A quantity of liquid methanol, CH 3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500K. At this temperature, the methanol vaporizes and decomposes according to the reaction CH 3OH(g) CO(g) + 2 H 2(g), K c= 6.90×10 –2. If the concentration of H 2 in the equilibrium mixture is 0.426M, what mass of methanol was initially introduced into the vessel?

Answers

Answer 1

Answer:

74.3g of methanol were introduced into the vessel

Explanation:

In the equilibrium:

CH₃OH(g) ⇄ CO(g) + 2H₂(g)

Kc is defined as the ratio between concentrations in equilibrium of :

Kc = 6.90x10⁻² = [CO] [H₂]² / [CH₃OH]

Some methanol added to the vessel will react producing H₂ and CO. And equilibrium concentrations must be:

[CH₃OH] = ? - X

[CO] = X

[H₂] = 2X

Where ? is the initial concentration of methanol

As [H₂] = 2X = 0.426M; X = 0.213M

[CH₃OH] = ? - 0.213M

[CO] = 0.213M

[H₂] = 0.426M

Replacing in Kc to solve equilibrium concentration of methanol:

6.90x10⁻² = [0.213] [0.426]² / [CH₃OH]

[CH₃OH] = 0.560

As:

[CH₃OH] = ? - 0.213M = 0.560M

? = 0.773M

0.7733M was the initial concentration of methanol. As volume of vessel is 3.00L, moles of methanol are:

3.00L * (0.773 mol / L) = 2.319 moles methanol.

Using molar mass of methanol (32.04g/mol), initial mass of methanol added was:

2.319 moles * (32.04g / mol) =

74.3g of methanol were introduced into the vessel

Related Questions

A sample of ice absorbs 15.6kJ of heat as it undergoes a reversible phase transition to form liquid water at 0∘C. What is the entropy change for this process in units of JK? Report your answer to three significant figures. Use −273.15∘C for absolute zero.

Answers

Answer:

Entropy change of ice changing to water at 0°C is equal to 57.1 J/K

Explanation:

When a substance undergoes a phase change, it occurs at constant temperature.

The entropy change Δs, is given by the formula below;

Δs = q/T

where q is the quantity of heat absorbed or evolved in Joules and T is temperature in Kelvin at which the phase change occur

From the given data, T = 0°C = 273.15 K, q = 15.6 KJ = 15600 J

Δs = 15600 J / 273.15 K

Δs = 57.111 J/K

Therefore, entropy change of ice changing to water at 0°C is equal to 57.1 J/K

The entropy change of ice changing to water will be "57.1 J/K".

Entropy change

The shift in what seems like a thermodynamic system's condition of confusion is caused by the transformation of heat as well as enthalpy towards activity. Entropy seems to be greater mostly in a network with a high quantity or measure of chaos.

According to the question,

Temperature, T = 0°C or,

                          = 273.15 K

Heat, q = 15.6 KJ or,

            = 15600 J

We know the formula,

Entropy change, Δs = [tex]\frac{q}{T}[/tex]

By substituting the values, we get

                                 = [tex]\frac{15600}{273.15}[/tex]

                                 = 57.11 J/K

Thus the above answer is correct.    

Find out more information about Entropy change here:

https://brainly.com/question/6364271

A sailor on a trans-Pacific solo voyage notices one day that if he puts 735.mL of fresh water into a plastic cup weighing 25.0g, the cup floats in the seawater around his boat with the fresh water inside the cup at exactly the same level as the seawater outside the cup (see sketch at right).

Calculate the amount of salt dissolved in each liter of seawater. Be sure your answer has a unit symbol, if needed, and round it to 2 significant digits.

You'll need to know that the density of fresh water at the temperature of the sea around the sailor is 0.999/gcm3. You'll also want to remember Archimedes' Principle, that objects float when they displace a mass of water equal to their own mass.

