsf{L_B}[/tex] )  = 58 (

825 - 165[tex]\mathsf{L_B}[/tex]  = 58

825 = 165[tex]\mathsf{L_B}[/tex] +58

825 = 223[tex]\mathsf{L_B}[/tex]

[tex]\mathsf{L_B}[/tex] = 825/223

[tex]\mathsf{L_B}[/tex]  = 3.70 m

[tex]\mathsf{L_A = 5 - L_B}[/tex]

[tex]\mathsf{L_A = 5 - 3.70}[/tex]

[tex]\mathsf{ L_A}[/tex] = 1.30 m

The length the divider is to  equilibrium from Part A = 1.30 m and from Part B = 3.70 m

Answer:

0.327 M

Explanation:

Step 1: Write the balanced equation

2 NH₃(g) ⇄ N₂(g) + 3H₂(g)

Step 2: Make an ICE chart

        2 NH₃(g) ⇄ N₂(g) + 3 H₂(g)

I              x             0            0

C          -2y            +y         +3y

E         x-2y             y           3y

Step 3: Find the value of y

The concentration of N₂ at equilibrium is 0.0161 M. Then,

y = 0.0161

Step 4: Find the value of x

The concentration of NH₃ at equilibrium is 0.295 M. Then,

x-2y = 0.295

x-2(0.0161) = 0.295

x = 0.327

Answer:

0.44

Explanation:

We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.

For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M

pH= -log [H^+]

pH= - log[0.36]

pH= 0.44

Answer:

Enthalpy of formation is the energy change when one mole of a substance is formed from its constituent atoms under standard conditions

Answer:

1.543 pounds = 700 grams

Answer:

Higher frequency than visible light -  Ultraviolet light, X-rays, and Gamma rays

Lower frequency than visible light - Infrared radiation, microwaves, and Radio waves

Explanation:

The frequencies of electromagnetic radiations vary according to their wavelengths. The relationship between the frequency and wavelength of the waves is expressed such that:

      λ = c/f, where λ = wavelength, c = speed of light, and f = frequency.

Thus, there is an inverse relationship between the wavelength and the frequency of electromagnetic waves.

The order of the electromagnetic waves based on their frequency from the lowest to the highest is radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma-rays

Hence, electromagnetic waves with higher frequencies than visible light include ultraviolet light, X-rays, and Gamma rays while those with lower frequencies include Infrared radiation, microwaves, and Radio waves.

Answer:

need points

Explanation:

Answer:

The compound contains a o molecular orbital formed by the overlap of one carbon sp2 hybrid orbital and one hydrogen sp3 hybrid orbital.

Explanation:

Molecular orbital is function which describes wave like behavior of an electron in a molecule. The molecular orbital theory describes the electronic structure of molecule using quantum mechanics. Electrons are not assigned to individual bonds between atoms. The compound contains sp2 hybrid orbial which is polar C - CI bond.

Answer:

0.8 part of the product is water

Explanation:

Volume (or parts) of water = 4

Volume (or parts) of lemonade = 1

Total volume = 4 + 1 = 5

Fraction of water = Volume of water / Total volume = 4 / 5 = 0.8

Answer:

The pH of the solution will be 3

Explanation:

The strength of acids is determined by their ability to dissociate into ions in aqueous solution. A strong acid is any compound capable of completely and irreversibly releasing protons or hydrogen ions, H⁺. That is, an acid is said to be strong if it is fully dissociated into hydrogen ions and anions in solution.

Being pH=- log [H⁺] or pH= - log [H₃O⁺] and being a strong acid, all the HClO₃ dissociates:

HClO₄      +    H₂O        →      H₃O⁺      +      ClO₄-  

So: [HCLO₄]= [H₃O⁺]

The molar concentration is:

[tex]molar concentration=\frac{number of moles of solute}{volume solution}[/tex]

The molar mass of HClO₄ being 100 g / mole, then if 100 grams of the compound are present in 1 mole, 0.025 grams in how many moles are present?

