Answer:
a) N2 (g) + H2 = 2 NH3
b) You have to state the mass of hydrogen
Define mass number of an atom.
Na2CO3 reacts with dil.HCl to produce NaCl, H2O and CO2. If 21.2 g of pure Na2CO3 are added in a solution containing 21.9g HCl , a. Find the limiting reagent. (2) b. Calculate the number of moles of excess reagent left over.(2) c. Calculate the number of molecules of H2O formed.(1) d. Calculate volume of CO2 gas produced at 270C and 760mm Hg pressure.(2) e. Write significance of limiting reagent
Answer:
See explanation
Explanation:
Equation of the reaction;
Na2CO3(aq) + 2HCl(aq) -------> 2NaCl(aq) + H2O(l) + CO2(g)
Number of moles of Na2CO3 = 21.2g/106g/mol = 0.2 moles Na2CO3
Number of moles of HCl = 21.9g/36.5g/mol = 0.6 moles of HCl
1 mole of Na2CO3 reacts with 2 moles of HCl
0.2 moles of Na2CO3 reacts with 0.2 × 2/1 = 0.4 moles of HCl
Hence Na2CO3 is the limiting reactant
Since there is 0.6 moles of HCl present, the number of moles of excess reagent=
0.6 moles - 0.4 moles = 0.2 moles of HCl
1 mole of Na2CO3 forms 1 mole of water
0.2 moles of Na2CO3 forms 0.2 moles of water
Number of molecules of water formed = 0.2 moles × 6.02 × 10^23 = 1.2 × 10^23 molecules of water
1 mole of Na2CO3 yields 1 mole of CO2
0.2 moles of Na2CO3 yields 0.2 moles of CO2
1 mole of CO2 occupies 22.4 L
0.2 moles of CO2 occupies 0.2 × 22.4 = 4.48 L at STP
Hence;
V1=4.48 L
T1 = 273 K
P1= 760 mmHg
T2 = 27°C + 273 = 300 K
P2 = 760 mmHg
V2 =
P1V1/T1 = P2V2/T2
P1V1T2 = P2V2T1
V2 = P1V1T2/P2T1
V2 = 760 × 4.48 × 300/760 × 273
V2= 4.9 L
The limiting reactant is the reactant that determines the amount of product formed in a reaction. When the limiting reactant is exhausted, the reaction stops.
(S)-Pentan-2-ol was treated sequentially with methanesulfonyl chloride (CH3SO2Cl) and then potassium iodide. What is the final product that forms
Answer:
(S)-Pentan-2-ol was treated sequentially with methanesulfonyl chloride (CH3SO2Cl) and then potassium iodide. What is the final product that forms
Explanation:
Alcohols are poor leaving groups.
To make -OH group a better-leaving group, it should be treated with sulfonyl chlorides.
Then, methane sulfonyl group makes will be substituted on the -OH group and forms sulfonyl esters and makes it a better leaving group.
After that treating with KI proceeds through nucleophilic bimolecular substitution and the final product formed is shown below:.
A student dropped a piece of nickel metal into a solution of HCl(aq). He observed the formation of gas bubbles and collected the gas into another test tube. The student performed a splint test and observed that the splint flared up when he placed the splint into the test tube of the gas. What can be said about the results of this students experiment?
a. The student performed the splint test incorrectly. He should of observed a popping sound when the splint was placed in the test tube.
b. The experiment was performed incorrectly. Nickel doesn't react with HCl. Therefore, the student picked up the wrong metal when conducting the experiment.
c. The student completed the experiment correctly and there were no errors in the experiment.
d. The student performed the splint test incorrectly. He should of observed the flame being extinguished when the splint was placed in the test tube.
Answer:
a. The student performed the splint test incorrectly. He should of observed a popping sound when the splint was placed in the test tube.
Explanation:
It is given that a student performed an experiment where he dropped a nickel metal in to HCl solution. He observed the reaction and performed a splint test in the test tube that is filled with a gas which is formed while Nickle is dropped into the solution of HCl.
But the experiment that the student performed was incorrect. He must have observed the popping sound when the splint was placed in the test tube.
