Oxidation of Alcohols: Practical Methods
1. a) State the reagents & conditions used in the oxidation of alcohols.
b) State the colour change observed for the oxidising agent.
2.a) Explain why oxidation of a primary alcohol under distillation produces an aldehyde whereas oxidation
under reflux produces a carboxylic acid. You could use ethanol oxidation as an example. Include
structural formulae in your explanation.
b) Which experimental set-up below would you use to:
i) oxidise ethanol to ethanoic acid?
ii) oxidise ethanol to ethanal?
2. For ea
drawin
a) ethanc
b) etha
c) pre

Answers

Answer 1

Answer:

1a) The most common reagents used for the oxidation of alcohols are potassium permanganate (KMnO4), chromic acid (H2CrO4), and potassium dichromate (K2Cr2O7). Other oxidizing agents include sodium hypochlorite (NaOCl), pyridinium chlorochromate (PCC), and Jones reagent (CrO3/H2SO4). The conditions vary depending on the reagent used, but generally, the reaction is carried out under acidic or basic conditions and at elevated temperatures.

b) The oxidizing agents generally have a distinctive color, and their color changes during the reaction. For example, potassium permanganate is purple in its initial state, but it turns brown when it is reduced. Similarly, potassium dichromate is orange, but it changes to green when it is reduced.

2a) When a primary alcohol is oxidized, it can produce either an aldehyde or a carboxylic acid, depending on the reaction conditions. When the oxidation is carried out under distillation conditions, the aldehyde is formed as the reaction intermediate, which is then distilled off before it can be further oxidized to a carboxylic acid. On the other hand, when the oxidation is carried out under reflux conditions, the aldehyde is in equilibrium with the carboxylic acid, and the carboxylic acid is formed as the major product. For example, when ethanol is oxidized using potassium dichromate in acidic conditions:

Under distillation conditions:

CH3CH2OH + [O] → CH3CHO + H2O

Under reflux conditions:

CH3CH2OH + 2[O] → CH3COOH + H2O

b) i) The experimental set-up to oxidize ethanol to ethanoic acid would involve refluxing ethanol with an excess of potassium dichromate in acidic conditions.

ii) The experimental set-up to oxidize ethanol to ethanal would involve distilling a mixture of ethanol and a limited amount of oxidizing agent, such as pyridinium chlorochromate or Jones reagent, at a temperature that is lower than the boiling point of ethanal.

See the attached image for the requested drawings of ethane, ethanol, and propanone.

(please could you kindly mark my answer as brainliest)


Related Questions

Draw the hydrogen bonding of G-C and A-T pairs by hand. For each hydrogen bond, please point out which are hydrogen bond donors, and which are hydrogen bond acceptors.

Answers

Everyone agrees that guanine-cytosine (GC) base pairs have three hydrogen bonds, but adenine-thymine (AT) base pairs only have two.

What do adenine's hydrogen bond acceptors and donors look like?

Testing the significance of the these two polar organisations together necessitates an analogue whereby both are replaced to nonpolar functionality, preferably maintaining steric dimensions and forms as closely as possible. Adenine carries a hydrogen - bonding acceptor (N1) as well as a donor (NH2) along its Watson-Crick base pairing edge.

What do donors and acceptors of cytosine hydrogen bonds do?

Three hydrogen bonds hold guanine-cytosine base pairs, often known as GC base pairs, together. The bases are marked with the names of the hydrogen - bonding donors and recipients. The hydrogen - bonding donors all are NH groups. Nitrogen and oxygen atoms with a single pair of electrons can act as hydrogen bond acceptors.

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A chemist heats the block of gold as shown in the interactive, then places the metal sample in a cup of oil at 25.00 °C instead of
a cup of water. The temperature of the oil increases to 26.52 °C. Calculate the mass of oil in the cup. The specific heat of gold is
0.129 J/g °C and the specific heat of oil is 1.74 J/g °C.
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Answers

FCC iDisk ldkkdbd oaks

Match the terms to the appropriate definitions and/or descriptions

HELP!!

Answers

Absolute dating:

Using the abnormal isotopes inside specimens and using half-life calculations to learn the absolute dates.Carbon 14 datingRadiometric dating

What matches other terms?

Zircon: A crystal that helps determine the age of an igneous intrusion or layer of a very old specimen.

Meteorites: Help to determine the age of the universe because it is assumed they were around the same time as the Earth was formed

Compression melting: Was likely formed by tectonic and volcanic events

Relative dating: When scientist are simply looking for a logical sequence of events

An igneous intrusion: A crystal that helps determine the age of an igneous intrusion or layer of a very old specimen

Unconformity: When layers are missing from one area to another because of erosion of exposed parts that occurred because of an earthquake or other geological event.

Index fossils: If a fossil is determined to be a certain age, the layer it was found in is likely of the same age.

