Consider the following reaction:

CO(g)+2H2(g)⇌CH3OH(g)

A reaction mixture in a 5.15-L flask at a certain temperature initially contains 26.6 g CO and 2.36 g H2. At equilibrium, the flask contains 8.63 g CH3OH.

Part A
Calculate the equilibrium constant (Kc) for the reaction at this temperature.

Answer:

density of second liquid = 650 kg/m³

Explanation:

Given that:

The volume of the plastic block submerged inside the water  = 0.5 V

The force on the plastic block  = [tex]\rho_1V_1g[/tex]

[tex]= 0.5p_1 V_g[/tex]

when the block is floating, the weight supporting the force (buoyancy force) is:

W [tex]= 0.5p_1 V_g[/tex]

[tex]\rho Vg = 0.5p_1 V_g[/tex]

[tex]\rho = 0.5 \rho _1[/tex]

where;

water density [tex]\rho _1[/tex] = 1000

[tex]\rho = 0.5 (1000)[/tex]

[tex]\rho = 500 kg/m^3[/tex]

In the second liquid, the volume of plastic block in the water = (100-23)%

= 77% = 0.7 V

The force on the plastic block is:

[tex]= 0.77p_2 V_g[/tex]

when the block is floating, the weight supporting the force (buoyancy force) is:

[tex]W = 0.77p_2 V_g[/tex]

[tex]\rho Vg = 0.77 \rho_2 V_g \\ \\ \rho = 0.77 \rho_2 \\ \\ 500 = 0.77 \rho_2 \\ \\ \rho_2 = 500/0.77[/tex]

[tex]\mathbf{ \rho_2 \simeq 650 \ kg/m^3}[/tex]

Answer:

[tex]\alpha=17.7[/tex]

Explanation:

From the question we are told that:

Mass [tex]m=13g[/tex]

Volume [tex]V=10mL[/tex]

Angle [tex]\theta=23[/tex]

Sample Tube=10cm

Generally the equation for concentration is mathematically given by

 [tex]C=m/v[/tex]

 [tex]C=\frac{13}{10}\\C=1.3g/mL[/tex]

Therefore the Specific Rotation

 [tex]\alpha=frac{\theta }{m*l}[/tex]

 [tex]\alpha=frac{23 }{1.3*1.0}[/tex]

 [tex]\alpha=17.7[/tex]

Answer:

10.71%

Explanation:

The dissociation of acetic acid can be well expressed as follow:

CH₃COOH ⇄   CH₃COO⁻  + H⁺

Let assume that the prepared amount of the aqueous solution is 14mM since it is not given:

Then:

The I.C.E Table is expressed as follows:

                     CH₃COOH       ⇄   CH₃COO⁻        +           H⁺  

Initial              0.0014                       0                                0

Change            - x                           +x                               +x

Equilibrium   (0.0014 - x)                 x                                 x

Recall that:

Ka for acetic acid CH₃COOH  = 1.8×10⁻⁵

∴

[tex]K_a = \dfrac{[x][x]]}{[0.0014-x]}[/tex]

[tex]1.8*10^{-5} = \dfrac{[x][x]]}{[0.0014-x]}[/tex]

[tex]1.8*10^{-5} = \dfrac{[x]^2}{[0.0014-x]}[/tex]

[tex]1.8*10^{-5}(0.0014-x) = x^2[/tex]

[tex]2.52*10^{-8} -1.8*10^{-5}x = x^2[/tex]

[tex]2.52*10^{-8} -1.8*10^{-5}x - x^2 =0[/tex]

By rearrangement:

[tex]- x^2 -1.8*10^{-5}x +2.52*10^{-8}= 0[/tex]

Multiplying through  by (-) and solving the quadratic equation:

[tex]x^2 +1.8*10^{-5}x-2.52*10^{-8}= 0[/tex]

[tex](-0.00015 + x) (0.000168 + x) =0[/tex]

x = 0.00015 or x = -0.000168

We will only consider the positive value;

so x=[CH₃COO⁻] = [H⁺] = 0.00015

CH₃COOH = (0.0014 - 0.00015) = 0.00125

However, the percentage fraction of the dissociated acetic acid is:

[tex]= \dfrac{ 0.00015}{0.0014}\times 100[/tex]

= 10.71%

Answer:

Option C

Explanation:

From the question we are told that:

Difference in energy [tex]\delta E =3.49 * 10^{-17} J[/tex]

The Ground state Difference in energy at n=1

[tex]\delta E_g = 2.18 * 10^{-18} × Z^2[/tex]

Generally the equation for Difference in energy is mathematically given by

[tex]\delta E=\delta E_g[/tex]

Therefore

[tex]3.49 * 10^{-17} = 2.18 * 10^{-18} * Z^2[/tex]

[tex]Z^2=16[/tex]

[tex]Z=4[/tex]

Therefore

Charge on element Z Q_Z

[tex]Q_Z= Atomic\ no\. of\ element - No.\ of\ electrons\ of\ element[/tex]

[tex]Q_Z =4-1[/tex]

[tex]Q_Z=+3[/tex]

Option C

Answer:

Molar mass for eugenol is 161.3 g/mol

Explanation:

This question talks about freezing point depression:

Our solute is eugenol.

Our solvent is camphor.

Formula to state the freezing point depression difference is:

ΔT = Kf . m . i where

ΔT = Freezing T° of pure solvent - Freezing T° of solution

In this case ΔT = 0.62°C

Kf for camphor is: 37°C /m

As eugenol is an organic compund, i = 1. No ions are formed.

To state the molar mass, we need m (molal)

Molal are the moles of solute in 1kg of solvent. Let's replace data:

0.62°C = 40 °C/m . m . 1

0.62°C / 40 m/°C = 0.0155 m

We convert mass of camphor from g to kg = 100 g . 1kg / 1000g = 0.1 kg

0.0155 molal = moles of solute / 0.1 kg

0.0155 m/kg . 0.1 kg = 0.00155 moles

We know that these moles are contained in 250 mg, so the molar mass will be:

0.25 g / 0.00155 mol = 161.3 g/mol

Notice, we convert mg to g, for the units!

Answer:

Physical

Chemical

Explanation:

Intermolecular forces are the forces that hold the molecules of a substance together in a particular state of matter. They decide the physical properties of a substance.

The intra molecular forces are the bond forces that hold atoms together in molecules. The nature of this bonding determines the chemical properties of substances.

Answer:

1.) Propanone (ketone)

2.) Ethanal( aldehyde)

3.) 3-phenyl-2-propenal (aldehyde)

4.) Butanone (ketone)

5.) Ethanol ( alcohol)

6.) 2-propanol (alcohol)

Explanation:

In organic chemistry, ALCOHOL ( also known as alkanol) are compounds in which hydroxyl groups are linked to alkyl groups. They can be considered as being derived from the corresponding alkanes by replacing the hydrogen atoms with hydroxyl groups. The hydroxyl group is the functional group of the alcohol as it is responsible for their characteristic chemical properties. A typical example of alcohol is ethanol and 2-propanol.

Alkanals or ALDEHYDES have the general formula RCHO while alkanones or KETONES have the general formula RR'CO where R and R' may be alkyl or aryl groups. The main similarity between these two classes of compounds is the presence of the carbonyl group. In aldehydes, there is a hydrogen atom attached to the carbon In the carbonyl group while there is none on the ketones.

Some common examples of ketones are Propanone, Butanone while examples of aldehydes are Ethanal and 3-phenyl-2-propenal

Answer:

0.17 g

Explanation:

Since the volume of gas collected is 132 mL, we need to find the number of moles of gas present in 132 mL.

So, number of moles, n = volume of gas, v/molar volume, V

n = v/V where v = 132 mL = 0.132 L and V = 22.4 L

So, substituting the values of the variables into the equation, we have

n = v/V

n = 0.132 L/22.4 L

n = 0.005893 mol

We then need to calculate the molar mass of CO, M = atomic mass of carbon + atomic mass of oxygen = 12 g/mol + 16 g/mol = 28 g/mol

Also, number of moles of gas, n = m/M where m = mass of CO and M = molar mass of CO

m = nM

m = 0.005893 mol × 28 g/mol

m = 0.165004 g

m ≅ 0.17 g to 2 significant digits

Answer:

The correct answer is - 2.557 KJ

Explanation:

In this case, Hg is melting, the process is endothermic, so the energy change will have a positive sign.

we can calculate this energy by the following formula:

Q = met

where, m = mass,

e = specific heat

t = temperature

then,

Q = 78*0.14* (273-38.8)

here 0.14 = C(Hg)

= 2.557 Kj

Answer:

See explanation

Explanation:

The molecule IF5 possesses five I-F polar bonds. However, the presence of polar bonds does not automatically imply that the molecule will be polar.

