A compound (C_9H_9BrO_2) gives the following NMR data. Draw the structure of the compound.
'1^H-NMR: 1.39 ppm, t(3H); 4.38 ppm, q(2H); 7.57 ppm, d(2H); 7.90 ppm, d(2H)
13^C-NMR: 165.73; 131.56; 131.01; 129.84; 127.81; 61.18; 14.18
You do not have to consider stereo chemistry.
You do not have to explicitly draw H atoms.
Do not include lone pairs in your answer.

Answer:

(a )people separate mixtures in order to ger a specific substance that they need.

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = 4.74

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

Answer:

The answer is o2

Explanation:

I took the test

Answer:

[tex]H_2SO_4(aq)\rightarrow H^+(aq)+HSO_4^-\\\\HSO_4^-(aq)\rightarrow H^+(aq)+SO_4^{2-}rightarrow[/tex]

Explanation:

Hello,

In this case, given that the sulfuric acid is a diprotic acid (two hydrogen ions) we can identify two ionization reactions, the first one, showing up the dissociation of the first hydrogen to yield hydrogen sulfate ions and the second one, showing up the dissociation of the hydrogen sulfate ions to hydrogen ions and sulfate ions by separated as shown below:

[tex]H_2SO_4(aq)\rightarrow H^+(aq)+HSO_4^-\\\\HSO_4^-(aq)\rightarrow H^+(aq)+SO_4^{2-}[/tex]

They are have one-sensed arrow, since sulfuric acid is a strong acid.

Regards.

The equations that represent the first and second ionization steps for sulfuric acid in water are H₂SO₄→HSO₄+H⁺ & HSO₄⁻→SO₄⁻+H⁺ respectively.

Ionization reactions are those reactions in which atom or molecule will convert into ion by bearing a positive or negative charge on itself.

In water in the following way ionization of sulphuric acid takes place:

        H₂SO₄ → HSO₄⁻ + H⁺

        HSO₄⁻ → SO₄⁻ + H⁺

Hence, two steps are shown above.

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Answer:

[tex]H_2O[/tex]

Explanation: Research has proven that ;

Water is a Polar Covalent Molecule

It consists of 2 Hydrogen molecules bonded to one Oxygen molecule and  the two hydrogen atoms are not evenly distributed around the oxygen atom.

Answer:

See explanation

Explanation:

When we talk about electrophilic substitution, we are talking about a substitution reaction in which the attacking agent is an electrophile. The electrophile attacks an electron rich area of a compound during the reaction.

The five membered furan ring is aromatic just as benzene. This aromatic structure is maintained during electrophilic substitution reaction. The attack of the electrophile generates a resonance stabilized intermediate whose canonical structures have been shown in the image attached.

Answer:

[tex]\huge\boxed{Option \ 2}[/tex]

Explanation:

A reaction is spontaneous at all temperatures by the following combinations:

=> A negative enthalpy change ( [tex]\triangle H < 0[/tex] )

=> A positive entropy change ( [tex]\triangle S > 0[/tex] )

See the attached file for more better understanding!

from Gibbs Equation, [tex] \Delta G = \Delta H - T\Delta S [/tex]

reaction is spontaneous if $\Delta G$ is negative.

so, first option is not valid at high temperature, ($-h+ts$)

second, is always a spontaneous reaction, ($-h-ts$)

third, is never spontaneous ($+h+ts$)

4th is similar to second, spontaneous at higher temperatures ($+h-ts$)

Answer:

whats the ph  ofpoh=9.78

Explanation:

Answer:

The temperature of the air at this given elevation will be 53.32425°C

Explanation:

We can calculate the final temperature through the combined gas law. Therefore we will need to know 1 ) The initial volume, 2 ) The initial temperature, 3 ) Initial Pressure, 4 ) Final Volume, 5 ) Final Pressure.

Initial Volume = 1.2 L ; Initial Temperature = 25°C = 298.15 K ; Initial pressure = 1.0 atm  ; Final Volume = 1.8 L ; Final pressure = 0.73 atm  

We have all the information we need. Now let us substitute into the following formula, and solve for the final temperature ( T[tex]_2[/tex] ),

P[tex]_1[/tex]V[tex]_1[/tex] / T[tex]_1[/tex] = P[tex]_2[/tex]V[tex]_2[/tex] / T[tex]_2[/tex],

T[tex]_2[/tex] = P[tex]_2[/tex]V[tex]_2[/tex]T[tex]_1[/tex] / P[tex]_1[/tex]V[tex]_1[/tex],

T[tex]_2[/tex] = 0.73 atm [tex]*[/tex] 1.8 L [tex]*[/tex] 298.15 K / 1 atm [tex]*[/tex] 1.2 L = ( 0.73 [tex]*[/tex] 1.8 [tex]*[/tex] 298.15 / 1 [tex]*[/tex] 1.2 ) K = 326.47425 K,

T[tex]_2[/tex] = 326.47425 K = 53.32425 C

According to the concept of redox reactions, the answer to this question is option C.

