Nucleophilic aromatic substitution involves the formation of a resonance-stabilized carbanion intermediate called a Meisenheimer complex as the nucleophile attacks the ring carbon carrying the eventual leaving group.

a. True
b. False

Answers

Answer 1

Answer:

True

Explanation:

Aromatic rings undergo nucleophillic substitution reactions in the presence of a electron withdrawing group which stabilizes the Meisenheimer complex.

When the nucleophile attacks the ring carbon atom carrying the eventual leaving group. A resonance-stabilized carbanion intermediate called a Meisenheimer complex is formed.

Subsequent loss of the leaving group from the intermediate complex yields the product of the reaction.


Related Questions

10. At 573K, NO2(g) decomposes forming NO and O2. The decomposition reaction is second order in NO2 with a rate constant of 1.1 M-1s-1. If the initial concentration of NO2 is 0.056 M, how long will it take for 75% of the NO2 to decompose

Answers

Answer:

48.67 seconds

Explanation:

From;

1/[A] = kt + 1/[A]o

[A] = concentration at time t

t= time taken

k= rate constant

[A]o = initial concentration

Since [A] =[A]o - 0.75[A]o

[A] = 0.056 M - 0.042 M

[A] = 0.014 M

1/0.014 = (1.1t) + 1/0.056

71.4 - 17.86 = 1.1t

53.54 = 1.1t

t= 53.54/1.1

t= 48.67 seconds

Hence,it takes 48.67 seconds to decompose.

Alex drips hydrochloric acid onto a 5.9 g piece of magnesium in a single displacement reaction. How many molecules of HCl are required? 2HCl(aq) + Mg(s) → MgCl2(aq) + H2(g)

how do you do this?

Answers

2.96 × 10²³ molecules is required if Alex drips hydrochloric acid onto a 5.9 g piece of magnesium in a single displacement reaction

According to this question, hydrochloric acid (HCl) reacts with magnesium metal (Mg) to produce magnesium chloride and hydrogen has as follows:

2HCl(aq) + Mg(s) → MgCl2(aq) + H2(g)

Based on the balanced chemical equation above; 2 moles of HCl reacts with 1 mole of Mg.

Next, we convert 5.9g of Mg to moles by using the formula; mole = mass/molar mass

Where; Mg = 24g/mol

mole = 5.9/24

mole = 0.246mol of Mg

If 2 moles of HCl reacts with 1 mole of Mg. 0.246 mol of Mg will react with (0.246 × 2) = 0.492mol of HCl

To convert mole to number of molecules, we multiply number of moles by 6.02 × 10²³ (Avogadro's no.)

Hence, number of molecules of HCl required is 0.492mol × 6.02 × 10²³

= 2.96 × 10²³ molecules of HClHCl

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What does the third quantum number (m) describe?
A. Which energy level the electron is in
B. What type of orbital the electron is in
C. What direction the electron is spinning
D. The specific orbital within a sublevel

Answers

I think c the best answer

The third quantum number (m) describes the specific orbital within a sublevel. The correct answer is option D.

Quantum numbers are a set of four numbers that describe the properties of an electron in an atom. They specify the energy, position, and orientation of an electron in an atom.

The third quantum number (m) is also called the magnetic quantum number. It describes the orientation of the orbital in space. Each orbital within a sublevel has a different orientation in space, and the magnetic quantum number tells us which orbital we are talking about.

The value of m can range from -l to +l, where l is the second quantum number (the angular momentum quantum number). The value of l determines the number of orbitals in a sublevel, and the value of m determines the specific orbital within that sublevel.

In conclusion, the third quantum number (m) describes the specific orbital within a sublevel. It tells us how the orbital is oriented in space, and it can have values ranging from[tex]\rm -l \ to +l[/tex], where l is the second quantum number.

Option D is the correct answer.

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Three important nutritional additions to training for a long distance race are
O Protein
O Water
O Increase calories
O All of the answer choices

Answers

All of the answer choices would likely be correct. This is just due to the fact that you need to stay hydrated and have protein in your system. The increase of calories would also be nice on account of the burning of them that occurs in a long distance race- therefore, ALL OF THE ANSWER CHOICES, is the correct choice.