When the splint was added to the gas splint flared up. The hydrogen gas pops out when exposed to the flame.
[tex]$Ni + HCl(aq) = NiCl + H_2$[/tex]
Thus the correct option is (a).
Explain why caffeine can be extracted from the tea leaves into hot water and how you extracted the aqueous solution and isolated the crude caffeine.
Answer:
The hot water dissolves the flavor and color components.
Explanation:
Caffeine can be extracted from the tea leaves into hot water because the hot water dissolves the flavor and color components away from the solid vegetable. This is an example of a solid-liquid extraction. We can extracted the aqueous solution and isolated the crude caffeine by converting the components of caffeine into their calcium salts which are insoluble in water. Then the caffeine can be extracted from the water by using methylene chloride.
14 protons,14 electrons and 14 neutrons
the answer is silicon!!
Water has a density of 1.00 g/mL. If you put an object that has a density of 0.79 g/mL into water, it will sink to the
bottom.
ANSWER:
True
False
Answer:
False
Explanation:
An object with a density greater than 1.00g/mL (greater than the density of water) will sink. An object with a density less than the density of water, will float.
If the water has a density of 1.00 g/mL. If you put an object that has a density of 0.79 g/mL into water, it will sink to the bottom, this statement is false.
What is density?The density of an actual content is its mass per unit volume. The most common symbol for density is d, but the Latin letter D can also be used.
Three of an object's most fundamental properties are mass, volume, and density. Mass describes how heavy something is, volume describes its size, and density is defined as mass divided by volume.
The density of something is a measure of how heavy it is in relation to its size. When an artifact is more dense than water, it plunges; when an object is less dense than water, it floats.
Density is a property of a substance that is independent of the amount of substance.
As in the given scenario, water is having density 1 g/mL and object in having density less then it so it will float on water.
Thus, the given statement is false as the material will not sink, rather it will float on water.
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a sample of copper was heated at 275.1 C and placed into 272 g of water at 21.0 C. The temperature of the water rose at 29.7 C. How many grams of copper were in the sample
Answer:
104.8 g
Explanation:
From the question given above, the following data were obtained:
Initial temperature of copper (T꜀) = 275.1 °C
Mass of water (Mᵥᵥ) = 272 g
Initial temperature of water (Tᵥᵥ) = 21 °C
Equilibrium temperature (Tₑ) = 29.7 °C
Mass of copper (M꜀) =?
NOTE:
Specific heat capacity of copper (C꜀) = 0.385 J/gºC
Specific heat capacity of water (Cᵥᵥ) = 4.184 J/gºC
Finally, we shall determine the mass of the copper in the sample. This can be obtained as follow:
Heat loss by copper = Heat gained by water
M꜀C꜀(T꜀ – Tₑ) = MᵥᵥCᵥᵥ(Tₑ – Tᵥᵥ)
M꜀ × 0.385 (275.1 – 29.7) = 272 × 4.184(29.7 – 21)
M꜀ × 0.385 × 245.4 = 1138.048 × 8.7
M꜀ × 94.479 = 9901.0176
Divide both side by 94.479
M꜀ = 9901.0176 / 94.479
M꜀ = 104.8 g
Thus, the mass of the copper in the sample is 104.8 g
What does the term spontaneous mean in chemical reactions?
A. Producing heat as a product
B. Occurring without added energy
C. Occurring only at high temperatures
D. Occurring in an aqueous solution
Answer:
B
Explanation:
Spontaneous in chemical reactions means without any external input.
Occurring without added energy. Hence, option B is correct.
What is a spontaneous reaction?A spontaneous reaction is a reaction that supports the formation of products under the conditions under which the reaction is happening.
Spontaneous Reaction- a reaction that favours the formation of products at the conditions under which the reaction is occurring.
A non-spontaneous reaction can be made spontaneous if it is inside a controlled environment, this is what happens in nuclear power plants that create atomic fusion and fission in chambers that are controlled to control different particles to create nuclear active rays.
Hence, option B is correct.
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Match the description with the type of precipitation being described.
