Melanie has completed the analysis of her data for the reaction of KMnO4 with malonic acid and data for a reaction of KMnO4 with tartaric acid. She compared the activation energies, Ea, she calculated for the two reactions and found the Ea for the malonic acid reaction to be greater than the Ea for the tartaric acid reaction.
Required:
What does this mean about the magnitude of the rate constant, k, and the rate of the reaction?
Answer:
See explanation
Explanation:
The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation;
k= Ae^-Ea/RT
Where;
k= rate constant
A= pre-exponential factor
Ea=activation energy
R= gas constant
T= temperature
We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.
Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
The study of chemistry and bonds is called chemistry. There are two types of elements metal and nonmetals.
The correct answer is mentioned below.
What is the Arrhenius equation?The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equationThe equation is as follows:-
[tex]k= Ae^{-Ea/RT[/tex] Where;
k= rate constantA= pre-exponential factorEa=activation energyR= gas constantT= temperatureWe can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have very high activation energy are markedly slow. Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.
Hence, the correct answer is mentioned above.
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Determine the effect each given mutation would have on the rate of glycolysis in muscle cells.
a. loss of binding site for fructose 1 ,6-bisphophate in pyruvate kinase.
b. loss of allosteric binding site for ATP in pyruvate kinase.
c. loss of allosteric binding site for AMP in phosphofructokinase.
d. loss of regulatory binding site for ATP in phosphofructokinase.
1. Increase
2. decrease
3. No effect
Answer:
a. Decrease
b. Increase
c. Increase
d. No effect
Explanation:
Glycolysis is present in muscle cells which converts glucose to pyruvate, water and NADH. It produces two molecules of ATP. Cellular respiration produces more molecules of ATP from pyruvate in mitochondria. Glycolysis increases in pyruvate kinase.
a. Loss of binding site for fructose 1,6-bisphosphate in pyruvate kinase: Decrease
b. Loss of allosteric binding site for ATP in pyruvate kinase: No effect
c. Loss of allosteric binding site for AMP in phosphofructokinase: Increase
d. Loss of regulatory binding site for ATP in phosphofructokinase: Increase
A. An important substrate in the glycolysis pathway is fructose 1,6-bisphosphate. It stimulates pyruvate kinase, an essential enzyme in glycolysis. The amount of pyruvate kinase that is activated will decrease if the fructose 1,6-bisphosphate binding site in pyruvate kinase is eliminated. As a result the rate of glycolysis in the muscle cells will probably decrease.
B. The allosteric ATP binding site of pyruvate kinase controls how active the enzyme is. However, pyruvate kinase is not significantly regulated by ATP in muscle cells. Therefore, it is unlikely that deletion of the ATP-binding allosteric site in pyruvate kinase would have no effect on the rate of glycolysis in muscle cells.
C. The rate-limiting enzyme in glycolysis, phosphofructokinase, is activated from all forms by AMP. It increases the rate of glycolysis by stimulating the activity of phosphofructokinase. If the allosteric binding site for AMP is eliminated, phosphofructokinase activation will be reduced. As a result, the rate of glycolysis in muscle cells will decrease.
D. Phosphofructokinase is inhibited allosterically by ATP. It regulates the rate of glycolysis by a feedback mechanism. High ATP concentrations cause phosphofructokinase to bind to its regulatory site, limiting its activity and delaying glycolysis. If the regulatory binding site for ATP is eliminated, the inhibitory action of ATP on phosphofructokinase would be lost. As a result, muscle cells will glycolysis at a faster rate.
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A uniform plastic block floats in water with 50.0 % of its volume above the surface of the water. The block is placed in a second liquid and floats with 23.0 % of its volume above the surface of the liquid.
What is the density of the second liquid?
Express your answer with the appropriate units.
Answer:
density of second liquid = 650 kg/m³
Explanation:
Given that:
The volume of the plastic block submerged inside the water = 0.5 V
The force on the plastic block = [tex]\rho_1V_1g[/tex]
[tex]= 0.5p_1 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
W [tex]= 0.5p_1 V_g[/tex]
[tex]\rho Vg = 0.5p_1 V_g[/tex]
[tex]\rho = 0.5 \rho _1[/tex]
where;
water density [tex]\rho _1[/tex] = 1000
[tex]\rho = 0.5 (1000)[/tex]
[tex]\rho = 500 kg/m^3[/tex]
In the second liquid, the volume of plastic block in the water = (100-23)%
= 77% = 0.7 V
The force on the plastic block is:
[tex]= 0.77p_2 V_g[/tex]
when the block is floating, the weight supporting the force (buoyancy force) is:
[tex]W = 0.77p_2 V_g[/tex]
[tex]\rho Vg = 0.77 \rho_2 V_g \\ \\ \rho = 0.77 \rho_2 \\ \\ 500 = 0.77 \rho_2 \\ \\ \rho_2 = 500/0.77[/tex]
[tex]\mathbf{ \rho_2 \simeq 650 \ kg/m^3}[/tex]
A skydiver slows down from 65 m/s to 5 m/s by opening the parachute. If this
takes 0.75 seconds, what is the skydiver's acceleration?
