Me please answer as follows

Me Please Answer As Follows

Answers

Answer 1

Answer:

no reaction occurs .that is no product


Related Questions

What volume is occupied by 0.104 mol of helium gas at a pressure of 0.91 atm and a temperature of 314 K ?

Answers

Answer:

The volume will be "2.95 L".

Explanation:

Given:

n = 0.104

p = 0.91 atm

T = 314 K

Now,

The Volume (V) will be:

= [tex]\frac{nRT}{P}[/tex]

By putting the values, we get

= [tex]\frac{0.104\times 0.0821\times 314}{0.91}[/tex]

= [tex]\frac{2.6810}{0.91}[/tex]

= [tex]2.95 \ L[/tex]

How many g of Al are required to produce 2.8 mol of Al2O3

Answers

Answer:

290 g Al₂O₃

General Formulas and Concepts:

Atomic Structure

Reading a Periodic TableMoles

Stoichiometry

Using Dimensional Analysis

Explanation:

Step 1: Define

[Given] 2.8 mol Al₂O₃

[Solve] g Al₂O₃

Step 2: Identify Conversions

[PT] Molar Mass of Al: 26.98 g/mol

[PT] Molar Mass of O: 16.00 g/mol

Molar Mass of Al₂O₃: 2(26.98) + 3(16.00) = 101.96 g/mol

Step 3: Convert

[DA] Set up:                                                                                                       [tex]\displaystyle 2.8 \ mol \ Al_2O_3(\frac{101.96 \ g \ Al_2O_3}{1 \ mol \ Al_2O_3})[/tex][DA] Multiply [Cancel out units]:                                                                      [tex]\displaystyle 285.488 \ g \ Al_2O_3[/tex]

Step 4: Check

Follow sig fig rules and round. We are given 2 sig figs.

285.488 g Al₂O₃ ≈ 290 g Al₂O₃

Topic: AP Chemistry

Unit: Atomic Structure

290 g is the answer yeaaaa

Rock, metal, wood, glass, animals, and plants are all forms of what?

Answers

They are all forms of solids

The equilibrium constant (K p) for the interconversion of PCl 5 and PCl 3 is 0.0121:
PCl5 (g) → PCl3 (g) + Cl2 (g)
A vessel is charged with PCl 5 giving an initial pressure of 0.123 atm and yields PCl 3 and Cl 2. At equilibrium, the partial pressure of PCl 3 is ________ atm.
A) 0.0782.
B) 0.0455.
C) 0.0908.
D) 0.0330.
E) 0.123.

Answers

Answer: At equilibrium, the partial pressure of [tex]PCl_{3}[/tex] is 0.0330 atm.

Explanation:

The partial pressure of [tex]PCl_{3}[/tex] is equal to the partial pressure of [tex]Cl_{2}[/tex]. Hence, let us assume that x quantity of [tex]PCl_{5}[/tex] is decomposed and gives x quantity of [tex]PCl_{3}[/tex] and x quantity of [tex]Cl_{2}[/tex].

Therefore, at equilibrium the species along with their partial pressures are as follows.

                         [tex]PCl_{5}(g) \rightarrow PCl_{3}(g) + Cl_{2}(g)\\[/tex]

At equilibrium:  0.123-x          x              x

Now, expression for [tex]K_{p}[/tex] of this reaction is as follows.

[tex]K_{p} = \frac{[PCl_{3}][Cl_{2}]}{[PCl_{5}]}\\0.0121 = \frac{x \times x}{(0.123 - x)}\\x = 0.0330[/tex]

Thus, we can conclude that at equilibrium, the partial pressure of [tex]PCl_{3}[/tex] is 0.0330 atm.

Question 65 pts
(07.02 MC)

During a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)

Group of answer choices

It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

Answers

Answer:

It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed

Explanation:

A reaction may be endothermic or exothermic. In an endothermic reaction, energy is absorbed by the process while in an exothermic process energy is given out by the process.

Recall that the enthalpy change of a reaction = enthalpy of products - enthalpy of reactants

Hence, where the energy required to break bonds in the reactants is less than the energy released when the products are formed, the reaction is endothermic.

For an endothermic reaction, the enthalpy change of the reaction is positive.