Gu
Magnesium metal is reacted with hydrochloric acid to produce
hydrogen gas. A sample of hydrogen gas is collected over water
in a eudiometer at 28.0°C. The atmospheric pressure is 636
mmHg. Determine the pressure (in atm) of the hydrogen gas
produced
Pressure =
atm

Answers

The pressure of hydrogen gas is 607.7 mmHg

According of Dalton's law of Partial pressure, the total pressure of a mixture of gases is the sum of the partial pressures of the individual gases in the mixture.

We can now write;

The for hydrogen collected over water, we have a mixture of hydrogen gas and water vapour.

Total pressure = pressure of hydrogen gas + vapour pressure of water

Pressure of hydrogen gas = Total pressure - vapour pressure of water

Pressure of hydrogen gas =  636 mmHg - 28.3 mmHg

Pressure of hydrogen gas = 607.7 mmHg

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HELP! How is the mass number of an atom calculated?
A - total number of electrons

B - total number of protons

C - protons plus neutrons

D - electrons plus neutrons

Answers

The answer is C. Mass number = protons + neutrons

Leo carefully pipets 50.0 mL of 0.500 M NaOH into a test tube. She places the test tube
into a small beaker to keep it from spilling and then pipets 75.0 mL of 0.250 M HCl into
another test tube. When Leo reaches to put this test tube of acid into the beaker along
with test tube of base she accidentally knocks the test tubes together hard enough to
break them and their respective contents combine in the bottom of the beaker. Is the
solution formed from the contents of the two test tubes acidic or basic? What is the pH of
the resulting solution?
Please answer below questions one by one to assist you receive full credits
(Alternatively, you can discard my hints below, solve the problem using your own way
and send me the picture/copy of your complete work through email)
The mole of NaOH before mixing is
mol (save 3 significant figures)
The mole of HCl before mixing is
mol (save 4 significant figures)
After mixing, the solution is
(choose from acidic or basic)
The total volume of mixture is
L (save 3 significant figures)
The concentration of [OH-] is
M (save 3 significant figures)
The concentration of [H'l is
M (save 3 significant figures)

Answers

Let's consider the neutralization reaction between HCl and NaOH.

NaOH + HCl ⇒ NaCl + H₂O

To determine the pH of the resulting mixture, we need to determine the reactant in excess. First, we will calculate the reacting moles of each reactant.

NaOH: 0.0500 L × 0.500 mol/L = 0.0200 mol

HCl: 0.0750 L × 0.250 mol/L = 0.0188 mol

Now, let's determine the reactant in excess and the remaining moles of that reactant.

                    NaOH    +     HCl ⇒ NaCl + H₂O

Initial           0.0200       0.0188

Reaction    -0.0188       -0.0188

Final         1.20 × 10⁻³          0

The volume of the mixture is 50.0 mL + 75.0 mL = 125.0 mL. Then, 1.20 × 10⁻³  moles of NaOH are in 125.0 mL of solution. The concentration of NaOH is:

[NaOH] = 1.20 × 10⁻³ mol/0.1250 L = 9.60 × 10⁻³ M

NaOH is a strong base according to the following equation.

NaOH ⇒ Na⁺ + OH⁻

The concentration of OH⁻ is 1/1 × 9.60 × 10⁻³ M = 9.60 × 10⁻³ M.

The pOH is:

pOH = -log [OH⁻] = -log 9.60 × 10⁻³ = 2.02

We will calculate the pH using the following expression.

pH = 14.00 - pOH = 14.00 - 2.02 = 11.98

The pH is 11.98. Since pH > 7, the solution is basic.

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Consider a hypothetical metal that has a density of 10.6 g/cm3, an atomic weight of 176.8 g/mol, and an atomic radius of 0.130 nm. Compute the atomic packing factor if the unit cell has tetragonal symmetry, values for the a and c lattice parameters are 0.570 and 0.341, respectively.

Answers

Answer:

0.3323

Explanation:

GIven that:

Density of the metal = 10.6 g/cm^3

atomic weight = 176.8 g/mol

atmic radius = 0.130 nm

values of a and c = 0.570 nm and 0.341 nm respectively

For us to determine the atomic packing factor, we need to first determine the volume of all spheres (Vs) and the volume of unit cell (Vc).

