Answer:
[tex]M_{base}=0.709M[/tex]
Explanation:
Hello,
In this case, since the reaction between potassium hydroxide and nitric acid is:
[tex]KOH+HNO_3\rightarrow KNO_3+H_2O[/tex]
We can see a 1:1 mole ratio between the acid and base, therefore, for the titration analysis, we find the following equality at the equivalence point:
[tex]n_{acid}=n_{base}[/tex]
That in terms of molarities and volumes is:
[tex]M_{acid}V_{acid}=M_{base}V_{base}[/tex]
Thus, solving the molarity of the base (KOH), we obtain:
[tex]M_{base}=\frac{M_{acid}V_{acid}}{V_{base}} =\frac{0.498M*42.7mL}{30.0mL}\\ \\M_{base}=0.709M[/tex]
Regards.
please help guys the question is
give reasons
a. we have to separate the mixture
b. All impure substances are not harmful.
c. A mixture of iron fillings and sand can be separated by using a magnet
d. A sentences "shake before well use" is written on the bottle of the medicine.
Answer:
(a )people separate mixtures in order to ger a specific substance that they need.
Half-cells were made from a nickel rod dipping in nickel sulfate solution and a copper rod dipping in copper sulfate solution. The cells were combined to construct a voltaic electrochemical cell. Sketch the cell and label anode and cathode with charges, electrode material and electrolyte solutions, half-reactions and overall reaction, give direction of electron flow and movement of ions.
Answer:
Check the Attachment.
Half-reactions:
Anode: (OXIDATION) Ni --> Ni2+ + 2e-
Cathode: (REDUCTION) Cu2+ +2e- --> Cu
Overall reaction: Ni + Cu2+ --> Ni2+ + Cu
Explanation:
Overall, reaction is basically Anode + Cathode, where electrons on both sides cancel out (if not, you need to multiply the equation in a way you can cancel them out).
Hope this helps.
Refer to the figure.
30. How many planes are shown in the figure?
31. How many planes contain points B, C, and E?
32. Name three collinear points.
3. Where could you add point G on plane N
so that A, B, and G would be collinear?
4. Name a point that is not coplanar with
A, B, and C.
5. Name four points that are coplanar.
BN
Answer:
30. 5 planes are shown
31. 1 plane
32. CEF
33. on line AB
34. E or F
35. ABCD or BCEF or CDEF or ACEF
Explanation:
30. Each of the surfaces of the rectangular pyramid is a plane. There are 5 planes.
__
31. 3 points define one plane only.
__
32. The only points shown on the same line segment are points E, F, and C.
__
33. If G is to be collinear with A and B, it must lie on line AB.
__
34. The only points shown that are not on plane N are points E and F. Either of those will do.
__
35. There are three planes that have 4 points shown on them. The four points that are on the same plane are any of ...
ABCDBCEFCDEFPlane ACEF is not shown on the diagram, but we know that those 4 points are also coplanar. (Any point not on line CE, together with the three points on that line, will define a plane with 4 coplanar points.)
What is silica gel commonly used for? A. Absorbing moisture to protect goods from damage. B. As insulation in buildings. C. As a lacquer on wood to make it water-resistant. D. A soft, flexible padding, such as on pen grips or mouse pads.
Answer:
A
Explanation:
Absorbing moisture to protect goods from damage. Hence, option A is correct.
What is silica gel?Silica gel is a desiccant, or drying agent, that manufacturers often place in little packets to keep moisture from damaging certain food and commercial products.
Silica Gel is a good drying agent for preventing corrosion, contamination, spoilage, and mould growth in many commodities and products due to its physical properties.
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Which of the following is a salt that will form from the combination of a strong base with a weak acid?
Select the correct answer below:
A. NaHCO3
B. H2O
C. CH3CO2H
D. NH4Cl
Answer:
A. NaHCO₃
Explanation:
NaHCO₃ ⇒ NaOH + H₂CO₃
NaOH is a strong base and H₂CO₃ is a weak acid. Therefore, NaHCO₃ is a salt of a strong base-weak acid reaction. The salt is basic because carbonic acid (H₂CO₃) is a weak acid so it remains undissociated. So, there is a presence of additional OH⁻ ions that makes the solution basic.
Hope that helps.
Calculate the amount of heat that must be absorbed by 10.0 g of ice at –20°C to convert it to liquid water at 60.0°C. Given: specific heat (ice) = 2.1 J/g·°C; specific heat (water) = 4.18 J/g·°C; ΔH fus = 6.0 kJ/mol.
