Calculate the pH of a 0.20 M NH3/0.20 M NH4Cl buffer after the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.

Answers

Answer 1

Answer:

Explanation:

For pH of a buffer solution , the formula is

pH = pKa + log [ Base ] / [ conjugate acid ]

=   pKa + log [ NH₃ ] / [ NH₄⁺ ]

Ka = Kw / Kb

Kb for NH₄OH = 1.8 x 10⁻⁵

Ka = 10⁻¹⁴ / 1.8 x 10⁻⁵

= 5.6 x 10⁻¹⁰

pH = - log ( 5.6 x 10⁻¹⁰ ) + log 0.2 / 0.2

= 10 - log 5.6

= 9.25

Effect of addition of HCl

H⁺ of HCl will react with NH₃ to produce NH₄⁺

25 mL of .1 HCl = 2.5 mM of HCl

25 mL of .1 NH₄⁺ = 2.5 mM of NH₄⁺

65 mL of .2 M NH₃ = 13 mM of NH₃

65 mL of .2 M NH₄⁺ = 13 mM of NH₄⁺

NH₃ + H⁺ = NH₄⁺

NH₄⁺ formed = 2.5 + 13  mM

15.5 mM of NH₄⁺

NH₃ = 13 mM

Concentration of NH₃ = 13 / 90

Concentration of NH₄⁺ = 15.5 / 90

pH of final buffer mixture

= 9.6 + log 13 / 15.5

= 9.25 - .076

= 9.174

Answer 2

The pH value  is mathematically given as

pH= -6.332.

What is the pH of a 0.20 M NH3/0.20 M NH4Cl buffer?

Question Parameters:

the pH of a 0.20 M NH3/0.20 M NH4Cl buffer

the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.

Generally, the equation for the Chemical Reaction  is mathematically given as

HCl + NH3 --> NH4^+ + Cl^-

Therefore

pH= pka + log(13/14).

pH= -6.3 + log 0.93.

pH= -6.3+ (-0.032).

pH= -6.332.

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Related Questions

At a given temperature the vapor pressures of benzene and toluene are 183 mm Hg and 59.2 mm Hg, respectively. Calculate the total vapor pressure over a solution of benzene and toluene with X Benzene

Answers

CHECK COMPLETE QUESTION BELOW

At a given temperature the vapor pressures of benzene and toluene are 183 mm Hg and 59.2 mm Hg, respectively. Calculate the total vapor pressure over a solution of benzene and toluene with Xbenzene = 0.580.

Answer:

The total vapor pressure is [tex]81.3 mmHg[/tex]

Explanation:

We will be making use of Dalton and Raoults equation in order to calculate the total pressure,

Which is [tex]PT= (PA × XA) +(PB ×XB)[/tex]

PT= total vapor pressure

From the question

Benene's Mole fraction = 0.580

then to get Mole fraction of toluene we will substract the one of benzene from 1. because total mole fraction is always 1.

= (1 - 0.580) = 0.420

Vapor pressure of benzene given = 183 mmHg

Vapor pressure of toluene given= 59.2 mmHg

If we substitute those value into above equation, we have

PT=(183×0.580)+(59.2×0.420)

=81.3mmHg

Therefore,, the total vapor pressure of the solution is 81.3 mmHg

Indicate the peptides that would result from cleavage by the indicated reagent: a. Gly-Lys-Leu-Ala-Cys-Arg-Ala-Phe by trypsin b. Glu-Ala-Phe-Gly-Ala-Tyr by chymotrypsin

Answers

Answer:

a. Gly-Lys + Leu-Ala-Cys-Arg + Ala-Phe

b. Glu-Ala-Phe + Gly-Ala-Tyr

Explanation:

In this case, we have to remember which peptidic bonds can break each protease:

-) Trypsin

It breaks selectively the peptidic bond in the carbonyl group of lysine or arginine.

-) Chymotrypsin

It breaks selectively the peptidic bond in the carbonyl group of phenylalanine, tryptophan, or tyrosine.

With this in mind in "peptide a", the peptidic bonds that would be broken are the ones in the "Lis" and "Arg" (See figure 1).

In "peptide b", the peptidic bond that would be broken is the one in the "Phe" (See figure 2). The second amino acid that can be broken is tyrosine, but this amino acid is placed in the C terminal spot, therefore will not be involved in the hydrolysis.

