Answer:
W = 278.64375 Joules
Explanation:
The information given in this problem are;
Initial volume = 0L
Final volume = 2.50L
ΔV = 2.50 - 0 = 2.50 L
External pressure, P = 1.10 atm
Work = ?
These parameters are related by the equation;
w = - P ΔV
W = - (1.10 )(2.50)
W = 2.75 L atm
Upon conversion to joules;
1 liter atmosphere is equal to 101.325 joule
W = 278.64375 Joules
An aqueous solution of potassium bromide, KBr, contains 4.34 grams of potassium bromide and 17.4 grams of water. The percentage by mass of potassium bromide in the solution is 20 %.
Answer:
True
Explanation:
The percentage by mass of a substance in a solution can be calculated by dividing the mass of the substance dissolved in the solution by the total mass of the solution. This can be expressed mathematically as:
Percentage by mass = mass of substance in solution/mass of solution x 100
In this case;
mass of KBr = 4.34 grams
mass of water = 17.4 grams
mass of solution = mass of KBr + mass of water = 4.34 + 17.4 = 21.74
Percentage by mass of KBr = 4.34/21.74 x 100
= 19.96 %
19.96 is approximately 20%.
Hence, the statement is true.
Half-cells were made from a nickel rod dipping in nickel sulfate solution and a copper rod dipping in copper sulfate solution. The cells were combined to construct a voltaic electrochemical cell. Sketch the cell and label anode and cathode with charges, electrode material and electrolyte solutions, half-reactions and overall reaction, give direction of electron flow and movement of ions.
Answer:
Check the Attachment.
Half-reactions:
Anode: (OXIDATION) Ni --> Ni2+ + 2e-
Cathode: (REDUCTION) Cu2+ +2e- --> Cu
Overall reaction: Ni + Cu2+ --> Ni2+ + Cu
Explanation:
Overall, reaction is basically Anode + Cathode, where electrons on both sides cancel out (if not, you need to multiply the equation in a way you can cancel them out).
Hope this helps.
20. What volume of 0.350M KMnO4 solution must be diluted to prepare 600. mL of
0.150M KMnO4 solution?
Answer:
25.7 mL
Explanation:
Step 1: Given data
Initial volume (V₁): ?Initial concentration (C₁): 0.350 MFinal volume (V₂): 600 mLFinal concentration (C₂): 0.150 MStep 2: Calculate the volume of the initial solution
We have a concentrated solution and we want to prepare a diluted one. We can calculate the initial volume using the dilution rule.
C₁ × V₁ = C₂ × V₂
V₁ = C₂ × V₂ / C₁
V₁ = 0.150 M × 600 mL / 0.350 M
V₁ = 25.7 mL
Emission of which one of the following leaves both atomic number and mass number unchanged?
(a) positron
(b) neutron
(c) alpha particle
(d) gamma radiation
(e) beta particle
Answer: Gamma Radiation
Explanation:
The emission of Gamma rays does not cause a change in both the atomic and mass number. They are electromagnetic radiation.
The radiations that leaves without changing the atomic mass and atomic number of the particle have been gamma radiations. Thus, option D is correct.
Radiations have been the energy that has been evolved by the particles during energy transitions. The nuclear decay results with the release of the energy from the particle resulting in the change in the atomic mass.
The electromagnetic radiations have been capable of emitting the radiation without changing the mass and atomic number of the element. The gamma radiations have been the electromagnetic radiations. Thus, option D is correct.
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whts the ph of po4 9.78
Answer:
4.22
Explanation:
We know from the question, that the pOH of the solution is 9.78. Now the pOH is defined as -log [OH^-].
If the pOH of a solution is given, one may obtain the pH of such solution from the formula;
pH + pOH =14
Hence we can write;
pH = 14-pOH
pH = 14 - 9.78 = 4.22
Hence the pH of the solution is 4.22.
Calculate the moles of Iron (Fe) in 3.8 x 10^{21} atoms of Iron. Please show your work
Answer: 6.31×10⁻³ moles Fe
Explanation:
To calculate moles when given atoms, we need to use Avogadro's number.
