one mole of a perfect gas at 300K as an initial pressure at 15 atm and is allowed to contract isothermally to a pressure of 1atm. calculate the entropy change from this contraction

Answers

Answer 1

Answer:

-46.67 J.

Explanation:

We are given;

Initial Pressure = 15atm = 15 × 10^(3) J

Final pressure = 1atm = 1 × 10^(3) J

Temperature = 300k

The pressures were converted to Joules.

Formula for the entropy change is;

∆S_system = ∆S_surrounding = -(dQ)/T

-(dQ)/T = (-(15 × 10^(3)) - (1 × 10^(3))/300)

= -46.67 J.


Related Questions


How does a scientist form a hypothesis?

Answers

Explanation: The hypothesis is a prediction, but it involves more than a guess. Most of the time, the hypothesis begins with a question which is then explored through background research. It is only at this point that researchers begin to develop a testable hypothesis.

(Unless you are creating an exploratory study, your hypothesis should always explain what you expect to happen)

Which substance has nonpolar covalent bonds?

CO
NO2
H2
NaBr

Answers

Answer:

H2

Explanation:

Answer:

[tex]{ \bf{H _{2} }} \\ { \tt{hydrogen \: gas}}[/tex]

A chemist makes of nickel(II) chloride working solution by adding distilled water to of a stock solution of nickel(II) chloride in water.Calculate the concentration of the chemist's working solution. Round your answer to significant digits.

Answers

Answer:

0.0900 mol/L

Explanation:

A chemist makes 330. mL of nickel(II) chloride working solution by adding distilled water to 220. mL of a 0.135 mol/L stock solution of nickel(II) chloride in water. Calculate the concentration of the chemist's working solution. Round your answer to significant digits.

Step 1: Given data

Initial concentration (C₁): 0.135 mol/LInitial volume (V₁): 220. mLFinal concentration (C₂): ?Final volume (V₂): 330. mL

Step 2: Calculate the concentration of the final solution

We prepare a dilute solution from a concentrated one. We can calculate the concentration of the working solution using the dilution rule.

C₁ × V₁ = C₂ × V₂

C₂ = C₁ × V₁/V₂

C₂ = 0.135 mol/L × 220. mL/330. mL = 0.0900 mol/L

1. Show that heat flows spontaneously from high temperature to low temperature in any isolated system (hint: use entropy change that occurs during the process for your proof).
2. Work out the entropy change for the decomposition of mercuric oxide using mathematical and graphical arguments.

Answers

Answer:

1 ) Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

                 = Q/tc - Q/th

2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

Explanation:

1) To show that heat flows spontaneously from high temperature to low temperature

example :

Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )

Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment

Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )

Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

                 = Q/tc - Q/th

2) Entropy change for Decomposition of mercuric oxide

2HgO (s) → 2Hg(l) + O₂ (g)

Δs = positive

there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C

hence ΔSdecomposition = S⁻ Hg  -  S⁻ HgO =

Δh of reaction = 181.6 KJ

Temp = 500 + 273 = 773 k

hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

An electron in the ground state absorbs a single photon of light and then relaxes back to the ground state by emitting an infrared photon (1200 nm) followed by an orange photon (600 nm). What is the wavelength of the absorbed photon?
A. 400 nm
B. 600 nm
C. 1800 nm

Answers

B. 600 nm would be the wavelength

Write the balanced half-equations for silver + oxygen= silver oxide:

Answers

Answer: The balanced half-equations for silver + oxygen= silver oxide are:

Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]

Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]

Explanation:

The word equation is as follows.

silver + oxygen = silver oxide

In terms of chemical formulas this equation can be written as follows.

[tex]Ag + O_{2} \rightarrow Ag_{2}O[/tex]

The removal on electron(s) from an atom, ion or molecule in a chemical reaction is called oxidation.

The gain of electron(s) by an atom, ion or molecule in a chemical reaction is called reduction.

Hence, half-reaction equations for the given reaction is as follows.

Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]

Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]

As the number of atoms participating in the reaction are equal. Hence, the half-equations are balanced.

Thus, we can conclude that the balanced half-equations for silver + oxygen = silver oxide are:

Oxidation-half reaction: [tex]Ag \rightarrow 2Ag^{+} + 2e^{-}[/tex]

Reduction-half reaction: [tex]O_{2} + 2e^{-} \rightarrow 2O^{-}[/tex]

1. What is the difference between accidental discoveries and scientific investigations?

Answers

Answer:

the discovery will always need to be tested more where if you're investigating you should already be in a more controlled environment

The difference between accidental discoveries and scientific investigations are as follows.

