A 1.30 L buffer solution consists of 0.107 M butanoic acid and 0.345 M sodium butanoate. Calculate the pH of the solution following the addition of 0.075 moles of NaOH . Assume that any contribution of the NaOH to the volume of the solution is negligible. The Ka of butanoic acid is 1.52×10−5 .

Answers

Answer 1

Answer:

The pH of the solution following the addition of 0.075 moles of NaOH is 5.7.

Explanation:

The equation of the buffer solution is the following:

C₄H₇O₂H(aq) + H₂O(l) ⇄ C₄H₇O₂⁻(aq) + H₃O⁺(aq)     (1)    

The pH of the buffer solution can be found using the Henderson-Hasselbalch equation:

[tex] pH = pKa + log(\frac{[NaC_{4}H_{7}O_{2}]}{[C_{4}H_{8}O_{2}]}) [/tex]   (2)

The NaOH added will react with butanoic acid tot produce sodium butanoate:

C₄H₇O₂H(aq) + OH⁻(aq) ⇄ C₄H₇O₂⁻(aq) + H₂O(l)  (3)          

[tex] n_{C_{4}H_{7}O_{2}H}_{i} = C*V = 0.107 M*1.30 L = 0.139 moles [/tex]

[tex] n_{C_{4}H_{7}O_{2}^{-}} = 0.345 M*1.30 L = 0.449 moles [/tex]

[tex] n_{NaOH} = 0.075 moles [/tex]

[tex] n_{C_{4}H_{7}O_{2}H} = 0.139 moles - 0.075 moles = 0.064 moles [/tex]

[tex] n_{C_{4}H_{7}O_{2}^{-}} = 0.449 moles + 0.075 moles = 0.524 moles [/tex]

[tex]C_{C_{4}H_{7}O_{2}H} = \frac{0.064 moles}{1.30 L} = 0.049 M[/tex]

[tex] C_{C_{4}H_{7}O_{2}^{-}} = \frac{0.524 moles}{1.30 L} = 0.403 M [/tex]

Now, from equation (1) we have:

C₄H₇O₂H(aq) + H₂O(l) ⇄ C₄H₇O₂⁻(aq) + H₃O⁺(aq)

0.049 - x                           0.403 + x            x  

[tex] Ka = \frac{[C_{4}H_{7}O_{2}^{-}][H_{3}O^{+}]}{C_{4}H_{7}O_{2}H} [/tex]

[tex]1.52 \cdot 10^{-5} = \frac{(0.403 + x)x}{0.049 - x}[/tex]

[tex]1.52 \cdot 10^{-5}*(0.049 - x) - (0.403 + x)x = 0[/tex]

By solving the above equation for x we have:            

x = 1.85x10⁻⁶ = [H₃O⁺]

So, the concentration of butanoic acid and sodium butanoate is:

[tex][C_{4}H_{7}O_{2}^{-}] = 0.345 + 1.85 \cdot 10^{-6} = 0.345 M[/tex]

[tex][C_{4}H_{7}O_{2}H] = 0.049 - 1.85 \cdot 10^{-6} = 0.049 M[/tex]

Finally, from equation (2) we have:

[tex] pH = pKa + log(\frac{[NaC_{4}H_{7}O_{2}]}{[C_{4}H_{8}O_{2}]}) [/tex]

[tex]pH = -log(1.52 \cdot 10^{-5}) + log(\frac{0.345}{0.049}) = 5.7[/tex]

Therefore, the pH of the solution following the addition of 0.075 moles of NaOH is 5.7.

I hope it helps you!


Related Questions

how many moles of copper are equivalent to 3.44x10^23 atoms of copper?

Answers

Answer:

0.571moles

Explanation:

The Avogrado's number or constant denoted by NA will be used for this question.

The Avogrado's number = 6.022 × 10^23 particles, is contained in 1 mole of a substance.

To get the number of atom/particles in a substance, the formula: N= n × NA is used.

Where; N= Number of atoms in

substance

n= number of moles

NA= Avogadro's constant

Hence, to find the number of moles of copper equivalent to 3.44 × 10^23, we say: n= N / NA

That is, n = 3.44 × 10^23 / 6.022 × 10^23

= 0.5712

Therefore, 0.571 moles of Copper (Cu) is equivalent to 3.44 × 10^23 atoms of Copper.