Avogadro's number: 6.022×10²³ atoms/mol
[tex](3.8*10^2^1 atoms)*\frac{mol}{6.022*10^2^3 atoms} =6.31*10^-^3 mols[/tex]
The atoms cancel out, and we are left with moles. There are 6.31×10⁻³ moles Fe.
Which one of the following compound does not undergo an aldol addition reaction in presence of aqueous sodium hydroxide?
a. butanal
b. 2-methylbutanal
c. 3-methylpentanal
d. 2, 2-dimethylbutanal
The compound does not undergo an aldol addition reaction in presence of aqueous sodium hydroxide is 2, 2-dimethylbutanal.
What is aldol reaction?The Aldol Reaction occurs when the enolate of an aldehyde or ketone combines with the carbonyl of another molecule at the aplha-carbon under basic or acidic circumstances to produce beta-hydroxy aldehyde or ketone.
For the formation of enolate ion, compound should contain alpha hydrogen in it and among the given compound only 2, 2-dimethylbutanal will not have alpha hydrogens.
Butanal, 2-methylbutanal and 3-methylpentanal will have aplha hydrogens in it so that it takes part in the aldol reaction.Hence 2, 2-dimethylbutanal does not undergo an aldol addition reaction.
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Determine whether the following statement about reaction rates is true or false. If the statement is false, select the reason why.
Increasing the temperature of a reaction system decreases the activation energy of the reaction.
A. True
B. False
Answer:
False
Explanation:
The reaction rate increases if the temperature also increases, as does the concentration of ractives or the presence of catalysts.
The reaction rate talks about how reagents are converted into products as a function of time, this process can take less or more depending on the factors to which the reaction is exposed.
The increasing temperature generates an increase in the kinetic energy of the particles, promoting their proximity and their reaction between them to be able to give the final product, so a faster reaction occurs, which is why it has promoted when the particles collide.
What is Non Metal?
help me find
The element which can not loose electron easily and having electronagtive character is called non-metal it has following property-
1. it can not conduct heat and electricity
2. it is netiher ductile not malleable
3. it is not lsuturous and also not sonorous
Explanation:
a nonmetal (or non-metal) is a chemical element that mostly lacks the characteristics of a metal. Physically, a nonmetal tends to have a relatively low melting point, boiling point, and density. A nonmetal is typically brittle when solid and usually has poor thermal conductivity and electrical conductivity. Chemically, nonmetals tend to have relatively high ionization energy, electron affinity, and electronegativity. They gain or share electrons when they react with other elements and chemical compounds. Seventeen elements are generally classified as nonmetals: most are gases (hydrogen, helium, nitrogen, oxygen, fluorine, neon, chlorine, argon, krypton, xenon and radon); one is a liquid (bromine); and a few are solids (carbon, phosphorus, sulfur, selenium, and iodine). Metalloids such as boron, silicon, and germanium are sometimes counted as nonmetals.
Which of the following is a salt that will form from the combination of a strong base with a weak acid?
Select the correct answer below:
A. NaHCO3
B. H2O
C. CH3CO2H
D. NH4Cl
Answer:
A. NaHCO₃
Explanation:
NaHCO₃ ⇒ NaOH + H₂CO₃
NaOH is a strong base and H₂CO₃ is a weak acid. Therefore, NaHCO₃ is a salt of a strong base-weak acid reaction. The salt is basic because carbonic acid (H₂CO₃) is a weak acid so it remains undissociated. So, there is a presence of additional OH⁻ ions that makes the solution basic.
Hope that helps.
A chemist prepares a solution of sodium nitrate by measuring out of sodium nitrate into a volumetric flask and filling the flask to the mark with water.
Calculate the concentration in mol/L of the chemist's sodium nitrate solution. Round your answer to 3 significant digits.
Answer:
5.74M or 5.74 mol/L (to 3 sign. fig.)
Explanation:
The molar mass of NaNO3 is 85g/mol, which means that:
1 mole of NaNO3 - 85g
? moles - 122.0g
= 122/85 = 1.44 moles
Concentration in mol/L = no. of moles (moles) ÷ volume (L)
[tex]\frac{1.44}{0.250}[/tex] = 5.74M or 5.74 mol/L (to 3 sign. fig.)