1. Its formation requires very strong updrafts
2. Its formation requires falling through a layer of above freezing air
3. Precipitation from cumuliform clouds is typically of this nature
4. Precipitation from stratus clouds is typically of this nature
Options:
a. Hail
b. Drizzle
c. Shower
d. Freezing Rain
Answer:
1. Its formation requires very strong updrafts = a. Hail
2. Its formation requires falling through a layer of above-freezing air = d. Freezing Rain
3. Precipitation from cumuliform clouds is typically of this nature = c. Shower
4. Precipitation from stratus clouds is typically of this nature = Drizzle
Explanation:
Hail formation requires very strong updrafts, these updrafts are the upward moving air created in a thunderstorm. This period of noticeable thunderstorms creates hails.
Freezing rain requires the presence of warm air, it requires falling through a layer of above-freezing air to the colder air below to produce an ice coating on anything it drops on.
Showers are produced by cumuliform clouds which look like cotton balls. Since cumuliform clouds precipitate too, these clouds can have fluctuating rain in a day in the form of showers.
Drizzle which raises low visibility is considered a type of liquid precipitation since it also falls from a cloud. Drizzle which is obviously smaller in diameter when compared to that of raindrops, however, is common with stratus clouds.
According to the Arrhenius equation, changing which factors will affect the
rate constant?
A. Temperature and the ideal gas constant
B. The activation energy and the constant A
C. The constant A and the temperature
D. Temperature and activation energy
Answer:
e−(Ea/RT): the fraction of the molecules present in a gas which have energies equal to or in excess of activation energy at a particular temperature
Answer:
D. Temperature and activation energy is the correct answer
Explanation:
^_^
You are stowing items and come across an aerosol bottle of hairspray. What should you do? Please choose all that apply
Answer:stow the hairspray
Explanation:
After standardizing a NaOH solution, you use it to titrate an HCl solution known to have a concentration of 0.203 M. You perform five titrations and obtain the following results: 0.210, 0.204, 0.201, 0.202, and 0.197 M. a) What is the mean
Answer:
0.203 is the mean of the concentration of the HCl solution
Explanation:
You have 5 concentrations. The most appropiate result is the mean of those results. The mean is a statistical defined as the sum of each result divided by the total amount of results. For the results of the problem, the mean is:
0.210 + 0.204 + 0.201 + 0.202 + 0.197 = 1.014 / 5 =
0.203 is the mean of the concentration of the HCl solutionWhich of the following molecules can be used in catabolic reactions to generate the carbon backbones required for gluconeogenesis?
a. glutathione, a short peptide containing glutamate, serine and histidine
b. butyrate, a short chain fatty acid
c. fructose, a monosaccharide
d. starch, a polysaccharide
Answer:
The correct option is A
Explanation:
Some amino acids, called glucogenic amino acids, when catabolized convert there carbon backbones to tricarboxylic acid (TCA) cycle intermediates. These intermediates can be subsequently metabolized into carbon dioxide and water with the release of ATP or the formation of glucose (known as gluconeogenesis.
All amino acids (with the exception of leucine and lysine) are glucogenic and can thus generate the carbon backbones required for gluconeogenesis. Thus, the correct option is a.
How much energy is required to melt 2 kg of gold? Use the table below and this equation.
a. 125.6 kJ
b. 1729 kJ
c. 10.4 kJ
d. 3440kJ
The equation for the energy required to melt 2 kg of gold is 3440 kJ.
What is energy?Energy is the ability to do work or cause change. It is an essential part of everyday life and is present in many forms, such as thermal energy, electrical energy, chemical energy, and mechanical energy. Energy can be converted from one form to another in order to do work.
The equation for calculating the energy required to melt a certain mass of material is Q = m x Lf, where Q is the energy required (in joules), m is the mass of the material (in kilograms), and Lf is the latent heat of fusion (in joules per kilogram).
Using the table below, we can see that the latent heat of fusion for gold is 1760 kJ/kg. Therefore, the equation for the energy required to melt 2 kg of gold is: Q = 2 kg x 1760 kJ/kg = 3440 kJ.