Accidental discoveriesThe discovery which is occur accidentally, means something discovered intensely.Examples of  accidental discoveries like, microwave, teflon, penicillin, plastic etc.

Scientific investigationA process of finding of answers of the question by using various research method.There are various scientific investigation, like fair testing, modeling, pattern, seeking, identification and classifying etcExample of scientific investigation are plant experiment.

To learn more about accidental discoveries,

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Imagine you are celebrating a birthday in December and need balloons. The temperature in the
store where you are purchasing the balloons is approximately 25°C and each balloon is filled
to a volume of 2 liters to obtain maximum pressure.
Use the gas laws to explain what will happen to the volume and pressure of the gas in the
balloon when go outside, where the temperature is 0°C. Include both Charles's Law
and Gay-
Lussac's Law in your answer.
ILL GIVE BRAINIEST PLEASE HELP

Answers

So I think that this is very cool elsewhere think that it’s also a little bit cool so you’re selling birthday OK the pressure is definitely 25 and the 2 L so basically the answer is five so everything is great that’s the answer

Which mechanisms is most significant in returning the ion concentrations to the resting state?

Answers

Answer:

Active transport by the Na+-K+ pump

Explanation:

Active transport by the Na+-K+ pump

Maintenance (and restoration) of the resting ion concentrations depends on the Na+-K+ pump. Once gated ion channels are closed, the combined action of the pump and ion leakage (particularly that of K+) establishes a resting membrane potential in a typical neuron of around âˆ'70 mV.

What evidence supports the law of conservation of energy?

Light energy is converted to chemical energy during photosynthesis.
Oxygen is made from the breakdown of carbon dioxide during photosynthesis.
Energy is absorbed by chlorophyll during photosynthesis.
The sun gives off light energy that is absorbed by plants.

Answers

Answer:

light energy is converted to chemical energy during photosynthesis.

Explanation:

Law of conservation of energy says: Energy can neither be created nor destroyed-only converted from one form of energy to another.

Answer:

A. Light energy is converted to chemical energy during photosynthesis.

help with the following would be greatly appreciated!

Answers

what is the question ?

4. If matter goes through a chemical change, are the physical properties likely to stay the same?

Please say yes or no and explain why.​

Answers

Answer: If matter goes through a chemical change then the physical properties are not likely to stay the same.

Explanation:

When chemical composition of a substance changes during a chemical reaction then it is called a chemical change.

Chemical change always leads to the formation of new substances. Properties like chemical reactivity, combustion, rusting etc are chemical changes.

For example, [tex]N_{2} + 3H_{2} \rightarrow 2NH_{3}[/tex]

Here, [tex]NH_{3}[/tex] will have different chemical as well as physical properties as compared to [tex]N_{2}[/tex] and [tex]H_{2}[/tex].

As physical properties are the properties that cause change in state of a substance.

Properties like boiling point, state of substance etc are physical properties.

Thus, we can conclude that if matter goes through a chemical change then the physical properties are not likely to stay the same.

Choose the correct statement. A) The cathode is the electrode where the oxidation takes place. B) The cathode is the electrode where the reduction takes place. C) Both oxidation and reduction may take place at the cathode, depending on the cell. D) The cathode is always positive

Answers

B. The cathode is the electrode where the reduction takes place took test

The mass of a single tantalum atom is 3.01×10-22 grams. How many tantalum atoms would there be in 37.1 milligrams of tantalum?

Answers

Answer: There are [tex]1.23 \times 10^{22}[/tex] atoms present in 37.1 mg of tantalum.

Explanation:

Given: Mass of single tantalum atom = [tex]3.01 \times 10^{-22} g[/tex]

Mass of tantalum atoms = 37.1 mg (1 mg = 0.001 g) = 0.0371 g

Therefore, number of tantalum atoms present in 0.0371 grams is calculated as follows.

[tex]No. of atoms = \frac{0.0371 g}{3.01 \times 10^{-22}}\\= 1.23 \times 10^{20}[/tex]

Thus, we can conclude that there are [tex]1.23 \times 10^{22}[/tex] atoms present in 37.1 mg of tantalum.