I hope the steps are clear and easy to follow.
A laboratory assistant needs to prepare 217 mL of 0.246 M solution. How many grams of calcium chloride will she need
Answer:
5.92 g
Explanation:
Convert milliliters to liters.
217 mL = 0.217 L
Since molarity (M) is moles per liter(mol/L), multiply the molarity by the volume to find out how many moles you will need.
0.217 L × 0.246 M = 0.05338 mol
Now, convert the moles to grams using the molar mass. The molar mass of calcium chloride is 110.98 g/mol.
0.05338 mol × 110.98 g/mol = 5.924 g ≈ 5.92 g
You will need 5.92 g of calcium chloride.
Atoms are indivisible spheres. 1.plum pudding model 2.Dalton model 3.Bohr model
Answer: 2. Dalton Model
Explanation:
John Dalton proposed that atoms are indivisible spheres. Although his model of an atom was not entirely new to the scientific world since the ancient Greeks has made a similar statement in the past ( all matter are made up of small indivisible particle called atom).
As of when Dalton proposed his model of an atom, electrons and nucleus where yet to be discovered.
The following reaction, catalyzed by iridium, is endothermic at 700 K: CaO(s) + CH4(g) + 2H2O (g) → CaCO3 (s) + 4H2 (g) For the reaction mixture above at equilibrium at 700 K, how would the following changes affect the total quantity of CaCO3 in the reaction mixture once equilibrium is re-established?
a. Increasing the temperature
b. Adding calcium oxide (CaO)
c. Removing methane (CH4)
d. Increasing the total volume
e. Adding iridium
Answer:
A. Increasing the temperature will favor forward reaction and more CaCo3 formed.
B. More CaCo3 will be formed.
C. CaCo3 will decrease and more react ants formed.
D. Less CaCo3 will be formed.
E. Iridium is a catalyst so there is no effect
Explanation:
A. Temperature will increase because it's an endothermic reaction.
B. Adding Cao will favor forward reaction and more CaCo3 formed.
C. Removing methane, more react ants are formed and CaCo3 decreases.
D. Irridi is a catalyst so it has no effect on the CaCo3 but only speeds its rate of reaction.
Consider the following reaction at 298K.
I2 (s) + Pb (s) = 2 I- (aq) + Pb2+ (aq)
Which of the following statements are correct?
Choose all that apply.
ΔGo > 0
The reaction is product-favored.
K < 1
Eocell > 0
n = 2 mol electrons
B-
Answer:
Eªcell > 0; n = 2
Explanation:
The reaction:
I2 (s) + Pb (s) → 2 I- (aq) + Pb2+ (aq)
Is product favored.
A reaction that is product favored has ΔG < 0 (Spontaneous)
K > 1 (Because concentration of products is >>>> concentration reactants).
Eªcell > 0 Because reaction is spontaneous.
And n = 2 electrons because Pb(s) is oxidizing to Pb2+ and I₂ is reducing to I⁻ (2 electrons). Statements that are true are:
Eªcell > 0; n = 2If we want to change a gas to its liquid state, should we add or remove energy from the gas?
Al diluir 25 g de sal de mesa en 250ml de agua, ¿En cuántos °C aumenta el punto de ebullición de la disolución formada? ( Ke = 0,52 °C/molal , PM NaCl = 58,44 g/mol)
Answer:
ΔT=[tex]0.87^{\circ}C[/tex]
Explanation:
Para esta pregunta debemos recordar la ecuación que nos permite calcular el aumento ebulliscopico (aumento del punto de ebullición):
ΔT=[tex]Kb*m[/tex]
Donde ΔT es el valor del aumento del punto de ebullición. Kb es la constante ebulloscopica para el agua ([tex]0.512\frac{Kg~^{\circ}C}{mol}[/tex]) y m es la molalidad ([tex]m=\frac{mol}{Kg~ of~ solvente}[/tex]).