In this case, enthalpy of reaction = 920 - (-750) = 1670 kJ/mol

Determine the kinds of intermolecular forces that are present in each element or compound. Part A KrKr Check all that apply. Check all that apply. dispersion forces dipole-dipole forces hydrogen bonding

Answers

Answer:

The kinds of intermolecular forces that are present in each element Kr-Kr.

Explanation:

Since Kr is an inert gas and in atomic form only it is highly stable.

So, Kr gas does not form molecules.

Between the atoms of inert gas, there exist London dispersion forces.

Hence, the intermolecular forces that are present between Kr-Kr atoms is London dispersion forces.

what causes pressure inside a bicycle tire

Answers

Answer:

The air inside the Tyre causes pressure because the particles bump into each other and cause pressure the more they bump into each other or their container the higher the pressure is.

hope it is helpful for you

Consider the following chemical equilibrium: Now write an equation below that shows how to calculate from for this reaction at an absolute temperature . You can assume is comfortably above room temperature. If you include any common physical constants in your equation be sure you use their standard symbols, found in the ALEKS Calculator.

Answers

Answer:

Kp=Kc *(RT)+-3

Explanation:

The relation between Kp and Kc is given below:

Where,

Kp is the pressure equilibrium constant

Kc is the molar equilibrium constant

R is gas constant , R = 0.082057 L atm.mol⁻¹K⁻¹

T is the temperature in Kelvins

Δn = (No. of moles of gaseous products)-(No. of moles of gaseous reactants)

For the first equilibrium reaction:

Δn = (0)-(2+1) = -3

Thus, Kp is:

Kp=Kc *(RT)+-3

A. Directions:Describe ways on how to protect humans and plants and animals Choose your answer in the box and fill in the concept map below​

Answers

Answer:

i) Humans - drinks lot of water

- use umbrella

- use hats and sunglasses

- apply sunblock when swimming

- wear rush guard

ii) Plants - water the plants

-put a shade on the plants

iii) Animals - provide pets with plenty of water

- place the animals under the tree during noon time

Which of the following is true for balancing equations?
A. There must be an equal number of atoms of each element on both sides of the equation.

B. The number of products should be equal to the number of reactants

C. The properties of products should be the same as the properties of the reactants

D. There must be an equal number of compounds on both sides of the equation

Answers

Answer:

A.

Explanation:

An equation with the equal amount and proportion of atoms of each element on both sides of the reaction is commonly referred to as a balanced chemical equation.

The law of conservation of matter asserts that no observable and empirical change in the amount of matter occurs within a conventional chemical process. As a result, each element in the product would have the same equal amount or numbers of atoms as the reactants.

a laser emits light with a frequency of 4.69 x 10 to the 14th power s - 1 calculate the wavelength of this light.

Answers

Answer:

6.40x10^-7

Explanation:

answer with work is attached.

write Balance chemical reaction for preparation of chlorine with or without application heat

Answers

Answer:

2KMnO4(aq) + 16HCl(aq) ------> 2MnCl2(aq) + 2KCl(aq) + 8H2O(l) + 5Cl2(g)

Explanation:

Chlorine is a diatomic halogen gas known for its greenish-yellow colour. It has a pungent smell and is only moderately soluble in water.

It is a very reactive gas and is never found in free state in nature.

Chlorine can be prepared in the laboratory by oxidation of hydrochloric acid using KMnO4 as follows;

2KMnO4(aq) + 16HCl(aq) ------> 2MnCl2(aq) + 2KCl(aq) + 8H2O(l) + 5Cl2(g)

The set up does not need to be heated.

define the following terms atom​

Answers

an atom is the smallest particle of all matter

Which statement is true about molarity and percent by mass? (3 points)
They have the same unit.
They are inversely related.
They are different units of dilution.
They are different units of concentration.

Answers

Answer:

The guy above used photoshop here is the actual answer.

Explanation:

The true statements about molarity and percent by mass is that they are the different units of concentration

What is concentration?

Concentration of any substance present in any solution guves idea about their relative amount in that and it can de described in terms of molarity and percent by mass.