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What is different between margerine and butter in term of organic chemistry
Answer:
The most important difference between the two is that butter is derived from dairy and is rich in saturated fats, whereas margarine is made from plant oils. ... If the margarine contains partially hydrogenated oils, it will contain trans fat, even if the label claims that it has 0 g.
Explanation:
(⌒_⌒;)
In a closed system, If a gas is transported to a container with double the volume of the previous container, the gas was held in, what is the gases' new volume?
The volume of the gas is fixed and will not change.
The volume of the gas will be half the original volume.
The volume of the gas will be the original volume squared.
The volume of the gas will be double the original volume.
Answer:
The volume of the gas is fixed and will not change.
Explanation:
The volume of the gas will not change because there is no change in temperature. Temperature increases the volume of gases enclosed in a container.
EXTRACTION OF CAFFEINE 1.Explain the reason each step of the separation is performed with three portions of the solvent rather than with a single portion of solvent. (e.g. Done in triplicate.) (0.5 pt) 2.Why should a separatory funnel not be vigorously shaken
Answer:
Throughout the explanations section below you will find a description of the question.
Explanation:
(1)
Whether a solution would be positioned inside a separative funnel, combined water, as well as solvent, disintegrate particulate caffeine. In every stage, the caffeine content incorporated relies upon the coefficient of caffeine partitioning throughout the combination of water as well as fluid.Thus, increasingly caffeine is taken from the solvent whenever the moment you bring additional solvent. Consequently, we separate the solvent from the single component.(2)
For compounds to be mixed thoroughly and separated into different layers, a shuddering mixture within the dividing funnel would be essential.However, it vibrates the separation funnel forcefully, restricts airflow within the funnel, which can also induce the fluid under it to burst or causing fluid to fire.Perform the following operation and express the answer in scientific notation.
7.296×10² ÷ 9.6×10^-9
Answer:
7.6×10¹⁰
Explanation:
7.296×10²÷9.6×10⁻⁹
To solve such problem,
We group the whole number ans solved seperately and also group the indices and solve the seperately
Step1 : 7.296/9.6 = 0.76
Step 2: applying the law of indices,
10²÷10⁻⁹ = 10⁽²⁺⁹⁾ = 10¹¹
Therefore,
7.296×10²÷9.6×10⁻⁹ = 0.76×10¹¹ = 7.6×10¹⁰
How many molecules in each sample?
64.7 g N2
83 g CCl4
19 g C6H12O6
Answer:
1.39x10²⁴ molecules N₂.25x10²³ molecules CCl₄6.38x10²² molecules C₆H₁₂O₆Explanation:
First we convert the given masses into moles, using the compounds' respective molar mass:
64.7 g N₂ ÷ 28 g/mol = 2.31 mol N₂83 g CCl₄ ÷ 153.82 g/mol = 0.540 mol CCl₄19 g C₆H₁₂O₆ ÷ 180 g/mol = 0.106 mol C₆H₁₂O₆Then we multiply each amount by Avogadro's number, to calculate the number of molecules:
2.31 mol N₂ * 6.023x10²³ molecules/mol = 1.39x10²⁴ molecules0.540 mol CCl₄ * 6.023x10²³ molecules/mol = 3.25x10²³ molecules0.106 mol C₆H₁₂O₆ * 6.023x10²³ molecules/mol = 6.38x10²² moleculesIf 0.21J of heat cause a 0.308 degree C temperature change, what mass of water is present?
a 0.0702 g
b 0.00540 g
c 0.163 g
d 18.4 g
Answer:
The correct answer is Option c (0.163 g).
Explanation:
Given:
Heat energy,
Q = 0.21 J
Specific heat,
c = 4.184 J/g°c
Change in temperature,
ΔT = 0.308°C
As we know,
⇒ [tex]Q=mc \Delta T[/tex]
By substituting the values, we get
[tex]0.21=m\times 4.184\times 0.308[/tex]
[tex]m=\frac{0.21}{0.308\times 4.184}[/tex]
[tex]=\frac{0.21}{1.28867}[/tex]
[tex]=0.163 \ g[/tex]
7.23 One equivalent of sodium methanethiolate is added to an electrophile that has two leaving groups. Which product will be major
The question is incomplete, the complete question is shown in the image attached to this answer
Answer:
A
Explanation:
We can see from the conditions of the reaction that the incoming nucleophile is -SCH3 and there are two possible leaving groups in the substrate.