Answer:
The amount of heat to absorb is 6,261 J
Explanation:
Calorimetry is in charge of measuring the amount of heat generated or lost in certain physical or chemical processes.
The total energy required is the sum of the energy to heat the ice from -20 ° C to ice of 0 ° C, melting the ice of 0 ° C in 0 ° C water and finally heating the water to 60 ° C.
So:
Heat required to raise the temperature of ice from -20 °C to 0 °CBeing the sensible heat of a body the amount of heat received or transferred by a body when it undergoes a temperature variation (Δt) without there being a change of physical state (solid, liquid or gaseous), the expression is used:
Q = c * m * ΔT
Where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation (ΔT=Tfinal - Tinitial).
In this case, m= 10 g, specific heat of the ice= 2.1 [tex]\frac{J}{g*C}[/tex] and ΔT=0 C - (-20 C)= 20 C
Replacing: Q= 10 g*2.1 [tex]\frac{J}{g*C}[/tex] *20 C and solving: Q=420 J
Heat required to convert 0 °C ice to 0 °C waterThe heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:
Q= m* ΔHfusion
In this case, being 1 mol of water= 18 grams: Q= 10 g*[tex]6.0 \frac{kJ}{mol} *\frac{1 mol of water}{18 g}[/tex]= 3.333 kJ= 3,333 J (being kJ=1,000 J)
Heat required to raise the temperature of water from 0 °C to 60 °CIn this case the expression used in the first step is used, but being: m= 10 g, specific heat of the water= 4.18 [tex]\frac{J}{g*C}[/tex] and ΔT=60 C - (0 C)= 60 C
Replacing: Q= 10 g*4.18 [tex]\frac{J}{g*C}[/tex] *60 C and solving: Q=2,508 J
Finally, Qtotal= 420 J + 3,333 J + 2,508 J
Qtotal= 6,261 J
The amount of heat to absorb is 6,261 J
The amount of heat to absorb is 6,261 J.
Calculation for heat:Heat required to raise the temperature of ice from -20 °C to 0 °C.
The formula for specific heat is used to calculate the amount of heat
Q = c * m * ΔT
Where,
Q =heat exchanged by a body,
m= mass of the body
c= specific heat
ΔT= change in temperature
Given:
m= 10 g,
specific heat of the ice= 2.1
ΔT=0 C - (-20 C)= 20 C
On substituting the values:
Q= 10 g*2.1 *20 C
Q=420 J
Heat required to convert 0 °C ice to 0 °C water.
The heat Q necessary to melt a substance depends on its mass m and on the called latent heat of fusion of each substance:
Q= m* ΔHfusion
Heat required to raise the temperature of water from 0 °C to 60 °C
m= 10 g,
Specific heat of the water= 4.18
ΔT=60 C - (0 C)= 60 C
On substituting:
Q= 10 g*4.18 *60 C
Q=2,508 J
Thus, Qtotal= 420 J + 3,333 J + 2,508 J
Qtotal= 6,261 J
The amount of heat to absorb is 6,261 J
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"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"
Answer:
245.66g of NH₄Cl is the mass we need to add to obtain the desire pH
Explanation:
The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:
pH = pKa + log [A⁻] / [HA]
Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical
First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.
pKa NH₃/NH₄⁺pKb = - log Kb
pKb = -log 1.8x10⁻⁵ = 4.74
pKa = 14 - pKb
pKa = 14 - 4.74
pKa = 9.26
Moles NH₃2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃
H-H equation:pH = pKa + log [NH₃] / [NH₄Cl]
8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]
-1.06 = log [0.400 moles] / [NH₄Cl]
0.0087 = [0.400 moles] / [NH₄Cl]
[NH₄Cl] = 0.400 moles / 0.0087
[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):
4.59 moles NH₄Cl ₓ (53.491g / mol) =
245.66g of NH₄Cl is the mass we need to add to obtain the desire pH
Assume that you are provided with the following materials:
• Strips of metallic zinc, metallic copper, metallic iron
• 1M aqueous solutions of ZnSO4, CuSO4, FeSO4, and aqueous iodine(I2)
• Other required materials to create Voltaic cells such as beakers, porous containers, graphite rods, a voltmeter, and a few wires with alligator clips.
In this modified version of the lab, after thoroughly studying the lab hand out and watching the videos,identify 4 different combinations of Voltaic cells that are possible to be created with the above materials.For each cell created, include the following details.
A) Which electrode was the anode,and which was the Cathode?
B) The anode and cathode half reactions.
C) Balanced equation for each cell you propose to construct.
D) Calculated Eocelle Short hand notation (line notation) for each cell (be sure to include the inactive electrode if needed).