Molarity is define as the moles of solute present in per unit volume of the solution and has a unit of mol/L.Percent by mass is define as the mass of solute present in total mass of solution and it is a unit less quantity.They both gives idea about the concentration, not of the dillutions.They are not inversely related else they are directly related to each other as they are depends on the moles or mass of solute.

Hence, molarity and percent by mass are the different units of concentration and directly related to each other.

To know more about molarity & percent mass, visit the below link:

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The Li2+ ion is very similar to the hydrogen atom, in that it has one electron and energy levels similar
to the hydrogen atom. However, the relation = − (
1

2 −
1

2) cannot be used for this ion but
rather the relation = −2+ (
1

2 −
1

2) where the constant 2+=1.96x10-17J.
Use this relation to determine the third ionization energy, which is energy required to remove the last
electron from a Li2+ ion in kJ/mol, if the ion starts off in the ground state (Li2+ → Li3+
+ e-
).

Answers

Hhhhccffdfgcfghbvvbh

The energy levels of hydrogenlike one-electron ions of atomic number Z differ from those of hydrogen by a factor of Z^2. Predict the wavelength of the 2s--->1s transition in He+.

Answers

Answer:

[tex]\mathbf{\lambda \simeq 3.039 \times 10^{-8} \ m}[/tex]

Explanation:

For a hydrogen-like atom, the spectral line wavelength can be computed by using the formula:

[tex]\bar v = Z^2 R_H \Big(\dfrac{1}{n_f^2}-\dfrac{1}{n_i^2}\Big)[/tex]

where:

emitted radiation of the wavenumber  [tex]\bar v[/tex] = ???

atomic no of helium Z = 2

Rydberg's constant [tex]R_H = 1.097*10^7 \ m^{-1}[/tex]

the initial energy of  the principal quantum [tex]n_1[/tex] = 2

the initial energy of  the principal quantum [tex]n_1[/tex] = 2

Now, the emitted radiation of the wavenumber can be computed as:

[tex]\bar v = (2)^2 (1.097*10^7 \ m^{-1} ) \Big(\dfrac{1}{1^2}-\dfrac{1}{2^2}\Big)[/tex]

[tex]\bar v = 3.291 \times 10^ 7/m[/tex]

Now, the wavelength for the transition can be computed by using the relation between the wavelength λ and the emitted radiation of the wavenumber  [tex]\bar v[/tex], which is:

[tex]\bar v = \dfrac{1}{\lambda}[/tex]

[tex]\lambda = \dfrac{1}{\bar v}[/tex]

[tex]\lambda = \dfrac{1}{3.291 \times 10^{7}}\times \dfrac{m}{1}[/tex]

[tex]\mathbf{\lambda =3.03859 \times 10^{-8} \ m}[/tex]

[tex]\mathbf{\lambda \simeq 3.039 \times 10^{-8} \ m}[/tex]

For each of the following changes at equilibrium, indicate whether the equilibrium shifts in the direction of products, reactants, or does not change: CaCO3(s)+heat⇌CaO(s)+CO2(g)
1) increasing the temperature
shifts equilibrium in the direction of the reactants
does not change
shifts equilibrium in the direction of the products
2) decreasing the volume of the container
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products
does not change
3) adding a catalyst
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products
does not change
4) adding more CaO(s)
does not change
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products

Answers

Answer:

shifts equilibrium in the direction of the products

shifts equilibrium in the direction of the reactants

does not change

shifts equilibrium in the direction of the reactants

Explanation:

When a constraint such as a change in pressure, concentration or temperature is imposed on a reaction system in equilibrium, the equilibrium position will shift in such a way as to annul the constraint.

The reaction is endothermic as written. Hence, increase in temperature increases the rate of forward reaction thereby shifting the equilibrium position towards the products.

When the volume of a reaction is decreased, the equilibrium position shifts in the direction which produces the least total volume. In this case, decrease in volume shifts the equilibrium position towards the reactants.

A catalyst has no effect on the equilibrium position. However, a catalyst may cause equilibrium to be achieved faster or at a lower temperature.

When more CaO is added, the equilibrium position shifts towards the reactants side and more CaCO3 is produced.

if salt and sand is mixed with distilled water, what will be the residue and what will be the filtrate?