A. 45 m/s2 up
B. 80 m/s2 up
C. 45 m/s2 down
D. 80 m/s2 down
Answer:
D. -80m/s^2
Explanation:
V = u + at
5 = 65 + a (0.75)
0.75a = -60
a = -60/0.75
a = -80m/s^2
Therefore, is decelerating at 80m/s^2
Answer:
[tex]\boxed {\boxed {\sf D. \ 80 \ m/s^2 \ down}}[/tex]
Explanation:
We are asked to find the acceleration of a skydiver. Acceleration is the change in velocity over the change in time, so the formula for calculating acceleration is:
[tex]a= \frac{v_f-v_i}{t}[/tex]
The skydiver was initially traveling 65 meters per second, then he slowed down to a final velocity of 5 meters per second. He slowed down in 0.75 seconds.
[tex]\bullet \ v_f = 5 \ m/s \\\bullet \ v_i= 65 \ m/s \\\bullet \ t= 0.75 \ s[/tex]
Substitute the values into the formula.
[tex]a= \frac{ 5 \ m/s - 65 \ m/s}{0.75 \ s}[/tex]
Solve the numerator.
[tex]a= \frac{-60 \ m/s}{0.75 \ s}[/tex]
Divide.
[tex]a= -80 \ m/s^2[/tex]
The acceleration of the skydiver is -80 meters per second squared or 80 meters per second squared down. The skydiver is slowing down or decelerating, so the acceleration is negative or down.
How many colors are there in a rainbow?
[tex]\boxed{\large{\bold{\blue{ANSWER~:) }}}}[/tex]
There are 7 colours in a rainbow The colours of the rainbow are Red, Orange, Yellow, Green, Blue, Indigo and Violet.Explanation:
there r seven colors in a rainbow.red, orange, yellow, green, blue, indigo and violet.hope it helps.stay safe healthy and happy..1. Most of the chemicals included in your General Chemistry Lab kit can be discarded down a drain. Describe a situation in which you would need to neutralize a chemical before discarding down a drain.
Answer: Chemicals like acids and bases are harmful and must be neutralized before draining.
Explanation:
A strong acid or strong base is required to be diluted or neutralized before it is discarded in the drain as if is discarded without diluting and neutralization it can spill and splash from sink or drain and can harm people in chemistry lab, moreover the fumes of the discarded chemical on spilling can cause respiratory tract burning and can even cause fire hazard so it must be converted into less harmful form and then must be drained.
42 Organic compound may have names ending in -ane, -ene, -ol or -oic acid. How many of these endings indicate the compounds contain double bonds in their molecules? * (1 Point)
Answer: Organic compounds ending with the name (-ene) indicate that the compounds contain double bonds in their molecules.
Explanation:
Organic compounds are those molecules that contains carbon atoms (as their main element), hydrogen and oxygen which are usually present. The presence of numerous organic compounds is due to the following properties of carbon:
--> the exceptional ability of carbon atoms to catenate, that is, to combine with one another to form straight chains, branched chains or ring compounds containing many carbon atoms.
--> The ease with which carbon combines with hydrogen, oxygen, Nitrogen and halogens
--> The ability of carbon atoms to form single, DOUBLE or triple bonds.
The organic compound that has the name ending with -ene are known as the alkenes. The members of the alkene series are formed from the alkanes by the removal of two hydrogen atoms and the introduction of a DOUBLE BOND in the carbon chain. They are named after the corresponding alkanes by changing the -ane ending to -ene.
Note: the systematic name of a compound is formed from the root hydrocarbon by adding a suffix and prefixes to denote the substitution of the hydrogen atoms.