First of all, we have to look at the conditions of the reaction. We can see that the reaction is taking place in DMF, a polar aprotoc solvent. This condition favours the SN2 synchronous mechanism over the SN1 ionic mechanism.
Hence, the nucleophile at the 1-position is preferentially substituted owing to the conditions of the reaction.
Thus, option A is the major product of the reaction.
what is the mass of insoluble calcium phosphate produced from .555 grams of calcium chloride
Answer:
0.518 g
Explanation:
Step 1: Write the balanced equation
3 CaCl₂ + 2 H₃PO₄ ⇒ Ca₃(PO₄)₂ + 6 HCl
Step 2: Calculate the moles corresponding to 0.555 g of CaCl₂
The molar mass of CaCl₂ is 110.98 g/mol.
0.555 g × 1 mol/110.98 g = 5.00 × 10⁻³ mol
Step 3: Calculate the moles of Ca₃(PO₄)₂ produced
5.00 × 10⁻³ mol CaCl₂ × 1 mol Ca₃(PO₄)₂/3 mol CaCl₂ = 1.67 × 10⁻³ mol Ca₃(PO₄)₂
Step 4: Calculate the mass corresponding to 1.67 × 10⁻³ moles of Ca₃(PO₄)₂
The molar mass of Ca₃(PO₄)₂ is 310.18 g/mol.
1.67 × 10⁻³ mol × 310.18 g/mol = 0.518 g
Methyl orange can change color by transitioning from one chromophore to another. When added to a clear solution and the solution turns red, it is determined to be a(n) __________ in its __________ stable form.
Answer:
acidic titration in its stable form
Explanation:
Methyl orange can change its color in titration solution. The yellow color is towards alkaline solution and red color is towards acidic solution. The Ph value of solution will change during this chemical process.
The tools shown in the diagram are used for gardening Each tool is made up
of two levers that are attached to each other. The handles are the input arms,
and the cutting blades are the output armo
Hand shears
Lopper
Which tool has a greater mechanical advantage, and why?
A. The lopper, because the input work is the same as the output work
B. The hand shears, because their shorter handles transfer force
more quickly to the cutting blade
C. The hand shears, because you can apply less total force to the
handles with one hand
D. The lopper, because its longer handles can produce more output
force with less input force
Answer:
D
Explanation:
The longer handles distribute the force across a longer distance.
Consider the titration of 30 mL of 0.030 M NH3 with 0.025 M HCl. Calculate the pH after the following volumes of titrant have been added: a) 0 mL; b) 10 mL; c) 20 mL; d)35 mL; e) 36 mL; f) 37 mL.
Answer:
a)10.87
b)9.66
c)9.15
d)7.71
e) 5.56
f) 3.43
Explanation:
tep 1: Data given
Volume of 0.030 M NH3 solution = 30 mL = 0.030 L
Molarity of the HCl solution = 0.025 M
Step 2: Adding 0 mL of HCl
The reaction: NH3 + H2O ⇔ NH4+ + OH-
The initial concentration:
[NH3] = 0.030M [NH4+] = 0M [OH-] = OM
The concentration at the equilibrium:
[NH3] = 0.030 - XM
[NH4+] = [OH-] = XM
Kb = ([NH4+][OH-])/[NH3]
1.8*10^-5 = x² / 0.030-x
1.8*10^-5 = x² / 0.030
x = 7.35 * 10^-4 = [OH-]
pOH = -log [7.35 * 10^-4]
pOH = 3.13
pH = 14-3.13 = 10.87
Step 3: After adding 10 mL of HCl
The reaction:
NH3 + HCl ⇔ NH4+ + Cl-
NH3 + H3O+ ⇔ NH4+ + H2O
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.010 L = 0.00025 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.00025 =0.00065 moles
Moles HCl = 0
Moles NH4+ = 0.00025 moles
Concentration at the equilibrium:
[NH3]= 0.00065 moles / 0.040 L = 0.01625M
[NH4+] = 0.00625 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.00625/0.01625)
pOH = 4.34
pH = 9.66
Step 3: Adding 20 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.020 L = 0.00050 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.00050 =0.00040 moles