Answers

Answer:

salt and sand

Explanation:it is what it is

I want to create water out of 45.4 Liters of Oxygen at STP. How much water will I produce?
STP: Standard Temperature and Pressure
72g H2O
36g H20
9g H20
18g H20

Answers

Answer:

72.96 of water produce by 45.4 L of oxygen at STP.

Explanation:

[tex]H_2+\frac{1}{2}O_2\rightarrow H_2O[/tex]

1 mole of oxygen=22.4 L at STP

[tex]\frac{1}{2}[/tex]\mole of oxygen=22.4/2=11.2 L

11.2 L of oxygen required to produce water=1 mole

1 L of oxygen required to produce water=1/11.2 mole

45.4 L of oxygen required to produce water=[tex]\frac{1}{11.2}\times 45.4[/tex]

45.4 L of oxygen required to produce water=[tex]\frac{45.4}{11.2}[/tex]moles

1 mole of water=18 g

[tex]\frac{45.4}{11.2}[/tex]moles of water=[tex]18\times \frac{45.4}{11.2}[/tex]

[tex]\frac{45.4}{11.2}[/tex]moles of water=72.96 g

Hence, 72.96 of water produce by 45.4 L of oxygen at STP.

A molecule contains hydrogen bonding if it contains hydrogen covalently bonded to Group of answer choices sulfur, oxygen, or fluorine. oxygen or nitrogen. fluorine, oxygen, or nitrogen. nitrogen, fluorine, oxygen, or nitrogen. chlorine, fluorine, or iodine.

Answers

Answer: A molecule contains hydrogen bonding if it contains hydrogen covalently bonded to (fluorine, oxygen, or nitrogen)

Explanation:

A hydrogen bond is a strong dipole-dipole attraction which occurs between

--> the hydrogen atom attached to a strongly electronegative atom, and

--> another strongly electronegative atom with a lone pair of electrons.

When an electronegative atom such as fluorine, oxygen or Nitrogen is bonded to hydrogen, a dipole develops causing the hydrogen to be partially negative. The electrostatic attraction between the partially positive hydrogen atom in one molecule and the partially negative atom of the more electronegative element in another molecule gives rise to the strong dipole-dipole attraction called hydrogen bonding.

Hydrogen fluoride, water and ammonia contain the three most electronegative elements, fluorine, oxygen and nitrogen respectively, linked directly to hydrogen. In addition, lone pairs of electrons are present in the fluorine, oxygen and nitrogen atoms of the three hydrides, making hydrogen bonds to form easily between them. These compounds which exhibits hydrogen bonding always have higher melting and boiling points.

Why do gases act more ideal at
lower pressures?

Answers

Answer:

Gases act more ideal at lower pressure beacuse the attractive forces between molecules will decrease or become less significant compared to the empty space between them.

Explanation:

Generally, a gas behaves more like an ideal gas at higher temperature and lower pressure as the potential energy due to intermolecular forces becomes less significant compared with the particles "kinetic energy" and the size of the molecules become less significant compared to the empty space between them.

Attractive forces between molecules, decrease the pressure of a reak gas, slowing the molecules and reducing collisions with the walls.The higher the value of a gas, the greater the attraction between molecules and the more easily the gas will compress.

HOPE IT HELPS MUCH

answered by: John Glenly Pillazo Mahusay

define a molecular mass and mole​

Answers

Answer:

A molecular mass is mass on the substance  and mole is a unit of substance such as atoms and electrons.

Explanation:

A molecular mass is the mass of a molecule of the substance and is called as molecular weight. Molar mass is measured in moles. Mass of one mole is 6.022x10²³ particles and is expressed in grams. The molar mass is said to be the mass of the given substance that is divided by the amount of the substance and s expressed in g/ml.

Molecular mass: A molecule's molecular mass is equal to the sum of all of the atoms' individual atomic masses. It establishes the molecular mass of a single unit.

Example:

Molecular mass of O2 = 32 atomic mass units

Mole: A mole is [tex]6.02214076 x 10^2^3[/tex]of any chemical unit, including atoms, molecules, ions, and others. Due to the large number of atoms, molecules, or other components that make up any material, the mole is a useful measure to utilize. The initial definition of the mole was the number of atoms in 12 grams of carbon-12.