The Grand Canyon: Was likely entirely formed by a river

Iguazu Falls in Argentina: Was likely formed by glacial forces

Yosemite Valley: The lowest layer of glaciers that lubricate and allows a glacier to move

The statement "An igneous intrusion is always younger than all the layers it cuts through" is true.

The statement "Using radiometric methods to find the approximate age of a layer or fossil" is true.

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The text format of the question goes thus:

Absolute dating

Zircon

Meteorites

Compression melting

Relative dating

An igneous intrusion

Unconformity

Index fossils

The Grand Canyon

Iguazu Falls in Argentina

Yosemite Valley

Carbon 14 dating

Radiometric dating

a. was kkely formed by glacial forces

b. is always younger than all the layers it cuts through

Using the abnormal isotopes inside specimens and using half-life calculations to learn the absolute dates.

d. If a fossil is determined to be a certain age, the layer it

was found in is likely of the same age.

e. Using radiometric methods to find the approximate age

of a layer or fossil

was likely entirely formed by a river

When layers are missing from one are to another because of erosion of exposed parts that occurred because of an earthquake or other geological event.

h was likely formed by tectonic and volcanic events

To learn absolute date of a more recent item.

J. the lowest layer of glaciers that lubricate and allows a

glacier to move k. A crystal that helps determine the age of an igneous intrusion or layer of a very old specimen

When scientist are simply looking for a logical sequence

of events

m. Help to determine the age of the universe because it is

assumed they were around the same time as the Earth

was formed

19. which sample, when dissolved in 1.0 liter of water, produces a solution with the lowest boiling point?

Answers

The sample with the lowest boiling point when dissolved in 1.0 liter of water is sodium chloride (NaCl). Sodium chloride is a common salt compound which, when dissolved in water, lowers the boiling point of the solution.

To calculate the boiling point, use the following equation: Boiling Point = K b x m, where Kb is the ebullioscopic constant and m is the molality of the solution.

The ebullioscopic constant for sodium chloride is 0.51 K kg mol-1 and the molality is equal to the number of moles of solute divided by the volume of the solution. Therefore, for a 1.0 liter solution, the boiling point of the solution would be 0.51 K kg mol-1 x 0.78 moles/1.0 liter = 0.398 K kg mol-1.

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Read through each scenario. Under the scenario, write which lab safety rule is being broken.

Answers

Explanation:

1. Carlos is using unknown chemicals, which is breaking the rules that state: "Treat every chemical hazardous" and "No chemical should be taken without proper authorisation".

2. Jane doesn't know where the eye-wash station is, so she is breaking Rule #1: "Know locations of laboratory safety showers, eyewash stations, and fire extinguishers. The safety equipment may be located in the hallway near the laboratory entrance."

3. Harry has broken the rule that says that "No horseplay will be tolerated." He has turned on the hot plate without instruction.

4. Brent is eating in class. Eating in laboratories where hazardous materials are present is prohibited, yet he still eats a bagel. He is at risk of food poisoning.

5. Sniffing or tasting chemicals can be dangerous or even deadly as the vapours or fumes can contain traces of unknown toxins.

6. She should be more careful, and according to lab safety rules, she should put her bag in the designated areas and work independently unless she is told by her instructor to do otherwise.

7.  Rachel should dress for the lab. If she doesn't and her clothes react badly to the chemicals, it would pose serious health problems.

8. I don't know about this question.

9. Water can act as a reactant, so the chemical in the sink may damage the lab or outside pipes if corrosive. Experiments should be left in the lab unless told to do otherwise by the instructor.

10. Clean up at the end of lab. In this situation, Diana and Mike didn't clean up thoroughly, which can damage their bench top.

11. Jake is performing experiments without permission. He may become a threat to himself if his body gets contaminated.

12. The experiments wouldn't be conducted correctly, which may contaminate the students around them or damage the lab. Heather and Jennifer might pose a threat to the lab.

13. Again, tasting or smelling lab materials are strictly prohibited. Rebecca  may harm her digestive system if she tries an unknown salt.

14. Unwanted reactions may occur, and  the result might be acidic, corrosive, contaminate the surrounding area or discolour some places.

15. Because if we do not follow procedures and rule, we may damage some tools or fellow students.

Chlorate is an oxyanion. It contains a single covalent bond between oxygen and chlorine atoms. The ion also have an ovaral negative charge. Show by calculation that the percentage by mass of chlorate 1 in calcium chlorate 1 is greater than the percentage by mass of chlorate 1 ions in Sodium chlorate​

Answers

Percentage by mass of chlorate 1 in calcium chlorate 1 is greater than the percentage by mass of chlorate 1 ions in Sodium chlorate.

What is an oxyanion? Give an example of an oxyanion.

An oxyanion is a polyatomic ion that contains at least one oxygen atom and one or more other elements, typically nonmetals. Examples of oxyanions include nitrate (NO3-), sulfate (SO42-), and phosphate (PO43-).