Write an equation to show how the base NaOH(s) behaves in water. Include states of matter in your answer. Click in the answer box to open the symbol palette.

Answers

Answer:

The reaction is given as:

[tex]NaOH(s)\rightarrow Na^+(aq)+OH^-(aq)[/tex]

Explanation:

Bases are defined as those chemical substances which give hydroxide ions in their aqueous solutions.

[tex]BOH(s)\rightarrow B^+(aq)+OH^-(aq)[/tex]

When sodium hydroxide is added to water it gets dissociated into two ions that are sodium ions and hydroxide ions. Along with this heat energy also releases during this reaction.

The reaction is given as:

[tex]NaOH(s)\rightarrow Na^+(aq)+OH^-(aq)[/tex]

The equation to show how NaOH behaves in water is NaOH → Na⁺ + (OH)⁻

The compound that produce negative hydroxide (OH−) ions when dissolved

in water are called bases .

This compounds NaOH (sodium hydroxide) is an example of a base.

When it dissolves in water it dissociate to form  negative hydroxide (OH−)

ions  and positive sodium (Na+) ions.

It can be represented by the following equation:

NaOH → Na⁺ + (OH)⁻

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At a constant temperature, a sample of a gas in a balloon that originally had a volume of 5.00 L and pressure of 626 torr has its volume changed to 6.72 L. Calculate the new pressure in torr.

Answers

Answer:

466 torr

Explanation:

Step 1: Given data

Initial pressure (P₁): 626 torrInitial volume (V₁): 5.00 LFinal pressure (P₂): ?Final volume (V₂): 6.72 LConstant temperature

Step 2: Calculate the final pressure

Since we have a gas changing at a constant temperature, we can calculate the final pressure using Boyle's law.

P₁ × V₁ = P₂ × V₂

P₂ = P₁ × V₁ / V₂

P₂ = 626 torr × 5.00 L / 6.72 L

P₂ = 466 torr

The insoluble salts below are put into 0.10 M hydrochloric acid solution. Do you expect their solubility to be more, less, or about the same as in a pure water solution?
1. Zinc sulfide
2. Silver chloride
3. Lead iodide
4. Silver hydroxide

Answers

Answer:

1. Zinc sulfide : about the same solubility, no common ion is found.

2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.

3. Lead iodide  : about the same solubility, no common ion is found.

4. Silver hydroxide : about the same solubility, no common ion is found.

Explanation:

Hello,

In this case, we first must remember that adding a common ion (which is related with the dissolving solid) decreases the solubility of the insoluble solid due to the fact Le Chatelier's principle states the reaction will shift leftwards (reactants) to reestablish equilibrium, therefore, we have:

1. Zinc sulfide : about the same solubility, no common ion is found.

2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.

3. Lead iodide  : about the same solubility, no common ion is found.

4. Silver hydroxide : about the same solubility, no common ion is found.

Best regards.

What attractive force holds two hydrogen atoms and one oxygen atom
together to make the substance water?
A. Molecules
B. Chemical bonding
O C. Valence electrons
O D. Cations

Answers

Answer:

It is a hydrogen bond but if I had to coose one of thee answers it is b. chemical bonding

Explanation:

A chemist fills a reaction vessel with 0.978 g aluminum hydroxide AlOH3 solid, 0.607 M aluminum Al+3 aqueous solution, and 0.396 M hydroxide OH− aqueous solution at a temperature of 25.0°C.
Under these conditions, calculate the reaction free energy ΔG for the following chemical reaction:
Al(OH)3(s) = A1+ (aq) +30H (aq)
Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoule.
KJ

Answers

Answer: [tex]\Delta G^{0}[/tex] = 168.12 kJ

Explanation: Gibbs Free Energy, at any time, is defined as the enthalpy of the system minus product of temperature and entropy of the reaction, i.e.:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

Enthalpy is defined as internal heat existent in the system. It is calculated as:

[tex]\Delta H^{0} = \Sigma H^{0}_{product} - \Sigma H^{0}_{reagent}[/tex]

Using Enthalpy Formation Table:

[tex]\Delta H^{0} = [3*(-299.9)+(-524.7)] - (-1277)[/tex]

[tex]\Delta H^{0} = 62,6 kJ[/tex]

Entropy is the degree of disorder in the system. It is found by:

[tex]\Delta S^{0} = \Sigma S^{0}_{products} - \Sigma S^{0}_{reagents}[/tex]

Calculating:

[tex]\Delta S^{0} = (-321.7) + 3(-10.8) - 0[/tex]

[tex]\Delta S^{0} = -354.1J[/tex]

And so, Gibbs Free energy will be:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

[tex]\Delta G^{0} = 62600 - [298.(-354.1)][/tex]

[tex]\Delta G^{0} = 168121.8 J[/tex]

Rounding to the nearest kJ:

[tex]\Delta G^{0}[/tex] = 168.12 kJ

What is the density of a 10 kg mass that occupies 5 liters?
( pls need help)

Answers

Answer: d=2000 g/L

Explanation:

Density is mass/volume. The units are g/L. Since we are given mass and volume, we can divide them to find density. First, we need to convert kg to g.

[tex]10kg*\frac{1000g}{1kg} =10000 g[/tex]

Now that we have grams, we can divide to get density.

[tex]d=\frac{10000g}{5 L}[/tex]

d=2000g/L

15. How many moles of carbon tetrachloride (CCI) is represented by 543.2 g of carbon tetrachloride? The atomic weight of carbon is 12.01
and the atomic weight of chlorine is 35.45.
O A. 11.4 moles
O B.3.53 moles
C. 5.42 moles
D. 8.35x10 moles

Answers

Answer:

well, first off. the formula for carbon tetrachloride is CCl4

We need to find the molar mass of carbon tetrachloride

1(Mass of C) + 4(mass of chlorine)

1(12) + 4(35.5)

12 + 142

154 g/mol

Number of moles of CCl3 in 543.2g CCl3

n = given mass / molar mass

n = 543.2/153

n = 3.53 moles

always remember to brainly the questions you find helpful

Answer:

3.53 moles

Explanation:

How does the spontaneity of the process below depend on temperature? PCl5(g)+H2O(g)→POCl3(g)+2HCl(g) ΔH=−126 kJ mol−1, ΔS=146 J K−1mol−

Answers

The given question is incomplete, the complete question is:

How does the spontaneity of the process below depend on temperature? PCI5(9)+H2O(g)POCI3(g) +2HCI(g) -126 kJ mol1, AS = 146 J K-'mol1 ΔΗ Select the correct answer below: nonspontaneous at all temperatures spontaneous at all temperatures spontaneous at high temperatures and nonspontaneous at low temperatures spontaneous at low temperatures and nonspontaneous at high temperatures

Answer:

The correct answer is spontaneous at all the temperatures.

Explanation:

Gibbs Free energy is an essential relation that determines the spontaneity of any reaction, that is, ΔG = ΔH - TΔS

When ΔG is less than zero, that is, negative, the reaction is considered to be in spontaneous state. Based on the given information, ΔH = -126 kJ/mol

= -126000 J/mol, it is negative

ΔS = 146 J/K/mol, it is positive

Now, ΔG = ΔH-TΔS

= (-ve) - T (+ve), Thus, when ΔH, is -ve, ΔS is +ve, -TΔS is -ve, the ΔG will be -ve. Therefore, reaction will be spontaneous at all the temperatures.  

What's the concentration of hydronium ions if a water-base solution has a temperature of 25°C (Kw = 1.0×10–14), with a concentration of hydroxide ions of 2.21×10–6 M? answer options: A) 2.8×10–8 M B) 4.52 ×10–9 M C) 1.6×10–9 M D) 3.1×10–6 M

Answers

Answer:

ITS NOT D. ITS B. 4.52x10^-9 M

Explanation:

Answer:

4.52 ×10–9 M

Explanation:


Zeros laced at the end of the significant number are...

Answers

Answer:

Zeros located at the end of significant figures are significant.

Explanation:

Hope it will help :)

g Does a reaction occur when aqueous solutions of barium hydroxide and aluminum sulfate are combined

Answers

Answer:

3BaO + Al₂(SO₄)₃  →  Al₂O₃+ 3BaSO₄

Explanation:

Yes! A reactiin occurs between barium hydroxide and auminium sulphate.

barium sulfate (BaSO4) and aluminum hydroxide (Al(OH)3) are the products obtained in this reaction.