Learn more about mole here:https://brainly.com/question/22540912

What is the gravitational potential energy of a 1500-kg truck resting on top of a 550-m hill on earth?( earth’s gravitational pull is 9.8m/s2).

Answers

Answer:

E = 8085 kJ

Explanation:

Given that,

The mass of a truck, m = 1500 kg

Height, h = 550 m

We need to find the gravitational potential energy of the truck. It can be calculated as follows :

[tex]E=mgh[/tex]

Put all the values,

[tex]E=1500\times 9.8\times 550\\\\E=8085000\ J\\\\or\\\\E=8085\ kJ[/tex]

So, the gravitational potential energy is 8085 kJ.

determine the mass in grams of 3.75 x 10^21 atoms of zinc. (the mass of one mole of zinc is 65.39 g)

Answers

Answer: The mass in [tex]3.75 \times 10^{21}[/tex] atoms of zinc is 0.405 g.

Explanation:

Given: Atoms of zinc = [tex]3.75 \times 10^{21}[/tex]

It is known that 1 mole of every substance contains [tex]6.022 \times 10^{23}[/tex] atoms. So, the number of moles in given number of atoms is as follows.

[tex]Moles = \frac{3.75 \times 10^{21}}{6.022 \times 10^{23}}\\= 0.622 \times 10^{-2}\\= 0.0062 mol[/tex]

As moles is the mass of a substance divided by its molar mass. So, mass of zinc (molar mass = 65.39 g/mol) is calculated as follows.

[tex]Moles = \frac{mass}{molar mass}\\0.0062 mol = \frac{mass}{65.39 g}\\mass = 0.405 g[/tex]

Thus, we can conclude that the mass in [tex]3.75 \times 10^{21}[/tex] atoms of zinc is 0.405 g.

Describe the electron configuration of an atom using principal energy level, sublevels, orbitals, and periodic table. Give one example others may not think about and why you made this selection.

Silicon is not allowed.

Answers

Explanation:

The electron density number as well as the sublevel letter are used to describe valence electrons in an atom. The third total energy and subbasement p, for example, is denoted by 3p. The electron configuration of oxygen, for example, is 1s^2 2s^2 2p^4, which means the first two electrons will couple up in the 1s orbital, while the following two protons will pair up in the 2s orbital.

The sample atom is Carbon with electron configuration; 1s² 2s² 2p².

The principal energy level of an electron refers to the shellp in which the electron is located relative to the atom's nucleus. In this case only 2 energy levels exist in a carbon atom; which are energy level 1 and 2

The sublevels exist within a principal energy and the electron configuration of an atom is described with consideration of energy sublevels. The sublevels in a carbon atom are;

s and p energy sublevels.

The orbitals in this configuration are: 1s 2s 2px 2py 2pz in which case; each orbital can accommodate 2 electrons each.

Ultimately, the location of an element on the periodic table with respect to group and period are used to determine the valency and no. of energy levels in the atom of that Element.

Read more:

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Please helpplease please..help

Answers

Answer:

vague symptoms are characteristic of an acute toxin, because of the of the lack of well defined consistency that these symptoms have in relation to the course of the disease progress.

What is the
energy
2) The energy transition from n = 1 →n= 3 in hydrogen is 12.09 eV (1.6022 X 10J= 1 eV)-
of light emitted from n = 3 →n=1?
E e fiz

Answers

Answer:

energy is the ability to do work

What is the product of the following reaction? K OC(CH3)3

Answers

Answer:

See explanation and image attached

Explanation:

The reaction is an E2 reaction. It is a synchronous reaction.

The base KOC(CH3)3 abstracts a proton as the bromide ion leaves in a single step.

This yields the product as shown in the image attached.