The molecular formula for calcium chlorate is Ca(ClO3)2, and the molecular formula for sodium chlorate is NaClO3.

To calculate the percentage by mass of chlorate 1 in calcium chlorate 1, we need to calculate the molar mass of Ca(ClO3)2 and the molar mass of chlorate 1.

Molar mass of Ca(ClO3)2 = 1 mol Ca + 2 mol ClO3

= 40.08 g/mol Ca + 2(35.45 g/mol Cl + 3(16.00 g/mol O))

= 238.06 g/mol

Molar mass of chlorate 1 = 35.45 g/mol Cl + 3(16.00 g/mol O)

= 99.45 g/mol

Now, we can calculate the percentage by mass of chlorate 1 in calcium chlorate 1:

% by mass of chlorate 1 in calcium chlorate 1 = (2 mol ClO3 x 99.45 g/mol) / (1 mol Ca(ClO3)2 x 238.06 g/mol) x 100%

= 83.3%

To calculate the percentage by mass of chlorate 1 in sodium chlorate, we only need to calculate the molar mass of NaClO3 and the molar mass of chlorate 1.

Molar mass of NaClO3 = 22.99 g/mol Na + 35.45 g/mol Cl + 3(16.00 g/mol O)

= 106.99 g/mol

Molar mass of chlorate 1 = 35.45 g/mol Cl + 3(16.00 g/mol O)

= 99.45 g/mol

Now, we can calculate the percentage by mass of chlorate 1 in sodium chlorate:

% by mass of chlorate 1 in sodium chlorate = (1 mol ClO3 x 99.45 g/mol) / (1 mol NaClO3 x 106.99 g/mol) x 100%

= 92.9%

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Ian noticed that during a reaction the beaker containing his reactants got very cold. What kind of reaction is this?

Answers

Answer: Endothermic Reaction

Explanation:

It is Endothermic Reaction because, during Endothermic reaction, heat is absorbed from the surrounding. It is cold because, due to the reaction, the heat is absorbed, lowering the temperature of the mixture in the beaker, making the reactants cold.

Review these definitions, and make sure to not get confused between Exothermic and Endothermic reactions.

Exothermic Reaction: A chemical reaction where energy is released.

Endothermic Reaction: A chemical reaction where energy is absorbed from the environment.

mpirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen

Answers

The empirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen is FeS2O3.

First determine the ratio of each element. Divide the mass of each element by its atomic weight and then divide the results by the smallest value obtained.

The atomic weights are: Fe=55.845, S=32.065 and O=16.00. Dividing the mass of each element by its atomic weight gives the following ratios: Fe=0.0240, S=0.0024 and O=0.0072.

Dividing the ratios by the smallest value (0.0024) gives us 10, 1 and 3 respectively. This means that the empirical formula is Fe10S1O3.

We must divide all values by the highest common factor, which in this case is 2. This gives us Fe5S1/2O3/2 or FeS2O3.

Therefore, the empirical formula for a compound which contains 0.0134 g of iron, 0.00769 g of sulfur and 0.0115 g of oxygen is FeS2O3.

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how is the atomic number of an atom determined? view available hint(s)for part a how is the atomic number of an atom determined? counting the number of atoms of an element in a mineral counting the number of protons circling the nucleus counting the number of protons in the nucleus counting the number of neutrons in the nucleus counting the number of protons and neutrons in the nucleus

Answers

The atomic number of an atom is determined by counting the number of protons in the nucleus. This is because the atomic number is defined as the number of protons in an atom's nucleus.

What is atomic number?

The atomic number is the number of protons in an atom. The periodic table is arranged according to atomic number, which determines the chemical properties of an element. All neutral atoms of a given element have the same number of protons and electrons.

A neutral atom has an equal number of positively charged protons and negatively charged electrons, which results in no overall charge.The electron arrangement in an atom determines how it will interact with other atoms. The element's chemical properties are determined by the electron configuration of its atoms.

The number of protons in the nucleus determines the element's atomic number, which is a fundamental property of the element. The atomic number identifies the element and its position on the periodic table.

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which property is a main difference between a nucleic acid and a carbohydrate?

Answers

The main difference between nucleic acids and carbohydrates is that nucleic acids are made up of nucleotides, while carbohydrates are made up of monosaccharides.

Therefore, the property that distinguishes nucleic acids from carbohydrates is their composition of nucleotides, which are the basic structural units of nucleic acids.

What are nucleic acids?

Nucleic acids are the biomolecules that encode and transmit genetic information in cells.

They are primarily composed of carbon, nitrogen, oxygen, and phosphorus, and are formed by polymerization reactions in which nucleotides are joined by phosphodiester bonds to form polynucleotide chains.

What are carbohydrates?

Carbohydrates are organic compounds composed of carbon, hydrogen, and oxygen, with the general formula CnH2nOn.

They are classified based on the number of monosaccharide units they contain, with monosaccharides being the simplest and most basic carbohydrate units.

