Answer: The balanced equation for the complete oxidation reaction of ethanol is [tex]C_2H_5OH+3O_2\rightarrow 2CO_2+3H_2O[/tex]
Explanation:
Combustion is the chemical process where an organic molecule reacts with oxygen gas present in the air to produce carbon dioxide and water molecules.
It is also known as an oxidation reaction because oxygen is getting added.
The chemical equation for the oxidation of ethanol follows:
[tex]C_2H_5OH+3O_2\rightarrow 2CO_2+3H_2O[/tex]
By stoichiometry of the reaction:
1 mole of ethanol reacts with 3 moles of oxygen gas to produce 2 moles of carbon dioxide gas and 3 moles of water molecules.
For the reaction of oxygen and nitrogen to form nitric oxide, consider the following thermodynamic data :
ΔH∘rxn 180.5kJ/mol
ΔS∘rxn 24.80J/(mol⋅K)
Required:
a. Calculate the temperature in kelvins above which this reaction is spontaneous
b. Calculate the equilibrium constant for the following reaction at room temperature, 25°C
Answer:
a. 7278 K
b. Kc = 4.542 × 10⁻³¹
Explanation:
a.
The reaction is spontaneous when ΔG° < 0. We can calculate ΔG° using the following expression.
ΔG° = ΔH° - T × ΔS°
Then, the reaction will be spontaneous when,
ΔH° - T × ΔS° < 0
T > ΔH°/ΔS
T > (180.5 × 10³ J/mol)/(24.80J/mol⋅K)
T > 7278 K
b.
First, we will calculate ΔG° at 25 °C (298 K)
ΔG° = ΔH° - T × ΔS°
ΔG° = (180.5 × 10³ J/mol) - 298 K × (24.80J/mol⋅K) = 1.731 × 10⁵ J/mol
Then, we will calculate the equilibrium constant (Kc) using the following expression.
ΔG° = - R × T × ln Kc
-ΔG°/R × T = ln Kc
-(1.731 × 10⁵ J/mol)/(8.314 J/mol.K) × 298 K = ln Kc
Kc = 4.542 × 10⁻³¹
What is the oxidation state of nitrogen in N ?
Answer:
+5
Explanation:
A compound, C20H28O, produces a 1H NMR spectrum with 11 distinct signals. The steps made by the integral trace measure 52, 17, 17, 26, 17, 25, 26, 9, 9, 35, and 8 mm. Complete the following table.
Integral # Products
52 mm
17 mm
17 mm
26 mm
17 mm
25 mm
26 mm
35 mm
8 mm
Solution :
The smallest integer value represents the smaller number of protons.
In this case, in the given values, the smallest numbers are 8 mm and 9 mm, so both contains 1H each. Then next highest value is 17 mm, which contains 1H more. Thus 17 mm contains 2H each. Then the next highest is 25 mm and 26 mm which contains 3M each and so on.
Thus the tables is :
Integral Protons
52 mm [tex]6[/tex]
17 mm [tex]2[/tex]
17 mm 2
26 mm 3
17 mm 2
25 mm 3
26 mm 3
9 mm 1
9 mm 1
35 mm 4
8 mm 1
The cation of the salt is sodium ion, and the anion is aurothiosulfate ion. Based on the chemical formula of the salt, what must the charge be of the aurothiosulfate ion [Au(S2O3)2 n- ]
Answer:
3-
Explanation:
Sodium aurothiosulfate is a salt with the formula Na₃Au(S₂O₃)₂. The cation of the salt is sodium ion, and the anion is aurothiosulfate ion. We can determine the charge of the aurothiosulfate ion, considering that the sum of the positive and negative charges must be equal to the charge of the compound, which is zero.
3 × Na⁺ + 1 × Au(S₂O₃)₂ⁿ⁻ = 0
3 × +1 + 1 × Au(S₂O₃)₂ⁿ⁻ = 0
Au(S₂O₃)₂ⁿ⁻ = 3-
what are the angles a and b in the actual molecule of which this is a lewis structure note for advanced students give the ideal angles and don t worry about small differences from the ideal that might be caused by the fact that different electron groups may have slightly different sizes
Answer:
The answer is "120 C and 109.5 C".