There are [tex]1.23\times 10^{20}[/tex] atoms of tantalum in 37.1 mg of tantalum.

Explanation:

Given:

Mass of single atom of tantalum =[tex]3.01\times 10^{-22} g[/tex]

To find:

The number of atoms of tantalum in 37.1 milligrams.

Solution:

Mass of tantalum = 37.1 mg

[tex]1 mg = 0.001 g\\37.1 mg=37.1\times 0.001 g=0.0371 g[/tex]

The number of atoms in 0.0371 grams of tantalum = N

Mass of a single atom of tantalum = [tex]3.01\times 10^{-22} g[/tex]

Then a mass of N atoms of tantalum will be:

[tex]0.0371 g=N\times 3.01\times 10^{-22} g\\N=\frac{0.0371 g}{ 3.01\times 10^{-22} g}\\=1.23\times 10^{20}[/tex]

There are [tex]1.23\times 10^{20}[/tex] atoms of tantalum in 37.1 mg of tantalum.

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what mass of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol

Answers

Answer: A mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.

Explanation:

Given: Mass of naphthalene = 25.0 g

Molality = 0.22 m

This means that 0.22 moles of solute is present per kg of solvent.

As 25.0 g  of naphthalene is there that will be 25.0 g per 1000 g (1 kg) is equal to 0.025 kg.

Hence, moles of phenol are calculated as follows.

[tex]Molality = \frac{moles}{mass (in kg)}\\0.22 m = \frac{moles}{0.025 kg}\\moles = 0.0055 mol[/tex]

Also, molar mass of phenol is 94.11 g/mol. This means that 1 mole of phenol contains 94.11 g.

Therefore, mass contained by 0.0055 moles of phenol is as follows.

[tex]0.0055 mol \times 94.11 g/mol \\= 0.518 g[/tex]

Thus, we can conclude that a mass of 0.518 g of phenol must be dissolved in 25.0 g of naphthalene to produce a solution that is 0.22 m in phenol.

What types of house are found in very cold regions​

Answers

Answer:

the house found in a very cold are Igloos or the ice house

g 0.500 L of a solution with a concentration of 0.25 M is needed. To prepare this solution, a stock solution with a concentration of 1.25 M is prepared. What volume of the stock solution is needed to create the desired solution

Answers

Answer:

0.1 L

Explanation:

From the question given above, the following data were obtained:

Concentration of stock solution (C₁) = 1.25 M

Volume of diluted solution (V₂) = 0.5 L

Concentration of diluted solution (C₂) = 0.25 M

Volume of stock solution needed solution (V₁) =?

The volume of the stock solution needed can be obtained as follow:

C₁V₁ = C₂V₂

1.25 × V₁ = 0.25 × 0.5

1.25 × V₁ = 0.125

Divide both side by 1.25

V₁ = 0.125 / 1.25

V₁ = 0.1 L

Therefore, the volume of the stock solution needed is 0.1 L

A chemist measures the energy change
ΔH during the following reaction:
2NH3(g)→N2(g)+3H2(g)
ΔH=160kJUse the information to answer the following questions.This reaction is:__________.
a. endothermic
b. exothermic
Suppose 70.9 g of NH3 react. Will any heat be released or absorbed?
a. Yes, absorbed
b. Yes, released
c. No.
If you said heat will be released or absorbed in the second part of this question, calculate how much heat will be released or absorbed. Round your answer to 3 significant digits.

Answers

Answer:

For (1): The correct option is (a)

For (2): The correct option is (a) and 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts.

Explanation:

There are 2 types of reactions that are classified based on enthalpy change:

Endothermic reactions: These are the reactions where heat is absorbed by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is positive for these reactions.

Exothermic reactions: These are the reactions where heat is released by the reaction. The change in enthalpy of the reaction, [tex]\Delta H_{rxn}[/tex] is negative for these reactions.

For (1):

For the given chemical reaction:

[tex]2NH_3(g)\rightarrow N_2(g)+3H_2(g);Delta H=160kJ[/tex]

As the change in enthalpy or heat of the reaction is positive. Thus, the reaction is an endothermic reaction because heat is absorbed by the reaction.

For (2):

When ammonia reacts, some amount of heat will be absorbed by the reaction. Thus, we can say the heat will be absorbed.