When the cell potential is positive. A redox reaction is spontaneous when the cell potential is positive.The cell potential is the measure of the driving force of the chemical reaction occurring in the electrochemical cell. In an electrochemical cell, a redox reaction occurs, which leads to the production of an electric potential.

If this potential is positive, then the redox reaction is considered spontaneous. However, if the potential is negative, then the reaction is non-spontaneous.In general, a redox reaction is spontaneous if the potential difference between the two electrodes of the cell is positive. This means that the reaction will occur spontaneously without any external energy input.

Thus, the correct option is C.

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Answer:

ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 )

Explanation:

Isomers are compounds that have the same molecular formula but different structural formulas. Hence any pair of compounds that can be represented by exactly the same molecular formula are isomers of each other.

If we look at the pair of compounds; ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 ), one compound has molecular formula, C2H7ON while the other has a molecular formula, C2H5ON, hence they are not isomers of each other.

Answer:

5.74M or 5.74 mol/L (to 3 sign. fig.)

Explanation:

The molar mass of NaNO3 is 85g/mol, which means that:

1 mole of NaNO3 - 85g

? moles - 122.0g

= 122/85 = 1.44 moles

Concentration in mol/L = no. of moles (moles) ÷ volume (L)

[tex]\frac{1.44}{0.250}[/tex] = 5.74M or 5.74 mol/L (to 3 sign. fig.)

I hope the steps are clear and easy to follow.

Answer:its saturated   or  unsaturaded

Explanation:

Answer:

  30. 5 planes are shown

  31. 1 plane

  32. CEF

  33. on line AB

  34. E or F

   35. ABCD or BCEF or CDEF or ACEF

Explanation:

30. Each of the surfaces of the rectangular pyramid is a plane. There are 5 planes.

__

31. 3 points define one plane only.

__

32. The only points shown on the same line segment are points E, F, and C.

__

33. If G is to be collinear with A and B, it must lie on line AB.

__

34. The only points shown that are not on plane N are points E and F. Either of those will do.

__

35. There are three planes that have 4 points shown on them. The four points that are on the same plane are any of ...

Plane ACEF is not shown on the diagram, but we know that those 4 points are also coplanar. (Any point not on line CE, together with the three points on that line, will define a plane with 4 coplanar points.)

Answer:

1. 36

2. Two

Explanation:

The Lewis structure shows the valence electrons present in a compound. Usually the valence electrons are shown as dot structures around the symbol of the elements involved in the compound.

For a compound AB4 where B is more electronegative than A and A has 8 electrons in its valence shell, there will be thirty six valence electrons on the outermost shell of the molecule.

There are six electron pair domains present in the molecule, four bond pairs and two lone pairs. The molecule is in a square planar geometry.

Answer: a- 36 valence electrons

b- 14 lone pairs

Explanation:

Valence is equal to A + 4B = 8 + 4(7)

With 4 bonds between A and the 4 B, that is 36 valence minus 8 electrons in those pairs = 28. 28 is 14 lone pairs.

Answer:

d. the conjugate base.

Explanation:

The general reaction of a weak acid, HA, with a strong base YOH, is:

HA + YOH → A⁻ + H₂O + Y⁻

Where A⁻ is the conjugate base of the weak acid and Y⁻ usually is a strong electrolyte.

That means after he complete reaction you don't have weak acid nor strong base, just conjugate base that will be in equilibrium with water, thus (Strong electrolyte doesn't change pH:

A⁻ + H₂O ⇄ HA + OH⁻

As the equilibrium is producing OH⁻, the pH of the solution is being affected for the conjugate base

Right option:

Answer:

D. Reduction takes place at the cathode, which is negatively charged.

Explanation:

In an electrolytic cell there are two electrodes; the cathode and the anode. The anode is the positive electrode while the cathode is the negative electrode. Oxidation occurs at the anode while reduction occurs at the cathode.

At the anode, species give up electrons and become positively charged ions while at the cathode species accept electrons and become reduced.

