For each of the following changes at equilibrium, indicate whether the equilibrium shifts in the direction of products, reactants, or does not change: CaCO3(s)+heat⇌CaO(s)+CO2(g)
1) increasing the temperature
shifts equilibrium in the direction of the reactants
does not change
shifts equilibrium in the direction of the products
2) decreasing the volume of the container
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products
does not change
3) adding a catalyst
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products
does not change
4) adding more CaO(s)
does not change
shifts equilibrium in the direction of the reactants
shifts equilibrium in the direction of the products

Answers

Answer 1

Answer:

shifts equilibrium in the direction of the products

shifts equilibrium in the direction of the reactants

does not change

shifts equilibrium in the direction of the reactants

Explanation:

When a constraint such as a change in pressure, concentration or temperature is imposed on a reaction system in equilibrium, the equilibrium position will shift in such a way as to annul the constraint.

The reaction is endothermic as written. Hence, increase in temperature increases the rate of forward reaction thereby shifting the equilibrium position towards the products.

When the volume of a reaction is decreased, the equilibrium position shifts in the direction which produces the least total volume. In this case, decrease in volume shifts the equilibrium position towards the reactants.

A catalyst has no effect on the equilibrium position. However, a catalyst may cause equilibrium to be achieved faster or at a lower temperature.

When more CaO is added, the equilibrium position shifts towards the reactants side and more CaCO3 is produced.


Related Questions

Calculate the number of iron atoms contained in 434.52 g of iron: Question 7 options: 2.620 x 10 26 Fe atoms 5.769 x 10 24 Fe atoms 4.685 x 10 24 Fe atoms 3.223 x 10 25 Fe atoms 1.169 x 10 23 Fe atoms

Answers

Answer:

[tex]\boxed {\boxed {\sf 4.685 \times 10^{24} \ Fe \ atoms}}[/tex]

Explanation:

We are asked to convert grams of iron to atoms of iron.

1. Convert Grams to Moles

First, we convert grams to moles. We use the molar mass or the mass in 1 mole of a substance. This is found on the Periodic Table because the molar mass is equal to the atomic mass, but the units are grams per mole instead of atomic mass units. Look up iron's molar mass.

Fe:  55.84 g/mol

We convert using dimensional analysis, so we must set up a ratio using the molar mass.

[tex]\frac {55.84 \ g \ Fe}{ 1 \ mol \ Fe}[/tex]

We are converting 434.52 grams to moles, so we multiply by this value.

[tex]434.52 \ g \ Fe *\frac {55.84 \ g \ Fe}{ 1 \ mol \ Fe}[/tex]

Flip the ratio so the units of grams of iron cancel.

[tex]434.52 \ g \ Fe *\frac { 1 \ mol \ Fe}{55.84 \ g \ Fe}[/tex]

[tex]434.52 *\frac { 1 \ mol \ Fe}{55.84}[/tex]

[tex]\frac { 434.52}{55.84} \ mol \ Fe[/tex]

[tex]7.781518625 \ mol \ Fe[/tex]

2. Convert Moles to Atoms

Next, we convert moles to atoms. We use Avogadro's Number or 6.02 ×10²³. It is the number of particles (atoms, molecules, formula units, etc) in 1 mole of a substance. For this problem, the particles are atoms of iron. We set up another ratio using this number.

[tex]\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 \ mol \ Fe}[/tex]

Multiply by the number of moles we calculated.

[tex]7.781518625 \ mol \ Fe *\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 \ mol \ Fe}[/tex]

The units of moles of iron cancel.

[tex]7.781518625 *\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 }[/tex]

[tex]4.68447421 \times 10^{24} \ atoms \ Fe[/tex]

The correct answer choice is Choice 3: 4.685 × 10²⁴ atoms of iron.

A gas within a piston–cylinder assembly undergoes an isothermal process at 400 K during which the change in entropy is −0.3 kJ/K. Assuming the ideal gas model for the gas and negligible kinetic and potential energy effects, evaluate the work, in kJ.

Answers

Answer:

W = -120 KJ

Explanation:

Since the piston–cylinder assembly undergoes an isothermal process, then the temperature is constant.

Thus; T1 = T2 = 400K

change in entropy; ΔS = −0.3 kJ/K

Formula for change in entropy is written as;

ΔS = Q/T

Where Q is amount of heat transferred.