Answer:
See explanation
Explanation:
First voltaic cell;
Zn(s)|Zn^2+(aq)||Cu^2+(aq)|Cu(s)
Anode;
Zinc
Cathode;
Copper
Oxidation half equation;
Zn(s)------> Zn^2+(aq) + 2e
Reduction half equation;
Cu^2+(aq) +2e -----> Cu(s)
Overall; Zn(s) + Cu^2+(aq) -----> Zn^2+(aq) + Cu(s)
E°cell = 0.34 -(-0.76) =1.1 V
Second voltaic cell;
Zn(s)|Zn^2+(aq)||Fe^2+(aq)|Fe(s)
Anode;
Zinc
Cathode;
Iron
Oxidation half equation;
Zn(s)------> Zn^2+(aq) + 2e
Reduction half equation;
Fe^2+(aq) +2e -----> Fe(s)
Overall; Zn(s) + Fe^2+(aq) -----> Zn^2+(aq) + Fe(s)
E°cell = (-0.44) -(-0.76) = 0.32 V
Third voltaic cell;
Fe(s)|Fe^2+(aq)||Cu^2+(aq)|Cu(s)
Anode;
Iron
Cathode;
Copper
Oxidation half equation;
Fe(s)------> Fe^2+(aq) + 2e
Reduction half equation;
Cu^2+(aq) +2e -----> Cu(s)
Overall; Fe(s) + Cu^2+(aq) -----> Fe^2+(aq) + Cu(s)
E°cell = 0.34 -(-0.44) = 0.78 V
Fourth voltaic cell
Cu(s)|Cu^2+(aq)||I2(aq)|C(s)|I^-(aq)
Anode;
Copper
Cathode;
Graphite rod
Oxidation half equation;
Cu(s)------> Cu^2+(aq) + 2e
Reduction half equation;
I2(aq) +2e -----> 2I^-(aq)
Overall; Cu(s) + I2(aq) -----> Cu^2+(aq) + 2I^-(aq)
E°cell = 0.54 -0.34 = 0.20 V
When we react a weak acid with a strong base of equal amounts and concentration, the component of the reaction that will have the greatest effect on the pH of the solution is:______.
a. the acid.
b. the base.
c. the conjugate acid.
d. the conjugate base.
Answer:
d. the conjugate base.
Explanation:
The general reaction of a weak acid, HA, with a strong base YOH, is:
HA + YOH → A⁻ + H₂O + Y⁻
Where A⁻ is the conjugate base of the weak acid and Y⁻ usually is a strong electrolyte.
That means after he complete reaction you don't have weak acid nor strong base, just conjugate base that will be in equilibrium with water, thus (Strong electrolyte doesn't change pH:
A⁻ + H₂O ⇄ HA + OH⁻
As the equilibrium is producing OH⁻, the pH of the solution is being affected for the conjugate base
Right option:
d. the conjugate base.a boy capable of swimming 2.1m/a in still water is swimming in a river with a 1.8 m/a current. At what angle must he swim in order to end up directly opposite his starting point?
Answer:
The boy must swim at an angle of 59°northwest to get to a position directly opposite his starting point.
Explanation:
To get to a point directly opposite his starting point, the boy must travel at an angle x, in a direction northwest of his starting point. The speed of the boy and the speed of the river current forms a right-angled triangle with an an opposite side of 1.8 m/a and a hypotenuse of 2.1 m/a having an angle x.
Sin x = opp/ hyp
Sin x = 1.8/2.1
x = sin⁻¹ (1.8/2.10
x = 58.99
x = 59°
Therefore, the boy must swim at an angle of 59° in the northwesterly direction to get to a position directly opposite his starting point.
Im really confused and select all that apply questions scare me.
Answer:
The 3rd one
Explanation:
Calculate the pH of a 0.20 M NH3/0.20 M NH4Cl buffer after the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.