The reaction is given by the equation below;

3BaO + Al₂(SO₄)₃  →  Al₂O₃+ 3BaSO₄

243
Am
95
1. The atomic symbol of americium-243 is shown. Which of the following is correct?
• A. The atomic mass is 243 amu, and the atomic number is 95.
B. The atomic mass is 338 amu, and the atomic number is 95.
• C. The atomic mass is 95 amu, and the atomic number is 243.
D. The atomic mass is 243 amu, and the atomic number is 338.​

Answers

Answer:

A. The atomic mass is 243 amu, and the atomic number is 95.

1500 L has how many significants figures

Answers

Answer:

It has 2

Explanation:

The significant figures are 1 and 5!

Hope this helps:)

Determine the oxidation state for each of the elements below. The oxidation state of ... silver ... in ... silver oxide Ag2O ... is ... ___ . The oxidation state of sulfur in sulfur dioxide SO2 is ___ . The oxidation state of iron in iron(

Answers

Answer:

The oxidation state of silver in [tex]\rm Ag_2O[/tex] is [tex]+1[/tex].

The oxidation state of sulfur in [tex]\rm SO_2[/tex] is [tex]+4[/tex].

Explanation:

The oxidation states of atoms in a compound should add up to zero.

Ag₂O

There are two silver [tex]\rm Ag[/tex] atoms and one oxygen [tex]\rm O[/tex] atom in one formula unit of [tex]\rm Ag_2O[/tex]. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of oxygen in most compounds (with the exception of peroxides and fluorides) is [tex]-2[/tex]. Silver oxide [tex]\rm Ag_2O[/tex] isn't an exception. Therefore:

[tex]\begin{aligned}&\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 2 \times \text{Oxidation state of $\rm Ag$}+ \rm 1 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the (average) oxidation state of [tex]\rm Ag[/tex]:

[tex]\text{Oxidation state of $\rm Ag$} = 1[/tex].

SO₂

Similarly, because there are one sulfur [tex]\rm S[/tex] atom and two oxygen [tex]\rm O[/tex] atoms in each [tex]\rm SO_2[/tex] molecules:

[tex]\begin{aligned}&\rm 1\times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\end{aligned}[/tex].

The oxidation state of [tex]\rm O[/tex] in [tex]\rm SO_2[/tex] is also [tex]-2[/tex], not an exception, either.

Therefore:

[tex]\begin{aligned}&\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times \text{Oxidation state of $\rm O$} = 0\\ &\rm 1 \times \text{Oxidation state of $\rm S$}+ \rm 2 \times (-2) = 0\end{aligned}[/tex].

Solve this equation for the oxidation state of [tex]\rm S[/tex] here:

[tex]\text{Oxidation state of $\rm S$} = 4[/tex].

If a substance has a half-life of 55.6 s, and if 230.0 g of the substance are present initially, how many grams will remain after 10.0 minutes?

Answers

Answer:

[tex]m=0.127g[/tex]

Explanation:

Hello,

In this case, for a first-order reaction, we can firstly compute the rate constant from the given half-life:

[tex]k=\frac{ln(2)}{t_{1/2}} =\frac{ln(2)}{55.6s}=0.0125s^{-1}[/tex]

In such a way, the integrated first-order law, allows us to compute the final mass of the substance once 10.0 minutes (600 seconds) have passed:

[tex]m=m_0*exp(-kt)=230.0g*exp(-0.0125s^{-1}*600s)\\\\m=0.127g[/tex]

Best regards.

I think I'm typing it into my calculator wrong. I will give brainliest to whoever gets it right.

Answers

Answer:

36.7 mg

Explanation:

The following data were obtained from the question.

Original amount (A₀) = 65.1 mg

Rate constant (K) = 2.47×10¯² years¯¹

Time (t) = 23.2 years

Amount of substance remaining (A) =?

Thus, we can obtain the amount of substance remaining after 23.2 years as follow

ln A = lnA₀ – Kt

lnA = ln(65.1) – (2.47×10¯² × 23.2)

lnA = 4.1759 – 0.57304

lnA = 3.60286

Take the inverse of ln

A = e^3.60286

A = 36.7 mg

Therefore, the amount remaining after 23.2 years is 36.7 mg.