Thus;

Q = ΔS × T

Q = -0.3 × 400

Q = -120 KJ

From the first law of thermodynamics, we can find the workdone from;

Q = ΔU + W

Where;

ΔU is Change in the internal energy

W = Work done

Now, since it's an ideal gas model, the change in internal energy is expressed as;

ΔU = m•C_v•ΔT

Where;

m is mass

C_v is heat capacity at constant volume

ΔT is change in temperature

Now, since it's an isothermal process where temperature is constant, then;

ΔT = T2 - T1 = 0

Thus;

ΔU = m•C_v•ΔT = 0

ΔU = 0

From earlier;

Q = ΔU + W

Thus;

-120 = 0+ W

W = -120 KJ

3. Oxalic acid, C H20, is a toxic substance found in rhubarb leaves. When mixed with sufficient
quantities of a strong base, this weak diprotic acid loses two protons to form a polyatomic ion
called oxalate, C2022. Write a balanced equation that describes the reaction between oxalic acid
and sodium hydroxide.

Answers

Answer:

COOHCOOH + 2OH⁻ ⇄  C₂O₄²⁻ + 2H₂O

Explanation:

The reaction of oxalic acid with a strong base like sodium hydroxide is the following:

COOHCOOH + OH⁻ ⇄ COOHCOO⁻ + H₂O    (1)

In this first reaction, the oxalic acid loses one proton. In a second reaction with NaOH, the ion COOHCOO⁻ loses its second proton to form ion oxalate as follows:

COOHCOO⁻ + OH⁻ ⇄ C₂O₄²⁻ + H₂O      (2)  

The general reaction between oxalic acid and NaOH is (eq 1 + eq 2):

COOHCOOH + 2OH⁻ ⇄  C₂O₄²⁻ + 2H₂O              

I hope it helps you!  

help me in my hw,wt is physical change and chemical change Answer it asap plz don't spam​

Answers

Answer:

Sorry but i don't undertsnad the question.

Explanation:

Answer:

A physical change is a change to the physical—as opposed to chemical—properties of a substance. They are usually reversible. The physical properties of a substance include such characteristics as shape, color, texture, flexibility, density, and mass.

A chemical change happens when one chemical substance is transformed into one or more different substances, such as when iron becomes rust.

Do u want examples ?

Select the correct relationship among the concentrations of species present in a 1.0 M aqueous solution of the weak acid represented by HA. A. [H2O] > [HA] > [A-] > [H3O ] > [OH-] B. [H2O] > [A-] ~ [H3O ] > [HA] > [OH-] C. [HA] > [H2O] > [A-] > [H3O ] > [OH-] D. [H2O] > [HA] > [A-] ~ [H3O ] > [OH-] E. [HA] > [H2O] > [A-] ~ [H3O ] > [OH-]

Answers

Answer:

D

Explanation:

We have to bear in mind that the acid is a weak acid. A weak acid does not dissociate completely in solution. We will have more concentration of undissociated acid than A^- and H3O^+ and OH^- in the system at equilibrium.

Being a weak acid, there is maximum concentration of water molecules followed by that of undissiociated acid.

Hence, for this solution, the concentration of ions in solution follows the order;

[H2O] > [HA] > [A-] ~ [H3O ] > [OH-]

What is the balanced form of the following equation?
Br2 + S2O32- + H2O → Br1- + SO42- + H+

Answers

Answer:

5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺

Explanation:

We will balance the redox reaction through the ion-electron method.

Step 1: Identify both half-reactions

Reduction: Br₂ ⇒ Br⁻

Oxidation: S₂O₃²⁻ ⇒ SO₄²⁻

Step 2: Perform the mass balance, adding H⁺ and H₂O where appropriate

Br₂ ⇒ 2 Br⁻

5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺

Step 3: Perform the charge balance, adding electrons where appropriate

2 e⁻ + Br₂ ⇒ 2 Br⁻

5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻

Step 4: Make the number of electrons gained and lost equal

5 × (2 e⁻ + Br₂ ⇒ 2 Br⁻)

1 × (5 H₂O + S₂O₃²⁻ ⇒ 2 SO₄²⁻ + 10 H⁺ + 10 e⁻)