Por lo tanto el primer paso es calcular la molalidad de la solución. Para lo cual tendremos que calcular las moles de sal en los 25 g. Si queremos hacer esto debemos recordar que la formula de sal de mesa es NaCl y que la masa molar de NaCl es 58.44 g/mol. Por lo tanto:
[tex]25~g~NaCl\frac{1~mol~NaCl}{58.44~g~NaCl}~=~0.42~mol~NaCl[/tex]
Ahora bien, también debemos saber los Kg de agua en la solución. Por lo que podemos usar la densidad del agua (1 g/mL) para convertir de mL a g y luego hacer la conversión a Kg:
[tex]250~mL\frac{1~g}{1~mL}\frac{1~Kg}{1000~g}~=~0.25~Kg[/tex]
Finalmente para el calculo de la molalidad podemos dividir los dos valores:
[tex]m=\frac{0.42~mol}{0.25~Kg}=1.68[/tex]
Con el valor de la molalidad se puede calcular ΔT al reemplazar los valores:
ΔT=[tex]1.68~\frac{mol}{Kg}*0.52\frac{Kg~^{\circ}C}{mol}=0.87^{\circ}C[/tex]
Si la temperatura de ebullición normal del agua es 100 ºC. Podemos calcular la temperatura final si adicionamos ΔT:
Temperatura final = 100 + 0.87 = 100.87 ºC
Espero sea de ayuda!
What is the final volume V2 in milliliters when 0.551 L of a 50.0 % (m/v) solution is diluted to 23.5 % (m/v)?
Answer:
[tex]V_2=1.17L[/tex]
Explanation:
Hello,
In this case, for dilution processes, we must remember that the amount of solute remains the same, therefore, we can write:
[tex]V_1C_1=V_2C_2[/tex]
Whereas V accounts for volume and C for concentration that in this case is %(m/v). In such a way, the final volume V2 turns out:
[tex]V_2=\frac{V_1C_1}{C_2}= \frac{0.551L*50.0\%}{23.5\%}\\ \\V_2=1.17L[/tex]
Best regards.
What attractive force holds two hydrogen atoms and one oxygen atom
together to make the substance water?
A. Molecules
B. Chemical bonding
O C. Valence electrons
O D. Cations
Answer:
It is a hydrogen bond but if I had to coose one of thee answers it is b. chemical bonding
Explanation:
g Which ONE of the following pairs of organic compounds are NOT pairs of isomers? A) butanol ( CH3-CH2-CH2-CH2-OH ) and diethyl ether ( CH3–CH2–O–CH2–CH3 ) B) isopentane ( (CH3)2-CH-CH2-CH3 ) and neopentane ( (CH3)4C ) C) ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 ) D) acrylic acid ( CH2=CH-COOH ) and propanedial ( OHC–CH2–CHO ) E) trimethylamine ( (CH3)3N ) and propylamine ( CH3-CH2-CH2-NH2 )
Answer:
ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 )
Explanation:
Isomers are compounds that have the same molecular formula but different structural formulas. Hence any pair of compounds that can be represented by exactly the same molecular formula are isomers of each other.
If we look at the pair of compounds; ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 ), one compound has molecular formula, C2H7ON while the other has a molecular formula, C2H5ON, hence they are not isomers of each other.
Calculate the molarity of bromide ions in 250. mL of a solution containing 25.9 g NaBr and 0.155 moles of HBr.
Answer:
[tex]1.628 M[/tex]
Explanation:
From the question we were given 0.155 moles of HBr, but Br and H are in ratio 1:1, then there are 0.155 moles of Br- ions.
We were also told that the solution contain NaBr, of 25.9 g. Then it must be converted to moles.
molar mass of NaBr =(22.99g + 79.90 )
= 102.89 g per mol.
the moles of NaBr can be calculated as 25.9 / 102.89
=0.252 moles
But Na and Br are in a ratio 1:1 , then there are 0.252 moles of Br-.
Then to get two Br- mol , we will add the first and second mol of Br- together
= 0.155 + 0.252
=0.407 moles.
The given solution has volume of 250 mL, but we know that there are 1000 ml in a liter, then if we convert to L for unit consistency we have
= 250/1000
= 0.25 L
molarity=0.407 moles/0.25 L
= 1.628 M.