Answers

Answer:

Amount of salt in 1 L seawater = 34 g

Explanation:

According to Archimedes' principle, mass of freshwater and cup = mass of equal volume of seawater

mass of freshwater = density * volume

1 cm³ = 1 mL

mass of freshwater = 0.999 g/cm³ * 735 cm³ = 734.265 g

mass of freshwater + cup = 734.265 + 25 = 759.265 g

Therefore,  mass of equal volume of seawater = 759.265 g

Volume of seawater displaced = 735 mL = 0.735 L (assuming the cup volume is negligible)

1 liter = 1000 cm³ = 1000 mL;

Density of seawater = mass / volume

Density of seawater = 759.265 g / 0.735 L = 1033.01 g/L

Density of freshwater in g/L = 0.999 g/ (1/1000) L = 999 g/L

mass of 1 Liter seawater = 1033.01 g

mass of 1 Liter freshwater = 999 g

mass of salt dissolved in 1 L of seawater = 1033.01 g - 999 g = 34.01 g

Therefore, amount of salt in 1 L seawater = 34 g

For the following reaction, 61.6 grams of bromine are allowed to react with 25.5 grams of chlorine gas. bromine (g) + chlorine (g) bromine monochloride (g) What is the maximum amount of bromine monochloride that can be formed? grams

Answers

Answer:

I need great answers

Explanation:

please rate my answer as great

How many mL of a 0.130 M aqueous solution of chromium(II) nitrate, Cr(NO3)2, must be taken to obtain 5.08 grams of the salt

Answers

Answer:

222.3 ml of a 0.130 M aqueous solution of chromium (II) nitrate must be taken to obtain 5.08 grams of the salt.

Explanation:

Being:

Cr: 52 g/moleN: 14 g/moleO: 16 g/mole

the molar mass of chromium (II) nitrate, Cr(NO₃)₂ is:

Cr(NO₃)₂ = 52 g/mole + 2* (14 g/mole + 3* 16 g/mole)= 176 g/mole

So: if 176 grams are present in 1 mole of the compound, 5.08 grams in how many moles of the compound will be present?

[tex]amount of moles=\frac{5.08 grams* 1 mole}{176 grams}[/tex]

amount of moles=0.0289 moles

Molarity (M) is the number of moles of solute that are dissolved in a given volume. It is then calculated by dividing the moles of the solute by the volume of the solution:

[tex]molarity (M)=\frac{number of moles of solute}{volume}[/tex]

Molarity is expressed in [tex]\frac{moles}{liter}[/tex]

So in this case:

molarity= 0.130 Mnumber of moles of solute= 0.0289 molesvolume= ?

Replacing:

[tex]0.130 M=0.130 \frac{moles}{liter} =\frac{0.0289 moles}{volume}[/tex]

Solving:

[tex]volume=\frac{0.0289 moles}{0.130 \frac{moles}{liter} }[/tex]

volume=0.2223 liters

Being 1 L= 1,000 mL:

volume=0.222 liters= 222.3 mL

222.3 ml of a 0.130 M aqueous solution of chromium (II) nitrate must be taken to obtain 5.08 grams of the salt.

A 30.5 g sample of a compound contains 9.29 g of nitrogen and the rest is oxygen. What is the empirical formula of the compound?

Answers

Answer:

The empirical formula of the compound is NO2.

Explanation:

The following data were obtained from the question:

Mass of compound = 30.5 g

Mass of nitrogen (N) = 9.29 g

Empirical formula of compound =?

Next, we shall determine the mass of oxygen in the compound. This can be obtained as follow:

Mass of compound = 30.5 g

Mass of nitrogen (N) = 9.29 g

Mass of oxygen (O) =?

Mass of O = mass of compound – mass of N.

Mass of O = 30.5 – 9.29

Mass of O = 21.21 g

Finally, we shall determine the empirical formula of the compound as follow:

Mass of nitrogen (N) = 9.29 g

Mass of oxygen (O) = 21.21 g

Divide by their molar mass.

N = 9.29 / 14 = 0.664

O = 21.21 / 16 = 1.326

Divide by the smallest

N = 0.664/ 0.664 = 1

O = 1.326/ 0.664 = 2

Therefore the empirical formula of the compound is NO2.