Step 5: Add both half-reactions

5 Br₂ + S₂O₃²⁻ + 5 H₂O ⇒ 10 Br⁻ + 2 SO₄²⁻ + 10 H⁺

What Volume of silver metal will weigh exactly 2500.0g. The density of silver

Answers

Answer:

cm3 = 2500.0 g / 10.5 g/cm3 = 238 cm3

An ice cube, measured at 260 Kelvin, is dropped into a cup of tea that is 350 Kelvin. The temperature of the tea is recorded every 30 seconds and shows the temperature dropping for 4 minutes. After 4 minutes the temperature stays steady at 300 Kelvin. What is this called?
A. Thermal equilibrium
B. Specific heat capacity
C. Latent heat
D. Temperature transfer

Answers

Answer:

Specific Heat Capacity

Please help fast
All four referenced Greek thinkers: Democritus, Aristotle, Archimedes, and Anaxagoras, observed Nature and argued for his theory of
the composition of matter and natural laws. Only one of them tested his hypothesis and proposed a natural laws based on reproducible
observations, controlled experiments, and mathematical reasoning. All others used logic and thought experiments, as philosophers do,
to support their theories. Who is the experimental scientist in this group?
O Democritus
O Aristotle
O Archimedes
O Anaxagoras

Answers

Answer:

Anaxagoras was perhaps the first literate person to attempt to explain physical phenomena rationally, basing his ideas upon careful observations and simple experiments. This is fundamental to modern science and is the sine qua non of environmental study.

PLEASE HELP!!
this is on USAtestprep
a)
b)
c)
d)

Answers

Answer:

The correct answer is option ( D )

Explanation:

Hope it helps you

have a good day dear :)

Nitrogen gas can be prepared by passing gaseous ammonia over solid copper (II) oxide at high temperatures. If 18.1 g of Nh3 is reacted with 90.4 g of CuO, which is the limiting reactant? How many grams of N2 will be formed? Explain how you solved for your answers.
Balanced Equation: 2NH3 + 3CuO → 3Cu + N2 + 3H2O

Answers

I first converted the given grams of the reactants into moles, and then divided the moles by the coefficients in front of each of the reactant. The result with the smallest value will be the limiting reactant, and the value of CuO was the smallest, so it's the limiting reactant.

After figuring out which reactant is the limiting one, I took their given grams and converted it into moles, the divided it by the ratio of N2 to CuO (it's in the equation) to obtain the moles of N2, and then multiply it with the molar mass of N2 to get its mass in grams.

What must happen to uranium before it can be used as a fuel source?

Answers

Answer: Uranium enrichment. Uranium is used to fuel nuclear reactors; however, uranium must be enriched before it can be used as fuel. Enriching uranium increases the amount of uranium-235 (U235) that can sustain the nuclear reaction needed to release energy and produce electricity at a nuclear power plant.

The radioactivity due to carbon-14 measured in a piece of a wood from an ancient site was found to produce 20 counts per minute from a given sample, whereas the same amount of carbon from a piece of living wood produced 160 counts per minute. The half-life of carbon-14, a beta emitter, is 5730 y. The age of the artifact is closest to

Answers

Answer:

The answer is "17200 years".

Explanation:

Given:

[tex]A = 20 \ \frac{counts}{minute}\\\\A_{o} = 160\ \frac{counts}{minute}[/tex]

Let the half-life of carbon-14, is beta emitter, is [tex]T = 5730\ years[/tex]

Constant decay [tex]\ w = \frac{0.693}{ T}[/tex]

[tex]= 1.209 \times 10^{-4} \ \frac{1}{year}\\[/tex]

The artifact age [tex]t= ?[/tex]

[tex]A = A_{o} e^{-wt} \\\\e^{-wt} = \frac{A}{A_{o}}\\\\-wt = \ln \frac{A}{A_{o}}\\\\= -2.079\\\\t = 1.7199 \times 10^{4} \ years\\\\\sim \ 17200\ years\\[/tex]

385 x 42.13 x 0.079 is (consider significant figures):

Answers

385 x 42.13 x 0.079 = 1281.38395

Is a 4p S 4s transition allowed in sodium? If so, what is its wavelength? If not, why not? b. Is a 3d S 4s transition allowed in sodium? If so, what is its wavelength? If not, why not? g

Answers

Answer:

a) 4p ⇒ 4s  transition is Allowed

b) 3d ⇒ 4s transition not allowed

Explanation:

a) 4p ⇒ 4s  transition

This transition is allowed because for a 4p state; l = 1 and for a 4s state I = 0

hence Δl = 1 - 0 = 1

Energy of 4p ( Ei ) = 3.75eV

Energy of 4s ( E2 ) = 3.19 eV

where : λ = 1240 eV nm / ( E₂ - E₁ )

                = 2214 nm ≈ 2.214 μm

b) 3d ⇒ 4s transition

This transition is not allowed  

a 3d state , l = 2 while for 4s state l = 0

hence Δl = 2 - 0 = 2

therefore the transition is not allowed

Arrange the following compounds in order of increasing reactivity (least reactive first.) to electrophilic aromatic substitution:.