Therefore, Br ion molarity is 1.628 M.
The molarity of the Br ions in the 250 ml solution has been 1.628 M.
Moles can be defined as the mass per unit molecular mass. Moles can be expressed as:
Moles = [tex]\rm \dfrac{weight}{molecular\;weight}[/tex]
Moles of NaBr = [tex]\rm \dfrac{25.9}{102.89}[/tex]
Moles of NaBr = 0.252 mol
Moles of HBr = 0.155 mol.
Since both the compounds have 1:1 ratio of atom: Br, the Br produced has been equal to the concentration of the compound.
Br from NaBr = 0.252 mol
Br from HBr = 0.155 mol.
Total Br ions = 0.407 mol.
Molarity can be expressed as:
Molarity = [tex]\rm moles\;\times\;\dfrac{1000}{Volume\;(ml)}[/tex]
Molarity of Br ions = 0.407 × [tex]\rm \dfrac{1000}{250\;ml}[/tex]
Molarity of Br ions = 1.628 M.
The molarity of the Br ions in the 250 ml solution has been 1.628 M.
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Indicate the peptides that would result from cleavage by the indicated reagent: a. Gly-Lys-Leu-Ala-Cys-Arg-Ala-Phe by trypsin b. Glu-Ala-Phe-Gly-Ala-Tyr by chymotrypsin
Answer:
a. Gly-Lys + Leu-Ala-Cys-Arg + Ala-Phe
b. Glu-Ala-Phe + Gly-Ala-Tyr
Explanation:
In this case, we have to remember which peptidic bonds can break each protease:
-) Trypsin
It breaks selectively the peptidic bond in the carbonyl group of lysine or arginine.
-) Chymotrypsin
It breaks selectively the peptidic bond in the carbonyl group of phenylalanine, tryptophan, or tyrosine.
With this in mind in "peptide a", the peptidic bonds that would be broken are the ones in the "Lis" and "Arg" (See figure 1).
In "peptide b", the peptidic bond that would be broken is the one in the "Phe" (See figure 2). The second amino acid that can be broken is tyrosine, but this amino acid is placed in the C terminal spot, therefore will not be involved in the hydrolysis.
Match each compound with its appropriate pKa value.
(a) 4-Nitrobenzoic acid, benzoic acid, 4-chlorobenzoic acid pKa=4.19,3.98, and 3.41pKa =4.19,3.98, and 3.41
(b) Benzoic acid, cyclohexanol, phenol pKa=18.0,9.95, and 4.19pK a =18.0,9.95, and 4.19
(c) 4-Nitrobenzoic acid, 4-nitrophenol, 4-nitrophenylacetic acid pKa=7.15,3.85, and 3.41pK a =7.15,3.85, and 3.41
Answer:
Explanation:
a) 4-nitrobenzoic acid pKa= 3.41
benzoic acid pKa= 4.19
4-chlorobenzoic acid pKa= 3.98
b) benzoic acid pKa= 4.19
cyclohexanol pKa= 18.0
phenol pKa= 9.95
c) 4-Nitrobenzoic acid pKa= 3.41
4-nitrophenol pKa= 7.15
4-nitrophenylacetic acid pKa= 3.85
I need to name an ionic compound containing a transition metal cation and a halogen anion. Below are the rules I should follow to write the correct name for such compound, but one of the options is incorrect: identify and select it.
a. Identify the metal and write its name first
b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table
c. From the charge of the anion work out the charge of cation as Roman number in parenthesis: specify this charge in the name as a Roman number in parenthesis.
d. Write the number of the anion after the name of the metal
Answer:
b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table
Explanation:
The keyword in this problem us "transition metal". Transition metals are found between the group 2 and group 3 elements. They have the d sub shells and also exhibit variable oxidation numbers (valency).
Among the options, the incorrect option is option B.
This is because transition metals d not have a fixed oxidation number and they cannot be obtained by looking up the group in the periodic table.
The iconic compounds obtain a transition of metal caution and a halon anon. As per the rules the correct name of the compounds should be written as to identify the incorrect one.