Moles HCl = 0
Moles NH4+ = 0.00050 moles
Concentration at the equilibrium:
[NH3]= 0.00040 moles / 0.050 L = 0.008M
[NH4+] = 0.01 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.01/0.008)
pOH = 4.85
pH = 14 - 4.85 = 9.15
Step 4: Adding 35 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.035 L = 0.000875 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.000875 =0.000025 moles
Moles HCl = 0
Moles NH4+ = 0.000875 moles
Concentration at the equilibrium:
[NH3]= 0.000025 moles / 0.065 L = 3.85*10^-4M
[NH4+] = 0.000875 M / 0.065 L = 0.0135 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.0135/3.85*10^-4)
pOH = 6.29
pH = 14 - 6.29 = 7.71
Step 5: adding 36 mL HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.036 L = 0.0009 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.0009 =0 moles
Moles HCl = 0
Moles NH4+ = 0.0009 moles
[NH4+] = 0.0009 moles / 0.066 L = 0.0136 M
Kw = Ka * Kb
Ka = 10^-14 / 1.8*10^-5
Ka = 5.6 * 10^-10
Ka = [NH3][H3O+] / [NH4+]
Ka =5.6 * 10^-10 = x² / 0.0136
x = 2.76 * 10^-6 = [H3O+]
pH = -log(2.76 * 10^-6)
pH = 5.56
Step 6: Adding 37 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.037 L = 0.000925 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.000925 =0 moles
Moles HCl = 0.000025 moles
Concentration of HCl = 0.000025 moles / 0.067 L = 3.73 * 10^-4 M
pH = -log 3.73*10^-4= 3.43
The pH of the solution in the titration of 30 mL of 0.030 M NH₃ with 0.025 M HCl, is:
a) pH = 10.86
b) pH = 9.66
c) pH = 9.15
d) pH = 7.70
e) pH = 5.56
f) pH = 3.43
Calculating the pH a) 0 mL
Initially, the pH of the solution is given by the dissociation of NH₃ in water.
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻ (1)
The constant of the above reaction is:
[tex] Kb = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]} = 1.76\cdot 10^{-5} [/tex] (2)
At the equilibrium, we have:
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻ (3)
0.030 M - x x x
[tex] 1.76\cdot 10^{-5}*(0.030 - x) - x^{2} = 0 [/tex]
After solving for x and taking the positive value:
x = 7.18x10⁻⁴ = [OH⁻]
Now, we can calculate the pH of the solution as follows:
[tex] pH = 14 - pOH = 14 + log(7.18\cdot 10^{-4}) = 10.86 [/tex]
Hence, the initial pH is 10.86.
b) 10 mL
After the addition of HCl, the following reaction takes place:
NH₃ + HCl ⇄ NH₄⁺ + Cl⁻ (4)
We can calculate the pH of the solution from the equilibrium reaction (3).
[tex] 1.76\cdot 10^{-5}(Cb - x) - (Ca + x)*x = 0 [/tex] (5)
Finding the number of moles of NH₃ and NH₄⁺
The number of moles of NH₃ (nb) and NH₄⁺ (na) are given by:
[tex] n_{b} = n_{i} - n_{HCl} [/tex] (6)
[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.010 L = 6.5\cdot 10^{-4} moles [/tex]
[tex] n_{a} = n_{HCl} [/tex] (7)
[tex] n_{a} = 0.025 mol/L*0.010 L = 2.5 \cdot 10^{-4} moles [/tex]
Calculating the concentrations of NH₃ and NH₄⁺The concentrations are given by:
[tex] Cb = \frac{6.5\cdot 10^{-4} moles}{(0.030 L + 0.010 L)} = 0.0163 M [/tex] (8)
[tex] Ca = \frac{2.5 \cdot 10^{-4} mole}{(0.030 L + 0.010 L)} = 6.25 \cdot 10^{-3} M [/tex] (9)
Calculating the pHAfter entering the values of Ca and Cb into equation (5) and solving for x, we have:
[tex] 1.76\cdot 10^{-5}(0.0163 - x) - (6.25 \cdot 10^{-3} + x)*x = 0 [/tex]
x = 4.54x10⁻⁵ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(4.54\cdot 10^{-5}) = 9.66 [/tex]
Hence, the pH is 9.66.
c) 20 mLWe can find the pH of the solution from the reaction of equilibrium (3).