[tex]moles of HClO_{4} =\frac{0.025 grams*1 mole}{100 grams}[/tex]

moles of HClO₄= 0.00025

Then:

[tex][HClO_{4}]=\frac{0.00025 moles}{0.25 L}[/tex]

[tex][HClO_{4}]=0.001 \frac{ moles}{ L}[/tex]

Being [HCLO₄]= [H₃O⁺]:

pH= - log 0.001

pH= 3

The pH of the solution will be 3

The cell potential for the electrochemical cell has been 1.40 V.

The standard reaction for the cell will be:

[tex]\rm 3\;Cl_2\;+\;2\;Fe\;\rightarrow\;6\;Cl^-\;+\;2\;Fe^3^+[/tex]

The half-reaction of the cells has been:

[tex]\rm Fe^3^+\;+\;3\;e^-\;\rightarrow\;Fe[/tex]

The potential for this reduction has been -0.04 V.

[tex]\rm Cl_2\;+\;2\;e^-\;\rightarrow\;2\;Cl^-[/tex]

The potential for the reduction has been 1.36 V.

The cell potential has been: Potential of reduction - Potential of oxidation

Cell potential = 1.36 - (-0.04) V

Cell potential = 1.40 V.

The cell potential for the electrochemical cell has been 1.40 V.

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Answer:

2-methyl-2-pentyl-1,3-dioxolane

Explanation:

In this case, we have two reactions:

First reaction:

1-heptyne + mercuric acetate -------> Compound A

Second reaction:

Compound A + HOCH2CH2OH -------> Compound C

First reaction

In the first reaction, we have as a main functional group a triple bond. We have to remember that mercuric acetate in sulfuric acid will produce a ketone. The carbonyl group (C=O) would be placed in the most substituted carbon of the triplet bond (in this case, carbon 2). With this in mind, we will have as a product: heptan-2-one. (See figure 1).

Second reaction

In this reaction, we have as reagents:

-) Heptan-2-one

-) Ethylene-glycol [tex]HOCH_2CH_2OH[/tex]

-) Sulfuric acid [tex]H_2SO_4[/tex]

When we put ethylene-glycol with a ketone or an aldehyde we will form a cyclic acetal. In this case, this structure would be formed on carbon 2 forming 2-methyl-2-pentyl-1,3-dioxolane. (See figure 2).

I hope it helps!

Answer:

6H20 represents six molecules of water

Answer:

6H20 represents six molecules of water

Explanation:

Density measures how tightly packed particles are.

If particles are tightly packed together, they will be more dense.

If they are loosely together, they will be less dense.

However, a common mistake is thinking that if something

is more dense it means that it's heavier.

However, that's not the case.

It has to do with how particles are packed in an object.

Answer:

a. Moles in the vessel = 1.85 moles of the gas

b. 1.11x10²⁴ molecules are in the vessel

Explanation:

a.It is possible to determine moles of a gas using the general law of gases:

PV = nRT

Where P is pressure: 5.00atm; V is volume = 9.00L; R is gas constant: 0.082atmL/molK; T is absolute temperature: 273.15K +24.0 = 297.15K

Computing the values:

PV / RT = n

5.00atm* 9.00L / 0.082atmL/molK*297.15K = n

b. With Avogadro's number we can convert moles of any compound to molecules thus:

Avogadro's number = 6.022x10²³ molecules / mole

1.85moles ₓ (6.022x10²³ molecules / mole) =

Answer: Reaction (1) , (3) and (4) are accompanied by an increase in entropy.

Explanation:

Entropy is the measure of randomness or disorder of a system. If a system moves from  an ordered arrangement to a disordered arrangement, the entropy is said to decrease and vice versa.

(1) [tex]2SO_2(g)+O_2(g)\rightarrow SO_3(g)[/tex]

3 moles of reactant are changing to 1 mole of product , thus the randomness is increasing. Thus the entropy also increases.

2) [tex]H_2O(l)\rightarrow H_2O(s)[/tex]

1 mole of Liquid reactant is changing to 1 mole of solid product , thus the randomness is decreasing. Thus the entropy also decreases.