Option B use the ability to check and to work out the charges (oxidation number) of the transition metal as per the group given in the table. The problem with the keyword is transition metal.Learn more about the ionic compound containing a transition metal.
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A 0.753 g sample of a monoprotic acid is dissolved in water and titrated with 0.250 M NaOH. What is the molar mass of the acid if 21.5 mL of the NaOH solution is required to neutralize the sample?
Answer:
[tex]MM_{acid}=140.1g/mol[/tex]
Explanation:
Hello,
In this case, since the acid is monoprotic, we can notice a 1:1 molar ratio between, therefore, for the titration at the equivalence point, we have:
[tex]n_{acid}=n_{base} \\\\V_{acid}M_{acid}=V_{base}M_{base}\\\\n_{acid}=V_{base}M_{base}[/tex]
Thus, solving for the moles of the acid, we obtain:
[tex]n_{acid}=0.0215L*0.250\frac{mol}{L}=5.375x10^{-3}mol[/tex]
Then, by using the mass of the acid, we compute its molar mass:
[tex]MM_{acid}=\frac{0.753g}{5.375x10^{-5}mol} \\\\MM_{acid}=140.1g/mol[/tex]
Regards.
15.Vicinal coupling is:A)coupling between 1H nuclei attached to adjacent C atoms.B)coupling between 1H nuclei in an alkene.C)coupling between 1H nuclei attached to the same C atom.D)coupling between 1H nuclei in an alkane.
Answer:
A)coupling between 1H nuclei attached to adjacent C atoms.
Explanation:
The word ‘vicinal’ in chemistry means three bonds from the functional groups. The two functional groups are in a relationship with the atoms in adjacent position to them.
The 1H nuclei consists of two Hydrogen nucleus which acts as the functional groups. They are however attached and in a relationship with the adjacent C atoms. This makes option A the right choice.
Predict the sign and calculate ΔS° for a reaction. Close Problem Consider the reaction H2CO(g) + O2(g)CO2(g) + H2O(l) Based upon the stoichiometry of the reaction the sign of Sºrxn should be _________ . Using standard thermodynamic data (in the Chemistry References), calculate Sºrxn at 25°C. Sºrxn = J/K•mol
Answer:
[tex]\mathbf{S^0_{rxn} = -140.41 \ J/mol.K}[/tex]
Based upon the stoichiometry of the reaction the sign of Sºrxn should be negative
Explanation:
Consider the reaction:
H2CO(g) + O2(g) --------> CO2(g) + H2O(l)
Using standard thermodynamic data;
Based upon the stoichiometry of the reaction the sign of Sºrxn should be _________ . calculate Sºrxn at 25°C. Sºrxn = J/K•mol
At standard thermodynamic data
[tex]\mathtt{S^0_{rxn} = \sum S^0 _{product} - \sum S^0 _{reactant}}[/tex]
[tex]S^0(CO_2)[/tex] = 213.79 J/mol.K
[tex]S^0(H_2O)=[/tex] 69.95 J/mol.K
[tex]S^0 ({H_2CO}) =[/tex] 218.95 J/mol.K
[tex]S^0 (O_2)[/tex] = 205.2 J/mol.K
[tex]\mathtt{S^0_{rxn} = (213.79 + 69.95) J/mol.K - (218.95+ 205.2) J/mol.K}[/tex]
[tex]\mathtt{S^0_{rxn} = (283.74) J/mol.K - (424.15) J/mol.K}[/tex]
[tex]\mathbf{S^0_{rxn} = -140.41 \ J/mol.K}[/tex]
Based upon the stoichiometry of the reaction the sign of Sºrxn should be negative
Suppose that 13 mol NO2 and 3 mol H2O combine and react completely. How many moles of the reactant in excess are present after the reaction has completed
Answer:
The number of moles of excess reagent NO₂ that are present after the reaction has completed is 7 moles.
Explanation:
The balanced reaction is:
3 NO₂ + H₂O → 2 HNO₃ + NO
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of reactants and products participate in the reaction:
NO₂: 3 molesH₂O: 1 moleHNO₃: 2 molesNO: 1 molesThe limiting reagent is one that is consumed in its entirety first, determining the amount of product in the reaction. When the limiting reagent ends, the chemical reaction will stop.