However, the number of atoms  in the unit cell (n) can be computed as:

[tex]n = \dfrac{\rho * V_c *N_A}{A} \\ \\ n = \dfrac{(10.6) * (5.7)^2 (3.41)*(10^{-24}) *(6.022*10^{23})}{176.8}[/tex]

n = 4.0

Thus, the number of atoms in the unit cell is 4

The atomic paking factor (APF) is calculated by using the formula:

[tex]\dfrac{Vs}{Vc} = \dfrac{4 * \dfrac{4}{3}\pi *R^3 }{a^2 *c} \\ \\ \\ \dfrac{Vs}{Vc} = \dfrac{4 * \dfrac{4}{3}\pi *(1.30*10^{-8})^3 }{(5.70*10^{-8})^2 *(3.41*10^{-8})}[/tex]

= 0.3323

How many milliliters of 0.204 Mol KMnO4 are needed to react with 3.24 g of iron(II) sulfate, FeSO4? The reation is as folows. 10FeSO4(aq) + 2 KMnO4(aq) = 5Fe2(SO4)3(aq) + 2MnSO4(aq) + K2SO4(aq) + 8H2O(l)​

Answers

Answer:

Explanation:

nFeSo4=3.36/152

nkmno4=1/5nFeSO4

V=17.68 ml

Hello, I am a bit stuck on this. Could someone help?

Answers

There is no picture or question. What am I supposed to answer to?

Two methods by which we can conserve water and water the plants.

Answers

Answer:

Two methods which help us to conserve water are:

Sprinkler irrigation system: this irrigation has an arrangement of vertical pipes with rotating nozzles on the top. It is more useful in the uneven and sandy land where sufficient water is not available.

Drip irrigation system: this irrigation system has an arrangement of pipes or tubes with very small holes in them to water plants drop by drop just at the base of the root. It is very efficient as water is not wasted at all.

313.9 liters of a gas has a pressure of 390.89 kPa at 76.6°C. If the pressure increases to 718.3 kPa and the temperature to 154.2°C, what would be the new volume of the gas?

A.) 210
B.) 353
C.) 470
D.) 209.92

Answers

Explanation:

P1V1/T1 = P2V2/T2

=((390.89×313.9)/76.6)×((718.3×V2)/154.2)

= (122700.371/76.7) × ((718.3×V2)/154.2)

make V2 the subject of the formula...

V2 =(122700.371×154.2)/(76.6×718.3)

V2 =18920397.21/55021.78

V2 = 343.87

Which one of these statements is/are true: I. All redox reactions with positive emfs are spontaneous. II. If a redox reaction is spontaneous, it must be fast. III. A spontaneous redox reaction will have a cathode reaction that has a more negative reduction potential than the anode. III only. I and III are true. I only. II only. All of I, II, and III are true.

Answers

Answer:

yea all the answers are true

Redox reaction is the transfer of the electron from one species to another. All of the three statements are true about the redox reaction.

What is a redox reaction?

A redox reaction is a type of chemical reaction in which the electrons are gained and lost by a species. The positive EMF of the cell results in spontaneous and will move the reaction in the forward direction.  

In a redox reaction, the cathode reaction is comparatively more negative than the reduction potential present at the anode.

Therefore, option E. All I, II, and III are true.

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When naming organic compounds, there are strict rules regarding punctuation.
1. A comma is used to separate two numbers.
2. A hyphen is used to separate a number from a letter.
Rewrite the name of this compound using hyphens and commas as appropriate.

Answers

The question is incomplete, the complete question is shown in the image attached to this answer

Answer:

2,3,3-trimethylhexane

Explanation:

IUPAC nomenclature provides a universally acceptable method of naming organic compounds from its structure.

According to this system of nomenclature;

A comma is used to separate two numbers.

A hyphen is used to separate a number from a letter.

Applying these rules, the name of the compound shown in the question should be written as 2,3,3-trimethylhexane.

The element Co exists in two oxidation states, Co(II) and Co(III), and the ions form many complexes. The rate at which one of the complexes of Co(III) was reduced by Fe(II) in water was measured. Determine the activation energy of the reaction from the following data:

T(K) K(s^-1)
293 0.054
298 0.100

Answers

We measured the Fe(II) reduction of one of the Co(III) complexes by water at a rate of about 0.545 kJ/mol (to three significant figures).