The geometry of the molecule is very important in determining the polarity of a compound. Since IF5 has a lone pair of electrons, the molecule is bent and as such there is a permanent dipole moment created in the molecule thereby making IF5 polar in nature.

Answer:

3.00 L

Explanation:

P₁V₁ = P₂V₂

V₁ = 1.00 L

P₁ = (x) atm

P₂ = [tex]\frac{1}{3}[/tex] · (P₁) = [tex]\frac{x}{3}[/tex]

V₂ = unknown

(x atm)(1.00 L) = ( [tex]\frac{x}{3}[/tex] atm)(V₂)

divide both sides by ( [tex]\frac{x}{3}[/tex] atm)

( 1.00x )( [tex]\frac{3}{x}[/tex] ) = V₂

x cancels out

(1.00)(3) = V₂

V₂ = 3.00 L

Answer:

a. 2..86 b. 4.86 c. 10.7 d. 8.7

Explanation:

a. Determine a pH at which 50% of ClCH2COOH will be in a form that possesses a charge.

Using the Henderson-Hasselbalch equation,

pH = pKa + log[A⁻]/[HA]

where [A⁻] = concentration of conjugate base (or charged form) and [HA] = concentration of acid.

At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1

So, pH = pKa + log[A⁻]/[HA]

pH = pKa + log1

pH = pKa = 2.86

b. Determine a pH at which pH more than 99% of ClCH2COOH will be in a form that possesses a charge.

Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.99x while the acidic concentration is remaining 1 % (1 - 0.99)x = 0.01x

Using the Henderson-Hasselbalch equation,

pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base (or charged form) = 0.99x and [HA] = concentration of acid = 0.01x.

pH = pKa + log0.99x/0.01x

pH = pKa + log0.99/0.01

pH = 2.86 + log99

pH = 2.86 + 1.996

pH = 4.856

pH ≅ 4.86

c. Determine a pH at which 50% of CH3CH2NH+3 will be in a form that possesses a charge.

Using the Henderson-Hasselbalch equation,

pH = pKa + log[A⁻]/[HA]

where [A⁻] = concentration of conjugate base and [HA] = concentration of acid.

At 50% concentration, [A⁻] = [HA] ⇒ [A⁻]/[HA] = 1

So, pH = pKa + log[A⁻]/[HA]

pH = pKa + log1

pH = pKa = 10.7

d. Determine a pH at which pH more than 99% of CH3CH2NH+3 will be in a form that possesses a charge.

Let x be the concentration of the acid. Since 99% of it should possess a charge, the basic concentration is 0.01x while the acidic concentration is remaining 99 % (1 - 0.01)x = 0.99x (which possesses the charge).

Using the Henderson-Hasselbalch equation,

pH = pKa + log[A⁻]/[HA] where [A⁻] = concentration of conjugate base = 0.01x and [HA] = concentration of acid = 0.99x.

pH = pKa + log0.01x/0.99x

pH = pKa + log1/99

pH = 10.7 - log99

pH = 10.7 - 1.996

pH = 8.704

pH ≅ 8.7

Answer:

the composition of the ∝ phase C∝ = 14  or [ 14 wt% B-86 wt% A ]

Explanation:

Given the data in the question;

Co = 53 or [ 53 wt% B-47 wt% A ]

W∝ = 0.5 = Wβ

Cβ = 92 or [ 92 wt% B-8 wt% A ]

Now, lets set up the Lever rule for W∝ as follows;

W∝ = [ Cβ - Co ] / [ Cβ - C∝ ]

so we substitute our given values into the expression;

0.5 = [ 92 - 53 ] / [ 92 - C∝ ]

0.5 = 39 /  [ 92 - C∝ ]

0.5[ 92 - C∝ ] = 39

46 - 0.5C∝  = 39

0.5C∝ = 46 - 39

0.5C∝ = 7

C∝ = 7 / 0.5

C∝ = 14  or [ 14 wt% B-86 wt% A ]

Therefore, the composition of the ∝ phase C∝ = 14  or [ 14 wt% B-86 wt% A ]

Answer:

0 J

Explanation:

Applying,

ΔE = q+w................ Equation 1

Where ΔE = change in internal energy of the system, q = Heat of the system, w = work of the system.