Calculating the concentrations of NH₃ and NH₄⁺The concentrations are (eq 8 and 9):
[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 8.0\cdot 10^{-3} M [/tex]
[tex] Ca = \frac{0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 0.01 M [/tex]
Calculating the pHAfter solving the equation (5) for x, we have:
[tex] 1.76\cdot 10^{-5}(8.0\cdot 10^{-3} - x) - (0.01 + x)*x = 0 [/tex]
x = 1.40x10⁻⁵ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(1.40\cdot 10^{-5}) = 9.15 [/tex]
So, the pH is 9.15.
d) 35 mLWe can find the pH of the solution from reaction (3).
Calculating the concentrations of NH₃ and NH₄⁺[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 3.85\cdot 10^{-4} M [/tex]
[tex] Ca = \frac{0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 0.0135 M [/tex]
Calculating the pHAfter solving the equation (5) for x, we have:
[tex] 1.76\cdot 10^{-5}(3.85\cdot 10^{-4} - x) - (0.0135 + x)*x = 0 [/tex]
x = 5.013x10⁻⁷ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(5.013\cdot 10^{-7}) = 7.70 [/tex]
So, the pH is 7.70.
e) 36 mL Finding the number of moles of NH₃ and NH₄⁺[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.036 L = 0 [/tex]
[tex] n_{a} = 0.025 mol/L*0.036 L = 9.0 \cdot 10^{-4} moles [/tex]
Since all the NH₃ reacts with the HCl added, the pH of the solution is given by the dissociation reaction of the NH₄⁺ produced in water.
At the equilibrium, we have:
NH₄⁺ + H₂O ⇄ NH₃ + H₃O⁺
Ca - x x x
[tex] Ka = \frac{x^{2}}{Ca - x} [/tex]
[tex] Ka(Ca - x) - x^{2} = 0 [/tex] (10)
Calculating the acid constant of NH₄⁺
We can find the acid constant as follows:
[tex] Kw = Ka*Kb [/tex]
Where Kw is the constant of water = 10⁻¹⁴
[tex] Ka = \frac{1\cdot 10^{-14}}{1.76 \cdot 10^{-5}} = 5.68 \cdot 10^{-10} [/tex]
Calculating the pH
The concentration of NH₄⁺ is:
[tex] Ca = \frac{9.0 \cdot 10^{-4} moles}{(0.030 L + 0.036 L)} = 0.0136 M [/tex]
After solving the equation (10) for x, we have:
x = 2.78x10⁻⁶ = [H₃O⁺]
Then, the pH is:
[tex] pH = -log(H_{3}O^{+}) = -log(2.78\cdot 10^{-6}) = 5.56 [/tex]
Hence, the pH is 5.56.
f) 37 mLNow, the pH is given by the concentration of HCl that remain in solution after reacting with NH₃ (HCl is in excess).
Calculating the concentration of HCl
[tex] C_{HCl} = \frac{0.025 mol/L*0.037 L - 0.030 mol/L*0.030 L}{(0.030 L + 0.037 L)} = 3.73 \cdot 10^{-4} M = [H_{3}O^{+}] [/tex]
Calculating the pH
[tex] pH = -log(H_{3}O^{+}) = -log(3.73 \cdot 10^{-4}) = 3.43 [/tex]
Therefore, the pH is 3.43.
Find more about pH here:
brainly.com/question/491373
I hope it helps you!
Calculate the average atomic mass for X
Answer:
39.0229 amu
Explanation:
Hello there!