The number of moles is calculated by using the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex] ......(1)

Given mass of ammonia = 70.9 g

Molar mass of ammonia = 17 g/mol

Using equation 1:

[tex]\text{Moles of ammonia}=\frac{70.9g}{17g/mol}=4.17mol[/tex]

By stoichiometry of the reaction:

If 2 mole of ammonia reacts, the heat absorbed is 160 kJ

So, if 4.17 moles of ammonia reacts, the heat absorbed will be = [tex]\frac{160kJ}{2mol}\times 4.17mol=333.6kJ[/tex]

Hence, 333.6 kJ of heat will be absorbed when 70.9 g of ammonia reacts

Perform the following operation and express the answer in scientific notation.
7.296×10² ÷ 9.6×10^-9

Answers

Answer:

7.6×10¹⁰

Explanation:

7.296×10²÷9.6×10⁻⁹

To solve such problem,

We group the whole number ans solved seperately and also group the indices and solve the seperately

Step1 : 7.296/9.6 = 0.76

Step 2: applying the law of indices,

10²÷10⁻⁹ = 10⁽²⁺⁹⁾ = 10¹¹

Therefore,

7.296×10²÷9.6×10⁻⁹ = 0.76×10¹¹ = 7.6×10¹⁰

A buffer is prepared containing 0.75 M NH3 and 0.20 M NH4 . Calculate the pH of the buffer using the Kb for NH3. g

Answers

Answer:

pH=8.676

Explanation:

Given:

0.75 M [tex]NH_{3}[/tex]

0.20 M [tex]NH_{4}[/tex]

The objective is to calculate the pH of the buffer using the kb for [tex]NH_3[/tex]

Formula used:

[tex]pOH=pka+log\frac{[salt]}{[base]}\\[/tex]

pH=14-pOH

Solution:

On substituting salt=0.75 and base=0.20 in the formula

[tex]pOH=-log(1.77*10^{-5})+log\frac{0.75}{0.20}\\ =4.75+0.5740\\ =5.324[/tex]

pH=14-pOH

On substituting the pOH value in the above expression,

pH=14-5.324

Therefore,

pH=8.676

Help pls!!!
For groups 13 through 18, the number of valence electrons is equal to the group number

a. minus 10
b. minus the period number
c. plus 1
d. plus the period number ​

Answers

Answer:

a. minus 10

Explanation:

An element in group 13 = Boron ,valence electrons = 3 , therefore, valence electrons in group 13 = group no. -10

An element in group 18 = Neon, valence electrons = 8 , therefore, valence electrons in group 18 = group no. - 10

For groups 13 through 18, the number of valence electrons in an atom is equal to the group number minus 10. Therefore, option (A) is correct.

What is a valence electron?

Valence electrons in an atom can be described as the electrons occupying the outer most electron shell of an atom while the electrons in the inner shell are core electrons. Lewis structures can be helpful to calculate the number of valence electrons.

Valence electrons can be filled in several electron shells as they are caused interaction between atoms and responsible for the formation of chemical bonds. Only valence electrons can contribute to the formation of a chemical bond and decide the reactivity of the element.

The general electronic configuration of group 13 is ns²np¹ has three valence electrons. It can be determined as group number - 10 = 13 - 10 = 3.

The general electronic configuration of group 18 is ns²np⁶ has eight valence electrons. It can be determined as group number - 10 = 18 - 10 = 8.

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HELP ME PLEASE!!!!!!
I WANT IT AS PARAGRAPHHHHH NOT POINT AND ANSWER THIS TWO QUESTIONS AS 1 PARAGRAPH

Answers

One of the lab safety rules being violated is that Jodi doesn't have her hair tied up. She should have her hair tied up. Having her long hair not tied up or away from her face is a safety hazard. Jodi is also not wearing glasses, which is essential when working with chemicals. One of the Bunsen Burners aren't being used but it's on, which is a fire hazard.

Answer:

Jodi should wear her hair up to avoid a mishap, such as lighting her hair on fire. Then, instead of using a fire extinguisher on Jodi, Kimberly should use a fire blanket to prevent additional damage. Mac is preoccupied with a second flame and maybe Jodi without her safety goggles?