Which of the following chemical equations corresponds to the standard molar enthalpy of formation of Na_2CO_3(s)?
a. 2 NA(s) + C(s) + 3 O(g) ------------> Na_2CO_3(s)
b. Na_2O(s) + CO_2(g) --------------->Na_2CO_3 (s)
c. Na_2(s) + C(s) + 3 O(g) -------------> Na_2CO_3 (s)
d. Na_2O(s) + CO(g) ---------------> Na_2CO_3(s)
e. 2 Na(s)+ C(s) + 3/2 O_2(g) ------------> Na_2CO_3(s)

Answers

Answer:

2 Na(s) + C(s) + 3/2 O₂(g) → Na₂CO₃(s)

Explanation:

The molar enthalpy of formation of a chemical is defined as the change in enthalpy during the formation of 1 mole of the substance from its constituent elements (Constituent elements are pure elements you have in the periodic table)

For Na₂CO₃ constituent elements are Na(s), C(s) and O₂(g) and the chemical equation that represents the molar enthalpy is:

2 Na(s) + C(s) + 3/2 O₂(g) → Na₂CO₃(s)

A 0.100 M solution of NaOH is used to titrate an HCl solution of unknown concentration. To neutralize the solution, an average volume of the titrant was 38.2 mL. The starting volume of the HCl solution was 20 mL. What's the concentration of the HCl? answer options: A) 0.788 M B) 0.284 M C) 3.34 M D) 0.191 M

Answers

Answer: it is A

Explanation: I am sure

Answer:

0.191 M

Explanation:

i took the test.

i) Briefly discuss the strengths and weaknesses of the four spectroscopy techniques listed below. Include in your answer the specific structural information you get from each method.
 IR
 UV-VIS
 NMR
 Mass Spec

Answers

delete please .....................................

A galvanic cell consists of a Cu(s)|Cu2+(aq) half-cell and a Cd(s)|Cd2+(aq) half-cell connected by a salt bridge. Oxidation occurs in the cadmium half-cell. The cell can be represented in standard notation as

Answers

Answer:

[tex]Cd(s)|Cd^{2+}(aq) || Cu^{2+}(aq)|Cu(s)[/tex]

Explanation:

A galvanic cell is composed of two electrodes immersed in a suitable electrolyte and connected via a salt bridge. One of the electrodes serves as a cathode where reduction or gain of electrons takes place. The other half cell functions as an anode where oxidation or loss of electrons occurs.

The representation is given by writing the anode on left hand side followed by its ion with its molar concentration. It is followed by a salt bridge. Then the cathodic ion with its molar concentration is written and then the cathode.

As it is given that cadmium acts as anode, it must be on the left hand side and copper must be on right hand side.

[tex]Cd(s)|Cd^{2+}(aq) || Cu^{2+}(aq)|Cu(s)[/tex]

The compound methylamine, CH3NH2, is a weak base when dissolved in water. Write the Kb expression for the weak base equilibrium that occurs in an aqueous solution of methylamine:

Answers

Answer:

Kb = [CH₃NH₃⁺] × [OH⁻] / [CH₃NH₂]

Explanation:

According to Brönsted-Lowry acid-base theory:

An acid is a substance that donates H⁺.A base is a substance that accepts H⁺.

When methylamine reacts with water, it behaves as a Brönsted-Lowry base, according to the following reaction.

CH₃NH₂(aq) + H₂O(l) ⇄ CH₃NH₃⁺(aq) + OH⁻(aq)

The basic equilibrium constant (Kb) is:

Kb = [CH₃NH₃⁺] × [OH⁻] / [CH₃NH₂]

What is the pOH of a solution at 25.0∘C with [H3O+]=4.8×10−6 M?

Answers

Answer:

8.68

Explanation:

pOH = 8.68

all you need is contained in the sheet

Answer:

Approximately [tex]8.68[/tex].

Explanation:

The [tex]\rm pOH[/tex] of a solution can be found from the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] with the following equation:

[tex]\displaystyle \rm pOH = -\log_{10} \rm \left[OH^{-}\right][/tex].

On the other hand, the ion-product constant of water, [tex]K_{\text{w}}[/tex], relates the hydroxide ion concentration [tex]\rm \left[OH^{-}\right][/tex] of a solution to its hydronium ion concentration [tex]\rm \left[{H_3O}^{+}\right][/tex]:

[tex]K_\text{w} = \rm \left[{H_3O}^{+}\right] \cdot \rm \left[OH^{-}\right][/tex].