Carbohydrates serve as a source of energy and a structural component in living organisms.

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In an open manometer with an atmospheric pressure of 104 kPa, the mercury level in the arm connected to the gas is 150 mm Hg lower than in the arm connected to the atmosphere. What is the pressure of the gas sample?​

Answers

The pressure of the gas sample is 104
kPa + 150 mm Hg = 254 kPa.

what combination would dissolve a solid solute the fastest? question 4 options: no heat, no stirring high temperature, no stirring high temperature, stirring cube shape, no heat

Answers

Out of the given options, the combination that would dissolve a solid solute the fastest is high temperature with stirring.

What is solute?

A substance that is dissolved in a solvent to make a solution is called a solute.

What is a solution?

A solution is a homogeneous mixture composed of a solute dissolved in a solvent.

What is solubility?

Solubility is the capacity of one substance to dissolve in another substance. Factors such as temperature, pressure, and the solvent's chemical structure influence solubility.

Therefore, it can be inferred that out of the given options, the combination that would dissolve a solid solute the fastest is high temperature with stirring. High temperature helps to dissolve the solid solute by increasing the kinetic energy of the molecules. Stirring ensures the solute is evenly dispersed in the solvent and provides a fresh surface for the solvent to attack.

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an unknown gas effuses at a rate 0.667 times the rate of co₂. what is the molar mass of the unknown gas?

Answers

An unknown gas effuses at a rate 0.667 times the rate of co₂. The molar mass of the unknown gas is 120 g/mol.

The rate of effusion for an ideal gas is proportional to the inverse square root of the gas' molar mass. It's known as Graham's law. Graham's Law explains the rate of effusion of a gas through a small hole into a vacuum. The rate of effusion for an ideal gas is proportional to the inverse square root of the gas' molar mass (relative molecular mass). According to the question, the effusion rate of the unknown gas is 0.667 times that of CO₂.

Let the molar mass of the unknown gas be "x".

Therefore, the effusion rate for the unknown gas is proportional to

.[tex]\[\frac{1}{\sqrt{x}}\].[/tex]

The effusion rate of CO₂ is proportional to \[\frac{1}{\sqrt{44}}\].

Now,

[tex]\[\frac{\text{Effusion rate of the unknown gas}}{\text{Effusion rate of CO}_2}=\frac{0.667}{1}\][/tex]

or,

\[tex]\[\frac{1}{\sqrt{x}}=\frac{0.667}{\sqrt{44}}\][/tex]]

or,

[tex]\[\sqrt{x}=\frac{\sqrt{44}}{0.667}\][/tex]

or,

[tex]\[x=\left ( \frac{\sqrt{44}}{0.667} \right )^{2}\][/tex]

Therefore, the molar mass of the unknown gas is 120 g/mol.

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Find an expression for the oscillation frequency of an electric dipole of dipole moment P and rotational inertia I for small amplitudes of oscillation about its equilibrium position in a uniform electric field of magnitude E.

Answers

The oscillation frequency of an electric dipole in a uniform electric field can be expressed as:

f = (1/2π) x (1/√(I/2P x E))

What is oscillation?

Oscillation can be defined simply as a variation that is repetitive (in time) of measures about a value which is central, or a value between two or more accounts of different states. The oscillation occurs not only in the mechanical system but it also occurs in dynamic systems areas of every scientific founding.

The oscillation frequency is given by

f = (1/2π) x (1/√(I/2P x E))

where:

   f is the oscillation frequency in Hertz (Hz)    I is the rotational inertia of the dipole in kg*m²    P is the dipole moment in Coulomb-meter (C*m)    E is the magnitude of the uniform electric field in Volts/meter (V/m)

This expression assumes small amplitude oscillations and is derived from the equation of motion of a simple harmonic oscillator. In this case, the torque on the dipole due to the electric field is proportional to the displacement of the dipole from its equilibrium position, and the restoring torque due to the rotational inertia of the dipole is proportional to the angular displacement. By equating these torques, we get the equation of motion of the dipole in terms of the oscillation frequency, rotational inertia, dipole moment, and electric field.

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."Scientists believe the amygdala is responsible for emotion."
What is the best definition for responsible as it is used in the previous
quote?


A Liable to be called on to answer
B. Having the job or duty
C. Politically answerable
D. Able to answer for one's conduct and obligations

Answers

D. Able to answer for one's conduct and obligations

What is the amygdala?

The amygdala is a pair of almond-shaped structures located in the brain's temporal lobes. It is part of the limbic system, which is involved in the processing of emotions and memory. The amygdala is involved in the formation of memories associated with emotional events, as well as the reaction to those memories.

The amygdala also plays a role in the regulation of the body's fight-or-flight response, which is the autonomic nervous system's response to danger or perceived danger. It is thought to be involved in the formation of fears and phobias, as well as the development of aggressive behaviors. In addition, the amygdala is believed to be involved in the processing of social cues, such as facial expressions and body language.