Which one of these is most likely to gain electrons and which one is most likely to lose electrons? (And please explain why)
1. Ra (Radium)
2. In (Indium)
3. P (Phosphorus)
4. Te (Tellurium)
5. Br (Bromine)
6. Rb (Rubidium)

Answers

Answer:

(I). The most likely to lose electron is Rubidium

(II). The most likely to lose electron is Bromine

Explanation:

Given that,

Radium, Indium, Phosphorus, Tellurium, Bromine and Rubidium

We know that,

Metal :

They atom which to lose electron these is called metal.

When the atom loses the electron then the positive charge come on the atom.

The most likely to lose electron is Rubidium

Non metal :

They atome which is gains electron. It is called non metal.

So, we can say that, the non metal gains electron.

When the atom gains the electron then the negative charge come on the atom.

The most likely to gain electron is Bromine

Hence, This is required answer.

HELPPPP Name the three states of matter. Describe the arrangement and movement of atoms in a substance for each state.

Answers

Solid, Liquid, and Gas

Solid is the state in which matter maintains a fixed volume and shape; liquid is the state in which matter adapts to the shape of its container but varies only slightly in volume; and gas is the state in which matter expands to occupy the volume and shape of its container.

The states of matter are solid, liquid, and gas. Solid is the state in which matter maintains a fixed volume and shape; liquid is the state in which matter adjusts to the shape of its container but tends to vary only mildly in volume; and gas is the state in which matter expands to occupy the volume and shape of its container.

What is matter?

Matter would be any substance with mass and volume that occupies space.

Matter exists in three states: solid, liquid, and gas. The states of matter are solid, liquid, and gas.

Solid is the phase in which matter retains a fixed volume and shape.Liquid is the entity in which matter adjusts to the shape of its container but tends to vary only slightly in volume.Gas is the phase in which matter expands to occupy the volume and shape of its container.

Thus, above-mentioned are the three states of matter.

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Which term is defined as “anything that has mass and occupies space”? a -compound b - element c - substance d - matter

Answers

The answer is matter

Answer:

D) Matter

Explanation:

what is the scientific term for salt​

Answers

Answer:

The scientific term for table salt is Sodium chloride.

Explanation:

The answer is sodium chloride.

It is composed of sodium and chloride. Like,

[tex] {na}^{ + } + {cl}^{ + } = nacl[/tex]

so, it's name is sodium chloride.

What group is calcium and sodium in?

Answers

Answer:

Calcium: Alkaline Earth

Sodium: Alkali Metal

Hope it helps!

Answer:

Calcium is in Alkaline Earth

Sodium is in Alkali Metal

What would be the pH of an HNO3 solution if the [H+] = 3.26 x 10-6 moles/liter? 5.49 4.67 6.32

Answers

Answer:

5.49

Explanation:

pH = - log[3.26 x 10-6] =5.49

How is the Law of Conservation of Mass being followed in a voltaic cell with a zinc anode and a copper cathode? A. No mass is lost because electrons are flowing, not atoms. B. The mass lost by the copper electrode is gained by the zinc cathode. C. The Law of Conservation of Mass is not followed when electricity is generated. D. The mass lost by the zinc electrode is gained by the copper cathode.

Answers

Answer:

b

Explanation:

In the given scenario, the mass lost by the copper electrode is gained by the zinc cathode. The correct option is B.

What is Law of Conservation of Mass?

The law of conservation of mass asserts that mass is neither created nor destroyed in a chemical reaction.

As electrons are lost at the anode, metal cations construct and dissipate into the solution, reducing the anode's mass through corrosion. The anode's lost electrons attract to the positively charged cathode and flow through the wire.

Thus, the correct option is B.

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Chromium is dissolved in sulfuric acid according to the following equation: Cr + H2SO4 ⇒ Cr2 (SO4) 3 + H2


a) How many grams of Cr2 (SO4) 3 can be obtained by reacting 165 g of 85.67% H2SO4 of purity?

b) If 485.9 g of Cr2 (SO4) 3 are obtained, what is the yield of the reaction?

Answers

Answer:

[tex]\large \boxed{\text{a)188.4 g; b) 98.67 $\, \%$}}[/tex]

Explanation:

We will need a balanced chemical equation with masses and molar masses, so, let's gather all the information in one place.