Note: q is positive, while w is negative

From the question,

Given: q = 425 J, w = -425 J

Substitute these values into equation 1

ΔE = 425-425

ΔE = 0 J

Hence the change in internal energy of the system is 0 J

Answer:

C. By super-cooling certain types of plasma.

Explanation:

Bose-Einstein condensate is a state of matter whereby atoms or particles become cooled to a very low energy state leading to their condensation to give a single quantum state.

Note that plasma refers to atoms that have had some or even all of its electrons stripped away leaving only positively charged ions. Simply put, plasma is ionized matter.

When certain types of plasma are super cooled, Bose-Einstein condensate are formed.

Answer: Chemicals like acids and bases are harmful and must be neutralized before draining.

Explanation:

A strong acid or strong base is required to be diluted or neutralized before it is discarded in the drain as if is discarded without diluting and neutralization it can spill and splash from sink or drain and can harm people in chemistry lab, moreover the fumes of the discarded chemical on spilling can cause respiratory tract burning and can even cause fire hazard so it must be converted into less harmful form and then must be drained.  

Answer:

41 g

Explanation:

The equation of the reaction is;

Cr(NO3)3(aq)+Na3PO4(aq)=3NaNO3(s)+CrPO4(aq)

Number of moles of chromium nitrate = 37g/ 146.97 g/mol = 0.25 moles

1 mole of sodium phosphate reacts with 1 mole of chromium nitrate

x moles of sodium phosphate react as with 0.25 moles of chromium nitrate

x= 1 × 0.25/1

x= 0.25 moles

Mass of sodium phosphate = 0.25 moles × 163.94 g/mol

Mass of sodium phosphate = 41 g

Answer:

O2(g) + 2H2O(l) --------> 2H2O2(aq) + 2e

Explanation:

An oxidation reaction reaction refers to a reaction in which electrons are lost. In this case, we are about to see the full balanced half-reaction for the oxidation of liquid water to aqueous hydrogen peroxide in basic aqueous solution.

The full equation is;

O2(g) + 2H2O(l) --------> 2H2O2(aq) + 2e

So, two electrons were lost in the process.

To answer this question, we will first find out the number of gaseous moles on each side of the equilibrium

on the left:

we have 2 moles of A, 5 moles of B and 12 moles of C

which gives us a grand total of 19 gaseous moles

on the right:

here, we have 14 moles of AC gas, we will not count the number of moles of B because it's a solid

giving us 14 gaseous moles on the right

Where does the reaction shift?

more gaseous moles means more space taken, because gas likes to fill all the space it can

if we have more volume, more gas can move around without colliding (reacting) with each other

Hence more volume favors the side with more gaseous moles

here, the left has more gaseous moles. So we can say that the reaction will shift towards the left, or the reactants side

Answer:

Explanation:

given reversible chemical reaction:

2A(g) + 5B(g) + 12C(g)  ↔  14AC(g) + 5B(s)

chemicals in solid form do not take up a lot of volume so change in container volume has no effect

look at chemicals in gas form only:

the total no. of moles of reactants in gas form = 2 + 5 + 12 = 19

the total no. of moles of products in gas form = 14

so an increase in volume of the container will favor the reaction direction with higher volume n high volume means higher no. of moles

the ans is the equilibrium will move towards a) reactants

Explanation:

The given chemical reaction is:

[tex]2Br^- (aq) + I_2(s) <-> Br_2(l) + 2I^- (aq)[/tex]

[tex]E^ocell=oxidation potential of anode + reduction potential of cathode\\[/tex]

The relation between Eo cell and Keq is shown below:

[tex]deltaG=-RTlnK_e_q\\delta=-nFE^o cell\\=>nFE^o cell=RTlnK_e_q\\lnK_e_q=\frac{nF}{RT} E^o cell[/tex]

The value of Eo cell is:

Br- undergoes oxidation and I2 undergoes reduction.

Reduction takes place at cathode.

Oxidation takes place at anode.