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The student decides to determine the molarity of the same Na2CO3 solution using a second method. When Na2CO3 is dissolved in water, CO3 ^2−(aq) hydrolyzes to form HCO3 ^−(aq), as shown by the following equation.CO3 2−(aq) + H2O(l)  HCO3 −(aq) + OH−(aq) Kb = [HCO3^ -][OH^- ]/ [CO3^2- ] - - - = 2.1 × 10^−4explain how the student could use the measured value in part (f)(i) to calculate the initial concentration of co3-2 (aq). (do not do any numerical calculations.)

Answers

To calculate the initial concentration of CO32- (aq), the student can use the measured value from part (f)

(i) to calculate the equilibrium concentration of HCO3- (aq) and OH- (aq)

according to the equilibrium expression: Kb = [HCO3-]eq [OH-]eq / [CO32-]eq.

The student can then use the equilibrium concentrations to calculate the initial concentration of CO32- (aq) by solving the equilibrium expression for [CO32-]eq.

The initial concentration of CO32- (aq) is equal to the sum of the equilibrium concentrations of HCO3- (aq) and OH- (aq).

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Suppose the molar solubility of Ag2CrO4 in water is x M, while its molar solubility in a 0.005 M solution of Na2CrO4 is y M. Which of the following is correct?A) It can't be determined.B) x < yC) x > yD) x = y

Answers

When Ag2CrO4 is dissolved in a Na2CrO4 solution, its molar solubility decreases. In other words, x > y.The correct answer is c.

The molar solubility is the quantity of a solute (in moles) that can be dissolved per liter of solution (in liters) at equilibrium. It is a measure of the solubility of the solute in the solvent.

Solubility is a measure of a compound's ability to dissolve in a particular solvent at a particular temperature and pressure.According to the common ion effect, the presence of a common ion decreases the solubility of a substance in solution.

Because Na2CrO4 and Ag2CrO4 are both soluble in water, they will dissociate into their constituent ions when dissolved in water according to the following reactions:Na2CrO4 → 2Na+ + CrO42-Ag2CrO4 → 2Ag+ + CrO42-When Ag2CrO4 dissolves in a Na2CrO4 solution, however, the addition of the common chromate ion, CrO42-, will push the above equilibrium to the left, resulting in a decrease in the amount of Ag2CrO4 that dissolves.

As a result, when Ag2CrO4 is dissolved in a Na2CrO4 solution, its molar solubility decreases. In other words, x > y.

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Only the first and second choices are correct.
Polysaccharides always:
Please choose the correct answer from the following choices, and then select the submit answer button.
are a string of three or more sugar molecules.
are polymers.
contain lipids.
All of the above are correct.
Only the first and second choices are correct.

Answers

The correct option will be only the first and second choices are correct.

What are Polysaccharides?

Polysaccharides, in general, are carbohydrates that contain a large number of monosaccharide units bonded by glycosidic bonds. Polysaccharides are the polymers in which the monomer is a sugar molecule. Polymers are large molecules made up of many smaller molecules connected together.

In this case, the smaller molecules are monosaccharides, which are combined to form polysaccharides. Polysaccharides are formed when three or more monosaccharides join together to form a chain.

The correct option is that only the first and second choices are correct.

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what is the correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing?

Answers

The correct order of the five para substituents on the carbocation intermediate, if arranged from most stabilizing to least stabilizing is as follows:1) Methoxy group (-OCH3): Methoxy group is an electron-donating group that has a stabilizing effect on carbocation.2) Alkyl groups (-CH3, -C2H5).

These groups also have an electron-donating effect, but their effect is less than that of methoxy.3) Halogens (-F, -Cl, -Br, -I): These are electron-withdrawing groups, but their inductive effect is much weaker than their mesomeric effect. The mesomeric effect of halogens is electron-donating, which compensates for their inductive electron-withdrawing effect.4) Nitro group (-NO2): Nitro is a strongly electron-withdrawing group that destabilizes carbocation.5) Carbonyl group (-COCH3): Carbonyl is also an electron-withdrawing group that destabilizes carbocation.

They are formed by the loss of a leaving group from a substrate, leaving behind a positively charged carbon atom. The stability of the carbocation intermediate is influenced by the nature of the substituents attached to the carbon atom. Substituents can be electron-donating or electron-withdrawing, depending on their effect on the carbocation.The most stabilizing substituents are electron-donating groups, such as methoxy (-OCH3) and alkyl groups (-CH3, -C2H5). These groups donate electrons to the carbocation, which increases its stability. Halogens (-F, -Cl, -Br, -I) are also electron-donating, but their mesomeric effect is stronger than their inductive effect. This means that their overall effect is electron-donating, but weaker than that of methoxy and alkyl groups.