Answer:

The 3rd one

Explanation:

Explanation:

Answer:

The best reducing agent is Zn(s)

Explanation:

A reducing agent must to be able to reduce another compound, by oxidizing itself. Consequently, the oxidation potential must be high. The oxidation potential of a compound is the reduction potential of the same compound  with the opposite charge. Given the reduction potentials, the best reducing agent will be the compound with the most negative reduction potential. Among the following reduction potentials:

Cd₂⁺(aq)|Cd(s) ⇒ -0.40 V

Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

Ni²⁺(aq)|Ni(s) ⇒‑0.25 V

Cu²⁺(aq)|Cu(s) ⇒ +0.34 V

Ag⁺(aq)|Ag(s) ⇒ +0.80 V

The most negative is Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

From this, the most reducing agent is Zn. Zn(s) is oxidized to Zn²⁺ ions with the highest oxidation potential (0.76 V).

Answer:

\text{0.30 cm}^{3} \times \left (\dfrac{10^{-2}\text{ m}}{\text{1 cm}}\right )^{3} = 3.0 \times 10^{-7} \text{ m}^{3}  

Explanation:

0.030 cm³ × ? = x m³

You want to convert cubic centimetres to cubic metres, so you multiply the cubic centimetres by a conversion factor.

For example, you know that centi means "× 10⁻²", so  

1 cm = 10⁻² m

If we divide each side by 1 cm, we get 1 = (10⁻² m/1 cm).

If we divide each side by 10⁻² m, we get (1 cm/10⁻² m) = 1.

So, we can use either (10⁻² m/1 cm) or (1 cm/10⁻² m) as a conversion factor, because each fraction equals one.

We choose the former because it has the desired units on top.

The "cm" is cubed, so we must cube the conversion factor.

The calculation becomes

[tex]\text{0.30 cm}^{3} \times \left (\dfrac{10^{-2}\text{ m}}{\text{1 cm}}\right )^{3} = 0.30 \times 10^{-6}\text{ m}^{3} = \mathbf{3.0 \times 10^{-7}} \textbf{ m}^{\mathbf{3}}\\\\\textbf{0.30 cm}^{\mathbf{3}} \times \left (\dfrac{\mathbf{10^{-2}}\textbf{ m}}{\textbf{1 cm}}\right )^{\mathbf{3}} = \mathbf{3.0 \times 10^{-7}} \textbf{ m}^{\mathbf{3}}[/tex]

hope this helps u

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Answer:

123.96 g Na₂O

Explanation:

4 Na  +  O₂  ⇒  2 Na₂O

You first need to find the limiting reagent.  Convert the reactants to moles and see which produces the least amount of product using the mole ratios in the chemical equation.

(91.96 g Na)/(22.99 g/mol Na) = 4 mol Na

(4 mol Na) × (2 mol Na₂O/4 mol Na) = 2 mol Na₂O

(32.0 g O₂)/(32.0 g/mol) = 1 mol O₂

(1 mol O₂) × (2 mol Na₂O/1 mol O₂) = 2 mol Na₂O

Since they both produce the same amount of product, you don't need to pick a limiting reagent.  Now, convert moles of Na₂O to grams.

(2 mol Na₂O) × (61.98 g/mol Na₂O) = 123.96 g Na₂O

Answer:

-195.8º < -191.5º < 100º

Explanation:

Water, or H20, starts boiling at 100ºC.

Nitrogen, or N2, starts boiling at -195.8ºC.

Carbon monoxide, or C0, starts boiling at -191.5ºC.

When we place these in order from decreasing boiling point:

-195.8º goes first, then -191.5º, and 100º goes last.

Answer:

therefore, N2, CO, H20

Decreasing boiling point

Explanation:

the bond existing in H2O is hydrogen bond

bond existing in N2 is covalent bond, force existing is dipole-dipole-interaction

bond existing in CO is covalent bond , force existing between is induced -dipole- induced dipole-interaction

hydrogen bond is the strongest , followed by dipole-dipole-interaction and induced -dipole- induced dipole-interaction

the stronger the bond , the higher the boiling point

therefore, N2, CO, H20

-------------------------------------->

Decreasing boiling point

Answer:

The amount of heat to absorb is 6,261 J

Explanation:

Calorimetry is in charge of measuring the amount of heat generated or lost in certain physical or chemical processes.

The total energy required is the sum of the energy to heat the ice from -20 ° C to ice of 0 ° C, melting the ice of 0 ° C in 0 ° C water and finally heating the water to 60 ° C.

So:

Being the sensible heat of a body the amount of heat received or transferred by a body when it undergoes a temperature variation (Δt) without there being a change of physical state (solid, liquid or gaseous), the expression is used:

Q = c * m * ΔT

Where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation (ΔT=Tfinal - Tinitial).