Tick (√) the statements that are correct.
a) By eating rice alone, we can fulfil nutritional requirement of our body. ( )
b) Deficiency Diseases can be prevented by eating a balanced diet. ( )
c) Balanced diet for the body should contain a variety of food items. ( )
d) Meat alone. is sufficient to provide all nutrients to the body. ( )
b) (√)
c)(✓)
hsjdhfjdkskkshd
Carbonic anhydrase is strongly inhibited by the drug acetazolamide, which is used as a diuretic (i.e., to increase the production of urine) and to lower excessively high pressure in the eye (due to accumulation of intraocular fluid) in glaucoma.
a. True
b. False
Answer:
a. True
Explanation:
There is strong inhibition of Carbon Anhydrase by Aceta-zolamide Carbonic Anhydrase. The drug acetazolamide is used as diuretic which increase the urine production in human body. It lowers pressure in eye in glaucoma.
CAN HF USED TO CLEAVE ETHERS EXPLAIN
Answer:
no
Explanation:
Fluoride is not nucleophilic (having the tendency to donate electrons) enough to allow for the use of HF to cleave ethers in protic media(protic solvents are polar liquid compounds that have dissociable hydrogen atoms). The rate of reaction is comparably low, so that heating of the reaction mixture is required.
how many of the electrons in a molecule of ethane are not involved in bondind
Ethane consists of 6C−H bonds and 1C−C bond. Total number of bonds is 7. Each bond is made up of two electrons
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g A high altitude balloon is filled with 1.41 x 104 L of hydrogen gas (H2) at a temperature of 21oC and a pressure of 745 torr. What is the volume of the balloon at a height of 20 km, where the temperature is -48oC and the pressure is 63.1 torr
Answer:
1.27 × 10⁵ L
Explanation:
Step 1: Given data
Initial pressure (P₁): 745 TorrInitial volume (V₁): 1.41 × 10⁴ LInital temperature (T₁): 21 °CFinal pressure (P₂): 63.1 TorrFinal volume (V₂): ?Final temperature (T₂): -48 °CStep 2: Convert the temperatures to the Kelvin scale
We will use the following expression.
K = °C + 273.15
K = 21 °C + 273.15 = 294 K
K = -48 °C + 273.15 = 225 K
Step 3: Calculate the final volume of the balloon
We will use the combined gas law.
P₁ × V₁ / T₁ = P₂ × V₂ / T₂
V₂ = P₁ × V₁ × T₂/ T₁ × P₂
V₂ = 745 Torr × 1.41 × 10⁴ L × 225 K/ 294 K × 63.1 Torr
V₂ = 1.27 × 10⁵ L
A hypothetical A-B alloy of composition 53 wt% B-47 wt% A at some temperature is found to consist of mass fractions of 0.5 for both and phases. If the composition of the phase is 92 wt% B-8 wt% A, what is the composition of the phase
Answer:
the composition of the ∝ phase C∝ = 14 or [ 14 wt% B-86 wt% A ]
Explanation:
Given the data in the question;
Co = 53 or [ 53 wt% B-47 wt% A ]
W∝ = 0.5 = Wβ
Cβ = 92 or [ 92 wt% B-8 wt% A ]
Now, lets set up the Lever rule for W∝ as follows;
W∝ = [ Cβ - Co ] / [ Cβ - C∝ ]
so we substitute our given values into the expression;
0.5 = [ 92 - 53 ] / [ 92 - C∝ ]
0.5 = 39 / [ 92 - C∝ ]
0.5[ 92 - C∝ ] = 39
46 - 0.5C∝ = 39
0.5C∝ = 46 - 39
0.5C∝ = 7
C∝ = 7 / 0.5
C∝ = 14 or [ 14 wt% B-86 wt% A ]
Therefore, the composition of the ∝ phase C∝ = 14 or [ 14 wt% B-86 wt% A ]
Calculate the mass of sodium phosphate in aqueous solution to fully react with 37 g of chromium nitrate(III) an aqueous solution?(report answer in grams and only three Sigg figs do not put the unit)
Answer:
41 g
Explanation:
The equation of the reaction is;
Cr(NO3)3(aq)+Na3PO4(aq)=3NaNO3(s)+CrPO4(aq)
Number of moles of chromium nitrate = 37g/ 146.97 g/mol = 0.25 moles
1 mole of sodium phosphate reacts with 1 mole of chromium nitrate
x moles of sodium phosphate react as with 0.25 moles of chromium nitrate
x= 1 × 0.25/1
x= 0.25 moles
Mass of sodium phosphate = 0.25 moles × 163.94 g/mol
Mass of sodium phosphate = 41 g
Use the Ka values for weak acids to identify the best components for preparing buffer solutions with the given pH values.