Answer:
Explanation:
For pH of a buffer solution , the formula is
pH = pKa + log [ Base ] / [ conjugate acid ]
= pKa + log [ NH₃ ] / [ NH₄⁺ ]
Ka = Kw / Kb
Kb for NH₄OH = 1.8 x 10⁻⁵
Ka = 10⁻¹⁴ / 1.8 x 10⁻⁵
= 5.6 x 10⁻¹⁰
pH = - log ( 5.6 x 10⁻¹⁰ ) + log 0.2 / 0.2
= 10 - log 5.6
= 9.25
Effect of addition of HCl
H⁺ of HCl will react with NH₃ to produce NH₄⁺
25 mL of .1 HCl = 2.5 mM of HCl
25 mL of .1 NH₄⁺ = 2.5 mM of NH₄⁺
65 mL of .2 M NH₃ = 13 mM of NH₃
65 mL of .2 M NH₄⁺ = 13 mM of NH₄⁺
NH₃ + H⁺ = NH₄⁺
NH₄⁺ formed = 2.5 + 13 mM
15.5 mM of NH₄⁺
NH₃ = 13 mM
Concentration of NH₃ = 13 / 90
Concentration of NH₄⁺ = 15.5 / 90
pH of final buffer mixture
= 9.6 + log 13 / 15.5
= 9.25 - .076
= 9.174
The pH value is mathematically given as
pH= -6.332.
What is the pH of a 0.20 M NH3/0.20 M NH4Cl buffer?Question Parameters:
the pH of a 0.20 M NH3/0.20 M NH4Cl buffer
the addition of 25.0 mL of 0.10 M HCl to 65.0 mL of the buffer.
Generally, the equation for the Chemical Reaction is mathematically given as
HCl + NH3 --> NH4^+ + Cl^-
Therefore
pH= pka + log(13/14).
pH= -6.3 + log 0.93.
pH= -6.3+ (-0.032).
pH= -6.332.
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What is the final volume V2 in milliliters when 0.551 L of a 50.0 % (m/v) solution is diluted to 23.5 % (m/v)?
Answer:
[tex]V_2=1.17L[/tex]
Explanation:
Hello,
In this case, for dilution processes, we must remember that the amount of solute remains the same, therefore, we can write:
[tex]V_1C_1=V_2C_2[/tex]
Whereas V accounts for volume and C for concentration that in this case is %(m/v). In such a way, the final volume V2 turns out:
[tex]V_2=\frac{V_1C_1}{C_2}= \frac{0.551L*50.0\%}{23.5\%}\\ \\V_2=1.17L[/tex]
Best regards.
Identify the compound that does NOT have hydrogen bonding.
A) CH3NH2
B) H2O
C) (CH3)3N
D) CH3OH
E) HF
Answer:
(CH3)3N
Explanation:
Hydrogen bonding can be called a type of intracellular force of the attraction. It is the force that occur between molecules. It is the bonding between the molecules and of hydrogen and electronegative items in the covalent bond. This is called the hydrogen donor. An electro-negative hydrogen atoms may be a hydrogen bonded. It is also called a hydrogen acceptor.
Thus in (CH3)3N, the hydrogen atoms becomes bonded with carbon. Carbon is not electronegative atoms. Thus it does not play as donor. Nitrogen is electronegative and play as hydrogen acceptor. But there is no presence of hydrogen acceptor. Thus there is no molecules that exhibit hydrogen molecules bonding.
[tex]\bold {(CH_3)_3N}[/tex] does not have hydrogen bonding because of the absence of electronegativity difference.
Hydrogen bond:
It is an inter-molecular bond. It is due to the difference in electronegativities of constituent atoms. This creates dipole in the atoms so, atoms start to attract each other.
In [tex]\bold {(CH_3)_3N}[/tex], the hydrogen atoms are bonded with carbon. The difference between the electronegativities Carbon and hydrogen is very less.
Therefore, [tex]\bold {(CH_3)_3N}[/tex] does not have hydrogen bonding because of the absence of electronegativity difference.
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place the following substances in Order of decreasing boiling point H20 N2 CO
Answer:
-195.8º < -191.5º < 100º
Explanation:
Water, or H20, starts boiling at 100ºC.
Nitrogen, or N2, starts boiling at -195.8ºC.
Carbon monoxide, or C0, starts boiling at -191.5ºC.
When we place these in order from decreasing boiling point:
-195.8º goes first, then -191.5º, and 100º goes last.
Answer:
therefore, N2, CO, H20
Decreasing boiling point
Explanation:
the bond existing in H2O is hydrogen bond
bond existing in N2 is covalent bond, force existing is dipole-dipole-interaction
bond existing in CO is covalent bond , force existing between is induced -dipole- induced dipole-interaction
hydrogen bond is the strongest , followed by dipole-dipole-interaction and induced -dipole- induced dipole-interaction
the stronger the bond , the higher the boiling point
therefore, N2, CO, H20
-------------------------------------->
Decreasing boiling point
What is the ph of 0.36M HNO3 ?
Answer:
0.44
Explanation:
We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.
For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M
pH= -log [H^+]
pH= - log[0.36]
pH= 0.44
A piece of plastic sinks in oil but floats in water. Place these three substances in order from lowest density to greatest density.