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Please Help me with this question, No.4

Answers

17.0 g of Al₂O₃ forms from 16 g of O₂ and excess Al ,and when the molar mass of  Al₂O₃ is 102 g/mol.

What is molar mass?

Molar mass is the mass of one mole of a substance. It is usually expressed in units of grams per mole (g/mol). For example, the molar mass of carbon is 12.01 g/mol, which means that one mole of carbon has a mass of 12.01 grams. Molar mass is useful in chemistry because it allows us to convert between mass and moles of a substance, which is important for many chemical calculations.

The molar mass of  Al₂O₃ is 102 g/mol, which means that for every 102 g of  Al₂O₃ produced, 3 × 32 g (or 96 g) of O₂ is consumed.

We can use this ratio to find the mass of  Al₂O₃ formed from 16 g of O₂:

96 g of O₂ produces 102 g of  Al₂O₃

1 g of O₂ produces (102 g / 96 g) of Al₂O₃

16 g of O₂ produces (102 g / 96 g) × 16 g = 17.0 g of  Al₂O₃

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A solution contains a total concentration of molecules [A]tot of 5.345 x 10-5 mol/l and a total concentration of molecules [B]tot of 1.245 x 10-4 mol/l. The dissociation constant for the complex AB is 2.208 x 10-6 mol/l. Part A - Concentration of AB in equilibrium Determine the equilibrium concentration [AB] of the heterodimeric complex AB formed by the molecules A and B in the solution.

Answers

The equilibrium concentration [AB] of the heterodimeric complex AB formed by the molecules A and B is 0.003026 mol/l.

Why equilibrium concentration is 0.003026 mol/l.?

The equilibrium concentration of the heterodimeric complex AB formed by the molecules A and B in the given solution can be determined using the dissociation constant for the complex AB and the total concentrations of molecules A and B provided in the problem statement.

The dissociation constant for the complex AB is given by Kd = [A][B]/[AB]

where [A] and [B] are the concentrations of the individual molecules A and B and [AB] is the concentration of the complex AB at equilibrium.

Rearranging this equation gives [AB] = [A][B]/Kd.

Substituting the given values of [A], [B], and Kd in the above equation,

we get: [AB] = (5.345 x 10⁻⁵mol/l) x (1.245 x 10⁻⁴mol/l)/(2.208 x 10⁻⁶mol/l)

[AB] = 0.003026 mol/l

Therefore, the equilibrium concentration [AB] of the heterodimeric complex AB formed by the molecules A and B in the given solution is 0.003026 mol/l.

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Did the control experiment verify or refute the results from exercise 1? use your results from exercises 1 and 2 to validate your answer.

Experiment 1 E Data Table 1 B Data Table 2 Data Table 1: Antacid Neutralization Data Mass of 0. 59 Crushed Antacid (9) Concentration 1. 0 of HCI (M) Volume HCI 5. 0 (mL) Concentration 1. 0 of NaOH (M) Initial NaOH 9. 4 mL Volume (mL) Final NaOH 8. 2 mL Volume (mL) Total Volume 1. 2 mL of NaOH Used (mL) Experiment 1 Data Table 1 Data Table 2 Data Table 2: Experimental Results I 0. 1825 g 0. 0012 HCl available for neutralization (g): Moles of NaOH required to reach stoichiometric point (mol): HCI neutralized by antacid (g): НСІ neutralized per gram of antacid (9) 0. 1387 0. 2774 Experiment 2 El Data Table 3 B Data Table 4 Data Table 3: Control Experiment Data Concentration 1. 0 of HCI (M) Volume HCI 5. 0 (mL) Concentration 1. 0 of NaOH (M) Initial NaOH 9. 2 mL Volume (mL) Final NaOH 3. 6 mL Volume (mL) Total Volume 5. 6 mL of NaOH Used (mL) Data Table 4: Control Experiment Results 0. 2049 Moles of 0. 0056mol NaOH needed to neutralize 5. 0 mL of 1. OM HCI (mol): Grams of HCI neutralized (g): NaOH 4. 4mL volume difference between back titration and control (ml): Grams of 0. 160g HCI neutralized by NaOH volume difference (9)

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Volume difference between back titration and controlHCI neutralized by NaOH volume difference is 0.0056 moles.