3) [tex]Br_2(l)\rightarrow Br_2(g)[/tex]

1 mole of Liquid reactant is changing to 1 mole of gaseous product , thus the randomness is increasing. Thus the entropy also increases.

4)  [tex]H_2O_2(l)\rightarrow H_2O(l)+\frac{1}{2}O_2(g)[/tex]

1 mole of Liquid reactant is changing to half mole of gaseous product and 1 mole of liquid product, thus the randomness is increasing. Thus the entropy also increases.

Answer:

a. Sodium cyclopentanecarboxylate

b. No reaction

Explanation:

In this case, in the cyclopentanecarboxylic acid we have a carboxylic acid functional group. Therefore we have an "acid". The acids by definition have the ability to produce hydronium ions ([tex]H^+[/tex]).

With this in mind, for molecule a. we will have an acid-base reaction, because NaOH is a base. When we put together an acid and a base we will have as products a salt and water. In this case, the products are  Sodium cyclopentanecarboxylate (the salt) and water.

For the second molecule, we have the hydronium ion  ([tex]H^+[/tex]). This ion can not react with an acid. Because, the acid will produce the hydronium ion also, so a reaction between these compounds is not possible.

See figure 1

I hope it helps!

Answer:

I hope it works

Explanation:

As we know that

w=m*g

given m=0.145 , g=9.8

hence we get

w= (9.8)*(0.145)

w=1.421 m/sec 2

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Answer:

a. MnO₄⁻ + 8H⁺ + 5Fe²⁺ → 5Fe³⁺ + Mn²⁺ + 4H₂O

b. 18.17% of Fe in the sample

Explanation:

a. In the reaction, Fe²⁺ is oxidized to Fe³⁺ and permanganate, MnO₄⁺ reduced to Mn²⁺, thus:

Fe²⁺ → Fe³⁺ + 1e⁻

MnO₄⁻ + 5e⁻ + 8H⁺ → Mn²⁺ + 4H₂O

5 times the iron and suming the manganese reaction:

MnO₄⁻ + 5e⁻ + 8H⁺ + 5Fe²⁺ → 5Fe³⁺ + 5e⁻ + Mn²⁺ + 4H₂O

b. Moles of permanganate in the titration are:

0.03942L × (0.0281 moles / L) = 1.108x10⁻³ moles of MnO₄⁻

Based on the reaction, 1 mole of permanganate reacts with 5 moles of iron, if 1.108x10⁻³ moles of MnO₄⁻ reacts, moles of iron are:

1.108x10⁻³ moles of MnO₄⁻ × (5 moles Fe²⁺ / 1 mole MnO₄⁻) =

4.431x10⁻³ moles of Fe²⁺. Molar mass of Fe is 55.845g/mol. 4.431x10⁻³ moles of Fe²⁺ are:

4.431x10⁻³ moles of Fe²⁺ ₓ (55.845g / mol) =

Percent mass is:

0.2474g Fe / 1.362g sample ₓ 100 =

The mass percent of iron in the sample is 22.6%.

The net ionic equation of the reaction is;

5Fe^2+(aq) + 8H^+(aq) + MnO4^-   -----> 5Fe^3+(aq) + Mn^2+(aq) + 4H2O(l)

Number of moles of MnO4^-  = 39.42/1000 L × 0.0281 M = 0.0011 moles

If 5 moles of Fe^2+ reacts with 1 mole of MnO4^-

x moles of Fe^2+ reacts with 0.0011 moles

x =  5 moles × 0.0011 moles/1 mole

x = 0.0055 moles

Mass of Fe^2+ =  0.0055 moles × 56 g/mol = 0.308 g

Mass percent of iron = 0.308 g/ 1.362 g × 100/1

= 22.6%

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Answer:

pH of the buffer is 3.75

Explanation:

It is possible to find pH of a buffer using Hendersson-Hasselbalch equation:

pH = pKa + log [A⁻] / [HA]

Where [A⁻] is molar concentration of the conjugate base and [HA] concentration of the weak acid

In the lactic buffer, pKa = 3.86. Lactic acid is the weak acid and its conjugate base is tha lactate salt. H-H equation for this buffer is:

pH = 3.86 + log [Lactate] / [Lactic acid]

Replacing with the concentrations of the problem:

pH = 3.86 + log [0.10M] / [0.13M]

pH = 3.75

Answer:

Electrical current drives nonspontaneous reactions in electrolytic cells.