Mᵣ:                      98.08           392.18

             2Cr + 3H₂SO₄ ⟶ Cr₂(SO₄)₃ + 3H₂

To solve the stoichiometry problem, you must

Use the molar mass of H₂SO₄ to convert  the mass of H₂SO₄ to moles of H₂SO₄ Use the molar ratio to convert moles of H₂SO₄ to moles of Cr₂(SO₄)₃ Use the molar mass of Cr₂(SO₄)₃ to convert moles of Cr₂(SO₄)₃ to mass of Cr₂(SO₄)₃

a) Mass of Cr₂(SO₄)₃

(i) Mass of pure H₂SO₄

[tex]\text{Mass of pure} = \text{165 g impure} \times \dfrac{\text{85.67 g pure} }{\text{100 g impure}} = \text{141.36 g pure}[/tex]

(ii) Moles of H₂SO₄

[tex]\text{Moles of H$_{2}$SO}_{4} = \text{141.36 g H$_{2}$SO}_{4} \times \dfrac{\text{1 mol H$_{2}$SO}_{4}}{\text{98.08 g H$_{2}$SO}_{4}} = \text{1.441 mol H$_{2}$SO}_{4}[/tex]

(iii) Moles of Cr₂(SO₄)₃

The molar ratio is 1 mol Cr₂(SO₄)₃:3 mol H₂SO₄ [tex]\text{Moles of Cr$_{2}$(SO$_{4}$)}_{3} = \text{1.441 mol H$_{2}$SO}_{4} \times \dfrac{\text{1 mol Cr$_{2}$(SO$_{4}$)}_{3}}{\text{3 mol H$_{2}$SO}_{4}} = \text{0.4804 mol Cr$_{2}$(SO$_{4}$)}_{3}[/tex]

(iv) Mass of Cr₂(SO₄)₃ [tex]\text{Mass of Cr$_{2}$(SO$_{4}$)}_{3} = \text{0.4804 mol Cr$_{2}$(SO$_{4}$)}_{3} \times \dfrac{\text{392.18 g Cr$_{2}$(SO$_{4}$)}_{3}}{\text{1 mol Cr$_{2}$(SO$_{4}$)}_{3}} = \textbf{188.4 g Cr$_{2}$(SO$_{4}$)}_{3}\\\text{The mass of Cr$_{2}$(SO$_{4}$)$_{3}$ formed is $\large \boxed{\textbf{188.4 g}}$}[/tex]

b) Percentage yield

It is impossible to get a yield of 485.9 g. I will assume you meant 185.9 g.

[tex]\text{Percentage yield} = \dfrac{\text{Actual yield}}{\text{Theoretical yield}} \times 100 \, \% = \dfrac{\text{185.9 g}}{\text{188.4 g}} \times 100 \, \% = \mathbf{98.67 \, \%}\\\\\text{The percentage yield is $\large \boxed{\mathbf{98.67 \, \%}}$}[/tex]

What is the independent variable of Smithers experience?

Please help controls and variables simpson? Smithers thinks that a special juice will increase the productivity of workers. He creates two groups of 50 workers each and assigns each group the same task (in this case, they're supposed to staple a set of papers). Group A is given the special juice to drink while they work. Group B is not given the special...

Answers

Answer:

Smithers thinks that a special juice will increase the productivity of workers. He creates two groups of 50 workers each and assigns each group the same task (in this case, they're ... Group A is given the special juice to drink while they work. Group ... 1. Control Group. Group B. 2. Independent Variable. volume of special juice.

Explanation:

Answer:

1. Group B

2. The juice

3. The number of stacks of paper

4. the juice did not help improve a quicker process

5. Group A can be given the juice, Group B can be given the juice without the special ingredient

USE QUIZLET FLASH CARDS IT CAN HELP YOU WITH A LOT OF QUESTION

what is the molarity of a 50.0 ml aqueous solution containing 10.0 grams of acetic acid, ch3cooh?

Answers

Answer:

3.34 M or 3.34 mol/L

Explanation:

The formula for molarity is moles of solution ÷ liters of solution. So, we have to convert grams into moles and mL to L.

To convert grams to moles, first find the molar mass of CH₃COOH by looking at the atomic mass of each individual element.