Explanation:
The carbon atom is hybridized by sp2. This angle of connection thus is 120 degrees. Alkene, specifically both carbons which are in the C=C, are an instance of carbon with sp2 hybridized atom's nucleus. Those three hybridized orbits were linked to certain other atoms forming sigma connections. Its remaining 2p orbital makes a pi link with 2p orbit by the side-overlap of all the other carbon. O is hybridized inside the [-OH] Group. The optimal bond angle therefore is [tex]109.5^{\circ}[/tex].
[tex]a= 120 \ C\\\\b= 109.5 \ C[/tex]
Please help me order these bonds urgent
Answer:
From least polar covalent to most polar covalent;
S-I< Br-Cl < N-H< Te-O
From most ionic to least ionic
Cs-F> Sr-Cl> Li- N> Al-O
Explanation:
Electro negativity refers to the ability of an atom in a bond to attract the shared electrons of the bond towards itself.
Electro negativity difference between two atoms is a key player in the nature of bond that exists between any two atoms. A large difference in electron negativity leads to an ionic bond while an intermediate difference in electro negativity leads to a polar covalent bond.
Based on electro negativity differences, the bonds in the answer have been arranged in order of increasing polar covalent nature or decreasing ionic nature.
Categorize the following reaction as an acid-base neutralization, precipitation, combination, decomposition, combustion, displacement, or disproportionation reaction.
Ba(C2H3O2)2(aq) + Na2CO3(aq) → BaCO3(s) + 2 NaC2H3O2(aq)
Answer:
Precipitation
Explanation:
Let's consider the balanced chemical equation between barium acetate and sodium carbonate to form barium carbonate and sodium acetate.
Ba(C₂H₃O₂)₂(aq) + Na₂CO₃(aq) → BaCO₃(s) + 2 NaC₂H₃O₂(aq)
Both products and reactants are salts. But, among the products, barium carbonate is solid. This allows us to classify it as a precipitation reaction.
A covalent bond is formed by the following process
Answer:
Covalent bonding occurs when pairs of electrons are shared by atoms.
Explanation:
Atoms will covalently bond with other atoms in order to gain more stability, which is gained by forming a full electron shell. By sharing their outer most (valence) electrons, atoms can fill up their outer electron shell and gain stability.
how does iron I differ from iron II
Answer:
Metals tend to form positive oxidation states. Here, Iron (I) has an oxidation state of +1 while Iron (II) has an oxidation state of +2. Similarly, Lead (I) has an oxidation state of +1 while Lead(II) has an oxidation state of +2. A change in oxidation state can rather cause significant changes in the compound.
Water put into a freezer compartment in the same refrigerator goes into a state of less molecular disorder when it freezes. Is this an exception to the entropy principle
Answer:
No it is not an exception to this principle
Explanation:
Work was carried out by this compressor to reduce the entropy of ice. What this means is that the ice gave out heat which is as a result of the work that the compressor was putting in. there are violations of this principle
the entropy principle has that the entropy of the universe is always going to be more than 0 (system + surrounding). in this question, the that of the system is negative while that of the surrounding is positive. As the refrigerator was cooling the water, the air outside was getting heated. Outside this refrigerator, the gain in entropy is more than the entropy that was lost in the water.
the entropy of the universe once again is more than 0.
When CH3NO2 burns in excess oxygen, it forms carbon dioxide, nitrogen dioxide and water. How many moles of oxygen are required to burn 17.10 mole(s) of CH3NO2
Explanation:
The given reaction is the combustion of CH3NO2.
The balanced chemical equation of the reaction is:
[tex]4CH_3NO_2+ 7O_2 ->4 CO_2+4NO_2+6H_2O[/tex]
So, from the balanced chemical equation, it is clear that:
4 moles of CH3NO2 --- 7 moles of oxygen gas is required.
then,
for 17.10 moles of CH3NO2 the following number of moles of oxygen is required.