Explanation:

Electrochemical cells are cells that produce electrical energy from chemical energy.

There are two types of electrochemical cells; voltaic cells and electrolytic cells.

A voltaic cell is an electrochemical cell in which electrical energy is produced from spontaneous chemical process while an electrolytic cell is an electrochemical cell where electrical energy is produced from nonspontaneous chemical processes. Current is needed to drive these nonspontaneous chemical processes in an electrolytic cell.

Answer:

electrolytic cells generate electricity through a non-spontaneous reaction while voltaic cells absorb electricity to drive a spontaneous reaction.

Explanation:

Answer via Educere/ Founder's Education

Answer:

- you have to do maths in all 3

- atoms make up everything even parts of a cel and theyre studied in chem and physics

- chemistry is used in biology by finding out what different substances are eg cytoplasm in a cell

Answer:

The boy must swim at an angle of 59°northwest to get to a position directly opposite his starting point.

Explanation:

To get to a point directly opposite his starting point, the boy must travel at an angle x, in a direction northwest of his starting point. The speed of the boy and the speed of the river current forms a right-angled triangle with an an opposite side of 1.8 m/a and a hypotenuse of 2.1 m/a having an angle x.

Sin x = opp/ hyp

Sin x = 1.8/2.1

x = sin⁻¹ (1.8/2.10

x = 58.99

x = 59°

Therefore, the boy must swim at an angle of 59° in the northwesterly direction to get to a position directly opposite his starting point.

Answer:

SCN- is a weak field ligand while CN- is a strong field ligand

Explanation:

The spectrochemical series is an arrangement of ligands according to their magnitude of crystal field splitting. Ligands that cause only a small degree of crystal field splitting are called weak field ligands while ligands that cause large crystal field splitting are called strong field ligands.

Strong field ligands often lead to the formation of low spin complexes with the least number of unpaired electrons while high spin complexes are formed by weak field ligands.

CN- is a strong field ligand as it lies towards the right hand side of the spectrochemical series.

SCN- is a weak field ligand hence it forms a high spin complex having the maximum number of unpaired electrons for Fe^3+, hence the answer.

SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

CN⁻ is a strong field ligand with a large splitting constant, and it is high up in the spectrochemical series.

Conversely, SCN⁻ is a weak field ligand with a low splitting constant, and it is lower in the spectrochemical series.

Hence, SCN⁻ lies in the lower (weak field) region of the spectrochemical series while CN⁻ lies in the higher (stronger field) region.

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Explanation:

using boyles law

p1v1=p2v2

735 x 1.76 = 700 x V2

1293.6 = 700 x V2

V2 = 1293.6/700

V2 = 1.85L

Answer:

-138.9 kJ/mol

Explanation:

Step 1: Convert 235.8°C to the Kelvin scale

We will use the following expression.

K = °C + 273.15 = 235.8°C + 273.15 = 509.0 K

Step 2: Calculate the standard enthalpy of reaction (ΔH°)

We will use the following expression.

ΔG° = ΔH° - T.ΔS°

ΔH° = ΔG° / T.ΔS°

ΔH° = (-936.92kJ/mol) / 509.0K × 0.51379 kJ/mol.K

ΔH° = -3.583 kJ (for 1 mole of balanced reaction)

Step 3: Convert -9.9°C to the Kelvin scale

K = °C + 273.15 = -9.9°C + 273.15 = 263.3 K

Step 4: Calculate ΔG° at 263.3 K

ΔG° = ΔH° - T.ΔS°

ΔG° = -3.583 kJ/mol - 263.3 K × 0.51379 kJ/mol.K

ΔG° = -138.9 kJ/mol