At [tex]25 \; ^\circ \rm C[/tex], [tex]K_{\text{w}} \approx 1.0 \times 10^{-14}[/tex]. For this particular [tex]25 \; ^\circ \rm C[/tex] solution, [tex]\rm \left[{H_3O}^{+}\right] = 4.8 \times 10^{-6}\; \rm mol \cdot L^{-1}[/tex].

Hence the [tex]\rm \left[OH^{-}\right][/tex] of this solution:

[tex]\begin{aligned}\left[\mathrm{OH}^{-}\right] &= \frac{K_\text{w}}{\rm \left[{H_3O}^{+}\right]} \\ &= \frac{1.0 \times 10^{-14}}{4.8 \times 10^{-6}}\; \rm mol\cdot L^{-1} \approx 2.08333 \times 10^{-9}\; \rm mol\cdot L^{-1}\end{aligned}[/tex].

Therefore, the [tex]\rm pOH[/tex] of this solution would be:

[tex]\begin{aligned}\rm pOH &= -\log_{10} \rm \left[OH^{-}\right] \\ &\approx -\log_{10} \left(4.8 \times 10^{-6}\right) \approx 8.68\end{aligned}[/tex].

Note that by convention, the number of decimal places in [tex]\rm pOH[/tex] should be the same as the number of significant figures in [tex]\rm \left[OH^{-}\right][/tex].

For example, because the [tex]\rm \left[{H_3O}^{+}\right][/tex] from the question has two significant figures, the [tex]\rm \left[OH^{-}\right][/tex] here also has two significant figures. As a result, the [tex]\rm pOH[/tex] in the result should have two decimal places.

Draw the product that valine forms when it reacts with excess CH3CH2OH and HCl followed by a wash with aqueous base.

Answers

Answer:

Product: ethyl L-valinate

Explanation:

If we want to understand what it is the molecule produced we have to analyze the reagents. We have valine an amino acid, in this kind of compounds we have an amine group ([tex]NH_2[/tex]) and a carboxylic acid group ([tex]COOH[/tex]).  Additionally, we have an alcohol ([tex]CH_3CH_2OH[/tex]) in the presence of HCl (a strong acid) in the first step, and a base ([tex]OH^-[/tex]).

When we have an acid and an alcohol in a vessel we will have an esterification reaction. In other words, an ester is produced. As the first step, the oxygen in the C=O (in the carboxylic acid group) would be protonated. In the second step, the ethanol attacks the carbon in the C=O of the carboxylic acid group producing a new bond between the oxygen in the ethanol and the carbon in the carboxylic acid. In step 3, a proton is transferred to produce a better leaving group ([tex]H_2O[/tex]). In step 4, a water molecule leaves the main structure to produce again the double bond C=O. Finally, a base ([tex]OH^-[/tex]) removes the hydrogen from the C=O bond to produce ethyl L-valinate

See figure 1

I hope it helps!

Which is an intensive property of a substance?

Answers

Answer:

length

Explanation:

edge 2020

hope this helps!

Answer:

A.) Density

Explanation:

Correct on edge.

For element radon, give the chemical symbol, atomic number, and group number.

Answers

Radon is Rn
Atomic number is 86
Group 18 (noble gases)

Consider the following reaction at 298.15 K: Co(s)+Fe2+(aq,1.47 M)⟶Co2+(aq,0.33 M)+Fe(s) If the standard reduction potential for cobalt(II) is −0.28 V and the standard reduction potential for iron(II) is −0.447 V, what is the cell potential in volts for this cell? Report your answer with two significant figures.

Answers

Answer:

The correct answer is 0.186 V

Explanation:

The two hemirreactions are:

Reduction: Fe²⁺ + 2 e- → Fe(s)  

Oxidation : Co(s)  → Co²⁺ + 2 e-

Thus, we calculate the standard cell potential (Eº) from the difference between the reduction potentials of cobalt and iron, respectively,  as follows:

Eº = Eº(Fe²⁺/Fe(s)) - Eº(Co²⁺/Co(s)) = -0.28 V - (-0.447 V) = 0.167 V

Then, we use the Nernst equation to calculate the cell potential (E) at 298.15 K:

E= Eº - (0.0592 V/n) x log Q

Where:

n: number of electrons that are transferred in the reaction. In this case, n= 2.