Bromobenzene Nitrobenzene Benzene Phenol

a. Bromobenzene < Nitrobenzene < Benzene < Phenol
b. Nitrobenzene < Bromobenzene < Benzene < Phenol
c. Phenol < Benzene < Bromobenzene < Nitrobenzene
d. Nitrobenzene < Benzene < Bromobenzene < Phenol

Answers

Answer:

Nitrobenzene < Bromobenzene < Benzene < Phenol

Explanation:

Aromatic compounds undergo electrophilic aromatic substitution reaction in the presence of relevant electrophiles. Certain substituents tend to increase or decrease the tendency of an aromatic compound towards electrophilic aromatic substitution reaction.

Substituents that increase the electron density around the ring such as in phenol tends to make the ring more reactive towards electrophilic substitution. Halogens such as bromine has a -I inductive effect as well as a +M mesomeric effect.

However the -I(electron withdrawing effect) of the halogens supersedes the +M electron donation due to mesomeric effect.

Putting all these together, the order of increasing reactivity of the compounds towards electrophilic aromatic substitution is;

Nitrobenzene < Bromobenzene < Benzene < Phenol

Sodium ethoxides are made by direct reaction of:
a. Sodium hydroxide and dry ethanol
b. Sodium metal and 70% ethanol
c. Sodium hydroxide and 70% ethanol
d. Sodium metal and dry ethanol​

Answers

Answer:c

Explanation:

How are all planets in the solar system similar?

A. They have a gas atmosphere.
B. They have a water atmosphere.
C. They have a gas-surface composition.
D. They have a rock surface composition.
THIS IS FOR SCIENCE!!!!!!
PLEASE HELP!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!

Answers

Answer:

They have a rock surface composition.

Explanation:

I hope this will help you

9. Consider a magnesium atom with charge +2. How many overall electrons are on this particle?
Hint: Magnesium's atomic number is 12.
10
12
14

Answers

14 try that one bro and let me know
10 when it’s the + sign you subtract and when it’s the - sign you add

Suppose that you add 24.3 g of an unknown molecular compound to 0.250 kg of benzene, which has a K f of 5.12 oC/m. With the added solute, you find that there is a freezing point depression of 3.14 oC compared to pure benzene. What is the molar mass (in g/mol) of the unknown compound

Answers

Solution :

We know that :

[tex]$\Delta T_f = k_f.m$[/tex]  and   [tex]$m=\frac{w_2}{m_2 \times w_1}$[/tex]

Then, [tex]$\Delta T_f = k_f.\frac{w_2}{m_2.w_1}$[/tex]   ..................(1)

Where,

[tex]w_1[/tex] = amount of solvent (in kg)

[tex]w_2[/tex] = amount of solute (in kg)

[tex]m_2[/tex] = molar mass of solute (g/mole)

[tex]m[/tex] = molality of solution (mole/kg)

Given :

[tex]\Delta T_f[/tex] = [tex]3.14\ ^\circ C[/tex],   [tex]k_f= 5.12\ ^\circ C/m[/tex]

                              [tex]=5.12 \ ^\circ C/mole/kg[/tex]

                              [tex]=5.12 \ ^\circ C \ kg/mole[/tex]

[tex]w_1[/tex] = 0.250 kg,  [tex]w_2[/tex] = 24.3 g

Then putting this values in the equation is (1),

[tex]$3.14 = \frac{5.12 \times 24.3}{m_2 \times 0.250}$[/tex]

[tex]$m_2 = \frac{5.12 \times 24.3}{3.14 \times 0.250}$[/tex]

[tex]m_2= 158.49[/tex]  g/mole

So, the molar mass of the unknown compound is 158.49 g/mole.

importance of hematology​

Answers

Answer:

Haematology is the specialty important for the diagnosis and management of a wide range of benign and malignant disorders of the red and white blood cells, platelets and the coagulation system in adults and children.