A sample of Br2(g) takes 12.0 min to effuse through a membrane. How long would it take the same number of moles of Ar(g) to effuse through the same membrane

Answers

Answer:

6 mins

Explanation:

The time taken for Ar to effuse can be obtained as follow:

Time for Br₂ (t₁) = 12 mins

Molar mass of Br₂ (M₁) = 2 × 80 = 160 g/mol

Molar mass of Ar (M₂) = 40 g/mol

Time for Ar (t₂) =?

t₂/t₁= √(M₂/M₁)

t₂ / 12 = √(40/160)

Cross multiply

t₂ = 12 × √(40/160)

t₂ = 12 × 0.5

t₂ = 6 mins

Therefore, it will take 6 mins for the same amount of Ar to effused out.

An unknown compound's 2,4-DNP product melting range is between 144-146'C. It does not give a silver mirror on the Tollens test and is slow to react to the chromic acid test. What would this compound be

Answers

Answer:

An unknown compound's 2,4-DNP product melting range is between 144-146'C. It does not give a silver mirror on the Tollens test and is slow to react to the chromic acid test. What would this compound be

Explanation:

From the given data it is clear that the unknown compound gives positive test with 2,4-DNP reagent.

That means it has a carbonyl group.Either aldehyde or ketone.

It does not give a silver mirror on the Tollens test and is slow to react to the chromic acid test.

That means aldehyde is absent.

So, the other carbonyl group that is ketone is present in the given unknown compound.

Other Questions
Kelso's has a debt-equity ratio of 0.6 and a tax rate of 35 percent. The cost of equity is 14.5 percent and the after tax cost of debt is 4.8 percent. What is the weighted average cost of capital If x = 7+3 root 5 by 7 - 3 root 5 , find the value of x^2 + 1 by x^2 Sulfonamides:A) interfere with elongation of peptidoglycanB) are metabolic analogs of PABA and block folic acid synthesisC) attach to the 30S ribosomal subunit and disrupt protein synthesisD) damage cell membranesE) block peptidases that cross-link glycan molecules Occurs when an area heart muscle dies or is permanently damaged because if an inadequate supply of oxygen to that area; also known as heart attack. Consider random samples of size 1200 from a population with proportion 0.65 . Find the standard error of the distribution of sample proportions. Round your answer for the standard error to three decimal places. Find the Greatest common factor of 120? Show your work! Calculate the number of phosphorus atoms in 6.2g of phosphorus Any help is much appreciated Read the following excerpt from a popular work of fiction. As you read, look for clues that tell you which genre the excerpt falls into.What kinds of details help classify this story as science fiction?A. an extraterrestrial or alien raceB. plot events occurring far in the futureC. time traveling into the pastD. scientists as main characters Michelle did a survey in four butterfly parks and wrote the following observations: a construction company built a scale A rectangle has an area of 18 cm2The lengths of the sides are whole numbers.How long could the sides of the rectangle be?Give all the examples you can think of The statement that there must be a preexisting cell in order for a new cell to form is known as cell Chinese immigrants into America saw their move as a A. permanent moveB. a move that was destined for failure. C.a temporary rather than permanent move. D.something that could be casily done. Where should there be a paragraph break in the following text? Billy felt good about his speech. He thought he made the points he wanted to make clearly and that he had made a connection with the crowd. He sat in his seat feeling satisfied. (1.) Mandy would have to do something crazy to win this debate. (2.) Mandy approached the podium, feeling smug. She knew she had one last trick up her sleeve. (3.) She casually smoothed out her dress and shot Billy a devious smile. She cleared her throat and said, (4.) I accept Billys offer to be his running mate, and the crowd cheered.A. 2.B. 3.C. 1.D. 4. Amanda and Kelly used to be friends after an argument with Amanda Kelly tell everyone at the galley middle school to me at the nearby park after school to watch her fight Amanda everyone at the school met at the park and watch Kelly fight and punched her over and over a student cause the police what do you think the consequences should be for Kelly A 165-km-long high-voltage transmission line 2.00 cm in diameter carries a steady current of 1,015 A. If the conductor is copper with a free charge density of 8.50 1028 electrons per cubic meter, how many years does it take one electron to travel the full length of the cable? PLZ help me label this How much energy has 410^10m^3 of water collected in a reservoir at a hight of 100 m from the power house ?What kind of energy is that? Two guitar strings, of equal length and linear density, are tuned such that the second harmonic of the first string has the same frequency as the third harmonic of the second string. The tension of the first string is 510 N. Calculate the tension of the second string.