Q: ratio between the concentrations of products over reactants, calculated as follows:

[tex]Q = \frac{ [Co^{2+} ]}{[Fe^{2+} ]} = \frac{0.33 M}{1.47 M} = 0.2244[/tex]

Finally, we introduce Eº= 0.167 V, n= 2, Q=0.2244, to obtain E:

E= 0.167 V - (0.0592 V/2) x log (0.2244) = 0.186 V

Select the correct answer.
Which state of matter is highly compressible, is made of particles moving independently of each other, and is present in large quantities near Earth’s surface?

A.
solid
B.
liquid
C.
gas
D.
plasma

Answers

Answer:

C. Gas

Explanation:

Gas!!!!! Letter C.....!!!!

2. Find the two generic molecules from Part 1 that are made of 3 atoms. a. Compare and contrast these two molecules by listing two similarities and two differences.

Answers

Answer:

hello the molecules are missing from your question below are the Generic molecules : [tex]ABE_{3}[/tex] and [tex]AB_{3} E[/tex]

answer : It can be determined  that both generic molecules are polar

It can be determined that both generic molecules have similar molecular shape

They have different Geometry

They differ in bond angles as well

Explanation:

The two generic molecules : [tex]ABE_{3}[/tex] and [tex]AB_{3} E[/tex]

comparing(similarities) these two generic molecules

It can be determined  that both generic molecules are polar

It can be determined that both generic molecules have similar molecular shape

differences between the generic molecules

They have different Geometry

They differ in bond angles as well

The solubility of lead(II) iodide is 0.064 g/100 mL at 20ºC. What is the solubility product for lead(II) iodide?

Answers

Answer:

[tex]Ksp=1.07x10^{-8}[/tex]

Explanation:

Hello,

In this case, the dissociation reaction is:

[tex]PbI_2(s)\rightleftharpoons Pb^{2+}(aq)+2I^-(aq)[/tex]

For which the equilibrium expression is:

[tex]Ksp=[Pb^{2+}][I^-]^2[/tex]

Thus, since the saturated solution is 0.064g/100 mL at 20 °C we need to compute the molar solubility by using its molar mass (461.2 g/mol)

[tex]Molar solubility=\frac{0.064g}{100mL}*\frac{1000mL}{1L}*\frac{1mol}{461.2g}=1.39x10^{-3}M[/tex]

In such a way, since the mole ratio between lead (II) iodide to lead (II) and iodide ions is 1:1 and 1:2 respectively, the concentration of each ion turns out:

[tex][Pb^{2+}]=1.39x10^{-3}M[/tex]

[tex][I^-]=1.39x10^{-3}M*2=2.78x10^{-3}M[/tex]

Thereby, the solubility product results:

[tex]Ksp=(1.39x10^{-3}M)(2.78x10^{-3}M)^2\\\\Ksp=1.07x10^{-8}[/tex]

Regards.

Solubility product constant for the product of lead(II) iodide is [tex]\bold { 1.07x 10^-^8}[/tex].

The dissociation reaction for lead (II) iodide

[tex]\bold {Pb I^2 (s) \leftrightharpoons Pb^2^+ + 2I^- }[/tex]

Solubility product constant at equilibrium.

[tex]\bold {Ksp = [Pb^2^++[I^-]^2}[/tex]

The molar solubility of the substance can be calculated by using the molar mass,

[tex]\bold {s = \dfrac {0.064}{100 mL} \times 461.2 g/mol = 1.39x10^-^3}[/tex]

Molar ratio between between PbI to lead and iodide ions is 1:1 and 1:2 respectively.

Thus Ksp will be,

[tex]\bold {Ksp =(1.39x10^-^3)(2.78x10^-^3 )^2}\\\\\bold {Ksp = 1.07x 10^-^8}[/tex]

Therefore, solubility product constant for the product of lead(II) iodide is [tex]\bold { 1.07x 10^-^8}[/tex].

To know more about  solubility product constant,

https://brainly.com/question/1419865

2. In what part of an atom can protons be found?
a. Inside the electrons

b. Inside the neutrons

C. Inside the atomic nucleus

d. Inside the electron shells

Answers

Answer:

c

Explanation:

it's found inside the atomic nucleus

In the atomic nucleus, protons (along with neutrons) can be found. Therefore answer is C.