How is activation energy determined?

Calculating a Reaction's Activation Energy A reaction's rate is influenced by the temperature at which it is carried out. The molecules travel more quickly and clash more frequently as the temperature rises. Moreover, the molecules contain greater kinetic energy.

We can use the Arrhenius equation to calculate the reaction's activation energy:

k = A × exp(-Ea/RT)

When the activation energy Ea, the rate constant k, the gas constant R, and the temperature T in Kelvin are all present.

Finding the natural logarithm of the equation's two sides results in:

ln(k) = ln(A) - (Ea/RT)

This equation can be rearranged to take a linear form:

ln(k) = (-Ea/R) × (1/T) + ln(A)

y = mx + b, where (1/T) is x, (-Ea/R) is the slope, and ln(A) is the y-intercept, has the form of a linear equation.

We can get the slope of the line using the given data:

slope = (-Ea/R) = (ln(k2/k1)) / (1/T2 - 1/T1)

where the rate constants for temperatures T1 and T2, respectively, are k1 and k2.

substituting the specified values:

k1 = 0.054s⁻¹ at 293 K

k2 = 0.100s⁻¹ at 298 K

T1 = 293 K

T2 = 298 K

slope = (-Ea/R)

= (ln(0.100/0.054)) / (1/298 - 1/293)

= 65.5 kJ/mol

Therefore, the activation energy of the reaction is:

Ea = slope * R = 65.5 kJ/mol × 8.314 J/mol-K = 545 J/mol

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cuales son las caracteristicas de el livermorio

Answers

Answer:

Livermorium is a radioactive, artificially produced element about which little is known. It is expected to be a solid and classified as a metal. It is a member of the chalcogen group. Livermorium has four isotopes with known half-lives, all of which decay through alpha decay

Why is bromine more electronegative than iodine?​

Answers

Answer

Accordingly the order of electronegativity of the given elements would be: Fluorine > Chlorine > Bromine > Iodine. ( Fluorine has the highest electronegativity.)

The Lewis dot model of a molecule is shown.

Based on the model, which of the following is true?


Each carbon has three lone pairs of electrons on it.

The octet of carbon atom remains incomplete in the molecule.

The two carbon atoms share a total of six electrons with each other.

The difference between the electronegativity of carbon and hydrogen is greater than 1.7.

Answers

Answer:

The two carbon atoms share a total of six electrons with each other.

Explanation:

Looking at the structure of the molecule H-C≡C-H as shown in the question, we will notice that there exists a triple bond between the two carbon atoms.

Each bond between the two carbon atoms represents two electrons shared. Since there are three bonds between the two carbon atoms, then a total of six electrons were shared between the two carbon atoms hence the answer chosen above.

Complete the following nuclear equations. I recommend filling in the atomic number below each symbol. Instead of using superscripts in our answers, put each answer in the corresponding box. A). 54Fe 4He --> 2 1n _____

Answers

Answer:

gamma ray

Explanation:

A piece of metal has a volume of 30.0cm3 and a mass of 252g. What is its density? what metal do you think this is?

Answers

Answer:

Explanation:

get density = D = m / V = 0.252 / 0.00003 = 8400 metal will be Cu => bronze

A 10.53 mol sample of krypton gas is maintained in a 0.8006 L container at 299.8 K. What is the pressure in atm calculated using the
van der Waals' equation for Kr gas under these conditions? For Kr, a = 2.318 L'atm/mol and b = 3.978x10²L/mol.

Answers

Answer:

-401.06 atm

Explanation:

Applying,

P = (nRT/V-nb)-(an²/V²)............... Equation 1

Where P = Pressure, R = Universal gas constant, V = molar Volume, T = Temperature in Kelvin, a = gas constant a , b = gas constant b, n = numbers of mole

From the question,

Given: T = 299.8 K, V = 0.8006 L, a = 2.318 L.atm/mol, b = 3.978×10²L/mol

Constant: R = 0.0082 atm.dm³/K.mol

Substitute these values into equation 1

P = [(0.0082×299.8×10.53)/(0.8006-(10.53×397.8)]-[(10.53²×2.318/0.8006²)]