In this case, m= 10 g, specific heat of the ice= 2.1 [tex]\frac{J}{g*C}[/tex] and ΔT=0 C - (-20 C)= 20 C

Replacing: Q= 10 g*2.1 [tex]\frac{J}{g*C}[/tex] *20 C and solving: Q=420 J

The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:

Q= m* ΔHfusion

In this case, being 1 mol of water= 18 grams: Q= 10 g*[tex]6.0 \frac{kJ}{mol} *\frac{1 mol of water}{18 g}[/tex]= 3.333 kJ= 3,333 J (being kJ=1,000 J)

In this case the expression used in the first step is used, but being: m= 10 g, specific heat of the water= 4.18 [tex]\frac{J}{g*C}[/tex] and ΔT=60 C - (0 C)= 60 C

Replacing: Q= 10 g*4.18 [tex]\frac{J}{g*C}[/tex] *60 C and solving: Q=2,508 J

Finally, Qtotal= 420 J + 3,333 J + 2,508 J

Qtotal= 6,261 J

The amount of heat to absorb is 6,261 J

The amount of heat to absorb is 6,261 J.

Heat required to raise the temperature of ice from -20 °C to 0 °C.

The formula for specific heat is used to calculate the amount of heat

Q = c * m * ΔT

Where,

Q =heat exchanged by a body,

m= mass of the body

c= specific heat

ΔT= change in temperature

Given:

m= 10 g,

specific heat of the ice= 2.1

ΔT=0 C - (-20 C)= 20 C

On substituting the values:

Q= 10 g*2.1  *20 C

Q=420 J

Heat required to convert 0 °C ice to 0 °C water.

The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:

Q= m* ΔHfusion

Heat required to raise the temperature of water from 0 °C to 60 °C

m= 10 g,

Specific heat of the water= 4.18  

ΔT=60 C - (0 C)= 60 C

On substituting:

Q= 10 g*4.18  *60 C

Q=2,508 J

Thus, Qtotal= 420 J + 3,333 J + 2,508 J

Qtotal= 6,261 J

The amount of heat to absorb is 6,261 J

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Answer:

0.44

Explanation:

We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.

For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M

pH= -log [H^+]

pH= - log[0.36]

pH= 0.44

Answer:

7.38 g/cm³ is the density of the metal

Explanation:

In a Face-centered cubic unit cell you have 4 atoms. Also, the edge length is √8×r (r is radius of the atom).

To solve this problem, we need first to calculate the volume of the unit cell and then, with molar mass calculate the mass of 4 atoms. As density is the ratio between mass and volume we can obtain this value.

Volume = a³

a = √8×r

(r = 198x10⁻¹²m)

a = 5.6x10⁻¹⁰ m

Volume = 1.756x10⁻²⁸ m³

1m = 100cm → 1m³ = (100cm)³:

1.756x10⁻²⁸ m³× ((100cm)³ / 1m³) =

There are 4 atoms of gold:

4 atoms × (1mol / 6.022x10²³ atoms) = 6.64x10⁻²⁴ moles of gold

As 1 mole weighs 195.08g:

6.64x10⁻²⁴ moles of gold × (195.08g / mol) =

1.296x10⁻²¹g / 1.756x10⁻²² cm³ =

The density of the metal is 7.40 g/cm³

In cubic crystal system, face-centered cubic FFC is the name given to sort of atom arrangement observed in which structure is made up of atoms organized in a cube with a portion of an atom in each corner and six extra atoms in the center of each cube face.

It is expressed by using the formula:

[tex]\mathbf{\rho = \dfrac{Z \times M}{N_A\times a^}}[/tex]

where;

For face-centered cubic FFC;

The edge length  [tex]\mathbf{a =2 \sqrt{2}\times r }[/tex]

[tex]\mathbf{a =2 \sqrt{2}\times 198 \ pm }[/tex]

[tex]\mathbf{a =560.0285 \ pm }[/tex]

a = 5.60 × 10⁻⁸ cm

Replacing it into the previous equation, we have:

[tex]\mathbf{\rho = \dfrac{4 \times 195.8}{6.022 \times 10^{23} \times( 5.60 \times 10^{-8} )^3}}[/tex]

[tex]\mathbf{\rho = 7.40\ g/cm^3 }[/tex]

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Answer:

I would say c) a closed circuit.

Hope I was right.

Answer:

Check the Attachment.

Half-reactions:

Anode: (OXIDATION) Ni --> Ni2+ + 2e-

Cathode: (REDUCTION) Cu2+ +2e- --> Cu

Overall reaction: Ni + Cu2+ --> Ni2+ + Cu

Explanation:

Overall, reaction is basically Anode + Cathode, where electrons on both sides cancel out  (if not, you need to multiply the equation in a way you can cancel them out).

Hope this helps.