Answer:
[tex]\rho _{oil}<\rho _{plastic}<\rho _{water}[/tex]
Explanation:
Hello,
In this case, since water and oil are immiscible due to the oil's nonpolarity and water's polarity, when mixed, the oil remains on the water since it is less dense than water. In such a way, for a plastic sunk in the oil and floating on the water (in middle of them) we can conclude that the plastic have a mid density, therefore, the required organization is:
[tex]\rho _{oil}<\rho _{plastic}<\rho _{water}[/tex]
Best regards.
Compounds A and B (both C10H14) show prominent peaks in their mass spectrum at m/z 134 and 119. Compound B also shows a less prominent peak at m/z 91. On vigorous oxidation with chromic acid, compound A is nonreactive while compound B yielded terephthalic acid.
Required:
From this information, deduce the structures of both compounds, and then draw the structure of B.
An electrolysis cell has two electrodes. Which statement is correct? A. Reduction takes place at the anode, which is positively charged. B. Reduction takes place at the cathode, which is positively charged. C. Reduction takes place at the dynode, which is uncharged. D. Reduction takes place at the cathode, which is negatively charged. E. Reduction takes place at the anode, which is negatively charged.
Answer:
D. Reduction takes place at the cathode, which is negatively charged.
Explanation:
In an electrolytic cell there are two electrodes; the cathode and the anode. The anode is the positive electrode while the cathode is the negative electrode. Oxidation occurs at the anode while reduction occurs at the cathode.
At the anode, species give up electrons and become positively charged ions while at the cathode species accept electrons and become reduced.
is the general formula of a certain hydrate. When 256.3 g of the compound is heated to drive off the water, 214.2 g of anhydrous compound is left. Further analysis shows that the percentage composition of the anhydrate is 21.90% Ca, 43.14% Se, and 34.97% O.. (Hint: Treat the anhydrous compound and water just as you have treated elements in calculating in the formula of the hydrate.) (Use an asterisk to enter the dot in the formula. If a subscript is 1, omit it.) Find the empirical formula of the anhydrous compound. Find the empirical formula of the hydrate.
Answer:
The general formula of the hydrate is Caa Seb Oc. nH2O. Based on the given information, the weight of the hydrated compound is 256.3 grams, the weight of the anhydrous compound is 214.2 grams.
Therefore, the weight of water evaporated is 256.3 g - 214.2 g = 42.1 grams
The molecular weight of water is 18 gram per mole. So, the number of moles of water will be,
Moles of water = weight of water/molecular weight
= 42.1 grams / 18 = 2.3
The given composition of calcium is 21.90 %. So, the concentration of calcium in anhydrous compound is,
= 214.2 * 0.2190 = 46.91 grams
The given composition of Se is 43.14 %. So, the concentration of selenium in anhydrous compound is,
= 214.2 * 0.4314 = 92.40 grams
The given composition of oxygen is 34.97%, So, the concentration of oxygen in anhydrous compound is,
= 214.2 * 0.3497 = 74.91 grams
The molecular weight of Ca is 40.078, the obtained concentration is 46.91 grams, stoichiometry will be, 46.91/40.078 = 1.17
The molecular weight of Se is 78.96, the obtained concentration is 92.40, stoichiometry will be,
92.40/78.96 = 1.17
The molecular weight of Oxygen is 15.999, the concentration obtained is 74.91, the stoichiometry will be,
74.91/15.999 = 4.68.
Thus, the formula becomes, Ca1.17. Se1.1e O4.68. 2.3H2O, the closest actual component is CaSeO4.2H2O
Question 14 (5 points)
What's the acid ionization constant for an acid with a pH of 2.11 and an equilibrium
concentration of 0.30 M?
O A) 4.87x10-8
B) 1.99x10-6
C) 3.32x10-4
OD) 2.01x10-4
Answer:
D) 2.01 x 10⁻⁴ .
Explanation:
pH = 2.11
[ H⁺ ] = [tex]10^{-2.11}[/tex]
Let the acid be HA
It will ionise as follows .
HA ⇄ H⁺ + A⁻
in equilibrium .30 [tex]10^{-2.11}[/tex] [tex]10^{-2.11}[/tex]
Acid ionisation constant Ka = [tex]\frac{(10^{-2.11})^2}{0.3}[/tex]
= 2 x 10⁻⁴
Answer:
D) 2.01 x 10⁻⁴ is correct!
Explanation:
I got it in class!