P = (25.89/-4188.0334)-(400.995)

P = -0.0618-400.995

P = -401.06 atm

J00
Sugar
(C2H2011)
260
KNO
220
180
Solubility (g solute per 100 g H,0)
140
NaNO,
NaBr
100
KBr
60
КСІ
Naci
20
0
0
20
Ce (50)
40 60
Temperature (°C)
80
100
Which compound would make a saturated solution if 98 grams were
dissolved in 100 grams of solution at 80 degrees Celsius?
O KBr
O Sugar
OKCI
O NaCl
alish

Answers

the compound would be CO2 which is glass so 80 degrees celsius would work

A fusion reaction releases energy because the binding energy of the resulting nucleus:______.
a. is released in the process.
b. is equal to the binding energy of the original nuclei.
c. is absorbed in the process.
d. is less than the binding energy of the original nuclei.
e. is greater than the binding energy of the original nuclei.

Answers

Answer:

a. is released in the process

Explanation:

In fusion reaction the nucleus is unstable so it releases its binding energy resulting in decreasing its mass so it becomes more stable.

A chemist is preparing to carry out a reaction that requires 5.75 moles of hydrogen gas. The chemist pumps the hydrogen into a 10.5 L rigid steel container at 20.0 °C. To what pressure, in kPa, must the hydrogen be compressed? (Show all work for full credit and circle your final answer) *

Answers

Answer:

The hydrogen must be compressed to 1333.13302 kPa.

Explanation:

An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar constant of the gases:

P * V = n * R * T

In this case:

P= ?V= 10.5 Ln= 5.75 molesR= 0.082 [tex]\frac{atm*L}{mol*K}[/tex]T= 20 C= 293 K (being 0 C= 273 K)

Replacing:

P* 10.5 L= 5.75 moles* 0.082 [tex]\frac{atm*L}{mol*K}[/tex] * 293 K

Solving:

[tex]P=\frac{5.75 moles* 0.082 \frac{atm*L}{mol*K} * 293 K}{10.5 L}[/tex]

P= 13.157 atm

If 1 atm is equal to 101.325 kPa, then 13.157 atm is equal to 1333.13302 kPa.

The hydrogen must be compressed to 1333.13302 kPa.

Hypercalcemia sign and symptoms severe symptoms

Answers

Answer:

Hypercalcemia can cause stomach upset, nausea, vomiting and constipation. Bones and muscles. In most cases, the excess calcium in your blood was leached from your bones, which weakens them. This can cause bone pain and muscle weakness.

Some symptoms are:

Fatigue, bone pain, headaches.

Nausea, vomiting, constipation, decrease in appetite.

Forgetfulness.

Lethargy, depression, memory loss or irritability.

Muscle aches, weakness, cramping and/or twitches.

Which of the following is an example of an optional deduction ? " a ) Medicare Ob ) Social Security c ) Retirement plan d ) State tax

Answers

Medicare  

United states program for people who are older than 60

When a marble is dropped into a beamer of water

Answers

Answer:

The water will rise.

Explanation:

hope this helps you

-Sweety<3

The mass of the marble is greater than that of the water. The marble weighs more than an equivalent volume of the water. The force from dropping the marble breaks the surface tension of the water. The marble has greater mass and volume than the water.

oxidation number of Ni in Ni(CO)4 is​

Answers

Answer:

0

Explanation:

answer from gauth math

The surface of silver metal, Ag(s), became tarnished when it was exposed to oxygen, producing Ag2O. In Ag2O, the oxidation state of silver is 1. According to this information, silver metal was _____. Please choose the correct answer from the following choices, and then select the submit answer button. Answer choices reduced

Answers

Answer: The silver metal was OXIDIZED.

Explanation:

OXIDATION is defined as loss of electrons and increase in oxidation number of an atom.

Oxidation number is the charge on an ion in an ionic compound or the charge that an atom in a covalent compound would have it it were ionic. There are basic rules governing oxidation number, they include:

--> the oxidation number of elements in their free states is ZERO. Example O2, Cl2,Na, Al, Ag.

-->The oxidation number for an ion is the same as the size and sign of the charge on the ion. For example the oxidation number of Zn2+ is +2.