In this case, according to given information, the idea here is to multiply the percent abundance by the mass number of each isotope and then add them all together as shown below:
[tex]=0.0967*38+0.7868*39+0.1134*40+0.0031*41\\\\=3.6746+30.6852+4.536+0.1271\\\\=39.0229amu[/tex]
Regards!
Question 4 of 30
Scientific research shows that Earth's climate is changing due to human
activities. How can scientific research on climate change help society?
A. It can help us stop storms before they occur.
B. It can help us find a new way to make more water.
C. It can help us track how quickly elements of the climate are
changing
D. It can help us reverse the effects of climate change.
th
C. It can help us track how quickly element of the climate are changing
Using the balanced equation for the combustion of ethane: 2C2H6 + 7O2 → 4CO2 + 6H2O, how many moles of O2 needed to produce 12 moles of H2O?
Answer:
14 moles of oxygen needed to produce 12 moles of H2O.
Explanation:
We are given that balance eqaution
[tex]2C_2H_6+7O_2\rightarrow 4CO_2+6H_2O[/tex]
We have to find number of moles of O2 needed to produce 12 moles of H2O.
From given equation
We can see that
6 moles of H2O produced by Oxygen =7 moles
1 mole of H2O produced by Oxygen=[tex]\frac{7}{6}[/tex]moles
12 moles of H2O produced by Oxygen=[tex]\frac{7}{6}\times 12[/tex]moles
12 moles of H2O produced by Oxygen=[tex]7\times 2[/tex]moles
12 moles of H2O produced by Oxygen=14 moles
Hence, 14 moles of oxygen needed to produce 12 moles of H2O.
The amount of oxygen required for the combustion of ethane to produce 12 moles of water is 14 moles.
How are the moles produced in reaction calculated?The moles of oxygen produced in the reaction can be given from the stoichiometric law of the balanced chemical equation.
The balanced chemical equation for the combustion of ethane is:
[tex]\rm 2\;C_2H_6\;+\;7\;O_2\;\rightarrow\;4\;CO_2\;+\;6\;H_2O[/tex]
The 6 moles of water are produced from 7 moles of oxygen. The moles of oxygen required to produce 12 moles of water are:
[tex]\rm 6\;mol\;H_2O=7\;mol\;Oxygen\\12\;mol\;H_2O=\dfrac{7}{6}\;\times\;12\;mol\;O_2\\ 12\;mol\;H_2O=14\;mol\;O_2[/tex]
The moles of oxygen required to produce 12 moles of water are 14 moles.
Learn more about moles produces, here:
https://brainly.com/question/10606802
The pKa of an acid can be determined through _____ (reduction, titration, filtration) with a strong base.
Gradually increase the volume of the base, stopping _____ (before, as, after) the equivalence point is reached.
The pKa of the acid is equal to the pH at the _____ (equivalence point, midway volume to the equivalence point, maximum volume).
Answer:
The pKa of an acid can be determined through titration with a strong base.
Gradually increase the volume of the base, stopping before the equivalence point is reached.
The pKa of the acid is equal to the pH at the midway volume to the equivalence point.
Explanation:
An acid HA dissociates in water as follows:
HA ⇄ H⁺ + A⁻ Ka
So, it produces hydrogen ions (H⁺) and a conjugate base (A⁻). The concentrations of HA, H⁺ and A⁻ at equilibrium determine the constant Ka. The pKa is calculated as:
pKa = -log Ka
The relationship between the pH of the solution and the pKa of the acid is described by the Henderson-Hasselbalch equation:
pH = pKa + log ([A⁻]/[HA])
The pKa can be experimentally determined by acid-base titration, in which a strong base is added to the acid solution. As the base is added, the acid HA is neutralized and the conjugate base A⁻ is formed. Thus, the concentration of the acid ([HA]) increases and the concentration of the conjugate base ([A⁻] decreases. The equivalence point is reached when the total amount of acid is neutralized with the added base. Before reaching the equivalence point, at the halfway point, half of the acid is neutralized and converted into the conjugate base. Thus:
[A-] = [HA] ⇒ log [A-]/[HA] = log 1 = 0 ⇒ pH = pKa
We measure the pH at that point and it is equal to the pKa of the acid.