[tex]The number of moles of O_2 required=17.10 mol. x \frac{7 mol}{4 mol} \\=29.925 mol[/tex]
Answer is :
29.9 mol of oxygen gas is required.
How many molecules are in
6.0 moles of methane (CH4)?
Answer:
[tex]{ \tt{1 \: mole = 6.02 \times {10}^{23} \: molecules }} \\ { \tt{6.0 \: moles = (6 \times 6.02 \times {10}^{23}) \: molecules }} \\ = { \bf{3.612 \times {10}^{24} \: molecules}}[/tex]
What is the fourth quantum number of the 3p electron in aluminum,
1s^2 2s^2 2p^6 3s^2 3p^1?
A. ms = -1
B. ms = +1/2
C. ms=0
D. ms = +1
Explanation:
here's the answer to your question
The quantum numbers are defined as the set of four numbers with the help of which we can get complete information about the electrons in an atom. The fourth quantum number is the spin quantum number. Here ms for 3p electron in 'Al' is ms = + 1/2. The correct option is B.
The quantum number which describes the spin orientation of the electron is defined as the spin quantum number. Since the electron can spin only in two ways, clockwise and anti-clockwise, the spin quantum number can have either the value +1/2 or -1/2 depending upon the direction of spin.
Thus for 3p electron in 'Al' ,ms is option B.
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Explain how the existence of isotopes relates to the number of neutrons within the nuclei of an element.
Answer:
because of it less attraction and its neutral position
Answer:
The existence of isotopes relates to the number of neutrons within the nuclei of an element because isotopes contain the same amount of protons (based on what element they are) but different number of neutrons in their nuclei. Because they have a different amount of neutrons, than the original element
,they also have a different atomic mass.
Explanation:
hope it helps!
How many moles in 3.30g of iron
The answer below is correct but to give you the process, here it is:
Molar mass of iron, Fe = 55.85 g/mol
3.30g/(55.85 g/mol) = 0.0591 mol
Enzyme catalyzing breakdown of atp to adp
Answer:
ATP hydrolase
Explanation:
Enzymes are biological catalysts which perform diverse functions in the body. Enzymes are specific in their mode of action because an enzyme fits into its substrate as a key fits into a lock.
The particular enzyme that catalyzes the breakdown of ATP to ADP is ATP hydrolase. The phosphate released by the action of this enzyme is used in the phosphorylation of other compounds thereby making them more reactive.
Solid aluminum (AI) and oxygen (0) gas react to form solid aluminum oxide (AIO). Suppose you have 7.0 mol of Al and 13.0 mol of o, in a reactor. Suppose as much as possible of the Al reacts. How much will be left? Round your answer to the nearest 0.1 mol mol 0.
Answer:
[tex]n_{O_2}^{leftover}=7.7mol[/tex]
Explanation:
Hello there!
In this case, according to the given information, it turns out firstly necessary for us to set up the corresponding chemical equation:
[tex]4Al+3O_2\rightarrow 2Al_2O_3[/tex]
In such a way, we calculate the moles of aluminum consumed by 13.0 moles of oxygen in the reaction, by applying the 4:3 mole ratio between them:
[tex]n_{Al}=13.0molO_2*\frac{4molAl}{3molO_2} =17.3molAl[/tex]
This means that Al is actually the limiting reactant and oxygen is in excess, for that reason we calculate the moles of oxygen consumed by 7.0 moles of aluminum:
[tex]n_{O_2}=7.0molAl*\frac{3molO_2}{4molAl} =5.3molO_2[/tex]
Thus, the leftover of oxygen is:
[tex]n_{O_2}^{leftover}=13.0mol-5.3mol\\\\n_{O_2}^{leftover}=7.7mol[/tex]
Whereas all the aluminum is assumed to be consumed.
Regards!