--> the sum of all the oxidation numbers of the elements in a compound is zero.

--> oxidation numbers are always written with either a positive or a negative sign.

On the other hand, reduction is the opposite of oxidation. As oxidation is taking place, reduction is also taking place. Reduction involves:

--> Gain of electron and

--> decrease in oxidation number

From the question, the silver metal had ZERO as it's oxidation number because it's in free state. After being exposed to oxygen to form silver oxide, the oxidation number became +1.

Since there is an increase in the oxidation number, the silver metal was OXIDIZED

A person uses 400.8 kcal of energy to run a race. Convert the energy used for the race to the following energy units:

(provide an answer in 4 significant figures)

Calories

calories

Food Calories

Joules

Kilojoules

Hint: 1kcal=4.184kJ

Answers

Calories, we know that fat burn is calories.

Other Questions
solve the equation:|x+3| >2x-1 A 26-year-old G2P1 woman at 41 weeks gestation is brought in by ambulance. The emergency medical technician reports that a pelvic examination performed 20 minutes ago when the patient had a severe urge to push revealed that she was fully dilated and the fetal station was 2. Fetal heart tones were confirmed to be in the 150s, with no audible decelerations. When the patient is placed on the fetal monitor, the heart rate is noted to be in the 60s. The maternal heart rate is recorded as 100. Without pushing, the fetal scalp is visible at the introitus. A repeat pelvic exam shows that the infant is in the occiput anterior position. What is the most appropriate next step in the management of this patient Complete the pattern ___ 8,579 ____85.7 8.57____ Challenge: For a particular job, the Amax Employment Agency charges a fee that is equal to 15% of the firstmonth's pay. If the job pays X dollars annually, express the agency fee algebraically. what are the problems of various employment sectors? which early governing group of the united states adopted the articles of confedertion and ratified it before the end of the revolutionary warA. First continental congressB. Second continental congressC. Sons of liberty A is the point (0, 8) and R is the point (5, 6). Find the point Con the y-axis such that angle ABC is 90 what is the uniqueness of comeplex integration from line integaration? I ..... for Christine. Do you know where she is? Solve for x.A. 37B. 27C. 30D. 31 Political Cartoon Analysis. Using you knowledge ofUS History, interpret the meaning of the politicalcartoon. Answer must be at least 3 completesentences.LASTING FREEDOM, PEACE S PROSPERITY COME FROM ADHERINS TO THE LAWS OF NATUREFEDERALSTATECOUNTYLOCALWe Be PeopleLAWS OF NATURE *20 points*What is the probability of drawing yellow marble followed by a red marble from a bag containing 12 yellow marbles, 14 red marbles, and 15 green marbles if the first marble is not replaced?a. 192/1,849b. 18/43c. 21/205 You plan to pass alpha particles through a field that contains a consistent type of particle. Which configuration will result in the largest deflection of alpha particles? (1 point)low-energy alpha particles passing through a field of low mass-number-particleslow-energy alpha particles passing through a field of high mass-number-particleshigh-energy alpha particles passing through a field of high mass-number-particleshigh-energy alpha particles passing through a field of low mass-number-particles Find the slope intercept form and the point slope the line perpendicular to 4x-7y=2 going through (-6,1) I dont know if I get this right so can someone correct it or check it ? The side-by-side stemplot below displays the arm spans, in centimeters, for two classes.A stemplot titled Arm Span (centimeters). For Class A, the values are 148, 151, 153, 155, 156, 159, 161, 162, 164, 165, 169, 169, 170, 171, 175, 176, 179, 179, 180, 182, 183, 186, 186, 190. For Class B, the values are 153, 155, 16, 160, 162, 162, 162, 163, 163, 165, 166, 167, 170, 173, 180, 181, 182, 189, 192, 202.Which statement correctly compares the variability of the arm spans for Class A to that of Class B?The arm spans for Class A have more variability than the arm spans for Class B.The arm spans for Class B have less variability than the arm spans for Class A.The arm spans for Class A have less variability than the arm spans for Class B.The arm spans for Class B have about the same variability as the arm spans for Class A. What is utilization of energy 45%of the total population of a village are males and there are 22000 females Find the male population of the village. how do i find the length of VN who claim that they are superior to all?