What type of bond would form between two atoms of phosphorus? A. Single covalent bond B. Single ionic bond C. Triple covalent bond D. Double covalent bond

Answers

Answer:

A double bond is formed when two pairs of electrons are shared between the two participating atoms. It is represented by two dashes (=). It is represented by two dashes (=). Double covalent bonds are much stronger than a single bond, but they are less stable

Explanation:

I need to name an ionic compound containing a transition metal cation and a halogen anion. Below are the rules I should follow to write the correct name for such compound, but one of the options is incorrect: identify and select it.
a. Identify the metal and write its name first
b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table
c. From the charge of the anion work out the charge of cation as Roman number in parenthesis: specify this charge in the name as a Roman number in parenthesis.
d. Write the number of the anion after the name of the metal

Answers

Answer:

b. Use the periodic table to work out the charge (oxidation number) on the transition metal according to the group in the periodic table

Explanation:

The keyword in this problem us "transition metal". Transition metals are found between the group 2 and group 3 elements. They have the d sub shells and also exhibit variable oxidation numbers (valency).

Among the options, the incorrect option is option B.

This is because transition metals d not have  a fixed oxidation number and they cannot be obtained by looking up the group in the periodic table.

The iconic compounds obtain a transition of metal caution and a halon anon. As per the rules the correct name of the compounds should be written as to identify the incorrect one.

Option B use the ability to check and to work out the charges (oxidation number) of the transition metal as per the group given in the table. The problem with the keyword is transition metal.

Learn more about the ionic compound containing a transition metal.

brainly.com/question/21578354.

If 100-mL of 1.0 M Sr(OH)2 is added to 100 mL of 1.0 M HCl, the pH of the mixture would be _____. Group of answer choices

Answers

Answer:

pH = 13.7

Explanation:

A strong acid (HCl) reacts with a strong base Sr(OH)₂ producing water and a salt, thus:

2HCl + Sr(OH)₂ → 2H₂O + SrCl₂

To solve this problem, we need to find initial moles of both reactants and, with the chemical equation find limiting reactant and moles in excess to find pH as follows:

The initial moles of HCl and Sr(OH)₂ are:

100mL = 0.1L ₓ (1.0mol / L) = 0.100 moles of both HCl and Sr(OH)₂

As 2 moles of HCl reacts per mole of Sr(OH)₂, moles of Sr(OH)₂ that reacts with 0.100 moles of HCl are:

0.100 moles HCl ₓ (1 mol Sr(OH)₂ / 2 mol HCl) = 0.050 moles Sr(OH)₂

That means HCl is limiting reactant and after reaction will remain in solution:

0.100 mol - 0.050mol =

0.050 moles of Sr(OH)₂

Find pH:

1 mole of Sr(OH)₂ contains 2 moles of OH⁻, 0.050 moles contains 0.050×2 = 0.100 moles of OH⁻. In 200mL = 0.2L:, molar concentration of OH⁻ is:

0.100 moles / 0.2L =

[OH⁻] = 0.5M

As pOH of a solution is -log[OH⁻],

pOH = -log 0.5M

pOH = 0.301

And knowing:

pH = 14 - pOH

pH = 14 - 0.301

pH = 13.7

Consider the bond dissociation energies listed below in kcal/mol. CH3-Br 70 CH3CH2-Br 68 (CH3)2CH-Br 68 (CH3)3C-Br 65 These data show that the carbon-bromine bond is weakest when bromine is bound to a __________.

Answers

Answer:

The answer is "Tertiary carbon".

Explanation:

Accent to the results, the carbon-bromine bond is weak, whenever, the bromine is connected to tertiary carbon so, bonding energy is separation for methyl-carbon, which is connected to the bromine = 70 kcal/mol and for the primary energy to the secondary energy is=  68 kcal/mol, and for tertiary CO2 = 65 kcal/mol.

The stronger the energy dissociating connection and the weaker, its power dissociation connection and its weaker bond becomes connecting with a tertiary carbon, that's why "Tertiary carbon" is the correct answer.

What will be formed when 2,2,3-trimethylcyclohexanone reacts with hydroxylamine?

Answers

Answer:

Following are the solution to this equation:

Explanation:

In the given-question, an attachment file of the choices was missing, which can be attached in the question and its solution can be defined as follows:

In the given question "Option (iii)" is correct, which is defined in the attachment file.

When 2,2,3-trimethylcyclohexanone reacts with hydroxylamine it will produce the 2,2,3-trimethylcyclohexanoxime.

Calculate the molality of a solution containing 141.5 g of glycine (NH2CH2COOH) dissolved in 4.456 kg of H2O

Answers

Answer:

0.423 m.