For the reaction 3H 2(g) + N 2(g) 2NH 3(g), K c = 9.0 at 350°C. What is the value of ΔG at this temperature when 1.0 mol NH 3, 5.0 mol N 2, and 5.0 mol H 2 are mixed in a 2.5 L reactor?

Answers

Answer:

ΔG = - 31.7kJ/mol

Explanation:

It is possible to find ΔG of a reaction at certain temperature knowing Kc following the equation:

ΔG = ΔG° + RT ln Q

ΔG° = -RT lnKc

ΔG = -RT lnKc + RT ln Q (1)

Where R is gas constant (8.314J/molK), T absolute temperature (350°C + 273.15 = 623.15K) and Q reaction quotient

For the reaction,

3H₂(g) + N₂(g) ⇄ 2NH₃(g)

Q = [NH₃]² / [H₂]³[N₂]

Where the concentrations of each chemical are:

[NH₃] = 1.0mol / 2.5L = 0.4M

[H₂] = 5.0mol / 2.5L = 2M

[N₂] = 2.5mol / 2.5L = 1M}

Q = [0.4M]² / [2M]³[1M]

Q = 0.02

And replacing in (1):

ΔG = -RT lnKc + RT ln Q

ΔG = -8.314J/molK*623.15K ln 9 + 8.314J/molK*623.15K ln 0.02

ΔG = - 31651J/mol

ΔG = - 31.7kJ/mol

whats the ph for a solution poh4 9.78 concentration of solution

Answers

Answer:

4.22

Explanation:

According to the question, the pOH of the solution is 9.78. You may recall that pOH is the hydroxide concentration of a solution.

Also pOH = -log[OH^-]. Hence the pOH is obtained from the hydroxide ion concentration.

Finally, pH + pOH =14

Hence;

pH = 14-pOH

pH= 14-9.78 = 4.22

pH= 4.22

If the Ksp for Li3PO4 is 5.9×10−17, and the lithium ion concentration in solution is 0.0020 M, what does the phosphate concentration need to be for a precipitate to occur?

Answers

Answer:

7.4 × 10⁻⁹ M

Explanation:

Step 1: Given data

Solubility product constant (Ksp) for Li₃PO₄: 5.9 × 10⁻¹⁷

Concentration of lithium ion: 0.0020 M

Step 2: Write the reaction for the solution of Li₃PO₄

Li₃PO₄(s) ⇄ 3 Li⁺(aq) + PO₄³⁻(aq)

Step 3: Calculate the phosphate concentration required for a precipitate to occur

The solubility product constant is:

Ksp = 5.9 × 10⁻¹⁷ = [Li⁺]³ × [PO₄³⁻]

[PO₄³⁻] = 5.9 × 10⁻¹⁷ / [Li⁺]³

[PO₄³⁻] = 5.9 × 10⁻¹⁷ / 0.0020³

[PO₄³⁻] = 7.4 × 10⁻⁹ M

A piece of solid Fe metal is put into an aqueous solution of Cu(NO3)2. Write the net ionic equation for any single-replacement redox reaction that may be predicted. Assume that the oxidation state of in the resulted solution is 2 . (Use the lowest possible coefficients for the reaction. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank. If no reaction occurs, leave all boxes blank and click on Submit.)

Answers

Answer:

Fe(s) + Cu^2+(aq) ---> Fe^2+(aq) + Cu(s)

Explanation:

The ionic equation shows the actual reaction that took place. It excludes the spectator ions. Spectator ions are ions that do not really participate in the reaction even though they are present in the system.

For the reaction between iron and copper II nitrate, the molecular reaction equation is;

Fe(s) + Cu(NO3)2(aq)----> Fe(NO3)2(aq) +Cu(s)

Ionically;

Fe(s) + Cu^2+(aq) ---> Fe^2+(aq) + Cu(s)

Enter your answer in the provided box.


The equilibrium constant KP for the reaction


CO(g) + Cl2(g) ⇌ COCl2(g)


is 5.62 × 1035 at 25°C. Calculate ΔG

o

f

for COCl2 at 25°C.

Answers

Answer:

The correct answer is -341.2 kJ per mole.