100 mL of 0.2 mol/L sodium carbonate solution and 200 mL of 0.1 mol/L calcium nitrate solution are mixed together. Calculate the mass of calcium carbonate that would precipitate and the concentration of the sodium nitrate solution that will be produced.

Answers

Answer:

Explanation:

Na2CO3+Ca(NO3)2=CaCO3+2NaNO3

nNa2CO3=0.02

nCa(NO3)2=0.02

mCaCO3=0.02*100=2 gram

nNaNo3=0.04

Cm=2/15

From the calculation, the mass of the product is 2 g.

What is a reaction?

A chemical reaction occurs when two more substances are mixed together. In this case, the reaction is shown by; Ca(NO3)2 + Na2CO3 ----> CaCO3(s) + 2NaNO3.

Number of moles of Na2CO3 = 100/1000 L *  0.2 mol/L = 0.02 moles

Number of moles of  Ca(NO3)2 = 200/1000 L *  0.1 mol/L = 0.02 moles

Since the reaction is equimolar, amount of the product = 0.02 moles * 100 g/mol = 2 g

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Based on the standard EMF series and your knowledge of half-reactions, determine the cell potential and spontanei ty of a cell that consists of a pure cobalt electrode in a solution of Co^2+ ions; the other half is a lead electrode immersed in a Pb^2+ solution.
Pb +2e- Pb Sn +2e Sn Ni 2e Ni Co 2e -0.126 -0.136 -0.250 -0.277 Co
a. +0.403, spontaneous
b. -0.403, nonspontaneous
c. +0.151, spontaneous
d. -0.151, nonspontaneous

Answers

Answer:

+0.151, spontaneous

Explanation:

Given that;

Co^2+(aq) + 2e ---->Co(s) -0.28 V

Pb^2+(aq) + 2e ---->Pb(s). -0.13 V

Hence Co is the anode and Pb is the cathode

E°cell = E°cathode - E°anode

So;

E°cell = -0.13 V - (-0.28 V)

E°cell = 0.15 V

The cell reaction is spontaneous since E°cell is positive.

convert 100kcals to kilojoules​

Answers

Answer:

Explanation:

418.4kj is the correct answer

It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of by-product formed. What is the by-product

Answers

Answer:

Biphenyl

Explanation:

The reaction of bromo benzene with magnesium-ether solution yields a Grignard reagent.

The byproduct of this reaction is biphenyl. It is formed when two unreacted bromobenzene molecules are coupled together.

Hence, It is advised that the bromobenzene solution be added slowly to the magnesium-ether solution so that it isn't present in a high concentration, thus reducing the amount of biphenyl by-product formed.

Write a balanced chemical equation for the reaction that occurs
when:
(a) titanium metal reacts with O21g2;
(b) silver(I) oxide decomposes into silver metal and oxygen gas when heated;
(c) propanol, C3H7OH1l2 burns in air;
(d) methyl tert-butyl ether, C5H12O1l2, burns in air.

Answers

Answer:

Explanation:

A balanced chemical equation refers to the reaction taking place whereby the number of atoms associated in the reactants side is equivalent to the number of atoms on the products side.

From the given information, the balanced equations are as follows:

[tex]\mathbf{(a) \ \ \ Ti(s) + O_{2(g)} \to TiO_{2(s)}}[/tex]

[tex]\mathbf{(b) \ \ \ 2Ag_{2}O \to 4Ag_{(s)} + O_{2(g)}}[/tex]

[tex]\mathbf{(c) \ \ \ 2C_3H_7OH + 9O_2 \to 6CO_2+8H_2O}[/tex]

[tex]\mathbf{(d) \ \ \ 2C_5 H_{12}O \to 10 CO_2 + 12 H_2O}[/tex]

HELP ASAP 15 POINTS

Why was Dalton's theory of the atom incorrect?
A. Dalton theorized that atoms were indivisible but they are actually made of smaller parts.
B. Dalton theorized that had negative charges spread throughout them but they are actually in electron shells.
C. Dalton' theory was correct.
D. Dalton theorized that atoms were too small to see but they are not.

Answers

Answer:

Answer is A.

Explanation:

The indivisibility of an atom was proved wrong: an atom can be further subdivided into protons, neutrons and electrons. According to Dalton, the atoms of same element are similar in all respects. However, atoms of some elements vary in their masses and densities. These atoms of different masses are called isotopes. :)

A solution is made by dissolving 0.565 g of potassium nitrate in enough water to make up 250. mL of solution. What is the molarity of this solution?