Explanation:

The following data were obtained from the question:

Mass of glycine (NH2CH2COOH) = 141.5 g

Mass of water = 4.456 kg

Molality =.?

Next, we shall determine the number of mole in 141.5 g of glycine (NH2CH2COOH.

This is illustrated below:

Mass of glycine (NH2CH2COOH) = 141.5 g

Molar mass of glycine (NH2CH2COOH) = 14 + (2x1) + 12 + (2x1) + 12 + 16 + 16 + 1 = 75 g/mol

Mole of glycine (NH2CH2COOH) =.?

Mole = mass /Molar mass

Mole of glycine (NH2CH2COOH) = 141.5/75

Mole of glycine (NH2CH2COOH) = 1.887 moles

Finally, we shall determine the molality of the solution as follow:

Molality is simply defined as the mole of solute per kilogram of water. Mathematically it is expressed as:

Molality = mole / mass (kg) of water

With the above formula, we can obtain the molality of the solution as follow:

Mole of glycine (NH2CH2COOH) = 1.887 moles

Mass of water = 4.456 kg

Molality =.?

Molality = mole /mass (kg) of water

Molality =1.887/4.456

Molality = 0.423 m

Therefore, the molality of the solution is 0.423 m

whts the ph of po4 9.78

Answers

Answer:

4.22

Explanation:

We know from the question, that the pOH of the solution is 9.78. Now the pOH is defined as -log [OH^-].

If the pOH of a solution is given, one may obtain the pH of such solution from the formula;

pH + pOH =14

Hence we can write;

pH = 14-pOH

pH = 14 - 9.78 = 4.22

Hence the pH of the solution is 4.22.

How many grams of PtBr4 will dissolve in 250.0 mL of water that has 1.00 grams of KBr dissolved in it

Answers

Answer:

[tex]m_{PtBr_4}=0.306gPtBr_4[/tex]

Explanation:

Hello,

In this case, since the solubility product of platinum (IV) bromide is 8.21x10⁻⁹, and the dissociation is:

[tex]PtBr_4(s)\rightleftharpoons Pt^{4+}(aq)+4Br^-(aq)[/tex]

The equilibrium expression is:

[tex]Ksp=[Pt^{4+}][Br^-]^4[/tex]

Thus, since the salt is added to a solution initially containing 1.00 grams of potassium bromide, there is an initial concentration of bromide ions:

[tex][Br^-]_0=\frac{1.00gKBr*\frac{1molKBr}{119gKBr}*\frac{1molBr^-}{1molKBr} }{0.250L}=0.0336M[/tex]

Hence, in terms of the molar solubility [tex]x[/tex], we can write:

[tex]8.21x10^{-9}=(x)(0.0336+4x)^4[/tex]

In such a way, solving for [tex]x[/tex], we obtain:

[tex]x=0.00238M[/tex]

Which is the molar solubility of platinum (IV) bromide. Then, since its molar mass is 514.7 g/mol, we can compute the grams that get dissolved in the 250.0-mL solution:

[tex]m_{PtBr_4}=0.00238\frac{molPtBr_4}{1L}*0.250L *\frac{514.7gPtBr_4}{1molPtBr_4} \\\\m_{PtBr_4}=0.306gPtBr_4[/tex]

Best regards.

A student mixed 50 ml of 1.0 M HCl and 50 ml of 1.0 M NaOH in a coffee cup calorimeter and calculate the molar enthalpy change of the acid-base neutralization reaction to be –54 kJ/mol. He next tried the same experiment with 100 ml of 1.0 M HCl and 100 ml of 1.0 M NaOH. The calculated molar enthalpy change of reaction for his second trial was:

Answers

Answer: The calculated molar enthalpy change of reaction for his second trial was -108 kJ.

Explanation:-

Molarity of a solution is defined as the number of moles of solute dissolved per Liter of the solution.