Hope this Helps!! :))
Nitric oxide reacts with oxygen to give nitrogen dioxide, an important reaction in the Ostwald process for the industrial synthesis of nitric acid: 2NO(g)+O2(g)⇌2NO2(g)
Part A If Kc=6.9×105 at 227 ∘C,
what is the value of Kp at this temperature? Express your answer using two significant figures. Kp =
Part BIf Kp=1.3×10−2 at 1000 K, what is the value of Kc at 1000 K? Express your answer using two significant figures. Kc =
Answer:
Kp=1.68×10⁴∆1.7×10⁴
Kc=1.06∆1.1
Explanation:
Value of Kp at 227°C is 2.86×10² and value of Kc at 1000 K is 1.56.
How are Kp and Kc related?Kp and Kc are related by the formula Kp=Kc(RT).For part A , Kp is calculated as,
Kp=6.9×10⁵×8.314×500=28.683×10² and for part B Kc is calculated as,
Kc=1.3×10[tex]^-2[/tex]/(8.314×1000)=1.56
Kc and Kp are equilibrium constants of a mixture of ideal gases. Kp is equilibrium constant when concentrations at equilibrium are in atmospheric pressure and Kc is equilibrium constant when concentrations are in molarity. The relation is only valid for gaseous mixtures. The relation between these two parameters is obtained through ideal gas equation.
Kc and Kp of reaction change with temperature of reaction but remain unaffected by change in concentration , pressure and presence of catalyst.
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Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced.
_______ → Ba(ClO)2 + H2O(l)
Answer:
2HClO(aq) + Ba(OH)₂(aq) → Ba(ClO)₂(aq) + 2H₂O(l)
Explanation:
The reaction corresponds to a neutralization reaction between an acid and a base, as follows:
2HClO(aq) + Ba(OH)₂(aq) → Ba(ClO)₂(aq) + 2H₂O(l)
From the equation above we have that the acid HClO reacts with the base Ba(OH)₂ to obtain a salt Ba(ClO)₂ and water.
In the balanced reaction, we have that 2 moles of HClO react with 1 mol of Ba(OH)₂ to produce 1 mol of Ba(ClO)₂ and 2 moles of water.
I hope it helps you!
What are the conjugate acid-base pairs in the following chemical reaction? HBr(aq)+ CH3COOH(aq) ⇌ CH3C(OH)2+(aq) + Br-(aq)
Answer:
HBr, CH3C(OH)2 and CH3COOH, Br-
Explanation:
The conjugate acid-base pairs acid reacts with base to form a conjugate acid and conjugate base.
Conjugate acid is formed when a bases receives a proton (H+) and a conjugate base is formed when an acid losses a proton (H+).
From the given equation:
HBr, CH3C(OH)2 and CH3COOH, Br- are conjugate acid-base pair, where HBr is an acid and CH3C(OH)2 is a conjugate acid while CH3COOH and Br- is the conjugate base.
The normal boiling point of a liquid is 282 °C. At what temperature (in °C) would the vapor pressure be 0.350 atm? (∆Hvap = 28.5 kJ/mol)
Answer:
The temperature at which the vapor pressure would be 0.350 atm is 201.37°C
Explanation:
The relationship between variables in equilibrium between phases of one component system e.g liquid and vapor, solid and vapor , solid and liquid can be obtained from a thermodynamic relationship called Clapeyron equation.
Clausius- Clapeyron Equation can be put in a more convenient form applicable to vaporization and sublimation equilibria in which one of the two phases is gaseous.
The equation for Clausius- Clapeyron Equation can be expressed as:
[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]
where ;
[tex]P_1[/tex] is the vapor pressure at temperature 1
[tex]P_ 2[/tex] is the vapor pressure at temperature 2
∆Hvap = enthalpy of vaporization
R = universal gas constant
Given that:
[tex]P_1[/tex] = 1 atm
[tex]P_ 2[/tex] = 0.350 atm
∆Hvap = 28.5 kJ/mol = 28.5 × 10³ J/mol
[tex]T_1[/tex] = 282 °C = (282 + 273) K = 555 K
R = 8.314 J/mol/k
Substituting the above values into the Clausius - Clapeyron equation, we have:
[tex]\mathtt{In \dfrac{P_2}{P_1}= \dfrac{\Delta \ H _{vap}}{R} \begin {pmatrix} \dfrac{T_2 -T_1}{T_2 \ T_1} \end {pmatrix} }[/tex]
[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{T_2 - 555}{555T_2} \end {pmatrix} }[/tex]
[tex]\mathtt{In \begin {pmatrix} \dfrac{0.350}{1} \end {pmatrix} } = \dfrac{28.5 \times 10^3 }{ 8.314 } \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]- 1.0498= 3427.953 \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]\dfrac{- 1.0498}{3427.953}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]- 3.06246906 \times 10^{-4}= \begin {pmatrix} \dfrac{1}{555}- \dfrac{1}{T_2} \end {pmatrix} }[/tex]
[tex]\dfrac{1}{T_2} = \begin {pmatrix} \dfrac{1}{555}+ (3.06246906 \times 10^{-4} ) \end {pmatrix} }[/tex]
[tex]\dfrac{1}{T_2} = 0.002108048708[/tex]
[tex]T_2 = \dfrac{1}{0.002108048708}[/tex]
[tex]\mathbf{T_2 }[/tex] = 474.37 K
To °C ; we have [tex]\mathbf{T_2 }[/tex] = (474.37 - 273)°C
[tex]\mathbf{T_2 }[/tex] = 201.37 °C
Thus, the temperature at which the vapor pressure would be 0.350 atm is 201.37 °C
The temperature of the liquid at the given vapor pressure is 201.5 ⁰C.