Predict the Normality of H2SO4 if 75 ml of 96.6 % pure H2SO4 added to 425 ml water. The density of H2SO4 is 1.83 g/cm3?
Explanation:
Normality is one of the concentration terms.
It is expressed as:
[tex]N=\frac{mass of the substance}{equivalent mass}* \frac{1}{volume of solution in L.}[/tex]
The volume of the solution is 425 mL.
Mass of sulfuric acid given is:
[tex]mass=volume * purity* density\\ = 75 mL * 0.966 * 1.83 g/mL\\\\=132.5 grams\\[/tex]
The equivalent mass of sulfuric acid is 49.0g/equivalents
Hence, the normality of the given solution is:
[tex]N=\frac{132.5g}{49.0g/equi.} *\frac{1000}{425mL} \\Normality=6.36N[/tex]
Answer is: 6.36N.
the -OH group cannot exhibit inductive effect? true/false, and reason for ur choice
Answer:
false
Explanation:
The inductive effects are know as the ability of the atom or a group to create polarization and electronic density long the covalent bond and it needs a higher density. The -OH group cannot exhibit the indictive effects as it becomes --O.Determine the molecular formula of a compound if it is composed of 40.92% carbon, 4.58% hydrogen, and 54.50% oxygen. The molar mass is 176.12 g/mol.
A) C3H8O3.
B) CH2O.
C) C2H3O2.
D) C3H4O3.
Answer:
No correct answer listed. See explanation for defense.
Explanation:
Given
C: 40.92% => 40.92g/100wt => (40.92/12)moles C = 3.41 moles O
H: 4.58% => 4.58g/100wt => (4.58/1)moles H = 4.58 moles H
O: 54.50% => 54.5g/100wt => (54.5/16)moles O = 3.41 moles O
Empirical ratio => C : H: O => (3.41/3.41) : (4.58/3.41) : (3.41/3.41) => 1 : 1.34 : 1
=> C : H : O => 3(1 : 1.34 : 1) => 3 : 4 : 3 => Empirical Formula C₃H₄O₃
Molecular Weight = Empirical Formula Wt x N
176.12 = 88 x N
N = whole number multiple of empirical formula = 176.12/88 = 2
∴ Molecular Formula => (C₃H₄O₃)₂ => C₆H₈O₆
Note => Only ionic compounds (salts) have subscripts reduced to lowest whole number ratios. Molecular compounds as C₆H₈O₆ are not reduced to lowest whole number ratios. Therefore, there is no correct answer in the answer choice list for the 'Molecular Formula'. Doc :-)
Hazmat products warnings or labels allowed in fc
Answer:
The Hazmat products warnings or labels allowed in fc include:
1. Fully Regulated Aerosol Placard
2. Fully Regulated Flammable Solid Placard
3. Fully Regulated Flammable
4. Lithium-Ion/Metal Battery label
Explanation:
Hazmat products (including explosives, flammable liquids and solids, and gases, etc.) are classified as dangerous substances and materials that pose a risk to people during their storage, handling, or transportation. The requirement for this Hazmat classification is to show that the identified products require diligence, carefulness, and alertness in handling, transporting, and storing them. The reason for this is that mishaps can occur. Some of them can also cause fire outbreaks.
4) In water, Vanillin, C8H8O3, has a solubility of 0.070 moles of vanillin per liter of solution at 25C. What will be produced if 5.00 g of vanillin are added to 1 L of water at 25 C
Answer:
An unsaturated solution.
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to firstly realize we need to calculate the grams of vanillin in 0.070 moles by using its molar mass of 152.15 g/mol:
[tex]m=0.070mol*\frac{152.15 g}{1mol} =10.65g[/tex]
Thus, since the solubility is 10.65 g per 1 L of solution, we can notice 5.00 g will complete dissolve and produce an unsaturated solution.
Best regards!