Explanation:

The reaction given is:  

CO (g) + Cl₂ (g) ⇔ COCl₂ (g)

Kp = 5.62 × 10³⁵

T = 25 °C or 298 K

The formula for calculating ΔG is,  

ΔG° = -RTlnKp

ΔG° = -8.314 × 298 ln (5.62 × 10^35)

ΔG° = -203.9 kJ/mol

ΔG° = ∑nΔG°f (products) -∑nΔG°f (reactants)

ΔG° = ΔG°f (COCl₂ (g)) - [ΔG°f (CO(g)) + ΔG°f (Cl₂(g))]

ΔG°f (COCl₂ (g)) = ΔG° + [ΔG°f (CO (g)) + ΔG°f (Cl₂(g))]

ΔG°f (COCl₂ (g)) = -203.9 + (-137.28 + 0.00)

ΔG°f (COCl₂ (g)) = -341.2 kJ/mol

The standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol

The given equation for the chemical reaction is

CO(g) + Cl2(g) ⇌ COCl2(g)

At the temperature of 25°C = (273 + 25) K, the equilibrium constant [tex]\mathbf{K_p = 5.62\times 10^{35}}[/tex]

Consider the expression for the relationship between [tex]\mathbf{\Delta G^o}[/tex] and [tex]\mathbf{K_p }[/tex] for the equilibrium reaction can be expressed as:

[tex]\mathbf{\Delta G^o = - RT In K_p}[/tex]

where;

gas constant (R) = 8.314 × 10⁻³ kJ/K.mol

[tex]\mathbf{\Delta G^o = - (8.314 \times 10^{-3}\ kJ/K.mol \times 298 \ K) \times In (5.62 \times 10^{35} )}[/tex]

[tex]\mathbf{\Delta G^o = -2.477572\ K \times 82.31680992}[/tex]

[tex]\mathbf{\Delta G^o = 203.95 \ kJ}[/tex]

Thus, the standard free energy for the reaction is 203.95 kJ/mol

For a given reaction, the standard Gibbs free energy can be calculated by using the formula:

[tex]\mathbf{\Delta G^o_{rxn} = \sum n \Delta G^o_f (products) - \sum m \Delta G^o_f (reactants) }[/tex]

[tex]\mathbf{\Delta G^o_{rxn} =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(\Delta G^o_{f} (CO)_{(g)} + \Delta G^o_{f} (Cl)_{2(g)} ) \Big ) \Big ] }[/tex]

replacing the values of and solving for COCl2 at standard free energy of formation of substances, we have:

[tex]\mathbf{-203.95 \ kJ/mol =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(-137.3 kJ/mol + 0 \ kJ/mol\Big ) \Big ] }[/tex]

Collecting like terms, we have:

[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -203.95 \ kJ/mol -137.3 kJ/mol }[/tex]

[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -341.25 \ kJ/mol }[/tex]

Therefore, we can conclude that the standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol

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What happens if we put raw eggs in a pot full of hot oil?​

Answers

It will also lose heat faster than water will. Water boils at 100C so the temperature is limited. If you heat the oil hotter than boiling then the water inside the egg will heat above the boiling point and steam pressure will explode the egg.


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A student determines the value of the equilibrium constant to be 1.5297 x 107 for the following reaction: HBr(g) + 1/2 Cl2(g) --> HCl(g) +1/2 Br2(g) Based on this value of Keq, calculate the Gibbs free energy change for the reaction of 2.37 moles of HBr(g) at standard conditions at 298 K.

Answers

Answer:

[tex]\Delta G=-97.14kJ[/tex]

Explanation:

Hello,

In this case, the relationship between the equilibrium constant and the Gibbs free energy of reaction is:

[tex]\Delta G=-RTln(K)[/tex]

Hence, we compute it as required:

[tex]\Delta G=-8.314\frac{J}{mol\times K}*298K*ln(1.5297x10^7)\\\\\Delta G=-40.99kJ/mol[/tex]

And for 2.37 moles of hydrogen bromide, we obtain:

[tex]\Delta G=-40.99kJ/mol*2.37mol\\\\\Delta G=-97.14kJ[/tex]

Best regards.