Name Formula Ka
Phosphoric acid H3PO4 7.5 x 10^-3
Acetic acid CH3COOH 1.8 x 10^-5
Formic acid HCOOH 1.8 x 10^-4
pH 1.9 =_________
pH 5.0 = ________
pH 3.9= ________
Answer:
pH= 1.9 then [tex]H_{3} PO_{4}[/tex]
pH = 5.0 , [tex]CH_{3} COOH[/tex]
pH = 3.9 , HCOOH
As we know range left [tex]pH= pKa+/- 1[/tex]
Classify the processes as endothermic or exothermic.
a. Ice melting
b. Water condensing on surface
c. Baking a cake
d. The chemical reaction inside an instant cold pack.
e. A car using gasoline
endothermic absorbs heat
exothermic gives heat
a. endothermic
b. exothermic
c. endothermic
d. exothermic
a. Ice melting - endothermic
b. Water condensing on the surface - exothermic
c. Baking a cake - endothermic
d. The chemical reaction inside an instant cold pack - endothermic
e. A car using gasoline - exothermic
What is an exothermic and endothermic reaction?An exothermic reaction can be described as a thermodynamic chemical reaction that emits energy from the system to its surroundings usually in the form of light, heat, or sound.
While an endothermic reaction can be described as an opposite of an exothermic reaction where the energy gains in the form of heat. In exothermic chemical reactions, the bond energy is transformed into thermal energy.
In exothermic reactions, the reaction happens the form of the kinetic energy of molecules when the energy is released. The release of energy is due to the electronic transition of electrons from one energy level to another.
The burning of gasoline, and water condensation is also an exothermic reaction in which energy is released while ice melting and baking cake is an endothermic reaction.
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What is the molecular geometry of CIO3F as predicted by the VSEPR model?
Multiple Choice
trigonal pyramidal
square planar
square pyramidal
tetrahedral
octahedral
Explanation:
since there are no lone pairs on the central atom, the shape will be tetrahedral
repining of fruits is which type of change
Answer:
irreversible.
I hope this will help you
2. For each of the ionic compounds in the table below, name the compound and explain the rule that you
used in formulating your name for the compound.
Name:
Rule for naming compound:
-PbF4
-NH4NO3
-Li2S
Answer:
2
Explanation:
Lead(|V) fluoride
Ammonium Nitrate
Lithium sulfide
For the rules, I don't know what you were taught. I just do it intuitively since I have done so much chemistry.
The first one the roman numerals represents the charge of the lead which much match the 4- charge from the 4 fluorides.
The second one is just two polyatomic ions which you just have to remember.
The last one is the typical ionic compound naming technique i guess.
For each of the following compounds, indicate the pH at which 50% of the compound will be in a form that possesses a charge and at which pH more than 99% of the compound will be in a form that possesses a charge.
ClCH2COOH (pKa = 2.86)
CH3CH2NH+3 (pKa = 10.7)
Express your answer using two decimal places
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Answer:
a. 2..86 b. 4.86 c. 10.7 d. 8.7
Explanation:
a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base (or charged form) and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 2.86
b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.99x while the acidic concentration is remaining 1 % (1 - 0.99)x = 0.01x
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base (or charged form) = 0.99x and [HA] = concentration of acid = 0.01x.
pH = pKa + log0.99x/0.01x
pH = pKa + log0.99/0.01
pH = 2.86 + log99
pH = 2.86 + 1.996
pH = 4.856
pH ≅ 4.86
c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA]
where [A⁻] = concentration of conjugate base and [HA] = concentration of acid.
At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1
So, pH = pKa + log[A⁻]/[HA]
pH = pKa + log1
pH = pKa = 10.7
d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.
Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.01x while the acidic concentration is remaining 99 % (1 - 0.01)x = 0.99x (which possesses the charge).
Using the Henderson-Hasselbalch equation,
pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base = 0.01x and [HA] = concentration of acid = 0.99x.
pH = pKa + log0.01x/0.99x
pH = pKa + log1/99
pH = 10.7 - log99
pH = 10.7 - 1.996
pH = 8.704
pH ≅ 8.7
What is the direct function of the energy released from the nuclear chain reaction in a nuclear power plant? turning the blades of the turbine heating water to produce steam powering the condenser carrying electricity from the plant to consumers
Answer:
the energy released is to make steam to create electricity. yes you are right i just didnt feel like being super technical
In a nuclear reaction, the direct function of the energy released from the nuclear chain reaction in a nuclear power plant is turning the blades of the turbine heating water to produce steam .