A researcher is attempting to produce ethanol using an enzyme catalyzed batch reactor. The ethanol is produced from corn starch by first-order kinetics with a rate constant of 0.05 hr-1. Assuming the concentration of ethanol initially is 1 mg/L, what will be the concentration of ethanol (in mg/L) after 24 hours
Answer:
The correct solution is "3.32 gm/L".
Explanation:
Given:
Rate constant,
[tex]K = 0.05 \ hr^{-1}[/tex]
Time,
[tex]t = 24 \ hours[/tex]
Concentration of ethanol,
[tex]C_o= 1 \ mg/L[/tex]
Now,
The concentration of ethanol after 24 hours will be:
⇒ [tex]C_o=C\times e^{-K\times t}[/tex]
By putting the values, we get
[tex]1=C\times e^{-0.05\times 24}[/tex]
[tex]1=C\times 0.30119[/tex]
[tex]C= 3.32 \ gm/L[/tex]
A rigid, sealed container that can hold 26 L of gas is filled to a pressure of
5.97 atm at 374 °C. The pressure suddenly decreases to 3.64 atm. What is
the new temperature inside the container, in units of °C?
Answer:
121 °C
Explanation:
From the question given above, the following data were obtained:
Initial pressure (P₁) = 5.97 atm
Initial temperature (T₁) = 374 °C
Final pressure (P₂) = 3.64 atm
Final temperature (T₂) =?
NOTE: Volume = constant
Next, we shall convert 374 °C to Kelvin temperature. This can be obtained as follow:
T(K) = T(°C) + 273
Initial temperature (T₁) = 374 °C
Initial temperature (T₁) = 374 °C + 273
Initial temperature (T₁) = 647 K
Next, we shall determine the final temperature. This can be obtained as follow:
Initial pressure (P₁) = 5.97 atm
Initial temperature (T₁) = 647 K
Final pressure (P₂) = 3.64 atm
Final temperature (T₂) =?
P₁ / T₁ = P₂ / T₂
5.97 / 647 = 3.64 / T₂
Cross multiply
5.97 × T₂ = 647 × 3.64
5.97 × T₂ = 2355.08
Divide both side by 5.97
T₂ = 2355.08 / 5.97
T₂ = 394 K
Finally, we shall convert 394 K to celsius temperature. This can be obtained as follow:
T(°C) = T(K) – 273
Final temperature (T₂) = 394 K
Final temperature (T₂) = 394 – 273
Final temperature (T₂) = 121 °C
Thus, the new temperature is 121 °C
A chemical reaction in a bomb calorimeter evolves 3.86 kJ of energy in the form of heat. If the temperature of the bomb calorimeter increases by 4.17 K, what is the heat capacity of the calorimeter?
Answer:
925.66 J/K
Explanation:
Applying,
Q = CΔt............. Equation 1
Where Q = amount of heat, C = heat capacity of the calorimeter, Δt = rise in temperature.
make C the subject of the equation
C = Q/Δt.............. Equation 2
From the question,
Given: Q = 3.86 kJ = 3860 J, Δt = 4.17K
Substitute into equation 2
C = 3860/4.17
C = 925.66 J/K
Precipitation of an ionic compound will occur upon mixing of desired reagents if the initial ion product is:_______
A) greater than the Ksp
B) equal to the pksp
C) equal to the Ksp
D) less than the Ksp
Answer:
A) greater than the Ksp
Explanation:
Given a solid ionic compound AB, it dissociates in water into its ions, as follows:
AB(s) → A⁺(aq) + B⁻(aq)
At equilibrium, the product of the concentrations of the ions is constant, and it is called Ksp:
AB(s) ⇄ A⁺(aq) + B⁻(aq)
Ksp = [A⁺][B⁻] ⇒ (concentrations at equilibrium)
Upon mixing the reagents for the formation of AB, the compound will precipitate if the initial ion product (Q) is greater than the Ksp. If Q is equal to Ksp, the ions are at equilibrium with the solid compound AB, and if is it less than the Ksp, the ions are soluble and no solid AB is formed yet.