The given parameters;
boiling point temperature, = 282 ⁰Cvapor pressure, P₂ = 0.35 atmenthalpy of vaporization, ∆Hvap = 28.5 kJ/molThe temperature of the liquid will be determined by applying Clausius- Clapeyron Equation;
[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )[/tex]
where;
R is ideal gas constant = 8.314 J/mol.kT₁ is the initial temperature in Kelvin = 282 + 273 = 555 KP₁ is the initial pressure = 1 atm[tex]ln(\frac{P_2}{P_1} ) = \frac{\Delta H}{R} (\frac{T_2 -T_1}{T_1T_2} )\\\\ln(\frac{0.35}{1} ) = \frac{28.5 \times 10^3}{8.314} (\frac{T_2 - 555}{555T_2} )\\\\-1.049 = 6.176- \frac{3427.95}{T_2} \\\\\frac{3427.95}{T_2} = 6.176 + 1.049\\\\\frac{3427.95}{T_2} = 7.225\\\\T_2 = \frac{3427.95}{7.225} \\\\T_2 = 474.5 \ K\\\\T_2 = 474.5 - 273 = 201.5 \ ^0C[/tex]
Thus, the temperature of the liquid at the given vapor pressure is 201.5 ⁰C.
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A hypothetical metal crystallizes with the face-centered cubic unit cell. The radius of the metal atom is 198 picometers and its molar mass is 195.08 g/mol. Calculate the density of the metal in g/cm3.
Answer:
7.38 g/cm³ is the density of the metal
Explanation:
In a Face-centered cubic unit cell you have 4 atoms. Also, the edge length is √8×r (r is radius of the atom).
To solve this problem, we need first to calculate the volume of the unit cell and then, with molar mass calculate the mass of 4 atoms. As density is the ratio between mass and volume we can obtain this value.
Volume of the unit cellVolume = a³
a = √8×r
(r = 198x10⁻¹²m)
a = 5.6x10⁻¹⁰ m
Volume = 1.756x10⁻²⁸ m³
1m = 100cm → 1m³ = (100cm)³:
1.756x10⁻²⁸ m³× ((100cm)³ / 1m³) =
1.756x10⁻²² cm³ → Volume of the unit cell in cm³Mass of the unit cell:There are 4 atoms of gold:
4 atoms × (1mol / 6.022x10²³ atoms) = 6.64x10⁻²⁴ moles of gold
As 1 mole weighs 195.08g:
6.64x10⁻²⁴ moles of gold × (195.08g / mol) =
1.296x10⁻²¹g is the mass of the unit cellDensity of the metal:1.296x10⁻²¹g / 1.756x10⁻²² cm³ =
7.38 g/cm³ is the density of the metalThe density of the metal is 7.40 g/cm³
In cubic crystal system, face-centered cubic FFC is the name given to sort of atom arrangement observed in which structure is made up of atoms organized in a cube with a portion of an atom in each corner and six extra atoms in the center of each cube face.