[tex]\text{no of moles}={\text{Molarity}\times {\text{Volume in L}}[/tex]

Thus [tex]\text{no of moles}of HCl={1.0M}\times {0.05L}=0.05moles[/tex]

Thus [tex]\text{no of moles}of NaOH={1.0M}\times {0.05L}=0.05moles[/tex]

[tex]HCl(aq)+NaOH(aq)\rightarrow NaCl(aq)+H_2O(l)[/tex]

Given for second trial:

[tex]\text{no of moles}of HCl={1.0M}\times {0.1L}=0.1moles[/tex]

[tex]\text{no of moles}of NaOH={1.0M}\times {0.1L}=0.1moles[/tex]

0.05 moles of [tex]HCl[/tex] reacts with 0.05 moles of [tex]NaOH[/tex] to release  heat = 54 kJ

0.1 moles of [tex]HCl[/tex] reacts with 0.05 moles of [tex]NaOH[/tex] to release  heat  =[tex]\frac{54}{0.05}\times 0.1=108kJ[/tex]

Thus calculated molar enthalpy change of reaction for his second trial was -108 kJ.

Explain your reasoning. Match each explanation to the appropriate blanks in the sentences on the right.
1. the atomic radius decreases
2. the number of gas molecules decreases
3. molar mass and structure complexity decreases
4. structure complexity decreases
5. molar mass decreases
6. each phase (gas, liquid, solid) becomes more ordered
A (I_2(g), Br_2 (g), Cl_2 (g), F_2 (B): The ranking can best be explained by the trend entropy decreases as______.
B (H_2O_2 (g), H_2S(g), H_2O(g): The ranking can best be explained by the decreases a trend entropy decreases as_______.
C. (C(s, amorphous), C(s, graphite), C(s, diamond): The ranking can best be explained by the trend entropy decreases as_______.

Answers

Answer:

A (I_2(g), Br_2 (g), Cl_2 (g), F_2 (B): The ranking can best be explained by the trend entropy decreases as 5. molar mass decreases.

B (H_2O_2 (g), H_2S(g), H_2O(g): The ranking can best be explained by the decreases a trend entropy decreases as 3. molar mass and structure complexity decreases.

C. (C(s, amorphous), C(s, graphite), C(s, diamond): The ranking can best be explained by the trend entropy decreases as 4. structure complexity decreases.

Explanation:

Hello.

In this case, we can understand a higher entropy when more disorder is present and a lower entropy when less disorder is present, thus:

A (I_2(g), Br_2 (g), Cl_2 (g), F_2 (B): The ranking can best be explained by the trend entropy decreases as 5. molar mass decreases since iodine has the greatest molar mass (254 g/mol) and fluorine the least molar mass (38 g/mol).

B (H_2O_2 (g), H_2S(g), H_2O(g): The ranking can best be explained by the decreases a trend entropy decreases as 3. molar mass and structure complexity decreases since hydrogen peroxide weights 34 g/mol as well as hydrogen sulfide but the peroxide has more bonds (more complex, higher entropy).

C. (C(s, amorphous), C(s, graphite), C(s, diamond): The ranking can best be explained by the trend entropy decreases as 4. structure complexity decreases since diamond has a well-ordered structure and amorphous carbon has a very disordered one.

Best regards.

A student is performing a Benedict’s test on an unknown substance. He adds the reagent (the chemical required to make a color change), and nothing happens. What can he conclude? A- The substance is glucose-based. B- The substance is not glucose-based. C- The test was inconclusive because he needed to also test with iodine or vinegar. D- The test was inconclusive because he forgot to add heat.

Answers

Answer:

The correct answer is : option D. The test was inconclusive because he forgot to add heat.

Explanation:

Benedict's test is a test that is used to confirm the presence of the simple carbohydrates (mono saccharides and some disaccharides). It is a reagent made by mixture of solution of CuSO4 with sodium citrate and Na2CO3.

Benedict's reagent is added to the substance to test and then heated if it turns yellow to orange or red the presence of simple sugar is confirmed.

Thus, the correct answer is : option D. The test was inconclusive because he forgot to add heat.

Answer:

The test was inconclusive because the student forgot to add heat.

Explanation:

If the test revealed it was not glucose, then the student could run these tests. The student, however, does not need these substances to run the glucose test properly.

How do covalent bonds form? A Sharing valence electrons between atoms. B Donating and receiving valence electrons between atoms. C Opposite slight charges attract each other between compounds. D Scientists are still not sure how they form.

Answers

Answer:

A. Sharing valence electrons between atoms.

Explanation:

This is the definition of a covalent bond. Option B describes ionic bonds, Option C describes intermolecular forces, and Option D is wrong because then there wouldn't be any mention of them in our high school chemistry textbooks :).  

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