C - 2(12.01) = 24.02

H - 4(1.01) = 4.04

O - 2(16.00) = 32.00

= 60.06

Now divide the number of grams by the molar mass.

10.0 g CH₃COOH ÷ 60.06 g = 0.167 mol CH₃COOH

To convert milliliters to liters, divide by 1000.

50.0 mL ÷ 1000 = 0.05 L

Now we can calculate the molarity.

M = moles of solution ÷ liters of solution

= 0.167 mol ÷ 0.05 L

= 3.34 M or 3.34 mol/L

The molarity is 3.34 M.

Hope that helps.

How many significant figures
are in this number?
107.051

Answers

Answer:

there are 6 significant figures in 107.051

Answer:

There Are 6 Significant Numbers

Explanation: But some problems stop at the . so it could 3 if im right but go with 6!

What u learned about the states of matter?

Answers

Answer:t

Explanation:

In everyday life, four states of matter are visible: solid, liquid, gas, and plasma.

Of course, matter also has other states, such as Bose-Einstein density and Fermion density, but these states are only observed under certain conditions.

name Two soft metals which can be cut with a knife.

Answers

Answer:

lithium, and sodium can be cut with a knife

Define freezing....... Correct and detailed answers will be marked as Brainliest.

Answers

Freezing:

The transformation of liquid into solid when it reaches when it's temperature is below freezing point.

Answer:

Freezing:

When liquid is converted to solid, the process is called freezing.

Conditions for freezing:

1) Temperature must be lowered.

2) The temperature should be below 0 degree centigrade.

Example:

The conversion of "liquid water" into "ice".

=> We can use a "freezer" to freeze things.

How do weathering and deposition differ? Weathering breaks down rocks; deposition leaves them in new places. Weathering has to do with air; deposition has to do with plants. Weathering occurs only in summer; deposition occurs year-round. Weathering can be chemical or physical; deposition is only chemical

Answers

Answer:

A. Weathering breaks down rocks; Deposition leaves them in new places.

Explanation:

Weathering is basically the complete process of rocks breaking apart.  In contrast, deposition is when the rocks are moved and carried away from their original place and put in new locations.

Answer:

a

Explanation:

Three determinations were made of the following percentage of oxygen in mercuric oxide. The results were 7.40%, 7.43%, and 7.35%. What was the average percentage?

Answers

7.39% Hope that helps! :)

The melting points of ionic compounds _____

Answers

Explanation:

ionic compounds have high melting points

Use the periodic table to determine which element the following spin diagram
represents:

(Using the image)

A. nitrogen
B. Oxygen
C. None of these
D. Boron

Answers

Answer:

B. Oxygen

Explanation:

Basically count each arrow since each arrow represents an electron. Then use the periodic table to find the element with 8 electrons, which is oxygen. Also, if you know the orbital patterns, you can identify that the 2p orbital represents an element in Group 16.

Consider the reaction of 2.5 grams of Li (s) reacting with 0.5 grams of N2 (g) to produce Li3N (s). A) How many total grams of Li3 N (s) would be produced? B) Which of the starting elements is the limiting reagent, and how many grams of the non-limiting reagent remain after the reaction has completed?

Answers

Answer:

A) The amount in grams of Li₃N produced is 1.243 g

B) N₂, is the limiting reagent

The mass of the non-limiting reagent, Li, remaining after the reaction is completed is 1.757 g

Explanation:

The given parameters are;

The mass of Li(s) = 2.5 grams

The mass of N₂ (g) = 0.5 grams

The chemical equation for the reaction can be presented as follows;

6 Li (s) + N₂ (g) → 2 Li₃N

Therefore, 6 moles of Li reacts with 1 mole of N₂  to produce 2 moles of Li₃N

The molar mass of Li = 6.941 g/mol

The molar mass of N₂ = 28.0134 g/mol

The number of moles of a reactant or product, n is given by the relation;

n = Mass of substance/(Molar mass of the substance)

For lithium, Li, n = 2.5/6.941 = 0.3602 moles

For Nitrogen gas, N₂, n = 0.5/28.0134  = 0.01785 moles

A) Given that 1 mole of  N₂ to produces 2 moles of Li₃N

0.01785  moles of  N₂ will produces 2×0.01785 = 0.0357 moles of Li₃N

The molar mass of Li₃N = 34.83 g/mol

The mass of Li₃N = 34.83 g/mol × 0.0357 moles = 1.243 g

B) 6  moles of Li reacts with 1 mole of N₂ to produce 2 moles of Li₃N

0.3602 moles will reacts with 1/6×0.3602 = 0.06003 mole of N₂

Therefore, N₂, is the limiting reagent and we have;