What are nuclear reactions?There are two types of nuclear reactions which are nuclear fusion and nuclear fission .They involve the combination and disintegration of the element's nucleus respectively.
In nuclear fission, the nucleus of the atom is bombarded with electrons of low energy which splits the nucleus in to two parts .Large amount of energy is released in the process.It is used in nuclear power reactors as it produces large amount of energy.
In nuclear fusion,on the other hand, is a reaction which occurs when two or more atoms combine to form a heavy nucleus.Large amount of energy is released in the process which is greater than that of the energy which is released in nuclear fission process.
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name a factor tht affects the value of electron affinity
Answer:
Atomic sizeNuclear chargesymmetry of the electronic configurationSometimes in lab we collect the gas formed by a chemical reaction over water . This makes it easy to isolate and measure the amount of gas produced.
Suppose the CO, gas evolved by a certain chemical reaction taking place at 50.0°C is collected over water, using an apparatus something like that in the sketch, and the final volume of gas in the collection tube is measured to be 132. mL. Calculate the mass of CO, that is in the collection tube. Round your answer to 2 significant digits.
Answer:
0.17 g
Explanation:
Since the volume of gas collected is 132 mL, we need to find the number of moles of gas present in 132 mL.
So, number of moles, n = volume of gas, v/molar volume, V
n = v/V where v = 132 mL = 0.132 L and V = 22.4 L
So, substituting the values of the variables into the equation, we have
n = v/V
n = 0.132 L/22.4 L
n = 0.005893 mol
We then need to calculate the molar mass of CO, M = atomic mass of carbon + atomic mass of oxygen = 12 g/mol + 16 g/mol = 28 g/mol
Also, number of moles of gas, n = m/M where m = mass of CO and M = molar mass of CO
m = nM
m = 0.005893 mol × 28 g/mol
m = 0.165004 g
m ≅ 0.17 g to 2 significant digits
Plastic is a polymer
-True
-False
TRUE
Explanation:
*not sure about this answer
Balance the following chemical equation.
CCl4 -> ___ C+ ___ Cl2
Answer:
Explanation:
CCl4 => C + 2Cl2
How can a Bose-Einstein condensate be formed? A. B super-heating a gas. B. By super-cooling certain types of solid. C. By super-cooling certain types of plasma. D. By super-heating a plasma
Answer:
C. By super-cooling certain types of plasma.
Explanation:
Bose-Einstein condensate is a state of matter whereby atoms or particles become cooled to a very low energy state leading to their condensation to give a single quantum state.
Note that plasma refers to atoms that have had some or even all of its electrons stripped away leaving only positively charged ions. Simply put, plasma is ionized matter.
When certain types of plasma are super cooled, Bose-Einstein condensate are formed.
Ethylene glycol (C2H6O2) is mixed with water to make auto engine coolants. How many grams of C2H6O2 are in 5.00 L of a 6.00 M aqueous solution
Answer:
1860g.
Explanation:
It is known that the molar mass of C2H6O2 is 62.08 g/mol.,
Now to solve for the number of moles of solute, one must multiply both
sides by the volume:
moles of solute = (6.00 M)(5.00 L) = 30.0 mol
Notice since the definition of molarity is mol/L, the
product M × L gives mol, a unit of amount.
Use the molar mass of C3H8O3, one can convert mol to g:
Mass m =30 mol × 62.08 g/mol
m = 1860g.
Hence, there are 1,860 g of C2H6O2 in the specified amount of
engine coolant.
0.28 M Ca(NO3)2
Express your answer using two significant figures.
Answer:
Mass=Moles × RFM
Mass= 0.28M× 164
Mass= 45.92 grammes
Si enfriamos mercurio de 100C. Calcular la cantidad de calor que se debe restar sabiendo que la masa de mercurio es de 1800gr
Answer:
I do not speak Spanish.
Explanation:
A molecule of acetone and a molecule of propyl aldehyde are both made from 3 carbon atoms, 6 hydrogen atoms, and 1 oxygen atom. The molecules differ in their arrangement of atoms. How do formulas for the two compounds compare? Both compounds have the same molecular formula, but have unique structural formulas. Both compounds have unique molecular formulas and structural formulas. Both compounds have the same structural formula, but have unique molecular formulas.
Explanation:
The structures of both acetone and propanal are shown below:
In the formula of propanal there is -CHO functional group at the end.
In acetone -CO- group is present in the middle that is on the second carbon.
The molecular formula is C3H6O.
Both have same molecular formula but different structural formulas.