Given,

* Mass of Antacid = 0.5g

* [HCl] = 1M

* [tex]V_{HCl}[/tex] = 5 ml (pipetted out)

* [NaOH] = 1M

* [tex]V_{NaOH}[/tex] - 1.2 ml (consumed)

* Amt. of HCl avaliable for neutralisation = 0.1825 g

* No. of moles of NaOH req. to reach eq. point = 0.0012

* Amt. of HCl neutralised by antalid = 0.1387 g

* Amt. of HCl neutralised by antalid = 0.1387 g

* Amt. of HCl neutralised per gram of antalid = 0.1387 g

Solution: [tex]([/tex][tex]N[/tex] × [tex]V[/tex][tex])_{HCl}[/tex] =  [tex]([/tex][tex]N[/tex] × [tex]V[/tex][tex])_{NaOH}[/tex]

               (1 x 5 ) =  [tex]([/tex][tex]1[/tex] × [tex]V[/tex][tex])_{NaOH}[/tex]

             = [tex]V(NaOH)[/tex] = ( 1 x 5) / 1 = 5ml

In control expt. data  [tex]V(NaOH)[/tex] = 5.6ml

But in given data, [tex]V(NaOH)[/tex] = 1.2ml

So, Volume diff. of NaOH between back titration and control = 5.6 - 1.2 = 4.4ml

So, given follows

So, 4.4 ml of HCl means,

its Conc. will be equal to, 4.4 x 36.5 / 1000 = 0.1606 g

This is correct in control expt. results

In control expt. data, [tex]V(NaOH)[/tex] = 5.6ml

This corresponds to 5.6 x 40 / 1000 = 0.224g

This correspond to 0.224 / 40 = 0.0056 moles

This is correct in control expt. results.

Titration is a laboratory technique used to determine the concentration of an unknown solution by reacting it with a known solution. It is a quantitative method used to determine the amount of a substance in a sample. Titration is often used in chemistry to determine the concentration of acids, bases, and salts.

In a titration, a measured amount of the unknown solution is slowly added to a known solution of a substance with a known concentration called the titrant. The titrant is added until the reaction is complete, and a color change or other observable change occurs. The point at which the reaction is complete is known as the endpoint, and it is usually determined using an indicator, which changes color when the reaction is complete.

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Enzyme A has a very broad pH optimum and exhibits the same catalytic activity at pH 6.5, as at pH 8.5. However, a competitive inhibitor, X, is effective at pH 6.5, but not at pH 8.5. Explain this observation. NOTE: Your answer must include potential effect(s) of pH 8.5 on X.

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Enzyme A has a broad pH optimum, which means that it is able to function at a wide range of pH levels. Its catalytic activity is the same at pH 6.5 as it is at pH 8.5. A competitive inhibitor, X, is able to stop the enzyme from functioning at pH 6.5, but not at pH 8.5. This is because the environment at pH 8.5 is different from that at pH 6.5, and the pH 8.5 environment is not conducive for X to interact with the enzyme and block it from functioning.

At pH 8.5, the inhibitor X is less active because the higher pH causes the inhibitor to become more positively charged, thus making it less able to bind to the active site of the enzyme. Furthermore, the increased pH causes the enzyme to become more positively charged, reducing the electrostatic attraction of the inhibitor. As a result, the enzyme is able to function at pH 8.5, even in the presence of the inhibitor X.

In summary, the broad pH optimum of enzyme A means that it can remain active at both low and high pH values, while the competitive inhibitor X is only active at lower pH levels due to its reduced ability to interact with the enzyme at higher pH.

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An amine that is insoluble in water can be made to dissolve by adding it to an aqueous solution of Select one: O a. HCI O b. NaOH O c. an amide O d. none of the above; it can't be made water soluble

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An amine that is insoluble in water can be made to dissolve by adding it to an aqueous solution of NaOH.

Therefore, option b. NaOH is correct option.

An amine is an organic compound with the formula RNH2 or R2NH or R3N, where R is an alkyl or aryl group. Amines are a type of derivative of ammonia, with one or more hydrogen atoms replaced by organic substituents.

Amines are classified as primary, secondary, or tertiary depending on the number of substituents attached to the nitrogen atom. Furthermore, they are weak bases, with aqueous solutions having pH values greater than 7 because of the presence of the amino group. When amines dissolve in water, they can act as either Bronsted-Lowry bases or Lewis bases. However, most amines are insoluble in water.Water-soluble amines Amines, despite being basic compounds, are often insoluble in water, which is a polar solvent.

As a result, they may be made water-soluble by reacting with acids. For instance, when an amine is added to an aqueous solution of hydrochloric acid, the amine ionizes and dissolves in the acidic solution. Water-soluble salts, such as ammonium chloride, are formed. Other acid-based techniques for making amines water-soluble include reacting them with sulfonic acids and oxoacids. Amines with low molecular weight are also soluble in water because they can form hydrogen bonds with water molecules.Solubility in water may be achieved by adding an amine to an aqueous solution of NaOH, which serves as a base, neutralizing the amine and making it soluble. Water-insoluble amines are converted to water-soluble compounds when they react with NaOH.

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Which layers of the stem are made of parenchyma cells? cortex and pith epidermis sclerenchyma epidermis and cortex.

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The cortex and pith layers of the stem are made up of parenchyma cells. These cells are responsible for storing and transporting nutrients and water throughout the plant.