By heating a 93% pure kclo3 sample, what percentage of its mass is reduced?
2KCLO3---->2KCL+3O2​

Answers

Explanation:

free your mind drink water and go outside take fresh air you will get answers

Complete the following equation of nuclear transmutation.
23892U + 126C → 24498Cf + 6 ______
Complete the following equation of nuclear transmutation.
U + C → Cf + 6 ______
A) 1n
B) 0 e
C) 0 e
D) 1H
E) 0g 0 -1 +1 1 0

Answers

Answer:

Option A. 1 0n

Explanation:

Details on how to balanced the equation for the reaction given in the question above can be found in the attached photo.

The missing part of the transmutation equation as it has been shown is 1/o n. Option A

What is nuclear transmutation?

Nuclear transmutation is the process of shifting the number of protons in an atom's nucleus to change one element into another. Nuclear processes that change one atomic nucleus into another with a different atomic number are involved.

The production of nuclear energy, radioactive decay, and the creation of new isotopes for use in science and industry all depend on nuclear transmutation, a fundamental idea in nuclear physics.

We have the equation as;

238/92 U + 12/6 C  ----> 244/98 Cf + 6 1/0 n

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Which of the following combinations will result in a reaction that is spontaneous at all temperatures?
Negative enthalpy change and negative entropy change
Negative enthalpy change and positive entropy change
Positive enthalpy change and negative entropy change
Positive enthalpy change and positive entropy change
PLS EXPLAIN WHAT EACH MEANS AND THE VARIABLES AND THE EXPLANATION BEHIND IT

Answers

Answer:

[tex]\huge\boxed{Option \ 2}[/tex]

Explanation:

A reaction is spontaneous at all temperatures by the following combinations:

=> A negative enthalpy change ( [tex]\triangle H < 0[/tex] )

=> A positive entropy change ( [tex]\triangle S > 0[/tex] )

See the attached file for more better understanding!

from Gibbs Equation, [tex] \Delta G = \Delta H - T\Delta S [/tex]

reaction is spontaneous if $\Delta G$ is negative.

so, first option is not valid at high temperature, ($-h+ts$)

second, is always a spontaneous reaction, ($-h-ts$)

third, is never spontaneous ($+h+ts$)

4th is similar to second, spontaneous at higher temperatures ($+h-ts$)

Assume that you are provided with the following materials:
• Strips of metallic zinc, metallic copper, metallic iron
• 1M aqueous solutions of ZnSO4, CuSO4, FeSO4, and aqueous iodine(I2)
• Other required materials to create Voltaic cells such as beakers, porous containers, graphite rods, a voltmeter, and a few wires with alligator clips.
In this modified version of the lab, after thoroughly studying the lab hand out and watching the videos,identify 4 different combinations of Voltaic cells that are possible to be created with the above materials.For each cell created, include the following details.
A) Which electrode was the anode,and which was the Cathode?
B) The anode and cathode half reactions.
C) Balanced equation for each cell you propose to construct.
D) Calculated Eocelle Short hand notation (line notation) for each cell (be sure to include the inactive electrode if needed).

Answers

Answer:

See explanation

Explanation:

First voltaic cell;

Zn(s)|Zn^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Zinc

Cathode;

Copper

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Zn(s) + Cu^2+(aq) -----> Zn^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.76) =1.1 V

Second voltaic cell;

Zn(s)|Zn^2+(aq)||Fe^2+(aq)|Fe(s)

Anode;

Zinc

Cathode;

Iron

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Fe^2+(aq) +2e -----> Fe(s)

Overall; Zn(s) + Fe^2+(aq) -----> Zn^2+(aq) + Fe(s)

E°cell = (-0.44) -(-0.76) = 0.32 V

Third voltaic cell;

Fe(s)|Fe^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Iron

Cathode;

Copper

Oxidation half equation;

Fe(s)------> Fe^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Fe(s) + Cu^2+(aq) -----> Fe^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.44) = 0.78 V

Fourth voltaic cell

Cu(s)|Cu^2+(aq)||I2(aq)|C(s)|I^-(aq)

Anode;

Copper

Cathode;

Graphite rod

Oxidation half equation;

Cu(s)------> Cu^2+(aq) + 2e

Reduction half equation;

I2(aq) +2e -----> 2I^-(aq)

Overall; Cu(s) + I2(aq) -----> Cu^2+(aq) + 2I^-(aq)

E°cell = 0.54 -0.34 = 0.20 V

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