It is expressed by using the formula:
[tex]\mathbf{\rho = \dfrac{Z \times M}{N_A\times a^}}[/tex]
where;
[tex]\rho[/tex] = density of the metalZ = atoms coordination no = 4 (for FCC)Molar mass (M) = 195.8 g/molAvogadro's constant (NA) = 6.022 × 10²³ /mola = edge lengthFor face-centered cubic FFC;
The edge length [tex]\mathbf{a =2 \sqrt{2}\times r }[/tex]
[tex]\mathbf{a =2 \sqrt{2}\times 198 \ pm }[/tex]
[tex]\mathbf{a =560.0285 \ pm }[/tex]
a = 5.60 × 10⁻⁸ cm
Replacing it into the previous equation, we have:
[tex]\mathbf{\rho = \dfrac{4 \times 195.8}{6.022 \times 10^{23} \times( 5.60 \times 10^{-8} )^3}}[/tex]
[tex]\mathbf{\rho = 7.40\ g/cm^3 }[/tex]
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How many atoms are in 65.0g of zinc?
from
1moles=iatom
Mole=mass÷avogardos
Where
Avogadro's= 6.02×10²³
So moles = 65.0÷6.02×10²³
Atoms of zinc = 391.6 ×10²³
The number of atoms present in the given mass of Zinc that is 65.0gm is [tex]5.99\times10^{ 23}[/tex].
Atoms are the basic building blocks of matter. They are the smallest units of an element that retain the chemical properties of that element.
Now, to determine the number of atoms in a given number of moles, we can use Avogadro's number, which is approximately [tex]6.022 \times10^{23}[/tex]atoms per mole.
First, we calculate the number of moles of zinc in 65.0g by dividing the given mass by the molar mass of zinc. The molar mass of zinc (Zn) is 65.38 g/mol.
Number of moles = Mass / Molar mass
Number of moles = 65.0g / 65.38 g/mol ≈ 0.9942 mol
Next, multiply the number of moles by Avogadro's number to find the number of atoms.
Number of atoms =[tex]Number of moles \times Avogadro's number[/tex]
Number of atoms = [tex]0.9942[/tex]mol × [tex]6.022 \times10^{23}[/tex] atoms/mol
Therefore, approximately [tex]5.99\times10^{ 23}[/tex] atoms are present in 65.0g of zinc.
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Which of the following contains a nonpolar covalent bond?
O A. Co
B. NaCl
O C. 02
O D. HE
Answer:
The answer is o2
Explanation:
I took the test
A student is using a coffee-cup calorimeter to determine the enthalpy change of the endothermic reaction of two aqueous solutions. After both solutions are added to the cup, the student neglects to put the lid on the cup. This would cause the magnitude of the calculated ΔH° value to be: the answer is: too small, since the solution will absorb heat from the room. But why? Wouldn't depend on if the reaction releases or absorbs heat. Wouldn't it be too large because heat escapes the cup? I'm so confused
Answer:
Explanation:
In all calorimetric experiment , the calorimeter must be isolated from the surrounding . Otherwise the heat change in the experiment can not be determined with precision .
The reaction is endothermic . Hence, there is lowering of temperature due to absorption of heat in the reaction equal to ΔH°. The value of ΔH° can be calculated by measuring fall in the temperature of the content . The fall in the temperature will be less when heat is allowed to come from the surrounding . Less fall of temperature will result in less ΔH° to be calculated .
Hence in the given experiment , if the student neglects to put lid on the cup , the experiment will give less value of ΔH°.
People take antacids, such as milk of magnesia, to reduce the discomfort of acid stomach or heartburn. The recommended dose of milk of magnesia is 1 teaspoon, which contains 500 mg of Mg(OH)2. What volume of HCl solution with a pH of 1.25 can be neutralized by 1 dose of milk of magnesia
Answer:
[tex]V_{HCl}=0.208L=208mL[/tex]
Explanation:
Hello,
In this case, since the chemical reaction is:
[tex]2HCl+Mg(OH)_2\rightarrow MgCl_2+2H_2O[/tex]
We can see that hydrochloric acid and magnesium hydroxide are in a 2:1 mole ratio, which means that the neutralization point, we can write:
[tex]n_{HCl}=2*n_{Mg(OH)_2}[/tex]
In such a way, the moles of magnesium hydroxide (molar mass 58.3 g/mol) in 500 mg are:
[tex]n_{Mg(OH)_2}=500mg*\frac{1g}{1000mg}*\frac{1mol}{58.3g} =0.00858mol[/tex]
Next, since the pH of hydrochloric acid is 1.25, the concentration of H⁺ as well as the acid (strong acid) is:
[tex][H^+]=[HCl]=10^{-pH}=10^{-1.25}=0.0562M[/tex]
Then, since the concentration and the volume define the moles, we can write:
[tex][HCl]*V_{HCl}=2*n_{Mg(OH)_2}[/tex]
Therefore, the neutralized volume turns out:
[tex]V_{HCl}=\frac{2*0.00858mol}{0.0562\frac{mol}{L} }\\ \\V_{HCl}=0.208L=208mL[/tex]
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