In other words, the limiting reagent is that reagent that is consumed first in a chemical reaction, determining the amount of products obtained. The reaction depends on the limiting reagent, because the other reagents will not react when one is consumed.
You can apply the following rule of three: if by stoichiometry of the reaction 3 moles of NO₂ react with 1 mole of H₂O, 13 moles of NO₂ react with how many moles of H₂O?
[tex]moles of H_{2}O=\frac{13 moles of NO_{2}*1 mole of H_{2}O }{3 moles of NO_{2}}[/tex]
moles of H₂O= 4.33 moles
But 4.33 moles of H₂O are not available, 3 moles are available. Since you have less moles than you need to react with 13 moles of NO₂, water H₂O will be the limiting reagent.
To determine the number of moles of excess reagent NO2 that are present after the reaction is complete, you can apply the following rule of three: if by stoichiometry of the reaction 1 moles of H₂O react with 3 mole of NO₂, 3 moles of H₂O react with how many moles of NO₂?
[tex]moles of NO_{2}=\frac{3 moles of NO_{2}*3 mole of H_{2}O }{1 mole of H_{2}O}[/tex]
moles of NO₂= 6 moles
If 6 moles of NO₂ react and 13 moles of the compound are present, the amount that remains in excess is calculated as: 13 moles - 6 moles= 7 moles
The number of moles of excess reagent NO₂ that are present after the reaction has completed is 7 moles.
When we react a weak acid with a strong base of equal amounts and concentration, the component of the reaction that will have the greatest effect on the pH of the solution is:______.
a. the acid.
b. the base.
c. the conjugate acid.
d. the conjugate base.
Answer:
d. the conjugate base.
Explanation:
The general reaction of a weak acid, HA, with a strong base YOH, is:
HA + YOH → A⁻ + H₂O + Y⁻
Where A⁻ is the conjugate base of the weak acid and Y⁻ usually is a strong electrolyte.
That means after he complete reaction you don't have weak acid nor strong base, just conjugate base that will be in equilibrium with water, thus (Strong electrolyte doesn't change pH:
A⁻ + H₂O ⇄ HA + OH⁻
As the equilibrium is producing OH⁻, the pH of the solution is being affected for the conjugate base
Right option:
d. the conjugate base.Sighting along the C2-C3 bond of 2-methylbutane, the least stable conformation (Newman projection) has a total energy strain of ______kJ/mol
Answer:
21 KJ/mol
Explanation:
For this question, we have to start with the linear structure of 2-methylbutane. With the linear structure, we can start to propose all the Newman projections keep it in mind that the point of view is between carbons 2 and 3 (see figure 1).
Additionally, we have several energy values for each interaction present in the Newman structures:
-) Methyl-methyl gauche: 3.8 KJ/mol
-) Methyl-H eclipse: 6.0 KJ/mol
-) Methyl-methyl eclipse: 11.0 KJ/mol
-) H-H eclipse: 4.0 KJ/mol
Now, we can calculate the energy for each molecule.
Molecule A
In this molecule, we have 2 Methyl-methyl gauche interactions only, so:
(3.8x2) = 7.6 KJ/mol
Molecule B
In this molecule, we have a Methyl-methyl eclipse interaction a Methyl-H eclipse interaction and an H-H eclipse interaction, so:
(11)+(6)+(4) = 21 KJ/mol
Molecule C
In this molecule, we have 1 Methyl-methyl gauche interaction only, so:
3.8 KJ/mol
Molecule D
In this molecule, we have three Methyl-H eclipse interaction, so:
(6*3) = 18 KJ/mol
Molecule E
In this molecule, we have 1 Methyl-methyl gauche interaction only, so:
3.8 KJ/mol
Molecule F
In this molecule, we have a Methyl-methyl eclipse interaction a Methyl-H eclipse interaction and an H-H eclipse interaction, so:
(11)+(6)+(4) = 21 KJ/mol
The structures with higher energies would be less stable. In this case, structures B and F with an energy value of 21 KJ/mol (see figure 2).
I hope it helps!