Hence,

[tex]E^ocell= (-1.07+0.53)V\\=-0.54V[/tex]

F=96485 C/mol

n=2 mol

R=8.314 J.K-1.mol-1

T=298K

Substitute all these values in the above formula:

[tex]ln K_e_q=\frac{2mol* 96485 C/mol}{8.314 J.K^-^1.mol^-^1x298K} \\\\lnK_e_q=77.8\\K_e_q=e^7^7^.^8\\=>K_e_q=6.13x10^3^3[/tex]

Answer:

Keq=6.13x10^33

Answer:

[tex]\boxed {\boxed {\sf {One \ atom \ donates \ both \ electrons \ in \ a \ pair}}}[/tex]

Explanation:

A covalent bond involves the sharing of electrons to make the atoms more stable, and so they satisfy the Octet Rule (8 valence electrons).

Typically each atom contributes an electron to form an electron pair. This is a single bond. There are also double bonds (two pairs of electrons), triple bonds (three pairs of electrons), and coordinate covalent bonds.

Sometimes, to satisfy the Octet Rule and achieve stability, one atom contributes both of the electrons in an electron pair. This is different from other covalent bonds because usually each of the 2 atoms contributes an electron to make a pair.

Answer:

The answer is "[tex]1.25 \times 10^{-3} \ \frac{m}{s}[/tex]"

Explanation:

Calculating the rate of the equation:

[tex]=-\frac{1}{2} \frac{\Delta [SO_2]}{\Delta t} =-\frac{\Delta [O_2]}{\Delta t}= +\frac{1}{2} \frac{\Delta [SO_3]}{\Delta t}\\\\=\frac{\Delta [SO_2]}{\Delta t}=\frac{0.0500-0.175\ M}{505}= -2.5 \times 10^{-3} \ \frac{m}{s}\\\\[/tex]

Rate:

[tex]=\frac{-2.5 \times 10^{-3}}{2}=1.25 \times 10^{-3} \ \frac{m}{s}[/tex]

Answer:

pH= 1.9 then [tex]H_{3} PO_{4}[/tex]

pH = 5.0 , [tex]CH_{3} COOH[/tex]

pH = 3.9 , HCOOH

As we know range left [tex]pH= pKa+/- 1[/tex]

Answer:

hydrogen bonding

Explanation:

just took the test :D

Answer:

56511.75 J

13506.3 Calories

Explanation:

Applying,

Q = cm(t₂-t₁).................. Equation 1

Where Q = amount of heat, m = mass of the iron, c = specific heat capacity of the iron, t₁ = initial temperature, t₂ = final temperature.

From the question,

Given: m = 75 g, c = 0.499 J/g.°C, t₂ = 1535°C, t₁ = 25°C

Substitute these values into equation 1

Q = 75(0.499)(1535-25)

Q = 75(0.499)(1510)

Q = 56511.75 J

Q in Calories is

Q = (56511.75×0.239)

Q = 13506.3 Calories

Answer:

[tex]H_2CO_3(aq)+2OH^-(aq)\rightarrow (CO_3)^{2-}(aq)+2H_2O(l)[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to set up this net ionic equation, by firstly setting up the complete molecular equation as follows:

[tex]H_2CO_3(aq)+2NaOH(aq)\rightarrow Na_2CO_3(aq)+2H_2O(l)[/tex]

Thus, since carbonic acid is weak it merely ionizes whereas sodium hydroxides ionizes for the 100 % as it is strong; thus, we can write the complete ionic equation:

[tex]H_2CO_3(aq)+2Na^+(aq)+2OH^-(aq)\rightarrow 2Na^+(aq)+(CO_3)^{2-}(aq)+2H_2O(l)[/tex]

Whereas sodium ions act as the spectator ones to be cancelled out for us to obtain:

[tex]H_2CO_3(aq)+2OH^-(aq)\rightarrow (CO_3)^{2-}(aq)+2H_2O(l)[/tex]

Regards!

Answer:

(A) Slipping and breaking

(B) Clean and dry

(C) Cracks

Explanation:

This describes the process of unpacking a glassware for use.

You should set out support like a cork ring or clamp (these are simple machines that'll hold the glassware in place) before removing the glassware from a glassware kit; to place the glassware in and to stop it from slipping and breaking.

Thoroughly check that the glassware is clean and dry and that it does not have any cracks, before using it.