PLEASE ANSWER THESE:
Question 4: Biological Molecules (5 points)
A. Pepsin is an enzyme used by the human body to break down food in the stomach.

i. Explain, in terms of a chemical reaction, how pepsin helps a person. (3 points)

ii. What are the building blocks of the pepsin macromolecule? (2 points)

Answers

Answer: the answer is A

Explanation: add me hope i helped

The concentration ratio of conjugate acid to conjugate base for a 20 mM solution at pH 7.0 of an amino acid is 20:1.

Required:
a. What is the pK of the side chain?
b. What amino acid might this be?

Answers

Answer:

a. 8.3= pKa of the aminoacid

b. Cysteine

Explanation:

The pH of an acid can be obtained using the H-H equation:

pH = pKa + log [A-] / [HA]

Where pH is the pH of the buffer = 7.0

pKa is the pka of the conjugate acid = ?

[A-] / [HA] is the ratio between conjugate base and conjugate acid. As the ratio of conjugate acid to conjugate base = 20:1, the [A-] / [HA] = 1/20

Replacing:

7 = pKa + log 1/20

7 = pKa - 1.30

7+1.30 = 8.3 = pKa of the aminoacid

The only aminoacid with a side chain with pKa = 8.3 is:

Cysteine. Allowing its identification.

An unknown weak acid with a concentration of 0.530 M has a pH of 5.600. What is the Ka of the weak acid

Answers

Answer:

Ka = 3.45x10⁻⁶

Explanation:

First we calculate [H⁺], using the given pH:

pH = -log[H⁺][H⁺] = [tex]10^{-pH}=10^{-5.6}[/tex] [H⁺] = 2.51x10⁻⁶ M

To solve this problem we can use the following formula describing a monoprotic weak acid:

[H⁺] = [tex]\sqrt{C*Ka}[/tex]

We input the data that we already know:

2.51x10⁻⁶ = [tex]\sqrt{0.530*Ka}[/tex]

And solve for Ka:

Ka = 3.45x10⁻⁶

What does Gibbs free energy predict?
A. It predicts what the rate of the reaction will be.
B. It predicts how high the activation energy is.
C. It predicts if entropy will increase or decrease.
D. It predicts whether or not a reaction will be spontaneous.

Answers

Answer:

It predicts whether or not a reaction will be spontaneous.

Explanation:

The equation;

∆G= ∆H - T∆S enables us to obtain the Gibbs free energy of a chemical process.

The Gibbs free energy value tells us whether a chemical process will be spontaneous or not.

When;

∆G>0 the reaction is not spontaneous

∆G=0 the reaction is at equilibrium

∆G<0 the reaction is spontaneous

Suppose a 48. L reaction vessel is filled with 1.6 mol of Br2 and 1.6 mol of OCl2. What can you say about the composition of the mixture in the vessel at equilibrium

Answers

Answer:

There will be very little of BrOCl BrCl

Explanation:

Based on the equilibrium:

Br2(g) + OCl2(g) ⇄ BrOCl(g) + BrCl(g)

The equilibrium constant, Kc, is:

Kc = 1.58x10⁻⁵ = [BrOCl] [BrCl] / [Br2] [OCl2]

As Kc is <<< 1, in equilibrium, the concentration of products will remain lower regard to the concentration of the reactants. That means, right answer is;

There will be very little of BrOCl BrCl

When 2-methyl-3-hexene is treated with Cl2 in methanol, three products are formed (neglecting stereoisomers). Draw curved arrows to show the movement of electrons in this step of the reaction mechanism.

Answers

Answer:

Explanation:

The structural formula of 2-methyl-3-hexene is drawn in the attached image below. After then, the three possible structures were drawn and the mechanism reaction.

From the mechanism shown, methanol deprotonates methoxide proton and neutralizes the positive charge to form methoxide. This is followed by the movement of electrons that takes place from the region of higher electron density to lower electron density.

3. Does entropy increase or decrease in the following processes?
A. Complex carbohydrates are metabolized by the body, converted into simple sugars.
Answer: Increase
es-lesund
B. Steam condenses on a glass surface.
Answer:
decreare
-->
MgCl2(s)
C. Mg(s) + Cl2(g)
correct
Answer:

Answers

Answer:

hope it helps much as you can

once a recrystallization is completed and filtered, what solvent would be suitable for transferring the leftover solids to filtration funnel

Answers

Answer:

To transfer leftover solids to the filtration funnel and wash out crystals after recrystallization, ice cold methanol should be used (the mother liquor used for recrystallization).

Explanation:

Hope this helped

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