Two significant plant stem layers are the cortex and pith. The pith is found at the stem's centre, while the cortex is situated in between the epidermis and the vascular tissue. Parenchyma cells, which are the most prevalent and adaptable form of plant cell, make up both of these layers. Large vacuoles and thin cell walls are characteristics of parenchyma cells, which may perform a variety of tasks include photosynthesis, water and nutrient transport, and storage. The flow of water and nutrients between the roots and leaves in stems is especially dependent on the parenchyma cells in the cortex and pith.

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Write a chemical equation for HNO3(aq) showing how it is an acid or a base according to the Arrhenius definition.Express your answer as a chemical equation. Identify all of the phases in your answer.Part CWrite a chemical equation for HF(aq) showing how it is an acid or a base according to the Arrhenius definition.Express your answer as a chemical equation. Identify all of the phases in your answe

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Part A The chemical equation for HNO3  showing it is acid is:-

HNO3 (aq) → H+ (aq) + NO3- (aq)

The phases are HNO3 (aq) = aqueous solution, H+ (aq) = aqueous solution and NO3- (aq) = aqueous solution.

Part B The chemical equation for HF showing it is acid is:-

HF (aq) → H+ (aq) + F- (aq)

The phases are HF (aq) = aqueous solution, H+ (aq) = aqueous solution, and F- (aq) = aqueous solution.

HNO3 (aq) is an acid according to the Arrhenius definition because the chemical substance HNO3 (nitric acid) dissociates in an aqueous solution to release hydrogen ions (H+).

HF (aq) is an acid according to the Arrhenius definition because the chemical substance HF (hydrofluoric acid) dissociates in an aqueous solution to release hydrogen ions (H+).

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The epithelial cells of the proximal convoluted tubule are adapted for reabsorption by: a. having thin walls. b. having rugae folds that increase surface area. c. secreting enzymes that activate absorption of substances. d. having microscopic projections called microvilli.

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Answer: d. possessing tiny protrusions known as microvilli. The proximal convoluted tubule's epithelial cells have microvilli on their surface, which increases their surface area and improves.

the efficiency of reabsorption of chemicals from the filtrate back into the circulation. The cells do not release enzymes to promote absorption, and the rugae folds and thin walls are not adaptations for reabsorption. The proximal convoluted tubule's epithelial cells are in charge of reabsorbing vital components from the glomerular filtrate, including glucose, amino acids, and electrolytes. Many microvilli, which are tiny finger-like projections on the surface of the cell that enhance the surface area accessible for reabsorption, are present in the cells, which enable them to perform this role. This modification makes it possible for chemicals to be reabsorbted more effectively as they move through the tubule. The rugae folds and thin walls, on the other hand, have little impact on reabsorption in the proximal convoluted tubule. In this region of the nephron, reabsorption likewise does not include enzyme secretion.

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How does the number of dissolved ions in solution affect the boiling point of that solution?

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A solution's boiling point rises as the amount of dissolved ions increases because more energy is needed to overcome greater intermolecular interactions that occur between the ions and solvent molecules.

The intermolecular interactions between the molecules of the solute and solvent are impacted when a solute is dissolved in a solvent. When it comes to ionic solutes, the ions separate and create ion-dipole interactions with the solvent molecules. In non-ionic solutions, these interactions are more potent than the dipole-dipole and London dispersion forces. Because the intermolecular interactions in a solution with more dissolved ions are stronger, more energy is needed to overcome them and reach the boiling point. The van 't Hoff factor, which measures the amount of ions created by each solute molecule, and the molality of the solution are used to quantify the boiling point elevation impact.

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true/ false: the main form of ketones present in the blood is called acetoacetate (select one word answer only please)

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The sentence "The main form of ketones present in the blood is called acetoacetate" is True.

Acetoacetate is one of the three ketone bodies produced in the human liver. The other two ketones are beta-hydroxybutyrate and acetone.

What are ketones? Ketones are substances that are formed when the body breaks down fat for energy when glucose, which is the body's main source of energy, is scarce.

The liver synthesizes ketones from fats as a backup source of fuel when the body runs out of glucose.

A high concentration of ketones in the bloodstream is known as ketosis, and it can occur when a person is fasting, dieting, or has uncontrolled diabetes.

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silver nitrate can inhibit the amylase reaction by?

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By severing disfluid connections, silver nitrate can prevent the amylase reaction from happening. Wheat flour's -amylase can be prevented from working by adding silver nitrate (AgNO₃).

As silver nitrate is a non-competitive inhibitor that disrupts the folding of the enzyme, it should be the most efficient in inhibiting amylase at 37°C if different inhibitors are tried with amylase to quantify the quantities of free-reducing sugars.

Accurate evaluation of the pasting qualities of wheat flour is hampered by endogenous -amylase. When rice flour with a medium to high amylose content is gelatinized, the capacity of silver nitrate (AgNO₃) solutions at seven various concentrations (0.001-0.1 m) to inhibit -amylase activity is compared with a deionized water (dH₂O) control (AC). Using a Quick Visco Analyzer, pasting characteristics are evaluated (RVA).

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