Q = [A⁺][B⁻] ⇒ (initial concentrations)
Q = Ksp ⇒ saturated solution (at equilibrium)
Q< Ksp ⇒ unsaturated solution (ions are soluble)
Q> Ksp ⇒ precipitation of solid compound.
Therefore, the correct option is A) greater than the Ksp
Consider the reaction: CaCO3(s)CaO(s) CO2(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions.
Answer:
the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions is 253.748 J/K
Explanation:
Given the data in the question;
CaCO₃(s) → CaO(s) + CO₂(g)
1.58 moles 1.58 moles 1.58 moles
Since 1 mole of CaCO₃ gives 1 mole of CaO and 1 mole of CO₂
Thus, 1.58 mole of CaCO₃ gives 1.58 moles of CaO and 1.58 moles of CO₂.
Now,
At 298 K, standard entropy values are;
ΔS° ( CaCO₃ ) = 92.9 J/mol.K
ΔS° ( CaO ) = 39.8 J/mol.K
ΔS° ( CO₂ ) = 213.7 J/mol.K
So,
ΔS°[tex]_{system[/tex] = ∑ΔS°( product ) - ∑ΔS°( reactant )
ΔS°[tex]_{system[/tex] = [ ΔS°(CaO) + ΔS°( CO₂ ) ] - ΔS°( CaCO₃ )
we substitute
ΔS°[tex]_{system[/tex] = [ 39.8 J/mol.K + 213.7 J/mol.K ] - 92.9 J/mol.K
ΔS°[tex]_{system[/tex] = 160.6 J/mol.K
i.e, for 1 mol CaCO₃, ΔS°[tex]_{system[/tex] = 160.6 J/mol.K
Now, for 1.58 mol CaCO₃,
ΔS°[tex]_{system[/tex] = 1.58 mol × 160.6 J/mol.K
ΔS°[tex]_{system[/tex] = 253.748 J/K
Therefore, the entropy change for the system when 1.58 moles of CaCO3(s) react at standard conditions is 253.748 J/K
Write the separation scheme for the isolation of triphenylmethanol from the reaction mixture once the reaction is complete. The separation begins after the addition of HCl and water to the reaction and includes the column chromatography procedure to further purify crude triphenylmethanol isolated in the day 1 procedure.
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Suppose we have two rock samples, A and B. Rock A was subject to both physical and chemical weathering while rock B was subject to chemical weathering only. Which rock would experience more chemical weathering? Why? (2pts) (Hint: consider the effect of surface area on the rate of chemical weathering)
Answer:
Rock A will have far more chemical weathering than Rock B due to the rise in area effect
Explanation:
Rock A undergoes both Physical and Chemical weathering. So, thanks to physical weathering there'll appear cracks within the rock, which can, in turn, increase the area of rock on which weathering is occurring. So, Chemical weathering will happen much faster now as there's a rise in the area. within the case of Rock B, there's only chemical weathering therefore the increase in the area won't be that very much like compared to Rock A.
In a first order reaction 40% of reactant gets converted into product in 30 minutes. What time would it require to convert 75% into product?
In a first order reaction 40% of reactant gets converted into product in 30 minutes. The time would it require to convert 75% into product is 81.57 minutes.
What is first order reaction?First order reaction is defined as a chemical reaction in which the concentration of just one ingredient directly affects the pace of the reaction. If the first-order reactant concentration is doubled in these reactions, the reaction rate will likewise double. Chemical reactions classified as first order kinetics have rates of reaction that depend on the molar concentration of one component.
First order reaction = 2.303 / t log a / (a-x)
k = 2.303 / 30 log 100 (100 - 40)
k = 0.0767 log 1.66
k = 0.017 min⁻¹
The time required to convert 75 % product
t = 2.303 / 0.017 log 100 (100 - 75)
t = 135.5 log 4
t = 135.5 x 0.602
t = 81.57 minutes
Thus, in a first order reaction 40% of reactant gets converted into product in 30 minutes. The time would it require to convert 75% into product is 81.57 minutes.
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