0.01785  moles of  N₂ will react with 6×0.01785 = 0.1071  moles of Li

The number of of moles of Li left = 0.3602 - 0.1071 =0.2531 moles

The mass of lithium left = 0.2531 moles × 6.941 g/mol = 1.757 g

The mass of lithium remaining after the reaction is completed = 1.757 g.

What is the atomic number of copper

Answers

Answer:

29

Explanation:

Copper is a chemical element with the symbol Cu and atomic number is 29

Explanation:

how to unscramble dtneinreigs

Answers

ANSWER: Ingredients.

Answer:

Ingredients OR tenderising

Explanation:

convert 0.5 seconds to milliseconds and .02 km to meters​

Answers

Answer:

0,5 seconds = 500 millisecondes

2 km = 200 meters

Explanation:

What are half reaction

Answers

Answer:

When you don't have a complete reaction.

Explanation:

Happens a lot between a solvent and a solute. The solute may not bind well with the solvent I.e. water.

If your talking about oxidation, the answer would be
the part of the reaction involving oxidation or reduction

Is iodine a atom,a molecule,an ion or a formule unit?

Answers

Answer:

It's an atom

Explanation:

It can't be a molecule since it's only one element, the ion would've been Iodide (I-), and it's not a formula

If the red car travels from 50 m to -25 m in 5 seconds, what is its velocity?

Answers

Answer:

V = 14m/s

Explanation:

velocity is the rate of change in displacement

V = (change in displacement)/time

V = (50 - (-20) )/5

V = (70)/5

V = 14m/s

which of the following molecules would you expect to be optically active

1. CCl2F2
2. 2-methyl butane
3. butan-2-ol​

Answers

Answer:

waaaaaaaaaaqwwwwwwwwwwww

An atom X has a proton number of 19 and relative atomic mass of 39.

(i) How many electrons, protons and neutrons are there in an atom of X?

(ii) How many electrons will there be in the outer energy level (shell) of an atom of X?

(iii) What is the electronic configuration of X?

Answers

Answer:

1) electron=19 Proton=19 Neutron=39-19=20

2) 1

3) in pic

Answer:

(i)electrons = 19; Protons = 19 Neutrons =39-19=20

(ii) 1

(iii) 2,8,8,1

Hope this helps.

Please mark me as Brainliest:))

What is the name of this compound? H single bonded to N with a pair of electron dots above and a single bond to H below, single bonded to the right to C with H above and below, and another C with H above, below, and right.

Answers

Answer:

Ethanamine (also known as ethylamine)

Explanation:

The compound that is requested by the question is ethanamine. Its trivial name is ethylamine.

It is a compound that contained the ethyl moiety (CH3CH2-) as well as the amine moiety (-NH2).

Ethanamine has a structure that can easily be determined by the statements in the question.

The structure of ethanamine is shown in the image attached.

Answer:

What is the name of this compound?

                                                                                    H       H

                                                                                    │       │

                                                               H ── N ── C ── C ── H

                                                                          │       │        │

                                                                          H      H        H

❌ A) ethanal

✔️B) ethylamine

❌ C) ethanoic acid

❌ D) methyl ethanoate

I Took Question Test And Have Day.

If an object's mass is 70 g, and its volume is 10cm cubed, what is its density?

Answers

The answer is 7,000

If an object's mass is 70 g, and its volume is 10cm cubed,  its density is 7 centimeter cube.

What is density?

The density of any solid substance is the unit of the area occupied by it in per centimeter of the cube of the volume in the given sample and calculated by dividing the mass and the volume of the compound unit will be centimeter cube.

The mass of the given object is 70 gram and the volume is given is 10 cm to find the density,

                       Density = mass of object / volume of object

substituting the value in the formula,

                 Density = 70 / 10

                 Density = 7 centimeter cube.

Therefore, the density of the given object will be 7 centimeter cube if  an object's mass is 70 g, and its volume is 10cm cubed.

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