Please explain and show work.

Answers

Molar mass of Potassium Nitrate:-

[tex]\\ \large\sf\longmapsto KNO_3[/tex]

[tex]\\ \large\sf\longmapsto 39u+14u+3(16u)[/tex]

[tex]\\ \large\sf\longmapsto 53u+48u[/tex]

[tex]\\ \large\sf\longmapsto 101u[/tex]

[tex]\\ \large\sf\longmapsto 101g/mol[/tex]

Now

[tex]\boxed{\sf No\:of\:moles=\dfrac{Given\:mass}{Molar\:mass}}[/tex]

[tex]\\ \large\sf\longmapsto No\:of\:moles=\dfrac{0.565}{101}[/tex]

[tex]\\ \large\sf\longmapsto No\:of\:moles=0.005mol[/tex]

We know

[tex]\boxed{\sf Molarity=\dfrac{Moles\:of\:solute}{Vol\:of\:Solution\:in\:L}}[/tex]

[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{\dfrac{250}{1000}L}[/tex]

[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{0.250}[/tex]

[tex]\\ \large\sf\longmapsto Molarity=0.02M[/tex]

[tex] \: \: \: \: \: \: \: \: \: [/tex]

Calculate the numerical value of the equilibrium constant, Kc, for the reaction below if the equilibrium concentrations for CO, H2 , CH4 and H2O are 0.989 M, 0.993 M, 1.078 M and 0.878 M, respectively. (calculate your answer to three sig figs)
CO(g) + 3 H2(g) ⇌ CH4(g) + H2O(g)

Answers

Kc = [CH4]×[H2O] / [CO]×[H2]^3

Kc = 1.078×0.878 / (0.989×0.933^3)

Kc = 0.977

The numerical value of the equilibrium constant, Kc, for the given reaction is found to be 0.977.

What is Equilibrium constant?

The Equilibrium constant may be defined as the numerical value that significantly indicated the correlation between the amounts of products and reactants present at equilibrium in a reversible chemical reaction at a definite temperature.

According to the question, the reaction is as follows:

[tex]CO +3H_2[/tex] ↔ [tex]CH_4+ H_2O[/tex].

The equilibrium concentrations are 0.989 M, 0.993 M, 1.078 M and 0.878 M, respectively.

Now, the equilibrium constant is calculated by the following formula:

Kc =  [CH4]×[H2O] / [CO]×[tex][H_2]^3[/tex]

             =  1.078×0.878 / (0.989×0.93[tex]3^3[/tex]).

             = 0.9464/(0.989 × 0.8121)

             =  0.977.

Therefore, the numerical value of the equilibrium constant, Kc, for the given reaction is found to be 0.977.

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15.27
The following equilibria were attained at 823 K:
COO(s) + H2() Co(s) + H2O(g) K = 67

COO(s) + CO(8) = Co(s) + CO2(8) K = 490

Based on these equilibria, calculate the equilibrium con-
stant for
H2(g) + CO2(g) = CO(g) + H2O(g) at 823 K.

Answers

The equilibrium constant for the reaction is K = 0.137

We obtain the equilibrium constant considering the following equilibria and their constants:

COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

COO(s) + CO(g) → Co(s) + CO₂(g)   K₂ = 490

We write the first reaction in the forward direction because we need H₂(g) in the reactants side:

(1)     COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

Then, we write the second reaction in the reverse direction because we need CO₂(g) in the reactants side. Thus, the equilibrium constant for the reaction in the reverse direction is the reciprocal of the constant for the reaction in the forward direction (K₂):

(2)   Co(s) + CO₂(g) → COO(s) + CO(g)   K₂ = 1/490

From the addition of (1) and (2), we obtain:

COO(s) + H₂(g) → Co(s) + H₂O(g)    K₁ = 67

+

Co(s) + CO₂(g) → COO(s) + CO(g)   K₂ = 1/490

-------------------------------------------------

H₂(g) +  CO₂(g) → CO(g) + H₂O(g)

Notice that Co(s) and COO(s) are removed that appear in the same amount at both sides of the chemical equation.

Now, the equilibrium constant K for the reaction that is the sum of other two reactions is calculated as the product of the equilibrium constants, as follows:

K = K₁ x K₂ = 67 x 1/490 = 67/490 = 0.137

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